Natural Or Synthetic Rubber Or Rubber-like Compound Containing Patents (Class 428/36.8)
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Patent number: 11965046Abstract: The present invention relates to a polymer latex for dip-molding applications obtainable by free-radical emulsion polymerization of a mixture of ethylenically unsaturated monomers comprising at least one conjugated diene and at least one ethylenically unsaturated nitrile compound in an aqueous medium in presence of seed latex particles having a glass transition temperature (mid point temperature Tmg) measured by DSC according to ASTM D3418-03 of ?50° C. to 50° C. wherein the seed latex particles do not contain structural units derived from ethylenically unsaturated nitrile compounds, to a method of preparing said polymer latex, to articles made by using said polymer latex and to a method for preparing dip-molded articles from said polymer latex.Type: GrantFiled: March 21, 2016Date of Patent: April 23, 2024Assignee: Synthomer Sdn. Bhd.Inventors: Andrew Kells, Sören Butz, Alexandra Abele, Peter Shaw, Brian Saunders, Gareth Simpson
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Patent number: 11845817Abstract: The present disclosure relates to synthetic polyisoprene elastomeric articles including: one or more cured blend compositions of pre-vulcanized synthetic polyisoprene particles and non-prevulcanized synthetic polyisoprene particles, wherein the pre-vulcanized synthetic polyisoprene particles and the non-prevulcanized synthetic polyisoprene particles are bonded by mono-sulfidic and/or di-sulfidic, and poly-sulfidic crosslinks, wherein the poly-sulfidic crosslinks are present in an amount of 60 to 79 percent of the total amount of crosslinks in the cured blend composition. Methods of making synthetic polyisoprene elastomeric articles such as gloves or condoms is also disclosed.Type: GrantFiled: March 8, 2019Date of Patent: December 19, 2023Assignee: Ansell LimitedInventors: Koralalage Don Sugathananda Amarasekera, David M. Lucas, Angodage Sujith Ruwan Samantha Perera, Dambadeni Arachchige Ruwani Upekshika Lalanthani
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Patent number: 11802194Abstract: A rubber composition is based on at least one elastomer, a reinforcing filler, a crosslinking system and an optionally hydrogenated hydrocarbon-based resin, predominantly composed of units selected from the group consisting of cyclopentadiene, dicyclopentadiene, methylcyclopentadiene and mixtures thereof, said hydrocarbonbased resin having an average molecular weight Mz of less than 2000 g/mol and a glass transition temperature Tg, expressed in ° C., such that: Tg?80?2*(% HA), wherein % HA represents the content of aromatic protons of said resin, the content of said hydrocarbon-based resin being within a range extending from 15 to 150 phr.Type: GrantFiled: May 17, 2022Date of Patent: October 31, 2023Assignee: COMPAGNIE GENERALE DES ETABLISSEMENTS MICHELINInventors: Benoit De Gaudemaris, Alain Hut
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Patent number: 11717025Abstract: A smoke filter apparatus comprising a segmented conduit formed of a plurality of nesting sections and comprising one or more filters. The filters may comprise a preferred filter sequence, wherein the preferred filter sequence comprises a metal screen filter, a charcoal filter, and an acetate filter.Type: GrantFiled: April 22, 2021Date of Patent: August 8, 2023Assignee: Squid Roach, Inc.Inventor: Edward T. Nista
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Patent number: 11465394Abstract: A plastic film composite for film packaging with an oriented outer film and a sealing film which differs from the outer film, both of which outer film and sealing film are either polyethylene-based or polypropylene-based. The outer film and the sealing film are connected by a polyolefin-based extrusion lamination comprising at least one layer. A film packaging comprising the plastic film lamination and a method for the production of packaging containers uses the plastic film composite.Type: GrantFiled: December 13, 2019Date of Patent: October 11, 2022Assignee: Mondi AGInventors: Jens Koesters, Jochen Brauer
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Patent number: 11365308Abstract: A rubber composition is based on at least one elastomer, a reinforcing filler, a crosslinking system and an optionally hydrogenated hydrocarbon-based resin, predominantly composed of units selected from the group consisting of cyclopentadiene, dicyclopentadiene, methylcyclopentadiene and mixtures thereof, said hydrocarbon-based resin having an average molecular weight Mz of less than 2000 g/mol and a glass transition temperature Tg, expressed in ° C., such that: Tg?80?2*(% HA), wherein % HA represents the content of aromatic protons of said resin, the content of said hydrocarbon-based resin being within a range extending from 15 to 150 phr.Type: GrantFiled: October 14, 2016Date of Patent: June 21, 2022Assignee: COMPAGNIE GENERALE DES ETABLISSEMENTS MICHELINInventors: Benoit De Gaudemaris, Alain Hut
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Patent number: 11345828Abstract: A siloxane-modified latex binder includes a polymerization product of a monomer or a mixture of monomers for producing a latex polymer and a non-hydrolyzable siloxane. The non-hydrolyzable siloxane is represented by Formula (I): wherein: R1, R2, R3, R4, R5, R6, R7, and R8 are independently hydrogen, alkyl, —O-alkyl, —OH, —S-alkyl, —SH, amino, amido, epoxy, carboxyl, acrylate, (meth)acrylate, cycloalkyl, aryl, alkalyl, polyether, alkenyl, or alkynyl; and n is an integer from 0 to about 300; provided that at least one of R1, R2, R3, R4, R5, R6, R7, and R8 is an alkenyl or alkynyl.Type: GrantFiled: December 20, 2018Date of Patent: May 31, 2022Assignee: COLUMBIA INSURANCE CO.Inventors: Yong Yang, Johanna L. Garcia De Visicaro, Luz Clarena Shavel, Robert Sheerin
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Patent number: 11168815Abstract: Hoses include an inner tube, a reinforcement layer disposed outwardly from the inner tube, and a cover layer disposed outwardly from the reinforcement layer, where the cover layer and/or the inner tube includes a cured composition having a sustainable content and formed from a mixture including EPDM/EPR sustainable polymer and a sulfur or peroxide based curing system. In some cases, the EPDM/EPR sustainable polymer has ethylene monomer derived from one or more renewable sources, such as, ethylene monomer derived from sugar cane. The mixture may further include one or more of recovered carbon black and sustainable oils from renewable sources. The hose embodiments may also include the reinforcement layer formed of fibers from sustainable material. The hose may contain the sustainable content in an amount of up to 75% by weight based upon total hose weight, or even greater than 25% by weight based upon total hose weight.Type: GrantFiled: March 9, 2020Date of Patent: November 9, 2021Assignee: ContiTech USA, Inc.Inventors: Lance Miller, Jeffrey T. Epperson, Jenny Zhaoxia Yu, Mathew Augustine, Jeffrey P. Dotson
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Patent number: 10982075Abstract: The present invention relates to a polymer latex for dip-molding applications including: particles of a carboxylated conjugated diene nitrile latex polymer in combination or association with particles of a latex polymer including at least one oxirane-functional group, to the use of said polymer latex for the production of dip-molded articles or for coating or impregnating a substrate, to compounded compositions including said polymer latex, to a method for making dip-molded articles and to articles made by using said polymer latex.Type: GrantFiled: June 1, 2016Date of Patent: April 20, 2021Assignee: Synthomer Sdn. Bhd.Inventors: Zhenli Wei, Dieter Wolters, Floyd Greaves, Alexandra Abele, Thian Hong Ng
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Patent number: 10662347Abstract: Methods for preparing copolymeric emulsions from at least one water soluble monomer and at least one water insoluble monomer are disclosed herein. In some embodiments, one or more surfactants and stabilizers may be used. In some embodiments, the monomers used in the process include, by total monomer weight, at least 50% water soluble monomers and at least 10% water insoluble monomers. Copolymer emulsions formed from the reaction product of at least one water soluble monomer and at least one water insoluble monomer are also disclosed along with articles coated with such emulsions and coating formulations made from such emulsions as well as methods for the manufacture and coating of such articles.Type: GrantFiled: October 29, 2014Date of Patent: May 26, 2020Assignee: ALLEGIANCE CORPORTATIONInventors: Daniel L. Holguin, Andre Mayer, Suo Phong Lee, Michael Meyers, Dennis Kopp, Wei Cheong Wong, Chii Yih Low, Shiping Wang, Xiaochuan Hu, Chuang Sim Chong
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Patent number: 10577138Abstract: Use of a combination of a sealing tape, cap and container for sealed storage of a sample at ?70° C. or below. A container receives sample for subsequent storage of the sample at ?70° C. or below. A cap encloses the sample in the container for subsequent storage of the sample at ?70° C. or below, a joint defined between the cap and the container. A sealing tape sealingly covers said joint between the cap and the receptacle during storage of the sample at ?70° C. or below, the sealing tape comprising a strip body having a first surface and a second surface, the first surface and the second surface being made of one of a silicone and a silicone rubber, a thickness between the first surface and the second surface ranging between 0.5 mil-60.0 mil, the strip body configured for the first surface at a first end to self-adhere to the second surface at a second end by overlaying in a silicone-to-silicone bond to cover said joint.Type: GrantFiled: April 26, 2017Date of Patent: March 3, 2020Inventor: Gourgen Ambartsoumian
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Patent number: 10538609Abstract: A synthetic polyisoprene latex emulsion has pre-vulcanization composition and post vulcanization composition. The pre-vulcanization composition comprises soluble sulfur with high S8 ring structure that is catalytically broken by a zinc dithiocarbamate. Surfactants present in the pre-vulcanization composition wets synthetic polyisoprene particles and permeates small sized sulfur and accelerator molecules into the interior of these particles thereby pre-vulcanizing the particles. The degree of pre-vulcanization is verified by isopropanol index test. The latex emulsion has post-vulcanization composition with accelerators that crosslink inter-particle region during post vulcanization cure cycle. The dipped synthetic polyisoprene article is substantially uniformly cured both in the inter-particle and intra-particle regions and reliably exhibits high cross link density, uniform distribution of double bonds in TEM and zinc segregation at the boundaries or original particles by electron microprobe analysis.Type: GrantFiled: June 28, 2017Date of Patent: January 21, 2020Assignee: Lifestyles Healthcare Pte. Ltd.Inventors: David M. Lucas, Sugath Amarasekera, Dave Narasimhan, Adeline Ai Lin Kung
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Patent number: 10363371Abstract: A laminated gasket (13) to be used for a medical syringe is provided, which includes a main body (14) made of an elastic material, and a film (15) provided on a surface of the main body (14). The gasket (13) has a circumferential surface portion (17) to be brought into contact with an inner peripheral surface (16) of a syringe barrel (11) of the syringe. The gasket (13) further includes a projection (22) provided on a surface portion of the film (15) present in the circumferential surface portion (17) as extending circumferentially of the gasket. The projection (22) has a height of not less than 15 ?m and not greater than 55 ?m and a width of not less than 30 ?m and not greater than 75 ?m. With this arrangement, the laminated gasket is excellent in sealability.Type: GrantFiled: July 3, 2017Date of Patent: July 30, 2019Assignee: SUMITOMO RUBBER INDUSTRIES, LTD.Inventors: Hiroaki Nakano, Yuki Sakashita, Yoshikazu Masuyama
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Nucleation efficiency of talc in the foaming behaviour and cellular structure of polymer-based foams
Patent number: 10160843Abstract: A polymer-based foam composition includes a polymer and up to 20 wt. % talc particles, based on the total weight of the composition. The talc particles include microcrystalline talc.Type: GrantFiled: June 18, 2013Date of Patent: December 25, 2018Assignee: Imerys Talc EuropeInventor: Gilles Meli -
Patent number: 10000619Abstract: A diaphragm including a cross-linked fluororubber layer obtained by cross-linking a fluororubber composition containing a fluororubber (A) and a carbon black (B), the cross-linked fluororubber layer having a loss modulus E? of 400 kPa or higher and 6,000 kPa or lower determined by a dynamic viscoelasticity test under conditions of measurement temperature: 160° C., tensile strain: 1%, static tension under a constant static load condition for measuring strain distribution: 157 cN, and frequency: 10 Hz.Type: GrantFiled: August 16, 2012Date of Patent: June 19, 2018Assignee: DAIKIN INDUSTRIES, LTD.Inventors: Junpei Terada, Daisuke Ota, Masanori Kitaichi, Shoji Fukuoka
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Patent number: 9981995Abstract: Azocarbonyl-functionalized silanes of formula I (R1)3-a(R2)aSi—R1—NH—C(O)—N?N—R4??(I) and methods for their production are provided. The silanes of formula (I) are useful in rubber mixtures to provide moldings having improved tear-resistance.Type: GrantFiled: April 8, 2015Date of Patent: May 29, 2018Assignee: Evonik Degussa GmbHInventors: Torsten Peterle, Julia Keck, Sascha Erhardt, Anke Blume, Caren Roeben
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Patent number: 9840572Abstract: An acrylic rubber contains (a) methyl methacrylate units, (b) ethyl acrylate units, (c) n-butyl acrylate units, (d) 2-methoxyethyl acrylate units, and (e) cross-linking site monomer units, in which the acrylic rubber contains 10 to 20% by weight of (a) the methyl methacrylate units, 15% by weight or less of (b) the ethyl acrylate units, 60 to 80% by weight of (c) the n-butyl acrylate units, 10 to 30% by weight of (d) the 2-methoxyethyl acrylate units, and 0.5 to 5% by weight of (e) the cross-linking site monomer units.Type: GrantFiled: July 3, 2015Date of Patent: December 12, 2017Assignees: ZEON CORPORATION, HONDA MOTOR CO., LTDInventors: Nobuyoshi Emori, Tomonori Ogawa, Takanori Arakawa, Takayuki Kogure, Kazutaka Yokoyama, Ryosuke Kodaira
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Patent number: 9809008Abstract: A laminate of a rubber layer (A) and a fluororesin layer (B) on the rubber layer (A), wherein the rubber layer (A) is a layer made of a rubber composition for vulcanization, the rubber composition for vulcanization contains an unvulcanized rubber (a1); at least one compound (a2) selected from the group consisting of a 1,8-diazabicyclo(5.4.0)undec-7-ene salt, a 1,5-diazabicyclo(4.3.0)-non-5-ene salt, 1,8-diazabicyclo(5.4.0)undec-7-ene, and 1,5-diazabicyclo(4.3.0)-non-5-ene; magnesium oxide (a3); and silica (a4), the amount of the compound (a2) is larger than 1.0 part by mass and not larger than 5.0 parts by mass, for each 100 parts by mass of the unvulcanized rubber (a1), the fluororesin layer (B) is a layer made of a fluoropolymer composition, and the fluoropolymer composition contains a fluoropolymer (b1) having a copolymer unit derived from chlorotrifluoroethylene.Type: GrantFiled: May 19, 2010Date of Patent: November 7, 2017Assignee: DAIKIN INDUSTRIES, LTD.Inventors: Toshiaki Masui, Tomihiko Yanagiguchi, Mayuko Taeda, Takeshi Inaba
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Patent number: 9803070Abstract: Disclosed are a carboxylic acid-modified nitrile copolymer latex for dip molding comprising a combination of a carboxylic acid-modified nitrile copolymer latex and a carboxylic acid-modified styrene copolymer latex, a latex composition for dip molding comprising the same and a molded article prepared therefrom. Molded articles with superior tensile strength are produced by respectively preparing a carboxylic acid-modified nitrile latex having a low glass transition temperature and an average particle diameter of 90 nm or higher, and a carboxylic acid-modified styrene latex having a glass transition temperature of 80° C. or higher and an average particle diameter less than 90 nm and then mixing the two latexes.Type: GrantFiled: November 13, 2012Date of Patent: October 31, 2017Assignee: LG CHEM, LTD.Inventors: Seung Hun Yang, Jung Su Han, Seung Uk Yeu, Byoung Yun Kim, Jung Eun Kim
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Patent number: 9637573Abstract: A polymer reactor-blend comprising at least a first component having a polydispersity index of greater than about 20 and is present in an amount of from about 1 wt. % to about 99 wt. % based on the total weight of the polymer and a second component having a polydispersity index of less than about 20 and is present in an amount of from about 1 wt. % to about 99 wt. % based on the total weight of the polymer wherein a molecular weight distribution of the second component lies within a molecular weight distribution of the first component.Type: GrantFiled: February 23, 2016Date of Patent: May 2, 2017Assignee: Chevron Phillips Chemical Company LPInventors: Mark L. Hlavinka, Qing Yang, William B. Beaulieu, Paul J. Deslauriers
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Patent number: 9500806Abstract: An optical printed circuit board having at least one optical interface on a surface, and a deformable dam structure provided on the optical printed circuit board adjacent to the at least one optical interface. The deformable dam structure has an absorbent portion for absorbing adhesive and a method or forming the same.Type: GrantFiled: July 15, 2015Date of Patent: November 22, 2016Assignee: Xyratex Technology LimitedInventor: Richard C. A. Pitwon
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Patent number: 9365442Abstract: Hydrophobically modified Si-containing polyamines are useful for treating scale in industrial process streams. Preferred hydrophobically modified Si-containing polyamines are particularly useful for treating aluminosilicate scale in difficult-to-treat industrial process streams, such as in the Bayer alumina process streams, nuclear waste streams and kraft paper mill effluent streams.Type: GrantFiled: March 6, 2013Date of Patent: June 14, 2016Assignee: Cytec Technology Corp.Inventors: Howard I. Heitner, Donald P. Spitzer
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Patent number: 9328242Abstract: The present invention relates to a polysiloxane composition which contains (A) at least one type of organopolysiloxane that contains at least two unsaturated aliphatic hydrocarbon groups in the molecule, (B) at least one type of organohydrogenpolysiloxane that contains at least two silicon-bonded hydrogen atoms in the molecule, (C) a hydrosilylation reaction catalyst, and (D) inorganic particles which have a major axis to minor axis ratio of 1 to 1.5 and in which the proportion of particles having a diameter of 50 ?m or greater is 5 wt. % or less of the total quantity of particles, and which satisfies prescribed conditions. The polysiloxane composition of the present invention has good processability and can provide a hard cured product having an extremely low coefficient of thermal expansion after curing.Type: GrantFiled: August 16, 2011Date of Patent: May 3, 2016Assignee: DOW CORNING TORAY CO., LTD.Inventors: Takuya Ogawa, Kazusato Shibata
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Latex comprising water and a styrenic block copolymer and a process for preparing articles therefrom
Patent number: 9321932Abstract: Articles with enhanced tensile strength and comfort are prepared from a latex comprising water and a styrenic block copolymer, wherein the styrenic block copolymer has 2 or more poly(vinyl aromatic) blocks and at least one block of polymerized conjugated diene, wherein the styrenic block copolymer has a weight average molecular weight of 150,000 to 250,000, the poly(vinyl aromatic) blocks have a weight average molecular weight ranging from 9,000 to 15,000, and the content of poly(vinylaromatic) blocks in the styrenic block copolymer ranges from 8 to 15% wt, based on the total styrenic block copolymer, by a process which comprises coating a surface with the latex to obtain a film, wherein the latex comprises a vulcanizing agent. The invention also provides a latex comprising such a styrenic block copolymer and a vulcanizing agent, as well as a styrenic block copolymer that is particularly suitable for use in such a latex.Type: GrantFiled: August 9, 2012Date of Patent: April 26, 2016Assignee: Kraton Polymers U.S. LLCInventor: Wouter De Jong -
Patent number: 9034992Abstract: An improved polymerization and process method allows the production of special nitrile rubbers which are characterized by a specific anion content and an excellent storage stability and allow a particularly good vulcanization rate and moreover result in vulcanized materials that have advantageous properties, especially with regard to the contact with metal components of molded parts based on said vulcanized materials.Type: GrantFiled: September 10, 2013Date of Patent: May 19, 2015Assignee: LANXESS Deutschland GmbHInventors: Werner Obrecht, Rolf Josten, Michael Klimpel
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Publication number: 20150118427Abstract: The invention relates to a composition Z comprising a component B, a component C, a component D, a component E and a component P, wherein the component B is a polyethylene glycol, the component C is a polyglycerol ester, the component D is an earth alkali carbonate, the component E is a phyllosilicate, and the component P is a polystyrene and/or an alloy thereof. Composition Z is suitable to increase the hydrophilic properties of processed solid or foamed polystyrene material, especially for making a film, sheet or food tray.Type: ApplicationFiled: April 17, 2013Publication date: April 30, 2015Applicant: CLARIANT FINANCE (BVI) LIMITEDInventors: Pirko Kolditz, Lutz Liebehentschel
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Patent number: 9012026Abstract: The invention relates to a copolyamide comprising at least two different units corresponding to the following general formulation: A/X.T A is chosen from a unit obtained from an amino acid, a unit obtained from a lactam and a unit corresponding to the formula (Ca diamine).(Cb diacid), with a representing the number of carbon atoms of the diamine and b representing the number of carbon atoms of the diacid, a and b each being between 4 and 36, advantageously between 9 and 18, X.Type: GrantFiled: April 1, 2014Date of Patent: April 21, 2015Assignee: Arkema FranceInventors: Thierry Briffaud, Philippe Blondel
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Publication number: 20150105198Abstract: A power transmission belt includes a transparent or semitransparent sheet material covering a portion of a surface of a belt body including a mark. At least a portion of the belt body covered with the sheet material is made of a rubber composition vulcanized with sulfur. The sheet material is made of a rubber material containing a diene rubber. The sheet material is vulcanized with sulfur together with the rubber composition forming the portion of the belt body covered with the sheet material such that the sheet material is connected to the belt body.Type: ApplicationFiled: December 17, 2014Publication date: April 16, 2015Inventors: Yoshinori Yamaji, Kenji Hirakuni
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Patent number: 8999470Abstract: Disclosed is a surface conductive laminated sheet which comprises a base material layer containing an ABS resin as a main component, and a surface layer laminated on the surface of at least one side of the base material layer. In the laminated sheet, the ABS resin in the base material layer includes a composition made of 5-15 mass % of vinyl cyanide monomer, 45-65 mass % of diene-based rubber, and 50-20 mass % of aromatic vinyl monomer, and includes a graft rubber having a graft rate of 50-80%. The graft rubber has a mass average molecular weight (Mw) of a graft chain of 18,000-56,000, and/or has a volume average particle diameter of 0.3 to 2.0 ?m. By using the laminated sheet, it is possible to obtain an electronic part packaging container, such as carrier tape etc., which has extremely few punch burrs regardless of the type of forming apparatus when punched by means of a slit method or embossing.Type: GrantFiled: March 18, 2011Date of Patent: April 7, 2015Assignee: Denki Kagaku Kogyo Kabushiki KaishaInventors: Junpei Fujiwara, Masatoshi Kawata, Yasushi Miyamura
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Patent number: 8999471Abstract: A cylindrical stopper for closing a medical system and a method for closing a medical system, and to the medical system itself, closed with the stopper of the invention.Type: GrantFiled: February 8, 2011Date of Patent: April 7, 2015Inventors: Thomas Nicola, Martin Schmidtlein
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Publication number: 20150093528Abstract: Methods and apparatuses disclosed herein relate to a recyclable thermoplastic unit that includes a casing body composed of a first thermoplastic having a first melting point. The casing body also includes a first locking mechanism that is configured to mate with a second locking mechanism of a sacrifice layer. The sacrifice layer is composed of a second thermoplastic and includes the second locking mechanism. The sacrifice layer has a melting point that is greater than the melting point of the casing body.Type: ApplicationFiled: December 5, 2014Publication date: April 2, 2015Inventor: Aya Seike
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Publication number: 20150079322Abstract: A novel precursor is disclosed. The precursor comprises (a) natural or synthetic rubber; (b) a material selected from the group consisting of thermoplastic vulcanizate (TPV), thermoplastic incorporating microparticles of rubber, and any combination thereof; and (c) a cross-linking agent. In some embodiments, the precursor additionally comprises components such as a cross-linking co-agent, carbon black, fillers. The incorporation of thermoplastic in to the precursor enables the inclusion of carbon black or other fillers without any necessity for addition of plasticizers or process oils.Type: ApplicationFiled: April 14, 2013Publication date: March 19, 2015Inventors: Mirco Pellegrini, Nitzan Eliyahu
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Patent number: 8980391Abstract: The present invention generally relates to vulcanization compositions used to vulcanize elastomeric articles, where the vulcanization compositions have reduced allergenic potential as compared to elastomeric articles formed using vulcanization compositions having non-fugitive accelerators. The present invention also relates to elastomeric articles formed using the vulcanization compositions. The invention further relates to methods for making a reduced-allergenicity vulcanization composition, and to methods for using the vulcanization compositions to vulcanize elastomeric articles.Type: GrantFiled: June 27, 2011Date of Patent: March 17, 2015Assignee: Allegiance CorporationInventors: Seong Fong Chen, Wei Cheong Wong, Chii Yih Low
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Patent number: 8956706Abstract: A flexible tubing material includes a radiation crosslinked blend of a first elastomeric polymer including a styrenic thermoplastic elastomer, an ethylene vinyl acetate elastomer, a polyolefin elastomer with a second elastomeric polymer including a polyolefin elastomer, a diene elastomer, or combination thereof, with the proviso that the first elastomeric polymer and the second elastomeric polymer are different. In an embodiment, a method of making a material includes providing the first elastomeric polymer, providing the second elastomeric polymer, blending the first elastomeric polymer and the second elastomeric polymer, extruding or injection molding the blend, and crosslinking the blend with radiation.Type: GrantFiled: December 29, 2010Date of Patent: February 17, 2015Assignee: Saint-Gobain Performance Plastics CorporationInventors: Sridhar Krishnamurthi Siddhamalli, Zhizhong Liu, Mark W. Simon, Charles S. Golub, Heidi Sardinha, Wayne Edward Garver, Mark F. Colton, Robert L. Wells, Gerald L. Stadt, Michael J. Tzivanis, William Risen, Nathan Klettlinger
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Publication number: 20150034227Abstract: An article having a fluid permeation prevention layer, such as a pneumatic tire or hose. A tire for example includes an outer tread layer, intermediate sidewall and carcass layers and an innermost air permeation prevention layer: (i) the air permeation prevention (APP) layer having an upper and a lower surface, the layer having a polymer composition exhibiting an air permeation coefficient (APC) of about 25×10?12 cc cm/cm2 sec cmHg (at 30° C.) or less and a Young's modulus of about 1 MPa to about 500 MPa, the polymer composition comprising: (A) at least 10 wt % of at least one thermoplastic resin component having an APC of about 25×10?12 cc cm/cm2 sec cmHg (at 30° C.) or less and a Young's modulus of more than 500 MPa, which is preferably a polyamide resin or mixture, and (B) at least 10 wt % of at least one elastomer component having an APC of more than about 25×10?12 cc cm/cm2 sec cmHg (at 30° C.Type: ApplicationFiled: October 17, 2014Publication date: February 5, 2015Inventors: Andy Haishung Tsou, Stephan Bertil Ohlsson, Yoshihiro Soeda, Shusaku Tomoi, Yuichi Hara
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Publication number: 20150017363Abstract: Devices for protecting horn and antler tips and, in particular, devices for protecting the tips of palmated and non-palmated antlers and horns of game animal when packaging, transporting and shipping antlers and horns of game animals.Type: ApplicationFiled: July 3, 2013Publication date: January 15, 2015Inventor: John T. Buck
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Patent number: 8920894Abstract: Disclosed is a vulcanized rubber laminate, wherein a thermoplastic resin layer and an unvulcanized epichlorohydrin rubber composition layer containing a specific maleimide compound, vulcanizing agent, and acid acceptor are heated and bonded. Specifically disclosed is a laminate configured by heating and bonding an unvulcanized epichlorohydrin rubber composition layer (A) and a thermoplastic resin (B), wherein the unvulcanized epichlorohydrin rubber composition contains: an epichlorohydrin rubber (a), a compound containing one or more maleimide group within the molecule (b), a vulcanizing agent (c), and an acid acceptor (d).Type: GrantFiled: June 1, 2010Date of Patent: December 30, 2014Assignee: Daiso Co., Ltd.Inventors: Toyofumi Otaka, Koushiro Hamaguchi, Yoritaka Yasuda, Taro Ozaki
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Publication number: 20140377481Abstract: Copolymers having a substantially heterogeneous composition distribution and strong UV absorption comprise the direct reaction product of an isoolefin and at least one terpene having the molecular formulae of (C5H8)n where n is equal to or greater than two, and optionally additional monomers. More specifically, the invention relates to copolymers of isobutylene and alloocimene that exhibit thermoplastic elastomeric properties and exhibit strong filler interaction. The present invention also relates to methods for producing copolymers of at least one isoolefin and at least one terepene by a two-phase living polymerization that produces a substantially linear diblock, triblock, and multiblock copolymer having substantially heterogeneous distribution of the isoolefin and terpene units.Type: ApplicationFiled: January 17, 2013Publication date: December 25, 2014Applicant: UNIVERSITY OF AKRONInventors: Judit E. Puskas, Gabor Kaszas
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Patent number: 8916248Abstract: Metal-coated polymer articles containing structural substantially porosity-free, fine-grained and/or amorphous metallic coatings/layers optionally containing solid particulates dispersed therein on polymer substrates, are disclosed. The substantially porosity-free metallic coatings/layers/patches are applied to polymer or polymer composite substrates to provide, enhance or restore vacuum/pressure integrity and fluid sealing functions. Due to the excellent adhesion between the metallic coating and the polymer article satisfactory thermal cycling performance is achieved. The fine-grained and/or amorphous metallic coatings are particularly suited for strong and lightweight articles, precision molds, sporting goods, aerospace and automotive parts and other components exposed to thermal cycling and stress created by erosion and impact damage.Type: GrantFiled: February 1, 2013Date of Patent: December 23, 2014Assignee: Integran Technologies, Inc.Inventors: Jonathan McCrea, Francisco Gonzalez, Gino Palumbo, Klaus Tomantschger, Rich Emrich, Konstantinos Panagiotopoulos, Mary Pasquantonio, John Kratochwil, Herath Katugaha
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Publication number: 20140367026Abstract: A kit, which is usable for temporary attachment of an electronic device to a support of a tyre casing, includes: an attachment member and a separation element. The attachment member includes an adhesive mass for attaching the electronic device to the support. The separation element, which separates the adhesive mass from the support, is able to adhere to the adhesive mass. An adhesion between the adhesive mass and the separation element exceeds an adhesion between the adhesive mass and the support as a function of a variation of at least one parameter of the adhesive mass.Type: ApplicationFiled: October 4, 2012Publication date: December 18, 2014Applicants: MICHELIN RECHERCHE ET TECHNIQUE S.A., COMPAGNIE GENERALE DES ETABLISSEMENTS MICHELINInventors: Claudio Battocchio, Thierry Penot, Pierre Voissier
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Patent number: 8906479Abstract: Disclosed is a shaped article comprising a composition comprising polyamide and ionomer wherein the ionomer comprises a mixture of Zn and alkali metal (M2) cations wherein the Zn/M2 equivalent ratio is from about 0.6 to about 6. The articles prepared from the compositions with mixed ion ionomers exhibit high stiffness, hardness and toughness, good scratch resistance, desirable low melt viscosity and high processability.Type: GrantFiled: December 30, 2011Date of Patent: December 9, 2014Assignee: E I du Pont de Nemours and CompanyInventors: Richard T. Chou, Herbert Vernon Bendler, Karlheinz Hausmann
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Patent number: 8881784Abstract: The invention relates to a device for inserting inside tires of a vehicle so that it follows its course without stopping after a bursting. The device comprises a cluster of flexible bladders (1) which are made of rubber, have a diameter of one to several inches according to the use, are interconnected by a cord (2.1) with its distribution branches (2.2, 2.3) and an inflating stem (3). The air enters each bladder via the cord by means of a very sensitive mini-check valve (9). During inflation, the air contained inside the space of the tire is purged via a purging system (6, 7, 8). In one variant, the principle of the valves, cord and purge is retained, but there are fewer bladders and they have the shape of sections of the tire. Bladders that are resistant to depression can also be used with the same valves and purge but without a cord. The refilling ensues by an over inflation step followed by a reduction effected by the purge until the operating pressure is reached.Type: GrantFiled: April 19, 2006Date of Patent: November 11, 2014Inventor: Philippe Biesse
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Patent number: 8877306Abstract: This invention relates to a pipe for fluid transport that is comprised of a hollow cylinder having an outer wall and an aperture extending longitudinally through the cylinder, wherein the outer wall is comprised of (a) from about 60 weight percent to about 95 weight percent of a polyarylene sulfide resin, (b) from about 5 weight percent to about 40 weight percent of a thermoplastic vulcanizate, and (c) from about 3 weight percent to about 15 weight percent of a compatibilizer. The present invention also relates to an impact resistant polyarylene sulfide composition which is comprised of (a) from about 60 weight percent to about 95 weight percent of a polyarylene sulfide resin, (b) from about 5 weight percent to about 40 weight percent of a thermoplastic vulcanizate, and (c) from about 3 weight percent to about 15 weight percent of a compatibilizer.Type: GrantFiled: March 9, 2006Date of Patent: November 4, 2014Inventor: Manoj Ajbani
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Patent number: 8875761Abstract: In accordance with embodiments of the present disclosure an inner tube comprises an encasing configured to hold air. The encasing comprises a reinforcing structure configured such that, as the encasing is inflated, an overall major diameter of the inner tube is reduced. The inner tube also comprises an inflation valve coupled to the encasing and configured to allow inflation of the encasing. Further, the inner tube comprises a pressure valve coupled to the encasing. The pressure valve is configured to be biased closed and allow air to leave the encasing when a differential pressure between inside of the encasing and outside of the encasing reaches a threshold pressure level. In the same or alternative embodiments, the encasing also comprises a reinforcing structure configured such that, as the encasing is inflated, an overall major diameter of inner tube is reduced.Type: GrantFiled: January 13, 2012Date of Patent: November 4, 2014Assignee: Bear CorporationInventor: George Robert French
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Publication number: 20140322468Abstract: Provided are methods for surface-modifying a rubber vulcanizate or a thermoplastic elastomer, the methods forming a surface with a chemically fixed lubricant instead of resin coating which has drawbacks, such as that the coating is, for example, removed or peeled during the movement within a vessel, whereby the lubricity is reduced. The present invention relates to a method for surface-modifying an object of a rubber vulcanizate or a thermoplastic elastomer, the method including step 1 of forming polymerization initiation points on a surface of the object, and step 2 of radically polymerizing a deliquescent monomer starting from the polymerization initiation points by irradiation with ultraviolet light having a wavelength within the range of 300 to 400 nm, to grow polymer chains on the surface of the object.Type: ApplicationFiled: April 24, 2014Publication date: October 30, 2014Applicant: SUMITOMO RUBBER INDUSTRIES, LTD.Inventor: Yasuhisa MINAGAWA
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Patent number: 8865316Abstract: A rubber laminate comprises a reinforcing layer and a second rubber layer laminated sequentially on a first rubber layer, at least one outer surface of the first rubber layer and the second rubber layer being covered with an ultra high molecular weight polyethylene layer, wherein the rubber layers covered with the ultra high molecular weight polyethylene layer are formed from a rubber composition comprising from 20 to 40 parts by mass of a softener per 100 parts by mass of a mixed rubber consisting of from 60 to 80% by mass ratio of a diene rubber and 20 to 40% by mass ratio of a ethylene-propylene-diene rubber and/or a butyl rubber.Type: GrantFiled: December 28, 2009Date of Patent: October 21, 2014Assignee: The Yokohama Rubber Co., LtdInventors: Peng Gong, Kazuto Yamakawa, Naoto Torii, Akira Sato
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Patent number: 8865280Abstract: A fuel hose according to an aspect of the present disclosure includes: a tubular inner rubber layer; a resin layer formed on an outer circumferential surface of the inner rubber layer; and an outer rubber layer formed on an outer circumferential surface of the resin layer, wherein the inner rubber layer includes a rubber material containing the following Components (A), (B) and (C), the outer rubber layer includes a rubber material containing the following Components (A?), (B) and (C?), and the resin layer includes a resin material containing the following Component (X) as a main component: (A) acrylonitrile-butadiene rubber, (A?) blend rubber containing acrylonitrile-butadiene rubber and acrylic rubber, (B) a sulfur vulcanizing agent, (C) an amine catalyst to form bonding points, (C?) an amine catalyst to form bonding points, which contains 1,5-diazabicyclo(4.3.0)non-5-ene salt (DBN salt), and (X) tetrafluoroethylene-perfluoro(alkylvinylether)-chlorotrifluoroethylene copolymer.Type: GrantFiled: April 24, 2012Date of Patent: October 21, 2014Assignee: Tokai Rubber Industries, Ltd.Inventors: Daigo Tamura, Ayumu Ikemoto, Masashi Noda, Yoshiki Kodaka
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Publication number: 20140302265Abstract: Disclosed are a carboxylic acid-modified nitrile copolymer latex for dip molding comprising a combination of a carboxylic acid-modified nitrile copolymer latex and a carboxylic acid-modified styrene copolymer latex, a latex composition for dip molding comprising the same and a molded article prepared therefrom. Molded articles with superior tensile strength are produced by respectively preparing a carboxylic acid-modified nitrile latex having a low glass transition temperature and an average particle diameter of 90 nm or higher, and a carboxylic acid-modified styrene latex having a glass transition temperature of 80° C. or higher and an average particle diameter less than 90 nm and then mixing the two latexes.Type: ApplicationFiled: November 13, 2012Publication date: October 9, 2014Applicant: LG CHEM, LTD.Inventors: Seung Hun Yang, Jung Su Han, Seung Uk Yeu, Byoung Yun Kim, Jung Eun Kim
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Patent number: 8833416Abstract: An inner tube having a closed polymeric envelope with a primary surface comprising means allowing compression of the polymeric envelope when inflated under the normal conditions of use of the assembled unit. A radially outer part has a meridian curvature such that the ratio of the average radius of its meridian curvature to the radius of a circle of perimeter equal to the meridian perimeter of the primary surface of the polymeric envelope is greater than 2.5 and preferably greater than 10, when the inner tube is inflated to a pressure of 2000 pascals and the ratio of the average radius of the meridian curvature of the side parts to the radius of a circle of perimeter equal to the meridian perimeter of the primary surface of the polymeric envelope is greater than 2.5 and preferably greater than 10, when the inner tube is inflated to a pressure of 2000 pascals.Type: GrantFiled: June 5, 2009Date of Patent: September 16, 2014Assignees: Michelin Recherche et Techniques S.A., Compagnie Generale des Etablissements MichelinInventors: Luc Bestgen, Christian Bidet
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Patent number: 8808866Abstract: An elastomeric article, such as a glove or a condom, is coated with a compound containing silicone, collagen and allantoin.Type: GrantFiled: February 5, 2013Date of Patent: August 19, 2014Assignees: Precision Components, Inc., Xela CorporationInventors: Anil Segat, Andreas Brown