Hydroxyl Patents (Class 423/707)
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Patent number: 10934416Abstract: A formulation based on two components, which, when added to items produced with epoxy vinyl ester or unsaturated polyester resin, provides the formulation with electric charge dissipation and/or antistatic characteristics, maintaining the mechanical characteristics thereof and the possibility of dyeing the material in all of the possible colour ranges includes a first component which is an active substance which is an ionic salt that allows ion mobility. The cation is a compound based on the (R4)N,N,N-trialkyl-alkyl-ol-ammonium species, as it is or derivatised on the OH group, and a system that supports said active substance. This additive or formulation added to epoxy vinyl ester or unsaturated polyester resin can be used in the production of agglomerated stone, gel coat, sheet moulding composite or bulk moulding composite.Type: GrantFiled: August 24, 2016Date of Patent: March 2, 2021Assignee: AVANZARE INNOVACION TECNOLOGICA S.L.Inventors: Julio Gomez Cordon, Luis Otaño Jimenez, Javier Perez Martinez
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Patent number: 10603639Abstract: A nanocomposite blend membrane and fabrication methods for making the nanocomposite membrane are disclosed. The nanocomposite blend membrane can be utilized in fuel cells. The nanocomposite blend membrane may include a blend polymer with a first sulfonated polymer and a second sulfonated polymer, as well as sulfonated tungsten trioxide (WO3) nanoparticles.Type: GrantFiled: August 23, 2017Date of Patent: March 31, 2020Inventors: Hossein Beydaghi, Mehran Javanbakht, Parisa Salarizadeh, Ahmad Bagheri Kharepouei, Ali Amoo Zadeh
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Patent number: 10138132Abstract: A method is disclosed for synthesizing MTW framework type molecular sieves using 1,1-diethyl-4-methylpiperidinium cations as a structure directing agent.Type: GrantFiled: September 7, 2017Date of Patent: November 27, 2018Assignee: Chevron U.S.A. Inc.Inventor: Dan Xie
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Patent number: 9663377Abstract: A method is disclosed for synthesizing molecular sieve material designated SSZ-105 using N-methyl quinuclidinium cations or N,N?-dimethyl-1,4-diazabicyclo[2.2.2]octane dications as a structure directing agent. SSZ-105 is a disordered aluminosilicate molecular sieve comprising at least one intergrown phase of an ERI framework type molecular sieve and an LEV framework type molecular sieve.Type: GrantFiled: December 9, 2015Date of Patent: May 30, 2017Assignee: Chevron U.S.A. Inc.Inventor: Dan Xie
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Patent number: 9359217Abstract: This disclosure is directed to a new cobalt aluminophosphate molecular sieve designated SSZ-85 and a method for preparing SSZ-85 using a 1,3-diisopropylimidazolium ionic liquid.Type: GrantFiled: December 3, 2013Date of Patent: June 7, 2016Assignee: Chevron U.S.A. Inc.Inventor: Stacey Ian Zones
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Patent number: 9328508Abstract: Process for manufacturing a thermally insulating material comprising the following steps: a) preparing an aqueous mixture of a solid mineral substance in suspension having a specific surface area S of greater than 5 m2/g; b) adding to the mixture at least one pore-forming agent; c) stirring so as to obtain a homogeneous mixture; d) preforming a substrate from the homogeneous mixture; e) optionally drying the substrate at least partially; f) removing, at least partially, the pore-forming agent; and such that said specific surface area S, expressed in m2/g and measured by BET, and the mean particle diameter Dpm of the pore-forming agents, expressed in micrometers and measured by dynamic light scattering, obey the relation: 1/S<Dpm<50/S.Type: GrantFiled: December 7, 2011Date of Patent: May 3, 2016Assignee: SAINT-GOBAIN ISOVERInventors: David Louapre, Caroline Parneix, Veneta Grigorova, Jerome Gilles
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Patent number: 9108190Abstract: The invention provides methods for rapidly synthesizing heteroatom containing zeolites including Sn-Beta, Si-Beta, Ti-Beta, Zr-Beta and Fe-Beta. The methods for synthesizing heteroatom zeolites include using well-crystalline zeolite crystals as seeds and using a fluoride-free, caustic medium in a seeded dry-gel conversion method. The Beta zeolite catalysts made by the methods of the invention catalyze both isomerization and dehydration reactions.Type: GrantFiled: September 12, 2013Date of Patent: August 18, 2015Assignee: University of MassachusettsInventors: Wei Fan, Chun-Chih Chang, Paul Dornath, Zhuopeng Wang
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Patent number: 8916129Abstract: A new family of crystalline aluminosilicate zeolites has been synthesized that has been designated UZM-43. These zeolites are similar to previously known ERS-10, SSZ-47 and RUB-35 zeolites but are characterized by unique x-ray diffraction patterns and compositions and have catalytic properties for carrying out various hydrocarbon conversion processes. Catalysts made from these zeolites are useful in hydrocarbon conversion reactions.Type: GrantFiled: December 18, 2012Date of Patent: December 23, 2014Assignee: UOP LLCInventors: Jaime G. Moscoso, Deng-Yang Jan
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Patent number: 8748684Abstract: A method of crystallizing a crystalline molecular sieve having a pore size in the range of from about 2 to about 19 ?, said method comprising the steps of (a) providing a mixture comprising at least one source of ions of tetravalent element (Y), at least one hydroxide source (OH), and water, said mixture having a solid-content in the range of from about 15 wt. % to about 50 wt. %; and (b) treating said mixture to form the desired crystalline molecular sieve with stirring at crystallization conditions sufficient to obtain a weight hourly throughput from about 0.005 to about 1 hr?1, wherein said crystallization conditions comprise a temperature in the range of from about 200° C. to about 500° C. and a crystallization time less than 100 hr.Type: GrantFiled: August 7, 2013Date of Patent: June 10, 2014Assignee: ExxonMobile Chemical Patents Inc.Inventors: Ivy D. Johnson, Wenyih Frank Lai
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Patent number: 8747807Abstract: A method for preparing a family of zeolites, examples of which have been designated UZM-5, UZM-5P and UZM-6, and are represented by the empirical formula Mmn+Cgh+Rrp+Al(1-x)ExSiyOz The method includes forming a Charge Density Mismatch (CDM) reaction mixture comprising reactive sources of Al, Si, optionally a framework element, E, and at least one organic nitrogen containing cation template, C, in the hydroxide form. After the CDM mixture is mixed while aging, an organic cation crystallization template, R, and at least one alkali metal or alkaline earth metal, M, is added. The combined final reaction mixture is reacted with mixing to produce the zeolite, which may be used in various hydrocarbon conversion processes.Type: GrantFiled: June 29, 2011Date of Patent: June 10, 2014Assignee: UOP LLCInventors: Deng-Yang Jan, Jaime G. Moscoso, Raelynn M. Miller, Susan C. Koster, Julio C. Marte
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Patent number: 8673263Abstract: A method of crystallizing a crystalline molecular sieve having a pore size in the range of from about 2 to about 19 ?, said method comprising the steps of (a) providing a mixture comprising at least one source of ions of tetravalent element (Y), at least one trivalent element hydroxide source (OH?), and water, said mixture having a solid-content in the range of from about 20% to about 30%; and (b) treating said mixture to form the desired crystalline molecular sieve with stirring at crystallization conditions sufficient to obtain a weight hourly throughput from about 0.005 to about 1 hr?1, wherein said crystallization conditions comprise a temperature in the range of from about 200° C. to about 500° C. and a crystallization time less than 100 hr, wherein said crystalline molecular sieve has a zeolite framework type of MFI.Type: GrantFiled: March 8, 2013Date of Patent: March 18, 2014Assignee: ExxonMobil Chemical Patents Inc.Inventors: Ivy D. Johnson, Wenyih F. Lai
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Patent number: 8597611Abstract: A new family of crystalline aluminosilicate zeolites has been synthesized designated UZM-45. These zeolites are represented by the empirical formula. Mmn+Rrp+Al(1-x)ExSiyOz where M is an alkali, alkaline earth, or rare earth metal such as lithium and strontium, R is an organoammonium cation such as the choline cation and E is a framework element such as gallium. These zeolites are characterized by unique x-ray diffraction patterns and compositions and have catalytic properties for carrying out various hydrocarbon conversion processes.Type: GrantFiled: June 29, 2011Date of Patent: December 3, 2013Assignee: UOP LLCInventors: Gregory J. Lewis, Mark A. Miller
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Patent number: 8557220Abstract: The invention concerns a process for preparing an EU-1 zeolite having a XO2/Y2O3 ratio in the range 10 to 100, comprising the following steps: a) mixing, in an aqueous medium, at least one source of at least one oxide XO2, X being selected from silicon and/or germanium, at least one source of at least one oxide Y2O3, Y being selected from aluminium, iron, gallium and boron, and at least one organic template Q; b) drying the reaction mixture derived from step a) at a temperature of less than 200° C.; c) hydrothermal treatment of the dried reaction mixture derived from step b) in an autoclave, said dried reaction mixture not being in contact with a liquid phase at the bottom of the autoclave.Type: GrantFiled: April 14, 2008Date of Patent: October 15, 2013Assignee: IFP Energies NouvellesInventors: Simone Goergen, Loïc Rouleau, Joël Patarin
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Patent number: 8557219Abstract: A method of crystallizing a crystalline molecular sieve having a pore size in the range of from about 2 to about 19 ?, said method comprising the steps of (a) providing a mixture comprising at least one source of ions of tetravalent element (Y), at least one hydroxide source (OH?), and water, said mixture having a solid-content in the range of from about 15 wt. % to about 50 wt. %; and (b) treating said mixture to form the desired crystalline molecular sieve with stirring at crystallization conditions sufficient to obtain a weight hourly throughput from about 0.005 to about 1 hr?1, wherein said crystallization conditions comprise a temperature in the range of from about 200° C. to about 500° C. and a crystallization time less than 100 hr.Type: GrantFiled: January 29, 2007Date of Patent: October 15, 2013Assignee: ExxonMobil Chemical Patents Inc.Inventors: Ivy D. Johnson, Wenyih Frank Lai
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Patent number: 8540956Abstract: The present invention provides a method for preparing large particles of titanium-silicalite molecular sieves. The method of the present invention includes the steps of preparing a dispersion solution of a primary crystalline molecular sieve; forming an aggregated particle solution by adding a flocculating agent and a coagulating agent into the dispersion solution; mixing the aggregated particle solution with a synthesis gel to form a mixture; and heat-treating the mixture. The average diameter of the titanium-silicalite molecular sieves in the present invention is more than 5 ?m. In the preparation of cyclohexanone oxime using the molecular sieve of the present invention as the catalyst, the selectivity and conversion rate of cyclohexanone oxime are high, the usage of hydrogen peroxide is enhanced, and the catalyst is easy to be recovered.Type: GrantFiled: March 29, 2010Date of Patent: September 24, 2013Assignee: China Petrochemical Development CorporationInventors: Pin-To Yao, Cheng-Fa Hsieh, Shih-Yao Chao, Yang-Min Liang
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Patent number: 8518370Abstract: The present invention relates to metalloaluminophosphate (MeAPO) molecular sieve with lamellar crystal morphology having an empirical chemical composition on an anhydrous basis, after synthesis and calcination, expressed by the formula HxMeyAlzPkO2 wherein, y+z+k=1 x<=y said molecular sieve having predominantly a plate crystal morphology in which the width (W) and the thickness (T) are W/T is >=10 The above metalloaluminophosphate (MeAPO) molecular sieve can be made by a method which comprises: a) forming a reaction mixture containing a texture influencing agent (TIA), an organic templating agent (TEMP), at least a reactive inorganic source of MeO2 insoluble in the TIA, reactive sources of AI203 and P205, b) crystallizing the above reaction mixture thus formed until crystals of the metalloaluminophosphate are formed, c) recovering a solid reaction product, d) washing it with water to remove the TIA and e) calcinating it to remove the organic template.Type: GrantFiled: March 10, 2008Date of Patent: August 27, 2013Assignees: Total Petrochemicals Research Feluy, Centre National de la Recherche Scientifique (CNRS)Inventors: Walter Vermeiren, Nikolai Nesterenko, Carolina Petitto, Francesco Di Renzo, Francois Fajula
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Patent number: 8361436Abstract: The invention concerns a crystalline solid designated IM-17 which has the X-ray diffraction diagram given below. Said solid has a chemical composition expressed by the empirical formula: mXO2: nGeO2: pZ2O3: qR: wH2O, in which R represents one or more organic nitrogen-containing species, X represents one or more tetravalent element(s) other than germanium and Z represents at least one trivalent element.Type: GrantFiled: October 17, 2008Date of Patent: January 29, 2013Assignee: IFP Energies NouvellesInventors: Yannick Lorgouilloux, Jean Louis Paillaud, Philippe Caullet, Joel Patarin, Nicolas Bats
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Patent number: 8349291Abstract: Crystalline microporous zeolites designated calcined UZM-22 and UZM-22HS have been synthesized. The calcined UZM-22 is represented by the empirical formula: M1?mn+Al1-xExSiyOz and UZM-22HS has an empirical formula of: M1an+Al(1-x)ExSiy?Oz? where M1 and M1? are exchangeable cations such as lithium or strontium and E is a framework element such as gallium. Both zeolites are obtained from an as synthesized microporous crystalline composition having an empirical formula of: Mmn+RrAl1-xExSiyOz either by calcination for UZM-22 or by various treatments such as ammonium hexafluorosilicate treatment for UZM-22HS.M is an alkali, alkaline earth, or rare earth metal such as lithium and strontium, R is a singly charged organoammonium cation such as the choline cation and E is a framework element such as gallium.Type: GrantFiled: June 23, 2010Date of Patent: January 8, 2013Assignee: UOP LLCInventors: Mark A. Miller, Jaime G. Moscoso, Gregory J. Lewis
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Patent number: 8206683Abstract: A method for synthesizing the all-silica zeolite beta with small crystal size is disclosed. This method comprises the steps of: (a) forming a reaction mixture comprising (1) a source of silicon dioxide (SiO2), (2) a source of fluoride ions (F?), (3) a source of tetraethylammonium cations (TEA+), and (4) water (H2O), at predetermined mole ratios of the source of silicon dioxide, the source of fluoride ions, the source of tetraethylammonium cations, and water; (b) crystallizing the reaction mixture; and (c) recovering the crystalline material formed, wherein the pH of the mixture before crystallization has a value of 6 to 9, and the pH of the mixture after crystallization has a value of 6 to 8. This improved method gives a fast and efficient way of synthesis of all-silica zeolite beta with an average crystal size of less than 5 ?m.Type: GrantFiled: June 11, 2009Date of Patent: June 26, 2012Assignee: Formosan Union Chemical Corp.Inventors: Yu-Yuan Wang, Chien-Hsun Tsai, Chi-Hsing Tsai
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Patent number: 8157907Abstract: A coating composition comprising zeolite nanocrystals, a zeolite precursor solution, and wetting agents in a mixture of solvents is provided. The coating composition can be used to form a transparent layer having a low refractive index on a substrate for antireflection effect.Type: GrantFiled: February 19, 2009Date of Patent: April 17, 2012Assignee: National Central UniversityInventors: Anthony Shiaw-Tseh Chiang, Shiao-Yi Li
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Patent number: 8158104Abstract: A new family of crystalline aluminosilicate zeolites has been synthesized designated UZM-7. These zeolites are represented by the empirical formula. Mmn+Rrp+Al(1-x)ExSiyOz where M is an alkali, alkaline earth, or rare earth metal such as lithium, potassium and barium, R is an organoammonium cation such as the choline or the diethyldimethylammonium cation and E is a framework element such as gallium. These zeolites are characterized by unique x-ray diffraction patterns and compositions and have catalytic properties for carrying out various hydrocarbon conversion processes.Type: GrantFiled: June 29, 2011Date of Patent: April 17, 2012Assignee: UOP LLCInventors: Gregory J. Lewis, Mark A. Miller, Lisa M. Knight
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Patent number: 8153099Abstract: A b-oriented MFI zeolite membrane with variable thickness is provided. The MFI zeolite membrane is composed of zeolite crystals whose b-axes are all uniformly oriented perpendicular to a substrate. Further provided is a method for preparing the MFI zeolite membrane. The method comprises forming zeolite or zeotype molecular sieve seeds with different thicknesses on a substrate and adding the seeded substrate to a gel for the synthesis of an MFI zeolite containing a structure-directing agent to grow zeolite or zeotype molecular sieve crystals thereon. The MFI zeolite membrane overcomes the limitations of prior art zeolite membranes to maximize its applicability.Type: GrantFiled: December 1, 2008Date of Patent: April 10, 2012Assignee: Industry-University Cooperation Foundation Sogang UniversityInventors: Kyung Byung Yoon, Hyun Sung Kim, Pham Cao Thanh Tung
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Patent number: 8105548Abstract: A zeolite membrane production apparatus is provided having a reaction container having a support insertion opening for insertion of tubular supports and which houses a reaction solution for formation of zeolite membranes on the surfaces of the supports, a heating means for heating the reaction solution through the reaction container, and a supporting apparatus provided on the reaction container in a freely detachable manner and which supports a plurality of the supports. The inner wall surface of the reaction container has two mutually parallel flat surfaces, the supporting apparatus has a plurality of supporting sections that anchor one end of each of the plurality of supports, and the plurality of supporting sections are provided in the supporting apparatus such that when the supporting apparatus is set in the reaction container, each of the plurality of supports is disposed between the two flat surfaces and parallel to the two flat surfaces.Type: GrantFiled: June 6, 2006Date of Patent: January 31, 2012Assignee: Mitsubishi Chemical CorporationInventor: Soushi Inoue
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Patent number: 8048403Abstract: This invention relates to a new family of crystalline aluminosilicate compositions designated the UZM-26 family. These include the species UZM-26P, UZM-26PX, UZM-26 and UZM-26X, which have unique structures. UZM-26P is an as synthesized layered composition, while UZM-26 is a calcined form of UZM-26P which has a three-dimensional structure. UZM-26PX is an ion-exchanged form of UZM-26P while UZM-26X is a calcined form of UZM-26PX which has a three-dimensional structure.Type: GrantFiled: December 16, 2008Date of Patent: November 1, 2011Assignee: UOP LLCInventors: Mark A. Miller, Gregory J. Lewis
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Publication number: 20110243837Abstract: A method for making a mesoporous or combined mesoporous/microporous inorganic oxide includes reacting a source of inorganic oxide with a complexing agent at a complexation temperature to provide a complex; decomposing the complex to provide a porous material precursor having an inorganic oxide framework containing at least some organic pore-forming agent; and removing the organic pore forming agent from the inorganic oxide framework by solvent extraction and/or calcination.Type: ApplicationFiled: June 15, 2011Publication date: October 6, 2011Applicant: LUMMUS TECHNOLOGY INC.Inventors: Zhiping Shan, Xintao Gao, Chuen Y. Yeh, Philip J. Angevine, Martin Kraus
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Patent number: 7956204Abstract: A process for oxidation of hydrocarbon, comprising contacting said hydrocarbon with hydrogen peroxide in the presence of a catalytically effective amount of crystalline, titanosilicate zeolite TS-1 catalyst for a time and at a temperature effective to oxidize said hydrocarbon, wherein the catalyst is in the form of binderless, shaped particles comprising titanosilicate, TS-1 and titanosilicate TS-1 precursors and having a defined cross sectional diameter. Also, a process for epoxidation of olefins using crystalline, titanosilicate zeolite TS-1 catalyst. Also a process for oxidation of hydrocarbon using crystalline, titanosilicate TS-1 catalyst, wherein the catalyst is in the form of binderless, shaped particles having a crystallite size of less than 0.2 micron and a defined cross sectional diameter.Type: GrantFiled: February 19, 2008Date of Patent: June 7, 2011Assignee: Chevron U.S.A. Inc.Inventor: Stephen J. Miller
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Patent number: 7901664Abstract: In a method of synthesizing an aluminophosphate or metalloaluminophosphate molecular sieve, a synthesis mixture is provided comprising water, a source of aluminum, a source of phosphorus, optionally a source of a metal other than aluminum, a tertiary amine, and an alkylating agent capable of reacting with said tertiary amine to form a quaternary ammonium compound capable of directing the synthesis of said molecular sieve. The synthesis mixture is maintained under conditions sufficient to cause the alkylating agent to react with the tertiary amine to produce the quaternary ammonium compound and to induce crystallization of the molecular sieve.Type: GrantFiled: March 31, 2008Date of Patent: March 8, 2011Assignee: ExxonMobil Chemical Patents Inc.Inventors: Guang Cao, Mobae Afeworki, Matu J. Shah, Machteld Maria Mertens
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Patent number: 7902102Abstract: Zeolite material of the pentasil type has an alkali metal and alkaline earth metal content of not more than 100 ppm and a molar ratio of Si to Al of from 250 to 1500, at least 90% of the primary particles of the zeolite material being spherical and 95% by weight of the spherical primary particles having a diameter of less than or equal to 1 ?m.Type: GrantFiled: December 2, 2004Date of Patent: March 8, 2011Assignee: BASF SEInventors: Marco Bosch, Ulrich Müller, Matthias Frauenkron
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Patent number: 7837977Abstract: A method is disclosed for preparing crystalline titanosilicate zeolite TS-1 from a reaction mixture containing only sufficient water to produce zeolite TS-1. In one embodiment, the reaction mixture is self-supporting and may be shaped if desired. In the method, the reaction mixture is heated at crystallization conditions and in the absence of an added external liquid phase, so that excess liquid need not be removed from the crystallized product.Type: GrantFiled: September 13, 2005Date of Patent: November 23, 2010Assignee: Chevron U.S.A. Inc.Inventor: Stephen J. Miller
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Patent number: 7807122Abstract: A process for manufacturing a metalloaluminophosphate molecular sieve, the process comprising the steps of: (a) combining at least one silicon source, at least one metal source, at least one structure-directing-agent (R), at least one phosphorus source, and at least one aluminum source to form a mixture having a molar composition according to formula: (n)Si:Al2:(m)P:(x)R:(y)H2O:(z)M wherein n is in the range of from about 0.005 to about 0.6, m is in the range of from about 1.2 to about 2.4, x is in the range of from about 0.5 to about 2, y is in the range of from about 10 to about 60, and z is in the range of from about 0.001 to 1; and (b) submitting the mixture to crystallization conditions to form the metalloaluminophosphate molecular sieve, wherein the metalloaluminophosphate molecular sieve has an X-ray diffraction pattern having a FWHM greater than 0.10 degree (2?) and an AEI/CHA framework type ratio of from about 0/100 to about 40/60 as determined by DIFFaX analysis.Type: GrantFiled: October 27, 2006Date of Patent: October 5, 2010Assignee: ExxonMobil Chemical Patents Inc.Inventors: Machteld Maria Mertens, Karl G. Strohmaier
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Patent number: 7767192Abstract: A molecular sieve comprising crystals or agglomerates of average diameter 100 nanometers or less, which molecular sieve has a crystal or agglomerate size distribution such that the variance in the longest dimension is less than 15% of the average longest dimension, and which is capable of forming a collodial suspension, may be prepared by producing a boiling aqueous synthesis mixture of a silica source and an organic structure directing agent in the form a hydroxide in an amount sufficient to cause substantially complete dissolution of the silica source, and crystallizing the solution at 120° C. or less. The crystal size may be controlled by selection of an appropriate crystallization temperature.Type: GrantFiled: June 3, 1996Date of Patent: August 3, 2010Assignee: Exxonmobil Chemical Patents Inc.Inventor: Johannes Petrus Verduijn
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Patent number: 7744850Abstract: A new family of crystalline aluminosilicate zeolites has been synthesized. These zeolites are represented by the empirical formula. Mmn+Rr+Al(1-x)ExSiyOz where M is an alkali, alkaline earth, or rare earth metal such as lithium and strontium, R is a singly charged organoammonium cation such as the choline cation and E is a framework element such as gallium. These zeolites are similar to ZSM-18 but are characterized by unique x-ray diffraction patterns and compositions and have catalytic properties for carrying out various hydrocarbon conversion processes.Type: GrantFiled: August 3, 2006Date of Patent: June 29, 2010Assignee: UOP LLCInventors: Mark A. Miller, Jaime G. Moscoso, Gregory J. Lewis
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Publication number: 20100119442Abstract: The present invention relates to a process for preparing at least one sheet silicate comprising Ga and/or Zn, and based thereon, a framework silicate, preferably of the RRO structure type, to the sheet silicate and framework silicate themselves and to the uses of the silicates, especially of the framework silicate, preferably as catalysts.Type: ApplicationFiled: April 3, 2008Publication date: May 13, 2010Applicants: BASF SE, RUB GES FUER INN UND TECH DER RUHR-UNI BOCHUM MBHInventors: Ulrich Mueller, Natalia Trukhan, Hermann Gies, Bart Tijsebaert, Csaba Varszegi, Dirk De Vos
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Patent number: 7713513Abstract: A family of crystalline aluminosilicate zeolites designated UZM-8HS and derived from UZM-8 have been synthesized. The aluminum content of the UZM-8HS is lower than that of the starting UZM-8 thus changing its ion exchange capacity and acidity. These UZM-8HS are represented by the empirical formula: M1an+Al(1?x)ExSiy?Oz? and are prepared by treatments such as acid extraction and AFS treatments.Type: GrantFiled: January 27, 2006Date of Patent: May 11, 2010Assignee: UOP LLCInventors: Deng-Yang Jan, Jaime G. Moscoso, Susan C. Koster, Lisa M. Knight, Gregory J. Lewis, Mark A. Miller, R. Lyle Patton, Stephen T. Wilson
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Patent number: 7625478Abstract: Blends of ZSM-48 catalysts are used for hydroprocessing of hydrocarbon feedstocks. The blend of ZSM-48 catalysts includes at least a portion of ZSM-48 crystals having a SiO2:Al2O3 ratio of 110 or less that are free of non-ZSM-48 seed crystals and have a desirable morphology.Type: GrantFiled: December 12, 2006Date of Patent: December 1, 2009Assignee: ExxonMobil Research and Engineering CompanyInventors: Wenyih F. Lai, Terry E. Helton, Dominick N. Mazzone
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Publication number: 20090291046Abstract: A b-oriented MFI zeolite membrane with variable thickness is provided. The MFI zeolite membrane is composed of zeolite crystals whose b-axes are all uniformly oriented perpendicular to a substrate. Further provided is a method for preparing the MFI zeolite membrane. The method comprises forming zeolite or zeotype molecular sieve seeds with different thicknesses on a substrate and adding the seeded substrate to a gel for the synthesis of an MFI zeolite containing a structure-directing agent to grow zeolite or zeotype molecular sieve crystals thereon. The MFI zeolite membrane overcomes the limitations of prior art zeolite membranes to maximize its applicability.Type: ApplicationFiled: December 1, 2008Publication date: November 26, 2009Inventors: Kyung Byung Yoon, Hyun Sung Kim, Pham Cao Thanh Tung
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Patent number: 7608554Abstract: There are provided methods for producing a zeolite layered composite, methods for producing a zeolite shaped body and methods for producing a zeolite layered intermediate body. In one aspect, there is provided a method for producing a zeolite layered composite, comprising layering a template-containing zeolite membrane having a composition the same as or similar to that of a zeolite shaped body of a completely crystallized zeolite composed of tetrapropylammonium ion (TPA) and silica sol in a mixing ratio (TPA/SiO2) of 0.015 to 0.08 by mole and containing a template therein on the zeolite shaped body, and simultaneously removing the template from the zeolite membrane and the zeolite shaped body by calcining the resulting layered product to obtain a zeolite layered composite comprising the zeolite shaped body and the zeolite membrane layered thereon.Type: GrantFiled: September 14, 2006Date of Patent: October 27, 2009Assignee: NGK Insulators, Ltd.Inventors: Toshihiro Tomita, Shinji Nakamura
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Patent number: 7604794Abstract: The present invention relates to an active and selective zeolite catalyst having MTT structure that is useful in skeletal isomerisation of light olefins. The method for the manufacture of the zeolite catalyst having MTT structure comprises the steps of a) preparing of a gel mixture capable of forming crystalline material, and the mixture comprising sources of alkali or alkaline earth metal (M), of an oxide of a trivalent element (X), of an oxide of a tetravalent element (Y), water and a directing agent (R), and the mixture having a composition, in terms of molar ratios, within the given ranges; b) maintaining the mixture under sufficient conditions, including a temperature of from about 100° C. to about 250° C., under dynamic mode of stirring until crystals of the material are formed, recovering the material; and c) removing the directing agent (R) partly or totally with a calcination procedure.Type: GrantFiled: March 9, 2004Date of Patent: October 20, 2009Assignee: Neste Oil OyjInventors: Marja Tiitta, Elina Harlin, Jaana Makkonen, Narendra Kumar, Dmitry Yu Murzin, Tapio Salmi
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Patent number: 7553477Abstract: The invention relates to a material which, once calcined and in the anhydrous state has general formula x (M1/n XO2):z ZO2:y GeO2:(1?y) SiO2, wherein x has a value of less than 0.2, preferably less than 0.15 and can equal zero; z has a value of between 0 and 0.1, preferably between 0 and 0.05; y has a value of between 0 and 1, preferably between 0 and 0.75; M represents one or more +n charged inorganic cations; X represents one or more +3 oxidation state chemical elements (Al, B, Ga, Fe); and Z represents one or more +4 oxidation state cations different from silicon and germanium, preferably Ti or Sn. Said material can be used as a component of catalysts in acid catalysis processes or as a metal or oxide support in separation and absorption/adsorption processes.Type: GrantFiled: September 8, 2006Date of Patent: June 30, 2009Assignees: Consejo Superior De Investigaciones Cientificas, Universidad Politecnica De ValenciaInventors: Avelino Corma Canós, María José Sabater Picot, Fernando Rey García, Susana Valencia Valencia
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Patent number: 7534416Abstract: An antireflective transparent zeolite hardcoat and fabrication method thereof. The transparent zeolite hardcoat comprises a zeolite nanostructure made of zeolite nanocrystals vertically stacked into a porous structure on a substrate, wherein the porosity increases with structure height thereby providing a smooth refractive index transition. The hardcoat is deposited from a solution comprising the reaction products of a mixture via a two-stage thermal condensation process, wherein the mixture comprises a silica source, water and a zeolite structure directing agent.Type: GrantFiled: April 16, 2008Date of Patent: May 19, 2009Assignees: Industrial Technology Research Institute, National Central UniversityInventors: Anthony Shiaw-Tseh Chiang, Shih-Ming Chen, Young-Jen Lee
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Patent number: 7449168Abstract: This invention relates to a process for making a germanium-zeolite without using fluoride compounds. The zeolite is preferably a MFI-type structure, most preferably a ZSM-5 MFI zeolite. The germanium-zeolite is synthesized essentially in the absence of fluoride compounds from an aqueous gel containing a silica source, a germanium source, an aluminum source and a structure directing agent in the presence of an acid which does not contain fluorine, such as sulfuric acid, acetic acid, nitric acid, phosphoric acid hydrochloric acid or formic acid.Type: GrantFiled: December 27, 2004Date of Patent: November 11, 2008Assignee: Saudi Basic Industries CorporationInventors: Gopalakrishnan G. Juttu, Alla Konstantin Khanmamedova, Scott F. Mitchell
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Patent number: 7384622Abstract: A zeolite suspension contains MEL-type zeolite nanocrystals as a principal component. A method for the production of MEL-type zeolite nanocrystals includes the steps of aging a synthesized solution comprising TEOS, TBAOH, water and alcohol and subjecting the aged solution to hydrothermal crystallization treatment at a predetermined temperature. A method for the production of a zeolite suspension includes the steps of aging a synthesized solution comprising TEOS, TBAOH, water and alcohol, subjecting the aged solution to hydrothermal crystallization treatment to produce MEL-type zeolite nanocrystals and mixing a composition having a surfactant dissolved in at least one organic solvent or a mixed solvent of alcohol-based organic solvents, amide-based organic solvents and ketone-based organic solvents with a zeolite nano-crystal suspension containing the MEL-type zeolite nanocrystals to produce a zeolite suspension.Type: GrantFiled: August 29, 2005Date of Patent: June 10, 2008Assignee: National Institute of Advanced Industrial Science and TechnologyInventors: Nobuhiro Hata, Guoqing Guan, Takenobu Yoshino, Syozo Takada
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Patent number: 7344696Abstract: The invention relates to a porous crystalline material (ITQ-24), the preparation method thereof and the use of same in the catalytic conversion of organic compounds. More specifically, the invention relates to a synthetic porous crystalline material which is characterised in that it is formed by tetrahedrally coordinated atoms which are interconnected by means of oxygens. Said material, which comprises a unit cell containing 56 tetrahedrally coordinated atoms, is known as ITQ-24. Moreover, in the calcined anhydrous state, the material has chemical formula nM1/pXO2: YO2, wherein: X is at least one trivalent element, Y is at least one tetravalent element, n is between 0 and 0.2 and M is at least one charge compensation cation in oxidation state p.Type: GrantFiled: August 9, 2005Date of Patent: March 18, 2008Assignees: Consejo Superior de Investigaciones Cientificas, Universidad Politecnica de ValenciaInventors: Avelino Corma Canós, Rafael Castañeda Sánchez, Vicente Fornés Seguí, Fernando Rey García
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Patent number: 7344694Abstract: A series of crystalline alumino-silicate zeolites identified as UZM-12 have been synthesized. These UZM-12 compositions have the ERI topology, a Si/Al>5.5 and can be prepared as nanocrystallites having an average particle size of about 15 to about 50 nanometers and a spheroidal morphology. The UZM-12 composition can be treated to remove at least a fraction of the framework aluminum atoms thereby providing zeolites with a Si/Al>5.75 and identified as UZM-12HS. Both the UZM-12 and UZM-12HS can catalyze various hydrocarbon conversion processes.Type: GrantFiled: October 6, 2004Date of Patent: March 18, 2008Assignee: UOP LLCInventors: Mark A. Miller, Gregory J. Lewis, Jana L. Gisselquist, Jaime G. Moscoso, R. Lyle Patton
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Patent number: 7341707Abstract: The invention concerns a method for production of microporous crystalline metalloaluminium phosphates (ELAPO) based adsorbents or catalysts by in-situ crystallisation of ELAPO inside a formed body. First the formed body containing aluminium phosphate (AIPO) and binder is prepared, thereafter the organic structure directing agent, EL source and water are added and finally ELAPO is crystallised in-situ at elevated temperature and pressure, while keeping the shape and size of the formed body.Type: GrantFiled: May 23, 2003Date of Patent: March 11, 2008Assignee: Polymers Holding ASInventors: Terje Fuglerud, Arne Gidløv Grønvold, Rune Wendelbo, Åse Slagtern, Ivar Martin Dahl
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Patent number: 7341706Abstract: The invention concerns a simple and cheap method for production of microporous crystalline metalloaluminiumphosphates (ELAPO) for use as adsorbent or catalyst by wholly or partially filling the pores of particles containing aluminum phosphate (AIPO) with an aqueous mixture containing an active source of metal and an organic structure directing agent and perform crystallization at elevated temperature under autogenous pressure to form crystals of ELAPO.Type: GrantFiled: November 6, 2002Date of Patent: March 11, 2008Assignee: Polymers Holding ASInventors: Terje Fuglerud, Arne Gidløv Grønvold, Eddy Walther Hansen, Ivar Martin Dahl, Åse Slagtern, Rune Wendelbo
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Patent number: 7267812Abstract: A crystalline inorganic porous material having two different types of pores which are macropores having a diameter in the micrometer range and micropores having a diameter in the angstrom range, at least part of the skeleton thereof having a zeolite structure. The crystalline inorganic porous material of the present invention has macropores and micropores and enables the effective transport of a substance by the macropores, thereby improving the effectiveness of the micropores of zeolite. Since a molded product can be obtained without using a binder, the selectivity of a reaction of interest can be improved in an acidic catalytic reaction or precision separation in adsorption/separation becomes possible.Type: GrantFiled: August 29, 2003Date of Patent: September 11, 2007Assignees: Tokuyama CoporationInventors: Ryoji Takahashi, Satoshi Sato, Akiyuki Yachi
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Patent number: 7094389Abstract: A crystalline material substantially free of framework phosphorus and comprising a CHA framework type molecular sieve with stacking faults or at least one intergrown phase of a CHA framework type molecular sieve and an AEI framework type molecular sieve, wherein said material, in its calcined, anhydrous form, has a composition involving the molar relationship: (n)X2O3:YO2, wherein X is a trivalent element; Y is a tetravalent element; and n is from 0 to about 0.5. The material exhibits activity and selectivity in the conversion of methanol to lower olefins, especially ethylene and propylene.Type: GrantFiled: December 20, 2004Date of Patent: August 22, 2006Assignee: ExxonMobil Chemical Patents Inc.Inventors: Guang Cao, Machteld M. Mertens, Karl G. Strohmaier, Richard B. Hall, Thomas Herman Colle, Mobae Afeworki, Antonie J. Bons, Wilfried J. Mortier, Chris Kliewer, Hailian Li, Anil S. Guram, Robert J. Saxton, Mark T. Muraoka, Jeffrey C. Yoder
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Patent number: 7074383Abstract: A process is described for the preparation of zeolitic catalysts in the form of microspheres, comprising zeolite and oligomeric silica, characterized by a high mechanical resistance. The process consists in subjecting to rapid drying the suspension, to which tetra-alkylorthosilicate is optionally added, resulting from the synthesis of zeolite by hydrothermal treatment at autogenous pressure of the reagent mixture containing tetra-alkylammoniumhydroxide as templating agent, and subjecting the product resulting from the drying to calcination.Type: GrantFiled: April 18, 2005Date of Patent: July 11, 2006Assignee: Enichem S.p.A.Inventors: Angela Carati, Giuseppe Bellussi, Maria Angela Mantegazza, Guido Petrini
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Patent number: 7029650Abstract: This invention relates to a process for making a germanium-zeolite. The zeolite is preferably a MFI-type structure, most preferably a ZSM-5 MFI zeolite. The germanium-zeolite is synthesized from an aqueous gel containing a silica source, a germanium source, an aluminum source and a structure directing agent in the presence of an acid to control the pH of the gel in the range of 6.5 to 13.5, preferably 7.5 to 11, to maximize the amount of germanium incorporated into the zeolite framework. Optionally, a sodium compound may be introduced into the reaction mixture gel either before or after the addition of the acid, preferably before.Type: GrantFiled: December 27, 2004Date of Patent: April 18, 2006Assignee: Saudi Basic Industries CorporationInventors: Gopalakrishnan G. Juttu, Alla Konstantin Khanmamedova, Scott F. Mitchell