Next To Polyester (polyethylene Terephthalate, Etc.) Patents (Class 428/423.7)
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Patent number: 6713167Abstract: A multilayer product which comprises a first element consisting of a layer of spongy, semi-rigid polymer (A), impregnated on one or both sides with polyurethane resin (B), and inserted between two layers of glass fibre, natural fibre or a combination of glass fibre and natural fibre (C) coupled with the central layer (B) (A) (B), wherein the first element is coupled with at least a second element comprising a layer of spongy, semi-rigid polymer (A) , wherein the second element is impregnated on one or both sides with polyurethane resin (B), and wherein the second element is coupled with an additional layer of glass fibre, natural fibre or a combination of glass fibre and natural fibre (C).Type: GrantFiled: October 9, 2001Date of Patent: March 30, 2004Assignee: Industrialesud S.p.A.Inventors: Giuseppe Di Sante, Patrizio D'Ambrosio, Mario Biggio, Guerino Di Sante, Cesare Di Domenico, Gabriella Giovannelli, Claudio Sfredda
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Patent number: 6703115Abstract: There are provided novel multilayer films comprising a layer comprising a thermoplastic polymer, such as an aliphatic-aromatic copolyester (AAPE), with or without filler, and a layer comprising a filled thermoplastic polymer. The polymers in the layers may be the same or different. The multilayer films are preferably characterized by having increased moisture vapor transmission rate (MVTR). Also provided are novel articles of manufacture comprising the novel multilayer films.Type: GrantFiled: January 25, 2002Date of Patent: March 9, 2004Assignee: Eastman Chemical CompanyInventors: Wesley Raymond Hale, Ted Calvin Germroth
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Publication number: 20040028953Abstract: The present invention relates to glazing made of transparent laminated glass of at least two glass panes united by a transparent intercalating sheet of the thermoplastic type and an antisun coat which essentially reflects rays outside the visible spectrum of the solar rays, in particular infrared rays. The laminated glazing is characterized in that it is equipped, on the surface facing the driving compartment, with a transparent coat which essentially reflects heat rays, of the low-emissive type. Besides its antisun function, it also has an insulating function.Type: ApplicationFiled: August 4, 2003Publication date: February 12, 2004Applicant: Saint-Gobain VitrageInventor: Franz Kraemling
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Patent number: 6689474Abstract: The present invention provides compositions comprising (a) a thermally stable polymer comprising resorcinol arylate polyester chain members substantially free of anhydride linkages linking at least two mers of the polymer chain, and (b) at least one auxiliary stabilizer additive selected from the group consisting of 2,2′-(1,4-phenylene)bis(4H-3,1-benzoxazin-4-one) and 1,3-bis[(2-cyano-3,3-diphenylacryloyl)oxy]-2,2-bis[[(2-cyano-3,3-diphenylacryloyl)oxy]methyl]propane. Both multilayer and unitary articles comprising the composition are also provided.Type: GrantFiled: December 5, 2002Date of Patent: February 10, 2004Assignee: General Electric CompanyInventors: James Edward Pickett, Joseph Anthony Suriano, Steven Thomas Rice, Xiangyang Li, Paul Dean Sybert
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Patent number: 6680093Abstract: A multilayer composite comprises a layer configuration A/C/B or A/C/B/C/A, wherein I. each layer A comprises a molding composition that comprises at least 50% by weight of a polymer A containing amino groups; II. layer B comprises a molding composition that consists of at least 50% by weight of a thermoplastic polyester or fluoropolymer B; III. each layer C comprises a molding composition that consists essentially of the following components a)-c): a) from 5 to 95 parts by weight of the polymer A, b) from 95 to 5 parts by weight of the polymer B, and c) from 1 to 90 parts by weight of a compatibilizer comprising an alkyl acrylate polymer.Type: GrantFiled: May 15, 1998Date of Patent: January 20, 2004Assignee: Degussa AGInventors: Hans Ries, Michael Schlobohm, Guido Schmitz
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Patent number: 6677400Abstract: An aqueous polyurethane resin dispersions containing i) a polyol component with a molecular weight above 300 daltons, containing a polyether diol initiated on an aromatic diol, ii) a polyol component with a molecular weight of 62 to 299 daltons, iii) a monofunctional isocyanate-reactive compound with an ethylene oxide content of at least 50 wt. % and a molecular weight of at least 400 daltons, iv) a polyisocyanate v) an aliphatic polyamine with a molecular weight of 60 to 300 daltons or hydrazine, and vi) a hydrophilic aliphatic diamine, a process for making the dispersion and substrates primed with the dispersion.Type: GrantFiled: August 5, 2002Date of Patent: January 13, 2004Assignee: Bayer AktiengesellschaftInventors: Thomas Münzmay, Uwe Klippert, Frank Kobor, Claus Kobusch, Gerald Kurek
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Patent number: 6667082Abstract: A multilayer film has a first layer and a second layer. The first layer comprises an additive, a binder, and a crosslinking agent. The additive is a flavor, fragrance, colorant, antimicrobial agent, antioxidant, chelating agent, and/or odor absorbent. The binder is a polysaccharide and/or a protein. The crosslinking agent comprises a compound with at least two carbonyl groups. The second layer comprises a non-water-soluble thermoplastic polymer comprising at least one member selected from the group consisting of polyolefin, polyamide, polyester, polyvinylidene chloride, polyvinyl chloride, and polystyrene. Each of the additive, binder, and crosslinking agent are present throughout a thickness of the first layer. Preferably, the first layer is coated onto the second layer, which is preferably a non-water-soluble thermoplastic polymer, e.g., polyolefin, polyamide, and/or polyester.Type: GrantFiled: January 20, 1998Date of Patent: December 23, 2003Assignee: Cryovac, Inc.Inventors: Charles R. Bamore, Narender P. Luthra, Walter B. Mueller, Woodrow W. Pressley, Scott W. Beckwith
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Patent number: 6664366Abstract: Thermally stable polymers comprising chain members derived from at least one 1,3-dihydroxybenzene moiety and at least one aromatic dicarboxylic acid moiety, said polymer being substantially free of anhydride linkages linking at least two mers of the polymer chain, are prepared using an interfacial method comprising the steps of: (a) combining at least one 1,3-dihydroxybenzene moiety and at least one catalyst in a mixture of water and at least one organic solvent substantially immiscible with water; (b) adding to the mixture from (a) a controlled stoichiometric ratio of at least one acid chloride and at least one base while maintaining the pH between about 4 and about 8.5, and (c) adjusting the pH of the reaction mixture to a value in the range of about 7 and about 9 following complete addition of acid chloride, and stirring the reaction mixture for a time sufficient to destroy any anhydride linkages in the polymer chain.Type: GrantFiled: March 25, 2002Date of Patent: December 16, 2003Assignee: General Electric CompanyInventors: James Manio Silva, David Michel Dardaris, Gregory Allen O'Neil, Joseph Anthony Suriano
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Patent number: 6656594Abstract: A method to produce shaped multi-layer plates having super-imposed layers includes individually extruding raw materials comprising powder, granules, or crystals, in liquid form, to form a plurality of separate layers, each layer being mono-component or multi-component, superimposing the separate layers, co-extruding the superimposed layers through a co-extrusion head with plane lips to form a continuous flat multi-layer plate with a plane surface, subjecting the flat multi-layer plate emerging from the co-extrusion head to a calendering pass to provide thermal, chemical and dimensional stabilization, subjecting the flat continuous multi-layer plate emerging from the calendering pass to a pass of thermal adjustment and shaping, and cooling and shearing to size the shaped multi-layer plate emerging from the pass of thermal adjustment and shaping so as to obtain shaped multi-layer plate of the desired length.Type: GrantFiled: July 23, 1999Date of Patent: December 2, 2003Assignee: B. Plas Bursa Plastik Sanayi, Ve Ticaret A.S. Demitras Organize San.Inventor: Mehmet Cel{overscore (a )}l Gökçen
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Patent number: 6649260Abstract: An optical coating film in accordance with the present invention makes it possible to prevent the generation of scratches having a size of a specific size or more, thus, since it becomes possible to reduce optical defects caused by the scratches, the optical coating film is suitably applicable to a base film for a prism sheet, an anti-reflection sheet and a hard coating film used for liquid crystal display, a base film for a near infrared ray absorbing film used for a front panel of a plasma display, a base film for a transparent conductive film used for touch panels and electro-luminescence or an anti-destruction film for cathode ray tube.Type: GrantFiled: December 6, 2001Date of Patent: November 18, 2003Assignee: Toyo Boseki Kabushiki KaishaInventors: Katsufumi Kumano, Naonobu Oda, Akira Ito
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Patent number: 6649727Abstract: The present invention relates to stable colloidal dispersions of sulfonated polyurethane ureas and self-supporting films formed from these dispersions. After formation of the sulfonated polyurethane urea, alcohols can be added to the aqueous dispersion to provide a water-alcohol system. The films of the present invention are minimally tacky and self-adhesive.Type: GrantFiled: July 27, 2000Date of Patent: November 18, 2003Assignee: 3M Innovative Properties CompanyInventors: Jeffrey T. Anderson, Carol-Lynn Spawn, Steven T. Hedrick, Howard S. Creel, Steven S. Kantner
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Publication number: 20030207123Abstract: The present invention describes the incorporation of several types of soft-block materials into resorcinol phthalate-co-polycarbonate polymers. In preferred embodiments, the soft-block materials contain aliphatic moieties or silicones as flexibilizing units. Several methods of incorporation into the copolymer structure are described including co-reaction of diols with iso/terephthaloyl chloride, replacement of the normal chainstopper with a p-alkylphenol, replacement of a portion of the bisphenol A with an aliphatic ester-bisphenol, and co-reaction of aliphatic diacid chlorides. The polymers of the present invention have good flow characteristics at temperatures generally used for coating, and have good thermostability and weatherability.Type: ApplicationFiled: December 2, 2002Publication date: November 6, 2003Inventors: Daniel Jospeh Brunelle, Tiberiu Mircea Siclovan, Paul Dean Sybert
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Patent number: 6635711Abstract: A moisture-crosslinkable polyurethane adhesive, comprising a)70 to 95% by weight of a polyurethane prepolymer obtained by polyaddition of at least one polyol to at least one diisocyanate trimerized as isocyanurate and, b) 5 to 30% by weight of an essentially amorphous poly-&agr;-olefin, the adhesive comprising a content of free NCO groups representing 1 to 20% by weight of the adhesive.Type: GrantFiled: August 11, 2000Date of Patent: October 21, 2003Inventors: Michel Miskovic, François Bauduin, Patrick Bouttefort, Jean-François Chartrel
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Patent number: 6632561Abstract: A composite comprises at least one layer which includes a composite comprising (a) from 1 to 99% by weight of a solid (I) with a primary particle size of from 5 nm to 100 &mgr;m or a mixture made from at least two solids, (b) from 99 to 1% by weight of a polymeric binder (II) which includes: (IIa) from 1 to 100% by weight of a polymer or copolymer (IIa) which has, along the chain, terminally and/or laterally, reactive groups (RG) which are capable of crosslinking reactions when exposed to heat and/or UV radiation, and (IIb) from 0 to 99% by weight of at least one polymer or copolymer (IIb) which is free from reactive groups RG, where the at least one layer has been applied to at least one second layer comprising at least one conventional separator.Type: GrantFiled: April 25, 2001Date of Patent: October 14, 2003Assignee: BASF AktiengesellschaftInventors: Stephan Bauer, Bernd Bronstert, Helmut Möhwald, Rainer Blum, Gerhard Dötter
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Patent number: 6632886Abstract: The present invention refers to an optical film comprising one or more polyarylates having at least some units represented by the general structure: wherein A represents one or more different bisphenolfluorene radicals having the general formula (I): wherein R1 and R2 independently represent an alkyl group, a halogen, an alkoxy group, an acyl group, a phenyl group or a nitrile group, with the proviso that R1 and R2 are not both an alkyl group; R3, R4, R5 and R6 represent a hydrogen atom, an alkyl group, a halogen, an alkoxy group, an acyl group, a phenyl group, a nitro group, or a nitrile group; B represents one or more different dicarboxy radicals having the formula: wherein X is a divalent hydrocarbon group having from 1 to 20 carbon atoms, and n is the number of the repeating units which build up the polymer and is a positive integer higher than 20.Type: GrantFiled: April 10, 2001Date of Patent: October 14, 2003Assignee: Ferrania, S.p.A.Inventors: Simone Angiolini, Mauro Avidano, Paolo Salvarani, Roberto Bracco
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Patent number: 6632040Abstract: An applicator brush for use in connection with a moisture-responsive adhesive, such as a cyanoacrylate adhesive, is made with bristles constructed of filaments of a synthetic polymeric material and treated by fluorination to provide a surface barrier against the permeation of the bristles by moisture. The applicator brush is furnished in an adhesive package in which bristles of the brush are in contact with adhesive carried in a reservoir of a container of the package.Type: GrantFiled: December 4, 2001Date of Patent: October 14, 2003Inventor: Robert L. Newell
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Patent number: 6627306Abstract: A soft elastic cushion for use in conjunction with an orthopedic aid has a textile composite comprising at least two layers arranged on the soft elastic cushion. It is possible in this way to secure a textile cover on a soft elastic substrate such as silicone.Type: GrantFiled: May 18, 2001Date of Patent: September 30, 2003Assignee: Thämert Orthopädische Hilfsmittel GmbH & Co. KGInventor: Reinhold Schneider-Nieskens
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Patent number: 6627303Abstract: Articles made from a thermoplastic resin composition comprising a high modulus fiber and a resorcinol polyester or resorcinol polyester carbonate resin showing high strength and stiffness along with surprisingly good retention of gloss and color when exposed to weathering.Type: GrantFiled: January 17, 2003Date of Patent: September 30, 2003Assignee: General Electric CompanyInventors: Robert R. Gallucci, Xiangyang Li, Paul D. Sybert
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Publication number: 20030180542Abstract: The present invention provides compositions comprising (a) a thermally stable polymer comprising resorcinol arylate polyester chain members substantially free of anhydride linkages linking at least two mers of the polymer chain, and (b) at least one auxiliary stabilizer additive selected from the group consisting of 2,2′-(1,4-phenylene)bis(4H-3,1-benzoxazin-4-one) and 1,3-bis[(2-cyano-3,3-diphenylacryloyl)oxy]-2,2-bis[[(2-cyano-3,3-diphenylacryloyl)oxy]methyl]propane. Both multilayer and unitary articles comprising the composition are also provided.Type: ApplicationFiled: December 5, 2002Publication date: September 25, 2003Inventors: James Edward Pickett, Joseph Anthony Suriano, Steven Thomas Rice, Xiangyang Li, Paul Dean Sybert
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Patent number: 6617031Abstract: The invention relate to a method of laminating flexible packaging, articles of manufacture and bonded laminates. The method comprises employing a laminating adhesive comprising an isocyanate-based composition comprising the reaction product of at least one polymeric polyol (part A) comprising the reaction product of at least one alkylene diol at least one diol; containing a pendant aliphatic chain; and at least one dicarboxylic acid; with at least one NCO terminated polyurethane prepolymer (part B) comprising the reaction product of at least one polyether polyol; and at least one polyisocyanate. The low viscosity laminating adhesive has enhanced processing characteristics at reduced temperature.Type: GrantFiled: March 17, 1998Date of Patent: September 9, 2003Assignee: H. B. Fuller Licensing & Financing Inc.Inventor: Brian S. Glasbrenner
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Patent number: 6617417Abstract: The invention relates to unsaturated polyester resins and more particularly polyester resin compositions curable at room temperature and comprising divinyl ethers. Unsaturated polyester resin compositions in accordance with the invention comprise 50-90 wt. % of at least one normal and/or one modified unsaturated polyester, not more than 30 wt. % of styrene, not more than 20 wt. % of at least one monofunctional and/or one multifunctional monomer, and 0.1-40 wt. % of at least one divinyl ether.Type: GrantFiled: January 31, 2002Date of Patent: September 9, 2003Assignee: Ashland, Inc.Inventors: Karri Airola, Outi Färm, Paul Mahbub, Eija Valtonen
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Publication number: 20030165753Abstract: Disclosed are a thermally transferable image protective sheet and a method for protective layer formation that can provide a protective layer which can protect an image of a record produced by a nonsilver photographic color hard copy recording method, can impart lightfastness and other properties to the record, and can realize a record having a glossy impression comparable to silver salt photographs. The thermally transferable image protective sheet comprises a support and a thermally transferable resin layer having a single-layer or multilayer structure stacked on the support so as to be separable from the support.Type: ApplicationFiled: February 28, 2003Publication date: September 4, 2003Applicant: Dai Nippon Prtg. Co., Ltd.Inventors: Taro Suzuki, Daisuke Fukui, Masahiro Fujita
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Publication number: 20030165671Abstract: An object of the present invention is to provide a heat-shrinkable polyester film having a good light blocking property even when the label is not auxiliary processed by printing.Type: ApplicationFiled: February 14, 2003Publication date: September 4, 2003Applicant: TOYO BOSEKI KABUSHIKI KAISHAInventors: Masatoshi Hashimoto, Norimi Tabota, Hiroshi Nagano
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Publication number: 20030162023Abstract: A panel comprising a coverstock layer, an adhesive layer, and at least one substrate layer comprising a polyester mat having dry acrylic polystyrene copolymer. The panel may also include at least one fiber layer also having dry acrylic polystyrene copolymer.Type: ApplicationFiled: February 27, 2002Publication date: August 28, 2003Applicant: LEAR CORPORATIONInventor: Frederick L. Hjortsberg
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Patent number: 6610392Abstract: A heat-shrinkable multilayer film comprises (A) a first layer, which is an outer layer, and which comprises polyolefin; (B) a second layer comprising at least one member selected from the group consisting of polyolefin, polystyrene, and polyurethane; (C) a third layer comprising at least one member selected from the group consisting of amorphous polyester and polyester having a melting point of from about 130° C. to about 260° C.; (D) a fourth layer, which is an outer layer, the fourth layer comprising at least one member selected from the group consisting of polyester, polyamide and polyurethane. The first layer preferably serves as a seal layer in a heat-shrinkable bag. The third layer provides enhanced impact strength, optics, grease-resistance, and free-shrink of the film, and renders the tape more easily orientable.Type: GrantFiled: March 4, 1998Date of Patent: August 26, 2003Assignee: Cryovac, Inc.Inventors: Ram K. Ramesh, John R. Wolf, George D. Wofford
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Patent number: 6610409Abstract: Multilayer articles are disclosed which comprise: a substrate layer comprising at least one thermoplastic polymer, thermoset polymer, cellulosic material, glass, or metal, and at least one coating layer thereon, said coating layer comprising at least one stabilizer additive and a thermally stable polymer comprising resorcinol arylate polyester chain members substantially free of anhydride linkages linking at least two mers of the polymer chain, prepared by an interfacial method comprising the steps of: (a) combining at least one resorcinol moiety and at least one catalyst in a mixture of water and at least one organic solvent substantially immiscible with water; and (b) adding to the mixture from (a) at least one dicarboxylic acid dichloride while maintaining the pH between 3 and 8.5 through the presence of an acid acceptor, wherein the total molar amount of acid chloride groups is stoichiometrically deficient relative to the total molar amount of phenolic groups.Type: GrantFiled: July 18, 2001Date of Patent: August 26, 2003Assignee: General Electric CompanyInventors: James Edward Pickett, Joseph Anthony Suriano, Steven Thomas Rice, Xiangyang Li
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Patent number: 6607795Abstract: Herein is disclosed an oxygen scavenging composition, comprising (i) an oxygen scavenging polymer comprising units having structure I: wherein R1 and R2 are independently selected from the group consisting of —O—, —NCO—, and —NR—, wherein R is selected from the group consisting of —H and —C1-C6 alkyls; (ii) a transition metal oxidation catalyst; and (iii) an energy-absorbing compound selected from the group consisting of microwave reactive materials and photoinitiators having a wavelength of maximum absorption of electromagnetic radiation from about 200 nm to about 750 nm. The oxygen scavenging composition can be used to form an oxygen scavenging packaging article.Type: GrantFiled: December 19, 2001Date of Patent: August 19, 2003Assignee: Chevron Phillips Chemical Company LPInventors: Hu Yang, Ta Yen Ching, Peter Kwan
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Patent number: 6607814Abstract: Substantially solvent-free multilayer articles characterized by excellent color retention and gloss retention, solvent resistance and recyclability comprise a substrate layer comprising a first material selected from the group consisting of a metal, ceramic, glass, a cellulosic material, a thermoset resin, and a thermoplastic resin, and a resinous coating layer which comprises at least one auxiliary color stabilizer additive and an arylate polymer comprising ester structural units derived from a resorcinol or alkylresorcinol isophthalate-terephthalate. An intermediate layer may also be present.Type: GrantFiled: July 18, 2001Date of Patent: August 19, 2003Assignee: General Electric CompanyInventors: James Edward Pickett, Joseph Anthony Suriano, Steven Thomas Rice, Xiangyang Li
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Patent number: 6599624Abstract: An adhesive tape provided on one side with a self-adhesive composition and comprising a backing material comprising a polyester film coated with a crosslinked, thermally vulcanizable polyurethane.Type: GrantFiled: December 14, 2000Date of Patent: July 29, 2003Assignee: tesa AGInventors: Uwe Schümann, Nicolai Böhm, Siegfried Krupke, Ulrike Wappler
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Patent number: 6596843Abstract: Thermally stable polymers comprising resorcinol arylate chain members are prepared using an interfacial method comprising the steps of: interfacial method for preparing polymers comprising resorcinol arylate polyester chain members substantially free of anhydride linkages linking at least two mers of the polymer chain, comprising the steps of: (a) preparing an aqueous solution comprising at least one resorcinol moiety, said solution having a pH less than or equal to about 5; (b) after step (a), preparing a mixture comprising the resorcinol moiety, at least one catalyst and at least one organic solvent substantially immiscible with water; and (c) adding to the mixture from (b) at least one dicarboxylic acid dichloride while maintaining the pH between 3 and 8.5 through the presence of an acid acceptor, wherein the total molar amount of acid chloride groups is stoichiometrically deficient relative to the total molar amount of phenolic groups.Type: GrantFiled: September 28, 2001Date of Patent: July 22, 2003Assignee: General Electric CompanyInventors: Daniel Joseph Brunelle, Paul Dean Sybert, Gregory Allen O'Neil, Joseph Anthony Suriano, Tiberiu Mircea Siclovan, Zhaohui Su
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Patent number: 6596407Abstract: The present invention provides a coated polyester film consisting of a polyester film having opacity as shown by an optical density of not less than 0.3, and a coating layer formed on at least one surface of this polyester film, wherein a surface of this coating layer shows a 60-degree specular glossiness G1 and a 75-degree specular glossiness G2, that satisfy the following formulas (1) and (2): G1≦20 (1) 1<G2/G1≦4 (2).Type: GrantFiled: June 5, 2001Date of Patent: July 22, 2003Assignee: Toyo Boseki Kabushiki KaishaInventors: Syuichi Nishimura, Satoshi Tsukamoto, Chikao Morishige, Tadashi Okudaira, Mutsuo Nishi
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Patent number: 6592995Abstract: The present invention relates to shape deformable materials, which are capable of (1) being deformed, (2) storing an amount of shape deformation, and (3) recovering at least a portion of the shape deformation when exposed to a humid environment. The shape deformable materials can advantageously be in the form of films, fibers, filaments, strands, nonwovens, and pre-molded elements. The shape deformable materials of the present invention may be used to form products, which are both disposable and reusable. More specifically, the shape deformable materials of the present invention may be used to produce products such as disposable diapers, training pants, incontinence products, and feminine care products.Type: GrantFiled: July 24, 2001Date of Patent: July 15, 2003Assignee: Kimberly-Clark Worldwide, Inc.Inventors: Vasily A. Topolkaraev, Dave A. Soerens
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Publication number: 20030129416Abstract: A process is provided for producing a transparent pane structure for motor vehicles, especially a transparent cover for motor vehicle roofs, in which under an outside pane there is a multilayer electrochrome element for influencing the transparency of the pane structure. In the process, the inside of the outer pane is coated with a complete, functional electrochrome package. Furthermore, a transparent pane structure produced using this process is provided.Type: ApplicationFiled: November 12, 2002Publication date: July 10, 2003Applicant: Webasto Systemkomponenten GmbH & Col. KGInventors: Werner Patz, Helmut Teschner
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Patent number: 6586063Abstract: A multilayer material for containing liquid products, specifically for liquid products comprising a hypochlorite bleach is provided. This multi-layer material comprises an inner layer, a layer of adhesive and an outer layer. Said multi-layer material further comprises a bleach resistant adhesive which prevents the degradation of the multi-layer material when exposed to the aggressive action of the hypochlorite bleach or components of said bleach.Type: GrantFiled: February 27, 1998Date of Patent: July 1, 2003Assignee: The Procter & Gamble CompanyInventors: Mario Albanesi, Marco Ciofani
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Patent number: 6586091Abstract: The invention provides a molded laminate with excellent adhesive strength which comprises an adhesive polymer composition layer and a gas-barrier resin layer comprising a polyamide resin or an ethylene-vinyl alcohol copolymer, the adhesive polymer composition layer comprising a modified polyester type elastomer obtained by modifying a saturated polyester type thermoplastic elastomer having a polyalkylene ether glycol segment content of 58 to 73% by weight with an unsaturated carboxylic acid or a derivative thereof in the presence of a radical generator.Type: GrantFiled: April 29, 2002Date of Patent: July 1, 2003Assignee: Mitsubishi Chemical CorporationInventors: Michihiro Iijima, Hideki Takahashi, Masatoshi Oomori
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Patent number: 6582786Abstract: Described is a membrane comprising a microlayer polymeric composite having at least about 10 microlayers. The microlayers are each individually up to about 100 microns thick and alternate between at least one fluid barrier material and at least one elastomeric material. The membrane can be formed into a pressurized bladder or cushioning device for many applications, including footwear and hydropneumatic accumulators.Type: GrantFiled: June 14, 2001Date of Patent: June 24, 2003Assignee: Nike, Inc.Inventors: Henry W. Bonk, David J. Goldwasser, Paul H. Mitchell
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Publication number: 20030108754Abstract: The invention relates to a co-extruded, biaxially oriented polyester film consisting of a base layer and at least one outer layer. The film contains at least one flame-retardant agent, at least one UV-stabilizer and has a matt outer layer which contains a mixture and/or a blend of two components (I) and (II), whereby component (I) is substantially a polyethylene terephthalate homopolymer, or a polyethylene terephthalate copolymer, or a mixture of polyethylene terephthalate homopolymers or polyethylene terephthalate copolymers, and component (II) is a polymer containing at least one sulphonate group.Type: ApplicationFiled: July 18, 2002Publication date: June 12, 2003Inventors: Ursula Murschall, Ulrich Kern, Guenther Crass, Gottfried Hilkert
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Patent number: 6572956Abstract: Substantially solvent-free multilayer articles characterized by excellent color retention and gloss retention, solvent resistance and recyclability comprise a substrate layer comprising a first material selected from the group consisting of a metal, ceramic, glass, a cellulosic material, a thermoset resin, and a thermoplastic resin, and a resinous coating layer which comprises resorcinol or alkylresorcinol isophthalate/terephthalate ester units. An intermediate layer may also be present.Type: GrantFiled: August 5, 1999Date of Patent: June 3, 2003Assignee: General Electric CompanyInventors: James Edward Pickett, Randall Lee Carter, Jimmy Lynn Webb, Daniel Robert Olson, Frank Axel Hoefflin, Hua Wang
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Patent number: 6565978Abstract: A multi-component composite coating composition is provided which includes a basecoat deposited from an aqueous basecoat film-forming composition and a transparent topcoat applied over the basecoat. The basecoat film-forming composition includes at least one crosslinkable film-forming resin and at least one amphiphilic alcohol having the structural formula: HO—R, wherein R includes a linear hydrocarbon segment having at least seven contiguous carbon atoms. The amphiphilic alcohol is present in an amount ranging from about 0.01 to about 50 weight percent based upon total amount of resin solids of the basecoat film-forming composition. A coated substrate is also provided.Type: GrantFiled: February 16, 1999Date of Patent: May 20, 2003Assignee: PPG Industries Ohio, Inc.Inventors: Edward S. Pagac, Daniel E. Rardon, Shanti Swarup
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Patent number: 6565945Abstract: A films composite useful for various printing methods, and particularly UV ray flexographic printing, includes a top layer formed on a substrate film made from a synthetic polymer, particularly polypropylene, containing a binder resin and having an arithmetical mean roughness Ra of 0.2 to 3.5 determined in accordance with JIS B 0601 and, optionally, an anchor layer formed between the substrate film and the top layer and containing an adhesive resin and an adhesive undercoat layer formed between the substrate film and the anchor layer and containing an adhesive resin.Type: GrantFiled: March 30, 1999Date of Patent: May 20, 2003Assignee: Oji Paper Co. Ltd.Inventors: Yoshiharu Nishikori, Hiroyuki Yamada, Koichi Katayama, Yasushi Kobayashi, Eiichi Mikami
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Patent number: 6565936Abstract: A film laminate is disclosed and comprises a biaxially oriented polyester film and another film laminated onto the polyester film, where the polyester film comprises a base layer at least 80% by weight of which is composed of a thermoplastic polyester, at least one cover layer and a metallic or ceramic layer located on the cover layer, where the cover layer is composed of a polymer or of a copolymer or of a mixture of polymers which comprises at least 40% by weight of ethylene 2,6-naphthalate units, up to 40% by weight of ethylene terephthalate units and, if desired, up to 60% by weight of units of other aliphatic, cycloaliphatic or aromatic diols and/or carboxylic acids, with the proviso that the Tg2 value of the polyester film is greater than the Tg2 value of the base layer but smaller than the Tg2 value of the cover layer.Type: GrantFiled: November 2, 1999Date of Patent: May 20, 2003Assignee: Mitsubishi Polyester Film GmbHInventors: Herbert Peiffer, Richard Lee Davis
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Publication number: 20030087105Abstract: The invention relates to a co-extruded, biaxially oriented polyester film containing a flame-retardant agent which can be dissolved in the polyester. The film has a matt outer layer which contains a mixture and/or a blend of two components (I) and (II), whereby component (I) is a polyethylene terephthalate homopolymer, or a polyethylene terephthalate copolymer, or a mixture of polyethylene terephthalate homopolymers or copolymers and component (II) is a polymer containing at least one sulphonate group.Type: ApplicationFiled: July 18, 2002Publication date: May 8, 2003Inventors: Ursula Murschall, Ulrich Kern, Guenther Crass, Gottfried Hilkert
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Patent number: 6548154Abstract: A bias transfer member or bias charging member for a xerographic device includes a support substrate, and a multi-layer conductive surface coating over the support substrate. The multi-layer coating includes a base layer of metal-containing particles in a polymer binder, an intermediate layer of conductive particles in a polymer binder, and a top layer of conductive particles in a polymer binder, wherein the amount of the conductive particles in the top layer is greater than the amount of the conductive particles in the intermediate layer. The multi-layer coating exhibits ideal electrical and abrasion resistance performance for use in bias charging or transfer members.Type: GrantFiled: November 28, 2000Date of Patent: April 15, 2003Assignee: Xerox CorporationInventors: Donald S. Stanton, Bing R. Hsieh, Allen J. Thompson, Yuan Yu, William H. Wayman, Michelle L. Schlafer, Heiko Rommelmann, Ann M. Kazakos, Alan R. Kuntz
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Publication number: 20030068500Abstract: The invention relates to a transparent, UV-stabilized, single or multi-layered thermoformable film which contains, as a principal constituent, a crystallizable thermoplastic, preferably polyethylene terephthalate, and at least one UV-stabilizer. The inventive films are characterized by having a good stretchability, thermoformability and good optical and mechanical properties. Said films are suitable for outdoor uses just like shaped bodies made of the same.Type: ApplicationFiled: July 18, 2002Publication date: April 10, 2003Inventors: Ursula Murschall, Ulrich Kern, Andreas Stopp, Guenther Crass
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Patent number: 6541550Abstract: The invention provides low temperature thermally activatable water-dispersed adhesive compositions and adhesives made from the compositions by removing water. The adhesive compositions of the invention comprise a mixture of low modulus crystallizing polyester polyurethane, acrylic ester copolymer, one or more hydrophobically-modified associative polyurethanes, and a stabilizer system comprising a combination of carbodiimide and branched primary amino alcohol.Type: GrantFiled: April 5, 2000Date of Patent: April 1, 2003Assignee: 3M Innovative Properties CompanyInventors: Arianne E. McCarthy, Terry J. Rayner
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Patent number: 6537657Abstract: A biaxially oriented polyester film for a thermal transfer ribbon characterized in that the biaxially oriented polyester film comprises a copolymerized polyethylene-2,6-naphthalate obtained by polycondensing 90 to 99.9 mole % of 2,6-naphthalenedicarboxylic acid and 0.1 to 10 mole % of isophthalic acid as dicarboxylic acid component, and 97 to 100 mole % of ethylene glycol component and 0 to 30 mole % of diethylene glycol component as diol component, the alternating current volume resistivity of the molten product of the film is 66×108 &OHgr;cm or less, the plane orientation coefficient of the film is 0.230 or more and 0.275 or less, and the density of the film is 1.3450 g/cm3 or more.Type: GrantFiled: August 6, 2001Date of Patent: March 25, 2003Assignee: Teijin LimitedInventors: Shinya Watanabe, Koji Furuya
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Patent number: 6538065Abstract: Block copolyestercarbonates substantially free of anhydride linkages linking at least two mers of the polymer chain may be prepared by a method which comprises the steps of: (A) preparing a hydroxy-terminated polyester intermediate in a molten reaction mixture comprising at least one 1,3-dihydroxybenzene moiety and at least one aromatic dicarboxylic acid diarylester under transesterification conditions, said polyester intermediate having a degree of polymerization of at least 4; and (B) conducting a reaction of said polyester intermediate with a carbonate precursor in a two-phase system comprising an aqueous phase and a water-immiscible organic solvent. Articles comprising the copolyestercarbonates are another aspect of the invention.Type: GrantFiled: July 26, 2001Date of Patent: March 25, 2003Assignee: General Electric CompanyInventors: Joseph Anthony Suriano, Tiberiu Mircea Siclovan, Gregory Allen O'Neil, Daniel Joseph Brunelle, Jimmy Lynn Webb
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Publication number: 20030054175Abstract: The present invention relates to a coated film comprising a polyester film having a coat on at lest one side thereof, obtained by applying on at least one side of a polyester film a coating solution containing (1) a self-emulsifiable isocyanate having repeating units of ethylene oxide and two or more isocyanate groups, and (2) at least one polymer selected from the group consisting of polyesters, polymers of vinyl monomers and polyurethanes, then drying and stretching the coated film.Type: ApplicationFiled: May 16, 2002Publication date: March 20, 2003Applicant: Mitsubishi Polyester Film CorporationInventors: Nariaki Okajima, Yoshio Shimizu
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Publication number: 20030054169Abstract: Biaxially oriented, co-extruded polyester films comprising a base layer consisting of at least 90 wt. % thermoplastic polyester, preferably polyethylene terephthalate (PET), at least one sealable outer layer and a second non-sealable outer layer and, optionally, other intermediate layers, in addition to at least one UV absorber, preferably hydroxy benzotriazole and triazine, and at least one flame-retardant agent, preferably organic phosphorous compounds. The inventive films are characterized by low inflammability, high UV stability, no embrittlement when subjected to thermal stress and a surface which is devoid of troublesome opacity. They are suitable for a multiplicity of uses both indoors and outside. The outer layers contain anti-blocking agents such as silicic acid having an average particle diameter of preferably less than 50 nm and/or more than 2 &mgr;m. Preferably, the sealable outer layer consists of a copolyester which is made of ethylene terephthalate and ethylene isophthalate units.Type: ApplicationFiled: July 26, 2002Publication date: March 20, 2003Inventors: Ursula Murschall, Ulrich Kern, Andreas Stopp, Guenther Crass, Herbert Peiffer
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Publication number: 20030054129Abstract: The invention concerns a unilaterally mat, sealable, UV-stabilized and flame-resistant, sealable, co-extruded, biaxially oriented polyester film comprising at least one base layer (B) and a sealable top coating (A) applied to both sides of said base layer, in addition to a mat covering (C). The film also contains at least one UV stabilizer as a light stabilizer. The invention further concerns a method for the production of said film and the use thereof.Type: ApplicationFiled: July 26, 2002Publication date: March 20, 2003Inventors: Ursula Murschall, Ulrich Kern, Guenther Crass, Herbert Peiffer, Hans Mahl