Shrinkable Or Shrunk (e.g., Due To Heat, Solvent, Volatile Agent, Restraint Removal, Etc.) Patents (Class 428/34.9)
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Patent number: 8263197Abstract: A heat-shrinkable polylactic acid (PLA) film and a method of its manufacture are provided. In an exemplary embodiment, the PLA films exhibit heat-induced shrinkage in the transverse direction with little to no concomitant shrinkage in the machine direction. The films may comprise any grade of PLA polymer, optionally including additives, such as antiblock, slip, plasticizers, viscosity enhancers and combinations thereof. A method of cast and tenner manufacture is disclosed, which includes a temperature conditioning step.Type: GrantFiled: July 7, 2011Date of Patent: September 11, 2012Assignee: Plastic Suppliers, Inc.Inventors: Edward Carl Tweed, Joseph B. McDaniel
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Publication number: 20120213956Abstract: Described herein are fugitive hot melt adhesive compositions having a substantial weight percent of renewable plant-based content. The adhesive compositions impart high initial adhesive bond strength between an object and a substrate quickly after application in the molten state, wherein the adhesive bond strength is spontaneously substantially reduced to a very low or near zero level after a short time, for example between about 1 minute and 60 minutes after application. Methods of use and articles formed using the compositions are also described.Type: ApplicationFiled: February 23, 2011Publication date: August 23, 2012Applicant: Adherent Laboratories, Inc.Inventors: William L. Bunnelle, Keith Knutson, Thomas H. Quinn
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Deep drawing packaging container, deep drawing packaged product and method of manufacturing the same
Patent number: 8247047Abstract: A deep drawn container with a top film made of a first heat shrinkable multilayer film, and a bottom film made of a second heat shrinkable multilayer film. The deep drawn container having a drawing ratio (D1) of the top film and a drawing ratio (D2) of the bottom film satisfying conditions: D1=1.1 to 4.0; D2=1.5 to 5.0; and (D2/D1)=1.05 to 4.55. A hot-water shrinkability of the first heat shrinkable multilayer film in a longitudinal direction (SM1) and in a transverse direction (ST1), and a hot-water shrinkability of the second heat shrinkable multilayer film in a longitudinal direction (SM2) and in a transverse direction (ST2) satisfy conditions: SM1=5 to 40%; ST1=5 to 40%; SM2=2 to 25%; ST2=2 to 25%; (SM1/SM2)=1.2 to 12; and (ST1/ST2)=1.2 to 12.Type: GrantFiled: September 28, 2007Date of Patent: August 21, 2012Assignee: Kureha CorporationInventors: Hitoshi Ishii, Seiichi Ibe -
Patent number: 8247700Abstract: A wired circuit board has a metal supporting board, an insulating layer formed on the metal supporting board, a conductive pattern formed on the insulating layer and having a pair of wires arranged in spaced-apart relation, and a semiconductive layer formed on the insulating layer and electrically connected to the metal supporting board and the conductive pattern. The conductive pattern has a first region in which a distance between the pair of wires is small and a second region in which the distance between the pair of wires is larger than that in the first region. The semiconductive layer is provided in the second region.Type: GrantFiled: March 12, 2009Date of Patent: August 21, 2012Assignee: Nitto Denko CorporationInventors: Jun Ishii, Yasunari Ooyabu, Visit Thaveeprungsriporn
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Patent number: 8227058Abstract: The present invention provides a heat-shrinkable laminated film including at least two layers, in which the first layer is composed of at least one kind of a polylactic acid series resin as the main component and the second layer is composed of at least one kind of a polyolefin series resin as the main component. Heat shrinkage ratio of this film in the film main shrinking direction is 30% or more when dipped in warm water of 80° C. for 10 seconds. Since this heat-shrinkable laminated film is made from a plant-derived resin, it promotes a use of biomass. Also, as this film exhibits excellent shrinkage property in low temperature, film rigidity, shrink finishing quality, and small natural shrinkage ratio, the film is suitably used for a molded product which requires heat shrinkage property, specifically, it is suitably used for shrinkable label.Type: GrantFiled: January 11, 2006Date of Patent: July 24, 2012Assignee: Mitsubishi Plastics, Inc.Inventors: Takeyoshi Yamada, You Miyashita
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Patent number: 8206797Abstract: A heat-shrinkable polyester film is obtained which is extremely satisfactory in openability along a perforation, has exceedingly high productivity, and is less apt to split in the lengthwise direction in processing, e.g., printing. Provided is a label which is formed from the heat-shrinkable film and is satisfactorily tearable. The label is one formed from a tubular material which comprises as a base a heat-shrinkable film thermally shrinking mainly in the film width direction and which has been cut according to an object to be packaged, both edges in the film width direction having been bonded to each other. The tubular material has been thermally shrunk to constitute the label, with which at least part of the periphery of the object to be packaged is covered. The label has an angle tear strength in the direction perpendicular to the main shrinkage direction (i.e., in the film length direction) of 100-310 N/mm and a tensile break strength in the direction perpendicular to the main shrinkage direction (i.e.Type: GrantFiled: December 11, 2008Date of Patent: June 26, 2012Assignee: Toyo Boseki Kabushiki KaishaInventors: Masayuki Haruta, Masatoshi Hashimoto, Masakazu Iwasaki, Katsuhiko Nose
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Patent number: 8206796Abstract: An article comprises a first polylactic acid layer and a second layer directly adjacent the first layer. The second layer comprises any of ethylene/unsaturated ester copolymer, ethylene/alkyl (meth)acrylate/glycidyl (meth)acrylate copolymer, and styrenic block copolymer. The article may be a shrink sleeve.Type: GrantFiled: May 5, 2006Date of Patent: June 26, 2012Assignee: Cryovac, Inc.Inventors: Slawomir Opusko, Paul A. Hughes, Michael L. Becraft, Larry B. McAllister
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Patent number: 8187683Abstract: An object of the present invention is to provide a multilayered polyamide-based tube for food packaging that is free from blocking in a Layer (C), and that has an excellent adherence to processed meat or like packaged food. The present invention provides a multilayered polyamide-based tube for food packaging comprising a Layer (A), a Layer (B) and a Layer (C); the multilayered polyamide-based tube having a low-temperature shrinkage ratio of 2 to 10%, and exhibiting heat shrinkage properties and gas barrier properties; the Layer (A) containing a polyamide-based resin; the Layer (B) containing a polyolefin-based resin; and the Layer (C) that comes in contact with the packaged food, the Layer (C) being a Layer (C-1) that contains a polypropylene-based resin having a heat distortion temperature (ISO 75B-1 or ISO 75B-2) of not less than 60° C. and a Vicat softening point of not less than 120° C.Type: GrantFiled: March 26, 2009Date of Patent: May 29, 2012Assignee: Gunze LimitedInventors: Hiroki Kuriu, Hiroyuki Yabuta
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Patent number: 8188178Abstract: A composition includes an elastomeric composition. The elastomeric composition can include an epichlorohydrin composition, and the elastomeric composition can be substantially free of a fluoroelastomer composition. The composition can further include a filler material which includes a reinforcement-grade carbon black. The composition can further include a peroxide curative.Type: GrantFiled: May 7, 2007Date of Patent: May 29, 2012Assignee: 3M Innovative Properties CompanyInventor: Pradip K. Bandyopadhyay
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Publication number: 20120128905Abstract: The invention relates to a method for producing a structural element comprising a fiber-reinforced plastic. According to the invention, a flexible hose is provided with a tubular woven fabric and shaped into the desired form. A plastic that is preferably in liquid form is applied to the tubular woven fabric and is subsequently cured.Type: ApplicationFiled: May 6, 2010Publication date: May 24, 2012Inventor: Valentine Troi
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Patent number: 8173231Abstract: The heat-shrinkable cylindrical label of the present invention comprises a cylindrical body formed a heat-shrinkable film into a cylindrical form, and a resin layer laid on a partial region of the cylindrical body, wherein the heat-shrinkable film is a film having a heat shrinkage ratio of 30% or more when the film is heated to 85° C. and having a shrinkage stress of 6.5 MPa or less when the film is heated to 85° C., and the resin layer is a layer which does not substantially deform when the layer is heated to 85° C. In a cylindrical-label-attached article, wherein the cylindrical label is shrunk by heat to be fitted to an article, the regions where the resin layer is formed rise up as a three-dimensional pattern in a convex form.Type: GrantFiled: January 21, 2009Date of Patent: May 8, 2012Assignee: Fuji Seal International, Inc.Inventors: Eiji Hikida, Akiko Haga
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Patent number: 8137773Abstract: The present invention provides a polyolefin series heat-shrinkable film comprising a mixed resin mainly containing a polyolefin series resin (A), polylactic acid series resin (B), and a resin (C) facilitating compatibility with the resin (A) and the resin (B), or comprising at least one layer made of the mixed resin, wherein mass ratio of the resin (A) to the resin (B) is (A)/(B)=99/1 to 70/30; heat shrinkage ratio of the film at least in one direction when dipped in hot water at 80° C. for 10 seconds is 20% or more; and natural shrinkage ratio of the film when stored at 40° C. under 50% RH environment for 7 days is less than 10%. This polyolefin series heat-shrinkable film exhibits excellent heat-shrinkable property and shrink finishing quality, and inhibits natural shrinkage. This invention also provides a polyolefin series heat-shrinkable label and container on which the heat-shrinkable label is fitted.Type: GrantFiled: November 30, 2006Date of Patent: March 20, 2012Assignee: Mitsubishi Plastics, Inc.Inventors: Takashi Hiruma, Takeyoshi Yamada
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Patent number: 8129007Abstract: Coextruded, biaxially oriented, heat-shrinkable films having a base layer comprising a polyester having an intrinsic viscosity greater than 0.75 and at least one outer heat-sealable layer directly adhered to the base layer are disclosed. The outer layer is heat-sealable and optionally peelable in particular to polyester containers. The invention further relates to a process for producing the film and to packages comprising a container, a product and the coextruded, biaxially-oriented heat-shrinkable film sealed onto the container. The packages are suitable for use with ready-prepared foods, so-called “ready-meals”, which are intended to be warmed in a microwave or in a conventional oven.Type: GrantFiled: January 29, 2007Date of Patent: March 6, 2012Assignee: Cryovac, Inc.Inventor: Roberto Forloni
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Patent number: 8129006Abstract: The present invention refers to a multilayer heat shrinkable film characterized by a combination of desirable properties, such as high shrinkage, good optical properties, excellent sealability and stack sealability. The invention further is directed to a method of producing said film. The invention is further directed to the use of said film or bags and pouches made therefrom for packaging goods as for example food products. The invention also refers to tubes made with the film.Type: GrantFiled: September 28, 2006Date of Patent: March 6, 2012Assignee: Flexopack S.A.Inventor: Dimitrios Ginossatis
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Publication number: 20120051977Abstract: Embodiments of the present invention provide systems and methods for point of use location treatment of potable water supplies on demand on board passenger vehicles, such as aircraft. The systems described generally provide increased safety features, alternate ultraviolet light sources, and reduced power consumption.Type: ApplicationFiled: August 31, 2010Publication date: March 1, 2012Applicant: MAG Aerospace Industries, Inc.Inventors: Razmik B. Boodaghians, Jeff Lassegard
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Patent number: 8080294Abstract: Disclosed in one aspect is a film comprising at least one core layer comprising a blend of at least 20 wt %, by weight of the core layer, of a first linear LLDPE having a molecular weight distribution (Mw/Mn) within the range of from 1.0 to 4.0; and at least 20 wt %, by weight of the core layer, of a second LLDPE—in a certain embodiment a short-chain branched LLDP—having a molecular weight distribution (Mw/Mn) within the range of from 1.0 to 7.0; characterized in that the density of the second LLDPE is greater than the density of the first LLDPE by at least 0.002 g/cm3; and/or the I2 of the second LLDPE is greater than the I2 of the first LLDPE by at least 0.5 dg/min. In certain embodiments, the first and second LLDPEs are produced by a metallocene-catalyzed reaction. In yet another embodiment, the combined molecular weight distribution (Mw/Mn) of the first and second LLDPEs is greater than 4.0.Type: GrantFiled: May 16, 2008Date of Patent: December 20, 2011Assignee: ExxonMobil Oil CorporationInventor: Pang-Chia Lu
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Patent number: 8043695Abstract: In some preferred embodiments, a heat shrinkable foamed sheet has a foamed layer (2) constituting a core layer, and a non-foamed layer (3) constituting a surface skin layer integrally formed on the formed layer. The non-foamed layer (3) is less than about 1.55 ?m in maximum surface smoothness measured in accordance with ISO8791-4. Alternatively, by regulating various dimensions of foam cells formed in the foamed layer (2) so as to fall within predetermined ranges, a heat shrinkable foamed sheet excellent in surface smoothness and printing nature can be obtained.Type: GrantFiled: May 14, 2007Date of Patent: October 25, 2011Assignee: American Fuji Seal, Inc.Inventors: Otis Jerome Ballard, Kevin Michael Bickett, Bruce Larry Atcher, Minoru Hasegawa
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Patent number: 8039070Abstract: A heat-shrinkable film suitable for forming an easy opening cook-in bag is provided. The film comprises at least five layers, including an inner layer, an inner frangible layer, a barrier layer, an outer frangible layer, and an outer layer. The film is capable of being formed into a bag comprising a lap seal, a top end seal, and a bottom end seal, wherein the seals are heat sealed to a closed condition to contain and protect a product disposed therein. The lap seal, top end seal, and bottom end seal each are able to remain sealed during cook-in conditions. Additionally, the lap seal, top end seal, and bottom end seal each are peelable and easily openable by application of force.Type: GrantFiled: January 21, 2009Date of Patent: October 18, 2011Assignee: Curwood, Inc.Inventors: Bradley Thomas Sawall, Thomas Andrew Schell, Benjamin Ray Stover
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Publication number: 20110240501Abstract: A light sensitive media packaging with unique shrink-wrap light protection label that works as a light barrier to protect media from light damage.Type: ApplicationFiled: April 12, 2011Publication date: October 6, 2011Inventor: Jeffrey Janus
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Patent number: 8021759Abstract: The present invention is directed to a heat-shrinkable, thermoplastic film or bag which contains at least one homogeneous ethylene alpha-olefin copolymer having a density of at least 0.90 g/cc. Oriented films made in accordance with the present invention exhibit improved optics and improved impact resistance. A homogeneous ethylene alpha-olefin may be present in a monolayer film either alone or in a blend or may be included in one or more layers of a multilayer film in accordance with the present invention.Type: GrantFiled: December 22, 1997Date of Patent: September 20, 2011Assignee: Cryovac Inc.Inventors: Kelly R. Ahlgren, Robert Babrowicz, Solomon Bekele, Blaine C. Childress, Marvin R. Havens, Vincent W. Herran, Ronald D. Moffitt, Gautam P. Shah, George D. Wofford
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Publication number: 20110217493Abstract: The present invention provides weather-, sunlight-, and use-protected hydrant markers, and methods of protecting and extending the useful life of hydrant markers by protecting them against weather, sunlight, and use, through the application of a heat shrinkable material onto the marker.Type: ApplicationFiled: March 5, 2010Publication date: September 8, 2011Inventor: Philip R. Cowen
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Patent number: 8012553Abstract: A stretch mold container of the present invention is obtained by draw-forming a resin composition containing a poly-L-lactic acid (A) and a poly-D-lactic acid (B) at a molar ratio A:B in a range of 95:5 to 60:40, and has an amount of heat shrinkage of 5.0% or less under heat treatment conditions of 65° C.×24 hours. Despite of being made from the polylactic acids, the stretch mold container exhibits excellent heat resistance.Type: GrantFiled: May 8, 2007Date of Patent: September 6, 2011Assignee: Toyo Seikan Kaisha, Ltd.Inventors: Takurou Ito, Hiroki Mori, Hiroaki Sugioka
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Patent number: 7998545Abstract: A heat-shrinkable polylactic acid (PLA) film and a method of its manufacture are provided. In an exemplary embodiment, the PLA films exhibit heat-induced shrinkage in the transverse direction with little to no concomitant shrinkage in the machine direction. The films may comprise any grade of PLA polymer, optionally including additives, such as antiblock, slip, plasticizers, viscosity enhancers and combinations thereof. A method of cast and tenner manufacture is disclosed, which includes a temperature conditioning step.Type: GrantFiled: May 7, 2010Date of Patent: August 16, 2011Assignee: Plastic Suppliers, Inc.Inventors: Edward Carl Tweed, Joseph B. McDaniel
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Patent number: 7993713Abstract: A heat shrinkable multilayer film comprising an outer surface layer (a) formed of a thermoplastic resin, a first intermediate layer (b1) formed of a polyamide resin, a second intermediate layer (b2) formed of a saponified product of an ethylene-vinyl acetate copolymer, and an inner surface layer (c) formed of a polyolefin resin, wherein the shrink of the heat shrinkable multilayer film in water at 90° C. is within a range of from 3 to 45% in each of machine and transverse directions, and the polyamide resin is a mixture of 60 to 90% by weight of an aliphatic polyamide having a melting point of 210° C. or higher and 10 to 40% by weight of an aromatic polyamide comprising isophthalic acid and terephthalic acid as main components.Type: GrantFiled: January 15, 2007Date of Patent: August 9, 2011Assignee: Kureha CorporationInventors: Hitoshi Ishii, Seiichi Ibe, Tadayoshi Itoh, Shigeyoshi Nakaki
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Publication number: 20110177268Abstract: The invention relates to a film of plastics material stretched to present a privileged shrinkage orientation and used in particular for fabricating heat-shrink sleeves, the film including at least one line of mechanical weakness and at least one local region of extra thickness extending along the line of weakness so as to border it, the line of weakness and the adjacent local region of extra thickness together defining a tear line. According to the invention, the local region of extra thickness is constituted by applying liquid or semi-liquid material to the film, the applied material being applied to the film in a quantity that depends on the expected shrinkage ratio in the portion of the film that includes the tear line while a sleeve made using such a film is being heat-shrunk onto an article.Type: ApplicationFiled: January 14, 2011Publication date: July 21, 2011Applicant: Sleever International CompanyInventor: Eric Fresnel
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Patent number: 7981492Abstract: Multilayer laminates useful in packaging of respiring food products and packages made therefrom. The laminates have a CO2 permeability rate of at least about 10 cm3/100 in2/24 hours and an O2 permeability rate of less than about 5.3 cm3/100 in2/24 hours.Type: GrantFiled: October 28, 2008Date of Patent: July 19, 2011Assignee: Exopack, LLCInventor: Jay D. Hodson
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Publication number: 20110171517Abstract: A battery tubing according to the present invention is provided. The battery tubing is hollow and shrinkable. The battery tubing has at least one perforation line and a user can easily tear the battery tubing along the perforation line. The present invention further provides a battery wrapped with the above battery tubing.Type: ApplicationFiled: January 5, 2011Publication date: July 14, 2011Applicant: E-ONE MOLI ENERGY CORP.Inventors: Yu Chang LEE, Sung Yi TSAI, Chun Sheng SU
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Patent number: 7964255Abstract: A heat-shrinkable multilayer material for packaging, in particular food packaging, comprises a first layer made of heat-shrinkable material, a microwave susceptible material covering at least a part of the first layer, at least one second layer made of shrinkable or non-shrinkable material, the first and second layer can be connected to each other by embedding the microwave susceptible material, wherein the microwave susceptible material is arranged in a pattern between the first and second layer, the pattern creating areas of increased stiffness within the multilayer material when microwave energy is applied onto.Type: GrantFiled: October 4, 2007Date of Patent: June 21, 2011Assignee: Micro Shaping, Ltd.Inventors: Bernhard Fink, Michael Krainz, Michael Washuettl
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Patent number: 7959995Abstract: A deep drawing heat shrinkable multilayer film includes: an intermediate layer made of a vinylidene chloride copolymer resin (a); and a resin layer made of a first thermoplastic resin (b) layered on at least one surface of the intermediate layer. The multilayer film has hot water shrinkabilities in longitudinal and transverse directions at a temperature of 90° C. range from 3% to 35% respectively.Type: GrantFiled: March 30, 2007Date of Patent: June 14, 2011Assignee: Kureha CorporationInventors: Hitoshi Ishii, Seiichi Ibe
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Publication number: 20110129576Abstract: The invention has for its object to provide a heat-shrinkable laminated film for deep drawing, which has an increased carbon dioxide transmission rate (CO2TR) and an enhanced ratio (CO2TR/O2TR) of carbon dioxide transmission rate-to-oxygen transmission rate (O2TR), and is less susceptible to pinholes. In the inventive heat-shrinkable laminated film for deep drawing, a polyamide resin composition layer (a) containing a polyamide resin mixture comprising 60 to 95% by mass of an aliphatic polyamide resin (A) and 5 to 40% by mass of a polyamide base resin (B) having a heat of crystalline fusion of 5 to 40 J/g is laminated onto a heat-sealing resin layer (a) containing a polyolefin resin via an adhesive resin layer (b).Type: ApplicationFiled: November 17, 2008Publication date: June 2, 2011Applicant: Kureha CorporationInventors: Seiichi Ibe, Tadayoshi Itoh, Hitoshi Ishii
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Patent number: 7947348Abstract: Polypropylene compositions, particularly suited for preparation of stretched/oriented articles, especially for injection stretch blow moulded bottles, comprising: A) one or more propylene homopolymers or propylene copolymers or their mixtures; B) from 500 to about 1500 ppm by weight of talc in form of particles having average particle diameter of equal to or less than 1.5 ?m. Said compositions display higher crystallization temperature with respect to the same polyolefin (A) without addition of (B), while keeping good levels of transparency, particularly when (A) is or comprises a random polymer.Type: GrantFiled: December 15, 2006Date of Patent: May 24, 2011Assignee: Basell Poliolefine Italia, s.r.l.Inventors: Fiorella Pradella, Pierre-Alain Weiss, Claudio Cavalieri, Gabriella Sartori
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Patent number: 7939174Abstract: A film roll of a heat-shrinkable polyester film characterized in that the heat-shrinkable polyester film meets the following requirements (1) and (2). (1) When samples are cut off therefrom at an almost equal interval along the longitudinal direction, and immersed in hot water at 85° C. for 10 seconds, subsequently in water at 25° C. and withdrawn, heat-shrinkage percentages in the maximum shrinkage direction of all the samples are 20% or more. (2) When raw polymers used for production of the film above comprises of a major constitutional unit and one or more sub constitutional units different therefrom; and the content of the primary sub constitutional unit is determined, the content of the primary sub constitutional unit in each sample is more than 7 mole % in 100% of all constitutional units, and when an average of the contents of the primary sub constitutional unit is calculated, the contents thereof of all the samples fall within a range of ±2 mole % relative to the average.Type: GrantFiled: June 23, 2005Date of Patent: May 10, 2011Assignee: Toyo Boseki Kabushiki KaishaInventors: Satoshi Hayakawa, Norimi Tabota, Yoshinori Takegawa, Katsuya Ito, Shigeru Komeda, Katsuhiko Nose
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Patent number: 7939147Abstract: An open-ended tube comprising walls of a heat-sealable multi-layer polymeric film, wherein said film comprises an outer shrinkable substrate layer and an inner heat-sealable layer, wherein said substrate layer has a degree of shrinkage in the longitudinal dimension of the tube of about 0% to about 50% over the temperature range 55 to 100° C., and a degree of shrinkage in the transverse dimension of the tube of 5 to about 70% over the temperature range 55 to 100° C.; and use thereof in the manufacture of packaging for a container suitable as a receptable for a ready-prepared ovenable meal.Type: GrantFiled: January 21, 2003Date of Patent: May 10, 2011Assignee: DuPont Teijin Films U.S. Limited PartnershipInventors: Mark Edward Dawes, Gary Victor Rhoades, Stephen William Sankey
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Patent number: 7938313Abstract: A container blank comprises at least one substrate layer made of disposable material and at least one film layer disposed substantially over the substrate layer and having at least one portion adapted to shrink away from the substrate layer upon application of heat. The shrunk film layer portion is adapted to thermally insulate the substrate layer located substantially behind the shrunk film layer portion.Type: GrantFiled: January 9, 2009Date of Patent: May 10, 2011Assignee: Dixie Consumer Products LLCInventor: Gerald J. Van Handel
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Patent number: 7939148Abstract: The invention relates to a film structure combining a metallocene-rich layer and an HDPE-containing layer. A preferred embodiment is a structure having metallocene-rich skin layers and an HDPE-containing core. The structures of the invention are particularly useful for collation shrink.Type: GrantFiled: March 18, 2004Date of Patent: May 10, 2011Assignee: ExxonMobil Chemical Patents Inc.Inventors: Donna Sue Davis, Maksymilian Pierre Ravel
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Patent number: 7935401Abstract: A shrink film comprises a skin layer and a base layer. The skin layer may comprise polystyrene or modified polyester. The base layer may comprise alpha-olefin/cyclic-olefin copolymer or alpha-olefin/vinyl aromatic copolymer. The film has a free shrink at 100° C. of at least about 10%. The film is useful for shrink sleeve applications.Type: GrantFiled: October 27, 2005Date of Patent: May 3, 2011Assignee: Cryovac, Inc.Inventors: Slawomir Opuszko, Hubert J. Cook, Vincent W. Herran, Larry B. McAllister
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Publication number: 20110081510Abstract: The invention relates to blown films and methods of making blown films using a melt-strength enhanced polyester composition. The composition has a zero-shear viscosity and a degree of shear thinning that are comparable to PVC's melt rheology. The polyester composition has a branching agent and/or a fluoropolymer processing additive and an inherent viscosity of at least 0.60 dl/g. The diacid component of the polyester composition comprises 97 to 100 mole percent of residues of terephthalic acid, naphthalenedicarboxylic acid, isophthalic acid or mixtures thereof. The glycol component of the polyester composition comprises 97 to 100 mole percent of residues of ethylene glycol, 1,4-cyclohexanedimethanol, diethylene glycol, neopentyl glycol or mixtures thereof.Type: ApplicationFiled: August 24, 2010Publication date: April 7, 2011Applicant: EASTMAN CHEMICAL COMPANYInventors: Wayne Ken Shih, Rondell Paul Little, JR., Freddie Wayne Williams
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Patent number: 7910206Abstract: The present invention relates to a self-rolling pressure-sensitive adhesive sheet, including a shrinkable film layer; a restriction layer disposed on a side of the shrinkable film layer; and a pressure-sensitive adhesive layer disposed on the side of the restriction layer which is opposite to the side on which the shrinkable film layer is disposed. The self-rolling pressure-sensitive adhesive sheet is a releasable pressure-sensitive adhesive sheet, in which the pressure-sensitive adhesive layer or the pressure-sensitive adhesive layer after an adhesiveness decreasing treatment has a pressure-sensitive adhesive power (180° C. peeling, against a silicon mirror wafer, tensile speed: 300 mm/min) of 6.Type: GrantFiled: November 9, 2007Date of Patent: March 22, 2011Assignee: Nitto Denko CorporationInventors: Kazuyuki Kiuchi, Akira Shoji, Akinori Nishio, Kunio Nagasaki
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Publication number: 20110052846Abstract: The heat-shrinkable cylindrical label of the present invention comprises a cylindrical body formed a heat-shrinkable film into a cylindrical form, and a resin layer laid on a partial region of the cylindrical body, wherein the heat-shrinkable film is a film having a heat shrinkage ratio of 30% or more when the film is heated to 85° C. and having a shrinkage stress of 6.5 MPa or less when the film is heated to 85° C., and the resin layer is a layer which does not substantially deform when the layer is heated to 85° C. In a cylindrical-label-attached article, wherein the cylindrical label is shrunk by heat to be fitted to an article, the regions where the resin layer is formed rise up as a three-dimensional pattern in a convex form.Type: ApplicationFiled: January 21, 2009Publication date: March 3, 2011Applicant: FUJI SEAL INTERNATIONAL, INC.Inventors: Eiji Hikida, Akiko Haga
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Patent number: 7887903Abstract: The present invention provides a laminated film including at least two layers of an outer layer having a printed portion on a surface and an inner layer subjected to an antifogging treatment in which principal resin comprising a solid content of the printed portion is made of chlorinated polypropylene-based resin or urethane-based resin. This antifog laminated film hardly degrades in an antifogging property even when the antifog laminated film subjected to printing on the outer layer of a surface subjected to the antifogging treatment and the printed surface are strongly brought into contact with each other due to an operation of winding the film into a roll or the like.Type: GrantFiled: April 19, 2005Date of Patent: February 15, 2011Assignee: Kureha CorporationInventors: Tsutomu Uehara, Takeo Omori, Tadayoshi Itoh
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Publication number: 20110003099Abstract: The invention relates to the use linear polyethylene having an MIR indicative of the presence of some long chain branching having a density of 0.91 to 0.94 g/cm3 determined according to ASTM D4703/D1505, an I2.16 (MI) of from 0.05 to 1 g/10 min, and I21.6/I2.16 (MIR) of more than 35, the MI and MIR being determined according to ASTM 1238 D at 190° C., and a difference between the MD Tensile force based on ASTM D882-02 at 100% elongation and MD 10% Offset yield of a reference film as defined herein having a thickness of 25 ?m of at least 15 MPa. The invention also relates to coextruded film structures made using such linear polyethylene in the core layer of a multi-layer structure to provide easily processes, strong, highly transparent films.Type: ApplicationFiled: March 4, 2009Publication date: January 6, 2011Inventor: Michael J. Vinck
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Patent number: 7862869Abstract: The present invention provides a flexible multilayer packaging film and packages formed therefrom wherein the films include a first film layer comprising a first biaxially-oriented polymer selected from the group consisting of a polyester, a polyolefin, a polyamide, and a blend thereof and a surface-roughened portion, a second film layer comprising an adhesive, a third film layer comprising a barrier material, a fourth film layer comprising a second biaxially-oriented polymer selected from the group consisting of a polyester, a polyolefin, a polyamide, and a blend thereof and at least one score-line; wherein the packages comprise a tear-initiation area and a directional tear zone.Type: GrantFiled: October 20, 2003Date of Patent: January 4, 2011Assignee: Milprint, Inc.Inventors: Daniel S. Papenfuss, Michael Scott Hartman, Amy Lynn Kraimer, Sam Edward Wuest
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Patent number: 7846517Abstract: A heat-shrinkable polylactic acid (PLA) film and a method of its manufacture are provided. In an exemplary embodiment, the PLA films exhibit heat-induced growth in the cross direction with concomitant shrinkage in the machine direction. The films may comprise any grade of PLA polymer, optionally including additives, such as antiblock, slip, viscosity enhancers and combinations thereof. A method of manufacture is disclosed which includes a post-extrusion temperature conditioning step.Type: GrantFiled: April 19, 2006Date of Patent: December 7, 2010Assignee: Plastic Suppliers, Inc.Inventor: Joseph B. McDaniel
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Publication number: 20100300905Abstract: An article, such as a polymeric film, sachet, purge control pad, or label, includes a sulfur scavenger. In some embodiments, an oxygen scavenger is also included. A method includes providing an article, including a sulfur scavenger and an oxygen scavenger; and subjecting the article to a dosage of actinic radiation effective to trigger the oxygen scavenger. A method of reducing the sulfur content of a package containing a food product includes either (1) providing a film including a layer including a zinc ionomer, and a layer including an oxygen scavenger; packaging the food product in the film; and storing the package for at least 24 hours; or (2) providing the food product at a temperature of 40° F.; providing a film including a layer including a sulfur scavenger; packaging the food product in the film; and storing the package for at least 24 hours.Type: ApplicationFiled: August 13, 2010Publication date: December 2, 2010Applicant: CRYOVAC, INC.Inventors: Drew V. Speer, Cynthia L. Ebner, Michael D. Grah
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Patent number: 7838770Abstract: The present invention relates to a method as well as to a joint assembly (12) for splicing a first and a second eclectic cable (1, 2) by means of a tubular elastic sleeve (15) at a splicing zone (11) between such cables (1, 2), said tubular sleeve (15) being supported in an expanded condition on a removable hollow supporting element (16) detachable in a first supporting portion (17) and a second supporting portion (18).Type: GrantFiled: September 16, 2004Date of Patent: November 23, 2010Assignee: Prysmian Cavi e Sistemi Energia S.r.l.Inventors: Francesco Portas, Ubaldo Vallauri
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Patent number: 7833467Abstract: A polyester container obtained by stretch-forming a preform of a thermoplastic polyester resin formed by injection forming wherein the central portion of the bottom wall is the remaining part of the gate at the time of injection forming, and is formed relatively thicker than the bottom wall surrounding the central portion, and the central portion of the bottom wall is substantially amorphous, and the bottom wall surrounding the central portion is oriented and crystallized. The container exhibits excellent heat resistance and shock resistance despite a thick portion that is the remaining portion of the injection gate is formed at the center of the bottom portion.Type: GrantFiled: July 25, 2005Date of Patent: November 16, 2010Assignee: Toyo Seikan Kaisha, Ltd.Inventors: Ryo Suenaga, Tsutomu Iwasaki, Taku Hosokai, Toshiki Sakaguchi, Hisao Iwamoto
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Patent number: 7829163Abstract: The present invention provides a shrink sleeve for use on a closure of an article. The present invention does so by providing a decorated closure for an article, such as a container, used to package an item or items. The decorated closure includes a shrink sleeve and a closure for an article. The closure has a top end, a bottom end, and a side surface. The closure may further include a centerpoint of the top end and a centerpoint of the bottom end with a longitudinal axis passing therethrough. The shrink sleeve is shrunk around at least the side surface of the article, and includes at least one visible decoration on a surface of the shrink sleeve.Type: GrantFiled: October 18, 2005Date of Patent: November 9, 2010Assignee: Multi-Color CorporationInventors: Philip J. Albenice, John Voelker
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Patent number: 7829655Abstract: In the heat-shrinkable polyester film of the present invention, the main shrinkage direction is the longitudinal direction. In addition, the hot-water heat shrinkage ratios in the longitudinal direction and the width direction when the film is treated in hot water at 90° C. for 10 seconds, the refractive indexes in the longitudinal direction and the width direction and the natural shrinkage ratio after aging at 40° C. and 65% RH for 700 hours or more are each controlled in predetermined ranges. The heat-shrinkable polyester film of the present invention is manufactured by stretching an unstretched film at a ratio of 2.5 times or more and 6.0 times or less in the width direction at a temperature of Tg+5° C. or more and Tg+40° C. or less, passing the film in an intermediate zone that does not execute an active heating operation, heat-treating the film at a temperature of 100° C. or more and 170° C. or less over a period of 1.0 second or more and 10.Type: GrantFiled: June 13, 2007Date of Patent: November 9, 2010Assignee: Toyo Boseki Kabushiki KaishaInventors: Takurou Endo, Masayuki Haruta, Norimi Tabota, Katsuhiko Nose
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Publication number: 20100266791Abstract: The present invention refers to a multilayer heat shrinkable film characterized by a combination of desirable properties, such as high shrinkage, good optical properties, excellent sealability, high abuse and high puncture resistance. The invention further is directed to a method of producing said film. The invention is further directed to the use of said film or bags and pouches made thereof for packaging goods as for example food products. The invention also refers to tubes made with the film.Type: ApplicationFiled: April 14, 2010Publication date: October 21, 2010Applicant: FLEXOPACK S.A.Inventor: Dimitris Gkinosatis
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Patent number: 7793861Abstract: A vapor-dispersing device comprising a moveable piston with an evaporative member is described that operates by the repetitive movement of the piston to bring the evaporative member into repeated contact with the exposed end of a liquid transfer means to wick volatile liquid out from a reservoir onto the evaporative member and to expel vapors out through vents.Type: GrantFiled: January 17, 2007Date of Patent: September 14, 2010Assignee: The Dial CorporationInventors: Jeffrey Bankers, Kevin Hafer