Next To Polyamide (nylon, Etc.) Patents (Class 428/423.5)
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Patent number: 7267878Abstract: A moisture-curing hot-melt-adhesive composition in granulate, tablet or powder form can be produced by a.) fusing the reactive hot-melt-adhesive composition and heating the melt, subject to exclusion of moisture, b.) extruding this melt through one or more dies onto a cooled surface, subject to exclusion of moisture, c.) cooling the granulate, subject to exclusion of moisture, whereby the composition solidifies, d.) removing the cooled hot-melt-adhesive granulate, e.) filling the granulate into moisture-tight packages, subject to exclusion of moisture. These reactive hot-melt adhesives are pourable and free-flowing and therefore can be used with all conventional application machines for hot-melt adhesives.Type: GrantFiled: November 7, 2003Date of Patent: September 11, 2007Assignee: Henkel Kommanditgesellschaft auf Aktien (Henkel KGAA)Inventors: Hartmut Primke, Gerald Petry, Ingolf Scheffler, Juergen Wichelhaus, Michael Krebs, Michael Rudolph, Andrew Nixon, Hans-Peter Kohlstadt
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Patent number: 7244501Abstract: A composite sheet material that includes at least one porous core layer including a thermoplastic material and from about 20 weight percent to about 80 weight percent fibers based on a total weight of the porous core layer, and at least one skin covering a surface of the core layer. The skin includes at least one of a thermoplastic film, a fiber based scrim, a non-woven fabric, and a woven fabric.Type: GrantFiled: March 26, 2004Date of Patent: July 17, 2007Assignees: Azdel, Inc., General Electric CompanyInventors: Venkatkrishna Raghavendran, Daniel Scott Woodman, Erich Otto Teutsch, Ralph Robert Buoniconti, Scott Michael Davis, Paul Anthony Bristow, Minquan Cheng, Daniel Wardell Sowle, Benny Ezekiel David
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Patent number: 7175916Abstract: A composite of a resin member bonded to a vulcanized rubber member is obtained with using a rubber member vulcanized with a radical-generating agent (e.g., an organic peroxide) and a thermoplastic resin having at least 2 atoms, on average, selected from H and S atom per molecule, each atom having not less than 0.006 of an orbital interaction energy coefficient S represented by the following formula (1): S=(CHOMO,n)2/|Ec?EHOMO,n|+(CLUMO,n)2/|Ec?ELUMO,n| ??(1) wherein Ec: an orbital energy (eV) of a radical, CHOMO,n: a molecular-orbital coefficient of a highest occupied molecular orbital (HOMO) of an n-th H or S atom constituting a basic unit of the resin, EHOMO,n: an orbital energy (eV) of the HOMO, CLUMO,n: a molecular-orbital coefficient of a lowest unoccupied molecular orbital (LUMO) of the n-th H or S atom constituting the basic unit of the resin, ELUMO,n: an orbital energy (eV) of the LUMO, and above all represent a value calculated by a semiempirical molecular orbital method MOPACPM3.Type: GrantFiled: January 9, 2002Date of Patent: February 13, 2007Assignee: Daicel-Degussa Ltd.Inventors: Toru Ikuta, Hajime Komada, Mitsuteru Mutsuda
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Patent number: 7097908Abstract: The present invention relates to a multilayer structure comprising a transparent polyamide-based layer and a layer based on a thermoplastic polyurethane (TPU). The invention also relates to a decorated article consisting of an object to which the above structure has been bonded, the polyamide layer being on the outside. According to another embodiment, the polyamide/TPU structures may be bonded to a polyurethane foam or to a polyurethane resin. It is also possible to overmould the polyurethane foam or the polyurethane resin to the polyamide/TPU structure placed in a mould, the polyamide layer being adjacent to the mould wall. The structure obtained is useful, for example for making skis or sports shoes. The invention also relates to these structures. Advantageously, the polyamide layer is semicrystalline. Advantageously, the TPU layer is transparent. Each of the layers may be formed from several layers.Type: GrantFiled: October 18, 2004Date of Patent: August 29, 2006Assignee: ArkemaInventors: Christophe Lacroix, Thibaut Montanari
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Patent number: 6994909Abstract: The invention relates to a laminating adhesive including a reaction product of at least one polymeric polyol (part A) and at least one NCO terminated polyurethane prepolymer (part B). The part A includes a reaction product of at least one alkylene diol; at least one dial containing a pendant aliphatic chain; and at least one dicarboxylic acid. The part B includes a reaction product of at least one polyether polyol; and at least one polyisocyanate. The adhesive exhibits an initial viscosity of less than about 25,000 mPa.s at about 25° C.Type: GrantFiled: June 20, 2003Date of Patent: February 7, 2006Assignee: H.B. Fuller Licensing & Financing Inc.Inventor: Brian S. Glasbrenner
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Patent number: 6932882Abstract: A multi-layer application film formed by laminating at least two resin films, a top layer film (I) being formed from a crosslinkable resin coating composition (A), an under layer film (II) being formed from a thermoplastic resin (B), showing practically no stickiness per se, and having a tensile elongation at breakage in the range of 50 to 1000%, said multi-layer application film being applied onto a plastic substrate.Type: GrantFiled: July 11, 2001Date of Patent: August 23, 2005Assignee: Kansai Paint Co., LTDInventors: Naoya Haruta, Takeshi Tomiyama, Toshio Kondo, Yu Akaki, Osamu Isozaki
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Patent number: 6872798Abstract: The invention relates to a polycarbonate composite material which can be thermoplastically shaped and which comprises at least two layers. The invention is characterised in that at least one layer comprises an LOI value of lower than 29 and at least one layer comprises an LOI value of higher than 29. The invention also relates to methods for producing said material, the use of the same and flame-proof polycarbonate moulded parts.Type: GrantFiled: November 2, 2001Date of Patent: March 29, 2005Assignee: Roehm GmbH & Co., KGInventors: Detlef Bumann, Andreas Fetzer, Michael Meier-Kaiser
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Patent number: 6846532Abstract: A laminate packaging material for use with food products, and a retortable pouch comprising that material, are disclosed. The laminate material includes an outer polyethylene terephthalate layer, a nylon second layer, and a polypropylene inner layer. A solventless adhesive is used to bond the layers together. The solventless adhesive includes surface-modified exfoliated montmorillonite clay platelets. The platelets lie generally parallel to the plane of the laminate, and overlap to form a barrier to oxygen and other volatile materials. The retortable pouch is formed by heat sealing the edges one of more sheets of the laminate such that the polypropylene layers face inward and are welded together. The pouch and its contents can then be pasteurized by heat-treatment without degradation of the laminate or the heat seal.Type: GrantFiled: February 15, 2001Date of Patent: January 25, 2005Assignee: Sonoco Development, Inc.Inventor: Francis J. Bensur
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Patent number: 6846534Abstract: Described is a membrane comprising a microlayer polymeric composite having at least about 10 microlayers. The microlayers are each individually up to about 100 microns thick and alternate between at least one gas barrier material and at least one elastomeric material. The membrane can be formed into a pressurized bladder or cushioning device for many applications, including footwear and hydropneumatic accumulators.Type: GrantFiled: May 23, 2003Date of Patent: January 25, 2005Assignee: Nike, Inc.Inventors: Henry W. Bonk, David J. Goldwasser, Paul H. Mitchell
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Patent number: 6797215Abstract: The present invention relates to membranes including an urethane including a polyester polyol, wherein the membrane has a gas transmission rate of 15.0 or less for nitrogen gas wherein the membrane has an average thickness of approximately 20.0 mils. Under certain embodiments, the membranes include blends of one or more polyester polyol based thermoplastic urethanes and one or more barrier materials. The membranes can be employed in a variety of applications and can be used as either monolayers or multi-layered laminates.Type: GrantFiled: September 27, 2001Date of Patent: September 28, 2004Assignee: Nike, Inc.Inventors: Henry W. Bonk, David Goldwasser
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Publication number: 20040185266Abstract: Provided is a gas-barriering coated film obtained by coating a gas barriering layer on at least one face of a flexible film or an inorganic-deposited polymer film, wherein the above gas-barriering layer is a polyurethane resin-cured material formed from a composition comprising an active hydrogen-containing compound (A) and an organic polyisocyanate compound (B), and 20% by weight or more of a skeletal structure represented by Formula (1) is contained in the above resin-cured material. The gas-barriering coated film of the present invention is excellent in various performances such as a layer-to-layer adhesive property, a gas barriering property at a high humidity, a bending resistance and a retort treating resistance in addition to a high gas barriering property, and therefore it is applied to various uses including packing materials for food and medicines to which a high gas barriering property is required.Type: ApplicationFiled: January 29, 2004Publication date: September 23, 2004Inventors: Takeshi Nomura, Takeshi Koyama
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Patent number: 6790514Abstract: A substrate suitable for printing a toner image thereon, comprising: a sheet of plastic; an underlayer coating, on the sheet of plastic, comprising a first polymer material preferably comprising a polymer chosen from the group consisting of amine terminated polyamide, a silane coupling agent and amino propyl teriethoxy silane; an overlayer coating, directly on the underlayer, comprising a second polymer material and having an outer surface to which a toner image can be fused and fixed, the second polymer preferably consisting essentially of a polymer chosen from the group consisting of ethylene acrylic acid copolymer, polyvinyl pyridine and styrene butadine copolymer.Type: GrantFiled: April 7, 2000Date of Patent: September 14, 2004Assignee: Hewlett-Packard Indigo B.V.Inventors: Yaacov Almog, Sergio Brandriss
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Patent number: 6787244Abstract: The present invention describes the use of poly-o-hydroxy amides (PHAs) for adhesively bonding articles or materials, especially components used in the semiconductor industry, such as chips and wafers, a process for adhesively bonding materials, especially chips and/or wafers, chip and/or wafer stacks produced by the process, and adhesive compositions which comprise the poly-o-hydroxy amides of the formula (I).Type: GrantFiled: July 30, 2002Date of Patent: September 7, 2004Assignee: Infineon Technologies AGInventors: Recai Sezi, Andreas Walter
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Patent number: 6783821Abstract: A good layer adhesion can be achieved in a composite having two or more layers wherein a layer I is obtained from a molding composition which has the following components: a) from 0 to 80 parts by weight of a polyamide selected from the group consisting of PA6, PA66, PA6/66 and a mixture thereof; b) from 0.Type: GrantFiled: December 21, 2001Date of Patent: August 31, 2004Assignee: Degussa AGInventors: Hans Ries, Guido Schmitz, Harald Haeger
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Publication number: 20040147188Abstract: The compositions comprise one or more fluorochemical urethane compounds and one or more silsesquioxane compounds. This fluorochemical urethane compound(s) comprises the reaction product of (a) one or more polyfunctional isocyanate compounds; (b) one or more fluorochemical monofunctional compounds; and optionally (c) one or more hydrophilic polyoxyalkylene compounds; and/or (d) one or more silane compounds.Type: ApplicationFiled: January 28, 2003Publication date: July 29, 2004Applicant: 3M Innovative Properties CompanyInventors: Mitchell T. Johnson, Larry A. Lien
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Publication number: 20040142182Abstract: The invention relates to a transparent gas barrier packaging laminate having a required bending stiffness, comprising outer layers of heat-sealable polyolefin, two polymer carrier layers each being coated with a SiOx gas barrier layer, wherein the two polymer carrier layers with SiOx layers are laminated to each other by means of an intermediate polymer layer, which in comparison to the other surrounding layers is relatively stiff and thicker. The required stiffness of the packaging laminate is obtained by the I-beam interaction between the two carrier layers and the intermediate distancing polymer layer. Preferably, the thickness of the intermediate polymer layer constitutes from about 30 to about 55% of the total thickness of the packaging laminate. The invention also relates to a packaging container such as a pouch or similar manufactured from the packaging laminate and to a method of manufacturing of the packaging laminate.Type: ApplicationFiled: November 13, 2003Publication date: July 22, 2004Applicant: TETRA LAVAL HOLDINGS & FINANCE S.A.Inventors: Torsten Olofsson, Sven Andren, Monika Burki
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Patent number: 6716777Abstract: A fabric structure is constructed having a fabric base sheet, a viscidity layer, a polymeric back layer, and a protective layer. The polymeric back layer is prepared from SBC (styrenic block copolymer) for the advantage of low specific gravity and preventing the drawback of PVC or the like that pollutes the environment when disposed off. The protective layer is prepared from PU series or modified SBC (styrenic block copolymer) series agent. When the fabric structure used to make a bag, the front surface of the fabric base sheet is disposed outside the bag and the surface of the protective layer is disposed inside the bag.Type: GrantFiled: November 8, 2001Date of Patent: April 6, 2004Assignee: Epitech Inc.Inventor: Chun-Wei Lin
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Patent number: 6706413Abstract: The present invention is a non-porous, breathable membrane of at least polyamide-4,6, with an elongation at rupture of about 250 to about 500% in the longitudinal direction and about 200 to about 500% in the transverse direction. The membrane has a higher heat resistance than a non-porous, breathable membrane made from polyether ester and, if it also contains an antioxidant, passes the oven/watertightness test. If the membrane is produced from a mixture of polyamide-4,6 and about 10 to about 30% by weight polyether amide, the membrane exhibits a surprisingly increased water-vapor permeability. The membrane is usable in the manufacture of thermally protective clothing.Type: GrantFiled: April 3, 2002Date of Patent: March 16, 2004Assignee: Sympatex Technologies GmbHInventors: Bertram R. Böhringer, Henricus Joannes Maria Van De Ven, Jozef Christiaan Wilhelmus Spijkers
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Patent number: 6677400Abstract: An aqueous polyurethane resin dispersions containing i) a polyol component with a molecular weight above 300 daltons, containing a polyether diol initiated on an aromatic diol, ii) a polyol component with a molecular weight of 62 to 299 daltons, iii) a monofunctional isocyanate-reactive compound with an ethylene oxide content of at least 50 wt. % and a molecular weight of at least 400 daltons, iv) a polyisocyanate v) an aliphatic polyamine with a molecular weight of 60 to 300 daltons or hydrazine, and vi) a hydrophilic aliphatic diamine, a process for making the dispersion and substrates primed with the dispersion.Type: GrantFiled: August 5, 2002Date of Patent: January 13, 2004Assignee: Bayer AktiengesellschaftInventors: Thomas Münzmay, Uwe Klippert, Frank Kobor, Claus Kobusch, Gerald Kurek
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Patent number: 6667082Abstract: A multilayer film has a first layer and a second layer. The first layer comprises an additive, a binder, and a crosslinking agent. The additive is a flavor, fragrance, colorant, antimicrobial agent, antioxidant, chelating agent, and/or odor absorbent. The binder is a polysaccharide and/or a protein. The crosslinking agent comprises a compound with at least two carbonyl groups. The second layer comprises a non-water-soluble thermoplastic polymer comprising at least one member selected from the group consisting of polyolefin, polyamide, polyester, polyvinylidene chloride, polyvinyl chloride, and polystyrene. Each of the additive, binder, and crosslinking agent are present throughout a thickness of the first layer. Preferably, the first layer is coated onto the second layer, which is preferably a non-water-soluble thermoplastic polymer, e.g., polyolefin, polyamide, and/or polyester.Type: GrantFiled: January 20, 1998Date of Patent: December 23, 2003Assignee: Cryovac, Inc.Inventors: Charles R. Bamore, Narender P. Luthra, Walter B. Mueller, Woodrow W. Pressley, Scott W. Beckwith
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Patent number: 6635711Abstract: A moisture-crosslinkable polyurethane adhesive, comprising a)70 to 95% by weight of a polyurethane prepolymer obtained by polyaddition of at least one polyol to at least one diisocyanate trimerized as isocyanurate and, b) 5 to 30% by weight of an essentially amorphous poly-&agr;-olefin, the adhesive comprising a content of free NCO groups representing 1 to 20% by weight of the adhesive.Type: GrantFiled: August 11, 2000Date of Patent: October 21, 2003Inventors: Michel Miskovic, François Bauduin, Patrick Bouttefort, Jean-François Chartrel
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Patent number: 6627306Abstract: A soft elastic cushion for use in conjunction with an orthopedic aid has a textile composite comprising at least two layers arranged on the soft elastic cushion. It is possible in this way to secure a textile cover on a soft elastic substrate such as silicone.Type: GrantFiled: May 18, 2001Date of Patent: September 30, 2003Assignee: Thämert Orthopädische Hilfsmittel GmbH & Co. KGInventor: Reinhold Schneider-Nieskens
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Patent number: 6617031Abstract: The invention relate to a method of laminating flexible packaging, articles of manufacture and bonded laminates. The method comprises employing a laminating adhesive comprising an isocyanate-based composition comprising the reaction product of at least one polymeric polyol (part A) comprising the reaction product of at least one alkylene diol at least one diol; containing a pendant aliphatic chain; and at least one dicarboxylic acid; with at least one NCO terminated polyurethane prepolymer (part B) comprising the reaction product of at least one polyether polyol; and at least one polyisocyanate. The low viscosity laminating adhesive has enhanced processing characteristics at reduced temperature.Type: GrantFiled: March 17, 1998Date of Patent: September 9, 2003Assignee: H. B. Fuller Licensing & Financing Inc.Inventor: Brian S. Glasbrenner
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Patent number: 6617417Abstract: The invention relates to unsaturated polyester resins and more particularly polyester resin compositions curable at room temperature and comprising divinyl ethers. Unsaturated polyester resin compositions in accordance with the invention comprise 50-90 wt. % of at least one normal and/or one modified unsaturated polyester, not more than 30 wt. % of styrene, not more than 20 wt. % of at least one monofunctional and/or one multifunctional monomer, and 0.1-40 wt. % of at least one divinyl ether.Type: GrantFiled: January 31, 2002Date of Patent: September 9, 2003Assignee: Ashland, Inc.Inventors: Karri Airola, Outi Färm, Paul Mahbub, Eija Valtonen
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Publication number: 20030134093Abstract: An ink jet recording material which enables the recorded ink images to exhibit enhanced light fastness, water resistance and hot moisture resistance, includes an ink receiving layer formed on a support material and containing a light fastness-enhancing agent containing hydroquinone-&bgr;-D-glucoside, a salt of pyrocatechol-3,5-disulfonic acid and/or salt of p-hydroxybenzenesulfonic acid, and an inorganic pigment and a cationic polymeric material which are in the form of a plurality of composite particles prepared by mixing an aqueous dispersion of inorganic pigment particles with a cationic polymeric material having a molecular weight of 100,000 or more, to cause the aqueous dispersion of the inorganic pigment particles to be coagulated with the cationic polymeric material, and subjecting the resultant coagulate of the inorganic pigment with the cationic polymeric material to pulverization to form inorganic pigment-cationic polymeric material composite particles having an average composite particle size of 10Type: ApplicationFiled: December 2, 2002Publication date: July 17, 2003Inventors: Ryu Kitamura, Eriko Endo, Tomomi Takahashi, Kazuaki Ohshima
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Patent number: 6592995Abstract: The present invention relates to shape deformable materials, which are capable of (1) being deformed, (2) storing an amount of shape deformation, and (3) recovering at least a portion of the shape deformation when exposed to a humid environment. The shape deformable materials can advantageously be in the form of films, fibers, filaments, strands, nonwovens, and pre-molded elements. The shape deformable materials of the present invention may be used to form products, which are both disposable and reusable. More specifically, the shape deformable materials of the present invention may be used to produce products such as disposable diapers, training pants, incontinence products, and feminine care products.Type: GrantFiled: July 24, 2001Date of Patent: July 15, 2003Assignee: Kimberly-Clark Worldwide, Inc.Inventors: Vasily A. Topolkaraev, Dave A. Soerens
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Publication number: 20030129897Abstract: A forming panel having board with a release barrier of a substrate and a barrier/release layer secured to the board by an adhesive.Type: ApplicationFiled: October 17, 2002Publication date: July 10, 2003Inventors: Howell B. Eleazer, Allan M. Smith, Thomas E. Godfrey, William S. Freeman
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Publication number: 20030124358Abstract: A weatherable composition comprising an upper layer that comprises an aliphatic polyamide resin and an additive composition comprising an hindered amine light stabilizer and a hydroxyphenyl triazine or pyrimidine UV absorber; an intermediate layer that comprises a polymer system compatible with polymer in the upperlayer, and optionally, an additive composition comprising TiO2, dyes, pigments, and special effects additives; and a polymeric substrate, wherein the intermediate layer is disposed between and in intimate contact with the upper layer and the substrate. The composition finds utility in articles such as automotive parts.Type: ApplicationFiled: October 2, 2002Publication date: July 3, 2003Applicant: General Electric CompanyInventors: Peter H. Th. Vollenberg, Sandeep Dhawan, Kyle P. Starkey, Safwat E. Tadros
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Patent number: 6582786Abstract: Described is a membrane comprising a microlayer polymeric composite having at least about 10 microlayers. The microlayers are each individually up to about 100 microns thick and alternate between at least one fluid barrier material and at least one elastomeric material. The membrane can be formed into a pressurized bladder or cushioning device for many applications, including footwear and hydropneumatic accumulators.Type: GrantFiled: June 14, 2001Date of Patent: June 24, 2003Assignee: Nike, Inc.Inventors: Henry W. Bonk, David J. Goldwasser, Paul H. Mitchell
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Publication number: 20030104218Abstract: This invention relates to blends of nylon homopolymers and copolymers with poly(hydroxyamino ether) polymers. More particularly, there are provided blends of nylon 6 and its copolymers with poly(hydroxyamino ether) which form films having high miscibility, high clarity and good processability.Type: ApplicationFiled: November 21, 2001Publication date: June 5, 2003Inventors: Mingliang L. Tsai, Murali K. Akkapeddi, Clark V. Brown, Darnell C. Worley
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Patent number: 6565978Abstract: A multi-component composite coating composition is provided which includes a basecoat deposited from an aqueous basecoat film-forming composition and a transparent topcoat applied over the basecoat. The basecoat film-forming composition includes at least one crosslinkable film-forming resin and at least one amphiphilic alcohol having the structural formula: HO—R, wherein R includes a linear hydrocarbon segment having at least seven contiguous carbon atoms. The amphiphilic alcohol is present in an amount ranging from about 0.01 to about 50 weight percent based upon total amount of resin solids of the basecoat film-forming composition. A coated substrate is also provided.Type: GrantFiled: February 16, 1999Date of Patent: May 20, 2003Assignee: PPG Industries Ohio, Inc.Inventors: Edward S. Pagac, Daniel E. Rardon, Shanti Swarup
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Patent number: 6548154Abstract: A bias transfer member or bias charging member for a xerographic device includes a support substrate, and a multi-layer conductive surface coating over the support substrate. The multi-layer coating includes a base layer of metal-containing particles in a polymer binder, an intermediate layer of conductive particles in a polymer binder, and a top layer of conductive particles in a polymer binder, wherein the amount of the conductive particles in the top layer is greater than the amount of the conductive particles in the intermediate layer. The multi-layer coating exhibits ideal electrical and abrasion resistance performance for use in bias charging or transfer members.Type: GrantFiled: November 28, 2000Date of Patent: April 15, 2003Assignee: Xerox CorporationInventors: Donald S. Stanton, Bing R. Hsieh, Allen J. Thompson, Yuan Yu, William H. Wayman, Michelle L. Schlafer, Heiko Rommelmann, Ann M. Kazakos, Alan R. Kuntz
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Patent number: 6541550Abstract: The invention provides low temperature thermally activatable water-dispersed adhesive compositions and adhesives made from the compositions by removing water. The adhesive compositions of the invention comprise a mixture of low modulus crystallizing polyester polyurethane, acrylic ester copolymer, one or more hydrophobically-modified associative polyurethanes, and a stabilizer system comprising a combination of carbodiimide and branched primary amino alcohol.Type: GrantFiled: April 5, 2000Date of Patent: April 1, 2003Assignee: 3M Innovative Properties CompanyInventors: Arianne E. McCarthy, Terry J. Rayner
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Publication number: 20030060564Abstract: The present invention relates to shape deformable materials, which are capable of (1) being deformed, (2) storing an amount of shape deformation, and (3) recovering at least a portion of the shape deformation when exposed to a humid environment. The shape deformable materials can advantageously be in the form of films, fibers, filaments, strands, nonwovens, and pre-molded elements. The shape deformable materials of the present invention may be used to form products, which are both disposable and reusable. More specifically, the shape deformable materials of the present invention may be used to produce products such as disposable diapers, training pants, incontinence products, and feminine care products.Type: ApplicationFiled: July 24, 2001Publication date: March 27, 2003Inventors: Vasily A. Topolkaraev, Dave A. Soerens
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Patent number: 6534137Abstract: A two-component laminated multilayer film suitable for use in packaging articles such as pet food comprises a first component and a non-heat-shrinkable second component. The first component comprise an outer first film layer, an optional second film layer, and an optional third film layer. The first and third film layers comprise ethylene/alpha-olefin copolymer, while the second film layer is a modified ethylene copolymer. The second component comprises an outer fourth layer, an oxygen barrier fifth layer, sixth and seventh layers which serve as tie layers and are positioned on either side of the barrier layer. The multilayer film is heat sealable to itself and another film. The multilayer film has a total thickness of at least 2 mils, an impact strength of at least about 3 ft-lbs, an elongation at break of less than 300%, a tear propagation of at least 50 grams, a tensile modulus of at least 45,000 psi, total free shrink at 180° F. of from less than 50 percent.Type: GrantFiled: October 12, 1999Date of Patent: March 18, 2003Assignee: Cryovac, Inc.Inventor: Parimal M. Vadhar
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Publication number: 20030049458Abstract: A composite structure including a polyurea show surface, or top layer, and a polyurethane backing layer is disclosed. Preferably, the show surface of the composite structure is substantially free of volatile organic compounds and is aliphatic such that it is ultraviolet light stable. Specifically, the show surface is the reaction product of an aliphatic polyisocyanate or aliphatic polyisocyanate blend, and of a resin component which is a polyamine. The resin component reacts with the aliphatic polyisocyanate to form a polyurea. The show surface has a Shore D hardness of 70. Like the show surface, the polyurethane backing layer of the composite structure is substantially free of volatile organic compounds. This backing layer is the reaction product of a second polyisocyanate component, such as polymeric diphenylmethane diisocyanate, and of a second-layer resin component, which comprises a polyol having a functionality of at least three.Type: ApplicationFiled: August 31, 2001Publication date: March 13, 2003Inventors: Stephen Rickner, Joseph Jibrail, Jose Camba, Carlos Velasco, Calvin Peeler, Michael May
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Patent number: 6531076Abstract: Described are photochromic organic resin compositions and the impact resistant polymerizates and coating compositions made therefrom. The organic resin composition comprises the reaction product of at least one polyol having greater than 1.0 hydroxyl groups; at least one polyisocyanate having greater than 1.0 isocyanato groups; and at least one polyamine curing agent having greater than 1.0 amino groups. The polymerizates are made photochromic either by the addition of organic photochromic compounds to the reactants used to form the polymerizate or by methods that imbibe or transfer the photochromic compounds into the polymerizate. Optically clear photochromic and impact resistant articles such as ophthalmic lenses and articles having photochromic coatings prepared from the photochromic organic resin compositions are also described.Type: GrantFiled: January 19, 2001Date of Patent: March 11, 2003Assignee: PPG Industries Ohio, Inc.Inventors: John C. Crano, Carol L. Knox, Michael O. Okoroafor, Robert A. Smith, Rifat Tabakovic
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Publication number: 20030044620Abstract: Described is an article of a non-elastomeric poly(urea-urethane) substrate having free isocyanato surface groups and at least a partial coating of a photochromic polymeric coating on at least one surface of the substrate.Type: ApplicationFiled: August 30, 2002Publication date: March 6, 2003Inventors: Michael O. Okoroafor, Robert A. Smith
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Patent number: 6509104Abstract: An article having a non-thrombogenic surface and a process for making the article are disclosed. The article is formed by (i) coating a polymeric substrate with a crosslinked chemical combination of a polymer having at least two amino substituted side chains, a crosslinking agent containing at least two crosslinking functional groups which react with amino groups on the polymer, and a linking agent containing a first functional group which reacts with a third functional group of the crosslinking agent, and (ii) contacting the coating on the substrate with an antithrombogenic agent which covalently bonds to a second functional group of the linking agent. In one example embodiment, the polymer is a polyamide having amino substituted alkyl chains on one side of the polyamide backbone, the crosslinking agent is a phosphine having the general formula (A)3P wherein A is hydroxyalkyl, the linking agent is a polyhydrazide and the antithrombogenic agent is heparin.Type: GrantFiled: December 5, 2000Date of Patent: January 21, 2003Assignee: Michigan Biotechnology InstituteInventors: Zhi Heng Huang, William F. McDonald, Stacy C. Wright, Andrew C. Taylor
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Patent number: 6503617Abstract: Described is a multilayer film laminate having at least three layers, and gas barrier properties. The multilayer film laminate comprises sequentially: (I) at least two first layers, each of the first layers (I) having, on one side only, a vapor deposited coating selected independently from the group consisting of aluminum, SiOx and a metal oxide of main group 2 or 3 of the periodic table of the elements; and (II) an exterior polyolefin heat sealing layer. Also described is a method of using the multilayer film laminate as a barrier film in vacuum insulation panels.Type: GrantFiled: May 14, 2001Date of Patent: January 7, 2003Assignee: Wolff Walsrode AGInventors: Sven Jacobsen, Christian Kuckertz, Rainer Brandt
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Patent number: 6497958Abstract: A highly refractive coating composition which can be stably preserved without losing the initial properties even after preserved for extended periods of time. The coating composition contains a metal oxide, a polymerizable alkoxysilane compound, a polymerization catalyst, an acidic aqueous solution and a solvent, wherein an organoamine compound is contained in an amount of from 0.05 to 1.3% by weight with respect to the metal oxide. A method of producing the coating composition comprises mixing a metal oxide suspension containing an organoamine compound in an amount of not smaller than 1.3% by weight with respect to the metal oxide, a polymerizable alkoxysilane compound, a polymerization catalyst, an acidic aqueous solution and a solvent, wherein the organoamine compound is removed so that the amount thereof is from 0.05 to 1.3% by weight with respect to the metal oxide contained in said metal oxide suspension.Type: GrantFiled: September 28, 2001Date of Patent: December 24, 2002Assignee: Tokuyama CorporationInventors: Takashi Abe, Kenichiro Kanou
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Patent number: 6495657Abstract: A polyamide and a process for preparing the polyamide are disclosed.Type: GrantFiled: October 27, 2000Date of Patent: December 17, 2002Assignee: Michigan Biotechnology InstituteInventors: William F. McDonald, Zhi Heng Huang, Stacy C. Wright, Morris Danzig, Andrew C. Taylor
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Patent number: 6485836Abstract: A composite material is described which comprises at least two layers of different plastics materials which are directly bonded to each other, wherein A) one layer of the composite comprises polyurethane, and B) a layer of the composite which is directly bonded to layer A) comprises a thermoplastic plastics material which is different from the material which layer A) comprises, wherein layer A) contains homogeneously distributed particles, which are at least coated with a thermoplastic plastics material which is different from the material comprising layer A), and which have a particle size of ≦50 nm, wherein the total surface area of the particles corresponds at least to the extent of the total interface between layers A) and B). A process for the production of these composites is also described, as is the use of these composites in motor vehicle construction.Type: GrantFiled: May 18, 2000Date of Patent: November 26, 2002Assignee: Bayer AktiengesellschaftInventors: Karsten Reihs, Flore Kempkes, Burkhard Köhler, Holger Warth
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Patent number: 6479612Abstract: A polymer having at least one urea linkage derived by contacting (1) at least one polyisocyanate, or mixture of polyisocyanates, (2) at least one fluorocarbon alcohol, fluorocarbon thiol or fluorocarbon amine, (3) at least one straight or branched chain alcohol, amine or thiol, and (4) at least one alcohol containing a sulfonic acid group or its salt, and then (5) optionally at least one linking agent useful for imparting oil repellency and water repellency to substrates.Type: GrantFiled: June 19, 2000Date of Patent: November 12, 2002Assignee: E. I. du Pont de Nemours and CompanyInventors: Thomas Wayne Del Pesco, Jack Kirchner, Andrew H. Liu
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Patent number: 6479576Abstract: Described is a multi-layer film comprising, (a) at least one first layer of polyamide; (b) at least one second layer of polyethylene or an ethylene-copolymerizate containing fine-particulate titanium dioxide, a majority of the titanium dioxide particles having a diameter of between 5 and 30 nm; (c) optionally at least one EVOH-containing third layer; and (d) optionally at least one bonding layer. The multi-layer film has a value of from 5 to 200, as determined from the summation of the product of the following equation (I) for all second layers of the multi-layer film, (A×B) Equation (I) Equation (I) is calculated for each second layer, A is the thickness of the second layer in micrometers, and B is the weight percent of titanium dioxide present in the second layer, based on the total weight of the second layer. Also described is the use of the film according to the present invention as a packaging material for foodstuffs.Type: GrantFiled: March 22, 2001Date of Patent: November 12, 2002Assignee: Wolff Walsfode AGInventors: Holger Eggers, Rainer Brandt
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Patent number: 6475625Abstract: In a structure for joining a first plastic part and a second plastic part, the first plastic part is composed of at least one resin such as polyamide (PA), polybutylene terephthalate (PBT), polyacetal (POM), polyethylene terephthalate (PET), or polyphenylene sulfide (PPS), while the second plastic part is composed of high-density polyethylene (HDPE). Between the two parts, a metamorphic polyethylene layer exhibiting a good joining property for both the first and second plastic parts is interposed to join the parts.Type: GrantFiled: April 5, 2001Date of Patent: November 5, 2002Assignee: Kyosan Denki Co., Ltd.Inventors: Nobuharu Muto, Hiroshi Osaki
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Publication number: 20020160205Abstract: A co-mingled polyurethane-polyvinyl ester composition can be used as a coating, which has good scratch, mar and solvent resistance. The coating is derived from a waterborne polyurethane solution containing free radically polymerizable monomers such as acrylate, ultraviolet light initiators, and optionally urethane crosslinking agents. A process for forming the co-mingled polyurethane-polyvinyl ester composition comprises drying the waterborne polyurethane containing the polymerizable monomers therein and radiation polymerizing, as by ultraviolet light, the free radically polymerizable monomers on a substrate such as a plastic sheet to form a laminate. Subsequently, the laminate can be utilized to form a coating on a product as by thermoforming, where if urethane crosslinking agents are utilized, the polyurethane will be crosslinked.Type: ApplicationFiled: April 11, 2002Publication date: October 31, 2002Applicant: OMNOVA Solutions Inc.Inventors: Guillermina C. Garcia, Raymond J. Weinert, Martin J. Fay
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Publication number: 20020155305Abstract: The invention relates to a coating for insulation material, which coating comprises a metal layer, such as an aluminum layer, and a plastic layer. The plastic layer contains plastic that crystallises when heated. The plastic can more particularly be a polyamide.Type: ApplicationFiled: February 22, 2002Publication date: October 24, 2002Applicant: UPM-Kymmene CorporationInventor: Juhani Peuramaki
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Publication number: 20020155307Abstract: The present invention is a non-porous, breathable membrane of at least polyamide-4,6, with an elongation at rupture of about 250 to about 500% in the longitudinal direction and about 200 to about 500% in the transverse direction. The membrane has a higher heat resistance than a non-porous, breathable membrane made from polyether ester and, if it also contains an antioxidant, passes the oven/watertightness test. If the membrane is produced from a mixture of polyamide-4,6 and about 10 to about 30% by weight polyether amide, the membrane exhibits a surprisingly increased water-vapor permeability. The membrane is usable in the manufacture of thermally protective clothing.Type: ApplicationFiled: April 3, 2002Publication date: October 24, 2002Applicant: SYMPATEX TECHNOLOGIES GMBHInventors: Bertram R. Bohringer, Henricus Joannes Maria Van De Ven, Jozef Christiaan Wilhelmus Spijkers
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Patent number: 6461732Abstract: Composites of at least two different plastics materials joined directly to one another, wherein A) is a thermoplastic polymer or a thermoplastic mixture of polymers which contain at least one polar compound of at least one of the metals of the 1st to the 5th main group or of the 1st to 8th subsidiary group of the Periodic System as an extremely finely divided powder, and B) is polyurethane.Type: GrantFiled: April 17, 2000Date of Patent: October 8, 2002Assignee: Bayer AktiengesellschaftInventors: Dieter Wittmann, Thomas Eckel, Bernd Keller, Wolfgang Raschilas