Abstract: An encapsulation composition, an encapsulation film including the same, an encapsulation product for organic electronic devices, and a method of manufacturing an organic electronic device are provided. The encapsulation composition can be useful in effectively preventing moisture or oxygen from flowing into the organic electronic device from external environments while realizing transparency when the organic electronic device is encapsulated by the encapsulation composition. Also, the encapsulation film formed of the encapsulation composition can be useful in ensuring mechanical properties such as handling properties and processability, and the organic electronic device whose encapsulation structure is formed by means of the encapsulation film may have improved lifespan and durability, thereby providing an encapsulation product for organic electronic devices showing high reliability.

Abstract: A metal organic framework (MOF) includes a coordination product of a metal ion and an at least bidentate organic ligand, where the metal ion and the organic ligand are selected to provide a deliverable adsorption capacity of at least 70 g/l for an electronic gas. A porous organic polymer (POP) includes polymerization product from at least a plurality of organic monomers, where the organic monomers are selected to provide a deliverable adsorption capacity of at least 70 g/l for an electronic gas.

Abstract: A reaction system and method for preparing compounds or intermediates from solid reactant materials is provided. In a specific aspect, a reaction system and methods are provided for preparation of boron-containing precursor compounds useful as precursors for ion implantation of boron in substrates. In another specific aspect, a reactor system and methods are provided for manufacture of boron precursors such as B2F4.

Abstract: A method of recycling mixtures of hydrochloric and hydrofluoric acid. In particular, a method of recycling hydrofluoric acid and boron fluoride mixtures. A process for upgrading mixtures of fluoroboron compounds contaminated with chlorides as an aqueous solution of boron fluoride hydrates, including a step of vacuum distillation. Also, a method of producing gaseous boron trifluoride.

Abstract: Provided are methods for storing gases on porous adsorbents, methods for optimizing the storage of gases on porous adsorbents, methods of making porous adsorbents, and methods of gas storage of optimized compositions, as in systems containing porous adsorbents and gas adsorbed on the surface of the porous adsorbent. The disclosed methods and systems feature a constant or increasing isosteric enthalpy of adsorption as a function of uptake of the gas onto the exposed surface of a porous adsorbent. Adsorbents with a porous geometry and surface dimensions suited to a particular adsorbate are exposed to the gas at elevated pressures in the specific regime where n/V (density) is larger than predicted by the ideal gas law by more than several percent.

Abstract: The present invention relates to a process for separating close-boiling and azeotropic components of mixtures, wherein said mixtures contain at least one hydrofluorocarbon compound, using at least one ionic liquid.

Abstract: An apparatus is described, as including a reaction region for contacting a reactant gas with a reactive solid under conditions effective to form an intermediate product, and an opening for allowing an unreacted portion of the gaseous reagent and the intermediate product to exit the reaction region. The apparatus can be beneficially employed to form a final product as a reaction product of the intermediate product and the reactant gas. The reaction of the reactant gas and reactive solid can be conducted in a first reaction zone, with the reaction of the reactant gas and intermediate product conducted in a second reaction zone. In a specific implementation, the reaction of the reactant gas and intermediate product is reversible, and the reactant gas and intermediate product are flowed to the second reaction zone at a controlled rate or in a controlled manner, to suppress back reaction forming the reactive solid.

Abstract: High energy reaction of halogen-containing carbon, boron, silicon and nitrogen compounds, with base component comprising at least one atom selected from Groups IA to VIA, transition metals, lanthanides and actinides of the Periodic Table of the Elements, excluding aluminum and aluminum oxide.

Abstract: An isotopically-enriched, boron-containing compound comprising two or more boron atoms and at least one fluorine atom, wherein at least one of the boron atoms contains a desired isotope of boron in a concentration or ratio greater than a natural abundance concentration or ratio thereof. The compound may have a chemical formula of B2F4. Synthesis methods for such compounds, and ion implantation methods using such compounds, are described, as well as storage and dispensing vessels in which the isotopically-enriched, boron-containing compound is advantageously contained for subsequent dispensing use.

Abstract: Disclosed is a process for producing a fluoride gas that can produces fluoride gases such as BF3, SiF4, GeF4, PF5 or AsF5 at a reduced production cost in a simple manner. The process is characterized in that a compound containing an atom, which, together with a fluorine atom, can form a polyatomic ion, is added to a hydrogen fluoride solution to produce the polyatomic ion in a hydrogen fluoride solution and to evolve a fluoride gas comprising the fluorine atom and the atom that, together with the fluorine atom, can form a polyatomic ion.

Abstract: An isotopically-enriched, boron-containing compound comprising two or more boron atoms and at least one fluorine atom, wherein at least one of the boron atoms contains a desired isotope of boron in a concentration or ratio greater than a natural abundance concentration or ratio thereof. The compound may have a chemical formula of B2F4. Synthesis methods for such compounds, and ion implantation methods using such compounds, are described, as well as storage and dispensing vessels in which the isotopically-enriched, boron-containing compound is advantageously contained for subsequent dispensing use.

Abstract: Embodiments are described that generally relate to the storage and release of a gas using piezoelectric materials.

Abstract: Orthoborate salts suitable for use as electrolytes in lithium batteries and methods for making the electrolyte salts are provided. The electrolytic salts have one of the formulae (I). In this formula anionic orthoborate groups are capped with two bidentate chelating groups, Y1 and Y2. Certain preferred chelating groups are dibasic acid residues, most preferably oxalyl, malonyl and succinyl, disulfonic acid residues, sulfoacetic acid residues and halo-substituted alkylenes. The salts are soluble in non-aqueous solvents and polymeric gels and are useful components of lithium batteries in electrochemical devices.

Abstract: Methods of implanting boron-containing ions using fluorinated boron-containing dopant species that are more readily cleaved than boron trifluoride. A method of manufacturing a semiconductor device including implanting boron-containing ions using fluorinated boron-containing dopant species that are more readily cleaved than boron trifluoride. Also disclosed are a system for supplying a boron hydride precursor, and methods of forming a boron hydride precursor and methods for supplying a boron hydride precursor. In one implementation of the invention, the boron hydride precursors are generated for cluster boron implantation, for manufacturing semiconductor products such as integrated circuitry.

Abstract: The present invention provides an apparatus and method for the purification of gaseous inorganic halides utilizing a reactive metal and molecular sieves to remove impurities.

Abstract: The invention relates to the preparation of BF3 and H2SO4 of commercial grade from boron trifluoride hydrate effluents containing organic impurities. The process consists essentially in reacting the said effluent with oleum, in recovering the gaseous boron trifluoride thereby liberated and in subjecting the sulphuric acid by-product to treatment with hydrogen peroxide and to purging with air.

Abstract: The invention relates to the preparation of BF3 and H2SO4 of commercial grade from boron trifluoride hydrate effluents containing organic impurities.

Abstract: A method and apparatus for providing a substantially homogenous composition from partially immiscible liquids is disclosed where effective energy is applied as pulses of a given frequency to the interface region of an emulsion. The method and apparatus of the invention show substantial savings and efficiency in comparison with conventional methods.

Abstract: BF3, CO2 or both are removed from a mixture containing these gases with B2H6 by contacting the mixture with an inorganic hydroxide such as LiOH. B2H6 is synthesized by contacting BF3 with KBH4.

Abstract: Linear backbone phosphorus-boron polymers of the general formula (I): wherein R1, R2, R3, and R4, are the same or different and selected from H, optionally substituted alkyl, alkenyl and phenyl; and n is at least 2, and particularly high molecular weight polymers of absolute weight average molecular weight of at least 10,000. The polymers are of use as fire retardants.

Abstract: A dissolving device for dissolving a particulate solid in a supercritical or almost critical fluid comprises a circulation loop, in which there is a feed for feeding a feed stream of the supercritical or almost critical fluid, a cyclone, which is in communication with the feed and has a principal discharge for discharging a principal discharge stream of a solution of the particulate solid in the supercritical or almost critical fluid and has an auxiliary discharge for discharging an auxiliary stream of the supercritical or almost critical fluid with solid particles dispersed therein, the auxiliary discharge being in communication with the said feed. A dissolving device of this type has a low pressure drop and a high dissolving rate compared to the prior art.

Abstract: A method for producing uranium oxide includes combining uranium oxyfluoride and a solid oxidizing agent having a lower thermodynamic stability than the uranium oxide after "oxide"; heating the combination below the vapor point of the uranium oxyfluoride to sufficiently react the uranium oxyfluoride and the oxidizing agent to produce uranium oxide and a non-radioactive fluorine compound; and removing the fluorine compound after "compound".

Abstract: A system for the storage and delivery of a sorbable fluid, comprising a storage and dispensing vessel containing a sorbent material having sorptive affinity for the sorbable fluid, and from which the fluid is desorbable by pressure-mediated and/or thermally-mediated desorption, wherein the sorbent material is functionally enhanced by a reagent which alters the binding energy of the fluid to the sorbent. In a preferred aspect, the system is arranged for storage and delivery of B.sub.2 H.sub.6, in which the sorbent material has sorptive affinity for B.sub.2 H.sub.6 and is effective when B.sub.2 H.sub.6 is contacted with the sorbent to convert B.sub.2 H.sub.6 to a sorbed .BH.sub.3 form, which is desorbable by pressure-mediated desorption and/or thermally-mediated desorption to release B.sub.2 H.sub.6 from the sorbent, and means for selectively discharging desorbed B.sub.2 H.sub.

Abstract: A fire suppressant powder with particle sizes less than 5 .mu.m is made by a chemical reaction between a gas or vapour of a first material and a vapour or an aerosol of a second material. For example an aerosol of sodium hydroxide droplets may be reacted with carbon dioxide gas to produce sodium bicarbonate powder; or boron halide vapour may be reacted with steam to form boric acid powder The powder may be used in fire extinguishers either on its own, or combined with other ingredients such as silica and/or alumina, and calcium stearate.

Abstract: A method for producing uranium oxide includes combining uranium tetrafluoride and a solid oxidizing agent having a lower thermodynamic stability than the uranium oxide; heating the combination below the vapor point of the uranium tetrafluoride to sufficiently react the uranium tetrafluoride and the oxidizing agent to produce uranium oxide and a non-radioactive fluorine compound; and removing the fluorine compound.

Abstract: A method for effectively separating and removing or recovering BF.sub.3 existing in a liquid hydrocarbon which is characterized in that an organic liquid mixture containing suspended or dissolved BF.sub.3 is brought into liquid phase contact with a synthetic polymer fiber containing nitrile groups at a temperature of 50.degree. C. or lower, so that the BF.sub.3 is adsorbed by the synthetic polymer fiber and it is then heated to 80.degree. C. or higher to recover the BF.sub.3.

Abstract: A method of extracting a mineral or mineral species comprising contacting the mineral or mineral species with a leachate solution which contains metal or metalloid ions capable of forming soluble fluoro-complexes of high bond strength with fluorine in the mineral or mineral species.

Abstract: BF.sub.3 is vaporized from specified crude polyolefin reaction product mixture in a vaporization zone at a temperature insufficient to decompose BF.sub.3 or any BF.sub.3 promoter complex in the mixture, and the vaporized BF.sub.3 may be recovered directly. Further, a process for the oligomerization of a liquid olefin composition and recovery of BF.sub.3 is described in which inert volatile material present in a liquid olefin composition is removed from the composition by vaporization, forming a degassed liquid olefin composition free of inert volatile material. The degassed liquid olefin composition is then contacted in a reaction zone with BF.sub.3 under conditions to oligomerize the olefin, forming crude polyolefin oligomerization reaction product mixture containing dissolved BF.sub.3, which may be treated as described.

Abstract: The isotopes of boron, .sup.10 B and .sup.11 B, are separated by means of a gas-liquid chemical exchange reaction involving the isotopic equilibrium between gaseous BF.sub.3 and a liquid BF.sub.3 . donor molecular addition complex formed between BF.sub.3 gas and a donor chosen from the group consisting of: nitromethane, acetone, methyl isobutyl ketone, or diisobutyl ketone.

Abstract: A method of imaging a corporeal situs by radiological techniques, comprising delivery to the corporeal situs of an imagingly effectively amount of a physiologically acceptable composition comprising a boron reagent. A variety of illustrative boron reagents is described, including iodinated boron salts, and boron-containing cyclophosphazene and polyphosphazene reagents having radiopaque character. The reagents and method of the present invention may be employed for a wide variety of radiological imaging applications, e.g., excretory urography, angiocardiography, and aortography.

Abstract: Recovery of cerium values from fluoride-containing ores such as bastnasite is enhanced. The ore is ground, roasted, and leached with dilute hydrochloric acid to produce an ore concentrate. The concentrate is treated with a solution of hydrochloric acid and boric acid to solubilize cerium values and convert fluoride to tetrafluoroborate ion. Tetrafluoroborate is removed from the solution, e.g., by precipitation, and the solution is further processed for recovery of cerium values. Removal of tetrafluoroborate avoids loss of cerium as insoluble cerium tetrafluorborate during said further processing.

Abstract: Disclosed herein are boron trifluoride etherate complexes in which the ether of the complex has at least one tertiary carbon bonded to an ether oxygen. The etherates are useful for polymerizing a one-olefin or mixtures thereof, preferably comprising isobutylene, whereby the resulting polymer contains a high percentage (80-100%) vinylidene character.

Abstract: The method for preparing a gaseous metallic floride is here disclosed which comprises reacting a metal or its oxide with a fluorine gas or nitrogen trifluoride gas, the aforesaid method being characterized by comprising the steps of mixing the metal or its oxide with a molding auxiliary comprising a solid metallic fluoride which does not react with fluorine and nitrogen trifluoride; molding the resulting mixture under pressure; and contacting the molded pieces with the fluorine gas or nitrogen trifluoride gas, while the molded pieces are heated.

Abstract: The present invention provides a process for recovering boron trifluoride from an impure gaseous boron trifluoride residue. The process comprises: (a) feeding an impure gaseous boron trifluoride residue containing sulfur dioxide as an impurity into a mixture of boric and sulfuric acids wherein the acid mixture absorbs boron trifluoride from the impure boron trifluoride residue and slightly absorbs or does not absorb sulfur dioxide from the impure gaseous boron trifluoride residue; and (b) removing the unabsorbed sulfur dioxide from the acid mixture.The present invention also provides a boron trifluoride preparation and purification process.

Abstract: A multistage process for preparing pure BF.sub.3 from hexafluorosilicic acid, H.sub.2 SiF.sub.6, comprises reacting H.sub.2 SiF.sub.6 with oxygen acids of boron and/or boron oxide in the first stage to give hydroxyfluoroboric acid and silica, filtering off the silica and concentrating the hydroxyfluoroboric acid, adding oleum to the concentrate and then heating to form gaseous BF.sub.3.

Abstract: Stannous salts of a non-oxidizing anionic acid, e.g., stannous fluoborate or stannous sulfate, are prepared by reacting metallic tin with a preferably aqueous solution of such acid in the presence of a catalytically effective amount of finely divided catalyst particles, e.g., comprised of a precious metal, said catalyst particles providing hydrogen release at low overvoltages.

Abstract: Sulfuric acid contaminated with boron and fluoride values such as the waste acid of a boron trifluoride process is purified by contacting the contaminated acid with an inert gas to desorb boron trifluoride, and the inert gas is stripped by contacting with an absorbing liquid including concentrated sulfuric acid. Hydrogen fluoride and/or fluorosulfuric acid are added to contaminated sulfuric acid as agents to spring non-volatile boron value. In addition, the water content of the contaminated acid is adjusted within a narrow concentration range, to improve the efficiency of both the stripping and the absorption operations. The absorption of boron trifluoride into the absorbing sulfuric acid is improved when it contains boric acid. Preferably the contaminated sulfuric acid to be purified is one portion of the waste liquid and the absorbing liquid is another portion of the waste liquid of a boron trifluoride manufacturing process.

Abstract: A novel method for synthesizing pentafluorotellurium hypofluorite by effecting a reaction between B(OTeF.sub.5).sub.3 and elemental fluorine.

Abstract: Molten alkaline earth metal halides are used to convert highly stable oxides into the corresponding anhydrous halides. Usually a third reactant, such as silica, is added in order to bind the basic oxide thus formed. The solid oxide compounds (e.g. silicates) which result are wellknown ceramic phases of a high degree of purity.

Abstract: A process for the purification of by-product sulfuric acid resulting from the synthesis of boron trifluoride, wherein the ratio of fluorine to boron is three or more, which process comprises entraining the by-product acid in an inert gas, the process being characterized in that before entrainment the anhydrous sulfuric acid is diluted with water in a proportion of from about one to about ten percent by weight of water with respect to the acid to be treated, the temperature being maintained above 90.degree. C., the sulfuric acid obtained containing less than 0.003% fluorine and less than 0.005% boron, so that the quality is substantially equivalent to a sulfuric acid directly obtained by the oxidation of sulfur.

Abstract: A process for the decomposition of complexes of ortho-benzoyl benzoic acids, hydrogen fluoride, and boron trifluoride, whether or not the ortho-benzoyl benzoic acid is substituted, is disclosed wherein the ortho-benzoyl benzoic acid is obtained separately from the hydrogen fluoride and boron trifluoride. This process is characterized in that the complex is treated with an inert solvent at a temperature of at least 20.degree. C., in a distillation column having at least about 8 theoretical plates whereby the solvent reflux is operated at a rate equal to about 5 to about 40 times the weight of the feed delivery rate of the column.The process of the present invention also makes it possible to recover hydrogen fluoride and boron trifluoride for reuse as catalysts in the synthesis of ortho-benzoyl benzoic acid without causing decomposition of the acid.

Abstract: Metallic phosphates are prepared by heating mixtures of BPO.sub.4 and a metallic oxide or salt.

Abstract: The invention includes a process wherein an olefin is carbonylated with carbon monoxide to form carboxylic acid esters in the presence of a catalyst complex of one mole of BF.sub.3 and one mole of alcohol, and the catalyst is recovered from the desired reaction product and the reaction by-products and is recycled. The carbonylation is carried out until approximately one-half of the alcohol is consumed to form a reaction mass containing the BF.sub.3, the alcohol, and carboxylic acid esters in a 2:1:1 molar ratio. In the first step, the one mole of free BF.sub.3 is vaporized from the reaction mass. The remaining admixture is a 1:1:1 mixture of the aforesaid compounds. To this mixture additional alcohol is added and the mixture is subjected to distillation. An azeotrope of the product carboxylic acid ester and the alcohol and residual alcohol are removed by the distillation, leaving a residue containing a 1:2 BF.sub.

Abstract: Sulfuric acid contaminated with boron and fluoride values such as the waste acid of a boron trifluoride process is purified by contacting the contaminated acid with an inert gas to desorb boron trifluoride, and the inert gas is stripped by contacting with an absorbing liquid including concentrated sulfuric acid. Fluosulfonic acid is added to contaminated sulfuric acid at levels approximately three times the molar values of boric acid contaminant as an agent to spring non-volatile boron values. The absorption of boron trifluoride into the absorbing sulfuric acid is improved when it contains boric acid. Preferably the contaminated sulfuric acid to be purified is one portion of the waste liquid and the absorbing liquid is another portion of the waste liquid of a boron trifluoride manufacturing process. Boric acid is added to the absorbing liquid, then boron trifluoride is stripped from the inert gas and absorbed into the absorbing liquid.

Abstract: A method for recovering dissolved boron trifluoride from a hydrocarbon liquid in a vacuum column at moderate temperatures by trickling the hydrocarbon over metallic or ceramic packing in the column. Dissolved boron trifluoride catalyst is recovered from the crude oligomer reaction product resulting from the oligomerization of 1-decene.

Abstract: Cumene hydroperoxide is decomposed to phenol and acetone using boron trifluoride or a boron trifluoride complex as the decomposition catalyst. The boron trifluoride in the reaction product is reacted with a phosphorus-containing salt of an alkali metal such as sodium phosphate for recovery and reuse in the process.

Abstract: A method wherein a quartz tube is charged with chunks of metallurgical grade silicon and/or a mixture of such chunks and high purity quartz sand, and impurities from a class including aluminum, boron, and the like, as well as certain transition metals including nickel, iron, manganese and the like. The tube is then evacuated and heated to a temperature within a range of 800.degree. C. to 1400.degree. C., whereupon a stream of gas comprising a reactant, such as silicon tetrafluoride, continuously is delivered at low pressures through the charge for causing a metathetical reaction of impurities of the silicon and the reactant to occur for forming a volatile halide and leaving a residue of silicon of an improved purity. Additionally, the reactant may include carbon monoxide gas, whereby impurites such as iron and nickel react therewith to form volatile carbonyls.

Abstract: A mixture of BF.sub.3 gas and vapors of an alkane hydrocarbon having a normal boiling point in the range of about 80.degree. to about 125.degree. C are recovered as exhaust from the partial-condensing zone of a stripping system to which is fed 6-25 weight percent of said alkane as a liquid dissolved in the fluid reaction mixture from BF.sub.3 -phenolate catalyzed alkylation of phenol with 500-3000 M.W. liquid viscous mono-olefinic polymer of propylene or butylene and BF.sub.3 -free portion of the fluid reaction mixture is withdrawn as liquid from the partial-reboiling zone of said system. The removal of BF.sub.3 by use of such stripping operation is successful without boiling a mixture of said alkane and said alkylation reaction mixture.

Abstract: A method for decomposing an aromatic aldehyde-hydrogen fluoride-boron trifluoride complex in the presence of a decomposing agent represented by the formula ##SPC1##Wherein n is integer of 1-6, inclusive, and m is integer of 0-5, inclusive, and a total of n and m is 6 or less, to obtain an aromatic aldehyde, hydrogen fluoride and boron trifluoride separately without causing any change in the quality of the aromatic aldehyde or without forming undesirable byproducts is disclosed.