Glass, Ceramic Or Metal Oxide In Coating Patents (Class 428/384)
  • Patent number: 6555222
    Abstract: A reinforced polypropylene mirror assembly, and process for making the same, are described. The mirror assembly, especially the components thereof, includes a long glass fiber reinforced polypropylene material. Additionally, various additives may also be included in the reinforced polypropylene material, such as a UV stabilizer. Because of the physical properties of the reinforced polypropylene material, it is possible to combined several individual components of a conventional automobile side view mirror assembly into single, integral components, thus reducing part content, vehicle weight, and construction costs.
    Type: Grant
    Filed: January 13, 2000
    Date of Patent: April 29, 2003
    Assignee: Schefenacker Vision Systems France SA
    Inventors: Bernard Duroux, Gilles Benoit
  • Publication number: 20030068487
    Abstract: A crosslinkable thermal interface material is produced by combining at least one rubber compound, at least one amine resin and at least one thermally conductive filler. This interface material takes on the form of a liquid or “soft gel”. The gel state is brought about through a crosslinking reaction between the at least one rubber compound composition and the at least one amine resin composition. Once the foundation composition that comprises at least one rubber compound, at least one amine resin, and at least one thermally conductive filler has been prepared, the composition must be compared to the needs of the electronic component, vendor, or electronic product to determine if a phase change material and/or at least one solvent is needed to change some of the physical properties of the composition.
    Type: Application
    Filed: September 9, 2002
    Publication date: April 10, 2003
    Inventors: My Nguyen, Kim-Chi Le
  • Patent number: 6534196
    Abstract: The present invention relates to articles, having an extended useful life, which are used in contact with high temperature molten aluminum or molten zinc baths. One aspect of the invention encompasses articles, such as bearings, bushings, couplings or rollers, used in contact with molten aluminum or molten zinc which is coated with a high density coating consisting of a metal selected from Groups Vb, VIb, or VIIb metals (preferably molybdenum or tungsten), in pure or alloyed form. These coatings generally have a thickness of from about 0.06 to about 0.30 inch. Another aspect of the present invention encompasses a roll for guiding steel strip through a high temperature aluminizing bath, which utilizes a multi-layer structure, the first primer layer being a Group Vb, VIb or VIIb metal, preferably tungsten or molybdenum (in pure or alloyed form), the second layer comprising MCrAlY in which M is either nickel or cobalt, and the third layer comprising a refractory metal oxide of Al, Zr, Si or Cr.
    Type: Grant
    Filed: February 26, 2001
    Date of Patent: March 18, 2003
    Assignee: Cincinnati Thermal Spray
    Inventor: Robert K. Betts
  • Patent number: 6521344
    Abstract: A member for brakes that has a light weight, shock resistance characteristics, excellent corrosion resistance characteristics etc., high abrasive wear resistance characteristics and is made from fiber-composite material is comprised of an assemblage of yarns in which yarns, containing at least a bundle of carbon fibers and a carbon component other then carbon fiber are three-dimensionally combined and integrally formed so as to avoid separation there between; and matrices made of Si—SiC-based material filling the spaces between said yarns adjacent to each other within said assemblage of yarns.
    Type: Grant
    Filed: October 23, 1998
    Date of Patent: February 18, 2003
    Assignee: NGK Insulators Ltd.
    Inventor: Shigeru Hanzawa
  • Patent number: 6479144
    Abstract: Polyurethane elastomer yams (particularly spandex) containing certain silver-based antimicrobial formulations therein are provided. This invention relates to polyurethane elastomer yams (particularly spandex) containing certain silver-based antimicrobial formulations therein. Such formulations comprise antimicrobial compounds, such as, preferably, triclosan and/or silver-containing ion-exchange resins, such as zirconium phosphate, glass, and/or zeolite compounds. The inventive spandex yarns exhibit excellent antimicrobial qualities as well as surprisingly good anti-tack/frictional characteristics. As a result, antimicrobial spandex yams are provided which exhibit ease in processing, particularly in further knitting, weaving, etc., to produce fabrics therefrom. Such fabrics are also encompassed within this invention.
    Type: Grant
    Filed: December 4, 2000
    Date of Patent: November 12, 2002
    Assignee: Milliken & Company
    Inventors: Randy D. Petrea, Robert L. Schuette, Leland G. Close, Jr., Shirley Anne Whiteside
  • Publication number: 20020119304
    Abstract: The present invention relates to metal oxide particles capable of being highly dispersed in organic materials to form transparent colloids and ceramers. The metal oxide particles of the present invention have surfaces attached to a dispersing aid and a degree of crystallinity of greater than 55 percent. The crystallite diameter of the metal oxide particles is greater than about 4 nanometers and less than about 20 nanometers. The present invention also relates to the colloids and ceramers prepared using these metal oxide particles and the methods associated with the preparation of the particles, colloids, and ceramers.
    Type: Application
    Filed: November 19, 2001
    Publication date: August 29, 2002
    Applicant: 3M Innovative Properties Company
    Inventors: David S. Arney, Thomas E. Wood
  • Publication number: 20020084103
    Abstract: The present invention provides a silicon nitride ceramic substrate composed of a silicon nitride sintered body in which maximum size of pore existing in grain boundary phase of the sintered body is 0.3 &mgr;m or less, and having a thermal conductivity of 50 W/mK or more and a three point bending strength of 500 MPa or more, wherein a leak current is 1000 nA or less when an alternative voltage of 1.5 kV-100 Hz is applied to a portion between front and back surfaces of the silicon nitride sintered body under conditions of a temperature of 25° C. and a relative humidity of 70%. According to the above structure of the present invention, there can be provided a silicon nitride ceramic substrate capable of effectively suppressing a leak current generation when the above substrate is assembled into various power modules and circuit boards, and capable of greatly improving insulating property and operative reliability of power modules in which output power and capacity are greatly increased.
    Type: Application
    Filed: October 26, 2001
    Publication date: July 4, 2002
    Applicant: KABUSHIKI KAISHA TOSHIBA
    Inventors: Michiyasu Komatsu, Haruhiko Yamaguchi, Takayuki Naba, Hideki Yamaguchi
  • Patent number: 6406788
    Abstract: An elastic polyurethane fiber excellent in chlorine resistance, which contains particles of a metal compound selected from oxides and hydroxides of a metal selected from zinc and magnesium, and composite oxides of zinc and magnesium, a treating agent selected from a fatty acid, a styrene/maleic anhydride copolymer or its esterified products and a phosphoric ester adhering to the surface of the particles. The elastic polyurethane fiber is appropriate for an elastic fiber material for swimwear used in a swimming pool. The elastic polyurethane fiber can be produced by spinning a polyurethane spinning dope containing the metal compound particles to which such a specific treating agent as mentioned above adheres. The spinning dope suppresses secondary agglomeration of the metal compound particles and enables stabilized spinning of a modified polyurethane fiber.
    Type: Grant
    Filed: February 8, 2001
    Date of Patent: June 18, 2002
    Assignee: Asahi Kasei Kabushiki Kaisha
    Inventors: Masanori Doi, Akihiko Yoshizato
  • Publication number: 20020038680
    Abstract: Disclosed herein is a cooling roll which can provide bonded a magnet having excellent magnetic properties and having excellent reliability. A melt spinning apparatus is provided with a tube 2 having a nozzle 3 at the bottom thereof, a coil 4 for heating the tube and cooling roll 5 having a circumferential surface 53 in which dimple correcting means is provided. A melt spun ribbon 8 is formed by injecting the molten alloy 6 from the nozzle 3 so as to be collided with the circumferential surface 53 of the cooling roll 5 in an inert gas atmosphere (ambient gas) such as helium gas, so that the molten alloy 6 is cooled and then solidified. In this process, dimples to be produced on a roll contact surface of the melt spun ribbon are divided by the dimple correcting means, thereby preventing formation of huge dimples.
    Type: Application
    Filed: May 30, 2001
    Publication date: April 4, 2002
    Inventors: Akira Arai, Hiroshi Kato
  • Patent number: 6352771
    Abstract: A conductive roller for use in a laser printer includes a solid, thermoset urethane comprising a metal salt and having a hardness of between 30 Shore A and 50 Shore A on cube and a volume resistivity of 1E6 ohm-cm and 9E8 ohm-cm.
    Type: Grant
    Filed: February 24, 1999
    Date of Patent: March 5, 2002
    Assignee: Mearthane Products Corporation
    Inventors: Albert C. Chiang, John A. Roderick
  • Patent number: 6322889
    Abstract: A ceramic-matrix composite having a multilayered interfacial coating adapted to protect the reinforcing fibers from long-term oxidation, while allowing these to bridge the wake of advancing cracks in the matrix, is provided by selectively mismatching materials within adjacent layers of the interfacial coating, the materials having different coefficients of thermal expansion so that a low toughness interface region is created to promote crack deflection either within an interior layer of the mismatched interfacial coating or between adjacent layers of the mismatched interfacial coating.
    Type: Grant
    Filed: April 22, 1999
    Date of Patent: November 27, 2001
    Assignee: The United States of America as represented by the United States Department of Energy
    Inventors: Edgar Lara-Curzio, Karren L. More, Woo Y. Lee
  • Publication number: 20010031596
    Abstract: A method of manufacturing a bearing material, a bearing material and a bearing having the bearing material on a strong backing are described.
    Type: Application
    Filed: April 16, 2001
    Publication date: October 18, 2001
    Inventors: Julie Ann McDonald, John Edward Wheatley, Anthony Latkowski, David Geoffrey Hall
  • Patent number: 6291067
    Abstract: A photocatalytic powder for environmental clarification, comprising finely divided titanium dioxide particles having a coating of porous calcium phosphate formed on at least part of the surface of each titanium dioxide particle, wherein an anionic surface active agent is present at least on the interface between said coating of porous calcium phosphate and the titanium dioxide particle. This photocatalytic powder is produced by dispersing finely divided titanium dioxide particles in an aqueous slurry containing an anionic surface active agent, and then forming a coating of porous calcium phosphate on at least part of the surface of each titanium dioxide particle. This photocatalytic powder is used, for example, by supporting it in an organic polymer shaped article.
    Type: Grant
    Filed: July 14, 2000
    Date of Patent: September 18, 2001
    Assignees: Japan as represented by Director General of the Agency of Industrial Science and Technology, Showa Denko Kabushiki Kaisha
    Inventors: Hiroshi Taoda, Toru Nonami, Katsura Ito, Hiroyuki Hagihara
  • Patent number: 6113861
    Abstract: A photocatalytic sheet which has a base made of polymeric organic compound, that is not decomposed by a photocatalytic function, and also hardly loses the photocatalytic function after washing and is capable of providing the photocatalytic function even in an environment without sufficient ultraviolet radiation from outside. Using a fiber, a filament, a yarn made of fibers or filaments, a ribbon, a knitted fabric, a woven fabric, a nonwoven fabric, or a film as the base, a base protective layer is formed on a part of the base, which is made of the polymeric organic compound, and a photocatalytic semiconductor layer is formed on the entire surface of the base including the base protective layer.
    Type: Grant
    Filed: February 27, 1998
    Date of Patent: September 5, 2000
    Assignee: TAO, Inc.
    Inventor: Shiro Ogata
  • Patent number: 6074750
    Abstract: A composite comprised of reinforcement fibers having a continuous coating of a metal nitride wherein the metal is from the group consisting of silicon, aluminum, titanium, zirconium, hafnium, niobium, tantalum, and mixtures thereof, and a molten silicon infiltration formed silicon carbide matrix. The reinforcement fibers are fibers from the group consisting of elemental carbon, silicon carbide, and mixtures thereof. A method of forming the composite comprises depositing a continuous coating of the metal nitride on the fibers. A carbonaceous material is admixed with the coated fibers so that at least 5 volume percent of the mixture is the coated fibers. The mixture is formed into a preform having an open porosity ranging from about 25 volume percent to about 90 volume percent of the preform. The preform is heated in an inert atmosphere or partial vacuum, and infiltrated with molten silicon to produce an infiltrated product having the composition of the composite.
    Type: Grant
    Filed: March 14, 1995
    Date of Patent: June 13, 2000
    Assignee: General Electric Company
    Inventors: Milivoj Konstantin Brun, Krishan Lal Luthra, Raj Narain Singh
  • Patent number: 6060162
    Abstract: A pulsed voltage surge resistant magnet wire comprising a conductor, a continuous and concentric and flexible uniform coat of base insulation material superimposed on the conductor. An essentially continuous and concentric and uniform pulsed voltage surge shield overlaying the coat of base insulation material. The shield has therein an effective amount of a particulate material. The shield is superimposed on the coat of base insulation material, and has a continuous and concentric and flexible and uniform top coat of insulation material superimposed thereon.
    Type: Grant
    Filed: June 8, 1995
    Date of Patent: May 9, 2000
    Assignee: Phelps Dodge Industries, Inc.
    Inventors: Weijun Yin, Donald J. Barta
  • Patent number: 6053970
    Abstract: Two component, storage stable apatitic cement compositions, as well as methods for their production, are provided. The dry component of subject apatitic cements comprises basic calcium source particles at least partially coated with a partially neutralized acidic calcium phosphate. The dry component of subject compositions is prepared by combining basic calcium source particles with dissolved acidic phosphate in at least a partially aqueous medium, whereby the basic calcium source particles become partially coated with a partially neutralized acidic calcium phosphate. The reaction is terminated prior to completion of the reaction between the acidic phosphate and the basic calcium source by removing the available water from the reaction mixture. In a first mode, the subject cement may be produced by mechanically mixing an acidic phosphate source with basic calcium source particles in the presence of an aqueous solvent and stopping the reaction between the acid and base prior to completion.
    Type: Grant
    Filed: June 30, 1999
    Date of Patent: April 25, 2000
    Assignee: Norian Corporation
    Inventors: Ira C. Ison, Mark T. Fulmer, Bryan M. Barr, Brent R. Constantz
  • Patent number: 6004675
    Abstract: A coated glass fiber for light transmission consisting of a glass fiber for light transmission and at least one coating layer made of a UV-curing resin, wherein an outermost layer of the coating layer is made of a UV-curing resin having a Young's modulus of at least 100 kg/mm.sup.2 and a change of a cure shrinkage degree of 1% or less after a Young's modulus reaches one tenth of an end Young's modulus, which has good lateral pressure characteristics and low transmission loss.
    Type: Grant
    Filed: September 1, 1992
    Date of Patent: December 21, 1999
    Assignees: Sumitomo Electric Industries, Ltd., Nippon Telegraph & Telephone Corp.
    Inventors: Nobuhiro Akasaka, Tatsuya Kakuta, Kohei Kobayashi, Yasuo Matsuda, Shigeru Tomita
  • Patent number: 5965245
    Abstract: A prepreg comprising a semi-cured thermosetting resin and electrically insulating whiskers or short fibers dispersed in said semi-cured thermosetting resin, and if necessary, a carrier film attached or bound to said prepreg is suitable for producing multilayer printed circuit boards of reduced thinness, high wiring density and high connection reliability with high productivity and low production cost.
    Type: Grant
    Filed: September 13, 1996
    Date of Patent: October 12, 1999
    Assignee: Hitachi Chemical Company, Ltd.
    Inventors: Norio Okano, Kazuhito Kobayashi, Akishi Nakaso
  • Patent number: 5958583
    Abstract: A coated ceramic has alumina as an amorphous residue from an alumina sol containing alumina powder or and, optionally, a high emittance powder. The alumina powder alters the rheology and wetting characteristics of the sol to aid in forming the residue and increases the alumina concentration (% solids) in the residue. The high emittance powder radiates heat out of the residue and away from the ceramic when the coated ceramic is heated, such as during orbital reentry.
    Type: Grant
    Filed: December 20, 1996
    Date of Patent: September 28, 1999
    Assignee: The Boeing Company
    Inventors: Michael E. Rorabaugh, Charles W. Newquist, Juris Verzemnieks
  • Patent number: 5955391
    Abstract: In fiber composite ceramic containing reaction sintered SiC as a matrix and having BN-coated SiC continuous fibers as composite fibers, the thickness of the BN coating need not be especially made large, and a sliding effect during growing of cracks can be improved, i.e., breakdown energy can be increased. A method of manufacturing fiber composite ceramic in which large number of BN-coated SiC fibers covered with a BN coating are gathered to form yarns, or yarns are woven to form a two-dimensional or three-dimensional fabric, and a preform is formed by the yarns or the fabric, C powder is arranged in a gap portion between fibers of the preform to form a compact, a molten Si is impregnated into the compact to form an SiC matrix between fibers. A region having a high B concentration is formed around the SiC fibers before the preform is impregnated with the molten Si, and B in the region is solid-solved in Si during reaction sintering to suppress B in the BN-coated SiC fibers from being solid-solved in Si.
    Type: Grant
    Filed: March 28, 1997
    Date of Patent: September 21, 1999
    Assignee: Kabushiki Kaisha Toshiba
    Inventors: Tsuneji Kameda, Shoko Suyama, Akio Sayano, Masahiro Asayama, Yoshinori Hayakawa
  • Patent number: 5955194
    Abstract: An improved fiber reinforced glass composite includes a boron-containing refractory fiber having its surface enriched with boron nitride in a matrix of a black glass ceramic having the empirical formula SiCxOy where x ranges from about 0.5 to about 2.0, preferably 0.9 to 1.6 and y ranges from about 0.5 to 3.0, preferably 0.7 to 1.8. Preferably the black glass ceramic is derived from cyclosiloxane or non-cyclic siloxane monomers containing a vinyl group attached to silicon and/or a hydride-silicon group. The boron nitride-containing fiber is the product of treating the boron-containing fiber with ammonia at a temperature between about 1100.degree. C. and 1250.degree. C. Fibrous failure rather than brittle failure under stress can be obtained.
    Type: Grant
    Filed: June 12, 1995
    Date of Patent: September 21, 1999
    Assignee: AlliedSignal, Inc.
    Inventor: Scott Sager Campbell
  • Patent number: 5952100
    Abstract: A fiber-reinforced silicon--silicon carbide matrix composite having improved oxidation resistance at high temperatures in dry or water-containing environments is produced. The invention also provides a method for protecting the reinforcing fibers in the silicon--silicon carbide matrix composites by coating the fibers with a silicon-doped boron nitride coating.
    Type: Grant
    Filed: May 21, 1997
    Date of Patent: September 14, 1999
    Assignee: General Electric Company
    Inventors: Gregory Scot Corman, Krishan Lal Luthra
  • Patent number: 5932345
    Abstract: A novel heat-fusible copolymer possessing a combination of excellent properties, including mechanical strength, resistivity against radioactive rays, chemical resistance, low temperature stability, thermal resistance, processabilty, adhesiveness, thermal fusible adhesive stability, and simultaneously satisfying requirements relating to low hygroscopic characteristic and stable dielectric constant. Also, a powder, film, laminated film, laminated insulating material, and article, such as electronic modules and capacitors, made from a thermoplastic polyimide resin composed mainly of the copolymer and suitable for use as electronic components and materials for electronic circuit components. The copolymer possesses a glass transition temperature of 100.degree. C. to 250.degree. C., a hygroscopic degree of 1 or less, and a dielectric rate of 3 or less, and has the following formula: ##STR1## wherein Ar.sub.1 represents a quadrivalent organic radical, Ar.sub.
    Type: Grant
    Filed: September 10, 1996
    Date of Patent: August 3, 1999
    Assignee: Kanegafuchi Kagaku Kogyo Kabushiki Kaisha
    Inventors: Hiroyuki Furutani, Naoki Hase, Junya Ida, Yoshifumi Okamoto, Hitoshi Nojiri, Shinji Inoue, Hirosaku Nagano
  • Patent number: 5916932
    Abstract: A composite building material is disclosed produced from recycled materials. The composite building material is composed of an extruded mixture of high density polyethylene and a thermoplastic coated fiber material such as fiberglass. The resulting material has increased strength and is useful in high stress applications such as railroad ties.
    Type: Grant
    Filed: May 16, 1997
    Date of Patent: June 29, 1999
    Assignee: Rutgers, The State University
    Inventors: Thomas Jerome Nosker, Richard William Renfree
  • Patent number: 5908812
    Abstract: A superconducting oxide composite structure including a superconducting oxide member, a metal layer surrounding the superconducting oxide member, and an insulating layer of a complex oxide formed in situ adjacent to the superconducting oxide member and the metal layer is provided together with a method of forming such a superconducting oxide composite structure including encapsulating a superconducting oxide member or precursor within a metal matrix layer from the group of: (i) a reactive metal sheath adjacent to the superconducting oxide member or precursor, the reactive metal sheath surrounded by a second metal layer or (ii) an alloy containing a reactive metal; to form an intermediate product, and, heating the intermediate product at temperatures and for time sufficient to form an insulating layer of a complex oxide in situ, the insulating layer to the superconducting oxide member or precursor and the metal matrix layer.
    Type: Grant
    Filed: February 5, 1996
    Date of Patent: June 1, 1999
    Assignee: The Regents of the University of California
    Inventors: James D. Cotton, Gilbert Neal Riley, Jr.
  • Patent number: 5891362
    Abstract: A sol having dispersed in a liquid medium particles of a hydrated zinc stannate having a primary particle diameter of from 2 to 200 nm and represented by the formula xZnO.ySnO.sub.2.zH.sub.2 O wherein the molar ratio of x:y:z is 1:0.83 to 1.43:1.00 to 5.00.
    Type: Grant
    Filed: June 6, 1996
    Date of Patent: April 6, 1999
    Assignee: Nissan Chemical Industries, Ltd.
    Inventors: Yoshitane Watanabe, Keitaro Suzuki, Yoshinari Koyama, Motoko Iijima
  • Patent number: 5851668
    Abstract: A fiber having increased cut resistance is made from a fiber-forming polymer and a hard filler having a Mohs Hardness Value greater than about 3. The filler is included in an amount of about 0.05% to about 20% by weight. In preferred embodiments, the fiber-forming polymer is poly(ethylene terephthalate) or a liquid crystalline polyester comprising monomer units derived from 6-hydroxy-2-naphthoic acid and 4-hydroxybenzoic acid. Preferred fillers include tungsten and alumina.
    Type: Grant
    Filed: November 19, 1996
    Date of Patent: December 22, 1998
    Assignee: Hoechst Celanese Corp
    Inventors: Robert Bruce Sandor, Michele C. Carter, Gunilla E. Gillberg-LaForce, William F. Clear, John A. Flint, Herman Leslie Lanieve, Scott W. Thompson, Etheridge Odell Oakley, Jr., Edward Ronald Kafchinski, Mohammed Ishaq Haider
  • Patent number: 5843591
    Abstract: A method of treating a metal alkoxide solution to form metal oxide prepolymer molecules therein is characterized by irradiating the solution with light energy having a wavelength selected to break the metal-alkoxy group bond in said metal alkoxide, thereby to form the metal oxide prepolymer molecules in the solution. The prepolymer is converted into polymeric metal oxide gel. The stoichiometry of the oxide is high. A gel of carbon content below 4 atomic % can be achieved by the step of decarbonizing the gel, preferably using light to produce ozone.
    Type: Grant
    Filed: May 26, 1995
    Date of Patent: December 1, 1998
    Assignee: Hitachi, Ltd.
    Inventors: Tomoji Oishi, Ken Takahashi, Teteuo Nakazawa, Shigeru Tanaka, Tadahiko Miyoshi
  • Patent number: 5840433
    Abstract: A refractory article of manufacture comprises an article of graphite-alumina refractory material coated with at least one mineral having a sheet structure and a refractory oxide bond. The coating protects the article against thermal shock. A typical mineral having a sheet structure may be talc, a mica, vermiculite, antigorite, kaolinite, montmorillonite, pyrophyllite, or combinations of these materials. A typical refractory oxide bond is formed from alumina gel, silica sol, alumina sol, zirconia sol, or combinations of these materials (such as a combination of alumina gel and cationic silica sol). The coating may also contain a minor proportion of fibrous material and a minor proportion of particulate refractory filler other than the mineral having a sheet structure, and a portion of the mineral content of the mineral forming the sheet structure may include graphite.
    Type: Grant
    Filed: March 13, 1996
    Date of Patent: November 24, 1998
    Assignee: Foseco International Limited
    Inventor: Kassum Juma
  • Patent number: 5834117
    Abstract: A heat-resistant combination including a substrate, a first layer, and a second layer. The first layer includes a benzisidazole-based polymer with a first face in contact with the substrate; and the second layer contains a ceramic material and is securely fixed to a second face of said first layer.
    Type: Grant
    Filed: November 12, 1996
    Date of Patent: November 10, 1998
    Assignee: Sumitomo Wiring Systems, Ltd.
    Inventor: Yasuhiko Onishi
  • Patent number: 5814403
    Abstract: A computer model calculates a critical aspect ratio for a discontinuous fiber composite having fibers dispersed in a matrix. The critical aspect ratio is a function of the elastic modulus and the cohesive energy of the fiber and the matrix. The composite incorporates physical features such as fiber shape features or additives in the fiber or matrix which adjust the elastic modulus and/or cohesive energy of the fiber, of the matrix or both to a value different than the corresponding value for unmodified fiber material or matrix material. These adjustments are selected so that the critical aspect ratio for the material including the modifications will be less than the corresponding critical aspect ratio for the material without the modifications. The resulting composite provides enhanced load sharing between fiber and matrix.
    Type: Grant
    Filed: January 28, 1993
    Date of Patent: September 29, 1998
    Assignee: Exxon Research and Engineering Company
    Inventors: Michael P. Anderson, Liza M. Monette, John P. Dismukes, Shiun Ling, David J. Srolovitz
  • Patent number: 5789477
    Abstract: A composite building material is disclosed produced from recycled materials. The composite building material is composed of an extruded mixture of high density polyethylene and a thermoplastic coated fiber material such as fiberglass. The resulting material has increased strength and is useful in high stress applications such as railroad ties.
    Type: Grant
    Filed: August 30, 1996
    Date of Patent: August 4, 1998
    Assignee: Rutgers, The State University
    Inventors: Thomas Jerome Nosker, Richard William Renfree
  • Patent number: 5733655
    Abstract: A thermostructural composite article and a method for making in which the article comprises silicon carbide reinforcing fibers having an oxygen content by weight of not more than about 14% and an average diameter of less than about 20 microns in a refractory matrix at least partially formed by chemical vapor infiltration. The fibers in the composite article of the invention have an end-to-end fiber diameter uniformity ratio of less than about 1.5.
    Type: Grant
    Filed: August 25, 1995
    Date of Patent: March 31, 1998
    Assignee: Du Pont Lanxide Composites, L.P.
    Inventors: Susan Lydia Bors, Albert Zaki Fresco, Mark Henry Headinger
  • Patent number: 5719234
    Abstract: An object of the present invention is to provide a heat-curable high solid coating composition capable of forming a coating film which is excellent in both acid resistance and scratch resistance, and a method for forming a topcoat using said composition.The present invention provides a heat-curable high solid coating composition comprising:(A) a carboxyl-containing compound,(B) a vinyl polymer having an epoxy group, a hydroxyl group and a hydrolyzable alkoxysilyl group in one molecule,(C) a reactive organopolysiloxane, and(D) a crosslinked particulate polymer. The present invention also provides a method for forming a topcoat using said composition.
    Type: Grant
    Filed: November 12, 1996
    Date of Patent: February 17, 1998
    Assignee: Kansai Paint Company, Limited
    Inventors: Motoshi Yabuta, Masaaki Saika, Satoru Ito, Hiroyuki Okada, Yasumasa Okumura, Hiroshi Igarashi, Satoshi Ikushima
  • Patent number: 5714236
    Abstract: A method of decorating a firable article which includes the step of mixing a metallic salt with a fuel material which can supply oxygen to the salt in a reaction. This mixture causes complex formation of the salt, characterized by raising the pH of the mixture to at least 5. Additives in the mixture promote stability and provide the required viscosity surface tension and conductivity for use in an ink jet printer. When applying a solution of this mixture onto a firable article by ink jet printing, the mixture is such that upon drying, the mixture reacts to form an oxide of the metal to provide a decorative color pigment on the article.
    Type: Grant
    Filed: December 5, 1996
    Date of Patent: February 3, 1998
    Assignee: British Ceramic Research Limited
    Inventors: Steven Charles Withington, Sally-Anne Alsop, Philip Robert Jackson
  • Patent number: 5679149
    Abstract: The present invention provides a short carbon fiber reinforced hydraulic composite material making the best use of physical properties of short carbon fibers incorporated as reinforcing material. Microparticles are deposited on the short carbon fibers in an amount of 0.5 to 3 wt. %. These microparticles also have a particle diameter of 5 microns or less.
    Type: Grant
    Filed: November 19, 1996
    Date of Patent: October 21, 1997
    Assignee: Mitsubishi Chemical Corporation
    Inventors: Mitsuharu Tezuka, Mitsuru Awata, Akira Shiraki
  • Patent number: 5654095
    Abstract: A pulsed voltage surge resistant magnet wire comprising a conductor, a continuous and concentric and flexible uniform coat of base insulation material superimposed on the conductor and an essentially continuous and concentric and uniform pulsed voltage surge shield overlaying the coat of base insulation material.
    Type: Grant
    Filed: June 8, 1995
    Date of Patent: August 5, 1997
    Assignee: Phelps Dodge Industries, Inc.
    Inventors: Weijun Yin, Donald J. Barta
  • Patent number: 5639549
    Abstract: Disclosed is a fixing roll, comprising a core metal, a heat resistant elastic layer formed to cover the circumferential outer surface of the core metal, and a surface layer formed to cover the circumferential outer surface of the heat resistant elastic layer, the surface layer being formed of a tetrafluoroethylene-perfluoroalkyl vinyl ether copolymer resin film of a double layer structure consisting of an inner layer having a volume resistivity of 10.sup.11 .OMEGA..cm or less and an outer layer having a thickness falling within a range of between 3 .mu.m and 50 .mu.m, and the entire thickness of the resin film falling within a range of between 20 .mu.m and 500 .mu.m.
    Type: Grant
    Filed: May 8, 1992
    Date of Patent: June 17, 1997
    Assignee: Kinyosha Co., Ltd.
    Inventors: Noritomo Fukunaga, Michiyoshi Kurosawa
  • Patent number: 5631084
    Abstract: The invention relates to a refractory thermally-insulating component consisting essentially of refractory ceramic fibers which are mechanically combined with one another, the composition of which comprises at least 97.5% by weight of alumina, silica and zirconia in total, wherein:a) no organic or inorganic binder binds the fibers to one another;b) the fibers have the following chemical composition, as % by weight:Al.sub.2 O.sub.3 : 33-45%SiO.sub.2 : 41-53%ZrO.sub.2 : 5.5-17%MgO: 0.02-2%other oxides:<0.50% with Fe.sub.2 O.sub.3 +TiO.sub.2 .ltoreq.0.20% and Na.sub.2 O+CaO+K.sub.2 O.ltoreq.0.30%;c) the said fibers homogeneously have, throughout the entire body of the component, a degree of crystallinity of not less than 30% and not more than 64%, the crystals present being essentially formed of mullite crystals and of quadratic zirconia; andd) the said component has a linear shrinkage of no more than 3% after being held for 24 hours at 1450.degree. C.
    Type: Grant
    Filed: December 21, 1994
    Date of Patent: May 20, 1997
    Assignee: Societe Europeenne des Produits Refractaires
    Inventors: Daniel Urffer, Joseph Recasens
  • Patent number: 5605868
    Abstract: This invention is directed to the fabrication of SiC fiber reinforced, ceramic matrix composite articles exhibiting superior high temperature oxidative stability, those articles comprising:(a) a glass-ceramic matrix wherein alkali metal and/or alkaline earth metal aluminosilicate crystals constitute the predominant crystal phase;(b) a fiber reinforcing phase comprising SiC fibers coated with an alkali metal and/or alkaline earth metal sheet silicate entrained within said glass-ceramic matrix; and(c) a borosilicate glass phase dispersed as an intergranular glass within said glass-ceramic matrix, said borosilicate glass phase generally being present in an amount sufficient to provide an intergranular glass phase therein.
    Type: Grant
    Filed: December 29, 1994
    Date of Patent: February 25, 1997
    Assignee: Corning Incorporated
    Inventors: Kenneth Chyung, Steven B. Dawes, David C. Larsen, Ronald L. Stewart
  • Patent number: 5599624
    Abstract: Fibers having reduced surface roughness have a continuous coating of a silicone resin that undergoes pyrolysis in hydrogen or helium to form a hard, amorphous solid coat containing silicon, oxygen, and carbon. This silicon oxycarbide glass coating has exceptional high temperature strength and chemical stability compared to even vitreous silica. The coating is resistant to crystallization and oxidation at temperatures above 1000.degree. C.
    Type: Grant
    Filed: July 3, 1995
    Date of Patent: February 4, 1997
    Assignee: General Electric Company
    Inventor: Svante Prochazka
  • Patent number: 5585165
    Abstract: The present invention generally relates to mechanisms for preventing undesirable oxidation (i.e., oxidation protection mechanisms) of reinforcement materials in composite bodies. The oxidation protection mechanisms include getterer materials which are added to the composite body which gather or scavenge undesirable oxidants which may enter the composite body. The getterer materials may be placed into at least a portion of the composite body such that any undesirable oxidant approaching, for example, a fiber reinforcement, would be scavenged by (e.g., reacted with) the getterer. In a preferred embodiment of the present invention, the getterer material(s) form at least one compound (e.g., at least one glassy material) which acts as a crack sealant, thereby further enhancing the oxidation protection of the composite body. One or more ceramic filler materials which serve as reinforcements may have a plurality of superimposed coatings thereon, at least one of which coatings may function as a getterer.
    Type: Grant
    Filed: September 30, 1994
    Date of Patent: December 17, 1996
    Assignee: Lanxide Technology Company, LP
    Inventors: Christopher R. Kennedy, Birol Sonuparlak, Ali S. Fareed, John E. Garnier, Gerhard H. Schiroky
  • Patent number: 5580643
    Abstract: The present invention generally relates to mechanisms for preventing undesirable oxidation (i.e., oxidation protection mechanisms) of reinforcement materials in composite bodies. In a preferred embodiment of the invention, a coated ceramic filler material adaptable for use as a reinforcing component in a ceramic matrix composite is provided with a plurality of superimposed coatings. The coating system includes a first coating in substantially continuous contact with the ceramic filler material and one or more additional or outer coatings superimposed over the underlying coating and in substantially continuous contact therewith. Zonal junctions are formed between the filler and the first coating, between superimposed coatings, and between the outer coating and the ceramic matrix. The coatings are selected so that the interfacial shear strength of at least one of these several zones is weak relative to the other zones.
    Type: Grant
    Filed: June 7, 1995
    Date of Patent: December 3, 1996
    Assignee: Lanxide Technology Company, LP
    Inventors: Christopher R. Kennedy, Birol Sonuparlak, Ali S. Fareed, John E. Garnier, Gerhard H. Schiroky
  • Patent number: 5571621
    Abstract: An infrared radiation-interactive article comprising a supported or unsupported oxidizable metal film of an infrared radiation-interactive size and shape, with an oxidation-promoting salt in contact with the metal film, arranged so that in exposure to ambient moisture, the metal film is oxidizable to an infrared radiation non-interactive form. The article of the invention may be employed to carry out a method of generating a transient infrared radiation response, e.g., an infrared radiation reflectance signature, or infrared radiation absorption, at a selected locus receiving infrared radiation incident thereon, by disposing at the locus an infrared radiation interactively-effective amount of such infrared radiation-interactive article.
    Type: Grant
    Filed: June 7, 1995
    Date of Patent: November 5, 1996
    Assignee: Advanced Technology Materials, Inc.
    Inventors: Ward C. Stevens, Edward A. Sturm
  • Patent number: 5567518
    Abstract: A ceramic composite material comprising matrix material, reinforcing fibers and an intermediate interface material. The matrix material and reinforcing fibers consist of the same or different ceramic oxides having a melting point above 1600.degree. C. The interface material is applied as a coating on the fibers and consists of at least one ceramic oxide not exhibiting solid solubility, eutecticum below the temperature of manufacture or use or reactivity with any of the matrix or reinforcing materials. The matrix and reinforcing materials are substantially pure, and the combination fiber/interface material/matrix material is selected from the group consisting of: Al.sub.2 O.sub.3 /Al.sub.2 TiO.sub.5 /Al.sub.2 O.sub.3, YAG/Al.sub.2 TiO.sub.5 /Al.sub.2 O.sub.3, Al.sub.2 O.sub.3 /YAG/Al.sub.2 O.sub.3, Al.sub.2 O.sub.3 /SnO.sub.2 /Al.sub.2 O.sub.3, YAG/SnO.sub.2 /Al.sub.2 O.sub.3, Al.sub.2 O.sub.3 /mullite/Al.sub.2 O.sub.3, and mullite/ZrO.sub.2 /mullite.
    Type: Grant
    Filed: April 13, 1995
    Date of Patent: October 22, 1996
    Assignees: Volvo Aero Corporation, Rolls Royce PLC
    Inventors: Lars Pejryd, Robert Lundberg, Edwin Butler
  • Patent number: 5552352
    Abstract: A composite is comprised of reinforcement fibers having a continuous coating with a first layer of a metal oxide wherein the metal is from the group consisting of aluminum, yttrium, titanium, zirconium, beryllium, silicon, and the rare earths, and a molten silicon infiltration formed silicon carbide matrix. The coating may have a second layer from the group consisting of rhodium, iridium, metal carbide, metal silicide, metal nitride, and metal diboride, on the metal oxide coating. The reinforcement fibers being fibers from the group consisting of elemental carbon, silicon carbide, and mixtures thereof. A process for producing the fiber reinforced composite comprises depositing on the fibers a continuous coating comprised of the first layer of the metal oxide, and the second layer. A carbonaceous material is admixed with the coated fibers so that at least 5 volume percent of the mixture is the fibers.
    Type: Grant
    Filed: September 8, 1995
    Date of Patent: September 3, 1996
    Assignee: General Electric Company
    Inventors: Milivoj K. Brun, Krishan L. Luthra, Raj N. Singh
  • Patent number: 5508235
    Abstract: A Cu-doped/Fe-doped low expansion glass ceramic composition comprising:______________________________________ Wt. % ______________________________________ SiO.sub.2 50-65 Al.sub.2 O.sub.3 18-27 P.sub.2 O.sub.5 0-10 Li.sub.2 O 2-6 Na.sub.2 O 0-2 K.sub.2 O 0-2 B.sub.2 O.sub.3 0-1 MgO 0-4 ZnO 0-5 CaO 0-4 BaO 0-5 TiO.sub.2 1-3 ZrO.sub.2 1-3 As.sub.2 O.sub.3 0-1.5 Sb.sub.2 O.sub.3 0-1.5 CuO 0-3 Fe.sub.2 O.sub.3 0-1 ______________________________________wherein the total amount of SiO.sub.2, Al.sub.2 O.sub.3 and P.sub.2 O.sub.5 is 80-89 wt. %, and said glass ceramic contains as a dopant 0.1-3 wt. % CuO, 0.1-1 wt. % Fe.sub.2 O.sub.3 or a combined CuO+Fe.sub.2 O.sub.3 amount of 0.1-4 wt. %. The glass ceramic composition is suitable for use as a cladding material for solid laser energy storage mediums as well as for use in beam attenuators for measuring laser energy level and beam blocks or beam dumps used for absorbing excess or unused laser energy.
    Type: Grant
    Filed: July 6, 1994
    Date of Patent: April 16, 1996
    Assignee: Schott Glass Technologies, Inc.
    Inventor: Alexander J. Marker
  • Patent number: 5501907
    Abstract: A fibrous electrically-conductive filler herein provided comprises fibrous aluminum borate as a core material provided thereon with, in order, an optional titanium oxide intermediate layer and an antimony-free tin oxide layer. The fibrous electrically-conductive filler can be prepared by a method which comprises the steps of optionally forming an intermediate layer of titanium oxide by depositing titanium oxide hydrate on the surface of the core material and then calcining the titanium oxide hydrate layer; then forming a coating layer of tin oxide hydrate on the surface of the titanium oxide-coated fibrous aluminum borate or the fibrous aluminum borate as a core material and then calcining the coating layer at a temperature ranging from 150.degree. to 600.degree. C. in an inert gas atmosphere or a reducing atmosphere to form an antimony-free tin oxide layer.
    Type: Grant
    Filed: September 29, 1993
    Date of Patent: March 26, 1996
    Assignee: Mitsui Mining & Smelting Co., Ltd.
    Inventors: Takao Hayashi, Nobuyoshi Kasahara, Norihiro Sato, Kouichi Kawaratani
  • Patent number: 5498296
    Abstract: A metal oxide layer is provided around a thermocouple element. The metal oxide layer is formed by preparing a sol, in which particulates of a metal oxide are dispersed, by a sol-gel method, dipping the thermocouple element in this sol, energizing the thermocouple element as a cathode for bonding the precursor particulates of the metal oxide thereto, and heat treating the same. The thermocouple according to the present invention is compact with a thin insulating layer, excellent in flexibility, and provides no gas adsorption source.
    Type: Grant
    Filed: October 7, 1991
    Date of Patent: March 12, 1996
    Assignee: Sumitomo Electric Industries, Ltd.
    Inventors: Kazuo Sawada, Shinji Inazawa, Kouichi Yamada