Phosphorus Containing Metal Salt Formed In Situ Patents (Class 428/472.3)
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Patent number: 10907255Abstract: There is provided a high-strength galvanized steel sheet and a relatively low-strength galvanized steel sheet that undergoes complex forming, a galvanized steel sheet that exhibits consistently excellent press formability and that generates no hazardous fumes during welding as well as a manufacturing method therefor. The galvanized steel sheet has an oxide layer on the surface, where the oxide layer has an average thickness of 20 nm or more, and the oxide layer contains 30 mg/m2 or more of Zn, 1.0 mg/m2 or more of S, and 50 mg/m2 or more and 1,000 mg/m2 or less of polyethylene particles having an average particle size of 5.0 ?m or less.Type: GrantFiled: February 1, 2018Date of Patent: February 2, 2021Assignee: JFE STEEL CORPORATIONInventors: Shinichi Furuya, Akira Matsuzaki, Hiroyuki Masuoka, Katsuya Hoshino
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Patent number: 10487234Abstract: A matte clear coating composition for an aluminum member, comprising acrylic resin (A) having a hydroxy value of 100 to 200 mgKOH/g; melamine resin (B); silica particles (C) having an average particle size of 1.0 to 15 ?m; and polyolefin wax (D) having an average particle size of 10 to 40 ?m and a melting point of 145° C. to 180° C., the matte clear coating composition comprising 5 to 20 mass % of silica particles (C) and 3 to 15 mass % of polyolefin wax (D) based on the total solids content of acrylic resin (A) and melamine resin (B). The matte clear coating composition for an aluminum member satisfies both corrosion resistance and abrasion resistance (scratch resistance).Type: GrantFiled: October 18, 2017Date of Patent: November 26, 2019Assignee: KANSAI PAINT CO., LTD.Inventors: Ryusuke Shinke, Yoshinori Kato
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Patent number: 9580119Abstract: A trailer coupler assembly includes a grid assembly having a plate and a channel formed on the plate. A kingpin is received in the channel and is positioned to extend below a bottom surface of the plate. The channel is galvanized. A method of making a coupler assembly comprises the steps of providing a grid assembly having a channel, galvanizing the channel, and covering the channel.Type: GrantFiled: February 12, 2015Date of Patent: February 28, 2017Assignee: Wabash National, L.P.Inventor: Rodney P. Ehrlich
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Patent number: 8795839Abstract: A method for repairing optical elements having a coating, in which the coating is fully or partially removed or left on the optical element, a polishing layer being provided in the coating or a polishing layer being applied, which allows simple processing of the surface to achieve high geometrical accuracy and lower surface roughness. A new coating is applied onto the corresponding polishing layer. Also addressed are corresponding optical elements, including optical elements recycled according to the method.Type: GrantFiled: January 8, 2009Date of Patent: August 5, 2014Assignee: Carl Zeiss SMT GmbHInventor: Thure Boehm
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Publication number: 20140186641Abstract: A magnesium alloy part is inserted into a mold, a resin composition is injected and joined to the part, and a composite is obtained. A part having, formed thereon, a surface layer of a metal oxide, a metal carbonate, or a metal phosphate in use of a usual conversion treatment or a modification method thereof can be used for the magnesium alloy plate 1. The surface that has a larger amount of crystal-like objects of a nanolevel on the surface layer composed of the metal oxide, metal carbonate, or metal phosphate has a higher level of hardness, microscopic roughness, and good injection joining force, and these parameters can be controlled by a conversion treatment method. A resin composition 4, containing PBT or PPS as the main component, is used as the resin composition part.Type: ApplicationFiled: March 5, 2014Publication date: July 3, 2014Applicant: TAISEI PLAS CO., LTD.Inventors: Masanori Naritomi, Naoki Andoh, Naoki Yamano
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Patent number: 8758899Abstract: The present invention provides a dense-coverage, adherent phosphorous-based coating on the native oxide surface of a material. Disclosed phosphorous-based coatings include phosphate and organo-phosphonate coatings. The present invention also provides further derivatization of the phosphorous-based coatings to yield dense surface coverage of chemically reactive coatings and osetoblast adhesion-promoting and proliferation-promoting coatings on the native oxide surface of a titanium material.Type: GrantFiled: September 21, 2011Date of Patent: June 24, 2014Assignee: The Trustees of Princeton UniversityInventors: Jeffrey Schwartz, Michael J. Avaltroni, Kim S. Midwood, Jean E. Schwarzbauer, Ellen Gawalt
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Publication number: 20140048181Abstract: A flat steel product, intended to be formed into a component by hot press forming and having a base made of steel, onto which a metal anti-corrosion coating of a Zn or a Zn alloy is applied. A separate finishing coat is applied to at least one of the free surfaces of the flat steel product. The finishing coat includes at least one base metal compound (oxide, nitride, sulphide, sulphate, carbide, carbonate, fluoride, hydrate, hydroxide, or phosphate). Also, a method enabling the production of a flat steel product of this kind.Type: ApplicationFiled: March 8, 2012Publication date: February 20, 2014Applicant: THYSSENKRUPP STEEL EUROPE AGInventors: Janko Banik, Marc Blumenau, Maria Koeyer, Tobias Lewe, Axel Schrooten
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Publication number: 20140051311Abstract: This invention relates to a method for phosphating metal surfaces in which the metal surfaces are treated with an aqueous phosphate and titanium-based colloidal activating agent prior to phoshating, wherein the activating agent comprises at least one water-soluble silicon compound having at least one organic group. The invention also relates to a corresponding activating agent.Type: ApplicationFiled: October 25, 2013Publication date: February 20, 2014Applicant: Chemetall GmbHInventors: Thomas KOLBERG, Eckart SCHOENFELDER, Olaf DAHLENBURG, Manfred WALTER
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Patent number: 8623526Abstract: Disclosed are a gradient bioceramic coating comprising a rare earth oxide, a broadband laser method for preparing the bioceramic coating, and the use of the bioceramic coating in the field of medical materials.Type: GrantFiled: June 26, 2012Date of Patent: January 7, 2014Assignee: Guizhou UniversityInventors: Qibin Liu, Wenfei Li, Ling Wu
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Patent number: 8491713Abstract: Described is a new a solution comprising a phosphorous compound and optionally a solderability-enhancing compound and its use in a process for increasing the solderability and corrosion resistance of a metal or metal alloy surface.Type: GrantFiled: January 13, 2010Date of Patent: July 23, 2013Assignee: Atotech Deutschland GmbHInventors: Jürgen Barthelmes, Robert Ruether, Olaf Kurtz, Jana Breitfelder
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Publication number: 20130122318Abstract: A surface-passivated lithium metal, which has a composite top layer containing or consisting of at least two poorly soluble components containing lithium. Production of the surface-passivated lithium metal such that lithium metal below 180° C., thus in the solid state, is transformed into an inert, aprotic solvent with a passivating agent of the general formula Li[P(C2O4)?x/2 Fx] where x=0, 2, or 4 is also disclosed.Type: ApplicationFiled: November 16, 2010Publication date: May 16, 2013Applicant: Chemetall GMBHInventor: Ulrich Wietelmann
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Publication number: 20130066425Abstract: The present invention provides polymeric substrates comprising a biocompatible coating and methods of preparation thereof. In particular, the coating may be a ceramic material, especially a calcium phosphate material, which may be functionally graded. The invention provides the ability to apply high quality coatings to polymeric substrates without damaging the substrate (e.g., melting the polymeric material). The functionally graded coating can provide crystalline calcium phosphate near the coating interface with the substrate and provide amorphous calcium phosphate at the outer surface of the coating.Type: ApplicationFiled: November 9, 2012Publication date: March 14, 2013Applicant: North Carolina State UniversityInventor: North Carolina State University
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Patent number: 8323725Abstract: A soft magnetic material is a soft magnetic material including a composite magnetic particle (30) having a metal magnetic particle (10) mainly composed of Fe and an insulating coating (20) covering metal magnetic particle (10), and insulating coating (20) contains an iron phosphate compound and an aluminum phosphate compound. The atomic ratio of Fe contained in a contact surface of insulating coating (20) in contact with metal magnetic particle (10) is larger than the atomic ratio of Fe contained in the surface of insulating coating (20). The atomic ratio of Al contained in the contact surface of insulating coating (20) in contact with metal magnetic particle (10) is smaller than the atomic ratio of Al contained in the surface of insulating coating (20). Thus, iron loss can be reduced.Type: GrantFiled: June 16, 2010Date of Patent: December 4, 2012Assignees: Sumitomo Electric Industries, Ltd., Toda Kogyo Corp.Inventors: Toru Maeda, Naoto Igarashi, Haruhisa Toyoda, Hirokazu Kugai, Kazuyuki Hayashi, Hiroko Morii, Seiji Ishitani
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Patent number: 8206843Abstract: Disclosed are a gradient bioceramic coating comprising a rare earth oxide, a broadband laser method for preparing the bioceramic coating, and the use of the bioceramic coating in the field of medical materials.Type: GrantFiled: October 16, 2008Date of Patent: June 26, 2012Assignee: Guizhou UniversityInventors: Qibin Liu, Wenfei Li, Ling Wu
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Patent number: 8110304Abstract: A packing material for a lithium cell of the present invention includes a first adhesive layer, an aluminum foil layer, a coating layer, an adhesive resin layer or a second adhesive layer, and a sealant layer laminated sequentially onto one surface of a base material layer, wherein the coating layer includes a layer (A) in which 1 to 100 parts by mass of a phosphoric acid or a phosphate has been blended into 100 parts by mass of a rare earth element based oxide.Type: GrantFiled: January 31, 2008Date of Patent: February 7, 2012Assignee: Toppan Printing Co., Ltd.Inventor: Masayoshi Suzuta
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Patent number: 8105444Abstract: A process for producing a highly anticorrosive rare earth permanent magnet, characterized by sequentially subjecting an R—Fe—B sintered magnet to surface finishing involving cutting and/or polishing, plating pretreatment, nickel electroplating to a given plating thickness, immersion in an aqueous solution containing a phosphoric salt, washing with water and heat treatment at 150° to 400° C. for 1 to 24 hr in an atmosphere of 1.3×103 Pa or higher oxygen partial pressure so as to form a thin nickel oxide layer at the surface layer portion.Type: GrantFiled: May 30, 2007Date of Patent: January 31, 2012Assignee: Shin-Etsu Chemical Co., Ltd.Inventor: Kazuo Tamura
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Patent number: 8021758Abstract: Composites comprising an aluminum phosphate-based coating component and methods for sealing porous substrate surfaces.Type: GrantFiled: October 5, 2005Date of Patent: September 20, 2011Assignee: Applied Thin Films, Inc.Inventors: Sankar Sambasivan, Krishnaswamy K. Rangan
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Publication number: 20110186948Abstract: Magnetic material based on at least one magnetic 3d transition metal element and at least one Group IVA semiconductor element, this material being homogeneous and having a Curie temperature (Tc) of 350 K or higher. Method for the production and uses thereof, especially in spintronics.Type: ApplicationFiled: July 21, 2009Publication date: August 4, 2011Inventors: Pascal Pochet, Emmanuel Arras
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Publication number: 20110143154Abstract: This disclosure relates to phosphate coatings that inhibit corrosion of metals, specifically coatings comprising acidic phosphate and alkaline metal oxide/hydroxide components. In one particular embodiment, phosphate-based coating formulations that reduce or eliminate corrosion of steel and other metals are disclosed. In other embodiments, methods for coating steel surfaces with acidic phosphate and alkaline metal oxide/hydroxide components to reduce or eliminate corrosion of the metal surfaces are disclosed.Type: ApplicationFiled: August 20, 2010Publication date: June 16, 2011Inventors: Arun S. WAGH, Vadym Drozd
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Patent number: 7879456Abstract: Methods for bonding adherent phosphorous-containing coating layers to oxide surfaces on substrates wherein the substrates with oxide surfaces are selected from: (a) oxidized iron, titanium, silicon, tin and vanadium; (b) indium tin oxide; and (c) substrates with oxide layers deposited thereon, wherein the substrates on which oxide layers are deposited are selected from ceramics, semiconductors, metals, plastics and glass, and the method contacts the oxide surface with a carrier conveying an organo-phosphonic acid coating composition and heats the oxide surface and carrier at a sufficient temperature while maintaining contact for a sufficient time to bond a layer of the organophosphonic acid to the oxide surface. Coated articles prepared by the inventive method are also disclosed.Type: GrantFiled: July 8, 2008Date of Patent: February 1, 2011Inventors: Jeffrey Schwartz, Michael J. Avaltroni, Michael P. Danahy, Brett M. Silverman
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Patent number: 7776448Abstract: An aqueous composition for pretreating and depositing a coating on metal substrates is provided. The coating composition includes from about 1,500 to about 55,000 ppm based on the aqueous composition of a Group IIA dissolved metal ion, from about 100 to about 200,000 ppm based on the aqueous composition of a dissolved complex metal fluoride ion wherein the metal atom is selected from Group IIIA, Group IVA, Group IVB metals, Group VA, Group VB metals; and water. The composition is free of Group IIA metal fluoride precipitate achieved by including in the composition a complex metal salt different than the salt associated with the complex metal fluoride ion, with the complex metal salt being capable of complexing free fluoride ions to prevent a precipitation reaction. A process for coating a metal substrate with such an aqueous composition is further provided.Type: GrantFiled: June 6, 2008Date of Patent: August 17, 2010Assignee: PPG Industries Ohio, Inc.Inventors: Jeffrey Allen Greene, Donald Robb Vonk
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Patent number: 7763359Abstract: An aluminum phosphate composition comprising aluminum phosphate, aluminum polyphosphate, aluminum metaphosphate, or a mixture thereof. The composition may be characterized by, when in powder form, having particles wherein some of the particles have at least one or more voids per particle. In addition, the composition is characterized by exhibiting two endothermic peaks in Differential Scanning Calorimetry between about 90 degrees to about 250 degrees Celsius. The composition is also characterized by, when in powder form, having a dispersibility of at least 0.025 grams per 1.0 gram of water. The composition is made by a process comprising contacting phosphoric acid with aluminum sulfate and an alkaline solution to produce an aluminum phosphate based product; and optionally calcining the aluminum phosphate, polyphosphate or metaphosphate based product at an elevated temperature. The composition is useful in paints and as a substitute for titanium dioxide.Type: GrantFiled: February 27, 2006Date of Patent: July 27, 2010Assignees: Bunge Fertilizantes S.A., Universidade Estadual de CampinasInventors: Fernando Galembeck, Joäo de Brito
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Patent number: 7601229Abstract: A method for making soft magnetic material includes: a first heat treatment step applying a temperature of at least 400 deg C. and less than 900 deg C. to metal magnetic particles; a step for forming a plurality of compound magnetic particles in which said metal magnetic particles are surrounded by insulation film; and a step for forming a shaped body by compacting a plurality of compound magnetic particles. This provides a method for making soft magnetic material that provides desired magnetic properties.Type: GrantFiled: October 1, 2004Date of Patent: October 13, 2009Assignee: Sumitomo Electric Industries Ltd.Inventors: Haruhisa Toyoda, Hirokazu Kugai, Kazuhiro Hirose, Naoto Igarashi, Takao Nishioka
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Publication number: 20090233114Abstract: Grain-oriented electrical steel sheet having a chrome-free high tensile strength insulating film characterized by comprising steel sheet on the surface of which is formed an insulating film containing a phosphate and colloidal silica as main ingredients and containing crystalline magnesium phosphate uniformly dispersed over the entire surface.Type: ApplicationFiled: May 18, 2007Publication date: September 17, 2009Applicant: NIPPON STEEL CORPORATIONInventors: Kazutoshi Takeda, Fumiaki Takahashi, Shuichi Yamazaki, Hiroyasu Fujii, Fumikazu Andou
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Publication number: 20090208764Abstract: The present invention provides a grain-oriented electrical steel sheet product having a superior corrosion resistance, annealing resistance, film tension, and the like in insulating treatment based on a phosphate not containing chromium and a treatment agent for the same, so provides grain-oriented electrical steel sheet having an insulating film not containing chromium characterized by the insulating film containing a phosphate and one or more compounds selected from inorganic compounds of Fe, Ni, Co, Cu, Sr, and Mo in an amount, as metal elements, of 0.06 to 2.10 moles per mole of phosphate, and an insulating film agent of the same.Type: ApplicationFiled: July 14, 2005Publication date: August 20, 2009Inventors: Osamu Tanaka, Norikazu Fujii, Hiroyasu Fujii, Kazutoshi Takeda
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Patent number: 7569285Abstract: The present invention provides a dense-coverage, adherent phosphorous-based coating on the native oxide surface of a material. Disclosed phosphorous-based coatings include phosphate and organo-phosphonate coatings. The present invention also provides further derivatization of the phosphorous-based coatings to yield dense surface coverage of chemically reactive coatings and osteoblast adhesion-promoting and proliferation-promoting coatings on the native oxide surface of a titanium material.Type: GrantFiled: June 24, 2002Date of Patent: August 4, 2009Assignee: The Trustees of Princeton UniversityInventors: Jeffrey Schwartz, Michael P. Danahy, Michael J. Avaltroni, Kim S. Midwood, Jean E. Schwarzbauer, Michael D. Carolus, Ellen S. Gawalt
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Patent number: 7507483Abstract: An implantable device with a metal, metal alloy, metalloid, polymeric or ceramic surface and a phosphonic acid coating layer directly contacting the surface wherein the surface has hydroxyl groups covalently bonded to the acid groups of the coating layer and the phosphonate organic ligands are omega-functionalized.Type: GrantFiled: April 1, 2003Date of Patent: March 24, 2009Inventors: Jeffrey Schwartz, Michael J. Avaltroni, Michael D. Carolus, Eric L. Hanson, Jean E. Schwarzbauer, Kim S. Midwood, Michael P. Danahy
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Publication number: 20080292895Abstract: The invention relates to polymer foil comprising at least one polymer layer coated with a barrier glass coating of an oxide composition, wherein said oxide composition comprises the element Si in the form of an oxide network, the oxide composition preferably comprises Si and at least one other element X in an oxide network. The oxide network may preferably be applied using plasma. The foil may be a multi-layered foil comprising a plurality of layers, at least one of the layers being a barrier glass coating. The foil has good barrier properties.Type: ApplicationFiled: November 29, 2006Publication date: November 27, 2008Applicant: NANON A/SInventors: Maike Benter, Bahram Eshtehardi, Kjeld Schaumburg, Henry Kierkegaard
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Patent number: 7455905Abstract: The present invention concerns a high purity, annealed iron powder suitable for the preparation of soft magnetic composites. The powder is distinguished in that the content of inevitable impurities is less than 0.30% by weight, the oxygen content is less than 0.05% by weight, and the specific surface area as measured by the BET method is less than 60 m2/kg.Type: GrantFiled: September 8, 2004Date of Patent: November 25, 2008Assignee: Höganäs ABInventors: Zhou Ye, Ola Andersson
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Patent number: 7410705Abstract: A phosphate bonded ceramic is used to provide a protective coating on a rare earth-transition metal (RE-TM) alloy substrate, conferring degradation resistance to the alloy by being oxidation resistant and acting as a diffusion barrier, thereby minimising/preventing oxygen diffusion and elemental depletion. The alloy substrate may, for example, be a permanent magnetic alloy component and may be used in aerospace applications.Type: GrantFiled: November 26, 2003Date of Patent: August 12, 2008Assignee: Rolls-Royce PLCInventors: J. M. Shipton, legal representative, Mark H. Shipton
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Patent number: 7381281Abstract: A method of surface-treating a metal member involves heating, or heating under pressure, the metal member in an aqueous alkaline solution having a pH of 9 or more and containing a manganese compound and a chelating agent dissolved in water, whereby a mold release agent or dirt is removed from the metal member without any pre-cleaning process. The surface treatment forms on the metal member a surface treatment layer providing excellent corrosion resistance. Paint, which adheres well to the surface treatment layer, can provide additional corrosion protection.Type: GrantFiled: November 15, 2002Date of Patent: June 3, 2008Assignee: Chiyoda Chemical Co., LtdInventors: Akio Maeda, Seiji Kuge
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Patent number: 7332229Abstract: The invention provides a varnish that contains an insulting resin, a curing agent, a flame retardant, and an organic solvent. The flame retardant comprises flame retardant particles surface treated with at least one surface treatment agent selected from the group consisting of a phosphorus compound soluble in an organic solvent, an organosilicon compound and a dispersant having a carboxyl group. A formed material is obtained by applying and drying the varnish on a substrate. A multilayer structure is obtained by forming on a substrate having a conductor circuit layer an electrical insulation layer obtained by curing the formed material obtained from the varnish.Type: GrantFiled: April 15, 2003Date of Patent: February 19, 2008Assignee: Zeon CorporationInventors: Daisuke Uchida, Masafumi Kawasaki, Yasuhiro Wakizaka, Atsushi Tsukamoto
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Patent number: 7175914Abstract: In a heat exchanger having tubes and fins, a polyaniline film made of polyaniline and/or a derivative thereof is formed on the surfaces of the tubes and the fins. This polyaniline film is imparted with at least one hydrophilic functional group selected from the class consisting of a primary amino group, a secondary amino group, a tertiary amino group, an ammonium group, a nitric acid group, a carboxyl group, a sulfonic acid group, a phosphonic acid group and a hydroxyl group. Accordingly, the surfaces of the tubes and the fins has good water wettability while maintaining deodorizing and sterilizing functions.Type: GrantFiled: October 29, 2002Date of Patent: February 13, 2007Assignee: Denso CorporationInventors: Tomomi Takagi, Hitoshi Kuno, Hiroaki Fukuda, Yasushi Furukawa, Osamu Kasebe
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Patent number: 7175920Abstract: The present invention is to provide an ultra-thin copper foil with a carrier which comprises a release layer, a diffusion preventive layer and a copper electroplating layer laminated in this order, or a diffusion preventive layer, a release layer and a copper electroplating layer laminated in this order on the surface of a carrier foil, wherein a surface of the copper electroplating layer is roughened; a copper-clad laminated board comprising the ultra-thin copper foil with a carrier being laminated on a resin substrate; a printed wiring board comprising the copper-clad laminated board on the ultra-thin copper foil of which is formed a wiring pattern; and a multi-layered printed wiring board which comprising a plural number of the above printed wiring board being laminated.Type: GrantFiled: July 13, 2005Date of Patent: February 13, 2007Assignee: Circuit Foil Japan Co., Ltd.Inventors: Akitoshi Suzuki, Shin Fukuda, Kazuhiro Hoshino, Tadao Nakaoka
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Patent number: 7135075Abstract: An aqueous solution for depositing an inorganic corrosion resistant coating on a metal substrate is disclosed. The aqueous solution comprises a film-forming agent, a supplemental anion, and a substrate activator. The film-forming agent is a vanadate salt that forms the corrosion resistant coating. The supplemental anion accelerates the rate at which the corrosion resistant coating is formed. The substrate activator serves to remove any existing oxides from the metal substrate prior to the formation of the corrosion resistant coating. The present invention additionally covers objects so coated and methods of application.Type: GrantFiled: January 20, 2004Date of Patent: November 14, 2006Assignee: The Ohio State UniversityInventors: Rudolph G. Buchheit, Hong Guan, Valerie N. Laget
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Patent number: 7125610Abstract: A capacitor comprising an aluminum anode and a dielectric layer comprising phosphate doped aluminum oxide and process for making the capacitor. The capacitor has a CV Product of at least 9 ?F-V/cm2 at 250 volts. Furthermore, the capacitor is formed by the process of: forming an aluminum plate; contacting the plate with an anodizing solution comprising glycerine, 0.1 to 1.0%, by weight, water and 0.01 to 0.5%, by weight, orthophosphate; applying a voltage to the aluminum plate and determining an initial current; maintaining the first voltage until a first measured current is no more than 50% of the initial current; increasing the voltage and redetermining the initial current; maintaining the increased voltage until a second measured current is no more than 50% of the redetermined initial current, and continuing the increasing of the voltage and maintaining the increased voltage until a final voltage is achieved.Type: GrantFiled: March 17, 2003Date of Patent: October 24, 2006Assignee: Kemet Electronics CorporationInventors: John Tony Kinard, Anita Melody, legal representative, David Alexander Wheeler, Duane Earl Stenzinger, Albert Kennedy Harrington, Brian John Melody, deceased
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Patent number: 7033678Abstract: A resin coated metal sheet of the invention has an epoxy resin layer on a galvanized metal sheet, wherein the resin layer contains iron phosphide and at least one selected from the group consisting of aluminum triphosphate, calcium ion exchange silica and amorphous magnesium silicate compound. In the resin coated metal sheet, the epoxy resin is an urethane modified epoxy resin and/or dimer acid modified epoxy resin, and the iron phosphide has a maximum particle diameter of 15 ?m or less. The resin coated metal sheet has excellent weldability, formability and corrosion resistance.Type: GrantFiled: April 26, 2004Date of Patent: April 25, 2006Assignee: Kobe Steel, Ltd.Inventors: Hironobu Nakanishi, Kazuhisa Fujisawa, Hiroo Shige, Masatoshi Iwai
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Patent number: 7029769Abstract: An insulation film whose requisite constituent elements are first elements and a second element. The first elements include B, P, O and Fe. The second element can generate cations whose hexa-coordinated ion radius, defined by Shannon, R. D., is 0.073 nm or more, and which are bivalent or more. Since the second element having a large ion radius is incorporated into network formers made from the first elements, it is possible to improve the heat resistance of the insulation film.Type: GrantFiled: March 18, 2003Date of Patent: April 18, 2006Assignees: Kabushiki Kaisha Toyota Chuo Kenkyusho, Toyota Jidosha Kabushiki Kaisha, Finesinter Co., Ltd.Inventors: Shin Tajima, Takeshi Hattori, Mikio Kondoh, Kiyoshi Higashiyama, Hidefumi Kishimoto, Masaki Sugiyama, Tadayoshi Kikko
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Patent number: 7029762Abstract: The present invention provides an inorganic-organic composite-treated zinc-plated steel sheet whose treated coatings do not contain any chromium and which is excellent in corrosion resistance after degreasing, coating adhesion and electrodeposition coating performance. The inorganic-organic composite-treated zinc-plated steel sheet, which is obtained by forming a zinc phosphate coating, in a coating weight of 0.3 to 5 g/m2, on the zinc-plated steel sheet surface and forming thereon a post-treatment coating, in a coating weight of 0.01 to 1 g/m2, by using a post-treatment composition containing at least one compound (A) selected from the group consisting of thiocarbonyl group-containing compounds, sulfide group-containing compounds and guanidyl group-containing compounds, an organic resin (B), a crosslinking agent (C) and an inorganic corrosion inhibitor (D).Type: GrantFiled: June 24, 2004Date of Patent: April 18, 2006Assignees: Nippon Steel Corporation, Nippon Paint Co., Ltd.Inventors: Kiyokazu Ishizuka, Hidetoshi Shindo, Atsushi Morishita, Koichi Saito, Motohiro Sasaki, Atsuhiko Tounaka
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Patent number: 7026059Abstract: The present invention is to provide an ultra-thin copper foil with a carrier which comprises a release layer, a diffusion preventive layer and a copper electroplating layer laminated in this order, or a diffusion preventive layer, a release layer and a copper electroplating layer laminated in this order on the surface of a carrier foil, wherein a surface of the copper electroplating layer is roughened; a copper-clad laminated board comprising the ultra-thin copper foil with a carrier being laminated on a resin substrate; a printed wiring board comprising the copper-clad laminated board on the ultra-thin copper foil of which is formed a wiring pattern; and a multi-layered printed wiring board which comprising a plural number of the above printed wiring board being laminated.Type: GrantFiled: September 17, 2001Date of Patent: April 11, 2006Assignee: Circuit Foil Japan Co., Ltd.Inventors: Akitoshi Suzuki, Shin Fukuda, Kazuhiro Hoshino, Tadao Nakaoka
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Patent number: 7011895Abstract: The present invention is intended to provide an inorganic-organic composite-treated zinc-plated steel sheet whose treated coatings do not contain any hazardous chromate and which is excellent in corrosion resistance after alkaline degreasing and coating adhesion. An inorganic-organic composite-treated zinc-plated steel sheet which has a zinc phosphate coating, in a coating weight of 0.3 to 5 g/m2, on the zinc-plated steel sheet surface and, thereon, a post-treatment coating, in a coating weight of 0.01 to 1 g/m2, containing an organic resin (A), a zirconium compound (B), an inorganic corrosion inhibitor (C) and an organic corrosion inhibitor (D).Type: GrantFiled: June 24, 2004Date of Patent: March 14, 2006Assignee: Nippon Steel CorporationInventors: Kiyokazu Ishizuka, Hidetoshi Shindo, Koichi Saito, Motohiro Sasaki, Atsuhiko Tounaka
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Patent number: 6929705Abstract: The present invention relates to metallic sheets having an improved antimicrobial property and also related to a method of manufacturing such sheets. More particularly, it relates to the continuous coating on metallic sheets with a resin composition containing antimicrobial additives. The surface of the metallic article is afforded antimicrobial properties by coating a liquid dispersion or solution of fine particles made of an antimicrobial ingredient on the surface of the metallic sheet dispersed in a uniform layer and cured or dried to affix to the metallic surface. The inorganic antibacterial particles are metal component-supporting oxides and zeolite powders. The inorganic antibacterial core particles have at least a primary surface coating of at least one metal or metal compound having antimicrobial properties. Roll coaters apply the coating.Type: GrantFiled: August 23, 2001Date of Patent: August 16, 2005Assignee: AK Steel CorporationInventors: Frederick A. Myers, LeRoy R. Price
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Patent number: 6881279Abstract: A chemically and thermally stable chromate free aqueous liquid treatment for metals, especially aluminum, that imparts corrosion resistance as good as that from conventional chromate containing treatments, contains water and a fluoroacid selected from the group consisting of H2TiF6, H2 ZrF6, H2HfF6, H2SiF6, H2GeF6, H2SnF6, HBF4, and mixtures thereof; a water soluble organic carboxylic acid that contains at least two hydroxyl groups, exclusive of the hydroxyl groups that are part of any carboxyl groups, per carboxyl group in each acid molecule, the water soluble salts of such acids, and mixtures thereof; a source of phosphate ions; and an organic component selected from the group consisting of tannins and amino-phenolic polymers.Type: GrantFiled: December 11, 2002Date of Patent: April 19, 2005Assignee: Henkel CorporationInventors: Kevin K. Meagher, Thomas J. Prescott, Timm L. Kelly
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Patent number: 6866765Abstract: An R-T-B magnet (R is at least one kind of rare-earth elements including Y, and T is Fe or Fe and Co) has an electrolytic copper-plating film where the ratio [I(200)/I(111)] of the X-ray diffraction peak intensity I(200) from the (200) plane to the X-ray diffraction peak intensity I(111) from the (111) plane is 0.1-0.45 in the X-ray diffraction by CuKal rays. This electrolytic copper-plating film is formed by an electrolytic copper-plating method using an electrolytic copper-plating solution which contains 20-150 g/L of copper sulphate and 30-250 g/L of chelating agent and contains no agent for reducing copper ions and has a pH adjusted to 10.5-13.5.Type: GrantFiled: July 4, 2001Date of Patent: March 15, 2005Assignee: Hitachi Metals, Ltd.Inventors: Setsuo Ando, Minoru Endoh, Tsutomu Nakamura, Toru Fukushi
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Patent number: 6835459Abstract: A conductive and weldable anti-corrosion composition for coating metal surfaces which contains: (a) 5 to 40 wt. % of an organic binder containing: (aa) at least one epoxide resin (ab) at least one hardener selected from cyanoguanidine, benzoguanamine and plasticised urea resin (ac) at least one amine adduct selected from polyoxyalkylenetriamine and epoxide resin/amine adducts (b) 0 to 15 wt. % of an anti-corrosion pigment (c) 40 to 70 wt. % of a conductive pigment selected from powdered zinc, aluminum, graphite, molybdenum sulfide, carbon black and iron phosphide (d) 0 to 45 wt. % of a solvent; and a lacquered metal structural part which has a conductive organic layer.Type: GrantFiled: November 6, 2002Date of Patent: December 28, 2004Assignee: Henkel Kommanditgesellschaft auf AktienInventors: Wolfgang Lorenz, Andreas Kunz, Eva Wilke
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Patent number: 6835460Abstract: Excellent adhesion to subsequently applied paint or elastomer is obtained by coating a metal substrate with a phosphate conversion coating by contact with a liquid phosphating solution that contains zinc cations, phosphate anions, and at least one adhesion promoter selected from (i) film-forming organic substances, (ii) polymers of vinyl phenols modified by substitution of substituted aminomethyl moieties on their aromatic rings, (iii) inorganic oxides of one of the elements silicon, aluminum, titanium, and zirconium. Preferably, the phosphating solution also contains manganese and nickel cations and either iron cations or hydroxylamine. If adhesion to paint is desired, the adhesion promoter preferably is an acrylic film-forming substance, while if adhesion to elastomers is desired, the adhesion promoter preferably is a polymer of vinyl phenol and the phosphating solution preferably also contains calcium cations.Type: GrantFiled: May 24, 2004Date of Patent: December 28, 2004Assignee: Henkel Kommanditgesellschaft auf AktienInventors: Brian B. Cuyler, Bruce H. Goodreau, Robert W. Miller, Thomas J. Prescott
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Patent number: 6828033Abstract: Disclosed herein is a method of coating a substrate with a zinc dialkyldithiophosphate (ZDDP) material, comprising the steps of selecting a substrate which is reactive with said ZDDP material; providing an atmosphere containing said ZDDP material at a predetermined concentration; exposing said substrate to said atmosphere for a sufficient period of time and at a sufficient temperature, so as to cause said ZDDP material to form a layered substrate having a layer of a ZDDP derivative material thereon; and annealing said layered substrate.Type: GrantFiled: November 27, 2000Date of Patent: December 7, 2004Inventors: G. Michael Bancroft, Masoud Kasrai, Arthur Bzowski, Marina S. Fuller, Kathy De Jong
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Patent number: 6824882Abstract: Fluorinated phosphonic acid compounds, useful as treatments for substrate surfaces, have the formula: wherein: R1 is a straight chain alkylene group having from about 3 to about 21 carbon atoms, an oxa-substituted straight chain alkylene group having from about 2 to about 20 carbon atoms, or a thia-substituted straight chain alkylene group having from about 2 to about 20 carbon atoms; R2 is a perfluoroalkyl group having from about 4 to about 10 carbon atoms; R3 is hydrogen, an alkali metal cation, or an alkyl group having from about 1 to about 6 carbon atoms; and M is hydrogen or an alkali metal cation, with the proviso that if R1 is an unsubstituted straight chain alkylene group, then the sum of carbon atoms in R1 and R2 combined is at least 10.Type: GrantFiled: May 31, 2002Date of Patent: November 30, 2004Assignee: 3M Innovative Properties CompanyInventors: Larry D. Boardman, Mark J. Pellerite
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Patent number: 6818313Abstract: A corrosion-inhibiting coating, process, and system that provides a tight, adherent zinc- or zinc-alloy coating that is directly deposited onto steel or cast iron surfaces for enhanced corrosion protection. A process for applying the coating is also provided. The process includes the application of two sequential aqueous baths. The first bath contains a precursor zinc compound while the second bath contains a reducing agent to deposit the zinc directly upon the steel or cast iron.Type: GrantFiled: July 24, 2002Date of Patent: November 16, 2004Assignee: University of DaytonInventors: Andrew W. Phelps, Jeffrey A. Sturgill
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Publication number: 20040214022Abstract: Excellent adhesion to subsequently applied paint or elastomer is obtained by coating a metal substrate with a phosphate conversion coating by contact with a liquid phosphating solution that contains zinc cations, phosphate anions, and at least one adhesion promoter selected from (i) film-forming organic substances, (ii) polymers of vinyl phenols modified by substitution of substituted aminomethyl moieties on their aromatic rings, (iii) inorganic oxides of one of the elements silicon, aluminum, titanium, and zirconium. Preferably, the phosphating solution also contains manganese and nickel cations and either iron cations or hydroxylamine. If adhesion to paint is desired, the adhesion promoter preferably is an acrylic film-forming substance, while if adhesion to elastomers is desired, the adhesion promoter preferably is a polymer of vinyl phenol and the phosphating solution preferably also contains calcium cations.Type: ApplicationFiled: May 24, 2004Publication date: October 28, 2004Inventors: Brian B. Cuyler, Bruce H. Goodreau, Robert W. Miller, Thomas J. Prescott