Abstract: The method of applying adhesive to a substrate is performed by an installer donning a pair of shoes having pins extending from the undersurface thereof and using a notched spreading edge squeegee having an elongate handle to push adhesive from the configuration of a puddle to a configuration of parallel spaced apart lines of adhesive, the installer being capable of walking forwardly being the squeegee and further being capable of walking across the lines of adhesive without adversely affecting desired quality of adhesion.

Abstract: The present invention relates to an applicator for flowable materials which comprises a generally cylindrical housing having a chamber, a discharge opening, a wick projecting through said discharge opening, and a projecting structure for shielding the user from flowable materials and for preventing placement of the applicator in inappropriate receptacles. Further, the present invention relates to a storage and shipping rack for said applicators and to a method of dispensing flowable materials onto a surface. Preferably, the applicator is filled with metal coating and treating compositions such as aqueous acidic chromate compositions. Most preferably, the acidic compositions contain a very low concentration of a fluorinated surfactant.

Abstract: The invention encompasses methods of preventing corrosion of vessel sidewalls. In one aspect, the invention includes an anti-corrosion treatment method of reducing internal corrosion of an ammonium phosphate holding vessel comprising providing at least one quaternary-amine-comprising compound within the vessel. In another aspect, the invention includes a treatment method of reducing corrosion of a vessel sidewall surface comprising utilization of a quaternary amine to form a protective layer on the vessel sidewall surface. In another aspect, the invention includes an anti-corrosion treatment method of reducing corrosion of a vessel comprising: a) flowing a liquid into the vessel; b) adding at least one compound to the liquid, the compound being added to a concentration which exceeds the solubility of the compound in the liquid; and c) coating the compound onto an internal surface of the vessel to form a protective layer over the internal surface.

Abstract: A method of application of finning preventive agent in an apparatus for casting anodes for electrolyzing copper by pouring molten copper into the molds, in which the inner planes of the molds can be coated with the finning preventive agent in a reliable and efficient manner, is provided. Before pouring molten copper into the molds, silicon oil is automatically applied to the inner planes 2a.sub.1 to 2a.sub.10 of the molds M dividedly in three applications by industrial robots 24, 25 of a vertical multi-articulate type having brushes 30. An amount of silicon oil consumed is 4 to 10 cc for one mold.

Abstract: The present invention relates to formulations and methods for preventing surfaces of natural or mineral materials or cementitious products from becoming slippery, especially when wet. The formulations comprise a non-fluorine-containing acid; a fluorine-containing compound, hydrogen sulfate or acetic acid; and a surfactant.

Abstract: The abatement of bio-hazardous particulate materials, such as asbestos, has a high priority for providing children with a future. The method of the present invention involves abating such materials by encapsulating them in a simple and effective manner. The method uses a special formulation that when applied to a potentially bio-hazardous surface, such a coating on a substrate, seeps into the pores of the surface, encircles and encapsulates the particles. The formulation also bonds the encapsulated particles to the surface of the substrate carrying the coating. The results of the method are complete encapsulation of potentially bio-hazardous particulate matter found in a coating on a substrate, bonding of the encapsulated particles to the surface of the substrate, and finally, the sealed coating is resistant to impact and abrasion.

Abstract: The present invention relates to a process of depositing metals onto various substrates. Applications for which the present invention may be useful include the formation of catalysts such as those used in electrochemical applications, including fuel cells and the like, refining applications such as oil refining, automotive applications such as automotive catalytic converters, and other similar applications.

Abstract: A wipe-on clear protectant based on polyurethane is provided, which provides a finish that is durable and long lasting, is not injurious to the leather or artificial leather on which it is applied, in the instance of use on vinyl, impedes, rather than fosters, plasticizer migration, and is not slippery or tacky to the touch. In the preferred composition, polyurethane is dissolved in isopropyl alcohol, and ethylene glycol monobutyl ether is added, and the resulting liquid is wiped as a clear liquid onto the surface of the cleaned and dry leather or artificial leather produce which is to be protected. The finish dries clear, even, waterproof, smooth and without tackiness in less than thirty minutes.

Abstract: There are provided methods of lining the internal surface of a pipe, which includes first inserting two lining pigs into the pipe and then introducing a batch of resin thereinto, or inserting one lining pig between two batches of a resin, or first inserting a lining pig and then inserting two batches of a resin with another lining pig therebetween, or first introducing a lining pig made of a soft material capable of deforming so as to pass through a narrow-passing section and then introducing a batch of a resin into the pipe, causing the resin to move forward until the front end of the resin reaches an inner end of the pipe, and sucking the resin back from the inner end so as to line the internal surface of the pipe with the resin. There are also provided improved liquid blocking pigs for use in pipe lining treatment, each of such pigs comprises a spherical body made of a soft resilient material and a least one flexible liquid barrier diaphragm interposed in the spherical body.

Abstract: A wet wipe which includes a pattern bonded polypropylene nonwoven web adapted to provide a sustained controlled release to a surface of an aqueous alcoholic composition contained within the nonwoven web. The nonwoven web has a basis weight of from about 17 to about 100 grams per square meter and includes polypropylene meltblown fibers having diameters in a range of from about 0.01 to about 50 micrometers. The aqueous alcoholic composition contained within the polypropylene nonwoven web is present in a range of from about 300 to about 600 weight percent, based on a dry weight of the nonwoven web of 34 grams per square meter. The wet wipe provides a first release of the aqueous alcoholic composition in a range of from about 40 to about 70 weight percent, a second release in a range of from about 10 to about 25 weight percent, and a third release in a range of from about 5 to about 18 weight percent, of the composition originally present in the nonwoven web.

Abstract: A method for preventing the emission of fluorescence from polyalkylenenaphthalene-2,6-dicarboxylate, including mixing polyalkylenenaphthalene-2,6-dicarboxylate and at least one compound selected from cyclic imino esters and quinoxalines. The above cyclic imino esters and quinoxalines have an absorption intensity E, defined by the following expression: ##EQU1## wherein A is an absorbance measured in 1,1,2,2-tetrachloroethane at a concentration c (g/100 ml) and an optical path d (cm),of more than 200 at an ultraviolet wavelength range of 340 to 400 nm. And when a coating layer containing at least one ultraviolet absorber is formed on the surface of a molded article made of the above fluorescence-emission preventive mixture, a synergistic suppression of the emission of fluorescence can be obtained.

Abstract: A process for tipping surgical sutures includes dispensing tipping agent one drop at a time and contacting the suture portion to be tipped with the drop of tipping agent. A transversely oriented lifting/wiping string may be used to lift the suture into contact with the drop and may wipe away excess tipping agent. Alternatively, a transversely oriented string may be used to catch a drop and then place the drop onto the suture. The tipping agent absorbed into the tipped portion can then be cured and cut to provide a tipped suture. The tipping process and apparatus can be used in conjunction with a needle-suture assembly process. The process advantageously controls application of a droplet of tipping agent to minimize the amount of tipping agent used, thereby providing an aesthetic needle-suture attachment. Apparatus are disclosed for performing the process.

Abstract: Sulfonimide cure catalysts are used with aminoplast crosslinking agents and resins capable of reacting with aminoplast crosslinking agents to prepare heat curable compositions capable of crosslinking to form coatings and articles. Liquid or solid curable compositions may be prepared. Solid sulfonimide catalysts used in combination with solid glycoluril type crosslinking agents are well suited for powder coating systems containing hydroxy- and carboxy-functional resins.

Abstract: An apparatus applies dressing fluid to a bowling lane surface in a desired lane dressing pattern laterally across a plurality of zones on the bowling lane and longitudinally along a predetermined length of each of the zones. Each zone may be the width or a selected fractional width of one board across the bowling lane so that different discrete amounts of lane dressing can be applied to each board along a predetermined length. The apparatus includes a plurality of metering devices which supply lane dressing to corresponding lane dressing dispersion units which in turn supply lane dressing directly to an applicator. The applicator applies the lane dressing to the bowling lane according to the desired lane dressing pattern. A method is provided to supply discrete amounts of bowling lane dressing at desired incremental locations laterally across and longitudinally along a bowling lane.

Abstract: Various organosulfur gold compounds and their use for the production of gold decorations are known.The invention relates to new organosulfur gold compounds, to a process for their production and to their use for the production of preparations for producing a gold decoration on firing-resistant substrates.The gold compounds according to the invention are obtainable from monogold(I) dimercaptosuccinic acid and compounds of similar structure by dissolution thereof in water in the presence of a base and precipitation by acidification and, if desired, repetition of the dissolving and precipitating steps. The gold compounds according to the invention are characterized by a gold content of 60 to 90% by weight, an atomic ratio of greater than 0.7 to 4. Preferred gold compounds are soluble in water and are suitable as a constituent of organic/aqueous and exclusively aqueous bright and burnished gold preparations for the decoration of glass, porcelain and ceramic.

Abstract: A method is provided for fabricating thin films having various optical properties is provided. The disclosed method includes preparing a colloidal suspension and depositing the suspension on a substrate using a coating cylinder. The disclosed method finds particular utility in the area of manufacturing dielectric mirrors and non-reflecting films.

Abstract: A method of and apparatus for employing a surfactant which is provided in order to assist in the release from each other of mold components of a multipart mold employed in the molding of polymeric articles; for instance, such as a hydrophilic contact lens, upon completion of the molding process for the polymeric articles. The surfactant is applied in the form of a film or coating on surface portions of one of the mold components in order to facilitate the disengagement between the mold components during demolding, and the removal of excess polymeric molding material adhesively deposited on surfaces thereon.

Abstract: A process and an apparatus for producing a preform for plastic optical fiber having a refractive index distribution in which the refractive index is gradually decreased from the center of the preform toward the outer periphery thereof, by depositing a deposition layer comprising a polymer A (refractive index: N.sub.a) and a refractive index modifier having a refractive index different from that of the polymer A onto a surface of a rod member rotating about an axis thereof, by use of vapor-phase deposition based on a CVD (Chemical Vapor Deposition) process, or a coating process. A plastic optical fiber preform comprising deposition layers having a gradually decreasing refractive index distribution is formed by changing the mixing ratio between the polymer A and the refractive index modifier constituting the deposition layer.

Abstract: A composition useful for preparation of a graffiti-resistant barrier coating, related methods and compositions. The composition comprises from about 0.1 to about 30 percent by weight polyvinyl alcohol of molecular weight from about 7,000 to about 120,000 and being at least about 50% hydrolyzed; from about 0.1 to about 30 percent by weight non-stick agent such as silicone or polytetrafluoroethylene; and from about 0.1 to about 40 percent by weight adhesion promoter such as a urethane composition.

Abstract: A method by process for providing a liquid-free, toxic-free, environmentally friendly, non-transfiguring, flame and fire retardant, immersion-proof, non-pellicular and intra-matrix type aqueous repellent protective barrier to preferred substrates by various related embodiments, with particular utility toward dermal materials, both natural and synthesized. Methods enable durable and complete `breathable` treatments that are generally capable of virtual weightlessness and invisibility, without utilization of liquids. Complete process is particularly adaptable to `pocketable` packageability that is extremely cost-effective, undamageable, and longevous in shelf-life.

Abstract: An apparatus applies dressing fluid to a bowling lane surface in a discrete pattern laterally across a plurality of zones on the bowling lane. A carriage, for movement along a bowling lane, has an applicator mounted thereon for applying the dressing fluid to the bowling lane surface. Dressing fluid is supplied from a reservoir by means off a plurality of pulse valves which supply the dressing fluid to a plurality of fluid dispersion chambers, each having an inlet connected to one of the pulse valves and having an outlet positioned to apply dressing fluid to the applicator. The outlet has a width equal to the width of one of the zones. A controller is provided for selectively activating each of the pulse valves to discharge a discrete amount of fluid dressing into each dispersion chamber. Each zone may be the width of one board across the bowling alley so that different discrete amounts of oil can be applied to each board.

Abstract: A process for producing a preform for plastic optical fiber having a refractive index distribution in which the refractive index is gradually decreased from the center of the preform toward the outer periphery thereof, by depositing a deposition layer comprising a polymer A (refractive index: N.sub.a) and a refractive index modifier having a refractive index different from that of the polymer A onto an inner surface of a hollow cylindrical member rotating about an axis thereof, by use of vapor-phase deposition based on a CVD (Chemical Vapor Deposition) process, or a coating process. A plastic optical fiber preform comprising deposition layers having a gradually increasing refractive index distribution is formed by changing the mixing ratio between the polymer A and the refractive index modifier constituting the deposition layer.

Abstract: A process and device for the preparation of coatings on wires or fiber-like materials by mixing one or more polymers which contain carboxyl and/or amide groups (A) and with at least two carboxyl and/or amide groups, a hydroxyl number of less than 130 and a number average molecular weight of 200 to 5000, in the liquid state, with one or more polyisocyanates (B) with at least two free isocyanate groups in the molecule and a number average molecular weight of 200 to 3000, in the liquid state, and optionally one or more other components (C) which are normally present in lacquers, in the liquid state, continuously immediately before application in a ratio such that 0.5 to 5.0 isocyanate groups are allotted to each carboxyl group or that 0.02 to 2.

Abstract: A composite membrane including a microporous polymer film having a high air permeability as a support and a non-porous gas or vapor separating coating having a thickness of not more than 15 .mu.m is provided. The separation factor and flux of the membrane are substantially equal to those of the coating. Also provided is a process for the manufacture of a composite membrane including a support and a gas or vapor separating coating by drawing a polymeric film to which the coating material has been applied, and increasing the viscosity of the coating during drawing.

Abstract: A method for patterned metallization of substrate surfaces, especially circuit boards, even three-dimensional ones, by using electromagnetic UV radiation, particularly from an excimer laser. In the method a primer layer is applied to the full substrate surface in the area of a metal layer that is subsequently applied; insulating channels then are made in the primer layer by complete removal of the primer in certain areas by the action of electromagnetic radiation in the UV range; and afterward the remaining patterned primer layer is provided with the metal layer to form conductor strips. The method makes it possible to create insulating channels with extremely sharp contours in the primer layer on the surface of even three-dimensional, electronic circuit media.

Abstract: A brush for the application of nail varnish, or a similar product, includes a tuft obtained from a bundle of bristles which are substantially parallel and folded in two halfway along their length. The bristles are fixed at the folded part in a housing opening at the end of the rod. The bristles have cross-sections bounded by a circle of constant diameter and are chosen from at least two groups. The bristles of one group are arranged so as to exhibit a different mechanical behavior in flexure to that of the bristles of the other group so that these groups give a brush tuft which is open to the air and spread out, with relatively large spaces between bristles to promote good capillary action for varnishes whose viscosity may vary over a wide range.

Abstract: An applicator for coating sheet material has a relatively thick compressible, saturable layer for engaging the sheet which is effective to apply an optically clear coating when saturated with a flood of liquid coating composition. The coated article has virtually no visible defects and has high optical transmission and low haze.

Abstract: A method and apparatus for bonding, coating and/or dyeing yarn which impregnates the yarn with a solution containing at least one of a polymer resin, coating or dyestuff dissolved in a flammable solvent/carrier. The solvent/carrier in the impregnated yarn is then ignited to burn away a part of the solvent/carrier from the yarn. A portion of the solvent/carrier remains in the yarn to prevent damage to the yarn. The yarn containing the residual solvent/carrier then is dried at an elevated temperature.

Abstract: An automatic liquid lubricant application device for applying a liquid lubricant to the inside of a hole in a workpiece includes an applicator for insertion into the hole for application of the lubricant. The applicator includes a perforated tube surrounded by a sleeve of wicking material. A shoulder surrounding the applicator is sized to engage the workpiece on the marginal portions around the hole. The shoulder is mounted for limited axial movement when pressed against the workpiece. A fluid flow channel connected at one end to a source of lubricant is connected at the other end to the perforated tube. A flow control device for controlling the flow of lubricant in the channel is actuated by axial movement of the shoulder when engaging the workpiece.

Abstract: A process for producing an anti-slip article by preparing an aqueous dispersion containing a copolymer of styrene and a diene in a ratio by weight of from 20:80 to 80:20, and applying the aqueous dispersion onto a non-water-absorbing article.

Abstract: A membrane and electrode structure is formed by surface hydrolyzing an ion exchange membrane and then applying electrode ink of catalytically active particles on the surface of the membrane. The membrane and electrode structure of the present invention is particularly useful in fuel cells and batteries. The inventive process prevents the membrane from swelling or distorting following application of the electrode ink and also improves adhesion between the electrode ink layer and the surface of the membrane.

Abstract: A method and apparatus for applying a lubricant coating to surgical needles utilizes a belt coating system with two endless belts. The endless belts have confronting running sides and are rotated in opposite directions for feeding the surgical needles therebetween. The needles are fed between the confronting running sides and are pressed lightly between the endless belts, whose surfaces have been wetted with the lubricant solution. The needles are cured after coating.

Abstract: A vehicle masking material and method of use. The masking material in one embodiment includes polyvinyl alcohol, ethyl alcohol, glycerine or triethylene glycol, a surfactant, and water. The masking material is applied to a surface which is to be protected from paint overspray or other mechanical process, allowed to dry, and paint is applied. After drying of the paint, the masking material is removed by peeling or water washing.

Abstract: An oil applicator for applying a film of oil to a strip of metal has a hollow tubular shaft having a porous, oil absorbent sleeve, with oil sprays spraying oil onto the surface of the sleeve and a vacuum drawn through the hollow of the shaft to draw excess oil through apertures in the shaft wall for collection in a housing. A casing is provided that contains the applicator roll and a slot in the wall of the casing communicates with a duct through which a second vacuum is drawn which removes excess oil that may be applied to the strip of metal and collects the same in a second housing.

Abstract: The invention relates to plastisols which prevent a yellowing of top coats applied thereon, to a process for their preparation and to their use. The plastisols based on PVC or methacryl contain, in addition to basic adhesion promoters, aldehydes, ketones, their derivatives, oligomers or mixtures of same.

Abstract: A padding powder suspension or slurry and method for applying a padding powder for lubricating components of printing, copy and facsimile machines such as the photoreceptor drum, photoreceptor belt, wiper and doctor blade. The padding powder is comprised of a mica-group mineral or a mixture of a mica-group mineral and calcium stearate. The method comprises mixing the padding powder with a solvent, for example alcohol, to form a different substance. The mica-group mineral is inert so it does not dissolve in the alcohol. A suspension agent or surfactant may also be mixed with the padding powder and alcohol to keep the padding powder suspended in the alcohol for a longer period of time. The resulting suspension or slurry is then applied on the components. The suspension or slurry may easily be applied with brushes, spray devices, sponge materials or a soft cloth.

Abstract: A method by process for providing a liquid-free, toxic-free, environmentally friendly, non-transfiguring, flame and fire retardant, immersion-proof, non-pellicular and intra-matrix type aqueous repellent protective barrier to preferred substrates by various related embodiments, with particular utility toward dermal materials, both natural and synthesized. Methods enable durable and complete `breathable` treatments that are generally capable of virtual weightlessness and invisibility, without utilization of liquids. Complete process is particularly adaptable to `pocketable` packageability that is extremely cost-effective, undamageable, and longevous in shelf-life.

Abstract: A membrane and electrode structure is formed by applying ink of catalytically active particles on the surface of the membrane. The electrode ink comprises:(a) catalytically active particles;(b) a hydrocarbon having at least one ether, epoxy or ketone linkage and an alcohol group, preferably 1 methoxy 2 propanol; and(c) optionally, perfluorinated sulfonyl fluoride polymer or perfluorinated sulfonic acid polymer.

Abstract: A fabric covering adapted to be placed over the suction head of a conventional electric broom to prevent the scratching and/or marring of a non-carpeted floor surface. The fabric covering includes first and second opposed openings formed therethrough. The first opening includes an elastic band positioned in a peripheral hem to gather the covering about the suction head. The second opening is substantially, identically shaped as the suction opening formed in the bottom surface of the suction head. Therefore, once the covering is placed over the suction head, no portion of the suction head can contact either the floor surface or any inanimate objects which may be contacted when the electric broom is moved about the floor.

Abstract: A method and apparatus are provided for imparting a sliding capacity to a wire which is fed through at least one loop of a strand of material which has been steeped in a lubricant such as paraffin or wax. Preferably, the strand of material is advanced at a speed which is less than the feed speed of the wire. The apparatus includes means for feeding the wire and means for advancing the strand of material around the wire. The apparatus also includes a compensating device which adjusts the tension of the strand of material and checking device for automatically a checking the lubricating operation.

Abstract: A liquid anticorrosion composition adapted for application to ferrous tubular goods is provided comprising an aqueous solution of cyclohexylammonium benzoate and a benzoate salt, which is preferably prepared by reacting cyclohexylamine with excess sodium benzoate in an aqueous alcohol solvent. A sealable thread protector end cap which protects the precisely machined threads from physical abuse and which isolates or seals from the environment the corrosion inhibitor composition is also provided.

Abstract: In one form of the invention, an electronic device having a conformally coated Faraday cage, comprising a non-conductive conformal layer (30) substantially coveting the electronic device (10, 12) and a conductive conformal layer (34) substantially coveting the non-conductive conformal layer.

Abstract: Apparatus and method for applying a chemiluminescent fluid to an object. Two chemiluminescent fluid components are mixed within a reservoir. The mixed chemiluminescent fluid then flows through a porous applicator element mounted in a passageway in communication with the reservoir interior. The porous applicator element is in the form of a writing nib which may be utilized to manually apply the chemiluminescent fluid to an object.

Abstract: Novel gold(I) mercaptocarboxylic acid esters of the formula (I) ##STR1## in which X is a C.sub.1 - to C.sub.3 alkylene group and Z is a group from the series tricyclo(5,2,1,0.sup.2.6)decane-8- or -9-yl or tricyclo (5,2,1,0.sup.2.6)decyl-3- or -4-methyl. These esters can be prepared from mercaptocarboxylic acid esters of the formula (II) ##STR2## and from a gold(I) chloride-dialkylsulfide complex. The novel esters can be used in gold preparations for gilding solid bases, especially ceramic materials. Compared to known gold(I) mercaptocarboxylic acid esters, the novel esters result in considerably shorter drying times for gold preparations.

Abstract: A vehicle masking material and method of use. The masking material in one embodiment includes polyvinyl alcohol, ethyl alcohol, a plasticizer, a surfactant composition including a functional derivative of a fluorinated alkyl chain, and water. The masking material is applied to a surface which is to be protected from paint overspray or other mechanical process, allowed to dry, and paint is applied. After drying of the paint, the masking material is removed by peeling or water washing.

Abstract: Methods are disclosed for coating flat or curved planar surfaces by flowing a coating material through a porous applicator onto the surface of the object to be coated. Menisci of the coating material are maintained between the porous applicator and the surface of the object to be coated by attractive forces between the coating material and the surface of the object. Thin, uniform coating thicknesses, e.g., less than about 1 micron, and conformal coatings of objects having irregular surfaces can be obtained. The methods are useful, for example, for coating objects such as flat panel displays, optical devices, silicon and germanium wafers, and hybrid circuit boards.

Abstract: An item of footwear which has become scuffed or worn, or which is to be protected against wear, on its leather or leather-like external surfaces, is subjected to a preliminary cleaning. Thereafter, a coating of polyurethane elastomer dispersed in water, and possibly extended by acrylic resin dispersed in water, further including a colorant, a defoamer and a wetting agent, is brushed or swabbed onto the surface. The water evaporates, leaving a thin, flexible, scuff-resistant coating, the color of which covers and hides discoloration and scuffs on the original surface.

Abstract: A curable composition comprising:a) an aqueous dispersion of a Polymer having a MWt of at least 50,000, which is insoluble in water and which contains silane groups;B) a solution or dispersion of a Polymer which has a MWt between 300 and 20,000, comprising at least two silane groups and also comprising covalently bonded cationic hydrophilic groups the ratio of the Polymer (A) to the Polymer (B) being in the range 40:1 to 1:4.

Abstract: Sulfonimide cure catalysts are used with aminoplast crosslinking agents and resins capable of reacting with aminoplast crosslinking agents to prepare heat curable compositions capable of crosslinking to form coatings and articles. Liquid or solid curable compositions may be prepared. Solid sulfonimide catalysts used in combination with solid glycoluril type crosslinking agents are well suited for powder coating systems containing hydroxy- and carboxyfunctional resins.

Abstract: The disclosure relates to a metal oxide film formed on a glass substrate by the so-gel process with using a solution of a metal alkoxide. To afford water repellency to the oxide film, a fluoroalkylsilane is mixed with an alkoxysilane solution in the molar ratio of the alkoxysilane to the fluoroalkylsilane ranging from 1:10 to 10:1. Then, the mixed solution is diluted with a solvent such that the total concentration of the alkoxysilane and the fluoroalkylsilane is from 1 to 10 wt % in a diluted solution. Then, water in the amount of 100 mol % to 1000 mol % of the total amounts of the fluoroalkylsilane and the alkoxysilane is added to the diluted solution so as to partially hydrolyze the fluoroalkylsilane and the alkoxysilane, thereby forming a sol. Then, the sol is applied to the glass substrate, and the coated glass substrate is heated so as to form the metal oxide film thereon.