Fuel Cell Part Patents (Class 427/115)
  • Patent number: 10014531
    Abstract: In some examples, a fuel cell comprising a cathode, a cathode conductor layer adjacent the cathode, an electrolyte separated from the cathode conductor layer by the cathode, and an anode separated from the cathode by the electrolyte, wherein the anode, cathode conductor layer, cathode, and electrolyte are configured to form an electrochemical cell, and wherein at least one of cathode or the cathode conductor layer includes an exsolute oxide configured to capture Cr vapor species present in the fuel cell system.
    Type: Grant
    Filed: March 14, 2014
    Date of Patent: July 3, 2018
    Assignee: LG FUEL CELL SYSTEMS, INC.
    Inventors: Zhengliang Xing, Zhien Liu, Richard W. Goettler
  • Patent number: 10010872
    Abstract: A titanium-oxide catalyst containing catalytic metal shows catalysis under high temperature conditions. A titanium-oxide catalyst contains a titanium-oxide nanoparticle assembly and ruthenium particles. The titanium-oxide nanoparticle assembly is an assembly of titanium-oxide nanoparticles, which are nanoparticles of titanium oxide. The ruthenium particles have a smaller particle diameter than the titanium-oxide nanoparticle assembly and the titanium-oxide nanoparticles. The ruthenium particles are dispersed and supported on a surface of the titanium-oxide nanoparticle assembly.
    Type: Grant
    Filed: March 17, 2016
    Date of Patent: July 3, 2018
    Assignees: Nippon Pillar Packing Co., Ltd., Kochi University of Technology
    Inventors: Kazuya Kobiro, Masataka Otani, Keiichiro Moriwaki, Yukimi Hayashi
  • Patent number: 10008727
    Abstract: A fuel cell comprises a plurality of sub-cells, each sub-cell including a first electrode in fluid communication with a source of oxygen gas, a second electrode in fluid communication with a source of a fuel gas, and a solid electrolyte between the first electrode and the second electrode. The sub-cells are connected with each other with an interconnect. The interconnect includes a first layer in contact with the first electrode of each cell, and a second layer in contact with the second electrode of each cell. The first layer includes a (La,Mn)Sr-titanate based perovskite represented by the empirical formula of LaySr(1-y)Ti(1-x)MnxOb. In one embodiment, the second layer includes a (Nb,Y)Sr-titanate perovskite represented by the empirical formula of Sr(1-1.5z-0.5k±?)YzNbkTi(1-k)Od.
    Type: Grant
    Filed: December 12, 2013
    Date of Patent: June 26, 2018
    Assignee: SAINT-GOBAIN CERAMICS & PLASTICS, INC.
    Inventor: Guangyong Lin
  • Patent number: 9997794
    Abstract: A membrane electrode assembly is provided which includes an anode; a cathode; a membrane between the anode and the cathode; and a protective layer between the membrane and at least one electrode of the anode and the cathode, the protective layer having a layer of ionomer material containing a catalyst, the layer having a porosity of between 0 and 10%, an ionomer content of between 50 and 80% vol., a catalyst content of between 10 and 50% vol., and an electrical connectivity between catalyst particles of between 35 and 75%. A configuration using a precipitation layer to prevent migration of catalyst ions is also provided.
    Type: Grant
    Filed: April 1, 2015
    Date of Patent: June 12, 2018
    Assignee: Audi AG
    Inventors: Sergei F. Burlatsky, Ned E. Cipollini, David A. Condit, Thomas H. Madden, Sathya Motupally, Lesia V. Protsailo, Timothy W. Patterson, Lei Chen, Mallika Gummalla
  • Patent number: 9970118
    Abstract: A method for uniformly forming a nickel-metal alloy catalyst in a fuel electrode of a solid oxide electrolysis cell is provided. Specifically, before the nickel-metal alloy catalyst is formed, a metal oxide is uniformly distributed on nickel oxide contained in the fuel electrode through infiltration of a metal oxide precursor solution and hydrolysis of urea.
    Type: Grant
    Filed: December 23, 2016
    Date of Patent: May 15, 2018
    Assignee: KOREA INSTITUTE OF SCIENCE AND TECHNOLOGY
    Inventors: Jong Sup Hong, Si Won Kim, Man Soo Park, Hyoung Chul Kim, Kyung Joong Yoon, Ji Won Son, Jong Ho Lee, Hae Weon Lee, Byung Kook Kim
  • Patent number: 9923218
    Abstract: An illustrative example fuel cell electrolyte management device includes a first component having a first density and a second component having a second density that is less than the first density. The first component has a first side including a pocket and a second side facing opposite the first side. The second side of the first component includes a first plurality of fluid flow channels. The second component has a porosity configured for storing electrolyte in the second component. The second component fits within the pocket. The second component has a first side received directly against the first side of the first component. The second component has a second side including a second plurality of fluid flow channels.
    Type: Grant
    Filed: December 15, 2015
    Date of Patent: March 20, 2018
    Assignee: DOOSAN FUEL CELL AMERICA, INC.
    Inventors: Kevin A. Arpin, William Bajorek, Andrew Johnson, Sridhar Kanuri, Eric Livaich, Eric O'Brien, Timothy Patterson
  • Patent number: 9911993
    Abstract: The present disclosure is directed to a method and system for dynamically controlling seal decompression. The method includes monitoring a set of parameters associated with an operation of a seal, wherein the set of parameters includes a maximum pressure subjected to the seal and an exposure time at the maximum pressure, calculating a target pressure ramp down rate based on at least one of the maximum pressure and the exposure time, and decreasing a pressure about the seal at a decompression rate that is based on the target pressure ramp down rate.
    Type: Grant
    Filed: July 18, 2014
    Date of Patent: March 6, 2018
    Assignee: Nuvera Fuel Cells, LLC.
    Inventor: Scott Blanchet
  • Patent number: 9876091
    Abstract: After formation of a silicon nitride gate spacer and a silicon nitride liner overlying a disposable gate structure, a dielectric material layer is deposited, which includes a dielectric material that is not prone to material loss during subsequent exposure to wet or dry etch chemicals employed to remove disposable gate materials in the disposable gate structure. The dielectric material can be a spin-on dielectric material or can be a dielectric metal oxide material. The dielectric material layer and the silicon nitride liner are planarized to provide a planarized dielectric surface in which the disposable gate materials are physically exposed. Surfaces of the planarized dielectric layer is not recessed relative to surfaces of the silicon nitride layer during removal of the disposable gate materials and prior to formation of replacement gate structures, thereby preventing formation of metallic stringers.
    Type: Grant
    Filed: May 27, 2016
    Date of Patent: January 23, 2018
    Assignee: International Business Machines Corporation
    Inventors: Hemanth Jagannathan, Sanjay Mehta
  • Patent number: 9853308
    Abstract: A solid oxide fuel cell includes a fuel cell main body which includes a cathode layer, a solid electrolyte layer, and an anode layer and which has a power generation function; a connector disposed to face one electrode layer of the cathode layer and the anode layer; a current collector which is disposed between the one electrode layer and the connector and which is in contact with a surface of the one electrode layer and a surface of the connector, the surfaces facing each other, to thereby electrically connect the one electrode layer and the connector; and a groove provided in a portion of a surface of the one electrode layer, which surface is located on the side where the one electrode layer is in contact with the current collector, the portion of the surface being not in contact with the current collector.
    Type: Grant
    Filed: February 21, 2012
    Date of Patent: December 26, 2017
    Assignee: NGK SPARK PLUG CO., LTD.
    Inventors: Takeshi Ohno, Satoru Ishida, Hiroshi Sumi
  • Patent number: 9847520
    Abstract: Various embodiments include methods of fabricating an interconnect for a fuel cell stack. Methods for controlled pre-oxidation of an interconnect include oxidizing in a nitride-inhibiting environment to inhibit the formation of nitrides.
    Type: Grant
    Filed: July 11, 2013
    Date of Patent: December 19, 2017
    Assignee: BLOOM ENERGY CORPORATION
    Inventors: Shivanand Majagi, Harald Herchen, Sanjiv Kapoor, Michael Gasda, Chung-Dee Pong, Avinash Verma
  • Patent number: 9843053
    Abstract: An example fuel cell stack component includes a metallic layer applied to the component and an oxide layer applied to the metallic layer. The oxide layer includes a chemical component that is not in the metallic layer.
    Type: Grant
    Filed: September 9, 2010
    Date of Patent: December 12, 2017
    Assignee: Audi AG
    Inventors: Ellen Y. Sun, Lei Chen, Jean Yamanis, Neal Magdefrau, Dustin Frame
  • Patent number: 9839873
    Abstract: The present invention concerns a breathable product for protective mass transportation and cold chain applications, in particular a reflective sheet for covering temperature sensitive products the reflective sheet having at least a first layer made of a highly reflective moisture vapor permeable substrate having an outer side and an inner side, wherein said inner side comprises in addition at least a metal layer deposited by a PVD process to provide a thermal insulation through high reflection low convection while providing controlled moisture vapor permeability.
    Type: Grant
    Filed: May 31, 2017
    Date of Patent: December 12, 2017
    Assignee: E I DU PONT DE NEMOURS AND COMPANY
    Inventors: Serge Rebouillat, Malik Zeniti, Guy Hopp, Sylvain Wallerich, Noel Stephen Brabbs, Sabine Gabriel, Ioannis V Bletsos
  • Patent number: 9819029
    Abstract: An illustrative example method of making a fuel cell component includes mixing a catalyst material with a hydrophobic binder in a solvent to establish a liquid mixture having at least some coagulation of the catalyst material and the hydrophobic binder. The liquid mixture is applied to at least one side of a porous gas diffusion layer. At least some of the solvent of the applied liquid mixture is removed from the porous gas diffusion layer. The catalyst material remaining on the porous gas diffusion layer is dried under pressure.
    Type: Grant
    Filed: February 15, 2016
    Date of Patent: November 14, 2017
    Assignee: DOOSAN FUEL CELL AMERICA, INC.
    Inventors: Kevin Arpin, Nicole Hofstetter
  • Patent number: 9735423
    Abstract: The invention provides a nonaqueous electrolyte secondary battery having a cathode and an anode arranged so as to be opposite to each other, and an electrolyte layer put therebetween; wherein the cathode comprises: (a) a conductive polymer and (b) at least one selected from the group consisting of a polycarboxylic acid and a metal salt thereof, and wherein the anode comprises a material into which a base metal or ions thereof can be inserted and from which a base metal or ions thereof can be extracted. The invention further provides a cathode sheet for use in the nonaqueous electrolyte secondary battery mentioned above.
    Type: Grant
    Filed: June 27, 2012
    Date of Patent: August 15, 2017
    Assignee: NITTO DENKO CORPORATION
    Inventors: Masao Abe, Akira Otani, Yujiro Kawashima, Yoshihiro Uetani, Hiroyoshi Take, Yutaka Kishii, Aimi Matsuura, Yuki Kajisa, Yohei Ando
  • Patent number: 9735420
    Abstract: A positive electrode for lithium ion secondary batteries includes a collector and a positive electrode active material layer formed on at least one surface of the collector. The positive electrode active material layer contains a lithium-containing metal oxide having a unit cell represented by the following formula and a conductive material and has voids with a volume of 0.82×10?3 cm3/cm2 to 7.87×10?3 cm3/cm2 per unit area of the collector: LiFe1-xZrxP1-ySiyO4??(1) where 0<x<1 and 0<y<1. The unit cell has lattice constants satisfying 10.326?a?10.335, 6.006?b?6.012, and 4.685?c?4.714. The sum of the volume of the lithium-containing metal oxide and the volume of the conductive material is 1.61×10?3 cm3/cm2 to 6.46×10?3 cm3/cm2 per unit area of the collector.
    Type: Grant
    Filed: April 23, 2014
    Date of Patent: August 15, 2017
    Assignee: Sharp Kabushiki Kaisha
    Inventors: Isao Asako, Naoto Nishimura, Tomohisa Yoshie, Takahiro Matsuyama, Shougo Esaki, Shumpei Nishinaka, Yuichi Kamimura
  • Patent number: 9724640
    Abstract: The present invention provides: an electrode-supporting type of gas-separation membrane module for selectively effecting the passage of a gas via an electron exchange reaction due to a coupling-material layer and gas exchange via an ion-conducting separation layer; a tubular structure of same; a production method for the tubular structure; and a hydrocarbon-reforming method using the gas-separation membrane module. The present invention is advantageous in that outstanding chemical and mechanical durability can be ensured by using a fluorite-based ion-conducting membrane which is chemically stable in CO2 and H2O atmospheres in particular, at high temperature, and in that a pure gas can be produced inexpensively since the passage of gas occurs due to an internal circuit even without applying a voltage from the outside.
    Type: Grant
    Filed: October 31, 2013
    Date of Patent: August 8, 2017
    Assignee: KOREA INSTITUTE OF ENERGY RESEARCH
    Inventors: Jong Hoon Joo, Ji Haeng Yu, Chung-Yul Yoo
  • Patent number: 9728801
    Abstract: A fuel cell membrane electrode assembly is provided comprising a polymer electrolyte membrane comprising a first polymer electrolyte and at least one manganese compound; and one or more electrode layers comprising a catalyst and at least one cerium compound. The membrane electrode assembly demonstrates an unexpected combination of durability and performance.
    Type: Grant
    Filed: April 13, 2015
    Date of Patent: August 8, 2017
    Assignee: 3M INNOVATIVE PROPERTIES COMPANY
    Inventors: Daniel M. Pierpont, Steven J. Hamrock, Matthew H. Frey
  • Patent number: 9692059
    Abstract: There is provided a technique that suppresses a variation in particle diameter of a metal catalyst in the process of supporting the metal catalyst on a carrier. A CNT substrate having carbon nanotubes (CNTs) as the carrier arrayed thereon is placed in a processing chamber. Carbon dioxide is supplied to the processing chamber. After the carbon dioxide in the processing chamber is made supercritical, a complex solution in which a platinum complex is dissolved is supplied to the processing chamber. A sample temperature denoting temperature of the CNTs is controlled to be higher than an ambient temperature in the processing chamber. The CNT substrate is heated, such that a temperature difference between the ambient temperature and the sample temperature repeats increasing and decreasing. After the state of the supercritical fluid is changed to a non-supercritical state, the CNT substrate is heated, so as to cause the metal catalyst to deposit on the surface of the CNTs.
    Type: Grant
    Filed: November 21, 2012
    Date of Patent: June 27, 2017
    Assignee: TOYOTA JIDOSHA KABUSHIKI KAISHA
    Inventor: Ryoichi Nanba
  • Patent number: 9676627
    Abstract: Methods of growing boron nitride nanotubes and silicon nanowires on carbon substrates formed from carbon fibers. The methods include applying a catalyst solution to the carbon substrate and heating the catalyst coated carbon substrate in a furnace in the presence of chemical vapor deposition reactive species to form the boron nitride nanotubes and silicon nanowires. A mixture of a first vapor deposition precursor formed from boric acid and urea and a second vapor deposition precursor formed from iron nitrate, magnesium nitrate, and D-sorbitol are provided to the furnace to form boron nitride nanotubes. A silicon source including SiH4 is provided to the furnace at atmospheric pressure to form silicon nanowires.
    Type: Grant
    Filed: May 14, 2015
    Date of Patent: June 13, 2017
    Assignee: University of Dayton
    Inventor: Lingchuan Li
  • Patent number: 9647271
    Abstract: An aspect of the subject technology/invention of the present disclosure includes electrode structures or elements/components that have (e.g., present) fractal and/or self-complementary shapes or structures, e.g., on a surface. Such shapes or structures can be pre-existing. The electrodes can be made of any suitable material. The electrodes may function or operate or be used as a “seed” structure to incorporate or receive a material or materials useful for lattice assisted nuclear reactions and/or cold fusion processes.
    Type: Grant
    Filed: April 28, 2014
    Date of Patent: May 9, 2017
    Assignee: Fractal Antenna Systems, Inc.
    Inventor: Nathan Cohen
  • Patent number: 9647277
    Abstract: A method for forming a hydrolytically-stable hydrophilic coating on a fuel cell flow field plate comprises contacting a flow field plate with a titanium oxide sol to form a titanium oxide layer disposed upon the flow field plate. The coated flow field plate is subsequently contacted with a silicon oxide sol to form a silicon oxide/titanium oxide bilayer disposed upon the flow field plate. A flow field plate formed by the method is also provided.
    Type: Grant
    Filed: January 26, 2011
    Date of Patent: May 9, 2017
    Assignee: GM Global Technology Operations LLC
    Inventor: Richard H. Blunk
  • Patent number: 9640817
    Abstract: A power generator includes a cavity to accept a hydrogen producing fuel cartridge. A channel is coupled to receive hydrogen from the fuel cartridge. A manifold is coupled to the channel to receive hydrogen from the channel, the manifold having an opening to receive oxygen and water vapor, the manifold being positioned to provide the water vapor to the cavity. An array of fuel cell membranes is supported by the manifold to receive hydrogen from the manifold and oxygen from the opening in the manifold.
    Type: Grant
    Filed: September 8, 2016
    Date of Patent: May 2, 2017
    Assignee: Honeywell International Inc.
    Inventor: Steven J. Eickhoff
  • Patent number: 9634347
    Abstract: There is disclosed a method and components for repairing a fuel cell stack. In particular, the method and components relate to repairing a high temperature fuel cell stack incorporating ceramic components. The method includes identifying a fuel cell bundle within a fuel cell strip to be disconnected from the fuel cell strip, identifying at least one fuel feed pipe portion connected to the fuel cell bundle, and identifying at least one fuel outlet pipe portion connected to the fuel cell bundle. A cutting blade is positioned on the fuel feed pipe portion and cutting through the fuel feed pipe portion, and similarly for the fuel outlet pipe portion. The fuel cell bundle is then removed, and a replacement inserted in its place.
    Type: Grant
    Filed: July 16, 2015
    Date of Patent: April 25, 2017
    Assignee: LG Fuel Cell Systems Inc.
    Inventor: Eric Dean
  • Patent number: 9597697
    Abstract: The invention relates to an apparatus for the coating of a substrate, in particular of a circuit board, with a material application device for applying a coating material and with a gas supplying device for the supply of a gaseous medium, the material application device having an inner tubular element, the gas supply device having an outer tubular element which is arranged coaxially to the inner tubular element and surrounds the latter, so as to form between the outer and the inner tubular element a gas supply duct which has an annular orifice at one end, the supply duct being configured so that the gaseous medium flows out, parallel to the coating material, through the annular orifice, in order, when it impinges on the substrate, to displace the applied coating material and thereby distribute it over the area. The apparatus is distinguished in that the material application device has a jet valve which, in a first operating mode, carries out a jetted supply of material into the inner tubular element.
    Type: Grant
    Filed: March 8, 2010
    Date of Patent: March 21, 2017
    Inventor: Wolfgang Klingel
  • Patent number: 9570759
    Abstract: The present invention provides a manufacturing method of an electrode catalyst layer which contains a catalyst, carbon particles and a polymer electrolyte, wherein an oxide type of non-platinum catalyst is used as the catalyst and a fuel cell employing the electrode catalyst layer achieves a high level of power generation performance. The manufacturing method of the electrode catalyst layer of the present invention includes at least: preparing a first catalyst ink, in which a catalyst, first carbon particles and a first polymer electrolyte are dispersed in a first solvent, drying the first catalyst ink to form complex particles, preparing a second catalyst ink, in which the complex particles, second carbon particles and a second polymer electrolyte are dispersed in a second solvent, and coating the second catalyst ink on a substrate to form the electrode catalyst layer.
    Type: Grant
    Filed: March 28, 2012
    Date of Patent: February 14, 2017
    Assignee: Toppan Printing Co., Ltd.
    Inventors: Haruna Kurata, Hiroyuki Morioka, Saori Okada, Kenichiro Oota
  • Patent number: 9561987
    Abstract: The present invention is concerned with methods for the deposition of ceramic films on ceramic or metallic surfaces, particularly the deposition of sub-micron thickness ceramic films such as films of stabilised zirconia and doped ceria such as CGO (cerium gadolinium oxide). The present invention is particularly useful in the manufacture of high and intermediate temperature operating fuel cells including solid oxide fuel cells (SOFC) and also metal supported intermediate temperature SOFC operating in the 450-650° C. range.
    Type: Grant
    Filed: April 30, 2009
    Date of Patent: February 7, 2017
    Assignee: CERES INTELLECTUAL PROPERTY COMPANY LIMITED
    Inventors: Adam Bone, Richard Dawson, Robert Leah
  • Patent number: 9525197
    Abstract: The present invention relates to a lithium-air battery including: a negative electrode containing a negative-electrode active material; a positive electrode using oxygen as a positive-electrode active material; and an electrolyte medium arranged between the negative electrode and the positive electrode; wherein the electrolyte medium includes as primary solvent one or more compounds having an —N—CO— group in the molecule.
    Type: Grant
    Filed: October 10, 2011
    Date of Patent: December 20, 2016
    Assignees: TOYOTA MOTOR EUROPE NV/SA, THE UNIVERSITY COURT OF THE UNIVERSITY OF ST. ANDREWS
    Inventors: Fanny Jeanne Julie Barde, Peter George Bruce, Yuhui Chen, Stefan Freunberger
  • Patent number: 9515323
    Abstract: A method of preparation of metal-chalcogen-nitrogen-carbon (M-Ch-N—C) catalytic material utilizing a sacrificial support approach and using inexpensive and readily available precursors is described. Furthermore, the catalytic materials synthesized using the disclosed methods include multiple types of active sites.
    Type: Grant
    Filed: February 1, 2013
    Date of Patent: December 6, 2016
    Assignee: STC.UNM
    Inventors: Alexey Serov, Barr Halevi, Kateryna Artyushkova, Plamen B Atanassov
  • Patent number: 9515327
    Abstract: A fuel cell separator is provided with an opening that functions as a manifold. A resin coating is formed within the peripheral area of the fuel cell separator, in a state where the power generation area is masked with a masking jig. Subsequently, the masking jig is removed, and a conductive coating is formed within the power generation area of the fuel cell separator, the peripheral area of which has been masked by the resin coating.
    Type: Grant
    Filed: August 8, 2007
    Date of Patent: December 6, 2016
    Assignee: TOYOTA JIDOSHA KABUSHIKI KAISHA
    Inventors: Kazutaka Iizuka, Masakazu Suzuki, Masanori Matsukawa
  • Patent number: 9509009
    Abstract: The present disclosure provides a method of generating electricity from a long chain hydrocarbon, said method comprising contacting the liquid non-polar substrate with a plurality of enzymes, wherein at least one enzyme is non-electric current/potential enzyme that functions as a catalyst for chemical reaction transforming a first substrate or byproduct to a second substance that can be used with an additional electric current/potential generating enzyme.
    Type: Grant
    Filed: April 25, 2014
    Date of Patent: November 29, 2016
    Assignee: CFD Research Corporation
    Inventors: Yevgenia Ulyanova, Shelley Minteer, Sameer Singhal, Vojtech Svoboda, Jianjun Wei
  • Patent number: 9494839
    Abstract: A process for manufacturing an electrochemically active device comprising the steps of: —providing a substrate (110) comprising an electrode receiving surface portion (111) having substantially constant wetting tension throughout said electrode receiving surface portion, —providing a plurality of first electrodes (120) directly on said electrode receiving surface portion, —leaving intermediate portions (130) of said electrode receiving surface portion (111) free from said electrodes, —providing a layer of electrolyte (140) covering said plurality of first electrodes (120) and said intermediate portions (130), and—wherein wetting tension of the surfaces of the intermediate portions (130) is arranged to act more repelling on the electrolyte compared to the wetting tension of the surfaces of the plurality of first electrodes (120), whereby, the electrolyte is concentrated to the surfaces of the plurality of first electrodes (120), and the surfaces of the intermediate portions (130) are substantially free of elec
    Type: Grant
    Filed: April 4, 2012
    Date of Patent: November 15, 2016
    Assignees: ACREO SWEDISH ICT AB, LINTEC CORPORATION
    Inventors: Peter Andersson Ersman, Jun Kawahara, Kazuya Katoh, David Nilsson
  • Patent number: 9463440
    Abstract: Fabrication of oxide nanowire heterostructures with controlled morphology, interface and phase purity are desired for high-efficiency and low-cost photocatalysis. Disclosed herein is the formation of oxide nanowire heterostructures by sputtering and subsequent air annealing to result in oxide nanowires. This approach allows for fabrication of standing nanowire heterostructures with tunable compositions and morphologies.
    Type: Grant
    Filed: September 16, 2014
    Date of Patent: October 11, 2016
    Assignee: The Board of Trustees of the University of Alabama
    Inventor: Nitin Chopra
  • Patent number: 9437893
    Abstract: An in-membrane micro fuel cell comprises an electrically-insulating membrane that is permissive to the flow of cations, such as protons, and a pair of electrodes deposited on channels formed in the membrane. The channels are arranged as conduits for fluids, and define a membrane ridge between the channels. The electrodes are porous and include catalysts for promoting the liberation of a proton and an electron from a chemical species and/or or the recombination of a proton and an electron with a chemical specie. The fuel cell may be provided a biosensor, an electrochemical sensor, a microfluidic device, or other microscale devices fabricated in the fuel cell membrane.
    Type: Grant
    Filed: August 28, 2014
    Date of Patent: September 6, 2016
    Assignee: The Trustees of the Stevens Institute of Technology
    Inventors: Ayokunle Omosebi, Ronald Besser
  • Patent number: 9431670
    Abstract: A fuel cell membrane electrode assembly is provided comprising a polymer electrolyte membrane which comprises a polymer that comprises bound anionic functional groups, wherein the polymer electrolyte membrane additionally comprises cerium cations. In another aspect, a fuel cell membrane electrode assembly is provided comprising a polymer electrolyte membrane which comprises a polymer that comprises bound anionic functional groups, wherein at least a portion of the anionic functional groups are in acid form and at least a portion of the anionic functional groups are neutralized by cerium cations. In another aspect, a polymer electrolyte membrane is provided which comprises a polymer that comprises bound anionic functional groups, wherein the polymer electrolyte membrane additionally comprises cerium cations, and wherein the amount of cerium cations present is between 0.001 and 0.
    Type: Grant
    Filed: December 5, 2013
    Date of Patent: August 30, 2016
    Assignee: 3M INNOVATIVE PROPERTIES COMPANY
    Inventors: Matthew H. Frey, Daniel M. Pierpont, Steven J. Hamrock
  • Patent number: 9431676
    Abstract: An electrode for a biplate assembly includes an active material made from a compressed powder 11, and a non-metal carrier 10. A biplate assembly 20 includes electrodes 27, 28 each having a non-metal carrier 10. A method is disclosed for manufacturing an electrode 13 having a non-metal carrier 10. An apparatus 30 is disclosed for manufacturing such an electrode 13. A bipolar battery includes at least one such an electrode 13. The non-metal carrier 10 is preferably a non-conductive carrier.
    Type: Grant
    Filed: April 27, 2009
    Date of Patent: August 30, 2016
    Assignee: Nilar International AB
    Inventors: Lars Fredriksson, Neil H. Puester
  • Patent number: 9406945
    Abstract: A bipolar plate used in a fuel cell and a method of making a bipolar plate. The sheet is made generally from a stainless steel, and in a more preferable form from a ferritic stainless steel. In one configuration, a stamping or related metal forming tool operation will introduce a negative clearance as a way to move or otherwise reallocate a portion of the material making up the sheet into other portions as a way to reduce stretching, necking, thinning and related thickness deviations associated with the bends formed in the bipolar plate.
    Type: Grant
    Filed: August 22, 2014
    Date of Patent: August 2, 2016
    Assignee: GM Global Technology Operations LLC
    Inventors: Siguang Xu, Joseph N. Lovria, Elizabeth Dicocco
  • Patent number: 9391336
    Abstract: A membrane electrode assembly includes a membrane, an anode catalyst layer and a cathode catalyst layer. The anode catalyst layer is on a first side of the membrane and the cathode catalyst layer is on a second side of the membrane, wherein the second side of the membrane is opposite the first side of the membrane along a first axis. The cathode catalyst layer includes agglomerates formed of a catalyst support supporting catalyst particles, an agglomerate ionomer and an inter-agglomerate ionomer. The agglomerate ionomer surrounds the agglomerates and the inter-agglomerate ionomer is in regions between the agglomerates surrounded by the agglomerate ionomer. The agglomerate ionomer is different than the inter-agglomerate. Methods to produce the catalyst layer are also provided.
    Type: Grant
    Filed: August 23, 2010
    Date of Patent: July 12, 2016
    Assignee: Audi AG
    Inventors: Thomas H. Madden, Robert Mason Darling, Michael L. Perry
  • Patent number: 9385376
    Abstract: A manufacturing method of a fibrous perovskite-type oxide catalyst includes: a first preparing step; a jetting step; a heating step; and an impregnating step. The first preparing step prepares a first solution by mixing metal salts containing La, Sr, Fe, Co and O elements, a first polymer, a metal salt containing a Zn element and a first solvent. The jetting step jets the first solution by using an electrospinning method to produce a precursor fiber. The heating step heats the precursor fiber to produce a perovskite-type oxide mixed with a Zn oxide. The impregnating step impregnates the perovskite-type oxide with an alkaline solution to remove the Zn oxide.
    Type: Grant
    Filed: September 16, 2015
    Date of Patent: July 5, 2016
    Assignee: Toyota Jidosha Kabushiki Kaisha
    Inventor: Iwao Nitta
  • Patent number: 9379393
    Abstract: The present invention provides a carbon-cladded composite composition for use as a fuel cell flow field plate or bipolar plate. In one preferred embodiment, the composition comprises a core composite layer sandwiched between two clad layers, wherein (a) the clad layer comprises a conductive carbon or graphite material (e.g., carbon nano-tubes, nano-scaled graphene plates, graphitic nano-fibers, and fine graphite particles); (b) the core composite layer comprises a matrix resin and a conductive filler present in a sufficient quantity to render the composite layer electrically conductive with an electrical conductivity no less than 1 S/cm (preferably no less than 100 S/cm); and (c) the composition has a planar outer surface on each clad side having formed therein a fluid flow channel.
    Type: Grant
    Filed: December 26, 2006
    Date of Patent: June 28, 2016
    Assignee: Nanotek Instruments, Inc.
    Inventors: Bor Z. Jang, Aruna Zhamu, Jiusheng Guo
  • Patent number: 9358525
    Abstract: A NOx storage material comprises a support, a potassium salt impregnated on the support, the potassium impregnated on the support is promoted with a platinum group metal, and wherein the NOx storage material has an electrical property which changes based on the amount of NOx loading on the NOx storage material. An apparatus for direct NOx measurement includes a sensor coated with the NOx storage material. A method of determining NOx flux in a NOx containing gas comprises exposing the gas to the apparatus and converting a signal developed by the apparatus to a signal representative of the NOx flux.
    Type: Grant
    Filed: December 3, 2009
    Date of Patent: June 7, 2016
    Assignee: Johnson Matthey Public Limited Company
    Inventors: Hai-Ying Chen, Shadab Mulla, Todd Howard Ballinger
  • Patent number: 9356121
    Abstract: After formation of a silicon nitride gate spacer and a silicon nitride liner overlying a disposable gate structure, a dielectric material layer is deposited, which includes a dielectric material that is not prone to material loss during subsequent exposure to wet or dry etch chemicals employed to remove disposable gate materials in the disposable gate structure. The dielectric material can be a spin-on dielectric material or can be a dielectric metal oxide material. The dielectric material layer and the silicon nitride liner are planarized to provide a planarized dielectric surface in which the disposable gate materials are physically exposed. Surfaces of the planarized dielectric layer is not recessed relative to surfaces of the silicon nitride layer during removal of the disposable gate materials and prior to formation of replacement gate structures, thereby preventing formation of metallic stringers.
    Type: Grant
    Filed: September 15, 2014
    Date of Patent: May 31, 2016
    Assignee: International Business Machines Corporation
    Inventors: Hemanth Jagannathan, Sanjay Mehta
  • Patent number: 9181134
    Abstract: This description concerns a process of converting textile solid waste into a graphite manufacture and makes it possible both to reduce or totally eliminate the use of virgin textile materials for graphitization and to prepare graphite manufacture, such as simple articles (e.g., fibers, powder, foil, sheets, etc.) and complex shape articles (e.g., blocks, plates, rings, pipes, armors, etc.). Described is a sustainable textile solid waste material management process.
    Type: Grant
    Filed: March 22, 2012
    Date of Patent: November 10, 2015
    Assignee: ISRAZION LTD.
    Inventor: David Jacob
  • Patent number: 9184478
    Abstract: Systems and methods drawn to an electrochemical cell comprising a low temperature ionic liquid comprising positive ions and negative ions and a performance enhancing additive added to the low temperature ionic liquid. The additive dissolves in the ionic liquid to form cations, which are coordinated with one or more negative ions forming ion complexes. The electrochemical cell also includes an air electrode configured to absorb and reduce oxygen. The ion complexes improve oxygen reduction thermodynamics and/or kinetics relative to the ionic liquid without the additive.
    Type: Grant
    Filed: May 11, 2011
    Date of Patent: November 10, 2015
    Assignee: ARIZONA BOARD OF REGENTS FOR AND ON BEHALF OF ARIZONA STATE UNIVERSITY
    Inventors: Cody A. Friesen, Daniel Buttry
  • Patent number: 9178244
    Abstract: Embodiments relate to a composite for a fuel cell layer including a plurality of electron conducting components, a plurality of ion conducting components each having a first surface and a second surface and wherein each ion conducting component is positioned between two electron conducting components. The electron conducting components and the ion conducting components form a layer and at least one of the ion conducting components or the electron conducting components is geometrically asymmetric in one or more dimensions.
    Type: Grant
    Filed: December 23, 2010
    Date of Patent: November 3, 2015
    Assignee: intelligent Energy Limited
    Inventors: Jeremy Schrooten, Paul Sobejko, Gerard F. McLean
  • Patent number: 9153822
    Abstract: In one embodiment, a catalyst assembly includes a substrate including a base and a number of rods extending from the base; a catalyst layer including a catalyst material; and a first intermediate layer including a first coating material disposed between the substrate and the catalyst layer, the first coating material having a higher surface energy than the catalyst material. In certain instances, the number of rods may have an average aspect ratio in length to width of greater than 1. The catalyst assembly may further include a second intermediate layer disposed between the catalyst layer and the first intermediate layer, the second intermediate layer including a second coating material having a higher surface energy than the catalyst material. In certain instances, the first coating material has a higher surface energy than the second coating material.
    Type: Grant
    Filed: August 14, 2012
    Date of Patent: October 6, 2015
    Assignee: Ford Global Technologies, LLC
    Inventor: Alireza Pezhman Shirvanian
  • Patent number: 9127182
    Abstract: A polymer dispersion comprising one or more proton-conducting polymer materials in a liquid medium, and an electrocatalyst ink comprising one or more electrocatalyst materials and one or more proton-conducting polymer materials in a liquid medium are disclosed. The polymer dispersion and the electrocatalyst ink further comprise a protic acid. Electrocatalyst layers, gas diffusion electrodes, catalyzed membranes and membrane electrode assemblies prepared using the dispersion and/or the ink are also disclosed.
    Type: Grant
    Filed: May 17, 2006
    Date of Patent: September 8, 2015
    Assignee: JOHNSON MATTHEY FUEL CELLS LIMITED
    Inventors: Dharshini Chryshantha Fongalland, Pamela Kapila, Chandresh Nemchand Malde, Michael Ian Petch
  • Patent number: 9088011
    Abstract: A bipolar plate which can be produced particularly economically for a fuel cell, with which a high degree of efficiency is guaranteed over a long service life. The bipolar plate has a core layer consisting of a steel material, the surfaces of said core layer, which are associated with the respective electrolyte carriers of the fuel cell, having a corrosion protection layer, protecting the core layer against corrosion. The corrosion protection layers consist of a metal material and extend on both sides over the whole surface of the core layer. At the same time the corrosion protection layers are in turn coated over the whole surface with an electrically conductive functional coating, which is essentially entirely impermeable for the metal ions emerging from the core layer and/or the corrosion protection layers. The invention likewise relates to at least one fuel cell comprising a bipolar plate according to the invention.
    Type: Grant
    Filed: July 3, 2008
    Date of Patent: July 21, 2015
    Assignee: ThyssenKrupp Steel Europe AG
    Inventors: Stefan Wischmann, Horst Walter Tamler, Roland Wunderlich, Michael Steinhorst, Krasimir Nikolov, Nicole Weiher, Jens-Ulrik Becker, Stefan Peter Puls, Bernd Schuhmacher
  • Patent number: 9065140
    Abstract: A substantially crack-free electrode layer is described. The substantially crack-free electrode layer includes a substrate; and a substantially crack-free electrode layer on the substrate, the electrode layer comprising a catalyst, an ionomer, and a layered silicate reinforcement. Methods of making the electrode layer, electrode ink compositions, and membrane electrode assemblies incorporating the electrode layer are also described.
    Type: Grant
    Filed: September 15, 2010
    Date of Patent: June 23, 2015
    Assignee: GM Global Technology Operations LLC
    Inventors: Bradley M. Houghtaling, Jeanette E. Owejan
  • Publication number: 20150140204
    Abstract: A separator is provided that has a metal substrate and a conductive resin layer on the surface of the metal substrate. The conductive resin layer contains a resin and a conductive substance dispersed in the resin. The separator is configured such that the proportion of the conductive substance to the resin increases continuously from the metal substrate toward the surface of the separator.
    Type: Application
    Filed: July 3, 2013
    Publication date: May 21, 2015
    Applicant: TOYOTA SHATAI KABUSHIKI KAISHA
    Inventors: Yukihiro Suzuki, Eiichiro Morozumi, Takatoshi Asaoka
  • Patent number: 9034932
    Abstract: The invention provides a zwitterionic-bias material for blood cell selection, being a copolymer formed by zwitterionic structural units and charged structural units wherein the zwitterionic structural unit comprises at least one positively charged moiety and one negatively charged moiety, a distance between the positively charged moiety and the negatively charged moiety is a length of 1˜5 carbon-carbon bonds, and the zwitterionic structural units and charged structural units are randomly arranged to have zwitterionic-bias.
    Type: Grant
    Filed: November 14, 2013
    Date of Patent: May 19, 2015
    Assignee: CHUNG YUAN CHRISTIAN UNIVERSITY
    Inventors: Yung Chang, Jheng-Fong Jhong, Sheng-Han Chan, Wen-Lin Lin