Coating Opposite Sides Or Forming Plural Or Nonuniform Coats Patents (Class 427/152)
  • Patent number: 5780387
    Abstract: A reversible thermosensitive recording medium includes a support material; a thermosensitive recording layer whose transparency is reversibly changeable depending upon the temperature thereof, which is provided on the support material and includes a low-molecular-weight organic compound and a resin matrix in which the organic low-molecular-weight compound is dispersed; and an overcoat layer provided on the thermosensitive recording layer, the overcoat layer having a pencil hardness of 1H or more and including at the surface thereof at least three protrusions with a height of 0.05 .mu.m or more per area of 125 .mu.m.times.125 .mu.m of the surface of the overcoat layer.
    Type: Grant
    Filed: August 22, 1996
    Date of Patent: July 14, 1998
    Assignee: Ricoh Company, Ltd.
    Inventor: Shigeyuki Harada
  • Patent number: 5780388
    Abstract: The heat sensitive recording material of the present invention has, between a support and a heat sensitive recording layer, an intermediate layer having a tensile modulus of elasticity of from 1.times.10.sup.8 to 1.times.10.sup.10 dyne/cm.sup.2) as measured according to JIS K 7127. The heat sensitive recording material of the present invention is suitable to prevention of abrasion of a thermal head and prevention of sticking of the heat sensitive recording material to the thermal head.
    Type: Grant
    Filed: November 14, 1996
    Date of Patent: July 14, 1998
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Minoru Wada, Kotaro Nakamura
  • Patent number: 5773386
    Abstract: A thermal sensitive label, and method of manufacture, provide a label construction which is resistant to abrasion without requiring additional coatings. A substantially transparent synthetic material substrate (typically about 1-3 mils thick, but no more than 5 mils thick) has a thermally sensitive coating applied to a first face so that when heat is applied to the second face an image will form on the thermally sensitive material and it will be readable from the second face without significant distortion. A pressure sensitive adhesive, which is preferably pigmented, is disposed on the thermally sensitive material, and may be covered with a release liner. Alternatively, an adhesive release material may be applied on the second face of the substrate.
    Type: Grant
    Filed: February 26, 1997
    Date of Patent: June 30, 1998
    Assignee: Moore U.S.A. Inc.
    Inventor: Joseph W. Langan
  • Patent number: 5773385
    Abstract: A thermosensitive recording medium, having a support, an intermediate layer disposed thereon, and a thermal recording layer disposed on the intermediate layer, with the support being a plastic film or a synthetic paper having a thickness of less than or equal to 150 .mu.m, and the intermediate layer containing hollow particles having a volume ratio of hollow particle to total intermediate layer material of greater than or equal to 20% and having a thermal conductivity of the intermediate layer together with the support of less than or equal to 0.55 kcal/mh.degree.C. is provided which has improved properties such as reduced paper curl, excellent dot print reproducibility and sufficient adhesion between layers, and which is conveniently used in a wide variety of information recording applications.
    Type: Grant
    Filed: March 11, 1996
    Date of Patent: June 30, 1998
    Assignee: Ricoh Co., Ltd.
    Inventors: Yoshinori Katoh, Takanori Motosugi
  • Patent number: 5763354
    Abstract: A liner-less thermosensitive recording material having a substrate, a thermosensitive coloring layer formed on one side of the substrate, a thermosensitive adhesive layer which is formed on the other side of the substrate and becomes adhesive when activated, while being non-adhesive in a normal state, an optional protective layer formed on the thermosensitive coloring layer, and perforation which is formed perpendicular to the longitudinal direction of the liner-less thermosensitive recording material, wherein length of a non-cut part of the perforation is smaller than about 1.5 mm and a ratio of total length of cut parts to total length of the non-cut parts in the perforation is at least 2.
    Type: Grant
    Filed: December 23, 1996
    Date of Patent: June 9, 1998
    Assignee: Ricoh Co., Ltd.
    Inventor: Masanaka Nagamoto
  • Patent number: 5759953
    Abstract: A recording material comprising at least one thermosensitive element, comprising a substantially light-insensitive organic silver salt and an organic reducing agent therefor in thermal working relationship therewith, on a support, characterized in that an outermost layer of said recording material comprises at least one solid lubricant having a melting point below 150.degree. C. and at least one liquid lubricant in a binder, wherein at least one of said lubricants is a phosphoric acid derivative. The outermost layer of the recording material in contact with the heat source during the thermal image forming process may be the outermost layer of the thermosensitive element, a protective layer applied to the thermosensitive element or a layer on the opposite side of the support to the thermosensitive element.
    Type: Grant
    Filed: November 29, 1996
    Date of Patent: June 2, 1998
    Assignee: Agfa-Gevaert
    Inventors: Geert Defieuw, Jan Gilleir, Wim Mues, Robert Van Haute
  • Patent number: 5753587
    Abstract: A heat-sensitive image recording material contains on a support material1. at least one binder layer with a heat-sensitive imaging combination of an organic silver salt and an organic reducing agent for the organic silver salt, and2. at least one binder layer or a sequence of binder layers with a heat-sensitive imaging combination of an acid-sensitive leuco dye and an acidically reacting compound which acts as a developer for the leuco dye,wherein the leuco dye and developer are in thermal interaction with each other either in different layers or separately from each other in the same layer, characterised in that a layer with a water- or alcohol-soluble polymer is arranged between the combination of organic silver salt and organic reducing agent for the organic silver salt, on the one hand, and the combination of leuco dye and acidically reacting compound, on the other.
    Type: Grant
    Filed: September 18, 1996
    Date of Patent: May 19, 1998
    Assignee: Agfa-Gevaert AG
    Inventors: Wolfgang Podszun, Luc Leenders
  • Patent number: 5747412
    Abstract: A (photo)thermographic recording material comprising a (photo-addressable) thermosensitive element, a support and an outermost antistatic layer, the thermosensitive element comprising a substantially light-insensitive organic silver salt, an organic reducing agent for the substantially light-insensitive organic silver salt in thermal working relationship therewith and a binder, characterized in that the outermost antistatic layer is an organic layer with a resistivity of <10.sup.10 .OMEGA./.quadrature. at a relative humidity of 30%. The outermost antistatic layer may comprise a polythiophene with conjugated polymer backbone in the presence of a polymeric polyanion compound and a hydrophobic organic polymer having a glass transition value (T.sub.g) of at least 40.degree. C., the polythiophene being present at a coverage of at least 0.001 g/m.sup.2 and the weight ratio of the polythiophene to the hydrophobic organic polymer being in the range of 1/10 to 1/1000.
    Type: Grant
    Filed: November 29, 1996
    Date of Patent: May 5, 1998
    Assignee: AGFA-Gevaert N.V.
    Inventors: Luc Leenders, Geert Defieuw, Bart Horsten, Hans Strijckers
  • Patent number: 5744226
    Abstract: A thermal transfer medium which forms images having a matte finish is provided which comprises a substrate, a thin first coating and a thick second coating. The coatings are formulated such that only the second coating transfers to a receiving substrate upon exposure to a thermal print head leaving the first coating positioned on the substrate. Separation of the two coatings provides images with a matte finish. The first coating has a higher softening point than the second coating and in preferred embodiments, the binder resin in the first coating provides higher adhesion to the substrate than the binder resin in the second coating.
    Type: Grant
    Filed: June 27, 1996
    Date of Patent: April 28, 1998
    Assignee: NCR Corporation
    Inventors: Michael W. Olmstead, Thomas C. Miller, Jr., Thomas J. Obringer
  • Patent number: 5741752
    Abstract: This invention provides a transparent thermal recording medium, in which the transparent thermal recording medium comprises: a thermal recording layer, which is provided on a transparent layer, consisting essentially of an electron-donating chromophoric compound, an electron-accepting compound and binder resin; and a further-provided protective layer having an approximately equal refractive index to the refractive index of the thermal recording layer, wherein the binder resin is a compound having a group selected from a hydroxyl group and a carboxyl group. The transparent thermal recording medium can be effectively used for a block copy film, on which an image is formed, for plate-making, particularly, in photogravure, offset printing and screen process printing, because the transparent thermal recording medium has a contrast of light transmission factors between a color-imaging portion and a non-imaging portion, in which the contrast is not less than 50% at a wavelength ranging from 370 nm to 450 nm.
    Type: Grant
    Filed: June 7, 1995
    Date of Patent: April 21, 1998
    Assignee: Ricoh Company, Ltd.
    Inventors: Hiroshi Goto, Hideaki Ema, Kiyoshi Sakai
  • Patent number: 5728645
    Abstract: A heat transfer sheet comprising a polyester film substrate sheet, an adhesive layer formed on one surface of the substrate sheet by applying the adhesive layer to the substrate sheet and biaxially stretching both the layer and the sheet simultaneously, and at least two heat transfer layers formed on said adhesive layer, a first layer comprising a thermally migratable dye and an untransferable binder, and second layer comprising a dyed or pigmented, heat-meltable binder.
    Type: Grant
    Filed: January 19, 1996
    Date of Patent: March 17, 1998
    Assignee: Dai Nippon Insatsu K.K.
    Inventors: Katsuyuki Oshima, Jitsuhiko Ando, Masanori Torii
  • Patent number: 5726120
    Abstract: A coated front sheet useful in carbonless copy forms. The sheet has a moisture resistant coating of latex binder, color developer, and pigment in association with a substrate. The coating is formulated to permit formation of a legible image in use in the carbonless copy form, and to minimize the adverse effects of humid weather conditions. The substrate is resistant to degradation by moisture, and may be a moisture resistant polymer or paper impregnated with the moisture resistant coating.
    Type: Grant
    Filed: June 7, 1995
    Date of Patent: March 10, 1998
    Assignee: Moore Business Forms, Inc.
    Inventors: Rodney E. Williams, Kenneth D. Riggs
  • Patent number: 5712221
    Abstract: A thermal recording medium includes a thermal recording layer, which is provided on a transparent substrate, consisting essentially of an electron-donating chromophoric compound, an electron-accepting compound and a binder resin, an over layer, whose dynamic friction coefficient of the surface does not exceed 0.1, includes a resin having substantially the same refractive index as the thermal recording layer is further provided.
    Type: Grant
    Filed: May 17, 1996
    Date of Patent: January 27, 1998
    Assignee: Ricoh Company, Ltd.
    Inventors: Hiroshi Goto, Ichiro Sawamura
  • Patent number: 5712026
    Abstract: An image-receiving sheet for melt thermal transfer recording is disclosed, including: a support (I) comprising (i) a substrate layer (A) made of a stretched film having microvoids formed therein, said stretched film of substrate layer (A) is obtained by stretching a propylene resin film comprising a propylene resin in an amount of from 65 to 95% by weight and inorganic fine powder having a specific surface area of from 10,000 to 40,000 cm.sup.2 /g and an average grain diameter of from 0.5 to 2.3 .mu.m in an amount of from 5 to 35% by weight, (ii) a surface layer (B) made of a stretched propylene film comprising a propylene resin in an amount of from 35 to 65% by weight and inorganic fine powder having a specific surface area of from 25,000 to 300,000 cm.sup.2 /g and an average grain diameter of from 0.07 to 0.9 .mu.
    Type: Grant
    Filed: August 8, 1996
    Date of Patent: January 27, 1998
    Assignee: Oji-Yuka Synthetic Paper Co., Ltd.
    Inventors: Hironobu Amagai, Takatoshi Nishizawa, Motoshi Henbo
  • Patent number: 5679615
    Abstract: A reversible heat-sensitive recording medium which includes at least a support and formed thereon a heat-sensitive recording layer including at least the following components: an electron-donating color-forming compound having a lactone ring, (b) an electron-accepting compound having a phenolic hydroxyl group, (c) at least one organic compound selected from compounds represented by formulae (I) to (V), and (d) a thermoplastic resin having an erasing action. The content of the thermoplastic resin having an erasing action is being from 15 to 70% by weight based on the total amount of components (a) to (d) Formulae (I) to (V) are as follows:R.sub.1 --CO--N(R.sub.2)R.sub.3 (I)R.sub.1 --CO--NH--R.sub.4 --NH--CO--R.sub.2 (II)R.sub.1 --CO--O--R.sub.2 (III)R.sub.1 --NH--CO--NH--R.sub.2 (IV)R.sub.1 --CO--R.sub.2 (V)wherein R.sub.1 represents an alkyl group, an aryl group, an alkenyl group, or a hydroxyalkyl group; R.sub.2 and R.sub.
    Type: Grant
    Filed: September 13, 1995
    Date of Patent: October 21, 1997
    Assignee: Tomoegawa Paper Co., Ltd.
    Inventors: Tatsuru Matsumoto, Kenichi Tanaka
  • Patent number: 5670446
    Abstract: This invention includes novel sultine compounds and the reaction of these compounds to form colored compounds. The invention also includes the use of these color-forming compounds in the manufacture and imaging of thermal imaging papers and pressure-sensitive imaging papers.
    Type: Grant
    Filed: May 30, 1996
    Date of Patent: September 23, 1997
    Assignee: Minnesota Mining and Manufacturing Company
    Inventors: Nusrallah Jubran, Alan R. Katritzky, Josef V. Ugro, Jr.
  • Patent number: 5670448
    Abstract: A low cost transparency-making recording sheet with stabilized productivity and quality has a support sheet releasably provided on an unrecording surface of a transparent substrate, and is characterized in that a thermoplastic resin layer is interleaved between the transparent substrate and the support sheet by an extrusion coating technique.
    Type: Grant
    Filed: June 15, 1995
    Date of Patent: September 23, 1997
    Assignee: Dai Nippon Printing Co., Ltd.
    Inventor: Shinji Kometani
  • Patent number: 5661101
    Abstract: A recording material is provided with, on a support, at least a coloring layer containing a first coloring component which is substantially colorless and a second coloring component which is substantially colorless and is colored by reacting with the first coloring component, wherein the coloring layer contains a polyvinyl alcohol resin having syndiotacticity of greater than or equal to 55 molar % as diad indication and a saponification degree of greater than or equal to 85 molar %. There is also disclosed a recording material having a protective layer provided on the coloring layer of the aforementioned recording material, wherein the polyvinyl alcohol resin having syndiotacticity of greater than or equal to 55 molar % as diad indication and a saponification degree of greater than or equal to 85 molar % is contained in at least one of the coloring layer and the protective layer.
    Type: Grant
    Filed: June 6, 1996
    Date of Patent: August 26, 1997
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Shintaro Washizu, Hidenori Gotoh
  • Patent number: 5661099
    Abstract: A self-wound label stock includes a thermal paper substrate. One face of the substrate is coated with a primer layer having ultraviolet light blockers and a release layer having a smooth surface finish. Another face of the substrate is coated with an adhesive layer. Non-thermal printing is applied between the substrate and the primer layer. Thermal printing is applied to the substrate through the primer and release layers. A separator divides the label stock into individual labels.
    Type: Grant
    Filed: August 4, 1995
    Date of Patent: August 26, 1997
    Assignee: Media Solutions, Inc.
    Inventor: Chauncey T. Mitchell, Jr.
  • Patent number: 5658847
    Abstract: A thermal transfer printing receiver sheet for use in association with a compatible donor sheet, the receiver sheet comprising an opaque polyester supporting substrate having a deformation index, at a temperature of 200.degree. C. and under a pressure of 2 megaPascals, of at least 4.0%, the substrate having, on a surface thereof, an adherent layer comprising an acrylic resin and having a coat weight within the range from 0.05 to 10 mgdm.sup.-2, the adherent layer having, on a surface thereof remote from the substrate, a dye-receptive receiving layer to receive a dye thermally transferred from the donor sheet.
    Type: Grant
    Filed: September 25, 1995
    Date of Patent: August 19, 1997
    Assignee: Imperial Chemical Industries PLC
    Inventors: Catherine Jane Goss, John Francis, Charles Richard Hart, Karen Goodchild
  • Patent number: 5652195
    Abstract: A heat-sensitive recording material suited for use in direct thermal imaging, wherein said recording material comprises in the order given:(i) a transparent polymeric support,(ii) a heat-sensitive imaging layer, and(iii) a protective layer characterized in that said protective layer is an opaque layer containing uniformly distributed in an organic hydrophilic polymeric binder at least one opacifying pigment in the form of particulate material some of which protrudes from the surface of said binder and has anti-stick properties with regard to a thermal print head, and wherein the opacity of layer (iii) corresponds with an absorption and/or scattering of at least 80% of the light of the visible wavelength range (400 to 700 nm), wherein said opaque layer has been coated from an aqueous dispersion of said opacifying pigment particles or precursors thereof.
    Type: Grant
    Filed: July 13, 1995
    Date of Patent: July 29, 1997
    Assignee: Agfa-Gevaert N.V.
    Inventors: Bartholomeus Horsten, Guy Jansen, Ronald Schuerwegen
  • Patent number: 5646088
    Abstract: A thermosensitive recording material having a high degree of background whiteness, superior light resistance without coloring of the background when exposed to the light, and a method of producing a stable coating liquid or forming a thermosensitive coloring layer and a protective layer are provided.
    Type: Grant
    Filed: February 15, 1996
    Date of Patent: July 8, 1997
    Assignee: Ricoh Co., Ltd.
    Inventors: Kunihiko Hada, Yasutomo Mori, Motoi Orihara, Shuji Miyamoto
  • Patent number: 5612281
    Abstract: A recording sheet for ink-jet recording, thermal transfer recording or electrographic recording comprises a transparent support and a transparent colorant-receptive layer, in which the colorant-receptive layer has a void volume of 50-80%, in which the network structure is formed of silica fine particles having a mean primary particle diameter of 10 nm or less and a water-soluble resin, and the weight ratio of silica fine particles/the water-soluble resin is in the range of 1.5/1 to 10/1.
    Type: Grant
    Filed: April 5, 1995
    Date of Patent: March 18, 1997
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Takashi Kobayashi, Yoshio Tani
  • Patent number: 5610118
    Abstract: A thermosensitive recording element having improved abrasion resistance, said element comprising (a) a support; (b) a first layer comprising an organic polymeric binder and either a substantially colorless electron donating dye precursor or an electron accepting compound or mixtures thereof; and (c) a second layer comprising an organic polymeric binder compatible with the binder in (b) and either a substantially colorless electron donating dye precursor or an electron accepting compound, wherein both dye precursor and electron accepting compound are present in the element and wherein the first layer is interposed between the support and second layer. These elements have wide application in the printing industry.
    Type: Grant
    Filed: December 29, 1994
    Date of Patent: March 11, 1997
    Assignee: International Paper Company
    Inventor: Albert H. Smith
  • Patent number: 5599416
    Abstract: There is provided a thermal transfer type emblem made of thermoplastic synthetic resin comprising three-dimensional design elements made of a flexible thermoplastic synthetic resin sheet as well as a method of manufacturing the same. Design elements formed with a design printed in color on the surface are bonded to the underside of a carrier film and a hot-melt type film is bonded to the lower surface of each of said design elements. If necessary, a synthetic resin adhesive layer is provided therebetween and said hot-melt type film may be bonded to a sheet of releasing paper at the underside. By appropriately selecting materials for the hot-melt type film and the synthetic resin adhesive layer, the flexible and three-dimensional emblem can be so made as to firmly adhere to an object by simply pressing the emblem with an iron regardless of the material of the object.
    Type: Grant
    Filed: May 12, 1995
    Date of Patent: February 4, 1997
    Inventor: Eiji Kuwahara
  • Patent number: 5597612
    Abstract: A process is disclosed for manufacturing paper web containing a CF layer for pressure sensitive recording paper. In order to ensure full sizing, the paper web is subjected to intermass sizing and the coating ink containing color acceptors constituted of color-reactive, mineral pigments is applied with a coating device in which the paper web is guided between two transfer rollers separated by a gap or set at minimal pressure. One of the transfer rollers applies volumetrically pre-dosed coating ink by means of a rotary and driven surface-profiled doctor bar, forming the CF layer on one side of the paper web, and the other transfer roller at the same time applies a volumetrically pre-dosed aqueous solution on the other side of the paper web, also by means of a rotary driven surface-profiled doctor bar. The amount of color-reactive pigment in the dried CF-layer comprises between 3.5 and 5 g/m.sup.2.
    Type: Grant
    Filed: July 26, 1994
    Date of Patent: January 28, 1997
    Assignee: Stora Feldmuhle AG
    Inventors: Horst Schoen, Horst W. Heyer, Wolfram Friesen
  • Patent number: 5593941
    Abstract: There is disclosed a process for production of a process for production of a thermally transferred image-receptive sheet which comprises:(a) coating a coating composition containing nylon, methanol and calcium chloride onto a woven fabric substrate,(b) dipping the coated substrate into water to solidify a coated layer and leach out methanol and calcium chloride, wherein a microporous surface layer is formed so that the bottom of woven fabric is just filled up,(c) drying the dipped substrate, and(d) furnishing the dried substrate to obtain a final product, wherein a cover factor of woven fabric in the final product is not lower than 1700 and a ratio of cover factor of woven fabric immediately after coating relative to that of the final product is 0.97 to 1.03.
    Type: Grant
    Filed: December 27, 1994
    Date of Patent: January 14, 1997
    Assignee: Dynic Corporation
    Inventors: Hiromoto Kato, Hiroshi Fukuhara
  • Patent number: 5585321
    Abstract: Enhanced thermal papers having a thermosetting organic polymeric-material containing heat-metering layer which enhances the thermal characteristics of the papers and methods of enhancing imaging characteristics of thermal papers, including particularly facsimile papers, by depositing onto the heat-metering layers of such papers a thermosetting organic polymeric-material-containing heat-metering layer.
    Type: Grant
    Filed: October 7, 1994
    Date of Patent: December 17, 1996
    Assignee: Rand McNally & Company
    Inventors: Thomas J. Breen, David J. Barbee, Mark G. Lang
  • Patent number: 5578548
    Abstract: A thermographic element containing: (a) a substrate; (b) an image-forming layer coated onto the substrate; and (c) overlaying the image-forming layer, a topcoat layer composed of the reaction product of (1) a polymer composed of interpolymerized units derived from: (i) about 45-65 wt % of vinyl-substituted aromatic monomer; (ii) about 15-30 wt % vinyl monomer containing a pendant nitrile group; (iii) about 5-30 wt % hydroxyl-containing; ethylenically-unsaturated monomer; and (2) a suitable crosslinking agent. A slip agent is optionally used. The topcoat layer provides a thermographic element with high gloss in the imaged areas; has excellent runnability with no chatter in the feed direction of the element; and exhibits no removal of topcoat which prevents formation of printhead-created voids in the imaged areas.
    Type: Grant
    Filed: October 16, 1995
    Date of Patent: November 26, 1996
    Assignee: Minnesota Mining & Manufacturing Company
    Inventors: Jon A. Bjork, Ramesh C. Kumar, John C. Haidos
  • Patent number: 5571557
    Abstract: A transfer sheet for applying images to glass, plexiglass and the like to simulate the look of an etched surface is prepared by a three-step screen printing process wherein a polystyrene or release coated paper base is first coated with nitrocellulose and then heated. Thereafter a further coat comprising a combination of nitrocellulose, a silica flattening agent and mica/silica is applied followed by further heating. A screen printable solvent based adhesive suitable for polystyrene or paper is then applied, then heated and, thereafter a slip sheet applied to the adhesive side to permit stacking.
    Type: Grant
    Filed: May 9, 1995
    Date of Patent: November 5, 1996
    Assignee: Chartpak, Inc.
    Inventors: Norman P. De Bastiani, Richard J. Boucher
  • Patent number: 5543382
    Abstract: Disclosed is a heat-sensitive recording paper comprising (a) a support made of glassine paper, (b) a resin layer formed on one side or both sides of the support, and (c) a heat-sensitive recording layer containing a leuco dye and a color developing material which develops a color on contact with the leuco dye,the resin layer being formed by coating one side or both sides of the support with an organic solvent coating composition prepared by dissolving a resin in an organic solvent, followed by drying, andthe heat-sensitive recording layer being formed on the resin layer or on the side of the support not having the resin layer thereon,wherein the organic solvent coating composition may further contain a pigment in an amount of about 3 to about 25% by weight based on the amount of the resin.
    Type: Grant
    Filed: December 20, 1994
    Date of Patent: August 6, 1996
    Assignee: New Oji Paper Co., Ltd.
    Inventors: Kazuo Watanabe, Masatoshi Okuda, Shigeo Aoyama, Yoshimasa Tanaka
  • Patent number: 5525569
    Abstract: A transfer tape having a self-imaging liner includes a first polyethylene coating or film layer on a first face of the self-imaging liner with a first silicone coating over the first polyethylene coating or film layer and a pressure sensitive adhesive on the first silicone coating. A release sheet is provided between the second face of the self-contained carbonless sheet and is covered with a second sprayed on polyethylene coating, or film layer, in turn covered by a second silicone coating. The transfer tape may be in a roll configuration with the adhesive engaging the second silicone coating. The first silicone coating may be a differential coating and applied at a weight of about 3-10 grams per square meter. The adhesive may be a hot melt adhesive or adhesive from a pre-wound tape. A business form may be constructed of a face stock and the transfer tape, the transfer tape pressure sensitive adhesive engaging the face stock, and labels may be die cut out of the business form.
    Type: Grant
    Filed: March 7, 1994
    Date of Patent: June 11, 1996
    Assignee: Moore Business Forms, Inc.
    Inventor: Stanley C. Chess
  • Patent number: 5525572
    Abstract: An improved carbonless copy paper for use in magnetic image character recognition (MICR). Carbonless copy paper according to the present invention contains a coated front (CF) layer which contains a latex binding component. The improved carbonless copy paper of the present invention provides a more durable CF coating which when imprinted with indicia prevents sorting errors in magnetic image character recognition.
    Type: Grant
    Filed: August 20, 1992
    Date of Patent: June 11, 1996
    Assignee: Moore Business Forms, Inc.
    Inventor: Rodney E. Williams
  • Patent number: 5514635
    Abstract: A thermal writing device which changes color in response to induced temperature changes and a method for making such a device is disclosed. The thermal writing device includes a flexible substrate with low thermal mass for rapidly assimilating temperatures. Thermochromic inks which change color when subjected to temperature changes are printed upon or incorporated within this flexible substrate. The flexible substrate is disposed upon a support material having low thermal mass and poor heat conductance to facilitate rapid color transitions by the thermochromic inks with minimal expenditures of energy.
    Type: Grant
    Filed: December 29, 1993
    Date of Patent: May 7, 1996
    Assignee: Optum Corporation
    Inventor: Andrew S. Filo
  • Patent number: 5514636
    Abstract: A heat-sensitive recording material which is highly transparent and resistant to sticking. The recording material comprises a support, having thereon in the following order, a heat-sensitive recording layer and a protective layer comprising a pigment, a binder and a wax. The wax has a melting point of from 40.degree. C. to 100.degree. C. and said wax comprises wax particles having a 50% volume-average particle diameter of not more than 0.7 .mu.m. Furthermore, the protective layer contains the pigment in an amount of not more than 100 parts per 100 parts by weight of binder.
    Type: Grant
    Filed: September 19, 1995
    Date of Patent: May 7, 1996
    Assignee: Fuji Photo Film Co., Ltd.
    Inventor: Koh Takeuchi
  • Patent number: 5510311
    Abstract: A sheet of copy material of the type having on one face (18a;28a) thereof a coating (B) incorporating a colour-forming substance of the kind which when released onto a receptor material (F) produces a visible mark, and having an opposite face (18a;28b) of the material free from such coating, characterised in that said one face (18a;28a) of the material comprises a visible image (I) formed thereon before the deposition of said coating (B), which is translucent, so that said visible image (I) is discernible through said coating (B) and in that said opposite face (18b;28b) carries a further image (II) formed thereon after the deposition of said coating (B) on said one face (18a;28a).
    Type: Grant
    Filed: September 12, 1994
    Date of Patent: April 23, 1996
    Inventors: Michael P. Bond, Victor G. Atkinson
  • Patent number: 5508247
    Abstract: A linerless thermal label is produced by disposing a thermosensitive layer into a substrate and allowing the thermosensitive layer to dry, said thermosensitive layer comprising a color former causing the thermosensitive layer to remain color stable. A protective layer is applied on top of the thermosensitive layer and exposes the protective layer to a temperature and a time sufficient to dry the protective layer but not cause the thermosensitive layer to a change color. A heat curable silicone mixture is disposed on said protective layer and thereafter cured to form a release layer without causing color change in the thermosensitive layer. A pressure-sensitive adhesive is applied on an opposite side of the substrate which is exposed to a temperature for a time sufficient to dry the pressure-sensitive adhesive without causing color change in the thermosensitive layer, and the substrate is then rolled in a manner causing the pressure-sensitive adhesive to contact the release layer.
    Type: Grant
    Filed: September 26, 1994
    Date of Patent: April 16, 1996
    Assignee: Ricoh Electronics, Inc.
    Inventors: Steve Tran, Minh Ly, Kelly Morse
  • Patent number: 5476830
    Abstract: A latent image printing method and apparatus uses a substrate with one main surface having a covering comprising one of a first pair of a color developer and color former dye defining a background color in conjunction with the one main surface, wherein the color developer and the color former dye react when mixed to produce a first spectral response which is visible relative to the background color and a continuous coating over the covering which is non-porous with respect to the other of the pair and solvent-resistant to the other of the pair. The coating above selected portions of the covering corresponding to a desired latent image is removed.
    Type: Grant
    Filed: August 10, 1994
    Date of Patent: December 19, 1995
    Assignee: NOCOPI International, Inc.
    Inventor: Arshavir Gundjian
  • Patent number: 5472757
    Abstract: Disclosed is an ink jet recording sheet which comprises a support mainly composed of wood fibers, an ink-receiving layer provided on one side of the support and a tacky layer provided on another side of the support where a barrier layer comprising a film-forming material is provided between-the support and the ink-receiving layer and/or between the support and the adhesive layer. Spread of ink due to penetration of the adhesive into the ink-receiving layer is prevented and images excellent in sharpness and color quality can be obtained.
    Type: Grant
    Filed: December 22, 1993
    Date of Patent: December 5, 1995
    Assignee: Mitsubishi Paper Mills Limited
    Inventors: Susumu Ogawa, Kouji Idei, Hideaki Senoh
  • Patent number: 5462909
    Abstract: A business form such as a label, tag or the like is provided in which a thermally imagable substrate has on selected portions of its surface a plurality of different colored areas. At least one of the colored areas is obscured by thermally imaging the substrate in a selected area so as to provide color coded information. The colored areas may be preprinted as half-tone screened areas on the substrate in a number of different patterns and arrangements. The form may be printed with both color coded information and variable information in a single printing pass.
    Type: Grant
    Filed: April 4, 1994
    Date of Patent: October 31, 1995
    Assignee: The Standard Register Company
    Inventors: A. Dale Lakes, Patrick A. Konkol, Edward M. Ribar
  • Patent number: 5447899
    Abstract: A heat-sensitive recording material is prepared by forming a heat-sensitive recording layer on a synthetic paper having a laminated structure. The synthetic paper has a front surface having a smoothness (in accordance with JIS P-8119) of not less than 2000 seconds on which the heat-sensitive recording layer is provided, and a back surface having a smoothness of not more than 1000 seconds, and has an opacity (in accordance with JIS P-8138) of not higher than 40%. The heat-sensitive recording material is superior in recording runnability and recording quality, and gives recorded materials useful as a second original for diazo print.
    Type: Grant
    Filed: May 26, 1994
    Date of Patent: September 5, 1995
    Assignee: New Oji Paper Co., Ltd.
    Inventors: Gensuke Matoba, Ichiro Matsuoka
  • Patent number: 5446009
    Abstract: In a thermal recording sheet including an intermediate layer, and a thermal color developing layer containing a leuco dye type chromogenic component containing a leuco dye and an organic color developer as main ingredients and a metal chelate type chromogenic component containing an electron acceptor and an electron donor as main ingredients, stacked on a substrate, the intermediate layer contains a pigment having an oil absorption of 100 ml/100 g or less measured according to JIS K 5101, and the thermal color developing layer contains at least one of compounds of Formula (I) and Formula (II) as an organic color developer, a metal double salt of higher fatty acid having 16 to 35 carbon atoms as an electron acceptor, and a polyhydric hydroxy aromatic compound of Formula (III) as an electron donor, whereby providing a thermal recording sheet which is superior in dynamic sensitivity, background color, image stability such as oil resistance and plasticizer resistance, and print adaptability: ##STR1## wherein R is
    Type: Grant
    Filed: November 17, 1993
    Date of Patent: August 29, 1995
    Assignee: Nippon Paper Industries Co., Ltd.
    Inventors: Toshiaki Minami, Tadakazu Fukuchi
  • Patent number: 5427996
    Abstract: A heat-sensitive recording sheet superior in color formation and sticking resistance and excellent in storage stabilities such as plasticizer resistance and wet-rub resistance and printability which comprises a support and, provided thereon, a heat-sensitive recording layer and a protective layer is provided by using as a main component of the protective layer in the case of the protective layer comprising one layer a latex having a softening point of 200.degree.-350.degree. C. obtained by polymerizing mainly a specific hydrophobic vinyl monomer in the presence of a polymeric latex having a glass transition temperature of 50.degree. C. or lower and as a main component of the protective layer in the case of the protective layer comprising two or more layers a latex having a softening point of 150.degree.-260.degree. C. in the inner layer(s) and preferably, using in the outermost protective layer said specific latex having a softening point of 200.degree.-350.degree. C.
    Type: Grant
    Filed: September 8, 1993
    Date of Patent: June 27, 1995
    Assignee: Mitsubishi Paper Mills Limited
    Inventors: Makoto Motoda, Haruyoshi Funae, Takao Kosaka, Toru Nakazawa, Yasuko Kaneko
  • Patent number: 5418206
    Abstract: An abrasion resistant thermosensitive recording element having high gloss, and improved abrasion resistance and process of preparing said element are described. The element comprises (a) a support, (b) a first layer comprising an organic polymeric binder and a substantially colorless electron donating dye precursor, and (c) a second layer comprising an organic polymeric binder compatible with the binder in (b), an electron accepting compound capable of forming color by reaction with said dye precursor, and a crosslinking agent, wherein the first layer is interposed between the support and the second layer. These elements have wide application in the printing industry.
    Type: Grant
    Filed: October 22, 1991
    Date of Patent: May 23, 1995
    Assignee: International Paper Company
    Inventor: Albert H. Smith
  • Patent number: 5409881
    Abstract: A thermosensitive recording material composed of a support, a thermosensitive recording layer formed on the support, capable of producing colored images by heating, and a protective layer formed on the thermosensitive recording layer, which contains as a resin component a copolymer resin obtained by copolymerization of arylamide or methacrylamide, acrylonitrile, and a vinyl monomer having a carboxyl group, or a copolymer resin of a core-shell emulsion type obtained by copolymerization of acrylamide and/or methacrylamide in the presence of a seed emulsion of an acryl-based copolymer or methacryl-based copolymer, and as a crosslinking agent a compound having two or more alkyleneimino groups, a carbodiimide compound, a methyl ethyl ketoxime compound, or bis(.beta.-hydroxyethyl)sulfone.
    Type: Grant
    Filed: December 23, 1992
    Date of Patent: April 25, 1995
    Assignee: Ricoh Company, Ltd.
    Inventors: Yasutomo Mori, Mitsuru Naruse, Kunihiko Hada, Motoo Tasaka
  • Patent number: 5409883
    Abstract: A process for the manufacture of a thermal transfer donor element having at least two areas of thermally transferable colorant, at least one of said areas being a thermal dye transfer composition and at least one of said areas being a thermal mass transfer composition, which process comprises coating a first thermal dye or mass transferable layer containing a colorant onto a temporary substrate to form a primary thermal transfer element, said layer having a measurable surface area, and either 1) thermally transferring less than all of said layer onto a second temporary substrate having a non-imagewise distributed area of a second thermally respectively mass or dye transferable colorant thereon to form a thermal transfer donor element with at least two areas of different thermally transferable materials, or 2) splicing a portion of only one primary thermal dye or mass transfer element onto another thermal transfer element having at least a non-imagewise distributed second thermal mass or dye, transferable, res
    Type: Grant
    Filed: May 7, 1993
    Date of Patent: April 25, 1995
    Assignee: Minnesota Mining and Manufacturing Company
    Inventors: David A. Larshus, Richard S. Fisch, Jeffrey C. Chang, Peter A. Vono, Hsin-Hsin Chou
  • Patent number: 5409880
    Abstract: A multi-color heat-sensitive recording material which comprises a support having thereon at least two heat-sensitive recording layers, each of which comprises a colorless or pale-color color forming agent which forms a color by heating, a color developer and a binder, an intermediate layer being incorporated between the two heat-sensitive recording layers and the intermediate layer comprising at least gelatin and/or a gelatin derivative and polyvinyl pyrrolidone and/or a polyvinyl pyrrolidone derivative, with the polyvinylpyrrolidone and/or the polyvinylpyrrolidone derivative having an average molecular weight of not more than 160,000, the content of which ranges from 1 to 20 percent by weight based on the weight of the gelatin and/or gelatin derivative.
    Type: Grant
    Filed: May 18, 1993
    Date of Patent: April 25, 1995
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Yuichi Itabashi, Akira Igarashi
  • Patent number: 5407893
    Abstract: An ID card material comprises a thermal transfer image-receiving layer, and provided thereon, a substrate layer and a writing layer in this order, the substrate layer comprising a biaxially oriented polyester film layer having a thickness of 300 to 500 .mu.m and a resin layer having a thickness of 30 to 500 .mu.m selected from the group consisting of a polyolefin layer, a polyvinyl chloride type resin film layer and an ABS resin film layer.
    Type: Grant
    Filed: August 19, 1993
    Date of Patent: April 18, 1995
    Assignee: Konica Corporation
    Inventors: Kunihiro Koshizuka, Shigehiro Kitamura, Masataka Takimoto, Tomonori Kawamura
  • Patent number: 5405821
    Abstract: A thermal recording sheet superior in dynamic sensitivity, dot reproducibility, image quality and image storage stability, and having no trouble of turning yellow of the sheet caused by NOx gas.A thermal recording sheet comprising an intermediate layer and a thermal color developing layer provided in turn on a substrate, wherein the intermediate layer contains a pigment having an oil absorption (according to JIS K5101) of less than 80 ml/100 g, and a compound of the following general formula (I): ##STR1## wherein R denotes propyl, isopropyl, or n-butyl, and calcium carbonate are contained in the thermal color developing layer as an organic color developer and a pigment, respectively.
    Type: Grant
    Filed: August 26, 1993
    Date of Patent: April 11, 1995
    Assignee: Nippon Paper Industries Co., Ltd.
    Inventors: Toshiaki Minami, Tadakazu Fukuchi
  • Patent number: 5393560
    Abstract: A heat-sensitive recording material having a uniform protective layer on a heat-sensitive recording layer formed on a base sheet which is a plastic film or synthetic paper can be obtained without generating a bar-line, streak or scratch. The protective layer is formed on the heat-sensitive recording layer after adjusting Bekk smoothness (measured by TAPPI standard T479 om-81) of the heat-sensitive recording layer to 500.about.6,000 seconds, preferably 1,500.about.4,500 seconds.
    Type: Grant
    Filed: July 29, 1993
    Date of Patent: February 28, 1995
    Assignee: Kanzaki Paper Mfg. Co., Ltd.
    Inventors: Kiyomi Okada, Gensuke Matoba