Silsesquioxanes Patents (Class 424/70.121)
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Publication number: 20100233114Abstract: The invention relates to compositions containing at least one silicone film forming resin and at least one polysilicone polymer, as well as to methods of applying such compositions to keratin materials.Type: ApplicationFiled: February 4, 2010Publication date: September 16, 2010Applicant: L'Oréal S.A.Inventors: Michael S. DeGeorge, Jonathan Wright, Jeremy Puco
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Patent number: 7744857Abstract: Antiperspirant compositions containing suspended antiperspirant actives in a water-immiscible carrier leave visible deposits on skin or clothing unless the actives are masked. The carrier mixture in compositions herein comprise an alkylsiloxane which is substituted by a group R4 of formula —CH2—C(Ph) (RB)—R5-Ph in which RB represents H or methyl and R5 represents an alkylene group containing 0 to 3 carbons, and in which the proportion of aryl carbon atoms is at least 60% of all carbon atoms in the molecule. Preferably, the substituent comprises diphenylethyl. Optionally, the siloxane can be capped by the residue of a substituted vinyl group other than R4 or an alkyl, cycloalkyl or aralkyl alcohol.Type: GrantFiled: February 10, 2004Date of Patent: June 29, 2010Assignee: Unilever Home & Personal Care USA a division of Conopco, Inc.Inventors: Denise Marie Beachy, Kevin Ronald Franklin
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Patent number: 7704517Abstract: The present invention relates to a topical cosmetic composition that has improved non-oily feel comprising: (a) a hybrid silicone composite powder having a spherical shape with particle diameter ranging from 2 to 10 ?m, of which each particle has a composite structures consisting of two interpenetrating polymer networks of polydimethylsiloxane (PMS) and polymethylsilsesquioxane (PMSQ). These two interpenetrating polymer networks are joined together by physical entanglements instead of chemical bonds; (b) a volatile cosmetic fluid; (c) a silicone fluid with viscosity ranging from 2 to 350 cSt; (d) an oil base consisting of an oil, wax, oil gelling agent or the mixture thereof; (e) a surface active agent; (f) a cosmetic pigment; and (g) an optional aqueous gel containing glycerin, glycols and an aqueous thickening agent. The cosmetic composition provides an improved skin sensory feel and a superior matte finish, and is useful for skin treatment, makeup and personal hygiene products.Type: GrantFiled: March 2, 2004Date of Patent: April 27, 2010Assignee: Grant Industries, Inc.Inventors: James J. Wang, Jin L. Hung, Thomas J. Hrubec, David Granatell
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Publication number: 20090074701Abstract: The invention relates to methods of artificially coloring hair including applying to hair a composition containing at least one silicone film forming resin, at least one polysilicone polymer, and at least one hair colorant.Type: ApplicationFiled: September 14, 2007Publication date: March 19, 2009Applicant: L'OREAL S.A.Inventors: Delphine Allard, David W. Cannell, Michael S. DeGeorge, Jeremy Puco, Jonathan Wright
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Publication number: 20090074702Abstract: The invention relates to methods of preserving artificial color on keratin materials including applying to artificially colored keratin materials a composition containing at least one silicone film forming resin and at least one polysilicone polymer.Type: ApplicationFiled: September 14, 2007Publication date: March 19, 2009Applicant: L'OREAL S.A.Inventors: Delphine Allard, David W. Cannell, Michael S. DeGeorge, Jeremy Puco, Jonathan Wright
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Publication number: 20080305064Abstract: A process of styling hair involving applying onto the hair a composition containing: (a) at least one propylphenylsilsesquioxane resin comprising from about 30 to about 50 mole % of propyl siloxy units, based on the total mole % of siloxy units of the resin, and from about 50 to about 70 mole % of phenyl siloxy units, based on the total mole % of siloxy units of the resin; (b) at least one phenylsilsesquioxane resin; (c) at least one volatile solvent; and (d) optionally, at least one cosmetically-acceptable aromatic solvent.Type: ApplicationFiled: June 2, 2008Publication date: December 11, 2008Applicant: L'OREALInventors: Hy Si Bui, Jaimie Mecca, Carmen Castillo-Bucci
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Patent number: 7462729Abstract: The present invention is drawn to a process for providing emolliency to the skin using a series so called “silicone spider esters”. These esters are derived from poly-hydroxy functional compounds sequentially reacted with ethylene oxide or propylene oxide, followed by the reaction of the alkoxylate with fatty acid. The resulting products are called silicone spider esters because they resemble the spider, wherein appendages are alkoxylated esters. The restrictions this orientation imposes on rotation allows for the preparation of polar esters that have little or no water solubility, and provide both moisturization to the skin and emolliency by reducing transepidermal water loss.Type: GrantFiled: June 13, 2005Date of Patent: December 9, 2008Assignee: SurfaTech CorporationInventors: Kevin A. O'Lenick, Anthony J. O'Lenick, Jr.
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Publication number: 20070190015Abstract: Disclosed herein a cosmetic composition for treating keratin fibers, for instance, human keratin fibers such as the hair, comprising, in a cosmetically acceptable medium, at least one cationic poly(vinyllactam) polymer, at least one fatty alcohol, and at least one polyol with a molecular weight of greater than 80.Type: ApplicationFiled: December 22, 2006Publication date: August 16, 2007Inventor: Cecile Bebot
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Patent number: 7235230Abstract: The present invention relates to leave-on compositions for personal care comprising trimethylsilylalkylsilsesquioxanes, particularly trimethylsilyl-n-octylsilsesquioxanes (Caprylyl Trimethicones). Said trimethylsilylalkylsilsesquioxanes are especially useful in formulating emulsions.Type: GrantFiled: October 24, 2001Date of Patent: June 26, 2007Assignee: Clariant Finance (BVI) LimitedInventors: Gary E. LeGrow, W. Leonard Terry, Jr., Ray Figueroa, Peter Klug, Waltraud Simsch, Angelika Turowski
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Publication number: 20060057096Abstract: Disclosed herein is a cosmetic composition, in particular a hair composition, comprising, in a cosmetically acceptable medium, at least one quaternary ammonium cationic surfactant, at least one aminated silicone, at least one fatty alcohol, and at least one diol comprising 6 carbon atoms.Type: ApplicationFiled: September 7, 2005Publication date: March 16, 2006Inventors: Pascale Lazzeri, Sandrine Decoster
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Publication number: 20060008441Abstract: Compositions comprising at least one polymethylsilsesquioxane film former and at least one film former different from said at least one polymethylsilsesquioxane film former, wherein said at least one polymethylsilsesquioxane film former is present in an amount effective to provide at least one property chosen from long wear and transfer resistance.Type: ApplicationFiled: September 16, 2005Publication date: January 12, 2006Inventors: Mohamed Kanji, Carl Orr, Valerie Robert
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Publication number: 20040202637Abstract: A hair treatment agent, a shampoo or a hair coloring agent comprising a silylated peptide-silane compound copolymer composition which is produced by the following process and has viscosity in a range from 500 to 20000 mPa.s in 70% of solid content concentration of said copolymer composition at 20° C.Type: ApplicationFiled: April 8, 2004Publication date: October 14, 2004Inventors: Masato Yoshioka, Nobuyuki Goto, Sakiko Uchida, Sueko Daikai, Takashi Adachi, Mikuo Tachibana
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Publication number: 20040180032Abstract: A cosmetic composition comprising at least one silicone polyamide solvated or dispersed in a cosmetically acceptable carrier.Type: ApplicationFiled: March 15, 2003Publication date: September 16, 2004Inventors: Jean Marie Manelski, Neil D. Scancarella, Julio Gans Russ, Anjali Abhimanyu Patil, Joseph Frank Calello, Jodi Lorraine Kubida, Kaya Teray McIntosh
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Patent number: 6703027Abstract: An external composition containing a silicone-modified polysaccharide compound and a low viscosity silicone oil and/or powder component, which is useful for covering rough surfaces on a skin.Type: GrantFiled: December 28, 1999Date of Patent: March 9, 2004Assignee: Shiseido Company, Ltd.Inventors: Mari Kurosawa, Hiroshi Fukui
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Patent number: 6703008Abstract: Disclosed are aerosol hair spray compositions which comprise a first and a second silicone-grafted copolymer, wherein the copolymers exhibit a dichotomous viscosity behavior which results in superior hold and excellent hair feel benefits, and a method of styling hair comprising applying to the hair an effective amount of the above composition. The aerosol hair spray compositions comprise: (A) from about 0.Type: GrantFiled: March 5, 1999Date of Patent: March 9, 2004Assignee: The Procter & Gamble CompanyInventors: Jose Antonio Carballada, Thomas Allen Hutchins
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Patent number: 6635264Abstract: The use of an organosiloxane bearing at least one ultraviolet-absorbing group in, and for the preparation of, a cosmetic or dermatological composition as an agent for protecting the color of artificially colored keratin fibres against the effects of UV radiation, in particular solar radiation.Type: GrantFiled: October 30, 2000Date of Patent: October 21, 2003Assignee: L'Oreal S.A.Inventors: Hervé Richard, Alain Lagrange, Claude Dubief, Damarys Braida-Valerio
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Patent number: 6610280Abstract: A hair treatment composition containing a silicone component comprising droplets of silicone blend, the silicone blend comprising (i) from 50 to 95% by weight of the silicone component of a first silicone having a viscosity of at least 100,000 mm2/sec at 25° C., and (ii) from 5 to 50% by weight of the silicone component of a second silicone which is functionalised.Type: GrantFiled: April 5, 2002Date of Patent: August 26, 2003Assignee: Unilever Home & Personal Care USA, division of Conopco, Inc.Inventors: Nicholas Ainger, Peter Fairley
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Publication number: 20030086888Abstract: The present invention relates to leave-on compositions for personal care comprising trimethylsilylalkylsilsesquioxanes, particularly trimethylsilyl-n-octylsilsesquioxanes (Caprylyl Trimethicones). Said trimethylsilylalkylsilsesquioxanes are especially useful in formulating emulsions.Type: ApplicationFiled: October 24, 2001Publication date: May 8, 2003Applicant: Clariant international, LtdInventors: Gary E. LeGrow, W. Leonard Terry, Ray Figueroa, Peter Klug, Waltraud Simsch, Angelika Turowski
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Publication number: 20030077240Abstract: The invention relates to the use of phenylsilsesquioxane liquids of the general compositionType: ApplicationFiled: October 24, 2001Publication date: April 24, 2003Applicant: Clariant International, Ltd.Inventors: Gary E. LeGrow, W. Leonard Terry, Ray Figueroa
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Patent number: 6503494Abstract: The present invention relates to a cosmetic or dermatological composition for treating keratin substances, in particular human hair, comprising a grafted silicone polymer with a non-silicone organic skeleton with at least one monomer containing at least one polysiloxane and at least one crosslinked or non-crosslinked thickening polymer or copolymer of methacrylamide or a methacrylamide derivative.Type: GrantFiled: April 4, 2000Date of Patent: January 7, 2003Assignee: L'Oreal S.A.Inventors: Daniele Cauwet-Martin, Claude Dubief, Christine Dupuis
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Patent number: 6482399Abstract: A method of imparting improved conditioning properties to hair comprising treating the hair with a conditioning composition comprising a silicone compound having at least one quaternary ammonium moiety and ethoxylated monoalkyl quat.Type: GrantFiled: January 17, 2001Date of Patent: November 19, 2002Assignee: Unilever Home & Personal Care USA, division of Conopco, Inc.Inventor: Daniel Raymond Pyles
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Patent number: 6440429Abstract: An emulsified, water-in-oil type composition comprises the following components (A), (B), (C) and (D): (A) an oil phase, (B) a high molecular compound having orientation to oil-water interfaces, (C) a lower alcohol, and (D) water. A skin cosmetic preparation containing the emulsified, water-in-oil type composition is also disclosed.Type: GrantFiled: September 6, 1996Date of Patent: August 27, 2002Assignee: Kao CorporationInventors: Makoto Torizuka, Hirohisa Suzuki, Kana Fujiwara, Takashi Oda, Nobushige Tanaka, Katsuhiko Rindo
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Patent number: 6423303Abstract: Water-in-oil emulsions are disclosed that comprise (a) water; (b) from about 10 to 65% by weight of an oil; and (c) an emulsification system comprising a polysiloxane polyalkyl polyether copolymer and a phthalic anhydride derivative, substantially permanently maintaining the water and oil as an emulsion, the emulsification system and the emulsification system being substantially free from aluminum and zirconium salts, the emulsion being at a pH of from about 5 to 10.Type: GrantFiled: March 23, 2000Date of Patent: July 23, 2002Assignee: Stepan CompanyInventors: Irma Ryklin, Branko Sajic
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Patent number: 6375940Abstract: The use of an organosiloxane bearing at least one ultraviolet-absorbing group in, and for the preparation of,.a cosmetic or dermatological composition as an agent for protecting the colour of artificially coloured keratin fibres against the effects of UV radiation, in particular solar radiation.Type: GrantFiled: October 15, 1997Date of Patent: April 23, 2002Assignee: L'OrealInventors: Hervé Richard, Alain Lagrange, Claude Dubief, Damarys Braida-Valerio
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Patent number: 6368584Abstract: The invention relates to novel detergent cosmetic compositions comprising, in a cosmetically acceptable medium, at least one anionic surfactant chosen from 2-hydroxyalkyl ether carboxylic acid and salts thereof and at least one silicone chosen from: (i) volatile or non-volatile, linear, branched or cyclic and crosslinked or non-crosslinked polyalkylsiloxanes, polyarylsiloxanes or polyalkylarylsiloxanes; (ii) polysiloxanes comprising, in their general structure, one or more organofunctional groups chosen from: a) substituted or unsubstituted aminated groups; b) (per)fluorinated groups; c) thiol groups; d) carboxylate groups; e) hydroxylated groups; f) alkoxylated groups; g) acyloxyalkyl groups; h) amphoteric groups; i) bisulphite groups; j) hydroxyacylamino groups; k) carboxylic acid groups; l) sulphonic groups; m) sulphate or thiosulphate groups; (iii) linear polysiloxane(A)-polyoxyalkylene(B) block copolymers of (A—B)n type with n>3; (iv) grafted silicone polymers composed of a main chain not compriType: GrantFiled: February 15, 2000Date of Patent: April 9, 2002Assignee: L'Oreal S.A.Inventors: Nathalie Garnier, Danièle Cauwet-Martin, Serge Restle
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Publication number: 20020031488Abstract: Compositions comprising at least one polymethylsilsesquioxane film former and at least one film former different from said at least one polymethylsilsesquioxane film former, wherein said at least one polymethylsilsesquioxane film former is present in an amount effective to provide at least one property chosen from long wear and transfer resistance.Type: ApplicationFiled: June 19, 2001Publication date: March 14, 2002Inventors: Mohamed Kanji, Carl Orr, Valerie Robert
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Publication number: 20020015681Abstract: Disclosed are aerosol hair spray compositions which comprise a first and a second silicone-grafted copolymer, wherein the copolymers exhibit a dichotomous viscosity behavior which results in superior hold and excellent hair feel benefits, and a method of styling hair comprising applying to the hair an effective amount of the above composition. The aerosol hair spray compositions comprise: (A) from about 0.Type: ApplicationFiled: March 5, 1999Publication date: February 7, 2002Inventors: JOSE ANTONIO CARBALLADA, THOMAS ALLEN HUTCHINS
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Patent number: 6290942Abstract: The invention provides an emulsion comprising an organopolysiloxane of the formula: R1xR2yR3zSiO(4−x−y−z)/2 wherein R1 is a monovalent C1-20 hydrocarbon group, R2 is as defined for R1 or OX wherein X is hydrogen or a monovalent C1-6 hydrocarbon group, R3 is —R4COOH wherein R4 is a divalent C1-20 hydrocarbon group, 0<x≦2, 0≦y<0.05, 0 <z≦0.15, and 1.8<x+y+z<2.2, the organopolysiloxane containing at least one carboxyl group in the molecule and having a degree of polymerization of 200-20,000. The carboxyl-bearing silicone emulsion is formulated in a hair-care product, which when applied to hair, remains adsorbed on both sound hair and damaged hair, and is effective for imparting smoothness, suppleness, antistatic property, style-holding ability, and a pleasant finish.Type: GrantFiled: May 27, 1999Date of Patent: September 18, 2001Assignee: Shin-Etsu Chemical Co., Ltd.Inventors: Morizo Nakazato, Hisashi Aoki
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Patent number: 6287546Abstract: This invention relates to improved stabilized shampoo compositions containing siloxysilicate materials commonly referred to as MQ resins, wherein the stabilizers are selected from (i) long chain fatty alcohols with greater than 14 carbons; (ii) acrylates/steareth-20 methacrylate copolymer; acrylates copolymer; and acrylates/C10-30 alkyl acrylate crosspolymer; and (iii) selected N,N-disubstituted phthalamic acids and their ammonium salts.Type: GrantFiled: September 27, 1999Date of Patent: September 11, 2001Assignee: Colgate-Palmolive CompanyInventors: Charles Reich, Janine Chupa, Cheryl L. Kozubal, Dean Terng-Tzong Su
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Patent number: 6280748Abstract: A cosmetic raw material possesses excellent compounding stability in cosmetic products. The cosmetic raw material is produced from a vinyl-type polymer having a carbosiloxane dendrimer structure in its side molecular chain. The cosmetic raw material is composed of the vinyl-type polymer having a carbosiloxane dendrimer structure in its side molecular chain, and a solution or a dispersion of a liquid such as a silicone oil, organic oil, alcohol, or water.Type: GrantFiled: May 26, 1999Date of Patent: August 28, 2001Assignee: Dow Corning Toray Silicone, Ltd.Inventors: Yoshitsugu Morita, Haruhiko Furukawa, Takayuki Aso, Tadashi Hamachi
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Patent number: 6180117Abstract: Microemulsion compositions comprising MQ resins and microemulsifiable amino silicone fluids or gums and a surfactant having a high phase inversion temperature, the microemulsions formed therewith, a means for preparing said microemulsions, and personal care products comprising said microemulsions.Type: GrantFiled: February 10, 1995Date of Patent: January 30, 2001Assignee: General Electric CompanyInventors: Marianne D. Berthiaume, James H. Merrifield, Donna A. Riccio