Heterocyclic Organic Compound Component Patents (Class 427/151)
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Patent number: 4612558Abstract: A fluoran compound having the formula: ##STR1## wherein each of R.sub.1 and R.sub.2 is a hydrogen atom, a straight chain or branched alkyl group having from 1 to 8 carbon atoms, a cyclohexyl group, a substituted or unsubstituted phenyl group, or a substituted or unsubstituted benzyl group, Q is ##STR2## (wherein X is a hydrogen atom, a halogen atom, or a straight chain or branched alkyl group having from 1 to 8 carbon atoms), ##STR3## (wherein X is as defined above), or --(CH.sub.2).sub.n OR.sub.4 (wherein R.sub.4 is a straight chain or branched alkyl group having from 1 to 8 carbon atoms, a cycloalkyl group, a substituted or unsubstituted phenyl group, or a substituted or unsubstituted benzyl group, and n is an integer of from 1 to 8), and R.sub.3 is a hydrogen atom, a halogen atom, a lower fluoroalkyl group, an acyl group, an alkoxy group, an alkoxyalkyl group, or a straight chain or branched alkyl group having from 1 to 8 carbon atoms.Type: GrantFiled: March 12, 1985Date of Patent: September 16, 1986Assignee: Hodogaya Chemical Co., Ltd.Inventors: Mitsutoshi Anzai, Masahiko Yamaguchi, Kazuyuki Wakasugi, Susumu Suzuka, Michihiro Gonda, Toshiyuki Abe, Katsumasa Kikkawa, Mikiko Kanasugi
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Patent number: 4609928Abstract: A thermosensitive image transfer medium consisting of (i) an image transfer sheet having an image transfer layer consisting essentially of a leuco dye, and (ii) an acceptor sheet having an acceptor layer consisting essentially of a color developer which induces color formation in the leuco dye, the color developer being a mixture of a bisphenol derivative of the following formula and a p-hydroxybenzoic acid ester with a melting point of 100.degree. C. or less, and, of the image transfer layer and said acceptor layer, at least one layer containing a porous filler having an oil absorption of 50 ml/100 g or more as measured in accordance with the Japanese Industrial Standard K 5101, ##STR1## wherein X.sup.1 and X.sup.2 each represent a lower alkyl group or halogen, R.sup.1 and R.sup.2 each represent hydrogen or an alkyl group having 1 to 6 carbon atoms, and m and n each represent an integer of 0 through 4.Type: GrantFiled: December 13, 1983Date of Patent: September 2, 1986Assignee: Ricoh Company, Ltd.Inventors: Keishi Kubo, Nobuhiro Takigawa, Eiichi Kawamura
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Patent number: 4608579Abstract: A thermosensitive recording material comprising a support material and a thermosensitive coloring layer formed thereon, in which thermosensitive coloring layer, colored images are formed by the reaction between a colorless or light-colored leuco dye and a color developer of the following formula capable of inducing color formation in the leuco dye upon application of heat thereto, ##STR1##Type: GrantFiled: May 22, 1985Date of Patent: August 26, 1986Assignee: Ricoh Company, Ltd.Inventor: Keishi Taniguchi
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Patent number: 4605940Abstract: There is provided a thermoresponsive paper sheet comprising a normally colorless or pale-colored chromogenic substance in combination with a phenolic compound and the underlying paper substrate, said sheet further comprises a diether of the formula: ##STR1## wherein R.sup.4 is alkyl of 1 to 5 carbon atoms, benzyl or phenethyl.Type: GrantFiled: September 11, 1984Date of Patent: August 12, 1986Assignee: Yoshitomi Pharmaceutical Industries, Ltd.Inventors: Ryoichi Kinishi, Eisaburo Kaku, Naoki Hanayama
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Patent number: 4602264Abstract: In a recording material producing images due to a complex formed from an organic phosphorus-iron compound having a bond of PO.sup.- and/or PS.sup.- with Fe.sup.3+ in the molecule and a ligand compound which reacts with the organic phosphorus-iron compound, the present recording material is characterized in that (a) a colorless or light-colored oil-soluble and/or heat-fusible organic compound adheres to the surface of the organic phosphorus-iron compound and/or (b) an organic base is present out of contact with the organic phosphorus-iron compound. The present invention also provides a desensitizer comprising at least one compound selected from the group consisting of (a) organic phosphorus compounds having a bond of P--OH and/or P--SH, (b) organic compounds having an aminocarboxyl group and (c) salts of these compounds (a) and (b).Type: GrantFiled: August 11, 1983Date of Patent: July 22, 1986Assignee: Kanzaki Paper Manufacturing Co., Ltd.Inventors: Shunshuke Shioi, Gensuke Matoba, Makoto Miyake
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Patent number: 4600930Abstract: The recording material which reacts under the influence of heat contains an acid-modified polymer of acrylonitrile as an acceptor, in addition to a dyestuff precursor.Type: GrantFiled: October 5, 1984Date of Patent: July 15, 1986Assignee: Bayer AktiengesellschaftInventor: Hubertus Psaar
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Patent number: 4597793Abstract: In a desensitizing ink for the wet offset printing of a given area of the acceptor surface of a duplicating set containing an alkoxylated nucleophilic compound, preferably having a molecular weight lying in the range of from 2000 to 4000 and having a hydrophilic-lipophilic balance (HLB) of from 3 to 6, emulsified water is added to the mass of ink.This rapidly forms a fine stable emulsion of water in the ink which is favorable for continuous wet offset printing.Type: GrantFiled: March 4, 1983Date of Patent: July 1, 1986Assignee: Sicpa Holding S.A.Inventors: Albert Amon, Roger M. Weil
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Patent number: 4597993Abstract: Disclosed herein are a recording paper which is partially pressure-sensitized, comprising microcapsules containing a solution of a colorless color former, sheet material and binder, the microcapsules being fixed to a specified part of a surface of the sheet material via the binder painted on the specified part and majority of the fixed microcapsules having at least a part of the microcapsule exposed to outside of the binder, and a process for producing the recording paper which is partially specified.Type: GrantFiled: October 15, 1984Date of Patent: July 1, 1986Assignee: Kureha Kagaku Kogyo Kabushiki KaishaInventors: Yoshio Okada, Yuriko Igarashi
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Patent number: 4594269Abstract: A thermosensitive recording paper consisting of a dye precursor and a color developer capable of coloring said dye precursor on heating, wherein one type of overcoat layer selected from the group consisting of alginates, alumina sol, colloidal silica and a mixture of alumina sol with colloidal silica is provided as the topmost layer thereof to give improved chemical resistance and good printing quality with a reduced deterioration in sensitivity and no residues and sticking.Type: GrantFiled: March 14, 1983Date of Patent: June 10, 1986Assignee: Mitsubishi Paper Mills, Ltd.Inventors: Masahiro Miyauchi, Sadao Morishita, Fumio Okumura, Masahiro Higuchi
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Patent number: 4591888Abstract: Heat-sensitive recording sheet comprising a base sheet a color-forming layer including a colorless basic dyestuff and an organic color-developing agent, wherein said color-forming layer comprises a metal salt derivative of nitrobenzoic acid (having a particular formula). The sheet provides superior stability against contamination with oily substances while keeping excellent fundamental qualities thereof.Type: GrantFiled: September 14, 1984Date of Patent: May 27, 1986Assignee: Jujo Paper Co., Ltd.Inventors: Toshimi Satake, Toshiaki Minami, Fumio Fujimura
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Patent number: 4590497Abstract: A thermosensitive recording label includes a thermosensitive color-forming layer disposed on one side of a substrate and a heat reflecting layer disposed on another side of the substrate and a delayed action adhesive disposed on the heat reflecting layer. The thermosensitive recording label may be manufactured and used without a backing sheet, thus considerably reducing the weight and volume of the label. In use, the thermosensitive recording label is drawn from a roll or stack and the delayed action adhesive activated by a heat lamp, or the like, to place it in a tacky condition for placement on goods. The heat reflecting layer disposed between the delayed action adhesive and the thermosensitive color-forming layer prevents activation of the color-forming layer during heating of the delayed action adhesive.Type: GrantFiled: November 5, 1984Date of Patent: May 20, 1986Assignee: Ricoh Electronics, Inc.Inventors: Tomoo Shibata, Wissam J. Jurdi, Minoru Nomura
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Patent number: 4590500Abstract: Heat-sensitive recording sheet comprising a base sheet and a color-forming layer including a colorless basic dyestuff and an organic color-developing agent, wherein said color-forming layer comprises a metal derivative of phthalic acid monoester (having a particular formula). The sheet provides superior stability against contamination with oily substances while keeping excellent fundamental qualities thereof.Type: GrantFiled: August 21, 1984Date of Patent: May 20, 1986Assignee: Jujo Paper Co., Ltd.Inventors: Toshimi Satake, Yoshihide Kimura, Fumio Fujimura
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Patent number: 4590499Abstract: Heat-sensitive recording sheet comprising a heat-sensitive color developing layer having particular chemicals on the support sheet and an overcoat layer laminated thereon and a backcoat layer on the back of the support sheet, wherein the sheet provides excellent coloring characteristics and high stability in storage.Type: GrantFiled: August 5, 1985Date of Patent: May 20, 1986Assignee: Jujo Paper Co., Ltd.Inventors: Fumio Fujimura, Toshimi Satake, Manabu Mori, Toshiaki Minami, Tadakazu Fukuchi
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Patent number: 4590498Abstract: Chromogenic recording materials which utilizes a fluoran compound of the formula ##STR1## wherein R is methyl or ethyl, is described.Type: GrantFiled: February 23, 1984Date of Patent: May 20, 1986Assignee: Shin Nisso Kako Co., Ltd.Inventors: Masakichi Yahagi, Tetsuo Igaki, Sinzi Yosinaka, Kousaku Morita, Morikuni Saito, Kimiaki Kinoshita
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Patent number: 4587537Abstract: In a heat-sensitive recording sheet having a heat-sensitive coating layer comprising a colorless to light-colored dye precursor as color former and benzyl p-hydroxybenzoate as color developer which causes said dye precursor to develop a color by reacting with said dye precursor when heated, the color development sensitivity of said sheet particularly at low temperatures is enhanced by allowing said heat-sensitive coating layer to further comprise a terephthalic acid ester having a melting point of 60.degree. C. or higher and a wax having a melting point of 60.degree. C. or higher.Type: GrantFiled: May 13, 1983Date of Patent: May 6, 1986Assignee: Mitsubishi Paper Mills, Ltd.Inventors: Masahiro Miyauchi, Masahiro Higuchi
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Patent number: 4587538Abstract: Pressure sensitive record material uses a 2,3-disubstituted-1,2,3,4-tetrahydroquinazolin-4-ones of the formula (I): ##STR1## where R.sub.1 and R.sub.2 have defined meanings, as color formers. Preferred compounds of formula (I) are intense fade resistant and stable yellow color formers useful in making black copy formulations.Type: GrantFiled: November 2, 1984Date of Patent: May 6, 1986Assignee: The Wiggins Teape Group LimitedInventors: Kenneth J. Shanton, Farid Azizian
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Patent number: 4587539Abstract: Chromogenic azaphthalides of the formula ##STR1## wherein R.sub.1 and R.sub.2 independently of each other are hydrogen, C.sub.1 -C.sub.12 alkyl which is unsubstituted or substituted by halogen, hydroxyl, cyano or lower alkoxy, or are cycloalkyl, benzyl or phenyl, or benzyl or phenyl which are substituted by halogen, nitro, cyano, lower alkyl, lower alkoxy or lower alkoxycarbonyl; or R.sub.1 and R.sub.2 together with the nitrogen atom to which they are attached are a 5-membered or 6-membered heterocyclic radical and in particular pyrrolidinyl;X is hydrogen, halogen, lower alkyl, lower alkoxy, benzyl, phenyl, benzyloxy, phenoxy, or benzyl or benzyloxy which are substituted by halogen, nitro, lower alkyl or lower alkoxy;Y is C.sub.6 -C.sub.Type: GrantFiled: January 9, 1985Date of Patent: May 6, 1986Assignee: Ciba-Geigy CorporationInventors: Davor Bedekovic, Ian J. Fletcher
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Patent number: 4586061Abstract: A thermally-sensitive color-forming composition is disclosed which comprises chromogenic material and certain acidic developer material. Record material comprising this color-forming composition exhibits improved color-forming efficiency and/or image density.Type: GrantFiled: May 13, 1985Date of Patent: April 29, 1986Assignee: Appleton Papers Inc.Inventor: Kenneth D. Glanz
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Patent number: 4585483Abstract: A recording material is disclosed which contains an electron donating colorless dye and an electron accepting compound. The electron accepting compound is an aromatic compound having a substituted or unsubstituted sulfamoyl group and a hydroxyl group as substituents. The recording material can provide high density images which provide sufficient fastness during storage.Type: GrantFiled: May 21, 1984Date of Patent: April 29, 1986Assignee: Fuji Photo Film Co., Ltd.Inventors: Kensuke Ikeda, Ken Iwakura, Masato Satomura
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Patent number: 4583104Abstract: A recording material composed of an electron donating colorless dye and electron accepting compound is disclosed. The electron accepting compound is a phenol or naphthol compound having, as a substituent, an aryloxysulfonyl group which can be substituted or an alkoxysulfonyl group which can be substituted. The resulting material provides sufficient color density and strong color fastness by coloration reaction.Type: GrantFiled: September 5, 1984Date of Patent: April 15, 1986Assignee: Fuji Photo Film Co., Ltd.Inventors: Ken Iwakura, Masato Satomura, Takekatsu Sugiyama
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Patent number: 4580153Abstract: A record material utilizing the color forming reaction between a substantially colorless chromogenic material and an electron accepting reactant material is disclosed. The colorless chromogenic material used comprises a mixture of the first component consisting of at least one specified phthalide compound having two vinyl linkages and the second component of another kind of chromogenic material which is different from said first component. The first component of the chromogenic material is used in an amount of 5 to 80%, preferably 7 to 50%, by weight with respect to the amount of the second component and in such an amount that the reflectance at any wavelength within the range of 580 nm to 880 nm, preferably within the range of 500 to 880 nm of color images developed by said color forming reaction is less by at least 55% than that of said record material before color developing.Type: GrantFiled: July 24, 1984Date of Patent: April 1, 1986Assignee: Kanzaki Paper Manufacturing Co., Ltd.Inventors: Mitsuru Kondo, Nobuo Kanda, Akio Noguchi, Yukio Takayama
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Patent number: 4578340Abstract: Imaging sheets having a coating containing chromogenic material and a photosensitive composition, with at least the photosensitive composition encapsulated in rupturable microcapsules as an internal phase, are processed by free particle abrasion to rupture the microcapsules coating the surfaces of the imaging sheets by establishing relative motion between the imaging sheets and a body of free particles.Type: GrantFiled: November 13, 1984Date of Patent: March 25, 1986Assignee: The Mead CorporationInventors: Edward J. Saccocio, T. Kay Kiser, Richard F. Wright, Donald L. Head
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Patent number: 4578690Abstract: Disclosed is a recording sheet comprising a support having a layer of color developer capable of reacting with oil-soluble, basic, chromogenic dyes to produce rapidly a mark of improved color intensity and improved fade resistance. In addition to the conventionally used constituents such as binders, whitening agents, and fillers, the coating comprises (a) a phenol-formaldehyde condensate oligomer mixture, (b) an aromatic carboxylic acid, and (c) an inorganic magnesium compound, preferably magnesium oxide or magnesium hydroxide. Best results are obtained when components a, b, and c are present at ratios of 50 parts oligomer, 1.0-2.5 parts acid, and 10-40 parts magnesium compound.Type: GrantFiled: August 13, 1984Date of Patent: March 25, 1986Assignee: Nashua CorporationInventors: Norman T. Veillette, Robert J. Malik
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Patent number: 4576831Abstract: A process for producing a heat-sensitive recording paper is disclosed. The process involves pretreating base paper by a high-frequency corona discharge. The base paper treated in this manner can be utilized in producing a heat-sensitive recording material by providing a heat-sensitive layer thereon. By subjecting the base paper to the high-frequency corona discharge treatment the base paper can be uniformly coated with a heat-sensitive recording material without leaving any blank spaces thereon.Type: GrantFiled: August 23, 1983Date of Patent: March 18, 1986Assignee: Fuji Photo Film Co., Ltd.Inventors: Noriyuki Hosoi, Kensuke Ikeda, Hiroharu Matsukawa
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Patent number: 4575734Abstract: A thermosensitive image transfer medium consisting of (i) an image transfer sheet having an image transfer layer consisting essentially of a leuco dye, and (ii) an acceptor sheet having an acceptor layer consisting essentially of a coloring agent with a melting point of not higher than 200.degree. C., which induces color formation in the leuco dye, and, of the image transfer layer and the acceptor layer, at least one layer containing a particular image transfer auxiliary agent for facilitating image formation on the acceptor sheet.Type: GrantFiled: July 27, 1983Date of Patent: March 11, 1986Assignee: Ricoh Company, Ltd.Inventors: Norio Kurisu, Keishi Kubo
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Patent number: 4574294Abstract: Record material of the type in which the color forming reaction is between an electron donating chromogenic material and an electron accepting color developer uses one or more metal/oximes as the color developer. Preferred oximes are monoximes, especially salicylaldoxime and its ring substituted derivatives, and dioximes such as dimethylglyoxime and mioxime and the preferred metal is zinc. Metal oximate salts can be used especially the salicylaldoximate, diphenylglyoximate and benzaldoximates of zinc.Type: GrantFiled: June 15, 1984Date of Patent: March 4, 1986Assignee: The Wiggins Teape Group LimitedInventor: Kenneth J. Shanton
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Patent number: 4571605Abstract: A thermosensitive recording material which comprises a support material and a thermosensitive color-forming layer formed on the support material, comprising a colorless or light-colored leuco dye and a color developer capable of inducing color formation in the leuco dye upon application of heat thereto, is disclosed, in which the color developer is 4-hydroxydimethylphthalate or a first bisphenol derivative of the formula (I) ##STR1## wherein n is an integer of 1 or 2, and there is interposed between the support material and the thermosensitive color-forming layer an undercoated layer comprising a second bisphenol derivative of the formula (II), ##STR2## wherein X represents halogen, Y represents --SO.sub.2 --or-- ##STR3## m is an integer of 1 or 2, and the substitution positions of Xm in the benzene rings are symmetrical with respect to Y.Type: GrantFiled: November 9, 1984Date of Patent: February 18, 1986Assignee: Ricoh Company, LtdInventors: Takanori Motosugi, Hisashi Sakai
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Patent number: 4570170Abstract: In a thermosensitive recording material comprising a thermosensitive recording layer provided on a support and containing a usually colorless or light-color dye precursor and a color developer which reacts with the dye precursor when heated to effect color development of the dye precursor, the image keeping quality of the recording material can be improved by further containing in the thermosensitive recording layer a compound represented by the general formula: ##STR1## (wherein R.sub.1 and R.sub.2 represent an alkyl group or a halogen).Type: GrantFiled: September 28, 1984Date of Patent: February 11, 1986Assignee: Mitsubishi Paper Mills, Ltd.Inventors: Shigetoshi Hiraishi, Kazuyoshi Kondo
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Patent number: 4570171Abstract: 5-[N-(RCO)-N-R.sup.1 -amino] or (RCOO)-9-(N-R.sup.2 -N-R.sup.3 -amino)-12-(RCO)benzo[a]phenoxazines useful as color formers, particularly in electrochromic recording systems, are prepared by the interaction of the corresponding 5-(N-R.sup.1 -amino)-9-(N-R.sup.2 -N-R.sup.3 -amino)benzo[a]phenoxazinium halide or 9-(N-R.sup.2 -N-R.sup.3 -amino)benzo[a]phenoxazin-5-one with a reducing agent to obtain the corresponding leuco compound and subsequently interacting the leuco compound with at least two molecular proportions of an acylating agent.Type: GrantFiled: July 31, 1984Date of Patent: February 11, 1986Assignee: The Hilton-Davis Chemical Co.Inventor: William M. Hung
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Patent number: 4568956Abstract: A colorless, heat-sensitive and heat transfer recording sheet with pressure sensitivity comprising a base sheet, a heat-sensitive recording layer provided on one side of the base sheet and a heat transfer recording layer provided on the other side of the base sheet, the heat transfer recording layer being formed by coating on the base sheet a coating color comprising 3 to 20 parts by weight of microcapsules containing a colorless, electron-donating color former, 3 to 30 parts by weight of microcapsules containing a colorless, electron-accepting color developer, 3 to 30 parts by weight of a solid of a colorless, electron-donating, color former, 10 to 50 parts by weight of a solid of a colorless, electron-accepting, color developer and 25 to 200 parts by weight of a wax.Type: GrantFiled: February 11, 1985Date of Patent: February 4, 1986Assignee: Mitsubishi Paper Mills, Ltd.Inventors: Toshihiko Matsushita, Sadao Morishita, Mikiya Sekine
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Patent number: 4567496Abstract: A pressure-sensitive recording sheet is described. The sheet is comprised of a paper substrate which is treated with succinic acid derivatives having an alkenyl group or alkyl group containing from 4 to 18 carbon atoms, or salts thereof. This pressure-sensitive recording sheet is greatly reduced in the formation of fog which occurs in printing the sheet. Thus, it is very useful as no carbon paper.Type: GrantFiled: June 17, 1983Date of Patent: January 28, 1986Assignee: Fuji Photo Film Co., Ltd.Inventors: Yasuhiro Ogata, Masakazu Maekawa
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Patent number: 4567497Abstract: A heat-sensitive recording paper is described, comprising a paper support and a heat-sensitive color-forming layer on the paper support, wherein the paper support contains a cationic softening agent, such as a maleic anhydride copolymer/polyalkylenepolyamine reaction product. This recording paper is excellent both in highspeed recording and curling properties.Type: GrantFiled: March 5, 1985Date of Patent: January 28, 1986Assignee: Fuji Photo Film Co., Ltd.Inventors: Shigehisa Tamagawa, Tetsuro Fuchizawa
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Patent number: 4567498Abstract: Record material of the type in which the color forming reaction is between an electron donating chromogenic material and an electron accepting color developer uses one or more oximes as the color developer. Preferred oximes are monoximes, especially salicylaldoxime and its ring substituted derivatives, and dioximes such as dimethylglyoxime and mioxime.Type: GrantFiled: June 15, 1984Date of Patent: January 28, 1986Assignee: The Wiggins Teape Group LimitedInventor: Kenneth J. Shanton
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Patent number: 4562449Abstract: The invention relates to chromogenic dihydroquinazolines of the general formula: ##STR1## wherein: the ring A is a monocyclic or polycyclic, unsubstituted or substituted heterocyclic radical which may contain further heteroatoms as ring members,each of X.sub.1, X.sub.2 and Y independently of one another is hydrogen, halogen, lower alkyl, lower alkanoylamino, or a group of the formula ##STR2## X.sub.3 is hydrogen, halogen, lower alkyl or lower alkoxy; each of R.sub.1, R.sub.2, R.sub.3, R.sub.4, Z.sub.1 and Z.sub.2 independently of one another is C.sub.1 -C.sub.12 alkyl which is unsubstituted or substituted by halogen, hydroxyl, cyano or lower alkoxy, or is cycloalkyl, phenyl, or phenyl or benzyl each substituted by halogen, nitro, lower alkyl or lower alkoxy, and the radicals R may also be hydrogen; oreach pair of substituents (R.sub.1 and R.sub.2), (R.sub.3 and R.sub.4) and (Z.sub.1 and Z.sub.Type: GrantFiled: December 7, 1984Date of Patent: December 31, 1985Assignee: Ciba-Geigy CorporationInventors: Heinz Balli, Sigmund Gunzenhauser, Ian J. Fletcher, Davor Bedekovic
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Patent number: 4562448Abstract: A heat-sensitive transfer medium of this invention comprises the combination of a transfer sheet which has on one surface of a substrate a transfer layer consisted essentially of a leuco dye and a binder resin and is provided on its opposite surface with a 0.2-5 .mu.m-thick polyfluorocarbon-containing layer with a receiving sheet which is provided on the substrate with a receiving layer consisting essentially of a developer for the leuco dye and the binder resin, and further comprises adding a porous filler (oil absorption: 50-300 ml/100 g) to the receiving layer and/or the transfer layer.Type: GrantFiled: October 17, 1984Date of Patent: December 31, 1985Assignee: Ricoh Co., Ltd.Inventors: Hideo Watanabe, Minoru Hakiri, Kanjirou Kawasaki, Keishi Kubo, Nobuhiro Takigawa
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Patent number: 4561001Abstract: 3-(N-R.sup.2 -N-Acylamino)-7-(N-R.sup.3 -N-R.sup.4 -amino)-10-acylphenothiazines and phenoxazines useful as color formers, particularly in electrochromic recording systems, are prepared by the interaction of the corresponding 3-(N-R.sup.2 -amino)-7-(N-R.sup.3 -N-R.sup.4 -amino)phenothiazinium or phenoxazinium halide with a reducing agent to obtain the corresponding leuco compound and subsequently interacting the leuco compound with at least two molecular proportions of an acylating agent.Type: GrantFiled: July 31, 1984Date of Patent: December 24, 1985Assignee: The Hilton-Davis Chemical Co.Inventors: Michael B. Gunn, William M. Hung
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Patent number: 4558335Abstract: There is disclosed the use of benzyl 4-benzyloxybenzoate as a responsiveness-increasing agent in a thermoresponsive recording paper sheet comprising a normally colorless or pale-colored chromogenic substance in combination with a phenolic compound.Type: GrantFiled: March 11, 1982Date of Patent: December 10, 1985Assignee: Yoshitomi Pharmaceutical Industries, Ltd.Inventors: Naoki Hanayama, Eisaburo Kaku, Ryoichi Kinishi
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Patent number: 4555569Abstract: The invention relates to chromogenic quinazolines of the formula ##STR1## wherein Y is a polycyclic non-aromatic heterocyclic radical which is attached to the quinazoline moiety through a fused benzene nucleus and is unsubstituted or substituted, andZ is hydrogen, R, --OR.sub.1, --SR.sub.1 or --NR.sub.2 R.sub.3, whereinR and R.sub.1 are each alkyl which is unsubstituted or substituted by cyano or lower alkoxy, or are cycloalkyl, unsubstituted or substituted aryl or aralkyl or an unsubstituted or substituted heterocyclic radical, and R.sub.1 can also be haloalkyl,R.sub.2 and R.sub.3, each independently of the other, are hydrogen, alkyl which is unsubstituted or substituted by halogen, hydroxy, cyano or lower alkoxy, or are cycloalkyl, phenyl, benzyl, or phenyl or benzyl which are each substituted by halogen, nitro, cyano, lower alkyl, lower alkoxy or lower alkoxycarbonyl, and R.sub.2 can also be acyl; or R.sub.2 and R.sub.Type: GrantFiled: June 22, 1984Date of Patent: November 26, 1985Assignee: Ciba-Geigy CorporationInventors: Rudolf Zink, Ian J. Fletcher
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Patent number: 4554566Abstract: A heat-sensitive recording material is described, comprising a heat-sensitive recording layer containing an electron-donating colorless dye and an electron-accepting compound, said heat-sensitive layer being provided on a support member, and said heat-sensitive layer containing from 5 to 50% by weight, based on the total weight of the heat-sensitive layer-constituting components, of polymer particles having an average particle size of from 0.03 to 16 microns, selected from the group consisting of ethylene-.alpha.-olefin copolymer particles, low density polyethylene particles, and ethylene-vinyl acetate copolymer particles.Type: GrantFiled: September 21, 1984Date of Patent: November 19, 1985Assignee: Fuji Photo Film Co., Ltd.Inventors: Junichi Yoneda, Akira Igarashi
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Patent number: 4551740Abstract: 3-(R-Carbonyloxy)-7-(N-R.sup.1 -N-R.sup.2 -amino)-10-(RCO)-phenothiazines useful as color formers, particularly in electrochromic recording systems, are prepared by the interaction of the corresponding 7-(N-R.sup.1 -N-R.sup.2 -amino)phenothiazin-3-one with a reducing agent to obtain the corresponding leuco compound and subsequently interacting the leuco compound with about two molecular proportions of an acylating agent.Type: GrantFiled: July 31, 1984Date of Patent: November 5, 1985Assignee: The Hilton-Davis Chemical Co.Inventor: William M. Hung
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Patent number: 4550329Abstract: A heat sensitive record material comprising at least one colorless or light-colored electron donative dyestuff and at least one color developing agent represented by the general formula: ##STR1## where each of R.sub.1 and R.sub.2 is hydrogen atom, an alkyl group having from 1 to 5 carbon atoms, an alkoxy group having from 1 to 5 carbon atoms or a halogen atom, X is an alkyl group having from 1 to 5 carbon atoms or a halogen atom, Y is a hydroxyl group, an alkyl group having from 1 to 5 carbon atoms or a halogen atom, n is an integer of 1 to 3, and m is an integer of 1 to 4.Type: GrantFiled: August 31, 1984Date of Patent: October 29, 1985Assignee: Hodogaya Chemical Co., Ltd.Inventors: Michihiro Gonda, Katsumasa Kitsukawa, Susumu Suzuka, Mikiko Kanasugi, Yutaka Sato, Kikuo Otomo
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Patent number: 4549192Abstract: 4-(N-Acylamino)-8-(N--R.sup.1 --N--R.sup.2 -amino)imidazophenoxazines useful as color formers, particularly in electrochromic recording systems, are prepared by the interaction of the corresponding 1,3-diamino-7-(N--R.sup.1 --N--R.sup.2 -amino)phenoxazinium halide with a reducing agent to obtain the corresponding leuco compound and subsequently interacting the leuco compound with at least two molecular proportions of an acylating agent.Type: GrantFiled: July 31, 1984Date of Patent: October 22, 1985Assignee: The Hilton-Davis Chemical Co.Inventor: William M. Hung
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Patent number: 4547222Abstract: A liquid internal phase for use in encapsulated particles to produce high intensity marks includes an organic solvent having a specific amount of colorless chromogenic material and a larger amount of alkylated benzene material to yield a blue mark, and a specific amount of colorless chromogenic material and a lesser amount of alkylated benzene material to yield a black mark.Type: GrantFiled: May 21, 1984Date of Patent: October 15, 1985Assignee: NCR CorporationInventor: Nicola Marinelli
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Patent number: 4546365Abstract: A record member comprising a developer composition comprising a glass comprising a biphenol color developer and a resinous material is disclosed. These compositions are particularly useful as color developers for basic chromogenic material.Type: GrantFiled: May 23, 1984Date of Patent: October 8, 1985Assignee: Appleton Papers Inc.Inventors: Bruce W. Brockett, Robert E. Miller
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Patent number: 4544936Abstract: A heat-sensitive recording sheet is disclosed, comprising a base having thereon a heat-sensitive layer which contains, as main components, at least two kinds of fluoran dye color formers selected from different groups and a developer which causes coloration of the color former by heating. The color image of the heat-sensitive recording sheet fades less under influence of heat or humidity. Further the heat-sensitive recording sheet has high whiteness and less fogging of the background.Type: GrantFiled: May 31, 1983Date of Patent: October 1, 1985Assignee: Fuji Xerox Co., Ltd.Inventor: Naoki Yokoi
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Patent number: 4542394Abstract: A diazo-type thermosensitive recording material is disclosed, which comprises a support material, and at least two layers formed thereon, one of the layers being a diazonium compound layer comprising at least a diazonium compound, and another of the layers being a coupler layer comprising at least a coupler capable of reacting with the diazonium compound to form a dye, and a benzimidazole derivative having a substituent at the 1-position thereof.Type: GrantFiled: March 30, 1984Date of Patent: September 17, 1985Assignee: Ricoh Company, Ltd.Inventors: Yoshihiro Suguro, Masanaka Nagamoto
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Patent number: 4542395Abstract: Novel phenolic compounds useful as a color developer suitable for satisfying the quality requirements of heat-sensitive recording materials are provided, which compounds are expressed by the general formula ##STR1## wherein R.sub.1 represents an alkyl group or a cycloalkyl group and R.sub.2 represents hydrogen atom or an alkyl group; and also heat-sensitive recording materials usable in a broad application field are provided, which recording materials are provided with a heat-sensitive recording layer composed mainly of a colorless basic dye and the above compounds as a color developer by which the dye forms colors, overlaid on a substrate.Type: GrantFiled: November 5, 1984Date of Patent: September 17, 1985Assignees: Sanko Kaihatsu Kagaku Kenkyusho, Kanzai Paper Manufacturing Company Ltd.Inventors: Toranosuke Saito, Masakatu Kitani, Takashi Ishibashi, Naoto Arai, Takeshi Murakami, Toshitake Suzuki
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Patent number: 4540999Abstract: This invention provides a heat-sensitive record material comprising a base sheet and a heat-sensitive record layer formed over the base sheet and containing a colorless or pale-colored basic dye and a color developing material capable of forming a color when contacted with the dye, the record material being characterized in that the heat-sensitive record layer contains as the color developing material at least one compound represented by the formula ##STR1## wherein R.sub.1 and R.sub.2 are each alkyl having 1 to 8 carbon atoms, a group ##STR2## or a group ##STR3## wherein R.sub.3 and R.sub.4 are each a hydrogen atom, chlorine atom, hydroxyl or alkoxy having 1 to 8 carbon atoms, the heat-sensitive record layer further containing at least one compound selected from the group consisting of 1,1-bis(4-hydroxyphenyl)cyclohexane and hindered phenol compounds.Type: GrantFiled: July 10, 1984Date of Patent: September 10, 1985Assignee: Kanzaki Paper Manufacturing Co., Ltd.Inventor: Naoto Arai
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Patent number: 4540998Abstract: A record member comprising a developer composition comprising a zinc-modified addition product of a phenol and a diolefinic alkylated or alkenylated cyclic hydrocarbon is disclosed. These addition products are particularly useful as color developers for basic chromogenic material.Type: GrantFiled: May 23, 1984Date of Patent: September 10, 1985Assignee: Appleton Papers Inc.Inventors: Jerome R. Bodmer, Robert E. Miller
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Patent number: 4539577Abstract: A heat sensitive record material comprising a support sheet and a heat sensitive record layer formed on the support sheet, the heat sensitive record layer being composed essentially of a colorless or light-colored electron-donating colorless dye, an acidic substance which is thermally reactive with the electron-donating colorless dye to develop a color and a binder, characterized in that said heat sensitive record layer contains an effective amount of at least one anilide compound represented by the general formula: ##STR1## where R.sub.1 is an alkyl group having 1 to 6 carbon atoms or a cycloalkyl group; R.sub.2 is a hydrogen atom, an alkyl group having 1 to 4 carbon atoms, an alkoxy group having 1 to 4 carbon atoms, a sulfamoyl group or a halogen atom; R.sub.3 is a hydrogen atom, an alkyl group having 1 to 4 carbon atoms, an alkoxy group having 1 to 4 carbon atoms or a halogen atom; and n is an integer of 0 to 5.Type: GrantFiled: September 14, 1984Date of Patent: September 3, 1985Assignee: Hodogaya Chemical Co., Ltd.Inventors: Kazuo Kaneko, Michihiro Gonda, Susumu Suzuka, Katsumasa Kitsukawa