Surface Modified Glass (e.g., Tempered, Strengthened, Etc.) Patents (Class 428/410)
  • Publication number: 20150140336
    Abstract: A white glass contains, in terms of mole percentage on the basis of the following oxides, from 50 to 80% of SiO2, from 0 to 10% of Al2O3, from 11 to 30% of MgO, from 0 to 15% of Na2O and from 0.5 to 15% of P2O5.
    Type: Application
    Filed: January 23, 2015
    Publication date: May 21, 2015
    Applicant: ASAHI GLASS COMPANY, LIMITED
    Inventors: Takahiro SAKAGAMI, Seiki OHARA, Junko MIYASAKA, Hiroyuki HIJIYA, Kazutaka ONO
  • Publication number: 20150140325
    Abstract: Embodiments of glass composition including at least about 65 mol % SiO2, Al2O3 in the range from about 7 mol % to about 11 mol %, Na2O in the range from about 13 mol % to about 16 mol %; and a non-zero amount of one or more alkali earth metal oxides selected from MgO, CaO and ZnO, wherein the sum of the alkali earth metal oxides is up to about 6 mol %, are disclosed. The glass compositions can be processed using fusion forming processes and float forming processes and are ion exchangeable. Glass articles including such glass compositions and methods of forming such glass articles are also disclosed. The glass articles of one or more embodiments exhibit a Vickers indentation crack initiation load of at least 8 kgf.
    Type: Application
    Filed: November 14, 2014
    Publication date: May 21, 2015
    Inventors: Timothy Michael Gross, Xiaoju Guo, Charlene Marie Smith
  • Patent number: 9034469
    Abstract: A tempered glass substrate has a compression stress layer on a surface thereof, and has a glass composition comprising, in terms of mass %, 40 to 70% of SiO2, 12 to 21% of Al2O3, 0 to 3.5% of Li2O, 10 to 20% of Na2O, 0 to 15% of K2O, and 0 to 4.5% of TiO2, wherein the tempered glass substrate has a plate thickness of 1.5 mm or less, and an internal tensile stress in the tempered glass substrate is 15 to 150 MPa.
    Type: Grant
    Filed: February 8, 2012
    Date of Patent: May 19, 2015
    Assignee: NIPPON ELECTRIC GLASS CO., LTD.
    Inventor: Takashi Murata
  • Patent number: 9034442
    Abstract: According to one embodiment, a glass container may include a body formed from a Type I, Class B glass composition according to ASTM Standard E438-92. The body may have an inner surface, an outer surface and a wall thickness extending between the outer surface and the inner surface. The body may also include a compressively stressed layer extending into the wall thickness from at least one of the outer surface and the inner surface. A lubricous coating may be positioned on at least a portion of the outer surface of the body, wherein the outer surface of the body with the lubricous coating has a coefficient of friction less than or equal to 0.7.
    Type: Grant
    Filed: October 11, 2013
    Date of Patent: May 19, 2015
    Assignee: Corning Incorporated
    Inventors: Theresa Chang, Steven Edward DeMartino, Andrei Gennadyevich Fadeev, John Stephen Peanasky, Robert Anthony Schaut, Christopher Lee Timmons
  • Publication number: 20150132579
    Abstract: Ion exchangeable glasses that comprise at least one of a transition metal oxide or a rare earth oxide and have compositions that simultaneously promote a surface layer having a high compressive stress and deep depth of layer or, alternatively, reduced ion exchange time.
    Type: Application
    Filed: May 28, 2013
    Publication date: May 14, 2015
    Inventors: Xiaoju Guo, John Christopher Mauro, Marcel Potuzak, Morten Mattrup Smedskjaer
  • Patent number: 9028967
    Abstract: The present invention relates to a chemically strengthened glass for a display device, having a visible light transmittance Tva of 50% or more and less than 91% at a thickness of 1 mm using A light source, and an excitation purity Pe of less than 0.5% at a thickness of 1 mm.
    Type: Grant
    Filed: September 18, 2013
    Date of Patent: May 12, 2015
    Assignee: Asahi Glass Company, Limited
    Inventors: Akio Koike, Yuya Shimada, Isao Saito
  • Patent number: 9023480
    Abstract: A glass substrate for chemical strengthening is formed by a float process. The glass substrate includes at least one layer of a film formed of an inorganic material that contains H atoms in a concentration of 1.0×1015 to 1.0×1019 atom/mm3. The at least one layer is formed on at least one surface of the glass substrate.
    Type: Grant
    Filed: June 19, 2014
    Date of Patent: May 5, 2015
    Assignee: Asahi Glass Company, Limited
    Inventors: Naoki Okahata, Koji Nakagawa, Yuichi Kuwahara, Daisuke Kobayashi
  • Publication number: 20150118497
    Abstract: An ion exchangeable glass having a high degree of resistance to damage caused by abrasion, scratching, indentation, and the like. The glass comprises alumina, B2O3, and alkali metal oxides, and contains boron cations having three-fold coordination. The glass, when ion exchanged, has a Vickers crack initiation threshold of at least 10 kilogram force (kgf).
    Type: Application
    Filed: January 7, 2015
    Publication date: April 30, 2015
    Inventors: Matthew John Dejneka, Adam James Ellison, John Christopher Mauro
  • Patent number: 9016092
    Abstract: A glass for a magnetic recording medium substrate permitting the realization of a magnetic recording medium substrate affording good chemical durability and having an extremely flat surface, a magnetic recording medium substrate comprised of this glass, a magnetic recording medium equipped with this substrate, and methods of manufacturing the same. The glass is an oxide glass not including As or F.
    Type: Grant
    Filed: March 18, 2009
    Date of Patent: April 28, 2015
    Assignee: Hoya Corporation
    Inventors: Yoichi Hachitani, Kinobu Osakabe
  • Publication number: 20150111040
    Abstract: A method capable of forming a sufficiently thick low alkali concentration region without heating glass to a high temperature and even in an atmosphere which is not an atmosphere of plasma formation gas such as helium and argon, is provided. A glass substrate having a pair of main surfaces and being made of glass containing an alkali oxide in its composition, is disposed between a first electrode and a second electrode so that one main surface is separated from the first electrode and the other main surface is brought into contact with the second electrode, and a corona discharge is generated by applying a direct-current voltage to the first electrode as a positive electrode and the second electrode as a negative electrode, in a positive-electrode-side surface layer portion of the glass substrate, at least one positive ion including an alkali ion migrate toward the negative-electrode-side.
    Type: Application
    Filed: December 22, 2014
    Publication date: April 23, 2015
    Applicant: ASAHI GLASS COMPANY, LIMITED
    Inventors: Shiro FUNATSU, Akio KOIKE, Kiyoshi YAMAMOTO, Yuichi YAMAMOTO, Hiroshi WAKATSUKI, Junji NISHII, Kenji HARADA, Hiroshi IKEDA, Daisuke SAKAI
  • Publication number: 20150111030
    Abstract: A process for producing a chemically strengthened glass is provided. The method for producing a chemically strengthened glass includes subjecting a phase-separated glass to an ion exchange treatment. A chemically strengthened glass which is obtained by the process and a phase-separated glass which has been subjected to the ion exchange treatment are also provided.
    Type: Application
    Filed: October 27, 2014
    Publication date: April 23, 2015
    Applicant: ASAHI GLASS COMPANY, LIMITED
    Inventors: Junko MIYASAKA, Takahiro SAKAGAMI, Seiki OHARA, Kosho AKATSUKA, Manuel Diaz REYES, Kazutaka ONO, Hiroyuki HIJIYA
  • Publication number: 20150099124
    Abstract: Glass-ceramics exhibiting a Vickers indentation crack initiation threshold of at least 15 kgf are disclosed. These glass-ceramics may be ion exchangeable or ion exchanged. The glass-ceramics include a crystalline and amorphous phases generated by subjecting a thin precursor glass article to ceramming cycle having an average cooling rate in the range from about 10° C./minute to about 25° C./minute. In one or more embodiments, the crystalline phase may comprise at least 20 wt % of the glass-ceramics. The glass-ceramics may include ?-spodumene ss as the predominant crystalline phase and may exhibit an opacity ?about 85% over the wavelength range of 400-700 nm for an about 0.8 mm thickness and colors an observer angle of 10° and a CIE illuminant F02 determined with specular reflectance included of a* between ?3 and +3, b* between ?6 and +6, and L* between 88 and 97.
    Type: Application
    Filed: October 3, 2014
    Publication date: April 9, 2015
    Inventors: Lionel Joel Mary Beunet, Marie Jacqueline Monique Comte, Allan Mark Fredholm, Qiang Fu, Anne Paris, Sophie Peschiera, Charlene Marie Smith
  • Publication number: 20150093581
    Abstract: An object is to devise a tempered glass substrate that has high mechanical strength and hardly undergoes breakage even though having a large size. A tempered glass substrate has a compressive stress layer in a surface thereof, and includes 1 piece/cm3 or less of devitrified stones containing Zr.
    Type: Application
    Filed: December 4, 2014
    Publication date: April 2, 2015
    Inventors: Takashi MURATA, Takako TOJYO, Motokazu OGATA
  • Patent number: 8986841
    Abstract: A process for reinforcing a glass-ceramic article, into which a maximum tension is introduced beneath the surface of the glass-ceramic, advantageously in proximity to said surface. The invention also relates to an enamel that can be used for this reinforcement, this enamel being formed from a glass frit having the following composition, the proportions being expressed as weight percentages: SiO2 50-66% MgO 3-8% Na2O ?7-15% K2O 0-3% Li2O ?0-12% CaO ?0-10% BaO ?0-15% Al2O3 0-3% ZrO2 0-3% ZnO 0-5% B2O3 0-8% the sum of the alkaline-earth metal oxides CaO+BaO moreover being between 8 and 15%, and the sum of the alkali metal oxides Na2O+K2O+Li2O moreover being between 7 and 20%. The reinforced glass-ceramics obtained by the process.
    Type: Grant
    Filed: January 10, 2014
    Date of Patent: March 24, 2015
    Assignee: Eurokera S.N.C.
    Inventors: Stephanie Pelletier, Marie-Helene Chopinet, Caroline Faillat, Marie-Helene Rouillon, Pablo Vilato
  • Publication number: 20150079347
    Abstract: A glass sheet has one surface and the other surface facing the one surface in a thickness direction, wherein a fluorine concentration (average fluorine concentration by SIMS at a depth of 1 to 24 ?m) in the one surface is higher than that in the other surface. The following expression is satisfied: 0.07??F/?H2O. ?F (mol %) is a value obtained by subtracting an average fluorine concentration in the surface having the lower fluorine concentration from that in the surface having the higher fluorine concentration, and ?H2O (mol %) is an absolute value of a value obtained by subtracting an average H2O concentration in the surface having the higher fluorine concentration from that in the surface having the lower fluorine concentration.
    Type: Application
    Filed: September 26, 2014
    Publication date: March 19, 2015
    Applicant: ASAHI GLASS COMPANY, LIMITED
    Inventors: Satoshi MIYASAKA, Hideko NAKADA, Yasuo HAYASHI, Makoto FUKAWA, Toshifumi NIHEI, Masanobu SHIRAI, Naoki OKAHATA, Koji NAKAGAWA, Kazuhiko YAMANAKA, Kunio WATANABE, Shiro TANII, Nobuaki IKAWA, Daisuke KOBAYASHI, Junichi MIYASHITA, Ryosuke KATO
  • Publication number: 20150079400
    Abstract: Alkali boroaluminosilicate glasses with high resistance to crack initiation and damage due to sharp impact are provided. The glass compositions have melting and forming temperatures that allow forming the glass into sheets via float-based processes while still allowing for the glass to be efficiently ion exchanged. The glass compositions contain MgO, and when ion exchanged, have a Vickers indentation crack initiation load of at least about 10-15 kgf.
    Type: Application
    Filed: September 9, 2014
    Publication date: March 19, 2015
    Inventors: Qiang Fu, Xiaoju Guo
  • Publication number: 20150079318
    Abstract: The embodiments described herein relate to chemically and mechanically durable glass compositions and glass articles formed from the same. In another embodiment, a glass composition may include from about 70 mol. % to about 80 mol. % SiO2; from about 3 mol. % to about 13 mol. % alkaline earth oxide; X mol. % Al2O3; and Y mol. % alkali oxide. The alkali oxide may include Na2O in an amount greater than about 8 mol. %. A ratio of Y:X may be greater than 1 and the glass composition may be free of boron and compounds of boron. In some embodiments, the glass composition may also be free of phosphorous and compounds of phosphorous. Glass articles formed from the glass composition may have at least a class S3 acid resistance according to DIN 12116, at least a class A2 base resistance according to ISO 695, and a type HGA1 hydrolytic resistance according to ISO 720.
    Type: Application
    Filed: November 24, 2014
    Publication date: March 19, 2015
    Applicant: Corning Incorporated
    Inventors: Paul Stephen Danielson, Steven Edward DeMartino, Melinda Ann Drake, Robert Michael Morena, Santona Pal, Robert Anthony Schaut
  • Patent number: 8980777
    Abstract: The embodiments described herein relate to chemically and mechanically durable glass compositions and glass articles formed from the same. In another embodiment, a glass composition may include from about 70 mol. % to about 80 mol. % SiO2; from about 3 mol. % to about 13 mol. % alkaline earth oxide; X mol. % Al2O3; and Y mol. % alkali oxide. The alkali oxide may include Na2O in an amount greater than about 8 mol. %. A ratio of Y:X may be greater than 1 and the glass composition may be free of boron and compounds of boron. In some embodiments, the glass composition may also be free of phosphorous and compounds of phosphorous. Glass articles formed from the glass composition may have at least a class S3 acid resistance according to DIN 12116, at least a class A2 base resistance according to ISO 695, and a type HGA1 hydrolytic resistance according to ISO 720.
    Type: Grant
    Filed: October 25, 2012
    Date of Patent: March 17, 2015
    Assignee: Corning Incorporated
    Inventors: Paul Stephen Danielson, Steven Edward DeMartino, Melinda Ann Drake, Robert Michael Morena, Santona Pal, Robert Anthony Schaut
  • Publication number: 20150072129
    Abstract: A glass sheet includes 4 mol % or more of Al2O3. In the glass sheet, a surface Na2O amount in one surface of the glass sheet is lower than the surface Na2O amount in the other surface of the glass sheet by 0.2 mass % to 1.2 mass %.
    Type: Application
    Filed: September 26, 2014
    Publication date: March 12, 2015
    Applicant: ASAHI GLASS COMPANY, LIMITED
    Inventors: Naoki OKAHATA, Koji NAKAGAWA, Kazuhiko YAMANAKA, Kunio WATANABE, Shiro TANII, Nobuaki IKAWA, Daisuke KOBAYASHI, Junichi MIYASHITA, Ryosuke KATO, Toshifumi NIHEI, Yoichi SERA, Yasuo HAYASHI, Makoto FUKAWA
  • Publication number: 20150064411
    Abstract: A front glass plate for a stacked structure includes greater than or equal to 5 mol % of Al2O3, in terms of an oxide, as a component, 50% crack initiation load of the front glass plate being greater than or equal to 0.5 kg.
    Type: Application
    Filed: November 11, 2014
    Publication date: March 5, 2015
    Applicant: Asahi Glass Company, Limited
    Inventors: Jun SASAI, Kazutaka Ono, Tetsuya Nakashima, Keisuke Abe, Yasuyuki Kameyama, Nana Sato, Yasumasa Kato, Masao Fukami, Kazuhiko Mitarai
  • Publication number: 20150064472
    Abstract: Ion exchangeable glasses having coefficients of thermal expansion (CTE) at least about 90×10?7 ° C.?1. The glasses undergo rapid ion exchange, for example, in a molten KNO3 salt bath to a depth of layer of greater than 30 microns in less than 2 hours at temperatures of 370° C. to 390° C. When ion-exchanged to a depth of layer between 30 to 50 microns, the glasses exhibit a Vickers median/radial crack initiation threshold exceeding 30 kilograms force (kgf). The glasses are fusion formable and, in some embodiments, compatible with zircon.
    Type: Application
    Filed: August 22, 2014
    Publication date: March 5, 2015
    Inventors: Timothy Michael Gross, Xiaoju Guo
  • Publication number: 20150064473
    Abstract: Ion exchangeable glasses containing SiO2, Al2O3, Na2O, MgO, B2O3, and P2O5 are provided. The compressive stresses of these ion exchanged glasses are greater than 900 megapascals (MPa) at a depth of 45 or 50 microns (?m) with some glasses exhibiting a compressive stress of at least 1 gigaPascals (GPa). The ion exchange rates of these glasses are much faster than those of other alkali aluminosilicate glasses and the ion exchanged glass is resistant damage to impact damage. A method of ion exchanging the glass is also provided.
    Type: Application
    Filed: August 25, 2014
    Publication date: March 5, 2015
    Inventors: Matthew John Dejneka, Sinue Gomez, Timothy Micheal Gross, Xiaoju Guo
  • Publication number: 20150064474
    Abstract: Glass-ceramics and precursor glasses that are crystallizable to glass-ceramics are disclosed. The glass-ceramics of one or more embodiments include rutile, anatase, armalcolite or a combination thereof as the predominant crystalline phase. Such glasses and glass-ceramics may include compositions of, in mole %: SiO2 in the range from about 45 to about 75; Al2O3 in the range from about 4 to about 25; P2O5 in the range from about 0 to about 10; MgO in the range from about 0 to about 8; R2O in the range from about 0 to about 33; ZnO in the range from about 0 to about 8; ZrO2 in the range from about 0 to about 4; B2O3 in the range from about 0 to about 12, and one or more nucleating agents in the range from about 0.5 to about 12. In some glass-ceramic articles, the total crystalline phase includes up to 20% by weight of the glass-ceramic article.
    Type: Application
    Filed: August 27, 2014
    Publication date: March 5, 2015
    Inventors: Matthew John Dejneka, Qiang Fu, Timothy Michael Gross, Xiaoju Guo, Sumalee Likitvanichkul, John Christopher Mauro
  • Patent number: 8966939
    Abstract: Disclosed is a method of producing a glass substrate for an information recording medium including a rough polishing step of performing a rough polishing on a glass material containing 0.01 to 2 mass % of cerium oxide; a washing step of washing the glass material after the rough polishing step, so that the cerium content of the glass material surface becomes 0.125 ng/cm2 or less; and a precision polishing step of performing precision polishing on the glass material after the washing step by cyclically using a polishing material containing colloidal silica.
    Type: Grant
    Filed: March 10, 2011
    Date of Patent: March 3, 2015
    Assignee: Hoya Corporation
    Inventor: Hazuki Nakae
  • Publication number: 20150044474
    Abstract: The present disclosure relates to fusion formable highly crystalline glass-ceramic articles whose composition lies within the SiO2—R2O3—Li2O/Na2O—TiO2 system and which contain a silicate crystalline phase comprised of lithium aluminosilicate (?-spodumene and/or ?-quartz solid solution) lithium metasilicate and/or lithium disilicate. Additionally, these silicate-crystal containing glass-ceramics can exhibit varying Na2O to Li2O molar ratio extending from the surface to the bulk of the glass article, particularly a decreasing Li2O concentration and an increasing Na2O concentration from surface to bulk. According to a second embodiment, disclosed herein is a method for forming a silicate crystalline phase-containing glass ceramic.
    Type: Application
    Filed: October 23, 2014
    Publication date: February 12, 2015
    Inventors: George Halsey Beall, Nicholas Francis Borrelli, Charlene Marie Smith, Steven Alvin Tietje
  • Publication number: 20150044473
    Abstract: A method of manufacturing a tempered glass substrate includes: melting glass raw materials blended so as to have a glass composition including, in terms of mass %, 40 to 71% of SiO2, 3 to 23% of Al2O3, 0 to 3.5% of Li2O, 7 to 20% of Na2O, and 0 to 15% of K2O; forming the resultant molten glass into a sheet shape; and performing ion exchange treatment in a KNO3 molten salt, the KNO3 molten salt having a controlled concentration of Na ions, to form a compressive stress layer in a surface of the glass.
    Type: Application
    Filed: July 8, 2013
    Publication date: February 12, 2015
    Inventors: Takashi Murata, Takako Tojyo
  • Patent number: 8951927
    Abstract: An ion exchangeable glass having a high degree of resistance to damage caused by abrasion, scratching, indentation, and the like. The glass comprises alumina, B2O3, and alkali metal oxides, and contains boron cations having three-fold coordination. The glass, when ion exchanged, has a Vickers crack initiation threshold of at least 10 kilogram force (kgf).
    Type: Grant
    Filed: May 28, 2013
    Date of Patent: February 10, 2015
    Assignee: Corning Incorporated
    Inventors: Matthew John Dejneka, Adam James Ellison, John Christopher Mauro
  • Publication number: 20150037586
    Abstract: A glass article is provided having from greater than or equal to about 40 mol % to less than or equal to about 68 mol % SiO2, less than or equal to about 11 mol % Al2O3, an R2O:R?O molar ratio of from greater than or equal to about 1:1 to less than or equal to about 2:1, and an MgO:CaO molar ratio of from greater than or equal to about 0.6:1 to less than or equal to about 1.8:1. The class article may also include a compressive stress layer on at least one surface thereof, the compressive stress layer having a compressive stress that is greater than or equal to about 800 MPa, and a depth that is greater than or equal to about 20 ?m.
    Type: Application
    Filed: July 15, 2014
    Publication date: February 5, 2015
    Inventor: Timothy Michael Gross
  • Patent number: 8946103
    Abstract: An ion exchangeable glass having a high degree of resistance to damage caused by abrasion, scratching, indentation, and the like. The glass comprises alumina, B2O3, and alkali metal oxides, and contains boron cations having three-fold coordination. The glass, when ion exchanged, has a Vickers crack initiation threshold of at least 10 kilogram force (kgf).
    Type: Grant
    Filed: March 5, 2014
    Date of Patent: February 3, 2015
    Assignee: Corning Incorporated
    Inventors: Matthew John Dejneka, Adam James Ellison, John Christopher Mauro
  • Publication number: 20150030834
    Abstract: Embodiments are directed to strengthened glass articles comprising a thickness t?1 mm (1000 ?m), an inner region under a central tension CT (in MPa), and at least one compressive stress layer adjacent the inner region and extending within the strengthened glass article from a surface of the strengthened glass article to a depth of layer DOL (in ?m), wherein the strengthened glass article is under a compressive stress at the surface CSs (in MPa), wherein the strengthened glass article is an alkali aluminosilicate glass article comprising 0-5 mol % Li2O, and at least 3 mol % Al2O3, and wherein the DOL?70 ?m, and a CSs/DOL ratio?2.5 MPa/?m.
    Type: Application
    Filed: July 25, 2014
    Publication date: January 29, 2015
    Inventors: Laurence Ralph Morey, Jonathan David Pesansky, Kevin Barry Reiman, Benjamin Allen Stevens, Brina Paul Strines
  • Publication number: 20150030840
    Abstract: A method of strengthening an alkali aluminoborosilicate glass. A compressive layer extending from a surface of the glass to a depth of layer is formed by exchanging larger metal cations for smaller metal cations present in the glass. In a second step, metal cations in the glass are exchanged for larger metal cations to a second depth in the glass that is less than the depth of layer and increase the compressive stress of the compressive layer. Formation of the compressive layer and replacement of cations with larger cations can be achieved by a two-step ion exchange process. An alkali aluminoborosilicate glass having a compressive layer and a crack indentation threshold of at least 3000 gf is also provided.
    Type: Application
    Filed: October 2, 2014
    Publication date: January 29, 2015
    Inventors: Sinue Gomez, Lisa Ann Lamberson, Robert Michael Morena
  • Patent number: 8938990
    Abstract: For an information storage medium a glass substrate is produced in a method including the steps of: polishing a glass substrate with a polishing agent applied thereon; and subsequently, chemically strengthening a major surface of the glass substrate. The polishing agent contains cerium oxide at a purity equal to or larger than 99% by mass for CeO2/TREO, and has an alkaline earth metal content having a total mass equal to or smaller than 10 ppm by mass. The step of polishing is performed with a soft polishing pad to polish the glass substrate.
    Type: Grant
    Filed: September 13, 2011
    Date of Patent: January 27, 2015
    Assignee: Hoya Corporation
    Inventors: Hazuki Nakae, Toshiharu Mori
  • Publication number: 20150024210
    Abstract: A glass that is down-drawable and ion exchangeable. The glass has a temperature T35kp which the viscosity is 35 kilopoise. T35kp is less than the breakdown temperature Tbreakdown of zircon.
    Type: Application
    Filed: August 11, 2014
    Publication date: January 22, 2015
    Inventors: Matthew John Dejneka, Adam James Ellison, Benjamin Zain Hanson
  • Publication number: 20150017412
    Abstract: A tempered glass according to one embodiment of the present invention is a tempered glass having a compression stress layer in a surface thereof, the tempered glass including as a glass composition, in terms of mass %, 45 to 75% of SiO2, 10 to 25% of Al2O3, 0 to 10% of B2O2, 0 to 8% of MgO, 0 to 20% of SrO+BaO, and 0 to 14% of Na2O. Herein, the term “SrO+BaO” refers to the total amount of SrO and BaO.
    Type: Application
    Filed: February 19, 2013
    Publication date: January 15, 2015
    Inventors: Takashi Murata, Takako Tojyo, Masato Muguruma, Kosuke Kawamoto
  • Publication number: 20150010720
    Abstract: A colored glass, a surface of which is roughened in whole or in part. In the colored glass, an average value of gloss values measured at 9 points in the surface thereof at an incident angle of 60° in accordance with JIS 28741 (1991) is 30 or less, a ratio of a difference between a maximum gloss value and a minimum gloss value to the maximum gloss value is 20% or less, and a minimum value of visible-light transmittance at a thickness of 0.8 mm is 70% or less.
    Type: Application
    Filed: July 1, 2014
    Publication date: January 8, 2015
    Applicant: ASAHI GLASS COMPANY, LIMITED
    Inventors: Yoshitaka SAIJO, Mitsuru WAKATSUKI, Takahiro SAKAGAMI
  • Patent number: 8927444
    Abstract: A constitution of cover glass, the compositions consist in terms of weight % on the oxide basis, of from 64 to 69 wt. % of SiO2; from 7 to 11.5 wt. % of Al2O3; from 1.5 to 2.5 wt. % of B2O3; from 4.5 to 7.5 wt. % of MgO; 0%<CaO?2.5%; 0%<ZnO?2%; 0%<ZrO2?0.2%; 0%<TiO2?1%; from 14.5 to 16.5 wt. % of Na2O; from 1 to 4 wt. % of K2O; and 0%<SnO2?0.4%. The constitution then can be melted to form cover glass. Thereafter, the cover glass is dipped in KNO3 solution so that sodium ions, which is smaller in volume, contained in certain depth from the surface layer of the cover glass can be substituted by potassium ions, which is larger in volume. In this manner, squeezing effect is generated on the surface layer so as to form cover glass having high strength and resistance in both abrasion and scratch.
    Type: Grant
    Filed: March 18, 2013
    Date of Patent: January 6, 2015
    Assignee: Fortune Technology Corp.
    Inventor: Allen Yu
  • Publication number: 20150004390
    Abstract: A tempered glass has a compressive stress layer in a surface thereof, includes as a glass composition, in terms of mass %, 50 to 80% of SiO2, 10 to 30% of Al2O3, 0 to 6% of B2O3, 0 to 2% of Li2O, and 5 to 25% of Na2O, and is substantially free of As2O3, Sb2O3, PbO, and F.
    Type: Application
    Filed: June 6, 2013
    Publication date: January 1, 2015
    Applicant: Nippon Electric Glass Co., Ltd.
    Inventors: Kosuke Kawamoto, Takashi Murata, Takako Tojyo
  • Publication number: 20140376094
    Abstract: Embodiments of this disclosure pertain to articles that exhibit scratch-resistance and improved optical properties. In some examples, the article exhibits a color shift of about 2 or less, when viewed at an incident illumination angle in the range from about 0 degrees to about 60 degrees from normal under an illuminant. In one or more embodiments, the articles include a substrate, and an optical film disposed on the substrate. The optical film includes a scratch-resistant layer and an optical interference layer. The optical interference layer may include one or more sub-layers that exhibit different refractive indices. In one example, the optical interference layer includes a first low refractive index sub-layer and a second a second high refractive index sub-layer. In some instances, the optical interference layer may include a third sub-layer.
    Type: Application
    Filed: September 9, 2014
    Publication date: December 25, 2014
    Inventors: Robert Alan Bellman, Shandon Dee Hart, Karl William Koch, III, Charles Andrew Paulson
  • Publication number: 20140370303
    Abstract: Described herein are various antimicrobial glass articles that have improved resistance to discoloration when exposed to harsh conditions. The improved antimicrobial glass articles described herein generally include a glass substrate that has a low concentration of nonbridging oxygen atoms, a compressive stress layer and an antimicrobial silver-containing region that each extend inward from a surface of the glass substrate to a specific depth, such that the glass article experiences little-to-no discoloration when exposed to harsh conditions. Methods of making and using the glass articles are also described.
    Type: Application
    Filed: June 17, 2014
    Publication date: December 18, 2014
    Inventors: Yuhui Jin, Charlotte Diane Milia, Christine Coulter Wolcott
  • Publication number: 20140370264
    Abstract: The present invention provides a cover glass for a display, having high durability to slow cracking and strong abraded strength even though a compressive stress is large and a depth of a compressive stress layer is deep. The present invention relates to a cover glass for a display, in which a depth of a compressive stress layer (DOL) is 30 ?m or more, a surface compressive stress is 300 MPa or more, a position (HW) at which a compressive stress is half of a value of the surface compressive stress is a position of 8 ?m or more from a glass surface, and the depth of the compressive stress layer (DOL) and the position (HW) at which the compressive stress is half of the value of the surface compressive stress satisfy the following formula: 0.05?HW/DOL?0.23??(1).
    Type: Application
    Filed: June 11, 2014
    Publication date: December 18, 2014
    Applicant: ASAHI GLASS COMPANY, LIMITED
    Inventors: Seiki OHARA, Kazutaka Ono, Tetsuya Nakashima, Hiroyuki Ohkawa
  • Publication number: 20140370302
    Abstract: Described herein are various antimicrobial glass articles that have improved strength and resistance to discoloration. The improved antimicrobial glass articles described herein generally include a glass substrate with a compressive stress layer and an antimicrobial silver-containing region that each extend inward from a surface of the glass substrate to a specific depth. In some embodiments, the compressive stress layer has a compressive stress at the surface of about 500 MPa or greater and the compressive stress decreases monotonically from the surface into the depth of the glass substrate. Methods of making and using the glass articles are also described and include forming a compressive stress layer and forming an antimicrobial silver-containing region by preferentially exchanging a plurality of silver cations in a silver-containing medium for a specific plurality of first cations ions in the glass substrate.
    Type: Application
    Filed: May 28, 2014
    Publication date: December 18, 2014
    Applicant: CORNING INCORPORATED
    Inventors: Jaymin Amin, Timothy Michael Gross, Odessa Natalie Petzold, Rostislav Vatchev Roussev
  • Patent number: 8906506
    Abstract: A noble glass composition which is based on a known potassium-zinc crystal glass composition suitable for chemical strengthening, in which most of contained ZnO component is replaced with a combination of less expensive oxides. The noble glass composition is easily melted in a tank and formed by machine into table wares, and provides a chemical strengthened crystal glass article which has high practical strength as tableware and can be subjected to washing with an alkali.
    Type: Grant
    Filed: May 2, 2008
    Date of Patent: December 9, 2014
    Assignee: Toyo-Sasaki Glass Co., Ltd.
    Inventors: Noriaki Shibata, Hirokazu Toyoda, Keiko Tamamaki
  • Publication number: 20140356605
    Abstract: Described herein are glass, ceramic, or glass-ceramic articles having improved antimicrobial efficacy. Further described are methods of making and using the improved articles. The improved articles generally include a glass, ceramic, or glass-ceramic substrate, a compressive stress layer that extends inward from a surface of the glass, ceramic, or glass-ceramic substrate to a first depth therein, and an antimicrobial agent-containing region that extends inward from the surface of the glass, ceramic, or glass-ceramic substrate to a second depth therein.
    Type: Application
    Filed: May 28, 2014
    Publication date: December 4, 2014
    Applicant: CORNING INCORPORATED
    Inventors: Kaveh Adib, Matthew John Dejneka, Shari Elizabeth Koval
  • Publication number: 20140356628
    Abstract: A glass ceramic precursor glass and a glass ceramic having low levels of rhodium and a method of controlling the amount of rhodium in such glasses and glass ceramics. The precursor glass and glass ceramic contain from about 1 ppm to about 10 ppm and, in certain embodiments, from about 1 ppm to about 6 ppm rhodium. The method of controlling of reducing rhodium dissolution from a rhodium-containing material such as, for example, an alloy into a glass melt comprises controlling and/or lowering the partial pressure of oxygen at the rhodium-containing vessel/glass interface by imposing a high humidity condition around the external (non-glass-contact) surface of the rhodium-containing material. The lower concentration of rhodium minimizes its coloring effect on the white color of the glass ceramic.
    Type: Application
    Filed: May 23, 2014
    Publication date: December 4, 2014
    Applicant: Corning Incorporated
    Inventors: Samir Biswas, Qiang Fu, David Myron Lineman, Ronald Leroy Stewart
  • Patent number: 8889575
    Abstract: Ion exchangeable glass articles are disclosed. In one embodiment, a glass article formed from alkali aluminosilicate glass which may include Ga2O3, Al2O3, Na2O, SiO2, B2O3, P2O5 and various combinations thereof. The glass article may generally include about X mol % of Ga2O3 and about Z mol % of Al2O3, wherein 0?X?20, 0?Z?25 and 10?(X+Z)?25. The glass article may also include from about 5 mol % to about 35 mol % Na2O, SiO2 may be present in an amount from about 40 mol % to about 70 mol % SiO2. The glass article may further include Y mol % B2O3 where Y is from 0 to about 10. The glass article may further include (10-Y) mol % of P2O5. Glass articles formed according to the present invention may be ion-exchange strengthened. In addition, the glass articles may have a low liquid CTE which enables the glass articles to be readily formed into complex shapes.
    Type: Grant
    Filed: May 31, 2011
    Date of Patent: November 18, 2014
    Assignee: Corning Incorporated
    Inventors: Heather Debra Boek, Mark Owen Weller, Randall Eugene Youngman
  • Patent number: 8883663
    Abstract: The present disclosure relates to fusion formable highly crystalline glass-ceramic articles whose composition lies within the SiO2—R2O3—Li2O/Na2O—TiO2 system and which contain a silicate crystalline phase comprised of lithium aluminosilicate (?-spodumene and/or ?-quartz solid solution) lithium metasilicate and/or lithium disilicate. Additionally, these silicate-crystal containing glass-ceramics can exhibit varying Na2O to Li2O molar ratio extending from the surface to the bulk of the glass article, particularly a decreasing Li2O concentration and an increasing Na2O concentration from surface to bulk. According to a second embodiment, disclosed herein is a method for forming a silicate crystalline phase-containing glass ceramic.
    Type: Grant
    Filed: November 29, 2011
    Date of Patent: November 11, 2014
    Assignee: Corning Incorporated
    Inventors: George Halsey Beall, Nicholas Francis Borrelli, Charlene Marie Smith, Steven Alvin Tietje
  • Patent number: 8866590
    Abstract: A sealed insulating glass unit comprises two glass sheets held apart by a spacer, optionally with a sealant between the edges of the glass sheets outside the spacer. The insulating glass unit contains an electronic device, having information relating to the origin, manufacture and/or properties of the insulating glass unit capable of being read from the device by means actuated from outside the insulating glass unit. The device is embedded within the spacer or sealant so that it is concealed within the insulating glass unit.
    Type: Grant
    Filed: May 19, 2007
    Date of Patent: October 21, 2014
    Assignees: Dow Corning, Bystronic Lenhardt GmbH
    Inventors: Andreas Wolf, Richard Henry Thomas, Klaus Puschmann, Peter Schuler
  • Publication number: 20140308512
    Abstract: To provide a glass substrate for a display cover glass not only having excellent strength and antibacterial properties but also having a high transparency and a high visible transmittance suitable as a cover glass for a display device. A glass substrate for a display cover glass, which comprises a surface compressive stress layer and an antibacterial substance-containing layer formed on the glass substrate surface, characterized by having a ratio (T1/T2) of the transmittance T1 at a wavelength of 428 nm to the transmittance T2 at a wavelength of 650 nm of the glass substrate of at least 0.95, and a transmittance at a wavelength of 428 nm of at least 86% when the thickness of the glass substrate is from 0.1 to 3.0 mm.
    Type: Application
    Filed: June 24, 2014
    Publication date: October 16, 2014
    Applicant: Asahi Glass Company, Limited
    Inventors: Hiroyuki YAMAMOTO, Yusaku MATSUO
  • Publication number: 20140308526
    Abstract: An ion exchangeable glass that is free of lithium and comprising 0.1-10 mol % P2O5 and at least 5 mol % Al2O3. The presence of P2O5 enables the glass to be ion exchanged more quickly and to a greater depth than comparable glasses that do not contain P2O5.
    Type: Application
    Filed: June 24, 2014
    Publication date: October 16, 2014
    Inventors: Christy Lynn Chapman, Matthew John Dejneka, Sinue Gomez, Lisa Ann Lamberson
  • Publication number: 20140308525
    Abstract: A glass and a glass composition are provided that, following chemical tempering, not only exhibit high values of compressive stress and depth of ion exchange, but also excellent scratch tolerance. The glass composition includes SiO2, Al2O3, B2O3, ZrO2, and Na2O.
    Type: Application
    Filed: April 10, 2014
    Publication date: October 16, 2014
    Applicant: Schott AG
    Inventors: Oliver Hochrein, Inge Burger, Irmgard Westenberger, Jochen Alkemper, Gerd Rudas, Katharina Alt, Gordon Kissl, Gunther Paulus