Abstract: A process for recovering a metal chloride or mixed metal chloride from a solid waste material comprising recoverable metal containing constituents produced by lead, copper or zinc smelting and refining processes, said process comprising the steps of: (i) heating the solid waste material; (ii) treating the heated material of step (i) with a gaseous chloride to form a gaseous metal chloride containing product; and (iii) treating the gaseous metal chloride containing product of step (ii) to recover the metal chloride or mixed metal chloride. The metal chloride may be further treated to extract the metal itself.

Abstract: A mineral processing facility is provided that includes a cogen plant to provide electrical energy and waste heat to the facility and an electrochemical acid generation plant to generate, from a salt, a mineral acid for use in recovering valuable metals.

Abstract: Isotopes of either germanium or silicon are separated by a chemical exchange reaction. Preferably the compound is a hydro halide or halide composition and the donor can be a wide variety of compounds such as a lower molecular weight alcohol.

Abstract: A method for extracting metals from metal-containing materials, especially waste, by pyrohydrolysis. The metal-containing materials which contain at least one or more of the metals from the group consisting of Zn, Cd, Pb, Hg, Cu, Sn (as Sn(0) and Sn(II)), As, Sb, Au, Ag and Bi, are made to react at 700-1100.degree. C., advantageously 800-900.degree. C., with a gas composition which at least comprises 25-45% by volume of water vapor, 0-12% by volume of carbon dioxide, 2-20% by volume of hydrogen chloride, 0-15% by volume of carbon monoxide, the remainder being nitrogen and possibly oxygen. The metals from the above-mentioned group are extracted in the form of volatile metal chlorides.

Abstract: Transparent conductive coatings excellent in transparency are provided on substrates such as glass, plastics, etc. by the use of conductive coating materials obtained by maintaining aqueous solutions of hydrolyzable tin containing or indium containing compounds at pH of 8-12, and gradually hydrolyzing said compounds in the solutions to form sols containing colloidal particles, followed by drying and calcining.

Abstract: A process is provided for hydrometallurgical processing of steel plant dusts containing cadmium, lead, zinc, and iron values, along with impurities such as chloride and fluoride salts of sodium, potassium, magnesium, etc. The first step in the process involves leaching the dust in a mixed sulfate-chloride medium that dissolves most of the zinc and cadmium. Any iron and aluminum dissolved in this step is precipitated by oxidation and neutralization. Zinc is recovered from the resulting solution by solvent extraction which provides a raffinate which is recycled to the leaching step with a bleed stream also provided for recovery of cadmium and removal of other impurities from the circuit. The lead sulfate residue from the leaching step is leached with caustic soda, and zinc dust is used to cement the lead out from the caustic solution, which then joins the main solution for zinc recovery.

Abstract: Chlorine is reacted with excess tin in liquid tin(IV) chloride at 20.degree. to 90.degree. C., 30 to 300 dm.sup.3 (S.T.P.)h.sup.-1 of chlorine being passed in per dm.sup.3 of tin(IV) chloride present in the reaction chamber and 0.08 to 0.3 dm.sup.3 h.sup.-1 of tin(IV) chloride being recycled with cooling per 1 dm.sup.3 (S.T.P.)h.sup.-1 of chlorine passed in. An excess of tin of at least 4 times the weight of chlorine passed in per hour is maintained. An amount of tin(IV) chloride is taken out of the cycle such that the level of the tin(IV) chloride in the reaction chamber remains approximately constant. The tin(IV) chloride taken off is brought into contact at 60.degree. to 110.degree. C. for an average residence time of 1 to 7 hours with tin in liquid tin(IV) chloride, thereafter filtered and, if appropriate, treated with absorbing agents. Pure, ready-for-use tin(IV) chloride is obtained continuously without a purification by distillation in a simple, readily cleanable apparatus made of a cheap material.

Abstract: A process for treating zinc plant leach residues for the recovery of the lead, silver, and tin values contained therein is disclosed. The process includes the treatment of the zinc plant residue with concentrated sulphuric acid followed by water leaching and other hydrometallurgical steps to separately recover the lead, silver and tin.