Optical Brightening Patents (Class 427/158)
  • Patent number: 4559150
    Abstract: A stable composition for treating textile substrates, which composition comprises at least(a) an organic solvent which is sparingly soluble or insoluble in water and in which component (b) is dissolved and components (c) and (d) are dissolved or dispersed,(b) a vehicle for component (c) which is sparingly soluble or insoluble in water,(c) a finishing agent which is sparingly soluble or insoluble in water and which is soluble or dispersible in the vehicle (b), and(d) a water-soluble acid having a pK value greater than 1 and optionally in addition(e) a solid carboxylic acid which is sparingly soluble in water,(f) a polar solventand/or further additives or assistants, e.g. surfactants or chelating agents.The novel composition, which preferably contains fluorescent whitening agents as finishing agents, is used in particular for whitening synthetic fibre materials, especially finished goods such as curtains or underwear, in acid medium.
    Type: Grant
    Filed: August 3, 1983
    Date of Patent: December 17, 1985
    Assignee: Ciba Geigy Corporation
    Inventors: Carl Becker, Fritz Heizler
  • Patent number: 4548609
    Abstract: Disclosed is a method for marking mineral tanned leather by treating the unfinished leather with an anionic aqueous dispersion of a fluorescent pigment. The marked leather can then be sorted by exposure to UV-radiation.
    Type: Grant
    Filed: January 12, 1984
    Date of Patent: October 22, 1985
    Assignee: Sandoz Ltd.
    Inventor: Alfred Schone
  • Patent number: 4508784
    Abstract: The invention relates to novel 4-styryl-4'-vinylbiphenyls of the formula ##STR1## wherein the benzene rings A, B and C can carry non-chromophoric substituents and R.sub.3 is a second order non-chromophoric substituent, and R.sub.4 is hydrogen or a non-chromophoric substituent which cannot be a second order substituent, and also a process for obtaining them. These novel compounds can be used as fluorescent whitening agents for treating organic material of high molecular weight, preferably textile material, most preferably polyester fibres. The invention also discloses novel intermediates of the formula ##STR2## wherein A, B and C are as defined above, which are formed during the production of the novel 4-styryl-4'-vinylbiphenyls, and also a process for obtaining them.
    Type: Grant
    Filed: January 23, 1984
    Date of Patent: April 2, 1985
    Assignee: Ciba Geigy Corporation
    Inventor: Leonardo Guglielmetti
  • Patent number: 4505955
    Abstract: A uniform mixture consisting essentially of an aqueous silicone elastomeric emulsion and mineral particles having an average particle diameter of greater than 150 micrometers is described. The emulsion comprises an anionically stabilized, hydroxyl endblocked polydiorganosiloxane, colloidal silica, and an alkyl tin salt. The uniform mixture can be applied to building surfaces such as structural foam insulation or wooden walls to provide a protective covering. The cured coating can provide protection from weathering, physical damage, and fire.
    Type: Grant
    Filed: July 30, 1981
    Date of Patent: March 19, 1985
    Assignee: Dow Corning Corporation
    Inventor: Michael D. Meddaugh
  • Patent number: 4478598
    Abstract: The amphoteric styrene derivatives correspond to the formula ##STR1## in which X is oxygen, sulfur, a direct bond, --SO.sub.2 N(R.sub.5 --, --CON(R.sub.5 -- or --COO--, Y.sub.1 and Y.sub.2 independently of one another are C.sub.1 -C.sub.4 -alkylene or hydroxypropylene, R.sub.1 and R.sub.2 independently of one another are C.sub.1 -C.sub.4 -alkyl or, together with the N atom, are a pyrrolidine, piperidine, hexamethyleneimine or morpholine ring, and R.sub.1, together with R.sub.5, is also a piperazine ring, R.sub.3 and R.sub.4 are hydrogen, C.sub.1-4 -alkyl, chlorine, C.sub.1-4 -alkoxy or C.sub.3-4 -alkenyl or together, in the o-position relative to one another, are a trimethylene or tetramethylene group, R.sub.5 is hydrogen, C.sub.1-4 -alkyl or cyanoethyl or, together with R.sub.1, is a piperazine ring, Q is --COO or --SO.sub.3 and n is the number 1 or 2, and can be prepared by reacting the corresponding amine compounds with a halide of the formula Hal--Y.sub.
    Type: Grant
    Filed: February 22, 1982
    Date of Patent: October 23, 1984
    Assignee: Ciba-Geigy Corporation
    Inventors: Hans R. Meyer, Max Morf
  • Patent number: 4472457
    Abstract: Fibers which are equipped with at least one bleaching agent are obtained in that the fibers are contacted with a dispersion or a solution containing at least one bleaching agent, said dispersion or said solution is allowed to interact to the fibers and then the so treated fibers are dried.Preferably the fibers equipped according to the process of the invention are used as screen gauzes.
    Type: Grant
    Filed: August 23, 1983
    Date of Patent: September 18, 1984
    Assignee: Schweizerische Seidengazefabrik AG
    Inventor: Johannes A. Craamer
  • Patent number: 4460374
    Abstract: The invention relates to a stable composition for treating textile substrates which contains at least(a) an organic solvent which is sparingly soluble to insoluble in water and in which component (b) is dissolved and component (c) is dissolved or dispersed,(b) a vehicle for component (c) which is sparingly soluble to insoluble in water, and(c) a finishing agent which is sparingly soluble to insolube in water and which is soluble or dispersible in the vehicle (b). In addition to components (a), (b) and (c), the composition of the invention may also contain(d) a solid carboxylic acid which is sparingly soluble in water, and preferably soluble in the solvent (a), and/or(e) a polar organic solvent as well as further additives or assistants.The novel composition, which preferably contains fluorescent whitening agents as finishing agents, is used in particular for whitening manmade textiles, especially made-up goods such as curtains or underwear.
    Type: Grant
    Filed: February 8, 1982
    Date of Patent: July 17, 1984
    Assignee: Ciba-Geigy Corporation
    Inventors: Heinz Abel, Carl Becker, Paul Schafer
  • Patent number: 4433975
    Abstract: Cationic fluorescent whitening agents of the formula ##STR1## wherein B is a fluorescent whitening agent containing basic tertiary amino groups, m is the number of basic amino groups, and each of R.sub.1, R.sub.2 and R.sub.3 is alkyl of 1 to 4 carbon atoms which is unsubstituted or substituted by non-chromophoric groups, or is alkenyl of 2 to 4 carbon atoms which is unsubstituted or substituted by non-chromophoric groups. These compounds have good solubility in water and they make it possible to prepare concentrated solutions and can be used for whitening organic material.
    Type: Grant
    Filed: September 22, 1982
    Date of Patent: February 28, 1984
    Assignee: Ciba-Geigy Corporation
    Inventor: Hans R. Meyer
  • Patent number: 4432886
    Abstract: Cationic fluorescent whitening agents of the formula ##STR1## wherein B is a fluorescent whitening agent containing basic tertiary amino groups, m is the number of basic amino groups, and each of R.sub.1, R.sub.2 and R.sub.3 is alkyl of 1 to 4 carbon atoms which is unsubstituted or substituted by non-chromophoric groups, or is alkenyl of 2 to 4 carbon atoms which is unsubstituted or substituted by non-chromophoric groups. These compounds have good solubility in water and they make it possible to prepare concentrated solutions and can be used for whitening organic material.
    Type: Grant
    Filed: September 22, 1982
    Date of Patent: February 21, 1984
    Assignee: Ciba-Geigy Corporation
    Inventor: Hans R. Meyer
  • Patent number: 4384121
    Abstract: Cationic fluorescent whitening agents of the formula ##STR1## wherein B is a fluorescent whitening agent containing basic tertiary amino groups, m is the number of basic amino groups, and each of R.sub.1, R.sub.2 and R.sub.3 is alkyl of 1 to 4 carbon atoms which is unsubstituted or substituted by non-chromophoric groups, or is alkenyl of 2 to 4 carbon atoms which is unsubstituted or substituted by non-chromophoric groups. These compounds have good solubility in water and they make it possible to prepare concentrated solutions and can be used for whitening organic material.
    Type: Grant
    Filed: October 27, 1980
    Date of Patent: May 17, 1983
    Assignee: Ciba-Geigy Corporation
    Inventor: Hans R. Meyer
  • Patent number: 4366189
    Abstract: The invention relates to 4-heterocyclyl-4'-vinylstilbenes of the formula ##STR1## wherein Q is a monocyclic 5- or 6-membered aromatic heterocyclic ring which is unsubstituted or substituted by non-chromophoric groups and which contains no fused benzene rings or 1 or 2 fused benzene rings, or is a bicyclic 9-membered aromatic heterocyclic ring, phenyl which is unsubstituted or substituted by non-chromophoric groups, or is cyano, carboxyl, alkoxycarbonyl or alkylsulfonyl or arylsulfonyl, R.sub.o is hydrogen, alkyl which is unsubstituted or substituted by non-chromophoric groups, R.sub.1 is hydrogen, alkyl, alkoxycarbonyl, carbamoyl or sulfonamide, each of which is unsubstituted or substituted by non-chromophoric groups, or is alkenyl, carboxyl, alkylsulfonyl, arylsulfonyl or aralkylsulfonyl, cyano, sulfo or phosphonic acid dialkyl ester, and R.sub.2 is hydrogen, alkyl or alkenyl, each of which is unsubstituted or substituted by non-chromophoric groups, with the proviso that at most one of R.sub.1 and R.sub.
    Type: Grant
    Filed: December 10, 1980
    Date of Patent: December 28, 1982
    Assignee: Ciba-Geigy Corporation
    Inventors: Kurt Burdeska, Guglielmo Kabas, Kurt Weber
  • Patent number: 4276188
    Abstract: A new process for manufacturing 2-stilbenyl-1,2,3-triazoles as well as new 2-stilbenyl-1,2,3-triazoles and their use for the optically brightening of organic material are disclosed.
    Type: Grant
    Filed: August 1, 1979
    Date of Patent: June 30, 1981
    Assignee: Ciba-Geigy Corporation
    Inventor: Hans R. Meyer
  • Patent number: 4261855
    Abstract: Stilbene compounds of the formula ##STR1## in which the rings A, B and C can carry non-chromophoric substituents, R.sub.1 is hydrogen, alkyl which is unsubstituted or substituted by non-chromophoric substituents, or aryl which is unsubstituted or substituted by non-chromophoric substituents, and R.sub.2 is a carboxyl group or a functional derivative thereof, a cyano group, a sulphonic acid ester group, a sulphonamide group or a sulphonyl group, and the use thereof as fluorescent brightening agents for high-molecular organic material.
    Type: Grant
    Filed: June 1, 1979
    Date of Patent: April 14, 1981
    Assignee: Ciba-Geigy Corporation
    Inventor: Kurt Weber
  • Patent number: 4252604
    Abstract: Bis-(triazinylamino)-stilbenesulphonic acids ##STR1## wherein X is optionally substituted NH.sub.2 ##STR2## Y is a radical of formula Z is --COOR.sub.4, --CO--C.sub.m H.sub.2m+1, --CN or ##STR3## R.sub.1 is H, halogen, alkyl or alkoxy, R.sub.2 is H or alkyl,R.sub.3 is H, optionally substituted alkyl, cycloalkyl or phenyl or ##STR4## R.sub.4 is optionally substituted alkyl, R.sub.3 and R.sub.6 are H, alkyl, hydroxyalkyl or form together with N a heterocyclem is a whole number from 1 to 5 andn is 1 or 2,are optical brighteners suitable for cellulosic fibres, polyamide and polyurethane fibres and paper.
    Type: Grant
    Filed: August 30, 1977
    Date of Patent: February 24, 1981
    Assignee: Sandoz Ltd.
    Inventors: Fritz Fleck, Hans R. Schmid
  • Patent number: 4245007
    Abstract: New 1,4-bis-[azol-2'-yl]-naphthalene compounds, a process for their preparation as well as a process for optically brightening organic materials on using said compounds are disclosed.
    Type: Grant
    Filed: August 1, 1978
    Date of Patent: January 13, 1981
    Assignee: Ciba-Geigy Corporation
    Inventor: Leonardo Guglielmetti
  • Patent number: 4222739
    Abstract: Benzodifuranes of the formula ##STR1## wherein R represents hydrogen, alkyl or halogen, each of R.sub.1, R.sub.2 and R.sub.3 represents hydrogen or different non-chromophoric substituents, with the proviso that at least one of the symbols R, R.sub.1, R.sub.2 or R.sub.3 does not represent hydrogen, processes for their production and the use thereof for whitening organic material of high molecular weight, especially polyester, polyvinyl chloride or polystyrene.
    Type: Grant
    Filed: September 11, 1978
    Date of Patent: September 16, 1980
    Assignee: Ciba-Geigy Corporation
    Inventors: Bruno Kagi, Geza Kormany, Christian Luthi
  • Patent number: 4217301
    Abstract: A new process for the manufacture of cyano-substituted stilbene compounds, new stilbene compounds as well as their use as fluorescent brighteners or as intermediates for the manufacture of fluorescent brighteners are provided.
    Type: Grant
    Filed: March 16, 1978
    Date of Patent: August 12, 1980
    Assignee: Ciba-Geigy Corporation
    Inventors: Adolf E. Siegrist, Vincenzo Coviello
  • Patent number: 4212763
    Abstract: Bis-triazinylaminostilbene compounds of the formula ##STR1## in which R.sub.1 is alkyl, alkenyl, cyclohexyl or phenylalkyl, R.sub.2 is hydrogen, alkyl, cyclohexyl, benzyl, alkyl which is substituted by hydroxyl, cyano, sulpho or carbamoyl, alkoxyalkyl or hydroxyalkoxyalkyl or alkoxyalkoxyalkyl or mono- or di-alkylaminoalkyl, and R.sub.3 is hydrogen, alkyl, alkyl which is substituted by hydroxyl, cyano or sulpho, or alkoxyalkyl or hydroxyalkoxyalkyl or R.sub.2 and R.sub.3 together with the nitrogen atom to which they are bonded are a morpholine ring or a pyrrolidine, piperidine, hexamethyleneimine or piperazine ring which is unsubstituted or substituted by 1 or 2 alkyl groups, and M is hydrogen or an alkali metal, ammonium or amine ion, and, if R.sub.2 or R.sub.3 is hydroxyalkyl, R.sub.1 is methyl, cyclohexyl or alkenyl only, and their use as fluorescent brightening agents for organic material of high molecular weight are disclosed.
    Type: Grant
    Filed: June 26, 1978
    Date of Patent: July 15, 1980
    Assignee: Ciba-Geigy Corporation
    Inventor: Werner Fringeli
  • Patent number: 4210488
    Abstract: A process for improving the dry strength of paper and for improving the effect of optical brighteners in the preparation or coating of paper which includes the step of adding fillers and/or pigments and anionic brighteners to the paper making process the improvement comprising adding to paper making pulp a polypiperidine halide absorbed in a dispersed state on a fine-particle organic or inorganic carrier before the anionic brightener is added.
    Type: Grant
    Filed: February 23, 1979
    Date of Patent: July 1, 1980
    Inventors: Peter J. Reuss, Josef Weigl
  • Patent number: 4206072
    Abstract: Benzoxazolyl-phenyl-stilbenes of the formula ##STR1## in which X is a carboxylic acid group or an ester or amide thereof, a phenyl sulphonate group or a sulphonamide group, a cyano group or alkylsulphonyl and the ring A can be substituted by alkyl having 1 to 4 C atoms, phenyl, chlorine, alkoxy having 1 to 4 C atoms, phenoxy, cyano, alkylsulphonyl having 1 to 4 C atoms, phenylsulphonyl or alkoxycarbonyl having 2 to 6 C atoms, a process for their manufacture as well as their use for the optical brightening are disclosed.
    Type: Grant
    Filed: October 31, 1978
    Date of Patent: June 3, 1980
    Assignee: Ciba-Geigy Corporation
    Inventors: Hans R. Meyer, Kurt Burdeska
  • Patent number: 4206248
    Abstract: A process is disclosed for the production of a sun heat energy absorbing coating on a metallic substrate. The metallic substrate is pretreated for subsequent coating with a film of powder varnish and thereafter a coating based on a solid synthetic resin is deposited electrostatically or in a whirl sintering procedure. The coating consists of an inner brightening layer containing a metallic powder and an outer colored second layer absorbing the sun energy.
    Type: Grant
    Filed: March 2, 1978
    Date of Patent: June 3, 1980
    Assignee: Eltreva AG
    Inventor: Hans Schmidlin
  • Patent number: 4196229
    Abstract: Disclosed are compounds of formula I ##STR1## in which R.sub.1 and R.sub.4, independently, are hydrogen, a non-chromophoric second order substituent, or alkyl or alkenyl unsubstituted or substituted by a non-chromophoric group,R.sub.2 and R.sub.5, independently, are hydrogen or alkyl or alkenyl, unsubstituted or substituted by a non-chromophoric group,R.sub.3 and R.sub.6, independently, are hydrogen, alkyl, carboxyl or a non-chromophoric esterified carboxyl group,or R.sub.2, together with R.sub.3, and/or R.sub.5 together with R.sub.6, signify an alkylene bridge,R.sub.7 and R.sub.8, independently, signify hydrogen or a non-chromophoric substituent,or, when R.sub.7 is in the 3-position and/or R.sub.8 in the 3' position, R.sub.7 together with R.sub.2, and/or R.sub.8 together with R.sub.5 signify an alkylene bridge,with the proviso that no more than one of R.sub.1 and R.sub.2 and no more than one of R.sub.4 and R.sub.5 signify hydrogen,their production and use as optical brightening agents.
    Type: Grant
    Filed: June 12, 1978
    Date of Patent: April 1, 1980
    Assignee: Sandoz Ltd.
    Inventors: Fritz Fleck, Juerg Heller
  • Patent number: 4186119
    Abstract: Disclosed is a textile wet treatment process wherein, to increase the lubricity of the substrate, certain specified polyurethanes are employed in the treatment liquor.
    Type: Grant
    Filed: November 28, 1978
    Date of Patent: January 29, 1980
    Assignee: Sandoz Ltd.
    Inventors: Jose Canela, Hans Gerber
  • Patent number: 4172045
    Abstract: Process for the manufacture of 2-stilbenyl-1,2,3-triazoles containing carboxyl groups by reacting a 2-tolyl-1,2,3-triazole with an anil in the presence of a strongly basic alkali compound in a strongly polar, neutral to basic organic solvent as well as novel 2-stilbenyl-1,2,3-triazoles containing carboxyl groups are described.
    Type: Grant
    Filed: December 16, 1976
    Date of Patent: October 23, 1979
    Assignee: Ciba-Geigy Corporation
    Inventors: Hans R. Meyer, Reinhard Zweidler
  • Patent number: 4167628
    Abstract: Novel benzoxazole compounds of the formula ##STR1## wherein R.sub.1, R.sub.2 and A are certain substituents, a process for their manufacture as well as their use as optical brighteners are disclosed.
    Type: Grant
    Filed: December 9, 1977
    Date of Patent: September 11, 1979
    Assignee: Ciba-Geigy Corporation
    Inventor: Geza Kormany
  • Patent number: 4166176
    Abstract: The compounds of the formula ##STR1## WHEREIN X and Y denote halogen, hydroxyl, amino, alkoxy, aralkyloxy, cycloalkoxy, aryloxy, alkylmercapto, arylmercapto, alkylamino, dialkylamino, morpholino, piperidino, piperazino, pyrrolidino, acylamino, arylamino or alkyl,N denotes 0, 1 or 2 andQ denotes hydrogen, pyrazol-1-yl, oxazol-2-yl, benzoxazol-2-yl, naphthoxazol-2-yl, 1,2,4-oxadiazol-5-yl, 1,3,4-oxadiazol-2-yl, isoxazol-3-yl, isoxazol-5-yl, thiazol-2-yl, benzthiazol-2-yl, 1,3,4-thiadiazol-2-yl, imidazol-2-yl, benzimidazol-2-yl, 1,2,3-triazol-2-yl, 1,2,3-triazol-4-yl, 1,2,4-triazol-3-yl, 1,2,4-triazol-5-yl, 2 H-benzotriazol-2-yl, 2 H-naphthotriazol-2-yl, benzo[b]-furan-2-yl, naphtho[2,1-b]-furan-2-yl, benzo[b]-thiophen-2-yl, naphtho[2,1-b]-thiophen-2-yl, pyrimidin-2-yl, pyrridin-2-yl, quinazolin-4-yl or quinazolin-2-yl, if n is 1 or 2, or denotes naphthyl-, stilben-4-yl-, benzo[b]-furan-6-yl, dibenzofuran-3-yl-, dibenzofuran-2-yl, quinoxalin-6-yl-, quinazolin-6-yl- or 2 H-benzotriazol-5-yl, if n is 0,It being po
    Type: Grant
    Filed: March 20, 1978
    Date of Patent: August 28, 1979
    Assignee: Bayer Aktiengesellschaft
    Inventors: Udo Eckstein, Horst Harnisch
  • Patent number: 4162348
    Abstract: A method for coloring inorganic substrates such as glass beads, glass fibers, mineral wool, rock wool, mineral fiber boards and cloths, concrete molded materials, inorganic pigments and metallic powders, which comprises treating the inorganic substrate with (1) a cationic component comprising(a) a water soluble cationic resin or an aqueous solution of a water soluble cationic resin,(b) an aqueous solution of a water soluble cationic resin and a water soluble cationic dye, or(c) an aqueous dispersion of a water soluble cationic resin, a cationic dispersing agent plus a water insoluble dye or pigment and, optionally, a cationic water soluble dye; andWith (2) an anionic component comprising(d) an aqueous solution of a water soluble anionic dye,(e) an anionic dispersing agent or an aqueous solution of an anionic dispersing agent,(f) an aqueous solution of an anionic dispersing agent and a water soluble anionic dye, or(g) an aqueous dispersion of an anionic dispersing agent plus a water insoluble dye or pigment an
    Type: Grant
    Filed: January 28, 1976
    Date of Patent: July 24, 1979
    Assignee: Sumitomo Chemical Company, Limited
    Inventors: Shigeru Juzu, Hiroyuki Okazaki, Yasuyuki Suzuki
  • Patent number: 4154951
    Abstract: A compound of the formula (1) ##STR1## in which X and X' stand for an optionally functionally modified carboxy or sulfo group and wherein the naphthalene nuclei may carry further non- chromophoric substituents and a process for their preparation. These compounds are valuable optical brighteners and can be applied by the methods known in this field.
    Type: Grant
    Filed: December 16, 1974
    Date of Patent: May 15, 1979
    Assignee: Hoechst Aktiengesellschaft
    Inventor: Ulrich Pintschovius
  • Patent number: 4151163
    Abstract: (Pyrazolinylphenylsulfonyl)-piperazines of the formula ##STR1## wherein R.sub.1 is unsubstituted or substituted alkyl, aralkyl or alkenyl, R.sub.2 is unsubstituted or substituted alkyl, aryl or aralkyl R.sub.3, R.sub.4, R.sub.5, R.sub.6, R.sub.7 and R.sub.8 are certain substituents and Y is an anion, their preparation as well as their use as optical brighteners are disclosed.
    Type: Grant
    Filed: December 5, 1977
    Date of Patent: April 24, 1979
    Assignee: Ciba-Geigy Corporation
    Inventors: Eduard Troxler, Christian Luthi
  • Patent number: 4147648
    Abstract: A brightening composition consisting of a mixture of brighteners and 0 to 99.995% by weight of a commercially available washing agent, said mixture containing at least two brighteners of the formula ##STR1## in which A and B independently of one another denote a radical of the formula ##STR2## in which M represents hydrogen or an ammonium, alkaline earth metal, amine salt or alkali metal ion, as well as a process for brightening organic textiles are disclosed.
    Type: Grant
    Filed: June 27, 1977
    Date of Patent: April 3, 1979
    Assignee: Ciba-Geigy Corporation
    Inventors: Franz Gunter, Claude Eckhardt
  • Patent number: 4136229
    Abstract: Security paper which immediately reveals an attempt to alter handwriting thereon by the use of an alkaline ink remover and which is characterized by the incorporation therein of a pyrenesulphonic acid or a metal salt thereof, particularly an alkali metal or alkaline earth metal salt.Security paper incorporating such an acid or salt exhibits a fluorescent coloration when contacted with an alkaline ink remover.
    Type: Grant
    Filed: October 25, 1977
    Date of Patent: January 23, 1979
    Assignee: Societe Anonyme dite: Arjomari-Prioux
    Inventors: Jean-Yves Godet, Giampaolo Bartoli
  • Patent number: 4118560
    Abstract: Novel 1,4-bis-styryl-phenyl and 4,4'-bis-styryl-biphenyl derivatives, a process for their preparation, a process for optically brightening organic materials on using said compounds as well as detergent compositions containing said compounds are disclosed.
    Type: Grant
    Filed: November 11, 1976
    Date of Patent: October 3, 1978
    Assignee: Ciba-Geigy Corporation
    Inventor: Kurt Weber
  • Patent number: 4106941
    Abstract: Interpolymers from monomers containing optical brightening moieties and solubilizing groups are useful in optical brightening compositions. Photographic elements containing these optical brightening compositions have excellent light stability.
    Type: Grant
    Filed: July 17, 1974
    Date of Patent: August 15, 1978
    Assignee: Eastman Kodak Company
    Inventors: Peter W. Scullard, John Figueras, Carl F. Holtz
  • Patent number: 4071466
    Abstract: Pyrazoline compounds of the formula ##STR1## wherein R represents C.sub.3 -C.sub.20 -alkyl and X, Y and Z independently of one another represent hydrogen, halogen, C.sub.1 -C.sub.4 -alkyl, trifluoromethyl, C.sub.1 -C.sub.4 -alkoxy, aryl or acylamino, are useful as optical brighteners for macromolecular materials.
    Type: Grant
    Filed: January 13, 1976
    Date of Patent: January 31, 1978
    Assignee: Bayer Aktiengesellschaft
    Inventors: Josef Schroeder, Carl-Wolfgang Schellhammer
  • Patent number: 4066830
    Abstract: The invention is directed to new benzoxazole-styryls of the formula ##STR1## wherein the rings A, B, C and D can be substituted, as well as processes for their preparation. The invention relates also to a process for optically brightening high-molecular organic materials on using said compounds.
    Type: Grant
    Filed: March 3, 1976
    Date of Patent: January 3, 1978
    Assignee: Ciba-Geigy Corporation
    Inventors: Geza Kormany, Guglielmo Kabas
  • Patent number: 4042320
    Abstract: Described are aqueous, stable, highly concentrated, finely dispersed, flowable preparations of dyestuffs and optical brighteners insoluble to difficultly soluble in water, which preparations have a low content of dispersing agent and a particle size smaller than 10.mu., particularly smaller than 2.mu.
    Type: Grant
    Filed: May 2, 1975
    Date of Patent: August 16, 1977
    Assignee: Ciba-Geigy AG
    Inventors: Carl Becker, Jacques Wegmann, Andres Schaub
  • Patent number: 4031273
    Abstract: Process for the continuous optical brightening of synthetic polyamide fibre material from organic solvents, whereinA. the fibre material is dry cleaned,B. at least one ionic optical brightener is applied to the material from a solution, emulsion or dispersion in a non-polar organic solvent,C. the material is intermediately dried,D. the optical brightener is developed in a hot aqueous acid bath, andE. the fibre material is subsequently thermofixed.
    Type: Grant
    Filed: August 25, 1975
    Date of Patent: June 21, 1977
    Assignee: Ciba-Geigy Corporation
    Inventors: Gerhard Reinert, Jack Fallows, Paul Dussy
  • Patent number: 4027346
    Abstract: A modifying process for polyester synthetic fiber products wherein said polyester synthetic fiber products are dipped into a treating liquor having an aggregation initiating temperature in the range of 65.degree. - 125.degree. C and then treated by heating them to temperatures at least 1.degree. C higher than said aggregation initiating temperature. Said treating liquor is prepared by adding to an aqueous dispersed liquid of a polyester polyether block copolymer (1) a anion-nonion or nonion surface active agent which serves to improve the high temperature stability of said block copolymer dispersed liquid, (2) an adsorption promoting or aggregation temperature adjusting agent which serves to increase the affinity of said block copolymer to the polyester synthetic fibers and improve the sorption power of said block copolymer and, if desired, (3) dyestuffs and carriers.
    Type: Grant
    Filed: April 23, 1975
    Date of Patent: June 7, 1977
    Assignee: Toyo Boseki Kabushiki Kaisha
    Inventors: Masahiro Wada, Masakazu Date
  • Patent number: 4025507
    Abstract: Disclosed are compounds of formula I, ##STR1## in which THE R.sub.1 's are the same and signify hydrogen or methyl,The R.sub.2 's are the same and signify hydrogen; C.sub.1-6 alkyl; cyclohexyl, unsubstituted or substituted by up to three C.sub.1-6 alkyl radicals; or benzyl, unsubstituted or substituted by up to two substituents selected from halogen, C.sub.1-6 alkoxy and C.sub.1-6 alkyl, andThe M's signify hydrogen or a nonchromophoric cation,Their production and use as optical brightening agents for cellulosic substrates, particularly paper substrates.
    Type: Grant
    Filed: June 25, 1974
    Date of Patent: May 24, 1977
    Assignee: Sandoz Ltd.
    Inventors: Fritz Fleck, Hans-Rudolf Schmid
  • Patent number: 4024298
    Abstract: An improved method for manufacturing a charge image storage dielectric capable of bistable storage is described. The storage dielectric is made by coating phosphor particles with a secondary emissive-forming substance, and then heating the coated particles to form secondary emissive material and simultaneously bond it to the surface of the phosphor particles.
    Type: Grant
    Filed: April 19, 1976
    Date of Patent: May 17, 1977
    Assignee: Tektronix, Inc.
    Inventor: Ralph Allen Mossman
  • Patent number: 4024071
    Abstract: The 4,4'-bis-[2",4"-bis-(diisopropanolamino)-s-triazin-6"-yl-amino]-stilbene-2 ,2'-disulphonic acid, its manufacture as well as its use as optical brightener for natural or synthetic polyamides and especially for paper is disclosed.
    Type: Grant
    Filed: January 7, 1976
    Date of Patent: May 17, 1977
    Assignee: Ciba-Geigy Corporation
    Inventor: Werner Fringeli
  • Patent number: 4022772
    Abstract: Styrene compounds of the formula ##STR1## wherein Q denotes one of the ring systems of the formulae ##STR2## wherein M represents oxygen or sulphur, Z represents hydrogen, lower alkyl or phenyl and n represents the number 1 or 2 and the rings A and B can each contain 1 to 3 non-chromophoric substituents.
    Type: Grant
    Filed: August 6, 1975
    Date of Patent: May 10, 1977
    Assignee: Ciba-Geigy Corporation
    Inventors: Geza Kormany, Guglielmo Kabas, Hans Schlapfer, Adolf Emil Siegrist
  • Patent number: 4016156
    Abstract: New distyryl compounds of the formula ##STR1## WHEREIN R.sub.x denotes an optionally modified sulphonic acid group, a sulphone group, an optionally functionally modified carboxylic acid group or the nitrile group, R.sub.x ' denotes an optionally functionally modified sulphonic acid group, a sulphone group, an optionally functionally modified carboxylic acid group, the nitrile group, alkyl, alkoxy, chlorine or hydrogen, and R.sub.y and R.sub.y ', independently of one another, denote hydrogen, the sulphonic acid group or a salt thereof, chlorine, alkyl or alkoxy; these compounds are particularly useful as optical brighteners.
    Type: Grant
    Filed: December 16, 1975
    Date of Patent: April 5, 1977
    Assignee: Ciba-Geigy Corporation
    Inventors: Kurt Weber, Geza Kormany
  • Patent number: 4013642
    Abstract: Heterocyclic compounds containing sulpho groups, a process for their preparation as well as a process for optically brightening organic materials on using said compounds are disclosed.
    Type: Grant
    Filed: June 10, 1975
    Date of Patent: March 22, 1977
    Assignee: Ciba-Geigy Corporation
    Inventor: Hans Rudolf Meyer
  • Patent number: 4008224
    Abstract: A new process for the manufacture of cyano-substituted stilbene compounds, new stilbene compounds as well as their use as fluorescent brighteners or as intermediates for the manufacture of fluorescent brighteners are provided.
    Type: Grant
    Filed: October 30, 1974
    Date of Patent: February 15, 1977
    Assignee: Ciba-Geigy Corporation
    Inventors: Adolf Emil Siegrist, Vincenzo Coviello
  • Patent number: 4008172
    Abstract: Agent for the preparation of the baths for brightening the color of and removing the greyness from white and pastel colored textiles which are made from synthetic fibers or which are provided with an easy-care finish and are made from cotton or blends thereof with synthetic fibers, which consists essentially of an organic polymer which is soluble or emulsifiable in water and is a homopolymer of acrylic or methacrylic acid or an ester or amide thereof, a copolymer of acrylic or methacrylic acid or an ester of amide thereof with acrylic or methacrylic acid alkylpolyalkylene glycol ester, a polyvinyl acetate or a water-soluble starch derivative, and a mixture thereof, and a fluorescent brightener which is soluble or dispersible in water.
    Type: Grant
    Filed: October 31, 1974
    Date of Patent: February 15, 1977
    Assignee: Ciba-Geigy Corporation
    Inventors: Richard von Rutte, Walter Gasser
  • Patent number: 4004048
    Abstract: Non-aqueous process for improving a functional property of flexible, natural and synthetic, organic polymeric substrates, such as textiles, film and paper, for example, polyethylene terephthalate or cotton fabric, by applying thereto an agent other than a dye, which agent is capable of imparting the desired improved functional property to the substrate, which process comprises:1. applying said agent to the substrate from a liquid medium;2. optionally, drying the substrate to remove the liquid while substantially retaining the agent on the substrate; and3. contacting the agent-treated substrate with a fluorocarbon fluid at a temperature and for a time sufficient to effect fixation of the agent on the substrate, said fluorocarbon having an atmospheric pressure boiling point of at least 25.degree. C., a fluorine to carbon atom ratio of at least 1.5 and a solubility parameter of not greater than 7.
    Type: Grant
    Filed: May 28, 1975
    Date of Patent: January 18, 1977
    Assignee: E. I. Du Pont de Nemours and Company
    Inventor: Harold L. Jackson
  • Patent number: 4001138
    Abstract: A stable weakly acid or neutral solution of quaternized fluorescent brighteners consisting essentially of a quaternized fluorescent brightener of the formula ##SPC1##Wherein Y.sub.1 represents hydrogen methyl, ethyl, methoxy, halogen or together with Y.sub.2 represents a fused benzene ring, Y.sub.2 represents hydrogen, methyl, ethyl, methoxy, halogen or together with Y.sub.1 or Y.sub.3 represents a fused benzene ring, Y.sub.3 represents hydrogen, methyl, ethyl, alkoxy with 1 to 4 carbon atoms, halogen or together with Y.sub.2 or Y.sub.4 represents a fused benzene ring, Y.sub.4 represents hydrogen, alkyl with 1 to 4 carbon atoms, methoxy, halogen or together with Y.sub.3 represents a fused benzene ring, Y.sub.5 represents hydrogen, alkyl with 1 to 4 carbon atoms or phenyl which is unsubstituted or substituted by methyl and/or methoxy, Y.sub.6 represents hydrogen, alkyl with 1 to 4 carbon atoms, alkylsulphonyl with 1 to 4 carbon atoms, methoxy or halogen, Y.sub.
    Type: Grant
    Filed: November 29, 1974
    Date of Patent: January 4, 1977
    Assignee: Ciba-Geigy Corporation
    Inventor: Frank Lohmann
  • Patent number: 3997556
    Abstract: Disclosed are anionic optical brightening agents, such agents being 1,3-diphenyl pyrazolines characterized by having, in the 4- or 5-position of the pyrazoline ring, a sulphoalkyl substituent, their production and use.
    Type: Grant
    Filed: August 4, 1975
    Date of Patent: December 14, 1976
    Assignee: Sandoz Ltd.
    Inventors: Ivan Joseph Bolton, Alec Victor Mercer
  • Patent number: 3996210
    Abstract: Monobenzoxazolylstilbenes of formula ##STR1## wherein R--O is lower alkoxy and stands in one of the positions 5 or 6,R.sub.1 is hydrogen or lower alkyl andR.sub.2 is hydrogen, chlorine or lower alkyl.
    Type: Grant
    Filed: June 8, 1970
    Date of Patent: December 7, 1976
    Assignee: Sandoz Ltd.
    Inventors: Fritz Fleck, Salvatore Valenti