Transfer Or Copy Sheet Making Patents (Class 427/146)
  • Patent number: 5132139
    Abstract: A thermal printing ribbon is made from an aqueous dispersion of a thermal plastic binder and particles of a wax component, fat-soluble dyestuff and a pigment so that these particles are found side by side in the interstices of a skeleton or matrix formed by a thermoplastic. The thermal printing ribbon has a multistrike capacity.
    Type: Grant
    Filed: June 13, 1990
    Date of Patent: July 21, 1992
    Assignee: Pelikan Aktiengesellschaft
    Inventors: Norbert Mecke, Albert Schmedes
  • Patent number: 5120383
    Abstract: A thermal transfer ink sheet including a heat resistant support film, a first fusible ink layer disposed on the support film, an interlayer which will support the first ink layer in uniform layer condition during thermal printing and will still separate cleanly from the non-printed portion on the first ink layer and a second fusible ink layer on the interlayer. Several embodiments of the interlayer will maintain the first ink layer in uniform layer condition during thermal printing. The interlayer can be formed of: a material with a low melting point whose viscosity does not decrease substantially when its temperature is increased; a thin film of thermosetting resin; and a layer of material formed of minute grains or domains smaller than a pixel which will form a pixel sized layer support during thermal printing.
    Type: Grant
    Filed: August 30, 1989
    Date of Patent: June 9, 1992
    Assignee: Seiko Epson Corporation
    Inventors: Katsumori Takei, Hitoshi Fukushima, Kohei Iwamoto, Hiroto Nakamura
  • Patent number: 5102717
    Abstract: An inkable sheet comprises a substrate and ink-absorbent layer, the surface of which exhibits an internal contact angle of at least 120.degree.. A modifying treatment provides a microporous surface zone of reduced apparent hydrophilicity which accepts a high loading of an aqueous-based ink. Ink patterns of high resolution are thereby achievable.
    Type: Grant
    Filed: July 23, 1990
    Date of Patent: April 7, 1992
    Assignee: Imperial Chemical Industries PLC
    Inventors: Alan Butters, Graham A. Page, Roger N. Barker
  • Patent number: 5100718
    Abstract: There is featured a simplified, cost-reduced process for creating and applying decals to fabric materials, such as T-shirts. The invention uses conventional, non-permanent printing inks, such as oleic acid-based inks, found in typewriter and dot matrix printing ribbons. Conventional ink is injected below the surface of transfer laminate paper where it is trapped in the apertures created by the printing pins of, for example, a dot matrix printer. The design created by the injected ink is then transferred to the surface of a fabric by the application of heat, such as by use of a home iron, which causes the laminate sheet membranes to melt. As these layers melt, the ink trapped within is plasticized and the transfer process to the fabric is accomplished in the conventional manner. All types of information in the form of images, designs, characters and symbols can be injected into the laminate paper as benefits the imagination of the user.
    Type: Grant
    Filed: September 17, 1990
    Date of Patent: March 31, 1992
    Inventor: David L. Weintraub
  • Patent number: 5095001
    Abstract: A thermal transfer printing receiver sheet for use in association with a compatible donor sheet comprises a supporting substrate having a dye-receptive receiving layer, said dye receiving layer comprises a dye-receptive polymer and from 0.5 to 30% by weight of the layer of at least one antiplasticizer therefor.
    Type: Grant
    Filed: April 18, 1990
    Date of Patent: March 10, 1992
    Assignee: Imperial Chemical Industries PLC
    Inventors: Isabel S. Miles, Gary V. Rhoades, Moray W. Mackenzie
  • Patent number: 5071824
    Abstract: A heat transfer sheet which has a high recording sensitivity and can form image of high maximum reflection density and of high contrast is provided by containing in an ink layer of the heat transfer sheet at least one dye which has a product of an extinction coefficient (l.cm.sup.-1.g.sup.-1) and an evaporation or sublimation rate at 240.degree. C. (wt %.min..sup.-1) of at least 1.8.times.10.sup.2 (l.wt %.cm.sup.-1.g.sup.-1.min.sup.-1).
    Type: Grant
    Filed: September 13, 1989
    Date of Patent: December 10, 1991
    Assignee: Hitachi, Ltd.
    Inventors: Shuichi Ohara, Satoru Amou, Shinichi Akasaka
  • Patent number: 5069944
    Abstract: A thermal transfer record sheet comprising a substrate sheet and a dye receptive layer and a non-tacky layer in this order on at least one surface of the substrate sheet; the dye receptive layer being composed of a crosslinking reaction product of a composition comprising (A-1) a saturated polyester containing units derived from 2,2-bis(4-hydroxyphenyl)propane in the main chain of the polyester and having a glass transition temperature of at least 60.degree. C. and (A-2) a polyisocyanate compound, and the non-tacky layer (B-1) comprising a water-insoluble or sparingly water-soluble fluorine-containing surface-active agent and (B-2) having a thickness of 50 to 200 angstrom.
    Type: Grant
    Filed: March 15, 1990
    Date of Patent: December 3, 1991
    Assignee: Teijin Limited
    Inventors: Takashi Yamagishi, Yukito Yamamoto, Yoji Murakami
  • Patent number: 5068123
    Abstract: A process for producing a recording medium comprising a substrate and a plurality of image forming elements disposed thereon, which comprises the steps of: applying a binder onto the substrate to form thereon a binder layer; disposing the image forming elements on the binder layer; and simultaneously applying a vibration and a pressure to the image forming elements disposed on the binder layer sufficient to bond the image forming elements to the substrate as a substantially monoparticle layer.
    Type: Grant
    Filed: August 29, 1989
    Date of Patent: November 26, 1991
    Assignee: Canon Kabushiki Kaisha
    Inventors: Hiroshi Goto, Toshiaki Harada, Noriyoshi Ishikawa
  • Patent number: 5043318
    Abstract: The present invention provides dye transfer type thermal printing sheet comprising a base sheet, a dye-containing layer formed on the base sheet and a dye-permeable layer which is formed on the dye-containing layer and comprises at least one water dispersible polysiloxane graft polymer which is obtainable by polymerizing (B) 0.05 to 10% by weight of a polymerizable silane compound, (C) 1 to 30% by weight of an unsaturated organic acid and (D) 40 to 97.95% by weight of a monomer which is copolymerizable with the silane compound (B) and the unsaturaed organic acid (C) in the presence of (A) 1 to 20% by weight of a polysiloxane having terminal hydroxyl groups (provided that the total of the components (A), (B), (C) and (D) is 100% by weight) in an organic solvent except an alcohol or at least one salt of said graft polymer with a base, which has good storage stability, generates images with improve weather durability and prevents great decrease of print density as increase of the number of printing times.
    Type: Grant
    Filed: March 12, 1990
    Date of Patent: August 27, 1991
    Assignees: Matsushita Electric Industrial Co., Ltd., Nippon Shokubai Kagaku Kogyo Co., Ltd.
    Inventors: Tetsuji Kawakami, Hiromu Matsuda, Sigeru Tanimori, Yoshinori Sano
  • Patent number: 5035954
    Abstract: The heat-sensitive record materials have, between the base sheet and the recording layer, a middle layer which mainly comprises a binder and at least one pigment having an oil absorption of at leasat 80 cc/100 g measured by JIS K 5101. The middle layer comprises an acrylic thickener in an amount of 0.05 to 5 parts by weight per 100 parts by weight of the pigment on dry basis.The middle layer is formed by blade-coating on a base sheet a coating composition comprising at least one pigment having an oil absorption of at least 80 cc/100 g measured by JIS K 5101 and a binder, in which an acrylic thickener is comprised in such amount as described above.
    Type: Grant
    Filed: August 22, 1989
    Date of Patent: July 30, 1991
    Assignee: Kanzaki Paper Manufacturing Co., Ltd.
    Inventors: Naoki Yonese, Mikio Nakamura, Masato Kawamura, Yukio Takayama
  • Patent number: 5030612
    Abstract: Thermal dye sublimation transfer recording element for receiving sublimable basic dye-precursors, comprising a support having thereon a dye-developing layer containing a dye-developing copolymer having sulfonic acid side-groups that can react with the basic dye-precursor to produce a dye image, characterized in that said dye-developing vinyl copolymer comprises plasticizing comonomers, the weight percentage of plasticizing comonomers in the dye-developing vinyl copolymer being such that the glass transition temperature of the dye-developing vinyl copolymer is between 30.degree. C. and 90.degree. C.
    Type: Grant
    Filed: February 27, 1990
    Date of Patent: July 9, 1991
    Assignee: Agfa-Gevaert, N.V.
    Inventors: Herman J. Uytterhoeven, Roderich Raue, Siegfried Korte
  • Patent number: 5017546
    Abstract: Phenol/aldehyde condensation products useful in the development of colored images from colorless dyes are disclosed. The phenol/aldehyde condensation products are produced by the interaction of an alkyl-substituted salicylic acid, an alkyl-substituted phenol, an aldehyde, and a metal source. The phenol/aldehyde condensation products are particularly useful in a photosensitive imaging system in which images are formed by the image-wise reaction of the developer with one or more chromogenic materials, and in carbonless copy paper systems.
    Type: Grant
    Filed: July 13, 1990
    Date of Patent: May 21, 1991
    Inventors: Karl M. Brinkman, John L. Sullivan, David R. Hanley
  • Patent number: 5006863
    Abstract: A heat sensitive copy system uses a magnetic thermal transfer ribbon to transfer images onto an adjacent medium and near infra-red energy is used to transfer the images from the medium onto thermal paper or onto translucent paper for producing multiple copies in a manner which is not thickness sensitive.
    Type: Grant
    Filed: February 8, 1989
    Date of Patent: April 9, 1991
    Assignee: NCR Corporation
    Inventor: Shashi G. Talvalkar
  • Patent number: 4992351
    Abstract: A recording medium has a recording layer comprising image-forming elements (A), (B) and (C) containing at least a compound having unsaturated double bond and a photopolymerization initiator. The photopolymerization initiator in the element (A) is a compound represented by the following formula (I): ##STR1## (wherein Ar.sub.1 and Ar.sub.2 are ech aromatic ring or heterocyclis ring). The photopolymerization initiator in the element (B) has an absorption maximum in a wavelength region of 360 to 430 nm. The photopolymerization initiator in the element (C) has an absorption maximum in a wavelength region of 430 nm or longer. The recording medium is suitably used as a transfer recording medium in a recording apparatus which includes heating means and light irradiating means to provide the recording layer with heat energy and photoenergy to change the transfer characteristic of the recording layer.
    Type: Grant
    Filed: December 26, 1989
    Date of Patent: February 12, 1991
    Assignee: Canon Kabushiki Kaisha
    Inventors: Norio Ohkuma, Masanori Takenouchi, Masashi Miyagawa, Tadashi Yamamoto
  • Patent number: 4985260
    Abstract: An article comprising a substrate such as cellulose casing having thereon a desired indicia such as grill marks or a corporate logo, which in turn comprises a water soluble underlayer such as caramel and a water insoluble binder-sealant layer such as shellac. Also included are an indicia-containing processable food package, a method for preparing the substrate-indicia article, a method for making an indicia-containing food product, and an edible food product as for example a frankfurter having a desired indicia on its outer surface.
    Type: Grant
    Filed: March 24, 1989
    Date of Patent: January 15, 1991
    Inventors: Vitas Niaura, Jeffery A. Oxley, Elio E. Tarika
  • Patent number: 4976986
    Abstract: Disclosed is a method for regenerating an ink recording medium formed by successively laminating an anisotropic electrically conductive layer, a heating resistor layer for generating heat in response to application of an electric signal, an electrically conductive layer, an ink parting layer, and a heat-melting ink layer, in which the heat-melting ink layer after print-recording with the ink recording medium is regenerated by use of ink particles containing a binding resin and a coloring agent, the improvement is in that by use of the ink recording medium further including an ink parting layer having a thickness of 0.08 to 3 .mu.m, and a volume resistivity of 10.sup.8 .OMEGA. cm or more, the heat-melting ink layer after print-recording with the ink recording medium is electrified with the same polarity as the potential of electrified ink particles, and then the ink particles carried by an ink carrier is deposited on traces of transferred ink formed in the heat-melting ink layer.
    Type: Grant
    Filed: March 15, 1990
    Date of Patent: December 11, 1990
    Assignee: Fuji Xerox Co., Ltd.
    Inventors: Eiichi Akutsu, Hiroh Soga, Shigehito Ando
  • Patent number: 4977006
    Abstract: The present invention provides strucutures for dispensing ulra-thin adhesive labels without risk of predispensing and comprising a carrier web and a face film, the carrier web having a top and reverse side, a release surface being provided on the top side, the face film having two faces, an adhesive-backing being provided on a first of the faces, the second of the faces being mounted against the release surface and wherein the face film is frangible and the release surface positively defines at least one label-shape, the area covered by the adhesive backing corresponding substantially to at least the one label-shape.
    Type: Grant
    Filed: July 20, 1989
    Date of Patent: December 11, 1990
    Assignee: Revolutionary Adhesive Materials, Ltd.
    Inventors: Hylton H. Smith, Richard G. Foggin
  • Patent number: 4975410
    Abstract: A thermally-transferred color filter array element comprising a transparent support having thereon a thermally-transparent image comprising a repeating mosaic pattern of colorants in a receiving layer, one of the colorants being a mixture of a yellow dye and a cyan dye to form a green hue, said yellow dye having the formula: ##STR1## wherein: R.sup.1 and R.sup.2 represents hydrogen, alkyl, cycloalkyl, aryl or hetaryl; or can be taken together to form a 5- or 6-membered ring; or either or both of R.sup.1 and R.sup.2 can be joined to a carbon atom of the aromatic ring to form a 5- or 6-membered ring;R.sup.3 represents hydrogen or halogen:Y represents hydrogen, halogen, cyano, alkyl, alkoxy, aryl, hetaryl, aryloxy, acylamido, alkylsulfonamido, or arylsulfonamido; andn is a positive integer from 1 to 5; andsaid cyan dye having the formula: ##STR2## wherein R.sup.4 R.sup.5 represents hydrogen, alkyl, cycloalkyl, aryl or hetaryl;R.sup.6 represents hydrogen, alkyl or alkoxy;R.sup.5 may be taken together with R.sup.
    Type: Grant
    Filed: May 26, 1989
    Date of Patent: December 4, 1990
    Assignee: Eastman Kodak Company
    Inventors: Helmut Weber, Steven Evans
  • Patent number: 4968797
    Abstract: 4,4-diaryldihydroquinazolones of the formula ##STR1## wherein X.sup.1, X.sup.2 and X.sup.3, independently of one another, denote hydrogen, halogen, alkyl, aryl, alkanoylamino, aroylamino, heteryl, NY.sup.1 Y.sup.2, OY.sup.3 or SY.sup.3, at least one of the radicalsX.sup.1, X.sup.2 or X.sup.3 standing for NY.sup.1 Y.sup.2, OY.sup.3 or SY.sup.3,R.sup.1 denotes hydrogen, alkyl, cycloalkyl, aralkyl, aryl or the members of a bridge to the o-carbon of ring C,R.sup.2 denotes a radical of an acid,Y.sup.1, Y.sup.2 and Y.sup.3, independently of one another, denote hydrogen, alkyl, cycloalkyl, aralkyl aryl or heteryl or the remaining members of a 5- or 6-membered ring which reaches to one of the o-position benzene C atoms and may contain further hetero atoms orY.sup.1 +Y.sup.
    Type: Grant
    Filed: October 30, 1987
    Date of Patent: November 6, 1990
    Assignee: Bayer Aktiengesellschaft
    Inventors: Horst Berneth, Alfred Brack, Karlheinrich Meisel
  • Patent number: 4950501
    Abstract: A method of making a thermal-transfer ribbon for thermal printing in which an aqueous dispersion of the thermoplastic binder substance, a fat-soluble dyestuff and a wax or waxlike substance is formed. The dispersion is coated onto a foil or other carrier for the ribbon and water is evaporated. The coating is then subjected to a thermal treatment to melt the wax and dissolve the dyestuff therein prior to thermotransfer to a substrate.
    Type: Grant
    Filed: August 19, 1988
    Date of Patent: August 21, 1990
    Assignee: Pelikan Aktiengesellschaft
    Inventor: Albert Schmedes
  • Patent number: 4939063
    Abstract: A light-sensitive material comprising a light-sensitive layer containing silver halide, a reducing agent and an ethylenic unsaturated polymerizable compound provided on a paper support. The paper support comprises a coating layer containing a hydrocarbon resin provided on a base paper sheet, and the paper support has a low water absorptiveness of not more than 1 g/m.sup.2 on the surface of the coating layer on which the light-sensitive layer is provided. The water absorptiveness being a value measured according to the Cobb test method.
    Type: Grant
    Filed: June 17, 1988
    Date of Patent: July 3, 1990
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Shigehisa Tamagawa, Masayuki Kuroishi
  • Patent number: 4927666
    Abstract: A heat transferable sheet for use in combination with a heat transfer sheet comprises a substrate, an image-receiving layer provided thereon, and optionally a layer of a mold releasing agent provided on at least a part of the image-receiving layer. This heat transferable sheet exhibits good mold releasability and also provides a colored image having a high density, resolving power and continuous gradation.
    Type: Grant
    Filed: December 13, 1988
    Date of Patent: May 22, 1990
    Assignee: Dai Nippon Insatsu Kabushiki Kaisha
    Inventors: Sadanobu Kawasaki, Mineo Yamauchi, Masanori Akada
  • Patent number: 4902364
    Abstract: A metallized laminate and process of manufacture wherein a metallic layer or underlying ink layer appears in a pattern on the laminate. The method in a specific embodiment involves the steps of forming a laminate by coating a heat stable release coat onto a carrier sheet; coating an ink layer in a pattern on the heat stable release coating so that at least portions of the release coat remain uncovered with ink, and applying a metallic layer over the release coat so that at least a portion of the metallic layer is in direct contact with and adheres directly to the release coat. Portions of the metallic layer may be removed by an etchant. A heat activatable adhesive layer is applied over the metallic layer. The laminate so formed is heat transferable from the carrier sheet to an article.
    Type: Grant
    Filed: August 2, 1988
    Date of Patent: February 20, 1990
    Assignee: Dennison Manufacturing Company
    Inventors: Tim Parker, Dennis R. Benoit
  • Patent number: 4873167
    Abstract: The disclosed is a cleaning sheet comprising second microcapsules, which encapsulate a solvent dissolvable of a photo-curable material, so that any radiation curable material sticking to a surface of a pressure roller member of a transfer imaging system will be efficiently cleaned away, thereby maintaining a constantly smooth surface of the pressure member which can then apply pressure onto the photo-pressure sensitive sheet uniformly, resulting in a unblemished transmittance of the original image.
    Type: Grant
    Filed: March 8, 1988
    Date of Patent: October 10, 1989
    Assignee: Brother Kogyo Kabushiki Kaisha
    Inventor: Yuji Asano
  • Patent number: 4847110
    Abstract: A transfer recording medium comprising a substrate and a plurality of image forming elements bonded thereto by a binder is provided. The surface of each image forming element at least partially protrudes out of the binder. Such transfer recording medium may be prepared by applying the binder onto the substrate in a prescribed thickness, disposing the image forming elements in excess on the binder, and then removing the excess of the image forming elements. The thus prepared transfer recording medium provides an image having a high density and a faithfully reproducible color.
    Type: Grant
    Filed: September 9, 1987
    Date of Patent: July 11, 1989
    Assignee: Canon Kabushiki Kaisha
    Inventors: Kazuhiro Nakajima, Toshiharu Inui, Noriyoshi Ishikawa, Masashi Miyagawa
  • Patent number: 4840833
    Abstract: The object of the present invention is to provide a new ink composition and a reproducing material without using any pigment, capable of drawing or reproducing clear white colored letters or patterns on a sheet of black or dark colored paper, cloth, leather or the like, and the letters or patterns drawn or reproduced are easily erasable with the application of water when they become unnecessary. The ink composition of the present invention comprises a white colored water soluble aliphatic sulfate as a coloring matter. The white colored water soluble aliphatic sulfate which can be used in the present invention includes, alkali-salt of lauryl sulfate, myristil sulfate, cetyl sulfate, stearil sulfate and the like, of which alkali-salt includes sodium, potassium, lithium and the like. As the liquid ink composition, a powder of the white colored water soluble aliphatic sulfate is dispersed in a monohydric alcohol.
    Type: Grant
    Filed: February 18, 1988
    Date of Patent: June 20, 1989
    Assignee: Adger Kogyo Co., Ltd.
    Inventor: Zenshiro Iijima
  • Patent number: 4839338
    Abstract: A thermal transfer printing (TTP) receiver sheet has a release medium containing a particulate adjuvant.
    Type: Grant
    Filed: April 19, 1988
    Date of Patent: June 13, 1989
    Assignee: Imperial Chemical Industries PLC
    Inventor: Richard A. Marbrow
  • Patent number: 4824691
    Abstract: Imaged microcapsule-coated paper, e.g. pressure-sensitive copying paper, is produced by imaging paper by means of laser energy and then applying a coating of microcapsules over the image. The image may be a manufacturer's name, logo or trademark, and may be applied at high speed on the paper machine on which the paper is produced or on the coating machine used to apply the microcapsule coating.
    Type: Grant
    Filed: March 25, 1987
    Date of Patent: April 25, 1989
    Assignee: The Wiggins Teape Group Limited
    Inventor: Leslie Townsend
  • Patent number: 4820551
    Abstract: A reusable thermocolor ribbon for thermal transfer printing is described comprising a layer of a melt-applied color on one side of a plastic foil as carrier, where the melt-applied color contains a wax or wax-like substance, a pigment and an organic binder. A coating liquid which contains a thermoplastic binding agent in solution and the meltable wax or wax-like substance in finely dispersed solid form, is applied to the carrier of the thermocolor ribbon, where the coating liquid represents as solvent agent a mixture of a solvent and non-solvent for the thermoplastic binding agent at room temperature. The non-solvent/solvent mixture is evaporated while simultaneously its solvent capability for the plastic binding agent is reduced. This thermocolor ribbon can be used more than 20 times without impairment of the print quality. A process for preparing the thermocolor ribbon is also detailed herein.
    Type: Grant
    Filed: February 3, 1987
    Date of Patent: April 11, 1989
    Assignee: Pelikan Akteingesellschaft
    Inventors: Heinrich Krauter, Albert Schmedes, Norbert Mecke, Wieland Kuchenreuther
  • Patent number: 4818591
    Abstract: There is disclosed a thermal transfer recording medium comprising a support, a layer containing an aqueous emulsion of a heat-fusible substance provided on the support and at least one colorant layer comprising an aqueous emulsion of a thermoplastic resin and a colorant provided on the layer containing an aqueous emulsion of a heat-fusible substance, the colorant layer having a film thickness of not more than 2 .mu.m.
    Type: Grant
    Filed: September 30, 1986
    Date of Patent: April 4, 1989
    Assignee: Konishiroku Photo Industry Co., Ltd.
    Inventors: Shegehiro Kitamura, Masao Asano, Yoshiaki Shimizu, Takao Abe
  • Patent number: 4816344
    Abstract: A method for the preparation of a fluorescent ink layer for a fluorescent thermal transfer sheet is disclosed. The method comprises first forming a solution of a mixture comprising at least one acidic monomer, at least one basic monomer and at least one fluorescent dye. Thereafter, an emulsion of the solution is formed and the emulsion is polymerized.
    Type: Grant
    Filed: December 10, 1986
    Date of Patent: March 28, 1989
    Assignee: Pitney Bowes Inc.
    Inventor: Albert C. Chiang
  • Patent number: 4785048
    Abstract: An improved process for the production of microcapsules by the use of hydrogen transfer polymerization in the presence of a mixture of emulsifiers including either an aqueous solution of a sodium salt of naphthalene-sulfonic acid-formaldehyde condensate or diphenyloxide disulfonate with a polyvinyl alcohol. The process is particularly useful for the production of microcapsules containing a colorless dye intermediate used in carbonless copy paper (CCP) applications.
    Type: Grant
    Filed: February 8, 1988
    Date of Patent: November 15, 1988
    Assignee: Moore Business Forms, Inc.
    Inventor: Hung-Ya Chao
  • Patent number: 4778782
    Abstract: A heat transferable sheet which is to be used in combination with a heat transfer sheet, comprising (a) a substrate sheet and (b) a receptive layer formed on at least one surface of the substrate sheet for receiving dye which has migrated from said heat transfer sheet during heating printing, characterized in that said substrate sheet comprises a laminate having a synthetic paper laminated on at least one surface of a core material and said receptive layer is provided directly or over an intermediate layer on the surface of the substrate sheet on the side where the synthetic paper exists.
    Type: Grant
    Filed: February 25, 1987
    Date of Patent: October 18, 1988
    Assignee: Dai Nippon Insatsu Kabushiki Kaisha
    Inventors: Yoshikazu Ito, Masanori Akada, Hitoshi Arita
  • Patent number: 4777159
    Abstract: The dye transfer type thermal printing sheet and method for printing of this invention are a printing sheet comprising a transfer sheet in which a smooth heat-resistant layer composed of fine particles, a liquid lubricating material and a polymer is formed on one side of a substrate, and on the other side is formed a coloring material layer containing at least one sublimable dye, non-sublimable particles and a binder, a part of said non-sublimable particles jutting out from the reference surface of the sublimable dye layer; and an image-receiving sheet having, on a substrate for image-receiving sheet, a development layer composed of, at least, inorganic fine particles; a binder having dye-affinity and another binder immiscible with said binder; and a dye transfer type thermal method for printing which comprises placing the aforesaid coloring material layer and development layer of the above-mentioned printing sheet face to face with each other, heating the printing sheet selectively from the smooth heat-resis
    Type: Grant
    Filed: April 30, 1985
    Date of Patent: October 11, 1988
    Assignees: Matsushita Electric Industrial Co., Ltd., Mitsubishi Chemical Industries Limited
    Inventors: Nobuyoshi Taguchi, Akihiro Imai, Toshio Niwa, Yukichi Murata
  • Patent number: 4775658
    Abstract: A dye-receiving sheet for thermal transfer printing which is used in combination with a dye transfer sheet and comprises a substrate and a dye-receiving layer formed on one side of the substrate. The dye-receiving layer is made of a dye-receiving resin matrix dispersing a mixture of a silane copolymer and colloidal silica particles which form strong network structures through silane coupling, and a releasing surface active agent.
    Type: Grant
    Filed: September 25, 1987
    Date of Patent: October 4, 1988
    Assignee: Matsushita Electric Industrial Co., Ltd.
    Inventors: Hiromu Matsuda, Nobuyoshi Taguchi, Akihiro Imai
  • Patent number: 4775657
    Abstract: A dye-receiving element for thermal dye transfer comprises a support having thereon a dye image-receiving layer, such as a polycarbonate, coated with an overcoat layer comprising a condensation polymer comprising recurring units of a linear chain having at least four carbon atoms, such as a polyester or a polyurethane, the overcoat layer having a T.sub.g of at least 40.degree. C. less than the T.sub.g of the dye image-receiving layer.Use of the overcoat layer of the invention helps to destratify the dye and improves stability of the transferred dyes to light.
    Type: Grant
    Filed: February 11, 1988
    Date of Patent: October 4, 1988
    Assignee: Eastman Kodak Company
    Inventors: Daniel J. Harrison, Paul D. Yacobucci, Kin K. Lum, David B. Bailey
  • Patent number: 4774224
    Abstract: A dye-receiving element for thermal dye transfer comprising a resin-coated paper support having thereon a polymeric dye image-receiving layer, the resin coating having a surface roughness measurement of 7.5 Ra microinches-AA or less.
    Type: Grant
    Filed: November 20, 1987
    Date of Patent: September 27, 1988
    Assignee: Eastman Kodak Company
    Inventor: Robert B. Campbell
  • Patent number: 4772532
    Abstract: A developer sheet having reduced tack useful in forming reproductions having a controllable gloss finish or in forming transparencies is provided. The developer sheet has a support with a layer on the surface of the support of a finely divided thermoplastic developer material and a non-reactive, non-scattering pigment. The developer material is capable of reacting with a color precursor to produce a visible image while the pigment reduces tack. Both the developer material and the pigment are capable of forming an essentially transparent film upon the application of heat and/or pressure.
    Type: Grant
    Filed: March 18, 1987
    Date of Patent: September 20, 1988
    Assignee: The Mead Corporation
    Inventors: Paul C. Adair, Cheryl L. Moore
  • Patent number: 4772582
    Abstract: A dye-donor element for laser-induced thermal dye transfer comprising a support having thereon a dye layer and an infrared-absorbing material, and wherein the dye layer has a layer coated thereover which contains spacer beads of such particle size and concentration that effective contact between the dye-donor element and a dye-receiving element is prevented during the laser-induced thermal dye transfer.
    Type: Grant
    Filed: December 21, 1987
    Date of Patent: September 20, 1988
    Assignee: Eastman Kodak Company
    Inventor: Charles D. DeBoer
  • Patent number: 4769360
    Abstract: A cyan dye-donor element for thermal dye transfer comprises a support having thereon a dye of cyan hue dispersed in a polymeric binder, the dye having the formula: ##STR1## wherein R.sup.1 and R.sup.2 are substituted or unsubstituted alkyl, cycloalkyl or aryl;R.sup.3 and R.sup.4 are hydrogen, substituted or unsubstituted alkyl, halogen, --NHCOR.sup.1 or --NHSO.sub.2 R.sup.1 ; andJ is --C.tbd.N, --Cl, --NHCOR.sup.1, --NHCO.sub.2 R.sup.1, --NHCONHR.sup.1, --NHCON(R.sup.1).sub.2, --SO.sub.2 NHR.sup.1, --NHSO.sub.2 R.sup.
    Type: Grant
    Filed: September 14, 1987
    Date of Patent: September 6, 1988
    Assignee: Eastman Kodak Company
    Inventors: Steven Evans, Helmut Weber
  • Patent number: 4769258
    Abstract: A multiple-time ink-bearing medium containing a thermally-transferable ink for thermal printing, produced in a process comprising: preparing a resin solution of a water-soluble resin comprising polyvinyl alcohol as a major constituent; preparing a fusible ink material consisting of a mixture which includes a solid fatty acid as a major constituent, a coloring agent, and a fusible agent having a low melting point; finely dispersing the ink material in the resin solution, so as to provide an ink-layer composition; applying the ink-layer composition to one surface of a substrate; and drying the applied ink-layer composition to form an ink layer on the substrate.
    Type: Grant
    Filed: September 5, 1985
    Date of Patent: September 6, 1988
    Assignee: Brother Kogyo Kabushiki Kaisha
    Inventors: Tetuo Kobayashi, Mikio Imaeda
  • Patent number: 4762734
    Abstract: An emulsion process for the preparation of thermal ink donor films which comprises (1) the addition of wax or soluble polymer components to a warm hydrocarbon solution; (2) adding thereto first additives that are soluble in the solution; (3) forming an emulsion thereof by adding the formed solution to an alcohol or a polar solvent, which may also contain dissolved second additives, grinding the resulting emulsion with a suitable pigment; (4) coating the product obtained on a supporting substrate; and (5) thereafter heating to enable evaporation of the hydrocarbon.
    Type: Grant
    Filed: November 24, 1986
    Date of Patent: August 9, 1988
    Assignee: Xerox Corporation
    Inventors: James M. Duff, Randolph E. Branston
  • Patent number: 4760049
    Abstract: Dyes are transferred from a substrate to a plastics-coated paper by sublimation or vaporization using a thermal printing head by using a substrate of which there are dyes of the formula ##STR1## where R.sup.1, R.sup.2, R.sup.3, R.sup.4 and R.sup.5 each have defined meanings.
    Type: Grant
    Filed: October 29, 1987
    Date of Patent: July 26, 1988
    Assignee: BASF Aktiengesellschaft
    Inventors: Karl-Heinz Etzbach, Ruediger Sens
  • Patent number: 4753921
    Abstract: A dye-donor element for thermal dye transfer comprising a support having on one side a dye layer and on the other side a subbing layer and a slipping layer comprising a lubricant dispersed in a binder, the subbing layer comprising a polymer having an inorganic backbone which is an oxide of a Group IVa or IVb element, such as a titanium or zirconium alkoxide, and the binder contains hydroxyl groups, such as a cellulosic binder.
    Type: Grant
    Filed: October 13, 1987
    Date of Patent: June 28, 1988
    Assignee: Eastman Kodak Company
    Inventor: Richard P. Henzel
  • Patent number: 4753920
    Abstract: A dye-donor element for thermal dye transfer comprising a support having on one side thereof a dye layer and on the other side a slipping layer comprising a lubricating material dispersed in a polymeric binder, the lubricating material comprising a linear or branched aminoalkyl-terminated poly(dialkyl, diaryl or alkylaryl siloxane) such as an aminopropyldimethyl-terminated polydimethylsiloxane and said polymeric binder comprises cellulose acetate propionate, cellulose nitrate or cellulose acetate hydrogen phthalate. The particular binders used minimize sticking and dye crystallization when the dye-donor element is wound up upon itself.
    Type: Grant
    Filed: October 13, 1987
    Date of Patent: June 28, 1988
    Assignee: Eastman Kodak Company
    Inventor: Noel R. Vanier
  • Patent number: 4754034
    Abstract: 4,4-diaryldihydroquinazolones of the formula ##STR1## wherein X.sup.1, X.sup.2 and X.sup.3, independently of one another, denote hydrogen, halogen, alkyl, aryl, alkanoylamino, aroylamino, heteryl, NY.sup.1 Y.sup.2, OY.sup.3 or SY.sup.3, at least one of the radicals X.sup.1, X.sup.2 or X.sup.3 standing for NY.sup.1 Y.sup.2, OY.sup.3 or SY.sup.3,R.sup.1 denotes hydrogen, alkyl, cycloalkyl, aralkyl, aryl or the members of a bridge to the o-carbon of ring C,R.sup.2 denotes a radical of an acid,Y.sup.1, Y.sup.2 and Y.sup.3, independently of one another, denote hydrogen, alkyl, cycloalkyl, aralkyl aryl or heteryl or the remaining members of a 5- or 6-membered ring which reaches to one of the o-position benzene C atoms and may contain further hetero atoms orY.sup.1 +Y.sup.
    Type: Grant
    Filed: October 21, 1985
    Date of Patent: June 28, 1988
    Assignee: Bayer Aktiengesellschaft
    Inventors: Horst Berneth, Alfred Brack, Karlheinrich Meisel
  • Patent number: 4753922
    Abstract: A neutral-black dye-donor element for thermal dye transfer comprises a support having thereon a dye dispersed in a polymeric binder, the dye comprising a 1-((4-phenylazo)phenylazo)-8-amino-2-naphthol, such as one having the formula: ##STR1## wherein: each R.sup.1 is independently a substituted or unsubstituted alkyl group of from 1 to about 6 carbon atoms, a substituted or unsubstituted aryl group of from about 5 to about 10 carbon atoms, or two R.sup.1 groups may be joined together with the N atom to which they are attached to form a 5- or 6-membered heterocyclic ring; andR.sup.2 is hydrogen or R.sup.1.
    Type: Grant
    Filed: November 20, 1987
    Date of Patent: June 28, 1988
    Assignee: Eastman Kodak Company
    Inventors: Gary W. Byers, Derek D. Chapman, Michael J. McManus
  • Patent number: 4753923
    Abstract: A dye-donor element for thermal dye transfer comprising a support having on one side thereof a near-infrared absorbing dye comprising a dithiolene-nickel(II) complex dispersed in a polymeric binder, and on the other side thereof a slipping layer comprising a lubricant, the dye having the formula: ##STR1## wherein each R.sup.1, R.sup.2, R.sup.3 and R.sup.4 independently represents a substituted or unsubstituted alkyl group having from 1 to about 10 carbon atoms; a substituted or unsubstituted aryl group having from about 6 to about 10 carbon atms; a substituted or unsubstitutted heterocyclic group; or R.sup.1 and R.sup.2 may be combined together with the carbon atoms to which they are attached to form a 5- or 6-membered carbocyclic or heterocyclic ring; or R.sup.3 and R.sup.4 may be combined together with the carbon atoms to which they are attached to form a 5- or 6-membered carbocyclic or heterocyclic ring.
    Type: Grant
    Filed: November 20, 1987
    Date of Patent: June 28, 1988
    Assignee: Eastman Kodak Company
    Inventors: Gary W. Byers, Derek D. Chapman
  • Patent number: 4748150
    Abstract: A dye-receiving element for thermal dye transfer comprises a support, such as polyethylene-coated paper or poly(ethylene terephthalate), having thereon a subbing layer of a vinylidene chloride copolymer and a polymeric dye image-receiving layer, such as a polycarbonate.Use of the subbing layer of the invention improves the adhesion of the dye image-receiving layer to the support.
    Type: Grant
    Filed: September 15, 1987
    Date of Patent: May 31, 1988
    Assignee: Eastman Kodak Company
    Inventors: Noel R. Vanier, Kin K. Lum
  • Patent number: RE33819
    Abstract: A magenta dye-donor element for thermal dye transfer comprises a support having thereon a magenta dye dispersed in a polymeric binder, the magenta dye comprising a substituted 5-arylazoisothiazole.In a preferred embodiment, the magenta dye has the formula ##STR1## wherein R.sup.1 and R.sup.2 may each independently be hydrogen, alkyl, allyl, cycloalkyl or aryl; or R.sup.1 and R.sup.2 may be taken together to form a ring; or R.sup.1 or R.sup.2 may be part of a 5- or 6-membered heterocyclic ring;R.sup.3 may be hydrogen, alkyl, aryl, alkylthio or halogen;J may be alkyl, aryl or NHA, where A is an acyl or sulfonyl radical; andQ may be cyano, thiocyanato, alkylthio or alkoxycarbonyl.
    Type: Grant
    Filed: March 17, 1989
    Date of Patent: February 11, 1992
    Assignee: Eastman Kodak Company
    Inventors: William H. Moore, Max A. Weaver, Kin K. Lum