Plural Ink Receptive Layers Patents (Class 428/32.24)
  • Patent number: 11345820
    Abstract: Hollow particles containing monocrystalline titanium oxide and silica, and having a titanium oxide content of 86.0-99.5 mol % and a silica content of 0.5-14.0 mol %; and a method of producing the particles. A white ink containing the hollow particles as a coloring agent; the use of the white ink in inkjet recording; and a method for inkjet recording using the white ink.
    Type: Grant
    Filed: December 10, 2018
    Date of Patent: May 31, 2022
    Assignee: Nippon Kayaku Kabushiki Kaisha
    Inventors: Yukihiro Hara, Akihiro Nohara
  • Patent number: 11236243
    Abstract: The present invention provides energy curable ink and coating compositions that comprise polymerizable compounds, photoinitiators, and colorants. The polymerizable compounds comprise one or more polymerizable monomers and/or oligomers, wherein at least a portion is 3-methyl-1,5-pentanediol diacrylate. The inks and coatings of the invention exhibit excellent print properties after UV-LED, standard UV mercury vapor lamp, and electron beam cure.
    Type: Grant
    Filed: September 10, 2018
    Date of Patent: February 1, 2022
    Assignee: Sun Chemical Corporation
    Inventors: Mathew C. Mathew, David Biro
  • Patent number: 11098214
    Abstract: Provided herein is an inkjet dye-sublimation ink composition that is formulated to interact with an immobilizing composition such that the ink composition coagulates on the surface of an absorptive substrate, thereby substantially limiting soaking of the ink composition into the substrate. Also provided are a printing process and a printing machine, wherein the ink composition is directly printed on the substrate concomitantly with the immobilizing composition, and thereafter undergo heat-pressing to afford a dye-sublimation transfer of the dye to the substrate, thereby forming an image which is characterized by sharp and well defined edges of the dyed areas.
    Type: Grant
    Filed: October 30, 2017
    Date of Patent: August 24, 2021
    Assignee: Kornit Digital Ltd.
    Inventors: Allon Shimoni, Jacob Mozel
  • Patent number: 10933678
    Abstract: The present invention relates to: an ink-receiving layer composition for a decorative member, the composition comprising an acrylic emulsion, a metal salt, and organic particles or inorganic particles; a decorative member comprising a base layer, a printing layer formed on the base layer, and an ink-receiving layer disposed between the base layer and the printing layer and formed of a composition comprising an acrylic emulsion, a metal salt, and organic particles or inorganic particles; and a method for manufacturing a decorative member, the method comprising a step for preparing a base layer in a flat state, a step for coating a composition comprising an acrylic emulsion, a metal salt, and organic particles or inorganic particles on the base layer, a step for drying or UV curing the coated composition to form an ink-receiving layer, and a step for forming a printing layer on the ink-receiving layer.
    Type: Grant
    Filed: December 21, 2016
    Date of Patent: March 2, 2021
    Assignee: LG HAUSYS, LTD.
    Inventors: Ji-Yeon Seo, Heon-Jo Kim, Sam-Hun Yun
  • Patent number: 10906345
    Abstract: A fabric print medium containing a fabric base substrate, a primary coating composition that includes a polymeric binder and filler particles; and an image-receiving coating composition that includes, at least, a first crosslinked polymeric network and a second crosslinked polymeric network, that is applied over the primary coating composition. The fabric base substrate includes a surface energy-controlling agent. Also disclosed are the method for making such fabric print medium and the method for producing printed images using said material.
    Type: Grant
    Filed: September 9, 2016
    Date of Patent: February 2, 2021
    Assignee: Hewlett-Packard Development Company, L.P.
    Inventor: Xiaoqi Zhou
  • Patent number: 10906343
    Abstract: The present disclosure is drawn to a fabric print medium including a fabric substrate, a primary coating layer, and a secondary coating layer. The fabric substrate can have a first side and a second side. The primary coating layer can be applied to the first side of the fabric substrate at a thickness from 2 ?m to 250 ?m with a dry coat weight ranging from about 5 gsm to about 300 gsm and can include a polymeric binder and filler particles. The secondary coating layer can be applied to the primary coating layer at a thickness from 1 ?m to 50 ?m with a dry coat weight ranging from 0.5 gsm to 50 gsm and can include a first crosslinked polymeric network and a second crosslinked polymeric network. The primary coating layer can be two or more times thicker than the secondary coating layer.
    Type: Grant
    Filed: May 12, 2016
    Date of Patent: February 2, 2021
    Assignee: Hewlett-Packard Development Company, L.P.
    Inventors: Xiaoqi Zhou, Francois K. Pirayesh, Silke Courtenay
  • Patent number: 10899146
    Abstract: Provided herein are methods of obtaining good photocured-ink adhesion to low surface energy materials. The methods have greatly improved adhesion of photocured ink on low surface energy materials, including those that are subjected to high humidity or wet environments. The methods take into account the glass transition temperature (Tg) of the materials and the onset for the glass transition temperature, including ink applied to an exposed surface of the material at an elevated temperature that is close to the Tg of the material. The ink is allowed to sit briefly or soak, such as for more than 1 second, before the ink is cured. The ink may be photocured. Furthermore, the methods do not require solvents or surface treatment, including plasma or corona treatments, to obtain good ink adhesion.
    Type: Grant
    Filed: April 27, 2020
    Date of Patent: January 26, 2021
    Assignee: ALIGN TECHNOLOGY, INC.
    Inventor: Michael Christopher Cole
  • Patent number: 10723161
    Abstract: The present disclosure is drawn to leveling compositions, which can include from 80 wt % to 95 wt % water, from 0.5 wt % to 15 wt % organic solvent, and from 0.2 wt % to 6 wt % surfactant. The leveling compositions can further include from 1 wt % to 10 wt % cationic ionene polymer having a weight average molecular weight from 100 Mw to 8000 Mw, and from 1 wt % to 10 wt % polymeric binder.
    Type: Grant
    Filed: September 18, 2015
    Date of Patent: July 28, 2020
    Assignee: Hewlett-Packard Development Company, L.P.
    Inventors: Paul C. Landrum, Xiaoqi Zhou, Xulong Fu, Francois K. Pirayesh
  • Patent number: 10596831
    Abstract: An inkjet printing method including the steps of applying a first ink to a printing medium and applying a second ink to the printing medium so as to at least overlap a region provided with the first ink, wherein the first ink is an aqueous ink containing silver particles, the second ink is an aqueous ink containing an anionic dye, the printing medium includes an ink-receiving layer containing at least one cationic compound selected from a group consisting of a polyvalent metal salt and a salt of a cationic resin, and the content (g/m2) of the cationic compound per unit area of the ink-receiving layer is 0.20 g/m2 or more.
    Type: Grant
    Filed: May 11, 2018
    Date of Patent: March 24, 2020
    Assignee: CANON KABUSHIKI KAISHA
    Inventors: Kenichi Iida, Kazuhiko Araki, Tetsufumi Shiba, Takatoshi Tanaka
  • Patent number: 10301478
    Abstract: An aqueous primer coating composition to a substrate comprises an aqueous cationic polyurethane and an aqueous polymer of oxazoline or N-vinylpyrrolidone. Also disclosed is a method applying the coating composition to the substrate and an electrophotographical printing medium coated with the coating composition.
    Type: Grant
    Filed: May 16, 2017
    Date of Patent: May 28, 2019
    Assignee: HERCULES LLC
    Inventors: Venkataramanan Seshadri, Charles Joseph Wasserman, Biswajit Ghosh, Byoungchul Lee
  • Patent number: 10011135
    Abstract: A recording medium includes a substrate and an ink-receiving layer as the top layer. The ink-receiving layer contains inorganic particles. The inorganic particles contain cationized colloidal silica, alumina hydrate, and fumed alumina. A content of the cationized colloidal silica is 5% or more by mass and 25% or less by mass based on a content of the inorganic particles. The mass ratio of the alumina hydrate to the fumed alumina (alumina hydrate content:fumed alumina content) is from 95:5 to 55:45.
    Type: Grant
    Filed: April 7, 2017
    Date of Patent: July 3, 2018
    Assignee: Canon Kabushiki Kaisha
    Inventors: Naoya Hatta, Tetsuro Noguchi, Kazuhiko Araki, Arika Tanaka, Shoichi Takeda
  • Patent number: 9816000
    Abstract: An embodiment of the present disclosure is directed to a wet sacrificial coating composition. The coating composition is made from ingredients including: a waxy starch; at least one cross-linker; at least one hygroscopic material; at least one surfactant; and a liquid carrier.
    Type: Grant
    Filed: March 23, 2015
    Date of Patent: November 14, 2017
    Assignee: XEROX CORPORATION
    Inventors: Guiqin Song, Marcel P. Breton, Gordon Sisler, Brynn Dooley
  • Patent number: 9745700
    Abstract: A composition is provided, which comprises a water-soluble salt of a divalent metal; a complexing agent having an affinity for the divalent metal; and an optical brightening agent. Methods of using the composition, and recording sheets which include the composition, are also disclosed.
    Type: Grant
    Filed: July 23, 2014
    Date of Patent: August 29, 2017
    Assignee: INTERNATIONAL PAPER COMPANY
    Inventors: Zheng Tan, Jingxiu Wan, Benny J. Skaggs, Sen Yang, Benjamin Thomas Liguzinski
  • Patent number: 9662921
    Abstract: A recording medium including a substrate and an ink receiving layer on the substrate, the ink receiving layer containing inorganic particles and a water-soluble resin. The recording medium has an HM1 of 40 N/mm2 or less and has a rate of change of HM2 to HM1 of 400% or less. HM1 is a Martens hardness when an indenter is pushed at a 500 mN load over 180 seconds from a surface of the recording medium into a 1 ?m depth in a thickness direction thereof. HM2 is a Martens hardness when the indenter is pushed up to a position where the indenter is not in contact with the surface and is then pushed at a 500 mN load over 180 seconds from a pressing starting position into a 1 ?m depth in the thickness direction at the same point as that at which the indenter is first pushed.
    Type: Grant
    Filed: March 1, 2016
    Date of Patent: May 30, 2017
    Assignee: Canon Kabushiki Kaisha
    Inventors: Takashi Sugiura, Shinya Yumoto, Naotoshi Miyamachi, Tetsuro Noguchi, Hisao Kamo, Kazuhiko Araki, Ryo Taguri
  • Patent number: 9437843
    Abstract: The OLED display device includes a substrate, a first electrode located on the substrate, a pixel defining layer located on the first electrode to expose a part of the first electrode, a fluorine-based polymer layer located on the pixel defining layer, an organic layer located on the first electrode, and a second electrode located on the entire surface of the substrate. The method of manufacturing the OLED display device includes forming a first electrode on a substrate, forming a pixel defining layer on the first electrode, forming a fluorine-based polymer layer on the pixel defining layer, patterning the fluorine-based polymer layer and the pixel defining layer by laser ablation to open a part of the first electrode, forming an organic layer on the opened first electrode, and forming a second electrode on the entire surface of the substrate.
    Type: Grant
    Filed: August 14, 2013
    Date of Patent: September 6, 2016
    Assignee: Samsung Display Co., Ltd.
    Inventor: Min-Chul Suh
  • Patent number: 9308763
    Abstract: A printable recording material containing an opaque supporting substrate; a hydrophobic layer; an ink vehicle-receiving layer having a two-layer structure or having bimodal pore size distribution; and an ink colorant-receiving layer comprising inorganic particles. Also disclosed are the method for making such material and the method for producing printed images using said printable recording material.
    Type: Grant
    Filed: July 9, 2012
    Date of Patent: April 12, 2016
    Assignee: Hewlett-Packard Development Company, L.P.
    Inventors: Xiaoqi Zhou, Hongqian Wang, David Edmondson
  • Patent number: 9180716
    Abstract: A printable recording material that contains an opaque supporting substrate; a resin-rich barrier layer; a coating composition with bimodal pore size distribution; and an ink colorant-receiving layer. Also disclosed herein are the method for making such material and the method for producing printed images using said printable recording material.
    Type: Grant
    Filed: July 9, 2012
    Date of Patent: November 10, 2015
    Assignee: Hewlett-Packard Development Company, L.P.
    Inventors: Hongqian Wang, Xiaoqi Zhou, David Edmondson
  • Patent number: 9126420
    Abstract: In a multi-layer printer, the base white layer that is applied during printing is modified using the image to be printed. By altering the white layer to reflect the density of the top image, it is easier to reach saturation (density/gamut) without adding large amounts of ink. Thus, such undesirable side effects, such as gloss-banding are avoided.
    Type: Grant
    Filed: June 4, 2013
    Date of Patent: September 8, 2015
    Assignee: Electronics for Imaging, Inc.
    Inventors: Peter Heath, Dwight Cram, Bryan Ko, Joseph A. Lahut
  • Patent number: 9044986
    Abstract: Methods, materials, and systems for texturizing mold surfaces is disclosed. In one method and system of the invention, a first step involves generating a graphics file of a desired texture pattern. The graphics file is subsequently output to an ink jet printer, which is configured to print using an acid-etch resist ink. The acid-etch resist ink is formulated to provide optimal properties for ink jet printing, while also providing excellent acid-etch resist and superior handling properties. The acid-etch resist ink is printed onto a sheet of a carrier substrate that allows the acid-etch resist to be transferred to a mold surface, after which the mold surface is etched with a strong acid.
    Type: Grant
    Filed: December 16, 2011
    Date of Patent: June 2, 2015
    Assignee: IKONICS CORPORATION
    Inventors: Toshifumi Komatsu, Jeremy W. Peterson, Alexander S. Gybin
  • Patent number: 9005725
    Abstract: Transparent ink-jet recording films, compositions, and methods are disclosed. Such films do not exhibit excessive ink drying times. These films exhibit high maximum optical densities and have low haze values. These films are useful for medical imaging.
    Type: Grant
    Filed: January 20, 2015
    Date of Patent: April 14, 2015
    Assignee: Carestream Health, Inc.
    Inventors: Sharon M. Simpson, William D. Devine, William J. Ruzinsky
  • Patent number: 8974877
    Abstract: The present invention concerns a print medium for inkjet printing and a method of producing such a print medium. In particular, the present invention is directed to a print medium comprising a base layer having a first side and a reverse side, an absorptive layer being in contact with the first side of the base layer, and a topcoat being in contact with the absorptive layer.
    Type: Grant
    Filed: June 30, 2011
    Date of Patent: March 10, 2015
    Assignee: Omya International AG
    Inventors: Patrick A. C. Gane, Vesa Kukkamo, Catherine Jean Ridgway
  • Patent number: 8974878
    Abstract: Transparent ink-jet recording films, compositions, and methods are disclosed. Such films do not exhibit excessive ink drying times. These films exhibit high maximum optical densities and have low haze values. These films are useful for medical imaging.
    Type: Grant
    Filed: August 9, 2011
    Date of Patent: March 10, 2015
    Assignee: Carestream Health, Inc.
    Inventors: Sharon M. Simpson, William D. Devine, William J. Ruzinsky
  • Patent number: 8962111
    Abstract: The present invention provides for a print media comprising an image receiving layer comprising a latex ink film-forming aid. The present invention also provides for a method of forming an image using a latex ink and a print media coated with an image receiving layer comprising a latex ink film-forming aid. The present invention also provides for a printed product comprising a latex ink printed on a print media comprising an image receiving layer comprising a latex ink film-forming aid.
    Type: Grant
    Filed: October 25, 2010
    Date of Patent: February 24, 2015
    Assignee: Hewlett-Packard Development Company, L.P.
    Inventors: Xiaoqi Zhou, Xulong Fu, David Edmondson
  • Patent number: 8945693
    Abstract: Printable articles having a single coating/ink receiving layer are disclosed. In addition, printable articles having a single coating/ink receiving layer disposed on the printable article and a second coating layer disposed on the coating/ink receiving layer are disclosed.
    Type: Grant
    Filed: April 10, 2007
    Date of Patent: February 3, 2015
    Assignee: Hewlett-Packard Development Company, L.P.
    Inventors: Bor-Jiunn Niu, Dheya Alfekri
  • Patent number: 8906477
    Abstract: A recording medium includes a substrate and ink receiving layers including a first ink receiving layer and a second ink receiving layer in that order. The first ink receiving layer contains first inorganic particles including alumina and silica particles, and a first binder. In the first ink receiving layer, the mass ratio of the first binder to the first inorganic particles is from 0.13 to 0.33, and the mass ratio of the alumina particles to the silica particles is from 0.43 to 2.33. The second ink receiving layer contains second inorganic particles and a second binder. The mass ratio of the second binder to the second inorganic particles is from 0.05 to 0.30. The second ink receiving layer has a thickness from 2 ?m to 10 ?m, and the total thickness of ink receiving layers is from 10 ?m to 30 ?m.
    Type: Grant
    Filed: February 14, 2014
    Date of Patent: December 9, 2014
    Assignee: Canon Kabushiki Kaisha
    Inventors: Shinya Yumoto, Yasuhiro Nito
  • Patent number: 8900677
    Abstract: A print medium includes a first layer on at least one of a first side and a second side of a substrate and a second layer. The first layer consists essentially of at least 80% by dry weight of one or more particulate inorganic pigments (PIPs). A combination of a particle size and a coat weight of the first layer on the substrate yields an effective pore size of the first layer in a range of about 0.008 to about 0.5 microns. For two or more PIPs in the first layer, the average particle size of one of the PIPs differs by no more than about 50% from the average particle size of another of the PIPs. The second layer is on top of the first layer and includes a particulate inorganic pigment (PIP) having an average particle size of about 0.1 to about 2 microns.
    Type: Grant
    Filed: July 21, 2011
    Date of Patent: December 2, 2014
    Assignee: Hewlett-Packard Development Company, L.P.
    Inventors: Jason Swei, Sandeep K Bangaru
  • Patent number: 8846165
    Abstract: A recording medium includes a substrate and at least one ink-receiving layer, wherein an outermost ink-receiving layer of the recording medium contains inorganic particles, particles other than the inorganic particles, and a binder, the particles other than the inorganic particles have an average primary particle size of 30 nm or more and 100 nm or less, the outermost ink-receiving layer of the recording medium has a thickness of 5 ?m or more, 60% or more and 90% or less of the particles other than the inorganic particles in the outermost ink-receiving layer of the recording medium are present in a region 500 nm or less below the outermost surface of the recording medium, and the area ratio of a region containing the particles other than the inorganic particles to the outermost surface of the recording medium is 30% or more and 80% or less.
    Type: Grant
    Filed: June 25, 2013
    Date of Patent: September 30, 2014
    Assignee: Canon Kabushiki Kaisha
    Inventors: Yasuhiro Nito, Kazuhiko Araki
  • Patent number: 8846166
    Abstract: The invention provides a recording medium having a substrate, a first ink receiving layer and a second ink receiving layer which is an outermost layer in this order, wherein the first ink receiving layer contains alumina hydrate and polyvinyl alcohol, the second ink receiving layer contains alumina hydrate, polyvinyl alcohol, a cationic polymer particle and a zirconium compound, and the thickness of the second ink receiving layer is 3 ?m or more and 10 ?m or less.
    Type: Grant
    Filed: September 13, 2013
    Date of Patent: September 30, 2014
    Assignee: Canon Kabushiki Kaisha
    Inventors: Olivia Herlambang, Yasuhiro Nito, Hisao Kamo
  • Patent number: 8784954
    Abstract: A recording medium includes, in sequence, a support; a first ink-receiving layer including an inorganic particle, a water-soluble polymer having a hydroxyl group, a water-soluble polymer not having a hydroxyl group, and a boric acid compound; and a second ink-receiving layer including an inorganic particle, a water-soluble polymer having a hydroxyl group, and a boric acid compound. The second ink-receiving layer does not include the water-soluble polymer not having the hydroxyl group, or the second ink-receiving layer includes the water-soluble polymer not having the hydroxyl group but the content of the water-soluble polymer not having the hydroxyl group relative to that of the inorganic particle in the second ink-receiving layer is smaller than the content of the water-soluble polymer not having the hydroxyl group relative to that of the inorganic particle in the first ink-receiving layer.
    Type: Grant
    Filed: October 10, 2013
    Date of Patent: July 22, 2014
    Assignee: Canon Kabushiki Kaisha
    Inventors: Yasuhiro Nito, Hisao Kamo, Naoya Hatta
  • Patent number: 8784955
    Abstract: A printed article with metallic luster and gold-like appearance that encompasses a printable media on which a printed feature has been formed with an ink composition. The ink composition contains iron oxide pigment particles that have an average particle 5 size in the range of about 3 to about 300 nm and the printable media contains a bottom supporting substrate and an ink-absorbing layer with pore diameters that are smaller than the average size of the iron oxide pigment particles. In such printed article, the ink composition forms onto the printable media a printed feature that has a thickness that is below about 300 nm.
    Type: Grant
    Filed: October 22, 2010
    Date of Patent: July 22, 2014
    Assignee: Hewlett-Packard Development Company, L.P.
    Inventors: Vladek Kasperchik, Jayprakash C. Bhatt, Vladimir Jakubek
  • Patent number: 8765236
    Abstract: A recording medium includes a base, a second ink-receiving layer, and a first ink-receiving layer in this order. The first ink-receiving layer contains gas-phase method silica, a binder, a cationic polymer having a sulfonyl group, and glycol. The second ink-receiving layer contains gas-phase method silica and a binder and (1) does not contain any cationic polymer having a sulfonyl group or (2) contains a cationic polymer having a sulfonyl group in an amount not higher than 0.1 parts by mass based on 100 parts by mass of the gas-phase method silica.
    Type: Grant
    Filed: March 15, 2013
    Date of Patent: July 1, 2014
    Assignee: Canon Kabushiki Kaisha
    Inventors: Tetsuro Noguchi, Hisao Kamo, Isamu Oguri, Shinya Yumoto
  • Patent number: 8747968
    Abstract: A recording medium includes, in sequence, a support, a first ink-receiving layer containing a first inorganic particle and a first binder, a second ink-receiving layer containing a second inorganic particle and a second binder, and a third ink-receiving layer which is an outermost surface layer and contains a third inorganic particle, a third binder, and a particle different from the third inorganic particle and having an average secondary particle size of 1.0 to 20.0 ?m. A mass ratio of a content of the first binder to a content of the first inorganic particle is larger than a mass ratio of a content of the second binder to a content of the second inorganic particle. A content of the particle having the specific average secondary particle size is 0.5% by mass or more with respect to a content of the third inorganic particle.
    Type: Grant
    Filed: August 6, 2013
    Date of Patent: June 10, 2014
    Assignee: Canon Kabushiki Kaisha
    Inventors: Yasuhiro Nito, Hisao Kamo, Tetsuro Noguchi, Ryo Taguri, Isamu Oguri, Olivia Herlambang, Naoya Hatta, Shinya Yumoto, Kazuhiko Araki
  • Patent number: 8741401
    Abstract: A recording medium includes a support; and an ink-receiving layer, the ink-receiving layer having a lower layer and an upper layer, in which the lower layer contains fine inorganic particles, polyvinyl alcohol, and boric acid, the fine inorganic particles including at least one compound selected from alumina, hydrated alumina, and vapor-phase-process silica, in which the upper layer contains fine inorganic particles, polyvinyl alcohol, and boric acid, the fine inorganic particles including at least one compound selected from alumina and hydrated alumina, in which the lower layer has a boric acid content of 2.0% by mass to 7.0% by mass with respect to polyvinyl alcohol, and in which the upper layer has a boric acid content of 10.0% by mass to 30.0% by mass with respect to polyvinyl alcohol.
    Type: Grant
    Filed: February 7, 2012
    Date of Patent: June 3, 2014
    Assignee: Canon Kabushiki Kaisha
    Inventors: Tetsuro Noguchi, Hisao Kamo, Yasuhiro Nito, Ryo Taguri, Isamu Oguri, Olivia Herlambang, Naoya Hatta, Shinya Yumoto
  • Patent number: 8709554
    Abstract: Printable articles including a substrate, an image receiving layer over the substrate, and a barrier layer between the substrate and the image receiving layer are useful in the production of fine art reproductions. The image receiving layer comprises at least one pigment and two or more binders, wherein at least one of the two or more binders has a glass transition temperature (Tg) at least 20° C. less than a Tg of at least one other of the two or more binders. Printed articles including a printable article with marking material contained in the image receiving layer may exhibit a textured cracking pattern after application and drying of the marking material or a liquid laminate.
    Type: Grant
    Filed: March 14, 2011
    Date of Patent: April 29, 2014
    Assignee: Hewlett-Packard Development Company, L.P.
    Inventors: Dheya M. Alfekri, Ronald J. Selensky
  • Patent number: 8679597
    Abstract: A recording medium includes, in sequence, a support, a first ink-receiving layer, and a second ink-receiving layer, in which a content of a boric acid in the first ink-receiving layer is 2.0% by mass or more and 7.0% by mass or less with respect to a content of a polyvinyl alcohol in the first ink-receiving layer, a content of a boric acid in the second ink-receiving layer is 10.0% by mass or more and 30.0% by mass or less with respect to a content of a polyvinyl alcohol in the second ink-receiving layer, an outermost surface layer of the recording medium has a content of particles of 0.5% by mass or more and 5.0% by mass or less, the particles having an average secondary particle size of 1.0 ?m or more and 20.0 ?m or less with respect to a content of an inorganic pigment.
    Type: Grant
    Filed: November 15, 2012
    Date of Patent: March 25, 2014
    Assignee: Canon Kabushiki Kaisha
    Inventors: Yasuhiro Nito, Hisao Kamo, Tetsuro Noguchi, Ryo Taguri, Isamu Oguri, Olivia Herlambang, Naoya Hatta, Shinya Yumoto, Kazuhiko Araki
  • Patent number: 8641181
    Abstract: Provided is an image forming method including applying an ink that forms an image by inkjetting an ink composition containing coloring particles, a water-soluble polymerizable compound, a polymerization initiator and water onto a recording medium in which a base paper, a first layer containing a binder, and a second layer containing a white pigment are layered in this order, and a Cobb water absorption degree on a surface of the first layer placed on the base paper is 5.0 g/m2 or less as measured by a water absorption degree test according to JIS P8140 with a contact time of 15 seconds, and a water absorption amount on a surface of the second layer is 2 mL/m2 to 8 mL/m2 as measured by a Bristow method with a contact time of 0.5 seconds.
    Type: Grant
    Filed: March 25, 2011
    Date of Patent: February 4, 2014
    Assignee: FUJIFILM Corporation
    Inventors: Jun Matsumoto, Koji Yasuda, Kiyoshi Irita, Misato Sasada
  • Publication number: 20140004281
    Abstract: A recording medium includes a base paper, a polymer layer disposed on the base paper, and an ink-receiving layer disposed on the polymer layer. The base paper has a thickness of 50 ?m or more and 130 ?m or less. The polymer layer has a thickness of 20 ?m or more and 60 ?m or less. The polymer layer has an arithmetic average surface roughness Ra1 of 0.12 ?m or more and 0.18 ?m or less. The polymer layer has a roughness curve element average length RSm of 0.01 mm or more and 0.20 mm or less. The recording medium has an arithmetic average surface roughness Ra2 of 0.13 ?m or less.
    Type: Application
    Filed: June 25, 2013
    Publication date: January 2, 2014
    Inventors: Kazuhiko Araki, Yasuhiro Nito
  • Patent number: 8609210
    Abstract: The object of the present invention is to provide a coated printing paper used for ink jet printing machines, which has an ink fixing property and ink absorption property corresponding to ink jet printing, which inhibits poor dot diffusion, and which is excellent in abrasion resistance property of printed portions. According to the present invention, provided is a coated printing paper comprising a base paper, an undercoating layer which is applied on at least one surface of the base paper and contains a pigment and a binder, and one or more coating layers on the undercoating layer, wherein the base paper contains at least one selected from a cationic resin and a multivalent cation salt; the uppermost coating layer contains at least a colloidal silica; and the 75° gloss according to JIS Z8741 of the surface of the uppermost coating layer is 40% or more.
    Type: Grant
    Filed: July 13, 2010
    Date of Patent: December 17, 2013
    Assignee: Mitsubishi Paper Mills Limited
    Inventors: Masanori Nagoshi, Koji Idei, Hiroshi Matsuda, Kazutoshi Iida, Jun Urasaki
  • Patent number: 8609209
    Abstract: An ink jet recording medium including a substrate and an ink receiving layer provided on the substrate and composed of two or more layers of at least an upper layer and a lower layer. The ink receiving layer contains polyvinyl alcohol in an amount of 12.7% by mass or more based on the total mass of the ink receiving layer. The upper layer is a layer most distant from the substrate, contains a pigment and polyvinyl alcohol, the pigment containing 90% by mass or more of alumina hydrate, and has a thickness of 3.0-10.0 ?m. The lower layer is positioned just under the upper layer, contains a pigment and polyvinyl alcohol, the pigment containing 20% by mass or more of silica, and has a thickness 2.5-10 times larger than that of the upper layer and an average pore radius 0.90-1.30 times larger than that of the upper layer.
    Type: Grant
    Filed: September 30, 2011
    Date of Patent: December 17, 2013
    Assignee: Canon Kabushiki Kaisha
    Inventors: Ryo Taguri, Hisao Kamo, Yasuhiro Nito, Tetsuro Noguchi, Isamu Oguri, Olivia Herlambang, Naoya Hatta
  • Patent number: 8592012
    Abstract: A recording medium includes, in sequence, a support, a first ink-receiving layer, and a second ink-receiving layer, in which the first ink-receiving layer contains at least one selected from an alumina, an alumina hydrate, and a fumed silica, a polyvinyl alcohol, and a boric acid, in which a mass ratio of a content of the boric acid in the first ink-receiving layer to a content of the polyvinyl alcohol in the first ink-receiving layer is 2.0% by mass or more and 7.0% by mass or less, in which the second ink-receiving layer contains a fumed silica, a polyvinyl alcohol, and a boric acid, and in which a mass ratio of a content of the boric acid in the second ink-receiving layer to a content of the polyvinyl alcohol in the second ink-receiving layer is 10.0% by mass or more and 30.0% by mass or less.
    Type: Grant
    Filed: October 25, 2012
    Date of Patent: November 26, 2013
    Assignee: Canon Kabushiki Kaisha
    Inventors: Tetsuro Noguchi, Hisao Kamo, Yasuhiro Nito, Ryo Taguri, Isamu Oguri, Olivia Herlambang, Naoya Hatta, Shinya Yumoto
  • Patent number: 8592011
    Abstract: In an ink jet recording medium having at least two ink receiving layers, the total content of boric acid, a borate, and a water-soluble zirconium salt of a lower ink receiving layer located close to a support substrate to the total content of alumina and an alumina hydrate thereof is higher than the total content of boric acid, a borate, and a water-soluble zirconium salt of an upper ink receiving layer located apart from the support substrate to the total content of alumina and an alumina hydrate thereof.
    Type: Grant
    Filed: April 18, 2011
    Date of Patent: November 26, 2013
    Assignee: Canon Kabushiki Kaisha
    Inventors: Tetsuro Noguchi, Hisao Kamo, Yasuhiro Nito, Isamu Oguri, Ryo Taguri, Olivia Herlambang, Naoya Hatta
  • Patent number: 8586157
    Abstract: Printable substrates including a base sheet, a tie coating on a first surface of the base sheet, and a printable coating on the tie coating are generally provided. The tie coating can generally include a first crosslinked material formed from a film-forming binder, a first crosslinkable polymeric binder, a first crosslinking agent, and a first crosslinking catalyst. The printable coating can generally include a plurality of inorganic microparticies and a second crosslinked material formed from a second crosslinkable polymeric binder, a second crosslinking agent, and a second crosslinking catalyst. Methods of forming an image on such printable substrates are also generally provided, along with methods for forming such printable substrates.
    Type: Grant
    Filed: November 7, 2011
    Date of Patent: November 19, 2013
    Assignee: Neenah Paper, Inc.
    Inventor: Russell Dolsey
  • Patent number: 8557354
    Abstract: Transparent ink-jet recording films, compositions, and methods are disclosed. Such films exhibit improved ink-drying and smudging performance. These films exhibit high maximum optical densities and have low haze values. These films are useful for medical imaging.
    Type: Grant
    Filed: August 12, 2011
    Date of Patent: October 15, 2013
    Inventors: Sharon M. Simpson, John D. Szafraniec, James B. Philip, Jr.
  • Patent number: 8545948
    Abstract: Transparent ink-jet recording films, compositions, and methods are disclosed. Such films do not exhibit excessive ink drying times. These films exhibit high maximum optical densities and have low haze values. These films are useful for medical imaging.
    Type: Grant
    Filed: March 20, 2013
    Date of Patent: October 1, 2013
    Assignee: Carestream Health, Inc.
    Inventors: Sharon M. Simpson, William D. Devine, III, William J. Ruzinsky
  • Patent number: 8512826
    Abstract: A recording sheet for ink-jet printing includes a supporting substrate, at least one microporous ink-receptive coating overlying a front surface of said supporting substrate and at least one protective overcoating overlying said microporous coating. The protective overcoating includes at least one compound selected from the group consisting of polysaccharides and polyacrylamides, and fluoropolymer particles. The diameter of the fluoropolymer particles is between about 0.5 and 3 micrometers.
    Type: Grant
    Filed: May 4, 2011
    Date of Patent: August 20, 2013
    Assignee: Oce-Technologies B.V.
    Inventors: Rudolf A. H. M. Sturme, Dorothea M. H. Wijnhoven, Kolja Adamczyk, James A. Foley, Khizyr Kharunovich Khoultchaev
  • Publication number: 20130209708
    Abstract: The present invention concerns a print medium for inkjet printing and a method of producing such a print medium. In particular, the present invention is directed to a print medium comprising a base layer having a first side and a reverse side, an absorptive layer being in contact with the first side of the base layer, and a topcoat being in contact with the absorptive layer.
    Type: Application
    Filed: June 30, 2011
    Publication date: August 15, 2013
    Inventors: Patrick A.C. Gane, Vesa Kukkamo, Catherine Jean Ridgway
  • Patent number: 8491975
    Abstract: An inkjet print medium with a glossy ink-receiving surface, which includes a substrate, an undercoat layer containing acrylic-polyurethane hybrid polymer and polyoxazoline; and at least one ink-receiving layer containing inorganic pigment particles and a binder, wherein the undercoat is formed between the substrate and the at least one ink-receiving layer.
    Type: Grant
    Filed: October 23, 2009
    Date of Patent: July 23, 2013
    Assignee: Hewlett-Packard Development Company, L.P.
    Inventor: Jessica Liao
  • Patent number: 8486499
    Abstract: An ink jet recording medium including a substrate and two or more ink receiving layers provided on the substrate, wherein a first ink receiving layer that is an outermost ink receiving layer of the two or more ink receiving layers and a second ink receiving layer adjacent to the first ink receiving layer contain an alumina pigment, polyvinyl alcohol and boric acid. The first ink receiving layer contains polyvinyl alcohol in an amount of 7.0-10.5% by mass or less based on the alumina pigment and contains boric acid in an amount of 1.1-1.4% by mass or less based on the alumina pigment. The second ink receiving layer contains polyvinyl alcohol in an amount of 10.5-17.0% by mass or less based on the alumina pigment and contains boric acid in an amount of 1.5-2.5% by mass or less based on the alumina pigment.
    Type: Grant
    Filed: January 23, 2012
    Date of Patent: July 16, 2013
    Assignee: Canon Kabushiki Kaisha
    Inventors: Yasuhiro Nito, Hisao Kamo, Tetsuro Noguchi, Ryo Taguri, Isamu Oguri, Olivia Herlambang, Naoya Hatta, Shinya Yumoto
  • Patent number: 8481132
    Abstract: Transparent ink-jet recording films, compositions, and methods are disclosed. These compositions and methods can impart excellent adhesion properties between film layers and the transparent support. These films are useful for medical imaging.
    Type: Grant
    Filed: September 28, 2011
    Date of Patent: July 9, 2013
    Assignee: Carestream Health, Inc.
    Inventors: Sharon M. Simpson, James B. Philip
  • Patent number: 8481131
    Abstract: Transparent ink-jet recording films, compositions, and methods are disclosed. These compositions and methods can impart excellent adhesion properties between film layers and the transparent support. These films are useful for medical imaging.
    Type: Grant
    Filed: September 27, 2011
    Date of Patent: July 9, 2013
    Assignee: Carestream Health, Inc.
    Inventors: Sharon M. Simpson, William D. Devine, William J. Ruzinsky