Pressurizing Or Agitating During Reaction Patents (Class 423/93)
  • Patent number: 11180826
    Abstract: The present invention provides an additive for tin stripping, comprising 0.1 to 20 wt % of copper corrosion inhibitor and 0.1 to 20 wt % of nickel corrosion inhibitor; wherein said weight percentage is based on the total weight of said additive. The present additive can be used with nitric acid conventionally used for metal-stripping for not only reducing the usage of nitric acid but also improving the efficiency of tin stripping. The present invention also provides a method for Tin recycle and a reaction tank for metal recycle. Both of them are favorable for satisfying the needs of metal recycle (especially, tin recycle) in the field.
    Type: Grant
    Filed: March 6, 2019
    Date of Patent: November 23, 2021
    Assignee: UWIN NANOTECH CO., LTD.
    Inventor: Ching-Hsiang Hsu
  • Patent number: 10608288
    Abstract: The present invention relates to safety methods and mechanisms for treating electrolyte solutions in batteries, specifically metal-air batteries. Systems and methods of the invention protect the battery, protect the battery operator and protect the environment from potential material hazards. This invention provides materials for arresting a potentially hazardous electrolyte solution by forming solid or gel porous polymer structures. The polymer porous structures consume or confine the electrolyte solution thus preventing its hazardous potential.
    Type: Grant
    Filed: April 13, 2015
    Date of Patent: March 31, 2020
    Assignee: PHINERGY LTD.
    Inventors: Aviv Tzidon, Dekel Tzidon, Avraham Yadgar, Ilya Yakupov
  • Patent number: 8980203
    Abstract: The present invention relates to the recovery of high purity litharge from spent lead acid battery paste at a low temperature which does not produce sulfur dioxide. In the process lead acetate or other lead salt is produced which is converted to high purity litharge by precipitation with a base.
    Type: Grant
    Filed: May 24, 2013
    Date of Patent: March 17, 2015
    Assignee: Retriev Technologies Incorporated
    Inventors: W. Novis Smith, Steven Kinsbursky
  • Patent number: 8562923
    Abstract: The present invention relates to the recovery of high purity litharge from spent lead acid battery paste at a low temperature which does not produce sulfur dioxide. In the process lead acetate is produced which is converted to pure litharge.
    Type: Grant
    Filed: October 25, 2012
    Date of Patent: October 22, 2013
    Assignee: Toxco, Inc.
    Inventors: W. Novis Smith, Steven A. Kinsbursky
  • Patent number: 8470636
    Abstract: The present invention relates to aqueous processes to make metal chalcogenide nanoparticles that are useful precursors to copper zinc tin sulfide/selenide and copper tin sulfide/selenide. In addition, this invention provides processes for preparing crystalline particles from the metal chalcogenide nanoparticles, as well as processes for preparing inks from both the metal chalcogenide nanoparticles and the crystalline particles.
    Type: Grant
    Filed: November 22, 2010
    Date of Patent: June 25, 2013
    Assignee: E I du Pont de Nemours and Company
    Inventors: Daniela Rodica Radu, Lynda Kaye Johnson, Cheng-Yu Lai, Meijun Lu, Irina Malajovich
  • Patent number: 8211389
    Abstract: Uses for a composition comprising a polymer derived from at least two monomers: acrylic-x and an alkylamine, wherein said polymer is modified to contain a functional group capable of scavenging one or more compositions containing one or more metals are disclosed. These polymers have many uses in various mediums, including wastewater systems.
    Type: Grant
    Filed: April 6, 2010
    Date of Patent: July 3, 2012
    Assignee: Nalco Company
    Inventors: Paul J. Zinn, Jitendra T. Shah, William J. Andrews
  • Patent number: 8147780
    Abstract: Wet process of low environmental impact recovers the lead content of an electrode slime and/or of lead minerals in the valuable form of high purity-lead carbonates that are convertible to highly pure lead oxide by heat treatment in oven at relatively low temperature, perfectly suited for making active electrode pastes of new batteries or other uses.
    Type: Grant
    Filed: January 15, 2008
    Date of Patent: April 3, 2012
    Assignee: Millbrook Lead Recycling Technologies Limited
    Inventor: Federica Martini
  • Patent number: 7998440
    Abstract: An outstandingly low environmental impact wet process recovers the lead content of an electrode slime and/or of lead minerals in the valuable form of high purity lead oxide or compound convertible to highly pure lead oxide by heat treatment in oven at relatively low temperature, perfectly suited for making active electrode pastes of new batteries or other uses.
    Type: Grant
    Filed: November 3, 2009
    Date of Patent: August 16, 2011
    Assignee: Millbrook Lead Recycling Technologies Limited
    Inventor: Federica Martini
  • Patent number: 7785561
    Abstract: A process for producing high purity lead oxide from impure lead compounds particularly from waste lead battery paste which includes an oxidation-reduction step. The process results in a reduction of impure lead compounds to the +2 valence state and metal particle contaminants are oxidized to the +2 state.
    Type: Grant
    Filed: February 18, 2009
    Date of Patent: August 31, 2010
    Assignees: Toxco. Inc, Kinsbursky Brothers, Inc.
    Inventors: W. Novis Smith, Steven A. Kinsbursky
  • Patent number: 6793908
    Abstract: A solution method for preparing indium-tin oxide (ITO) powders is provided. Indium compounds and tin compounds are dissolved in water respectively to form two solution bodies. Some proper additives are added into the solution bodies to form metal hydroxyl compounds with determined composition. After water washing and filtration, proper additives are added into the solution to peptize the solution. During the peptization process, hydrolysis and condensation reactions occurs between different metal hydroxyl compounds. Solvent of the solution is then removed to form high quality nanometer grade ITO powders.
    Type: Grant
    Filed: May 9, 2002
    Date of Patent: September 21, 2004
    Assignee: Cheng Loong Corporation
    Inventors: Hsin Chung Lu, Chio Hao Hsu, I Chiao Lin, Chien Lung Weng
  • Patent number: 6442977
    Abstract: A sol-gel process for fabricating bulk, germanium-doped silica bodies useful for a variety of applications, including core rods, substrate tubes, immediate overcladding, pumped fiber lasers, and planar waveguides, is provided. The process involves the steps of providing a dispersion of silica particles in an aqueous quaternary ammonium germanate solution—typically tetramethylammonium germanate, gelling the dispersion to provide a gel body, and drying, heat treating, and sintering the body to provide the germanium-doped silica glass.
    Type: Grant
    Filed: June 20, 2000
    Date of Patent: September 3, 2002
    Assignee: Fitel USA Corp.
    Inventors: Suhas Bhandarkar, Frank J McNally, Thomas M Putvinski
  • Patent number: 6423393
    Abstract: A suede-like stitchbonded fabric is disclosed. The stitchbonded fabric includes a nonwoven substrate. A first yarn is stitchbonded into the substrate in a manner that forms loops at the surface of the substrate. A second yarn is then also stitchbonded into the substrate in order to secure the loops to the fabric. Thereafter, the fabric is abraded for substantially breaking all of the loops at the surface of the fabric.
    Type: Grant
    Filed: August 18, 2000
    Date of Patent: July 23, 2002
    Assignee: Tietex International, Ltd.
    Inventor: Martin Wildeman
  • Patent number: 6319482
    Abstract: The present invention relates to a process for treating fly ash/APC residues chlorides, sulphates, earth alkali metals selected from the group consisting of calcium, potassium, and sodium, and heavy metals selected from the group consisting of lead, which residues are obtained from air pollution control processes that utilize dry/semi-dry line injection, such that said residues may be disposed of as non-hazardous materials. The process comprises the sequential steps of: (a) washing and agitating the fly ash/APC residue (20) with water (50) to form a residue slurry containing solubilized lead salts and calcium chloride; (b) filtering (42) the residue slurry to remove a filtrate (46) having a pH of higher than about 11.8 and containing the solubilized lead salts and calcium chloride; and (c) recovering a first calcium enriched filter cake (44).
    Type: Grant
    Filed: November 18, 1998
    Date of Patent: November 20, 2001
    Assignee: Apex Residue Recovery Inc.
    Inventors: Steven E. Sawell, Stephen A. Hetherington
  • Patent number: 6120750
    Abstract: A lead-containing complex oxide containing substantially no alkali metal is produced under hydrothermal conditions in the absence of alkali metals using a Pb source which serves also as a mineralizer for precipitating the lead-containing complex oxide. Preferred Pb source acting as the mineralizer is lead oxide.
    Type: Grant
    Filed: March 22, 1999
    Date of Patent: September 19, 2000
    Assignees: Honda Giken Kobyo Kabushiki Kaisa, Shinichi Hirano
    Inventors: Shinichi Hirano, Yusuke Hirabayashi, Toshinobu Yogo, Wataru Sakamoto
  • Patent number: 6054104
    Abstract: A continuous system recovers germanium (Ge) from a chemical vapor deposit. A chemical vapor deposit scrubber scrubs a chemical vapor deposit to form a chemical vapor deposit scrubber solution. An equalization and neutralization mixer adds a caustic soda to the chemical vapor deposit scrubber solution to form an equalization and neutralization mixer solution having a pH above 12.0 to maintain the solubility of silicon oxide (SiO.sub.2) and hypochlorite (ClO.sup.-). A hypochlorite reduction mixer adds a peroxide to the equalization and neutralization solution to form a hypochlorite reduction solution to reduce hypochlorites. A precipitant and neutralization mixer adds a metal cation such as Epsom Salts (MgSO.sub.4) and a caustic soda, such as sodium hydroxide (NAOH), to the hypochlorite reduction solution to form a precipitant and neutralization solution to precipitate magnesium germanate (MgGeO.sub.3) and magnesium metasilicate (MgSiO.sub.3).
    Type: Grant
    Filed: January 14, 1998
    Date of Patent: April 25, 2000
    Assignee: Alcatel
    Inventors: David W. Lankewicz, Bruce D. Reilly
  • Patent number: 5518707
    Abstract: This invention relates to novel crystalline molecular sieves having the pharmacosiderite structure and having germanium and M metals as framework elements. Optionally, titanium and silicon can also be a framework element. The M metals can be any metal which has octahedral coordination and has a valence of +2, +3, +4 or +5. Illustrative of these M metals are niobium, tin, antimony, aluminum, gallium and tantalum.
    Type: Grant
    Filed: March 27, 1995
    Date of Patent: May 21, 1996
    Assignee: UOP
    Inventors: Robert L. Bedard, Lisa M. King
  • Patent number: 5342590
    Abstract: The invention provides a method of making alkali metal stannates which comprises heating a mixture of tin oxide with a solution of alkali under pressure. Preferably a stoichiometric excess of alkali over the tin is used.
    Type: Grant
    Filed: February 24, 1992
    Date of Patent: August 30, 1994
    Assignee: Alcan International Limited
    Inventor: David J. Randall
  • Patent number: 4127989
    Abstract: A process for separating and recovering metal values and salts from brine, such as brine produced from a subterranean geothermal reservoir, in which the brine is pressurized to above the bubble point pressure and thereafter a precipitating agent, such as a soluble sulfide, is added to the brine to form insoluble metal sulfide precipitates. The precipitates are separated from the brine while maintaining the brine at a pressure above the bubble point pressure, and the hot brine is subsequently utilized to derive energy therefrom. The brine effluent after such energy derivation and the precipitate are optionally processed to primarily recover saleable salts and metal values, respectively.
    Type: Grant
    Filed: January 25, 1978
    Date of Patent: December 5, 1978
    Assignee: Union Oil Company of California
    Inventor: Grant A. Mickelson
  • Patent number: 4057616
    Abstract: Metal hydroxides such as Fe(OH).sub.2, Fe(OH).sub.3 and Sn(OH).sub.2 are prepared in the form of spherical particles of uniform and controlled size suitable for tagging with a radioactive element such as technetium-99m. Aqueous suspensions of such tagged particles are useful in scintigraphy as lung scanning agents.
    Type: Grant
    Filed: November 7, 1975
    Date of Patent: November 8, 1977
    Assignee: Mallinckrodt, Inc.
    Inventor: Robert G. Wolfangel
  • Patent number: 4019950
    Abstract: In a hydrothermal process for manufacturing crystals of metal carbonates, including single crystals of lead carbonate of the cerussite crystalline form, the nutrient material consists of a carbonate or basic carbonate of the said metal, the solvent medium consists of a 0.5 to 5.0 molar aqueous solution of an alkali metal bicarbonate, and the heating is carried out in an autoclave under controlled temperature conditions such that the exterior of the autoclave wall adjacent to the nutrient and the solvent medium in the vicinity thereof is maintained at 200.degree. C to 400.degree. C, and that the exterior of the autoclave wall adjacent to the region of the solvent medium remote from the nutrient is maintained at 170.degree. C to 315.degree. C and at a temperature from 5.degree. C to 150.degree.
    Type: Grant
    Filed: November 7, 1975
    Date of Patent: April 26, 1977
    Assignee: The General Electric Company Limited
    Inventors: Derek Francis Croxall, Robert Christopher Kell, Robert Lambert
  • Patent number: 3970745
    Abstract: A method for producing hydrogen from water in which hydrogen is produced by reducing water using metallic germanium and the by-product, germanium monoxide, is reduced with a reducing agent to metallic germanium which is recycled and reused. In this case, it is necessary to regulate the oxidation of metallic germanium so as to stop at the germanium monoxide stage since the reduction of germanium dioxide to metallic germanium is difficult. Therefore, water vapor is advantageously reduced by using not less than 1 mole of metallic germanium to 1 mole of water vapor or it is indirectly reduced with an intermediate of carbon dioxide.
    Type: Grant
    Filed: March 24, 1975
    Date of Patent: July 20, 1976
    Assignee: Director-General of the Agency of Industrial Science and Technology
    Inventor: Norio Takeuchi
  • Patent number: 3959453
    Abstract: Single crystals of .beta.-PbO.sub.2 are formed when an intermediate oxide of lead represented by the generic formula, PbO.sub.x wherein x denotes a value falling in the range of 1.4 to 1.7, is heated in an aqueous alkali hydroxide solution under a pressure exerted by use of oxygen or an oxygen-containing gas. The single crystals are in the shape of slender rods, have a black color and have a metallic gloss.
    Type: Grant
    Filed: November 26, 1974
    Date of Patent: May 25, 1976
    Assignee: Agency of Industrial Science & Technology
    Inventors: Eiichi Torikai, Yoji Kawami
  • Patent number: 3933973
    Abstract: A method is disclosed for leaching finely divided lead sulphide bearing material to convert contained lead values to soluble lead acetate with concurrent conversion of sulphur values associated with the lead sulphide to an elemental state. The method involves forming a slurry consisting of the material dispersed in an aqueous medium containing free acetate ions and having a pH below 5.1. The slurry is reacted at a temperature of 60.degree. to 120.degree.C. with a free oxygen-bearing gas under a partial pressure of oxygen of 20 to 60 p.s.i. in order to convert lead sulphide to soluble lead acetate with concurrent production of insoluble elemental sulphur.
    Type: Grant
    Filed: October 16, 1973
    Date of Patent: January 20, 1976
    Assignee: Sherritt Gordon Mines Limited
    Inventors: David John Ivor Evans, Ian M. Masters