Zirconium Compound Containing Patents (Class 424/66)
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Patent number: 5102656Abstract: The invention is directed to a creamy, heterogeneous anhydrous antiperspirant product and to a method for making it. The product of the invention comprises essentially a volatile silicone product as a carrier, a gelling agent and a physiologically acceptable antiperspirant agent. Optional ingredients which can be included comprise surfactants, emollients, fillers, fragrances, coloring agents and the like. The method of the invention comprises mixing and heating the ingredients to a temperature above the melting point of the gelling agent, then cooling while mixing thoroughly to a temperature below the normal solidification point of the product.Type: GrantFiled: November 6, 1985Date of Patent: April 7, 1992Assignee: The Mennen CompanyInventor: Radhakrishna B. Kasat
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Patent number: 5098698Abstract: A process for preparing a submicron antiperspirant adduct. The process begins by dissolving a mixture of an aluminum-containing salt and a steric stabilizer in a solvent. The antiperspirant salt is then precipitated into the steric stabilizer. The resulting adduct of submicron size can be dispersed into a cosmetic carrier or otherwise processed.Type: GrantFiled: December 10, 1990Date of Patent: March 24, 1992Assignee: The Gillette CompanyInventors: Antoine Kawam, Shu-Sen Lee, Harvey A. Lazar
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Patent number: 5082652Abstract: Disclosed is an aerosol deodorant composition which includes an aerosol propellant, a volatile low-viscosity fluid, an oil absorbent particulate material, a silicone polymer and a deodorancy agent, such as at least one of a fragrance and a bactericide. The addition of the oil absorbent particulate material prevents dusting of liquid particles, and the addition of the silicone polymer prevents dusting by the oil absorbent particulate material. Also disclosed is an aerosol deodorant package including the aerosol deodorant composition and an aerosol delivery system having a valve which has orifices for passing the aerosol deodorant composition out of the package, the orifices having diameters such that the average delivery rate of the aerosol deodorant composition from the package is at most 0.44 gm/sec.Type: GrantFiled: August 22, 1989Date of Patent: January 21, 1992Inventors: Larry Mayfield, Thomas Russo, Kenneth Klausner, Charles Shalotsky
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Patent number: 5069897Abstract: Antipersipirant cream compositions, comprising:(a) from about 5% to about 60% of a volatile silicone oil(b) from about 5% to about 60% of a non-volatile emollient having a viscosity of at least about 2 cs at 25.degree. C.;(c) from about 2% to about 10% of a particulate thickening material; and(d) from about 15% to about 45% of a particulate antiperspirant active material;wherein the compositions have penetration force values of from about 250 grams to about 800 grams. These compositions preferably contain a cosmetic powder material, at a level of from about 0.5% to about 20%. This invention also provides methods for making these compositions.Type: GrantFiled: August 10, 1989Date of Patent: December 3, 1991Assignee: The Proctor & Gamble CompanyInventor: Thomas V. Orr
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Patent number: 5019375Abstract: Antiperspirant cream compositions, which exhibit reduced residue on the skin and excellent cosmetics and aesthetics, as well as good composition stability over time, are claimed. These compositions, which may be formulated to have relatively high viscosities, include a volatile silicone material, a particulate antiperspirant active, a clay thickening agent, an activator for the clay thickening agent, and a non-volatile paraffinic hydrocarbon fluid, such as mineral oil or branched chain C.sub.16 -C.sub.68 hydrocarbons. A method of treating or preventing perspiration in humans using these compositions is also claimed.Type: GrantFiled: March 14, 1989Date of Patent: May 28, 1991Assignee: The Procter & Gamble CompanyInventors: Paul R. Tanner, Randolph G. Nunn, Jr., John P. Luebbe
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Patent number: 5008103Abstract: Novel polysiloxane polymers are provided having general formula(CH.sub.3).sub.3 SI--O--(CH.sub.3).sub.2 SiO].sub.x [(CH.sub.3)R.sup.1 O].sub.y Si(CH.sub.3).sub.3wherein R.sup.1 is a polyoxyalkylene radical of the formula ##STR1## x has an average value from about 5 to 400, y has an average value of at least 1 and n has an average value from at least 1 to 200. Water-in-oil emulsions comprising the novel polysiloxane polymers are also described.Type: GrantFiled: December 29, 1988Date of Patent: April 16, 1991Assignee: General Electric CompanyInventors: William J. Raleigh, Raymond J. Thimineur, Anthony A. Zotto
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Patent number: 4985238Abstract: Suspensoid antiperspirant stick compositions, which provide the user with excellent antiperspirant efficacy, reduced residue upon application to the skin, reduced residue on the stick after dry-down, and excellent cosmetics and aesthetics, are disclosed. These compositions are substantially free of water and comprise a volatile silicone material, a particulate antiperspirant active, a low melting point wax, and a non-volatile paraffinic hydrocarbon fluid selected from mineral oils and branched chain C.sub.16 -C.sub.68 hydrocarbons. The method of preventing and controlling perspiration wetness using these compositions is also disclosed.Type: GrantFiled: March 14, 1989Date of Patent: January 15, 1991Assignee: The Procter & Gamble CompanyInventors: Paul R. Tanner, Randolph G. Nunn, Jr., John P. Luebbe
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Patent number: 4980156Abstract: An improved dry-feeling antiperspirant composition is provided which comprises an aqueous solution of an astringent emulsified in a volatile silicon fluid, the emulsion being stabilized by a combination of a long-chain alkyl modified polysiloxane-polyoxyalkylene copolymer and an organic surfactant having an HLB value from 8 to 18.Type: GrantFiled: December 12, 1988Date of Patent: December 25, 1990Assignee: General Electric CompanyInventors: William J. Raleigh, Raymond J. Thimineur, Anthony A. Zotto
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Patent number: 4954333Abstract: The invention relates to compositions for transparent or translucent antiperspirants comprising a polyol, the reaction product of an antiperspirant salt and a silane and an optional gelling agent, but no or substantially no water. When gelled, the composition is suitable for use as a stick antiperspirant. The invention also relates to the process by which compositions of the invention are prepared.Type: GrantFiled: January 31, 1989Date of Patent: September 4, 1990Assignee: Dow Corning CorporationInventor: Andrew H. Ward
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Patent number: 4948578Abstract: An antiperspirant composition is disclosed in the form of a transparent stick. The composition comprises a mixture of aluminum chlorohydrate, nonionic surfactant, liquid oil, and water, the latter being present in an amount from 20 to 50%. Preferably, the liquid oil is a combination of volatile silicone and emollient oil.Type: GrantFiled: May 12, 1989Date of Patent: August 14, 1990Assignee: Lever Brothers CompanyInventors: Allan R. Burger, Phillip E. Figdore, Samuel Q. S. Lin, Michael Massaro
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Patent number: 4944938Abstract: A clear quick drying highly active antiperspirant and deodorant gel free of monohydric alcohols comprising an antiperspirant, a volatile water soluble emollient, volatile siloxanes a, a volatile water insoluble emollient, a coupling agent and a solubilizer.Type: GrantFiled: December 16, 1988Date of Patent: July 31, 1990Assignee: Colgate-Palmolive CompanyInventor: A. Chimpirama Potini
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Patent number: 4944937Abstract: Cosmetic stick compositions comprising one or more liquid base materials, one or more solidfying agents for the liquid base materials, and from about 2% to about 30% (by total composition volume) of chemically inert particulates of at least 10 microns in diameter and having a density less than about 0.60 g/ml. The liquid base materials are typically present at a level of from about 10% to about 90% (by total composition weight), and the solidifying agent is typically present at a level of from about 3% to about 70% (by total composition weight). These cosmetic sticks may be of a gel stick type or a wax stick type, depending upon the particular liquid base materials and solidifying agents used. Preferred cosmetic sticks contain a safe and effective amount of an active material having, for example, antiperspirant or deodorant activity.Type: GrantFiled: December 19, 1984Date of Patent: July 31, 1990Assignee: The Procter & Gamble CompanyInventor: Patrick C. McCall
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Patent number: 4937069Abstract: A substantially anhydrous semi-solid antiperspirant composition comprising (1) antiperspirant powder (2) thickening/suspending agent containing fumed silica (3) thickening/solid emollient (4) nonvolatile liquid emollient/plasticizer and (5) volatile emollient.Type: GrantFiled: November 14, 1988Date of Patent: June 26, 1990Assignee: Bristol-Myers Squibb CompanyInventor: Chung T. Shin
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Patent number: 4933177Abstract: A cosmetic composition for the treatment of the hair and skin comprises at least 5 weight percent of pulverized particles of at least one plant. The particles have a granulometry lower than 125 microns. The compositions also includes a cohesion agent in an amount to maintain the homogeneity of the composition.Type: GrantFiled: June 15, 1988Date of Patent: June 12, 1990Assignee: Societe Anonyme dite: L'OREALInventors: Jean-Francois Grollier, Josiane Allec, Chantal Fourcadier, Georges Rosenbaum, Patrick Darmenton
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Patent number: 4921701Abstract: An antimicrobial water soluble substrate is formed by combining a silane, generically a quaternary ammonium salt form of a silane, with a water soluble powder selected from the group consisting of antiperspirant salts, starches, clays, and sugars. When the substrate is dissolved in water, the silane is released for redeposition.Type: GrantFiled: August 11, 1988Date of Patent: May 1, 1990Assignee: Dow Corning CorporationInventor: Lynne M. Blehm Blank
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Patent number: 4919934Abstract: Disclosed are wax based cosmetic stick compositions comprising: from about 10% to about 50% of a wax type solidifying agent; and from about 5% to about 90% of a polyalphaolefin. These compositions preferably comprise from about 1.0% to about 40% of an active component, such as a sunscreen agent, analgesic, moisturizing and antiperspirant or a deodorant active.Type: GrantFiled: March 2, 1989Date of Patent: April 24, 1990Assignee: Richardson-Vicks Inc.Inventors: George E. Deckner, Rupali A. Kulkarni
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Patent number: 4900534Abstract: The disclosure concerns a process for the manufacture of aluminium zirconium halohydrate having an aluminium:zirconium molar ratio of from 2:1 to 7:1 and having a metal:chlorine molar ratio of from 0.9:1 to 2.1:1. Metallic aluminium is dissolved in an aqueous starting solution comprising an oxyhalide, hydroxyhalide or carbonate of zirconium and an aluminium halide or basic aluminium halide, which solution is heated at about 50.degree. C. to 105.degree. C. The solution of the final aluminium zirconium halohydrate has a concentration of metal of 0.5 to 2.3 moles/kg and a size exclusion chromatogram of which the Band III proporition is at least 20%.Type: GrantFiled: August 5, 1987Date of Patent: February 13, 1990Assignee: Lever Brothers CompanyInventor: Peter W. Inward
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Patent number: 4900542Abstract: A batch process and continuous/semicontinuous processes for the manufacture of uniform, clear, microcrystalline emulsion compositions of gel-like consistency are disclosed.Type: GrantFiled: June 15, 1987Date of Patent: February 13, 1990Assignee: Carter-Wallace Inc.Inventors: Umberto V. Parrotta, Jr., Gianluigi Soldati, Frederick P. Sisbarro
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Patent number: 4889711Abstract: A novel composition for antiperspirant aerosol comprises an antiperspirant substance, a silicone-treated clay mineral and an oil substance.When the composition is sprayed over the skin, sweat can readily evaporate immediately after spraying and even after perspiration. Thus, the composition ensures a very good feel in use.Type: GrantFiled: August 8, 1988Date of Patent: December 26, 1989Assignee: Kao CorporationInventors: Masanobu Kai, Etsuko Chiku
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Patent number: 4871525Abstract: Aluminum zirconium hydroxy halide glycinate complex and a method of its preparation is disclosed having an empirical formula:Al.sub.2 (OH).sub.6-y.sup.X.sub.y ZrO(OH).sub.x Cl.sub.2-x /Neutral Amino Acidwherein x has a numerical value of 0 to 1.5, y has a numerical value of 0.7 to 3.0, X is chlorine, bromine or iodine, and whose polymer distribution as characterized by a size exclusion chromatograph is:(a) a peak height ratio of peak 4 to peak 3 of 0.5 to 1.8:1, and(b) peaks (1+2) contain less than 4% of the polymer distribution by weight.Type: GrantFiled: August 3, 1987Date of Patent: October 3, 1989Assignee: Westwood Chemical CorporationInventors: Rocco Giovanniello, Stephen M. Howe
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Patent number: 4863721Abstract: Polar solvent-free antiperspirant compositions comprising particulate cellulose ether polymers, preferably hydroxyethyl-cellulose. These antiperspirant compositions produce less stinging and burning than compositions not containing particulate cellulose ether polymers when applied to underarm skin following shaving.Type: GrantFiled: May 22, 1987Date of Patent: September 5, 1989Assignee: The Procter & Gamble CompanyInventors: Terri A. Beck, Raymond E. Bolich, Jr.
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Patent number: 4853214Abstract: Antiperspirant cream compositions, comprising:(a) from about 5% to about 60% of a volatile silicone oil(b) from about 0.1% to about 60% of a non-volatile emollient having a viscosity of at least about 10 cs at 25.degree. C.;(c) from about 2% to about 10% of a particulate thickening material; and(d) from about 15% to about 45% of a particulate antiperspirant active material; and(e) from about 0.1% to about 10% of a particulate cellulose ether polymer,wherein the compositions have penetration force values of from about 150 grams to about 800 grams at 25.degree. C. and at 50% relative humidity. These compositions preferably contain a cosmetic powder material, at a level of from about 2% to about 20%. This invention also provides methods for making these compositions.Type: GrantFiled: September 8, 1987Date of Patent: August 1, 1989Assignee: The Procter & Gamble CompanyInventor: Thomas V. Orr
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Patent number: 4851214Abstract: Personal malodors due to the chemical or bacterial action occurring on the skin or hair are inhibited by applying formulations containing N-soya-N-ethyl morpholinium ethosulfate.Type: GrantFiled: September 7, 1988Date of Patent: July 25, 1989Assignee: ICI Americas Inc.Inventors: Peter P. Walters, Ronald I. Davis
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Patent number: 4840789Abstract: Antiperspirant cream compositions, comprising:(a) from about 5% to about 60% of a volatile silicone oil;(b) from about 5% to about 60% of a non-volatile liquid C.sub.12 -C.sub.25 saturated or unsaturated hydrocarbon emollient;(c) from about 2% to about 10% of a particulate thickening material; and(d) from about 15% to about 45% of a particulate antiperspirant active material,wherein the compositions have penetration force values of from about 150 grams to about 800 grams at 25.degree. C. and at 50% relative humidity. These compositions preferably contain a cosmetic powder material, at a level of from about 0.5% to about 20%. This invention also provides methods for making these compositions.Type: GrantFiled: October 16, 1987Date of Patent: June 20, 1989Assignee: The Procter & Gamble CompanyInventors: Thomas V. Orr, Gerard B. Meyer
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Patent number: 4822603Abstract: Antiperspirant stick compositions comprising:(a) from about 35% to about 60% of a volatile silicone oil;(b) from about 1% to about 5% of a non-volatile emollient;(c) from about 2.5% to about 4% of a high melting point wax;(d) from about 10% to about 15% of a low melting point wax;(e) from about 0.2% to about 1.5% of a colloidal silica material;(f) from about 0.5% to about 4% of an inert spherical particulate material which is comprised of essentially spherical particles having a mean diameter of at least about 10 microns;(g) from about 2% to about 9% of a talcum material; and(h) from about 20% to about 33% of a particulate antiperspirant material;wherein the total level of talcum material and antiperspirant material is from about 25% to about 35%.Type: GrantFiled: May 28, 1987Date of Patent: April 18, 1989Assignee: The Procter & Gamble CompanyInventors: Richard D. Farris, John P. Luebbe, Gerald J. Quinlivan
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Patent number: 4822602Abstract: The present invention relates to cosmetic compositions in the form of solid sticks, especially deodorant sticks and antiperspirant sticks. The cosmetic stick compositions of the present invention comprise the essential components: (a) water-soluble active; (b) dimethicone copolyol; (c) volatile silicone oil; (d) propylene glycol; (e) C.sub.2 -C.sub.4 monohydric alcohol; (f) water; (g) solidifying agent; and (h) coupling agent. These compositions have excellent efficacy and cosmetic aesthetics.The present invention also relates to methods for treating or preventing malodor associated with human perspiration, especially underarm odor. The present invention further relates to methods for manufacturing cosmetic stick compositions of the present invention.Type: GrantFiled: April 29, 1987Date of Patent: April 18, 1989Assignee: The Procter & Gamble CompanyInventor: Anthony D. Sabatelli
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Patent number: 4822596Abstract: A personal antiperspirant product contains a moisture-absorbent polymer instead of or in addition to the usual metal salt. The product is applied to the skin in a finely divided form to give a dry, non-sticky deposit for absorbing skin moisture such as perspiration. The polymer is capable of absorbing an amount of moisture at least equal to its own weight after depositing the product onto the skin.Type: GrantFiled: November 6, 1985Date of Patent: April 18, 1989Assignee: Lever Brothers CompanyInventors: Martin Callingham, Dwaipayan Chaudhuri, Kenneth V. Curry, Barry G. Pike, Michael B. Taylor
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Patent number: 4818522Abstract: Antiperspirant formulations are provided in which water-immiscible adjuvants are encapsulated in thick-walled, hollow, substantially spherical particles of antiperspirant active, which is preferably a water-soluble compound or complex of a polyvalent metal or metals. The thick-walled particles resist rupture during normal handling and application of the antiperspirant formulation and provide slow release of the encapsulated adjuvant when the antiperspirant shell dissolves in perspiration. The adjuvant may be a fragrance, an antibacterial, antimicrobial or antifungal agent, a deodorant, or other dermatological preparation. The encapsulation is accomplished by emulsifying the adjuvant in an aqueous solution of the antiperspirant active, and spray drying the material in such a manner as to produce thick-walled, spherical particles with the liquid adjuvant in the hollow centers.Type: GrantFiled: September 14, 1987Date of Patent: April 4, 1989Assignee: Reheis, Inc.Inventors: Rudolph Ferentchak, James F. Kozischek
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Patent number: 4816261Abstract: Disclosed are deodorant gel stick compositions comprising from about 0.1 to about 10.0% of a deodorant active, from about 7% to about 35% of intermediate polarity emollients, from about 2% to about 8% of a benzylidene sorbitol, from about 7% to about 75% of a polar solvent, and from about 5% to about 40% of a coupling agent. These deodorant gel sticks provide very stable deodorant compositions with good efficacy as well as excellent cosmetics which are further characterized by their ease of manufacture.Type: GrantFiled: November 20, 1987Date of Patent: March 28, 1989Assignee: The Procter & Gamble CompanyInventors: John P. Luebbe, Paul R. Tanner, John D. Melanson, Jr.
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Patent number: 4806338Abstract: Antiperspirant aerosol compositions comprising from about 1% to about 40% of a particulate antiperspirant material, from about 0.005% to about 6.0% of a functionalized siloxane and from about 60% to about 95% of an aerosol propellant. Preferably the functionalized siloxane is an amino-functional silicone. Also preferably, the compositions also contain a silicon gum material and a volatile silicone oil.Type: GrantFiled: February 5, 1986Date of Patent: February 21, 1989Assignee: The Procter & Gamble CompanyInventor: Scott E. Smith
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Patent number: 4781917Abstract: Disclosed are antiperspirant gel stick compositions substantially free of unbound water comprising from about 5 to about 50% of a solubilized antiperspirant active, from about 7% to about 35% of intermediate polarity emollients, from about 1% to about 5% of a benzylidene sorbitol, from about 15% to about 75% of a polar solvent, from about 1% to about 20% of a coupling agent and from about 0.5% to about 10% of a bufferieng agent. These antiperspirant gel sticks provide very stable antiperspirant compositions with good efficacy as well as excellent cosmetic anesthetics which are further characterized by their ease of manufacture. Also disclosed is a method for the manufacture of these gel sticks as well as a method for treating or preventing perspiraton and malodor associated with human underarm perspiration.Type: GrantFiled: June 26, 1987Date of Patent: November 1, 1988Assignee: The Proctor & Gamble CompanyInventors: John P. Luebbe, Paul R. Tanner, Richard D. Farris
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Patent number: 4777035Abstract: An antiperspirant composition for roll-on application, which feels dry upon application, is prepared by encapsulating a relatively large amount of water onto a specific kind of a hydrophobic silica, and then suspending the water-loaded silica into an anhydrous liquid vehicle which has a particular antiperspirant material suspended therein.Type: GrantFiled: November 15, 1985Date of Patent: October 11, 1988Assignee: Bristol-Myers CompanyInventor: Chung T. Shin
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Patent number: 4777034Abstract: Composition enabling the degradations and inconveniences of perspiration to be counteracted, said composition comprising at least one anti-absorbant agent and/or an antiseptic agent and/or an anti-sweating agent and/or an antiseptic agent and/or an antimycotic agent and/or an anti-irritant agent and/or an antifungal agent and/or an anti-putrid agent and/or a deodorant and/or a nutrient agent and/ an emollient and/or a softening agent and/or a regenerating agent and/or a cicatrising agent and/or an astringent product and/or a softening agent and/or a moisturizing agent and/or a cleansing agent.Type: GrantFiled: October 29, 1987Date of Patent: October 11, 1988Inventors: Georges R. G. Olivier, Simone A. M. H. Olivier
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Patent number: 4775528Abstract: A composition of zirconyl hydroxy chloride and aluminum chlorhydroxide in stable solid form having improved antiperspirant efficacy when dissolved in water is made by heating a 2-20% by weight aqueous solution containing at least the aluminum chlorhydroxide component of the composition at a temperature of at least 50.degree. C. until the ratio of the height of peak 4 at Kd=0.7 to that of peak 3 at Kd=0.5 as measured by gel permeation chromotography on cross-linked dextran is at least 2:1, then subjecting the solution to rapid drying to solid form.Type: GrantFiled: April 9, 1987Date of Patent: October 4, 1988Assignee: The Gillette CompanyInventors: David T. Callaghan, Alan M. Phipps, Stephen J. Provancal
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Patent number: 4774079Abstract: An antiperspirant composition buffered to a pH in the range of from about 2.5 to about 4.5 having incorporated therein as active ingredients a combination of aluminum chlorohydrate, aluminum chloride and an aluminum zirconium polychlorohydrate complex; an additionally added buffering agent, preferably glycine, may be incorporated in the composition.Type: GrantFiled: September 26, 1985Date of Patent: September 27, 1988Assignee: Bristol-Myers CompanyInventors: Chung T. Shin, Milton S. Slade, Ara Nersesian
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Patent number: 4749569Abstract: A stable extrudable antiperspirant paste composition exhibiting high antiperspirant efficacy in which finely divided solid astringent antiperspirant is dispersed in a limited class of volatile silicone liquid vehicles and stabilized against syneresis by a combination of finely divided silica and a quaternized three-layer clay exfoliated with a polar solvent.Type: GrantFiled: November 28, 1986Date of Patent: June 7, 1988Assignee: The Gillette CompanyInventors: Francis J. Gianino, Philip P. Angelone, Jr.
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Patent number: 4743444Abstract: Cosmetic stick compositions comprising from about 10% to about 97% of a liquid base material, from about 1% to about 10% of a benzylidene sorbitol, and from about 1% to about 15% of a C.sub.14 -C.sub.16 fatty alcohol. Cetyl alcohol is a preferred C.sub.14 -C.sub.16 fatty alcohol. The cosmetic sticks preferably also contain an active material, such as an antiperspirant active or a deodorant active.Type: GrantFiled: February 20, 1986Date of Patent: May 10, 1988Assignee: The Procter & Gamble CompanyInventor: Patrick C. McCall
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Patent number: 4732754Abstract: Improved antiperspirant compositions having an astringent material suspended in a hydrophobic medium, and emulsions of aqueous solutions of astringent materials in a hydrophobic medium, said compositions having added thereto from 1 to 5% by weight of a C.sub.3 to C.sub.8 alkanediol compound.Type: GrantFiled: January 10, 1986Date of Patent: March 22, 1988Assignee: American Cyanamid CompanyInventor: Helga Krevald
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Patent number: 4725430Abstract: A clear or translucent cosmetic stick containing an acidic material and a reactive solvent, using dibenzyl monosorbitol acetal as the gelling agent an N-(2-hydroxyethyl) acetamide as the stabilizing agent. In particular are included antiperspirant sticks with an astringent metal salt and also containing lower aliphatic mono- and dihydric alkanols.Type: GrantFiled: September 13, 1985Date of Patent: February 16, 1988Assignee: American Cyanamid CompanyInventors: Thomas J. Schamper, Martin M. Perl, James D. Warren
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Patent number: 4725432Abstract: Solid stick compositions comprising a long-chain fatty alcohol having from about 8 to about 18 carbon atoms in the chain, volatile silicone and C.sub.20 or longer chain alcohols at levels of from about 1% to about 3% of the total long-chain fatty alcohol present in the compositions. These solid sticks have improved strength and hardness without undue brittleness.Type: GrantFiled: April 23, 1984Date of Patent: February 16, 1988Assignee: The Procter & Gamble CompanyInventor: William G. May
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Patent number: 4725431Abstract: Method for preparing an antiperspirant composition of the water-in-oil emulsion type having improved application and aesthetic properties which comprises emulsyfing the aqueous phase in the oil phase in the presence of about 1 to 3% by weight of at least one C.sub.12 to C.sub.20 saturated fatty acid ester of polyglycerol containing about 2 to 10 repeating glycerol units.Type: GrantFiled: December 26, 1985Date of Patent: February 16, 1988Assignee: American Cyanamid CompanyInventors: Joseph C. Hourihan, Helga Krevald
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Patent number: 4724139Abstract: A highly effective antiperspirant composition being essentially water-insoluble with the exception of the active astringent antiperspirant particles formed as a stick includes from about 5% to about 80% of a volatile isoparaffin liquid carrier, from about 5% to about 60% of one or more water-insoluble waxes and from about 8% to about 60% of an active aluminum or zirconium astringent antiperspirant salt in the form of finely divided particles.Type: GrantFiled: May 8, 1985Date of Patent: February 9, 1988Inventor: Victor Palinczar
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Patent number: 4722835Abstract: A method for producing solid gel antiperspirant sticks at a lower processing temperature, said sticks containing an acidic antiperspirant metal active compound, dibenzyl monosorbitol acetal as the gelling agent and at least one alcohol, a solvent which is an organic compatible, small organic compound of not greater than about five carbon atoms and is a good hydrogen bond donor or acceptor, and a stabilizing compound which is a basic metallic salt, and the gelled antiperspirant sticks formed by the process.Type: GrantFiled: May 27, 1986Date of Patent: February 2, 1988Assignee: American Cyanamid CompanyInventors: Thomas J. Schamper, Zsuzsanna M. Piso
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Patent number: 4722836Abstract: Wax-like antiperspirant composition sticks having uniformly distributed astringent salt suspension throughout the stick composition.Type: GrantFiled: September 27, 1982Date of Patent: February 2, 1988Assignee: American Cyanamid CompanyInventors: Daniel C. Geary, Helga Krevald, Peter P. Walters, Jr.
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Patent number: 4720381Abstract: Clear gel antiperspirant sticks comprising (a) about 37 to 94 percent by weight of a non-reactive alkanol, (b) about 1 to 10 percent of dibenzyl monosorbitol acetal, (c) 0 to 25 percent of an emollient, (d) about 5 to 25 percent of an antiperspirant active compound, and (e) about 0 to 3 percent of a C.sub.12 to C.sub.20 fatty acid.Type: GrantFiled: March 7, 1986Date of Patent: January 19, 1988Assignee: American Cyanamid CompanyInventors: Thomas J. Schamper, Martin M. Perl, James D. Warren
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Patent number: 4719103Abstract: Method for making an antiperspirant composition of the water-in-oil emulsion type having improved application properties and aesthetic appeal which comprises emulsifying the aqueous phase in the oil phase in the presence of from 1 to 3% by weight of a non-ionic surfactant having a resultant HLB value in the range of 6 to 9.Type: GrantFiled: December 23, 1985Date of Patent: January 12, 1988Assignee: American Cyanamid CompanyInventors: Helga Krevald, Joseph C. Hourihan
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Patent number: 4719102Abstract: A method for producing solid gel antiperspirant sticks at a lower processing temperature, said sticks containing an acidic antiperspirant metal active compound, dibenzyl monosorbitol acetal as the gelling agent and at least one alcohol, wherein a novel solvent is added which is an organic compatible, small compound of not greater than about five carbon atoms and is a good hydrogen bond donor or acceptor, and the gelled antiperspirant sticks formed by the process.Type: GrantFiled: April 12, 1985Date of Patent: January 12, 1988Assignee: American Cyanamid CompanyInventors: Munawar H. Randhawa, Thomas J. Schamper
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Patent number: 4704271Abstract: Antiperspirant compositions containing an aqueous solution of an astringent compound as a discontinuous or dispersed phase in a solid matrix of a volatile silicone, a solid alkanol containing at least 12 carbon atoms, a C.sub.4 to C.sub.8 alkylene diol, and a saturated C.sub.12 to C.sub.20 fatty acid ester of at least one polyglycerol emulsifying agent having a resultant HLB value of 6 to 9. The compositions may also contain an alkanoic acid having at least 12 carbon atoms.Type: GrantFiled: December 26, 1985Date of Patent: November 3, 1987Assignee: American Cyanamid CompanyInventors: Joseph C. Hourihan, Helga Krevald
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Patent number: 4695451Abstract: An aerosol antiperspirant composition in the form of a substantially stable water-in-oil emulsion is disclosed which consists of 25% to 50% by weight of a liquefied, normally gaseous propellant and 50% to 75% of a base consisting essentially of, by weight, 4 to 20% of at least one water-soluble, astringent salt having antiperspirant efficacy; 0.5 to 5% of a water-in-oil emulsifier; 10% to 25% of a propellant-soluble emollient-stabilizer agent consisting of a water-insoluble, organic, liquid emollient and a water-insoluble organic liquid having a boiling point in the range of 35.degree. C. to 155.degree. C., the weight ratio of emollient to organic liquid being in the range of 0.8:1 to 3:1, and 55% to 78% of water. In preferred compositions, C.sub.3 -C.sub.4 hydrocarbon propellants are employed.Type: GrantFiled: December 30, 1981Date of Patent: September 22, 1987Assignee: Colgate-Palmolive CompanyInventors: Alan Straw, Stewart Shields
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Patent number: 4690817Abstract: Polyvinyl alcohol polymers having pendant cationic quaternary nitrogen containing groups provide for a film forming moisture barrier in skin conditioning lotions, ointments, cosmetic conditioning treatments and pharmaceutical formulations.Type: GrantFiled: June 21, 1985Date of Patent: September 1, 1987Assignee: ICI Americas Inc.Inventors: Ronald I. Davis, Charalambos J. Phalangas, George R. Titus