Property Of Particle Specified (e.g., Oil Absorbtivity, Surface Area, Pore Size, Etc.) Patents (Class 428/32.37)
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Patent number: 7655287Abstract: An inkjet recording medium obtained by forming a coating layer containing a pigment and a binder on the surface of a base material and coating layer is subsequently pressed onto a heated mirror finished surface to dry to form an ink absorbing layer through a cast coating method, wherein pigment contains a colloidal silica that has a primary particle diameter of from 10 nm to 100 nm while the ratio of the secondary particle diameter to primary particle diameter is from 1.5 to 3.0.Type: GrantFiled: March 29, 2004Date of Patent: February 2, 2010Assignee: Nippon Paper Industries Co., Ltd.Inventors: Yoshio Yoshida, Shoichi Endo, Masanori Kawashima, Susumu Hagisawa, Takayuki Fujimoto, Masaya Tosaka, Yuu Suzuki, Kaoru Hamada
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Patent number: 7651747Abstract: A fusible print medium for use in inkjet printing. The fusible print medium includes a substrate and a fusible layer, the fusible layer comprising at least one organic pigment and at least one solid plasticizer. A method of producing the fusible print medium and a method of producing a photographic quality image are also disclosed.Type: GrantFiled: August 23, 2004Date of Patent: January 26, 2010Assignee: Hewlett-Packard Development Company, L.P.Inventors: Tienteh Chen, Radha Sen
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Patent number: 7638176Abstract: An ink-jet recording media is provided with a sealable coating that is applied to a non-permeable substrate to improve fade resistance, dry time and water resistance. The ink-jet recording media comprises: (a) a non-permeable substrate; (b) a porous basecoat disposed on a surface of the non-permeable substrate, the basecoat comprising at least one pigment, at least one binder, and, optionally, at least one mordant, and adapted to receive a colorant from an ink comprising at least one colorant and a liquid vehicle containing at least one polar solvent; and (c) a porous topcoat. Either (1) the porous basecoat further comprises a solvent-swellable polymer, adapted to swell when contacted by at least one polar solvent of the liquid vehicle, and the porous topcoat is either optional or comprises at least one pigment and at least one binder, or (2) the porous topcoat comprises the solvent-swellable polymer and at least one binder.Type: GrantFiled: June 11, 2003Date of Patent: December 29, 2009Assignee: Hewlett-Packard Development Company, L.P.Inventors: Vladek P Kasperchik, Gary Allan Ungefug
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Patent number: 7622170Abstract: A coating composition comprising low sodium containing colloidal silicas and ink jet recording sheets prepared from such coatings are described. The coating comprises binder and colloidal silica preferably having an average particle size in the range of about 1 to about 300 nanometers and which has a solids to alkali metal ratio of at least the sum of AW(?0.013SSA+9), AW being the atomic weight of alkali metal present in the colloidal silica and SSA being the specific surface area of the silica. It has been discovered that if the alkali metal, e.g., sodium, content of colloidal silica is reduced, coatings prepared from such colloidal silica and applied to conventional ink jet recording sheet supports provide a specular gloss of at least 30 at 60° C., even at a relatively high silica solids to binder solids ratio of 1:1 or greater.Type: GrantFiled: March 18, 2003Date of Patent: November 24, 2009Assignee: W. R. Grace & Co.-Conn.Inventors: Daniel Ray Fruge, Demetrius Michos
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Patent number: 7618692Abstract: A coating liquid for a recording layer, containing fumed silica of a bulk density higher than 50 g/l and a specific surface area by the BET method equal to or higher than 250 m2/g, and a recording medium having a recording layer prepared with such coating liquid. The recording layer contains a water-soluble resin, which is preferably crosslinked.Type: GrantFiled: November 2, 2004Date of Patent: November 17, 2009Assignee: FUJIFILM CorporationInventors: Ryoichi Nakano, Takashi Kobayashi
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Patent number: 7601779Abstract: A polymer compound comprises a unit composed of a sulfur-containing compound (A) having at least two active hydrogen groups, a unit composed of a compound (B) having at least two isocyanate groups and a unit composed of an amine compound (C) having at least two active hydrogen groups, and having an average particle size of 200 nm or smaller. The polymer compound can be used in a recording medium.Type: GrantFiled: February 23, 2006Date of Patent: October 13, 2009Assignee: Canon Finetech Inc.Inventors: Hirokazu Hyakuda, Hiroshi Kakihira
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Publication number: 20090239004Abstract: Disclosed is a media sheet for inkjet printing. The media sheet includes a porous substrate and a flocculent formulation disposed on the porous substrate. The flocculent formulation includes at least one cationic organic flocculant, at least one organic acid and a solvent. The media sheet used herein helps in improving the printing quality of images generated thereon. Further, methods for preparing such a media sheet that includes the porous substrate and the flocculant formulation disposed on the porous substrate are disclosed.Type: ApplicationFiled: March 18, 2008Publication date: September 24, 2009Inventor: Yagiang Ming
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Patent number: 7592054Abstract: An ink jet recording medium which is excellent in ink absorptivity, color density, gloss, water resistance, light fastness and yellowing resistance, in particular, ink absorptivity, color density, light fastness and yellowing resistance. The ink jet recording medium comprises at least one ink receptive layer containing polymeric organic particles provided on a support, wherein the polymeric organic particles have a glass transition temperature (Tg) of 40° C. or higher and are amphoteric polymeric organic particles having both of the functional groups of a cationic group and an anionic group on the surface thereof.Type: GrantFiled: August 6, 2003Date of Patent: September 22, 2009Assignee: Mitsui Chemicals, Inc.Inventors: Tadashi Ishida, Yoshihiko Tomita, Masaya Kusumoto
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Publication number: 20090197005Abstract: The specification pertains to a single or multiple coated printing sheet in particular but not exclusively for sheet-fed offset printing with an image receptive coating layer on a paper substrate. Unexpectedly short converting times and times until reprinting can be achieved by choosing a coating, in which the image receptive coating layer comprises a top layer and/or at least one second layer below said top layer, said top and/or second layer comprising a pigment part, wherein this pigment part is composed of 1-95 preferably of 80-95 parts in dry weight of a fine particulate carbonate and/or of a fine particulate kaolin or clay and 1-100, preferably 6 to 25 parts in dry weight of a fine particulate silica, and a binder part, wherein this binder part is composed of 5-20 parts in dry weight of binder and less than 4 parts in dry weight of additives. Furthermore methods for making such a printing sheet and uses of such a printing sheet are disclosed.Type: ApplicationFiled: July 12, 2006Publication date: August 6, 2009Applicant: SAPPI Netherlands Services B.V.Inventors: Jean-Pierre Haenen, Peter Resch, Bert Scholte
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Patent number: 7544418Abstract: The present invention is drawn to polymer-encapsulated pigments and methods of making the same. The method includes providing an emulsion including water and a discontinuous coating phase having a copolymer dissolved in a monomer mix; providing a pigment dispersion including water, surfactant, and pigments dispersed therein; mixing the emulsion with the pigment dispersion under high shear conditions such that the coating phase is deposited on the pigments, thereby forming polymer and monomer coated pigments; and polymerizing the monomers at the surface of the polymer and monomer coated pigments to form polymer-encapsulated pigments dispersed in a fluid medium.Type: GrantFiled: July 31, 2006Date of Patent: June 9, 2009Assignee: Hewlett-Packard Development Company, L.P.Inventors: Kent D. Vincent, Sivapackia Ganapathiappan
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Publication number: 20090142519Abstract: An ink-receiving layer has a bilayer constitution, which is formed by sequentially laminating a lower layer and an upper layer on a support. The upper layer contains alumina having an average pore diameter of less than 5 nm (alumina A) and alumina having an average pore diameter of 5 nm or more (alumina B) in a weight ratio of (alumina A):(alumina B)=100:0 to 70:30; the lower layer contains the alumina A and the alumina B in a weight ratio of (alumina A):(alumina B)=0:100 to 50:50; and the thickness ratio of the upper layer to the lower layer is as follows: (upper layer):(lower layer)=2:1 to 5:1.Type: ApplicationFiled: October 16, 2006Publication date: June 4, 2009Applicant: Seiko Epson CorporationInventors: Nobuyuki Nagai, Kenichi Endo, Kazuhiko Yamamoto, Junichi Iida
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Publication number: 20090117298Abstract: The invention provides an inkjet recording material having high glossiness and favorable ink absorbency, including a support having thereon an ink receiving layer containing silica fine particles and a water-soluble resin, the arithmetic average of the mass ratio of carbon atoms to silicon atoms contained in an outermost surface farthest from the support of the ink receiving layer being from 2.5 to 7.0, and the arithmetic average of the mass ratio of carbon atoms to silicon atoms contained in a region extending from the outermost surface to a depth of 5 ?m in the thickness direction of the ink receiving layer being from 1.5 to 4.0.Type: ApplicationFiled: October 27, 2008Publication date: May 7, 2009Applicant: FUJIFILM CORPORATIONInventors: Ryoichi Nakano, Chiyomi Takemasa
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Publication number: 20090110828Abstract: An ink jet recording medium comprising a substrate and an ink receiving layer which is provided on at least one surface of the substrate and contains inorganic fine particles having an average secondary particle size of 1-4 ?m as measured by a Coulter counter method in an amount of 0.2-2.0 g/m2 in terms of solid content mass. The ink receiving layer satisfies the following conditions with respect to a pore distribution curve as determined by a nitrogen adsorption method: (1) total pore volume in a pore size range of 10-30 nm is 0.25 ml/g or more, (2) total pore volume in a pore size range of 30-70 nm is 0.1 ml/g or more, and (3) volume ratio of the total pore volume in the pore size range of 10-30 nm to the total pore volume in the pore size range of 30-70 nm is from 1:0.4 to 1:1.Type: ApplicationFiled: October 16, 2008Publication date: April 30, 2009Applicant: Canon Kabushiki KaishaInventors: Yoshiyuki Nagase, Teruaki Okuda, Takeshi Hara, Takeshi Oota, Hirokazu Hyakuda
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Publication number: 20090035491Abstract: In the present invention, there is provided an ink-jet recording material which comprises, on a support, at least one ink-receptive layer containing fine inorganic particles having an average secondary particle size of 500 nm or less, a resin binder having an acetoacetyl group, and a compound having two or more terminal hydrazino groups, wherein the at least one ink-receptive layer contains at least one organic acid having a pKa of 2 to 5.Type: ApplicationFiled: March 31, 2006Publication date: February 5, 2009Inventors: Koichi Takei, Hiroshi Sakaguchi, Norimasa Miyachi
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Patent number: 7465370Abstract: An information carrier comprising a support and a receiving layer is disclosed, together with the method of preparation. The information carrier further comprises (optionally personalized) information applied, preferably by ink jet printing, on the receiver layer, and a new type of watermark, obtained by applying pattern-wise a curable varnish and curing it, and by curing an overall applied curable lacquer. One of the varnish and the lacquer have the ability upon penetration into the receiving layer of changing its transparency, thus creating a transparent watermark on an opaque background, or creating a opaque watermark on an transparent background. The finished information carrier is preferably cut in a set of multiple identification (ID) cards.Type: GrantFiled: November 3, 2005Date of Patent: December 16, 2008Assignee: Agfa-GevaertInventors: Eddie Daems, Luc Leenders
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Recording Medium for Water-Based Ink and Method for Determining Ink Absorbing Characteristic Thereof
Publication number: 20080233317Abstract: A mat type recording medium for ink jet printing is provided which exhibits optimum printability no matter which of dye ink and pigment ink may be used in printing. The recording medium, which is for recording with use of water-based ink containing an ink colorant, comprises a paper base and an ink receptive layer formed on a surface of the paper base, the ink receptive layer comprising a porous layer containing an inorganic pigment and also containing a substance reactive with the ink colorant.Type: ApplicationFiled: August 30, 2006Publication date: September 25, 2008Inventors: Satoshi Matsuura, Naho Ishida, Kenichi Yamaguchi, Hitoshi Nagashima, Sadayuki Sugama -
Patent number: 7416639Abstract: Disclosed herein is a recording medium comprising an alumina hydrate having an average pore radius of 20 to 200 ? and a half breadth of pore radius distribution of 20 to 150 ?.Type: GrantFiled: September 10, 2003Date of Patent: August 26, 2008Assignee: Canon Kabushiki KaishaInventors: Hitoshi Yoshino, Kyo Miura, Yuji Kondo
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Publication number: 20080182045Abstract: An ink receiving substrate includes a base substrate, and an ink receptive coating formed on the base substrate. The ink receptive coating includes a binder and a fumed silica and alumina dispersion, wherein the fumed silica and alumina dispersion includes between 5 and 30% alumina particles.Type: ApplicationFiled: January 30, 2007Publication date: July 31, 2008Inventors: Silke Courtenay, Eric L. Burch, David P. Rossing, Tao Chen, Xin Cheng
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Patent number: 7393571Abstract: Formulations comprising novel porous metal oxide particles and binder are particularly suitable for ink receptive coatings, e.g., for ink jet papers and films. The metal oxide particles used in this application have a porous structure that differs significantly from the nonporous silica colloids. The particles have a median particle size in the range of about 0.05 to about 3 microns and porosity such that when an aqueous dispersion of the particles is dried at least 0.5 cc/g of pore volume is from pores having a pore size of 600 ? or less. The particles also have a viscosity derived pore volume of at least 0.5 cc/g.Type: GrantFiled: July 7, 2004Date of Patent: July 1, 2008Assignee: W. R. Grace & Co.-Conn.Inventors: David Monroe Chapman, Demetrius Michos
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Patent number: 7354634Abstract: A composition for forming a receiving layer for inkjet printing is provided. The composition, which is a solution or dispersion of a binder resin and a water-containing synthetic silica obtained by a wet gelling method in a solvent containing 10-80% by weight of alcohol, has a low viscosity, exhibits excellent applicability, can adsorb a large amount of ink, and can form a hard receiving layer suitable for inkjet printing. A method of manufacturing the composition and a recording sheet for inkjet printing having a receiving layer formed from the composition are also provided.Type: GrantFiled: October 29, 2004Date of Patent: April 8, 2008Assignee: Lintec CorporationInventors: Nishikawa Takehiko, Hirota Koichi
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Patent number: 7344764Abstract: There is provided a thermal transfer receiving sheet comprising a substrate, a barrier layer laminated on said substrate, and an image receiving layer laminated on said barrier layer, wherein said barrier layer and said image receiving layer are laminated on at least one side of said substrate, characterized in that the major components of said barrier layer are a swellable lamellar inorganic component and an adhesive, wherein said swellable lamellar inorganic component has a mean particle diameter of at least 0.1 ?m and not greater than 100 ?m, and an aspect ratio (ratio of mean particle diameter to thickness of the lamellar composite) of at least 100 and not greater than 5000.Type: GrantFiled: March 3, 2004Date of Patent: March 18, 2008Assignee: OJI Paper Co., Ltd.Inventors: Chikara Tsukada, Masato Kawamura, Hideaki Shinohara
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Patent number: 7335407Abstract: The present invention comprises an inkjet recording element comprising a support having thereon at least two ink receiving layers capable of accepting an inkjet image, at least one of said layers comprising porous polyester particles. The present invention also includes a method of forming an inkjet print comprising providing an inkjet recording element comprising at least two ink receiving layers capable of accepting an inkjet image, at least one of said layers comprising porous polyester particles and printing on said inkjet recording element utilizing an inkjet printer.Type: GrantFiled: December 20, 2001Date of Patent: February 26, 2008Assignee: Eastman Kodak CompanyInventors: Christine J. Landry-Coltrain, Jeffrey W. Leon, Linda M. Franklin, Xiaoru Wang
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Patent number: 7303794Abstract: A thermal ink jet recording paper, incorporating dewatered and milled precipitated calcium carbonate (“PCC”) is disclosed. Precipitated calcium carbonate is dewatered and milled in the presence of an amphoteric or anionic dispersant to produce a high solids PCC composition. When used in coating formulations the PCC has a surface morphology and chemistry that enhances the printability of ink jet paper. Ink jet recording paper incorporating the PCC of the present invention has reduced ink feathering and spreading as well as improved optical density, dry time, and water fastness.Type: GrantFiled: March 31, 2004Date of Patent: December 4, 2007Assignee: Specialty Minerals (Michigan) Inc.Inventors: Annmarie Superka, Kevin Jay Roth
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Patent number: 7273643Abstract: An article having multiple spectral deposits is provided. The article can include a support and a single nanomorphic marking material adapted to reflect light having a first spectral content and adapted to reflect light having a second spectral content. The article can include a support and a nanomorphic marking material held by the support that luminesces at a plurality of wavelengths. The article can include a support and marking material having a first particle size and a second particle size. The first particle size reflects a first spectrum and the second particle size reflects a second spectrum. The article can include a support and a marking material held by said support with the marking material including a nanocrystalline particulate having a measurable property non-characteristic of the same marking material in a bulk state.Type: GrantFiled: June 24, 2003Date of Patent: September 25, 2007Assignee: Eastman Kodak CompanyInventors: David J. Nelson, Sridhar Sadasivan, Ramesh Jagannathan, Seshadri Jagannathan, Glen C. Irvin, Jr., Rajesh V. Mehta
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Patent number: 7199182Abstract: An aqueous resin composition is provided which does not use a high boiling point solvent, and yet displays favorable long term stability and excellent film formation, and does not suffer from problems such as skin generation. The aqueous resin composition comprises a water soluble magnesium salt (A) and an aqueous polyurethane (B).Type: GrantFiled: June 28, 2001Date of Patent: April 3, 2007Assignee: Dainippon Ink and Chemicals, Inc.Inventors: Yoshimasa Tanaka, Masato Inoue, Masatoshi Matsuo, Yutaka Hashimoto
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Patent number: 7144613Abstract: In a recording medium having a porous ink-receiving layer containing alumina hydrate of boehmite structure formed on a base material, the alumina hydrate has crystallinity ranging from 15 to 80 and microcrystals of the alumina hydrate are directed to be parallel to a plane direction of the ink-receiving layer at a parallelization degree of not less than 1.5. The recording medium is employed in an ink-jet recording method conducting printing by ejecting ink droplets through an orifice onto the recording medium. A process for producing the recording medium comprises the steps of: applying a coating liquid containing alumina hydrate of boehmite structure with shearing stress onto a base material; and drying the coated material to obtain a degree of parallelization of a microcrystal of the alumina hydrate with a plane direction of the ink-receiving layer of not less than 1.5.Type: GrantFiled: November 19, 1997Date of Patent: December 5, 2006Assignee: Canon Kabushiki KaishaInventors: Takeo Eguchi, Kyo Miura, Hitoshi Yoshino
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Patent number: 7097899Abstract: An information carrier comprising a support and a receiving layer is disclosed, together with the method of preparation. The information carrier further comprises (optionally personalized) information applied, preferably by ink jet printing, on the receiver layer, and a new type of watermark, obtained by applying pattern-wise a curable varnish and curing it, and by curing an overall applied curable lacquer. One of the varnish and the lacquer have the ability upon penetration into the receiving layer of changing its transparency, thus creating a transparent watermark on an opaque background, or creating a opaque watermark on an transparent background. The finished information carrier is preferably cut in a set of multiple identification (ID) cards.Type: GrantFiled: September 10, 2003Date of Patent: August 29, 2006Assignee: Agfa-GevaertInventors: Eddie Daems, Luc Leenders
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Patent number: 7083836Abstract: An ink jet recording element comprising a support having thereon, in order, a hydrophilic absorbing layer and a polymeric overcoat layer comprising particles of a substantially amorphous synthetic aluminosilicate. Such recording elements exhibit improved humidity keeping and smudge resistance, while maintaining good differential gloss.Type: GrantFiled: November 10, 2003Date of Patent: August 1, 2006Assignee: Eastman Kodak CompanyInventors: Charles E. Romano, Jr., Richard J. Kapusniak, Lori J. Shaw-Klein, Terry C. Schultz, Peter J. Ghyzel
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Patent number: 7056562Abstract: An inkjet recording element comprising a support having thereon, in order, a support having thereon a ink-receiving layer comprising a hydrophilic polymer and particles of an aluminosilicate in an amount of less than 30 weight percent solids, based on the total weight of the layer. Such recording elements exhibit improved humidity keeping for print sharpness.Type: GrantFiled: January 16, 2004Date of Patent: June 6, 2006Assignee: Eastman Kodak CompanyInventors: Richard J. Kapusniak, Charles E. Romano, Jr., Peter J. Ghyzel, Terry C. Schultz, Lori J. Shaw-Klein
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Patent number: 7052749Abstract: An inkjet recording element comprising a support having thereon a subbing layer comprising particles of an aluminosilicate for improved adhesion.Type: GrantFiled: January 16, 2004Date of Patent: May 30, 2006Assignee: Eastman Kodak CompanyInventors: Richard J. Kapusniak, Charles E. Romano, Jr., Lori J. Shaw-Klein, Peter J. Ghyzel, Terry C. Schultz
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Patent number: 7052748Abstract: An inkjet recording element comprising a support having thereon, in order, a support having thereon an ink-receiving layer comprising a hydrophilic polymer, a polymeric mordant, and particles of an aluminosilicate. Such recording elements exhibit improved humidity keeping.Type: GrantFiled: January 16, 2004Date of Patent: May 30, 2006Assignee: Eastman Kodak CompanyInventors: Richard J. Kapusniak, Charles E. Romano, Jr., Lori J. Shaw-Klein, Terry C. Schultz, Peter J. Ghyzel
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Patent number: 7018688Abstract: A composition, preferably a synthetic paper, is disclosed comprising a plastics substrate having a printable polymer coating, wherein the coating has a density of from 0.3 to 0.7 g/cm3. The low density provides improved adhesion and printability properties compared with the prior art, and permits the coating to be applied in a single layer of uniform density.Type: GrantFiled: March 22, 2001Date of Patent: March 28, 2006Assignee: Arjobex LimitedInventor: John Victor Shepherd
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Patent number: 7014894Abstract: There is disclosed an ink jet recording sheet which comprises a substrate and an ink accepting layer composed of at least two layers on the substrate, characterized in that the ink accepting layer comprises at least one cracked layer having cracks in lower layers other than a surface layer (the layer farthest from the substrate) and a contact layer in contact with the cracked layer, wherein part of the contact layer cuts into the cracked layer, and the cracked layer contains a hydrophobic resin (e.g. styrene-acrylics copolymer resin) as a binder, or wherein the contact layer is formed by coating with a coating solution having viscosity of at most 3000 mPa.s and a proportion of solid content in the range of 10 to 30% by weight. The above ink accepting layer is excellent in water resistance and strength of adhesion among the interlayers, whereby the ink jet recording sheet as a whole becomes excellent in scratch-abrasion resistance under wet conditions as well as image density.Type: GrantFiled: September 27, 2002Date of Patent: March 21, 2006Assignee: Nisshinbo Industries, Inc.Inventor: Hirotaka Yamamoto
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Patent number: 6994834Abstract: A surface modified fine silica powder which has been treated, preferably, with a treating agent containing an amino group, characterized in that the powder exhibits an adsorption amount for an anion source compound of 150% or more of that of an original powder which has not been treated; and a printing material using the silica powder. The surface modified fine silica powder can provide an excellent printed matter being free from blotting with ink or a cracking of coating film.Type: GrantFiled: September 22, 2000Date of Patent: February 7, 2006Assignee: Nippon Aerosil Co., Ltd.Inventors: Hirokuni Shirono, Masamichi Murota, Yuki Amano
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Patent number: 6979480Abstract: Improved macroporous ink receptor media are disclosed. An inkjet receptive media in accordance with one embodiment of the present invention comprises a web comprising a plurality of fibers and a coating overlaying at least a portion of a plurality of the fibers. In a preferred embodiment, the coating comprises a plurality of organic particles. In a preferred embodiment, the fibers define a plurality of pores. In a preferred embodiment, the web defines a plurality of macropores. The fibers of the web may be woven or non-woven. In a preferred embodiment, the web comprises a nonwoven macroporous material.Type: GrantFiled: June 9, 2000Date of Patent: December 27, 2005Assignee: 3M Innovative Properties CompanyInventors: Mark F. Schulz, David W. Tweeten
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Patent number: 6946240Abstract: The present invention relates to an imaging element comprising a support, an imaging layer, and at least one layer comprising a clay nanocomposite wherein said nanocomposite comprises a splayant and at least one natural clay particle having an aspect ratio of from 20:1 to 500:1.Type: GrantFiled: August 4, 2003Date of Patent: September 20, 2005Assignee: Eastman Kodak CompanyInventors: YuanQiao Rao, Joseph S. Sedita
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Patent number: 6945646Abstract: A recording medium includes a substrate and an ink-receiving layer provided on the substrate, wherein the ink—receiving layer includes an alumina hydrate having a boehmite structure, an average particle thickness of 2.0 to 6.0 nm and a crystallite size of 5.0 to 8.0 nm in a direction of a (020) plane, and the recording medium has a degree of parallelization of 30 to 1,000.Type: GrantFiled: September 23, 1999Date of Patent: September 20, 2005Assignee: Canon Kabushiki KaishaInventors: Hiroyuki Ogino, Hitoshi Yoshino
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Patent number: 6936317Abstract: Ink jet printing paper carries a pigment coating comprising (a) a major proportion of a finely divided precipitated calcium carbonate (PCC) having a surface area of at least 60 m2g?1, preferably 80 to 90 m2g?1 (b) a minor proportion of a gel-type silica and (c) binder. The silica is preferably present in an amount of 15 to 30% by weight of the total dry weight of silica and PCC. The pigment coating is preferably made up as an aqueous composition having a solids content of 25 to 35% and a Brookfield viscosity of 150 to 2000 mPa s and applied by a blade coating technique.Type: GrantFiled: December 12, 2000Date of Patent: August 30, 2005Assignee: Arjo Wiggins Fine Papers LimitedInventors: Mark Victor Watson, Gary Paul Westwood
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Patent number: 6916514Abstract: The invention relates to a cationic shelled particle comprising a colloidal alumina core having a median diameter of between 20 and 2000 nm and a positive charge, a layer on the surface of said core particle having a negative charge and comprising particles of a median diameter of less than 30% of the median diameter of said core particle, and an outer layer of positive charge.Type: GrantFiled: July 18, 2003Date of Patent: July 12, 2005Assignee: Eastman Kodak CompanyInventors: Joseph F. Bringley, Katherine M. Broadus, Lori Shaw-Klein, Gary N. Barber
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Patent number: 6908648Abstract: An ink-jet recording sheet containing a support having the following layers in the order: (a) a porous layer; and (b) a surface porous layer containing an organic particle A or an organic particle B, the organic particle A being insoluble in water and soluble in or swollen in a water soluble organic solvent having a SP value of 18.41 to 30.69 (MPa)1/2 and a boiling point of not less than 120° C.; the organic particle B comprising a copolymer having a specific recurring unit in an amount of not less than 5 weight % based on the total weight of the copolymer; the organic particle A and the organic particle B each having an average particle size of not more than 100 nm and a glass transition temperature of not less than 70° C., wherein the porous layer or the surface porous layer contains a compound having a polyvalent metal element.Type: GrantFiled: March 13, 2003Date of Patent: June 21, 2005Assignee: Konica CorporationInventor: Kenzo Kasahara
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Patent number: 6902780Abstract: A coating composition comprising relatively low alkali cationic colloidal silicas and ink jet recording sheets prepared from such coatings is described. The coating comprises binder and cationic colloidal silica preferably having an average particle size in the range of about 1 to about 300 nanometers and which has a solids to alkali metal ratio of at least the sum of AW(?0.013SSA+9), AW being the atomic weight of alkali metal present in the colloidal silica and SSA being the specific surface area of the silica. It has been discovered that if the alkali metal, e.g., sodium, content of colloidal silica is reduced, coatings prepared from such colloidal silica and applied to conventional ink jet recording sheet supports provide a specular gloss of at least 30 at 60° C., even at a relatively high silica solids to binder solids ratio of 1:1 or greater.Type: GrantFiled: March 18, 2003Date of Patent: June 7, 2005Assignee: W. R. Grace & Co.-ConnInventors: Daniel Ray Fruge, Demetrius Michos
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Patent number: 6890610Abstract: A recording element comprising a support having thereon an image-receiving layer, said recording element containing core-shell particles wherein said core comprises an inorganic or organic particle and said shell comprises an organosilane or a hydrolyzed organosilane derived from a compound having the formula: Si(OR)aZb wherein R is hydrogen, or a substituted or unsubstituted alkyl group having from 1 to about 20 carbon atoms or a substituted or unsubstituted aryl group having from about 6 to about 20 carbon atoms; Z is an alkyl group having from 1 to about 20 carbon atoms or aryl group having from about 6 to about 20 carbon atoms, with at least one of said Z's having at least one primary, secondary, tertiary or quaternary nitrogen atom; a is an integer from 1 to 3; and b is an integer from 1 to 3; with the proviso that a+b=4; and with the further proviso that the amount of organosilane shell material is such that Ratio R, which is the number of micromoles of organosilane used to shell the core particleType: GrantFiled: July 18, 2003Date of Patent: May 10, 2005Assignee: Eastman Kodak CompanyInventors: Joseph F. Bringley, Krishnamohan Sharma, Gary N. Barber
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Patent number: 6878423Abstract: A transfer sheet comprises a support, and a transfer layer for receiving an ink, wherein the transfer layer is formed in the support by heating at a predetermined temperature and is separable from the support. The hot-melt adhesive particle comprises a first particle having a melting point more than the predetermined temperature and a second particle having a melting point not more than the predetermined temperature. The transfer layer may further comprise a film-forming resin component and a dye fixing agent. The hot-melt adhesive particle may comprise a polyamide-series particle. In particular, the average particle size of the first particle may be 3 to 100 mm. The transfer sheet is excellent in stability on delivery of a paper as well as can prevent the inside of the printer from staining.Type: GrantFiled: June 6, 2002Date of Patent: April 12, 2005Assignee: Daicel Chemical Industries, Ltd.Inventor: Hideki Nakanishi
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Patent number: 6869649Abstract: A print medium having a heat-sealable layer comprised of a first component and a second component. The first component and the second component have different particle sizes and different glass transition temperatures. A method of producing the print medium is also disclosed. The print medium is used to produce a photographic-quality image by applying inkjet ink to the print medium. The heat-sealable layer of the print medium is sealed by exposing the layer to a temperature above the glass transition temperatures of the two components. An inkjet printer used to apply inkjet ink to the print medium may include a radiant heater.Type: GrantFiled: March 12, 2003Date of Patent: March 22, 2005Assignee: Hewlett-Packard Development Company, L.P.Inventor: Radha Sen
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Patent number: 6861112Abstract: The invention provides an aqueous dispersion comprising fumed silica particles, colloidal silica particles, and water. The fumed silica particles have a BET surface area of about 70 to about 140 m2/g, and the colloidal silica particles have a BET surface area of about 110 to about 150 m2/g. Also, the total amount of silica in the dispersion is about 35% to about 60% by weight, and the fumed silica particles comprise about 25% to about 80% by weight of the total amount of silica in the dispersion. The invention also provides a coating composition and a recording medium incorporating the inventive dispersion.Type: GrantFiled: November 15, 2002Date of Patent: March 1, 2005Assignee: Cabot CorporationInventors: Michael D. Morris, Joanne Liu, Steven E. Brown
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Patent number: 6861114Abstract: An ink jet recording element having a support having thereon a fusible, porous, image-receiving layer of at least two types of hydrophobic polymer particles having different glass transition temperatures, the first type of hydrophobic polymer particles having a Tg higher than about 60° C. that is substantially monodisperse and the second type of hydrophobic polymer particles having a Tg lower than about 25° C.Type: GrantFiled: November 7, 2002Date of Patent: March 1, 2005Assignee: Eastman Kodak CompanyInventors: Hwei-Ling Yau, David E. Decker, Xiaoru Wang, Wendy S. Krzemien
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Patent number: 6852379Abstract: An ink-jet recording paper is disclosed. The ink-jet recording paper has a support and a porous ink receiving layer comprising fine filler particles having an average particle diameter of from 5 to 100 nm, and the ink receiving layer contains a polymer particle dispersion of a cationic or nonionic polymer having a glass transition point of from ?30° C. to 40° C. and an average particle diameter of from 1 nm to 50 nm.Type: GrantFiled: September 6, 2002Date of Patent: February 8, 2005Assignee: Konica CorporationInventor: Kenzo Kasahara
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Patent number: 6840992Abstract: The present invention provides a coating for inkjet media, which includes at least one hydrophobic filler particle; and a binder. Another embodiment of the invention provides an inkjet media, which includes the above-described coating coated on a substrate. Another embodiment of the invention provides a method of inkjet printing, which includes inkjet printing at least one inkjet ink onto a substrate coated with the above-described coating.Type: GrantFiled: April 11, 2001Date of Patent: January 11, 2005Assignee: Degussa AGInventors: Holger Glaum, Astrid Mueller
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Patent number: 6838137Abstract: An ink jet recording material is constituted by a support and a recording layer on the support, in which a plurality of recording layer may be provided. At least one recording layer contains colloidal particles and a water-soluble resin. In order to produce the ink jet recording material, a sticking or adhesive interlayer is provided on a support, and a recording layer including at least one layer is superposed on the interlayer. At least one of the at least one layer of the recording layer contains colloidal particles and a water-soluble resin, and the recording layer is coated and formed on a forming material. Then, the forming material is peeled from said recording layer.Type: GrantFiled: March 31, 1999Date of Patent: January 4, 2005Assignee: OJI Paper Co., Ltd.Inventors: Bo Liu, Hiroyuki Nemoto, Hideo Ikezawa
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Patent number: 6838132Abstract: The object of the present invention is to provide an ink jet recording sheet which can give an image having an appearance looking like a picture, especially, an oil painting with maintaining sufficient print density. According to the present invention, there is provided an ink jet recording sheet comprising a support and an ink receiving layer provided on one side of the support, where the support is a fabric and the surface of the ink receiving layer has an arithmetical mean roughness of not more than 30 ?m measured in accordance with JIS B0601. The present invention further provides an ink jet recording sheet mentioned above, wherein the ink receiving layer is coated on a pigment layer coated on at least one side of the fabric or on at least one side of the fabric impregnated with a pigment component. The ink receiving layer preferably contains a gas phase method silica.Type: GrantFiled: July 27, 2000Date of Patent: January 4, 2005Assignee: Mitsubishi Paper Mills LimitedInventors: Yuji Iguchi, Katsuaki Arai