Abstract: Useful catalyst compositions are produced by treating substituted molecular sieves with reactive titanium compounds such as titanium tetrahalides, preferably in the vapor phase at elevated temperatures. The molecular sieve starting materials contain tellurium, boron or germanium oxides in addition to silicon and titanium oxides. Olefins are efficiently transformed to epoxides using these catalyst compositions and an oxidizing agent such as hydrogen peroxide or an organic hydroperoxide.
Abstract: The present invention relates to a zeolite catalyst, a process for using the catalyst for conversion of hydrocarbons, especially naphtha and LPG feedstock, and a process for preparing the catalyst.
Type:
Grant
Filed:
April 7, 1998
Date of Patent:
September 14, 1999
Assignee:
Intevep, S.A.
Inventors:
Jorge Tejada, Juan Lujano, Yilda Romero
Abstract: The present invention relates to a zeolite catalyst, a process for using the catalyst for conversion of hydrocarbons, especially naphtha and LPG feedstock, and a process for preparing the catalyst.
Type:
Grant
Filed:
January 5, 1996
Date of Patent:
September 1, 1998
Assignee:
Intevep, S.A.
Inventors:
Jorge Tejada, Juan Lujano, Yilda Romero
Abstract: Crystalline zeolites are prepared using a small quantity of an organic templating compound and a larger quantity of an amine component containing at least one amine having from one to eight carbon atoms, ammonium hydroxide, or mixtures thereof.
Abstract: Silica-bound extruded zeolites may be converted into binder-free zeolite aggregates by aging the zeolite in an aqueous ionic solution which contains hydroxy ions such that the initial molar ratio of OH.sup.- :SiO.sub.2 is up to 1.2 and which causes the silica binder to be converted substantially to zeolite of the type initially bound. Such extrudates have excellent mechanical strength and show advantageous properties such as adsorption comparable with non-extruded zeolite powder.
Abstract: The present invention relates to a zeolite catalyst, a process for using the catalyst for conversion of hydrocarbons, especially naphtha and LPG feedstock, and a process for preparing the catalyst.
Type:
Grant
Filed:
December 23, 1994
Date of Patent:
May 13, 1997
Assignee:
Intevep, S.A.
Inventors:
Jorge Tejada, Juan Lujano, Yilda Romero
Abstract: A method is disclosed for preparing a crystalline aluminosilicate zeolite from a reaction mixture containing only sufficient water so that the reaction mixture may be shaped if desired. In the method, the reaction mixture is heated at crystallization conditions and in the absence of an external liquid phase, so that excess liquid need not be removed from the crystallized material prior to drying the crystals.
Abstract: Silica-bound extruded zeolites may be converted into binder-free zeolite aggregates by aging the zeolite in an aqueous ionic solution which contains hydroxy ions such that the initial molar ratio of OH-:SiO.sub.2 is up to 1.2 and which causes the silica binder to be converted substantially to zeolite of the type initially bound. Such extrudates have excellent mechanical strength and show advantageous properties such as adsorption comparable with non-extruded zeolite powder.
Abstract: Molecular sieves, particularly zeolites, are prepared using heterobridged aza-polycyclic templates. The templates may be prepared in a series of reaction steps which include a Diels-Alder reaction between a diene and a dienophile.
Type:
Grant
Filed:
February 8, 1994
Date of Patent:
June 20, 1995
Assignee:
Chevron Research and Technology Company, A Division of Chevron U.S.A. Inc.