Next To Addition Polymer From Unsaturated Monomers Patents (Class 428/483)
  • Publication number: 20040029030
    Abstract: A method of forming a durable image including the steps of providing a substrate, depositing an image on the substrate, applying a curable coating over the image and curing the coating. The substrate may be formed from a plastics material, paper, card or any other suitable material. The image may be formed by ink, toner or the like. The coating is preferably curable by means of ultra violet light. The coating may be a transfer coating, transferred from a carrier. Alternatively the coating may be deposited by spraying onto the image. Apparatus for forming a durable image includes means for depositing an image on a substrate, means for applying a coating over the image and means for curing the coating.
    Type: Application
    Filed: April 23, 2003
    Publication date: February 12, 2004
    Inventor: Nicholas John Murray
  • Patent number: 6686051
    Abstract: A polyester polymer includes at least one hydroxyl terminated polyoxetane block containing repeat units derived from polymerizing at least one oxetane monomer having a pendant —CH2—O—(CH2)n—Rf group wherein said Rf group is partially or fully fluorinated. A preferred process for forming said polymer is by reacting a hydroxyl terminated polyoxetane with a polycarboxylic acid under appropriate conditions to form an ester linkage and then adding and reacting that product with polyester forming reactants. The polyester polymer containing at least one polyoxetane block therein when reacted with an amino resin curative can be used as a coating on a substrate wherein the coating has dry erase properties. The coated substrate can be used as prepared or applied to yet other substrates.
    Type: Grant
    Filed: October 27, 2000
    Date of Patent: February 3, 2004
    Assignee: OMNOVA Solutions Inc.
    Inventors: Raymond J. Weinert, Robert E. Medsker, Daniel D. Woodland, Edward N. Kresge, Daniel C. Gottschalk, Joe A. Wright
  • Patent number: 6686011
    Abstract: Multi-layered, coinjection stretch-blow molded containers are obtained by stretch-blow molding a preform prepared by coinjection molding a polyester resin and an EVOH resin blend in which one of the EVOH resins is dispersed as particles in an EVOH resin matrix. Containers prepared with this EVOH blend have good impact delamination resistance, good gas-barrier properties, and high transparency is high, even without an adhesive layer. The EVOH blend is composed of two EVOH resins having different ethylene contents and degrees of saponification. The blend exhibits at least two crystal fusion peaks by DSC.
    Type: Grant
    Filed: October 6, 2000
    Date of Patent: February 3, 2004
    Assignee: Kuraray Co., Ltd.
    Inventors: Shinji Tai, Hiroyuki Shimo
  • Patent number: 6682795
    Abstract: Multilayer hollow body made of plastic, especially a fuel tank, having at least two molded multilayer parts welded together to form a multilayer hollow body having a hollow portion formed by a multilayer wall, each of the multilayer parts comprising at least one thermoplastic non-barrier layer and at least one barrier layer which may be comprised of a liquid-crystal polymer (LCP).
    Type: Grant
    Filed: July 13, 2000
    Date of Patent: January 27, 2004
    Assignee: Solvay (Societe Anonyme)
    Inventors: Pierre Gilliard, Jules-Joseph Van Schaftingen
  • Publication number: 20040013893
    Abstract: The present invention relates to a coinjection stretch blow-molded container having a layer of thermoplastic polyester (A) that has specific properties and a layer of an ethylene-vinyl alcohol copolymer resin composition (B) that includes specific minor components and has specific properties, and the thickness ratio of the layer of thermoplastic polyester (A) to the layer of an ethylene-vinyl alcohol copolymer resin composition (B) (layer (A)/layer (B)) in the container body is in the specific range. The coinjection stretch blow molded container of the present invention has excellent gas barrier properties against, for example: oxygen and carbon dioxide; moisture-proofing properties; flavor-retention properties; flavor-barrier properties; and impact delamination resistance. In addition, the coinjection stretch blow molded container of the present invention has a good appearance and can be stably produced in long-run working lines.
    Type: Application
    Filed: February 19, 2003
    Publication date: January 22, 2004
    Applicant: KURARAY CO., LTD
    Inventors: Masakazu Nakaya, Shinji Tai, Hiroyuki Shimo
  • Patent number: 6680093
    Abstract: A multilayer composite comprises a layer configuration A/C/B or A/C/B/C/A, wherein I. each layer A comprises a molding composition that comprises at least 50% by weight of a polymer A containing amino groups; II. layer B comprises a molding composition that consists of at least 50% by weight of a thermoplastic polyester or fluoropolymer B; III. each layer C comprises a molding composition that consists essentially of the following components a)-c): a) from 5 to 95 parts by weight of the polymer A, b) from 95 to 5 parts by weight of the polymer B, and c) from 1 to 90 parts by weight of a compatibilizer comprising an alkyl acrylate polymer.
    Type: Grant
    Filed: May 15, 1998
    Date of Patent: January 20, 2004
    Assignee: Degussa AG
    Inventors: Hans Ries, Michael Schlobohm, Guido Schmitz
  • Patent number: 6680104
    Abstract: A decorative wrapping film for application to a three-dimensional substrate includes a biaxially-oriented polyester layer which has a first surface for adhering to a three-dimensional substrate and a second surface. A decorative layer is coated on the second surface of the polyester layer, and a protective layer is coated on the decorative layer.
    Type: Grant
    Filed: March 27, 1998
    Date of Patent: January 20, 2004
    Assignee: Leonard Kurz GmbH & Co.
    Inventors: Gregory J. Boris, Frank M. Yandrisevits, III
  • Patent number: 6677031
    Abstract: There is provided a multilayer film which is useful as a refractive polarizer film or a semi-transparent film. The multilayer film comprises a first layer comprising of a polyester whose main recurring unit is ethylene-2,6-naphthalene dicarboxylate and a second layer comprising mainly of a thermoplastic resin which is different from the polyester of the first layer, wherein at least one of the first and second layers contains 0.001 to 0.5 wt % of inert fine particles having an average particle diameter of 0.01 to 2 &mgr;m; the first and second layers each have a thickness of 0.05 to 0.3 &mgr;m and are laminated alternately to form a laminate comprising at least 11 layers; the laminate is oriented at least in one direction; and the second layer has a lower refractive index than the first layer at least in one direction. This multilayer film has excellent handling properties such as film formability and windability and an easily adjustable reflectance.
    Type: Grant
    Filed: August 22, 2001
    Date of Patent: January 13, 2004
    Assignee: Teijin Limited
    Inventors: Hirofumi Murooka, Hiroshi Tokuda
  • Patent number: 6677045
    Abstract: The present invention relates to a multilayer coating comprising at least one basecoat layer and one topcoat layer, the coating being preparable by A. applying a component (I), if desired radiation-curable component, based on polyurethane resins, polyacrylate resins, polyester resins and/or amino resins and also mixtures thereof to a substrate and subjecting it to thermal partial crosslinking or drying at temperatures of less than 100° C., preferably 60-80° C., and B. applying a topcoat to this coating layer, and subsequently carrying out radiation curing.
    Type: Grant
    Filed: April 4, 2000
    Date of Patent: January 13, 2004
    Assignee: BASF Coatings AG
    Inventors: Uwe Meisenburg, Karl-Heinz Joost, Andrea Hesselmaier, Heinz-Peter Rink, Reinhold Schwaim, Erich Beck, Rainer Königer
  • Patent number: 6673428
    Abstract: A flexible and stretchable sheet material that is capable of being stretched to conform to a three-dimensional substrate to form a protective and decorative coating thereon is comprised of a thin flexible support having adhered thereto a protective and decorative layer such as a paint layer comprising a colorant incorporated in a film-forming binder. Both the support and the protective and decorative layer are characterized by a very high degree of thickness uniformity and the sheet material exhibits a high level of surface uniformity, an ability to undergo substantial elongation, and a substantially uniform quality and appearance; whereby it can be stretched and bent in the process of bonding it to a substrate and still achieve a defect-free coating of uniformly attractive appearance.
    Type: Grant
    Filed: April 14, 2000
    Date of Patent: January 6, 2004
    Assignee: Eastman Kodak Company
    Inventor: Gerald G. Reafler
  • Patent number: 6673425
    Abstract: A multilayer optical body having improved dimensional stability is disclosed. The optical body includes an optical film, such as an oriented multilayer optical film, and a dimensionally stable layer, such as a transparent polycarbonate layer. In addition, in specific implementations, the invention includes an intermediate layer between the optical film and the dimensionally stable layer. Methods of making the optical body are also disclosed.
    Type: Grant
    Filed: October 27, 2000
    Date of Patent: January 6, 2004
    Assignee: 3M Innovative Properties Company
    Inventors: Timothy J. Hebrink, Andrew J. Ouderkirk
  • Publication number: 20040001960
    Abstract: The invention relates to a laminate comprising a first layer comprising polyester, and a second layer comprising a copolymer of ethylene and methyl acrylate obtained by copolymerization of ethylene monomers and methyl acrylate monomers in a tubular reactor. The laminate may also comprise additional layers. The laminate shows an improved adhesion strength between the first and the second layer.
    Type: Application
    Filed: December 13, 2002
    Publication date: January 1, 2004
    Inventors: Yves M. Trouilhet, Bernard Rioux
  • Patent number: 6667101
    Abstract: The present invention relates to a thermoformable multilayer film comprising in succession: a protective layer (A); a transparent layer (B) comprising (by weight the total amount being 100%) 0 to 100% of a fluoropolymer (B1) and 100 to 0% of a polymer (B2) essentially consisting of alkyl (meth)acrylate units; a layer (C) based on a polyamide with amine terminal groups; a layer (D) consisting of a polyolefin functionalized by an unsaturated carboxylic acid anhydride; a bonding layer (E) made of a polyolefin, said film being obtained by coextruding the various layers, said film being used to cover various substrates, for example by injection-moulding the substrate in the melt onto the multilayer film placed in the bottom of an injection mould, the layer (A) of the film being placed against the wall of the mould.
    Type: Grant
    Filed: January 26, 2001
    Date of Patent: December 23, 2003
    Assignee: Atofina
    Inventors: David Silagy, Jose Teixeira Pires, Philippe Bussi, Anthony Bonnet
  • Publication number: 20030232208
    Abstract: Volatile organic compound or other materials are produced in the thermoplastic manufacture of thermoplastic polyester beverage containers. Such materials can be eluted into beverages such as carbonated beverages, sparkling or still water from the polyester. Such thermoplastic polyester resins can be manufactured with a material that can prevent the formation of, or react with, and absorb volatile by-products during the formation of thermoplastic preforms or containers from the thermoplastic pellet or chip. Further, as the preform is blown into a polyester container, the active materials of the invention prevent the generation of additional undesirable volatile materials. Lastly, the scavenger material can act as a barrier that prevents transport of materials from the exterior of the container into the container contents.
    Type: Application
    Filed: June 5, 2002
    Publication date: December 18, 2003
    Applicant: Cellresin Technologies, LLC
    Inventors: Willard E. Wood, Neil J. Beaverson, Phillip A. Lawonn, Xiaoyan Huang
  • Publication number: 20030232209
    Abstract: An anti-fogging thermoplastic resin sheet is provided which has a remarkably improved strength in an anti-fogging coating film thereof, inhibiting coating film breakage during the forming, and which exerts excellent anti-fogging effects even in the case of a deep drawn formed articles and can prevent transfer of the anti-fogging coating film to the opposite surface when the anti-fogging thermoplastic resin sheet is wound in a roll. A formed article having excellent anti-fogging effects is also provided. A thermoplastic resin sheet comprising polystyrene, a polymer alloy of polystyrene and a rubber, a high-impact styrene resin, a copolymer of styrene and an acrylic monomer, polyolefin, polyethylene terephthalate, polyvinyl chloride or polyvinylidene chloride comprises on the surface thereof an anti-fogging coating film comprising a surfactant (A) and cyclodextrin or a water-soluble compound (B) in which hydroxyl groups of cyclodextrin are modified.
    Type: Application
    Filed: February 6, 2003
    Publication date: December 18, 2003
    Inventors: Hidetsugu Sawada, Tsuyoshi Fukukita, Mamoru Fukuoka
  • Patent number: 6663950
    Abstract: An optically active film composite including a polymeric film substrate coated with a layer of resin having a thickness of less than 6 microns and a pencil hardness of at least 2H, and which includes 30-60% by weight of nanoparticles of ATO or ITO, and nanoparticles of a second metallic compound being an inorganic compound and absorbing light having a wavelength in the range of 700-1100 nm. The composite preferably has a VLT of at least 50% and a %TSER of at least 35% with a weighted UV absorption of less than 1%.
    Type: Grant
    Filed: June 13, 2001
    Date of Patent: December 16, 2003
    Assignee: CPFilms, Inc.
    Inventors: Steven A. Barth, Anthony B. Port, Coby L. Hubbard
  • Patent number: 6663974
    Abstract: Structures of the present invention contain a non-oriented multilayer film with a polyolefin core having 40 weight-percent or less homogeneous ethylene/alpha-olefin, a modified polyolefin tie layer on each side of the core, and an adhesive layer on at least one tie layer. The adhesive layer contains a polar-modified polyolefin and a polyester, copolyester, or polyester/copolyester blend. The multilayer film has utility as a protective coating for metal surfaces.
    Type: Grant
    Filed: September 29, 2001
    Date of Patent: December 16, 2003
    Assignee: Dow Global Technology Inc.
    Inventors: Robert H. Kelch, Robert L. McGee
  • Patent number: 6656561
    Abstract: A composite solid surface article which includes a molded overlay composed of a solid surface material fabricated in a mold; an underlay core material composed of a polymeric material molded onto the overlay but which only covers a center portion of the overlay so that peripheral edges of the overlay are not covered by the underlay core material; and solid surface edge component of additional solid surface material at the edge of the underlay core material, and a method of making the composite using a removable liner.
    Type: Grant
    Filed: May 30, 2001
    Date of Patent: December 2, 2003
    Inventor: Vangala Bala Venkata Subbulu
  • Patent number: 6656601
    Abstract: The adhesive ethylene copolymer composition of the invention comprises a specific long-chain branched ethylene/&agr;-olefin copolymer (or this copolymer and its graft-modified product) and a tackifier (or a specific ethylene/vinyl acetate copolymer), and has specific density, MFR, crystallinity and graft quantity. The composition containing the tackifier can form a layer having good adhesive force to polystyrene resins, ABS resin, polyacrylonitrile resins and ethylene/vinyl acetate copolymer saponified resins even in an atmosphere of high temperatures. The composition containing the ethylene/vinyl acetate copolymer can form a layer having good adhesive force to polyester resins, polycarbonate resins, polyvinylidene chloride resins and ethylene/vinyl acetate saponified resins even in an atmosphere of high temperatures. The other adhesive ethylene copolymer composition of the invention comprises a blend of a graft-modified linear ethylene/&agr;-olefin copolymer and an olefin elastomer.
    Type: Grant
    Filed: October 10, 2000
    Date of Patent: December 2, 2003
    Assignee: Mitsui Chemicals Inc.
    Inventors: Hideshi Kawachi, Yuji Sawada, Haruhiko Tanaka
  • Patent number: 6652961
    Abstract: A biaxially oriented polyester film with a substantially non-crosslinked polymeric coating containing styrene and acrylate, wherein the coating is highly thermally stable with a primary onset temperature of greater than about 350C, having a glass transition temperature between about 0C and about 50C, having a solubility in a low molecular weight organic solvent, and having a surface energy of greater than about 35 dyne/cm and less than about 40 dyne/cm.
    Type: Grant
    Filed: November 7, 2002
    Date of Patent: November 25, 2003
    Assignee: Toray Plastics (America), Inc.
    Inventors: Steven J. Sargeant, Yasushi Takada, Masaaki Sudo, John Fitch
  • Patent number: 6653415
    Abstract: The invention relates to a method for producing defined layers or layer systems made of polymers or oligomers on any solid surface and with a controlled structure, according to which the layers are chemically deposited on the solid surface by means of live/controlled free-radical polymerization. Said method comprises the following steps: a) bonding the compounds of the general formula (a) A—L—I to the solid surface via the active group A where A represents an active group, I is the initiating group for ATRP polymerization and L is the binding link between A and I; b) carrying out live/controlled free-radical polymerization by reacting the initiator group I with monomers, macromonomers or mixtures able to undergo free-radical polymerization, which produces the polymer layer on the solid surface. The invention also relates to solid surfaces with oligomer or polymer layers and initiators for carrying out the method.
    Type: Grant
    Filed: February 22, 2001
    Date of Patent: November 25, 2003
    Inventors: Henrik Böttcher, Hellmuth Wurm, Manfred L. Hallensleben
  • Patent number: 6652984
    Abstract: A paper-plastic laminate sheeting capable of being converted by conventional equipment into envelopes, grocery bags and other dilatable container products that initially are in a flat state and are normally made of paper. The sheeting is composed of a paper facing sheet cold-laminated by means of a water-based adhesive to a reinforcing film of synthetic plastic material, such as polypropylene. The film is oriented to impart exceptional tear and burst strength characteristics to the resultant waterproof product. The product, whose exterior surface is formed by the paper facing sheet, is readily printable. For some applications, a second paper facing sheet is cold-laminated to the other side of the film to produce a three-ply laminate sheeting whose exposed surfaces are readily printable and can accept conventional adhesives.
    Type: Grant
    Filed: June 10, 2002
    Date of Patent: November 25, 2003
    Inventors: Arnold B. Finestone, Gilbert Bloch
  • Publication number: 20030215656
    Abstract: A process for reducing the haze of extrusions of clear polymeric blends containing styrene-butadiene copolymer and a polymer immiscible therewith. An assembly of extrusion layers in which a layer of clear polymeric blends containing styrene/butadiene copolymer and a polymer immiscible therewith is overlayered with layers of clear material that provides a smooth extruded surface.
    Type: Application
    Filed: June 19, 2003
    Publication date: November 20, 2003
    Applicant: Phillips Petroleum Company
    Inventors: Mark D. Hanes, Lee A. Carvell
  • Publication number: 20030215645
    Abstract: The strength of wood composites, including hybrid composites comprising wood members bonded to reinforced polyester members, is improved by modifying the polyester components with a polyisocyanate. Wood composites adhesively bonded with polyester resins modified according to this invention are particularly desirable for use in applications where exterior exposure is contemplated.
    Type: Application
    Filed: May 17, 2002
    Publication date: November 20, 2003
    Inventor: Ben R. Bogner
  • Publication number: 20030215655
    Abstract: Improved multi-layer coextruded blow-molded objects (such as fuel containers) having at least a barrier layer and a support layer are disclosed together with improved methods for preparing such objects. The barrier layer includes an amount of modified polyolefin having approximately the same density as the support layer, wherein the modified polyolefin is prepared by grafting an unsaturated carboxylic acid or a derivative thereof to the polyolefin, the modified polyolefin being added in an amount such that the gas-barrier layer sufficiently adheres to the adjacent layer and such that the gas barrier properties of the fabricated article are still adequate. The present invention also relates to modification of the rheology of base resins, such as PET (a preferred material for the barrier layer), so that they more closely match the rheology of high density polyethylene (a preferred material for the support layer).
    Type: Application
    Filed: November 1, 2002
    Publication date: November 20, 2003
    Inventors: Mark A. Barger, Joseph A. Schomaker, Ravi Ramanathan, Malcolm F. Finlayson, Chuiwah A. Cheung, Kalyan Sehanobish
  • Patent number: 6649250
    Abstract: This invention relates to an imaging element comprising a base polyester layer, an absorbent polyester layer above said base layer, and a glossy polymer layer above said absorbent layer; wherein said element has a 60° Gardner gloss greater than 30% wherein said glossy polymer layer has openings comprising between 5.0 and 10.
    Type: Grant
    Filed: October 11, 2001
    Date of Patent: November 18, 2003
    Assignee: Eastman Kodak Company
    Inventors: Thomas M. Laney, Cathy Fleischer
  • Patent number: 6649260
    Abstract: An optical coating film in accordance with the present invention makes it possible to prevent the generation of scratches having a size of a specific size or more, thus, since it becomes possible to reduce optical defects caused by the scratches, the optical coating film is suitably applicable to a base film for a prism sheet, an anti-reflection sheet and a hard coating film used for liquid crystal display, a base film for a near infrared ray absorbing film used for a front panel of a plasma display, a base film for a transparent conductive film used for touch panels and electro-luminescence or an anti-destruction film for cathode ray tube.
    Type: Grant
    Filed: December 6, 2001
    Date of Patent: November 18, 2003
    Assignee: Toyo Boseki Kabushiki Kaisha
    Inventors: Katsufumi Kumano, Naonobu Oda, Akira Ito
  • Publication number: 20030211346
    Abstract: This invention provides a water-based composition suitable for use on polyester-based substrates for increasing adhesion between the substrate and a topcoat or overcoat. The composition comprises: (1) a latex polymer formed from the polymerization of at least one monomer selected from the group consisting of bicyclic alkyl (meth)acrylates and aromatic (meth)acrylates and at least one monomer which imparts to the polymer the ability to be crosslinked; (2) a water soluble or water dispersible polymer selected from the group consisting of acrylate-based resins, sulfonated polyester-based resins and combinations thereof; and (3) a crosslinking agent.
    Type: Application
    Filed: September 25, 2001
    Publication date: November 13, 2003
    Applicant: 3M Innovative Properties Company
    Inventor: William L. Kausch
  • Publication number: 20030211347
    Abstract: A composite layered plastic article particularly resistant to outdoor exposure to heat, sunlight and UV degradation comprises a top surface exposed layer of PETG fused to a rigid substrate layer selected from PVC, or CPVC, or HIPS, or ABS, or ASA, or PC. The PETG layer is preferably co-extruded with the substrate layer and heat fused together to produce a laminated layered composite article.
    Type: Application
    Filed: May 7, 2002
    Publication date: November 13, 2003
    Applicant: PolyOne Corporation
    Inventors: Elvira B. Rabinovitch, James W. Summers
  • Publication number: 20030207973
    Abstract: A thermoplastic resin composition for an electrical/electronic contact part according to the present invention includes a thermoplastic resin and a polyol, wherein the polyol is contained in a range of 0.2 to 10 parts by weight based on 100 parts by weight of the thermoplastic resin. Alternatively, a thermoplastic resin composition for an electrical/electronic contact part according to the present invention includes: a thermoplastic resin; a halogenated aromatic compound which is contained in a range of 1 to 50 parts by weight based on 100 parts by weight of the thermoplastic resin; and a double salt represented by at least one of (X2O)n.Sb2O5 and (YO)n.Sb2O5, where X represents a monovalent alkaline metal element, and Y represents a divalent alkaline earth metal element, and n represents a ratio of X2O or YO to Sb2O5 exceeding 0.7, the double salt having an adsorbed water elimination rate of not more than 50 min.
    Type: Application
    Filed: April 4, 2003
    Publication date: November 6, 2003
    Applicants: OMRON CORPORATION, MITSUBISHI ENGINEERING-PLASTICS CORPORATION
    Inventors: Yutaka Takenaka, Kenji Funaki, Toshiyuki Furuya, Shigeru Muramatsu, Yoshitaka Kanazawa, Osamu Kimura
  • Patent number: 6638588
    Abstract: A multilayer permeable film structure having high temperature capabilities comprising a first, perforated sealable layer; a second primer layer and a third outer layer is disclosed. The multilayer permeable film structure can be heat sealed to a formed tray containing a volatile material.
    Type: Grant
    Filed: June 16, 2000
    Date of Patent: October 28, 2003
    Assignee: Pechiney Emballage Flexible Europe
    Inventors: William E. Bowen, Michael Stecker
  • Patent number: 6635340
    Abstract: The present application relates to a white, biaxially oriented, flame-retardant polyester film with at least one base layer which comprises, based on the weight of the base layer, from 2 to 60% by weight of a cycloolefin copolymer (COC), where the glass transition temperature of the COC is within the range from 70 to 270° C. The film also comprises from 0.5 to 30% by weight of flame retardant, based on the weight of the layer comprising the flame retardant. The film of the invention is suitable for packing foods or other consumable items which are sensitive to light and/or to air, or for use in industry, e.g. in the production of hot-stamping foils or as a label film, or for image-recording papers, printed sheets or magnetic recording cards.
    Type: Grant
    Filed: February 12, 2001
    Date of Patent: October 21, 2003
    Assignee: Mitsubishi Polyester Film GmbH
    Inventors: Herbert Peiffer, Klaus Oberlaender, Gottfried Hilkert, Ursula Murschall
  • Patent number: 6632518
    Abstract: Fluoropolymer films which combine the attributes of outdoor durability, chemical resistance and thermoformability with paint-like aesthetics are formed into film structures which have at least one surface coated with a primer of amine functional polymer and an overcoat of a thermoplastic adhesive of acid modified polyolefin. Fluoropolymer films so coated are securely bonded to a variety of thermoplastic substrates forming a laminated film structure which resists delamination when exposed to moisture and humidity.
    Type: Grant
    Filed: October 6, 1999
    Date of Patent: October 14, 2003
    Assignee: E. I. du Pont de Nemours and Company
    Inventors: James John Schmidt, Larry Glen Snow
  • Patent number: 6632493
    Abstract: Disclosed is a multi-layered plastic container (10) that substantially enhances product drainage and reduces product residual levels trapped in the container, especially for viscous liquid products, including oil-in-water emulsions, water-in-oil emulsions, polymeric gels, foams, surfactant mixtures, dispersions, colloidal dispersions, suspensions, polymer solutions, polymer melts, and products like catsup, mustard, syrup, etc. In a particularly preferred embodiment, the plastic container is made by blow-molding an extruded parison having an outer polyolefin layer (14), an intermediate adhesive layer (18), and an inner product-contacting layer (16) of a polyester material such as glycol-modified polyethylene terephthalate.
    Type: Grant
    Filed: August 3, 2001
    Date of Patent: October 14, 2003
    Assignee: The Procter & Gamble Company
    Inventors: Richard Emil Hildebrand, IV, Robert Joseph Kissner, Pauline Cruz Zamora, Tomokazu Hattori, Hiroshi Furumichi
  • Patent number: 6627308
    Abstract: The present invention relates to a release film comprising: a polyester film; a coating layer formed on one surface of said polyester film; and a release layer formed on a surface of said coating layer which exhibits a residual adhesion rate of not less than 80%, said release film satisfying all of the conditions represented by the following formulae (1) to (3): OL≦0.6 (1) TL≧80 (2) TL(H)≦8 (3)  wherein OL is an amount (mg/m2) of oligomers extracted with dimethylformamide from a surface of said release layer after the release film is heat-treated at a temperature of 180° C. for 10 minutes; TL is a total light transmittance (%) of said release film; and TL(H) is a total light transmittance (%) of a laminate prepared by interposing said release film between two polarizing plates disposed in a perpendicular relation to each other.
    Type: Grant
    Filed: April 3, 2001
    Date of Patent: September 30, 2003
    Assignee: Mitsubishi Polyester Films Corporation
    Inventors: Kimihiro Isaki, Masashi Inagaki
  • Patent number: 6623821
    Abstract: The invention provides a packaging film comprising a heat-shrinkable, heat-sealable polyester shrink film. The film comprises a homopolymer or copolymer of polyethylene terephthalate, preferably coated with a solvent-based, heat-seal coating, e.g., an amorphous copolyester. The film may be metallized and/or laminated to other films, e.g., ionomer films.
    Type: Grant
    Filed: January 31, 2000
    Date of Patent: September 23, 2003
    Assignee: E. I. du Pont de Nemours and Company
    Inventor: Terrance D. Kendig
  • Publication number: 20030175537
    Abstract: A film which is a biaxially oriented film comprising polyethylene-2,6-naphthalenedicaboxylate as a principal component, having a thermal strain; ratio RMD (150) in the machine direction of the film at a temperature of 150° C. is −1.5%≦RMD (150)≦0.0% when the thermal strain ratio RMD (T) in the machine direction of the film at a temperature T° C. based on the length LMD (t) in the machine direction (MD) of the film at a temperature t ° C.
    Type: Application
    Filed: July 30, 2002
    Publication date: September 18, 2003
    Inventors: Koji Furuya, Hiroshi Kusume
  • Patent number: 6620492
    Abstract: A laminate is provided made of two film materials with different tear resistance values, particularly made of polyester and polyethylene. The part of the laminate made from a film material with a high tear resistance is structured in multiple layers and has at least two layers made from this high tear resistance material connected with one another by an adhesive layer with a low shear resistance. This structure results in a laminate having improved tear resistance.
    Type: Grant
    Filed: January 14, 2003
    Date of Patent: September 16, 2003
    Assignee: Nordenia USA, Inc.
    Inventor: Michael E. Winkler
  • Patent number: 6620473
    Abstract: An in-mold decorating label, which comprises a thermoplastic resin film substrate layer (I) having provided on its backside a heat-sealable resin layer (II), the heat-sealable resin layer (II) containing a polyethylenic resin and at least one of (i) a fatty acid amide having a molecular weight of 300 or more and (ii) an organic or inorganic fine powder having an average particle size larger than thickness of the heat-sealable resin layer (II). This label for use in in-mold decorating has excellent feeding and discharging properties upon printing and workability during sheeting, which facilitates insertion of the label into a metal mold during in-mold decorating, and provides a label-laminated container which does not suffer from blister generation and has a large welding force between the container and the label.
    Type: Grant
    Filed: April 16, 2001
    Date of Patent: September 16, 2003
    Assignee: Yupo Corporation
    Inventors: Takatoshi Nishizawa, Masaki Shiina, Hironobu Taniguchi
  • Patent number: 6620474
    Abstract: Multilayer films comprising a quiet film layer having noise dampening properties and at least one second layer which are particularly useful for, ostomy bags (colostomy, ileostomy), trans-dermal delivery systems (TDDS), cosmetic patches, incontinence bags, medical collection bags, parenteral solution bags, and food packaging, as well as for protective clothing and soil fumigation applications. The quiet layer comprises a polymer resin or polymer resin composition having a Tangent Delta value of at least 0.25 at a temperature within the range of −5° C. and 15° C. or at least 0.32 at a temperature within the range of −12° C. to −5° C., and the at least one second layer has a storage modulus G′ equal to or greater than 2×104 N/cm2.
    Type: Grant
    Filed: September 20, 2002
    Date of Patent: September 16, 2003
    Assignee: Dow Global Technologies Inc.
    Inventors: Francois J. F. Regnier, Harvey C. Tung, Rochelle A. Woods, Jeffrey E. Bonekamp
  • Publication number: 20030170476
    Abstract: The invention relates to biaxially orientated, co-extruded polyester films, which have at least one base layer that contains a thermoplastic polyester, preferably polyethylene terephthalate and approx. 2 to 60 wt.-% of a cyclo-olefin copolymer that is preferably composed of norbornene and ethylene units and which have at least one cover layer that is devoid of a COC and which optionally have additional cover or intermediate layers and can contain conventional additives such as stabilisers and anti-blocking agents. Said films are characterised in particular by a degree of whiteness>70 %, an opacity>55 % and a gloss, (at least on one<side)>100 and are therefore suitable for numerous industrial applications. During the production of the films in accordance with the co-extrusion process, up to 70 wt.-% of reclaimed product can be used, without having a noticeable negative effect on the physical properties of the film.
    Type: Application
    Filed: November 20, 2002
    Publication date: September 11, 2003
    Inventors: Ursula Murschall, Cynthia Bennett, Ulrich Kern, Herbert Peiffer
  • Patent number: 6616998
    Abstract: A heat sealable packaging film producing a peelable seal is formed from a blend of 99 to 75 weight percent of a copolyester and 1 to 25 weight percent of an epoxy-containing impact modifying polymer. The copolyester has a diacid component of at least 50 mole percent terephthalic acid, naphthalenedicarboxylic acid, 1,4-cyclohexanedicarboxylic acid, or mixtures thereof and diol component of about 90 to 35 mole percent ethylene glycol and 10 to 65 mole percent of at least one of diethylene glycol or 1,4-cyclohexanedimethanol.
    Type: Grant
    Filed: April 2, 2001
    Date of Patent: September 9, 2003
    Assignee: Eastman Chemical Company
    Inventors: Kathleen Diane Greer, James Edward Rhein, Hubertus Jacobus Wilhelmus Moolenaar, Scott Ellery George, Richard Leon McConnell
  • Publication number: 20030165753
    Abstract: Disclosed are a thermally transferable image protective sheet and a method for protective layer formation that can provide a protective layer which can protect an image of a record produced by a nonsilver photographic color hard copy recording method, can impart lightfastness and other properties to the record, and can realize a record having a glossy impression comparable to silver salt photographs. The thermally transferable image protective sheet comprises a support and a thermally transferable resin layer having a single-layer or multilayer structure stacked on the support so as to be separable from the support.
    Type: Application
    Filed: February 28, 2003
    Publication date: September 4, 2003
    Applicant: Dai Nippon Prtg. Co., Ltd.
    Inventors: Taro Suzuki, Daisuke Fukui, Masahiro Fujita
  • Publication number: 20030165700
    Abstract: A laminated polyester film excellent in blocking resistance and processing suitability and exhibiting excellent electromagnetic transducing characteristics and excellent travel durability, when processed into a magnetic recording medium, and an electromagnetic recording medium using the laminated polyester film as a base film, are provided.
    Type: Application
    Filed: December 3, 2002
    Publication date: September 4, 2003
    Inventors: Masahiko Kosuge, Hirofumi Murooka, Takeshi Ishida
  • Patent number: 6613412
    Abstract: The invention relates to a hot peel carrier for decorative graphics and lettering applied to a substrate wherein the carrier has a film having opposite surfaces and an adhesive having a peel strength which decreases with increasing temperature, the adhesive being on a surface of the plastic film. The invention also provides a laminate for use in applying graphics to a substrate which incorporates the carrier, methods of using and methods of using the carrier and laminate disclosed herein. The various embodiments disclosed herein incorporating the aforementioned hot peel carrier have significant advantages stemming from the fact that immediate after a graphic is heat applied to a substrate, the adhesive of the carrier has substantially no adhesion to either the substrate or to the heated adhered graphic.
    Type: Grant
    Filed: April 24, 1997
    Date of Patent: September 2, 2003
    Assignee: Stahl's Inc.
    Inventor: Donald R. Dressler
  • Patent number: 6613426
    Abstract: A very fine anti-glare hard coat film which comprises a base film and a hard coat layer disposed on the base film and has a haze of 3% or greater, wherein the hard coat layer comprises (A) a resin cured by an ionizing radiation and, per 100 parts by weight of the resin, 2 to 25 parts by weight of (B) silica particles having an average diameter of 0.5 to 5 &mgr;m and 10 to 200 parts by weight of (C) fine particles having an average diameter of 1 to 60 nm. The very fine anti-glare hard coat film provides excellent visibility when the film is used for various types of displays since the film provides an excellent anti-glare property to the displays such as very fine liquid crystal displays without deterioration in the quality of displayed images.
    Type: Grant
    Filed: June 4, 2001
    Date of Patent: September 2, 2003
    Assignee: Lintec Corporation
    Inventors: Yutaka Onozawa, Shigenobu Maruoka, Satoru Shoshi
  • Publication number: 20030162043
    Abstract: An abrasion resistant coated film including a polyester film coated with a highly crosslinkable melamine coating with a crosslinking density of greater than about 50% and less than about 100%, wherein the coating is cured after transverse stretching and heat setting the film, a melamine coating having a crosslinking density between about 50% and about 100% containing between about 0.01% by weight and about 1.0% by weight of a colloidal particle selected from the group consisting of silica, TiO2, graphite and blends thereof, and a method of producing an abrasion resistant coated film including stretching a polyester film in the machine direction to form a uniaxially oriented film, applying a coating of highly crosslinkable melamine with a crosslinking density between about 50% and about 100% onto the uniaxially oriented film, heating and stretching the coated film in the transverse direction and curing the coating on the coated film.
    Type: Application
    Filed: February 21, 2002
    Publication date: August 28, 2003
    Inventors: John Fitch, Steven J. Sargeant
  • Patent number: 6610392
    Abstract: A heat-shrinkable multilayer film comprises (A) a first layer, which is an outer layer, and which comprises polyolefin; (B) a second layer comprising at least one member selected from the group consisting of polyolefin, polystyrene, and polyurethane; (C) a third layer comprising at least one member selected from the group consisting of amorphous polyester and polyester having a melting point of from about 130° C. to about 260° C.; (D) a fourth layer, which is an outer layer, the fourth layer comprising at least one member selected from the group consisting of polyester, polyamide and polyurethane. The first layer preferably serves as a seal layer in a heat-shrinkable bag. The third layer provides enhanced impact strength, optics, grease-resistance, and free-shrink of the film, and renders the tape more easily orientable.
    Type: Grant
    Filed: March 4, 1998
    Date of Patent: August 26, 2003
    Assignee: Cryovac, Inc.
    Inventors: Ram K. Ramesh, John R. Wolf, George D. Wofford
  • Publication number: 20030157352
    Abstract: The invention relates to a co-extruded, biaxially oriented polyester film consisting of a base layer and at least one outer layer. The film contains a UV-stabiliser and has a matt outer layer which contains a mixture and/or a blend of two components (I) and (II), whereby component (I) is substantially a polyethylene terephtalate homopolymer or a polyethylene terephthalate copolymer, or a mixture of polyethylene terephtalate homopolymers or polyethylene terephthalate copolymers, and component (II) is a polymer which contains at least one sulphonate group.
    Type: Application
    Filed: July 18, 2002
    Publication date: August 21, 2003
    Inventors: Ursula Murschall, Ulrich Kern, Guenther Crass, Gottfried Hilkert
  • Patent number: 6607834
    Abstract: Polyester-containing multilayer biaxially-oriented polypropylene films are provided. According to the invention, a two- or three-layer polyester-containing cap layer is bonded to a monoaxially oriented polypropylene core, followed by orientation of the resulting composite in a direction transverse to the direction of orientation of the core layer. At least one tie layer is interposed between the core and the polyester. Advantageously, the polyester contains silicone fluid as a processing aid.
    Type: Grant
    Filed: March 7, 2001
    Date of Patent: August 19, 2003
    Assignee: Applied Extrusion Technologies, Inc.
    Inventors: Alan M. Davis, John H. Lawrence, Tung-Yao Weng