Abstract: A process for bonding lignocellulosic material under heat and pressure, where the bonded lignocellulosic material is characterized by a low emission of formaldehyde, which comprises applying a binder to said lignocellulosic material, said binder comprising a urea-formaldehyde base resin having a ratio of formaldehyde to urea of 1.0:1-1.2:1, said base resin having essentially no free formaldehyde and said base resin when cured containing substantially more methylene groups than methylene ether groups, consolidating said lignocellulosic material and curing the binder.

Abstract: Amino-formaldehyde products with activated carboxylic ester groups cross-link compounds containing pendant primary or secondary amine groups.This is a continuation, of application Ser. No. 232,455, filed Feb. 9, 1981, which is a continuation of Ser. No. 128,613, filed 3/10/80, which is a division of Ser. No. 32,982, filed 4/25/79, which is a continuation-in-part of Ser. No. 926,762, filed 7/21/78, all now abandoned.

Abstract: Aqueous dispersions of a phenolic resole and a thermoplastics polymeric material or a rubber, suitable for use as adhesives, are prepared by(a) dissolving a solid thermoplastics polymeric material, such as a polyvinyl acetal or a nylon polyamide, or rubber in a phenol,(b) adding a nonionic or anionic surface active agent and/or protective colloid,(c) adjusting the mixture to a pH above 7 by addition of a base,(d) adding aqueous formaldehyde solution, or a formaldehyde donor, to a molar ratio of phenol to formaldehyde within the range 1:1 to 1:3,(e) if necessary, adding water, and(f) heating the mixture to form a phenolic resole.

Abstract: A novel magnet wire or other coated filament comprising an elongated filament with a surprisingly concentric and continuous coating superimposed thereupon. The coating may be applied to the desired thickness in a single pass.

Abstract: This invention relates to a novel group of plasticizers for polyvinyl butyral wherein the plasticizer comprises a mixture of at least one triethylene glycol diester of a monocarboxylic acid having a carbon chain comprising 7 or 8 carbon atoms and at least one dialkyl adipate in which the alkyl group contains from 3 to 8 carbon atoms or at least one alkyl alkylaryl adipate.

Abstract: Water reducible compositions useful as coating compositions for flexible substrates are prepard by reacting a glycidyl polyether of a dihydric phenol with a polyethylene glycol and ortho phosphoric acid.

Abstract: A polyacetal resin molded article having reduced water contamination is disclosed. The water contamination reduction feature is provided by the inclusion of a substantially water insoluble substance which forms a hydrophobic film on the molded article. It is furthermore required that the water insoluble substance-included polyacetal molded article be heat treated in air or in an inert gas to provide reduced water contamination.

Abstract: Amino-formaldehyde products with activated carboxylic ester groups cross-link compounds containing pendant primary or secondary amine groups.

Abstract: A graphics-bearing element is provided in which improved durability in liquid environments is provided through inclusion in a graphics layer of polyvinyl formal resin.

Abstract: The present invention relates to indirectly metallized labels for containers, such as bottles, coated with a lacquer that has been applied before metallizing, comprising 2 to 10 weight % (calculated on the amount of resin of said lacquer) of additives, which do not attack the metal of said labels and which are soluble in an aqueous caustic soda solution, containing 1.5 weight % of caustic soda, having a temperature of 80.degree. C.

Abstract: Polyglutaraldehyde (PGL) is polymerized in aqueous base or in aqueous highly polar solvent basic media to prepare powders, castable films or coatings for substrates such as amine substituted microbeads. PGL microspheres can be prepared by suspension polymerization in presence of a surfactant or by precipitating PGL from solution containing surfactant. Magnetic PGL microspheres are formed by suspension polymerization in the presence of magnetic particles such as iron oxide. Polyglutaraldehyde can be converted to a fluorescent polymer by reaction with m-aminophenol or other reagent. Proteins can be readily covalently bound to the polyglutaraldehyde.

Abstract: Dispersions containing (a) a pigment, (b) an oxalkylated novolak, (c) urea and/or a compound containing at least 2 long-chain aliphatic groups and which are connected via a bridge member containing ester and/or amide groups, and (d) water and/or agents retarding drying up, and, optionally, usual adjuvants, are useful for pigmenting natural or synthetic materials, especially aqueous systems containing cellulose ethers.

Abstract: There are obtained laminates of improved fire resistance comprising a substrate of reinforced phenolic resin, directly coated on at least one side thereof with a surface layer of a furan resin, and bonded to the outer surface of the furan resin a "gel-coat" of an unsaturated polyester resin, wherein the furan resin contains boron in sufficient amounts to impart an improved fire resistance to the laminates as compared to the fire resistance of the outer surface gel-coat. The boron is introduced as boric anhydride by use of a substantially anhydrous boric anhydride hardener solution to harden the furan resin.

Abstract: A coated plastic film possessing good printability slip properties, oxygen and moisture barrier properties and transparency which comprises applying to a plastic film a coating solution of a thermoplastic resin as base resin in which a synthetic resin of a network structure having a softening temperature above 100.degree. C. and being in the form of a fine powder are added, and drying thereafter.

Abstract: A plasticizer-containing film of a partially acetalized polyvinyl alcohol resin contains as the plasticizer a mixture of an ester of an organic cyclic acid and/or a conventional acetal plasticizer for said resin, and an ester of an oxygen acid of phosphorus.

Abstract: A thermosetting synthetic crosslinking resin containing selected ethers of the reaction product of an isoadipoguanamine mixture and formaldehyde can be incorporated into a variety of coating compositions to provide finishes that are characterized by hardness, flexibility, durability, excellent adhesion, and commercially-acceptable cure temperatures.

Abstract: A resin prepared by acid-catalytic condensation of p-phenylphenol with formaldehyde in the presence of an alcohol having a boiling point of 70.degree. C. or more is improved in solubility in various solvents, especially in ethyl acetate, polyethylene glycol and oil, and is useful as an acidic substance in No Carbon copying paper, which gives an intense color with higher speed, especially in the form of spot ink in flexographic printing or gravure printing.

Abstract: A photo-hardenable adhesive composition particularly suitable for use in the bonding of glass to other materials, especially plastics, as in the production of safety glass and armored glass laminates and comprising(A) a photopolymerizable ester of an .alpha.,.beta.-ethylenically unsaturated acid and a hydroxylated urethane or urea and having a molecular weight of 500 to 10,000(B) a photoinitiator(C) a substituted or unsubstituted aliphatic or cycloaliphatic N,N-dialkylamino alcohol ester of an .alpha.,.beta.-ethylenically unsaturated carboxylic acid, said alcohol having an alkylene moiety of up to six carbon atoms between hydroxy and the amino functions, and(D) an .alpha.,.beta.-ethylenically unsaturated carboxylic acid in an amount equal to one mole per mole of C, (C) and (D) being capable of reacting together to form a betaine, and preferably(E) at least one further copolymerizable monomer or oligomer and which may comprise an excess of (C) or (D) over equimolar.

Abstract: A thermosensitive recording material comprising a matrix of an electrically insulating, film-forming thermoplastic resin and dispersed as a fine powder in the matrix, a linear aliphatic dicarboxylic acid having at least 13 carbon atoms or its ammonium salt, and a thermosensitive electrostatic recording material provided by applying aforesaid material to the conductive surface of a thermally stable substrate.

Abstract: A packaging material which is capable of packaging an article(s) in a closely fitted and tightly sealed state and consists essentially of a composite film stretched at least in one direction,said composite film comprising a base film and a surface film provided on at least one surface of the base film and having certain specific shrinkage characteristics,said base film being made of a resin composition comprising a propylene polymer, andsaid surface film being made of a polymer composition comprising at least two of (A) a copolymer of propylene and ethylene in a weight proportion of 99.5:0.5 to 90:10, (B) a copolymer of propylene and an .alpha.-olefin having 4 to 10 carbon atoms in a weight proportion of 70:30 to 95:5 and (C) a copolymer of butene and any other .alpha.-olefin having 2 to 10 carbon atoms in a weight proportion of 70:30 to 99:1, each of the copolymers being in an amount of 10 to 90% by weight on the total weight of the copolymers.

Abstract: The invention is directed to biaxially oriented thermoplastic polymer flexible film having a substantially uniform thickness between about 0.005 and 0.030 of an inch (0.13 mm and 0.76 mm) and characterized by a structure comprised of discrete, platelet-like spherulitic crystalline aggregates compressed transversely to the plane of the film and biaxially oriented in the plane of the film and having a combination of improved properties and also to a rigid conduit or extrudate having a plurality of thermoplastic crystalline polymer layers each of which has a unique microstructure and improved properties.

Abstract: Concentrated boric anhydride solutions containing more than 5% of boric anhydride in an organic solvent selected from mono or polyalcohols, trialkylborate and/or dialkylacetal when the solvent also contains an acid selected from sulfuric acid and/or aromatic acids. These solutions are used as hardeners of formo-phenolic resols, more particularly for the manufacture of laminates comprising glass fibers and formo-phenolic resols.

Abstract: A pressure-sensitive or heat-sensitive recording material which contains in its color reactant system, as developer for the color former, at least one compound of the formula ##STR1## wherein X is the direct bond or ##STR2## each of R.sub.1, R.sub.2 and R.sub.3 independently is hydrogen or unsubstituted or substituted alkyl, aryl or aralkyl, or R.sub.1 and R.sub.3, together with the nitrogen atom to which they are attached, are a 5- or 6-membered heterocyclic radical, Q is carbon or an unsubstituted or substituted hydrocarbon radical, Y is halogen, and m is 1 to 3. The grouping --Q--Y.sub.m is preferably --C(Hal).sub.3, wherein Hal is halogen.

Abstract: Highly fire resistant composites or laminates particularly applicable as structural components in aircraft, e.g. in the engine nacelle, as part of the acoustic panel-fire wall structure, and capable of withstanding a 2,000.degree. F. flame temperature, comprising incorporating an additive in the form of an ammonium salt, or an amine salt, of a phosphonic acid or a phosphinic acid, into a resin, e.g., a polyimide or an epoxy resin, such additive being soluble in the resin. The resulting resin containing the additive, e.g., the ammonium, or amine, salt of phenyl phosphonic or phenyl phosphinic acid, is then applied to or impregnated into a substrate such as glass fiber cloth or graphite fiber, to form a composite structure which is then cured. The resulting cured composite when subjected to high temperatures of the order of, e.g., a 2,000.degree. F.

Abstract: Coating compositions comprising an unsaturated oil modified resin and an unsaturated melamine condensate. The unsaturated melamine condensate is a condensate of a methylolmelamine, an acrylamide, an ethylenically unsaturated fatty acid amide and optionally a C.sub.1 to C.sub.10 alcohol, wherein the methylolmelamine has at least about 5 methylol groups per melamine ring, wherein substantially all the methylol groups are condensed with the acrylamide, the unsaturated fatty acid amide or the alcohol, wherein the number of the acrylamide moieties of the condensate is in the range of about 1 to about 4 per melamine ring and the number of unsaturated fatty acid amide moieties is in the range of about 0.5 to about 2 per melamine ring, wherein the ratio of the acrylamide moieties to unsaturated fatty acid amide moieties is in the range of about 1:1 to about 3:1.

Abstract: A polyester film coated with an antistatic coating is provided. The film includes a polyester film support coated on at least one side with a latex coating. The coating includes stearamidopropyldimethyl-.beta.-hydroxy-ethylammonium nitrate present in a concentration in the range of between about 2.75 percent and 3.25 percent by weight, based on the total weight of the latex coating. The coating further includes a cross-linkable methylmethacrylate-ethylacrylate-methacrylamide terpolymer having a glass transition temperature in the range of between about 40.degree. C. and 50.degree. C. The terpolymer is present in a concentration in the range of between about 0.75 percent and 1.25 percent by weight, based on the total weight of the latex coating. The weight ratio of the nitrate to the terpolymer ranges between about 2.75:1 to below 3:1.A process for forming the above film is also disclosed.

Abstract: A polyester film coated with a slip composition is provided. The film includes a polyester film support coated on at least one side with a latex coating. The coating includes stearamidopropyldimethyl-.beta.-hydroxy-ethylammonium nitrate present in a coating weight in the range of up to 0.003 pounds per thousand square feet of biaxially oriented polyester film. The coating further includes a cross-linkable methylmethacrylate-ethylacrylate-methacrylamide terpolymer having a glass transition temperature in the range of between about 40.degree. C. and 50.degree. C. The terpolymer is present in a concentration in the range of between about 0.75 percent and 1.25 percent by weight, based on the total weight of the latex coating. The weight ratio of the nitrate to the terpolymer ranges between about 2.75:1 to below 3:1.A process for forming the above film is also disclosed. In this process a latex coating of the composition described above is coated onto a uniaxially drawn polyester film support.

Abstract: A method of producing an improved mineral board and the resulting product are disclosed. According to the present invention, the board is predominantly composed of perlite and a binder therefor, preferably urea-formaldehyde resin. The perlite is crushed after the composition is in its final shape but before the binder is set whereby its strength is substantially increased. The composition and process of making the board substantially reduce energy costs as compared to known methods for making wet-process mineral boards. The product composition may include up to 95% perlite by weight.

Abstract: A heat and pressure consolidated laminate in which the back most sheet has fused thereto a surface film composition of polyvinyl alcohol, animal glue or starch which serves as a glue line to which conventional glues adhere, the film being adhered to the back most sheet during heat and pressure consolidation of the laminate by transferring the same from a release layer to the back most surface of the laminate and fusing the transferred film to the thermosetting resin impregnated in the back sheet.

Abstract: Laminates of glazing material and polyvinyl butyral plasticized with propylene oxide oligomers.

Abstract: A method for increasing the boron.sup.10 content of a neutron absorbing article, such as one in flat, flexible sheet shape, includes coating a surface of such article with a solidifiable liquid synthetic organic polymeric material, such as a phenol formaldehyde type resin, applying boron carbide particles to the polymeric material and solidifying the polymer, such as by curing to cross-linked permanently set form, so as to hold the neutron absorbing boron carbide particles in place thereon. In highly preferred embodiments of the invention the boron carbide particles applied will extend beyond the surface of the external material and will serve as anchoring means for applications of subsequent coatings and the plurality of coatings, usually after initial partial curing to solidify them and make them form-retaining, will be permanently cross-linked simultaneously.

Abstract: A composition and process for the removal of phenolic resin composites from aluminum and its alloys which results in a minimum of corrosion to said metals. The process uses a solvent solution of nitric acid, a hexavalent chromium and incidental water in the proportions of about 0.01-0.12 moles of hexavalent chromium and 1-1.7 moles of H.sub.2 O per mole HNO.sub.3.

Abstract: Process for the preparation of a phenol resin modified with a liquid polybutadiene which comprises reacting a polybutadiene having a number average molecular weight of 150 to 5,000 with a phenol in the presence of an acid catalyst to obtain a composition which consists of a polybutadiene-phenol adduct and unreacted phenol, in said polybutadiene-phenol adduct, one molecule of phenol per 3 to 8 butadiene units being added to the polybutadiene, and reacting the composition of a polybutadiene-phenol adduct with a formaldehyde in the presence of a basic catalyst, said basic catalyst comprising a primary amine of the formula: R--NH.sub.2 wherein R is a hydrocarbon group having 1 to 20 carbon atoms in an amount of 0.01 to 0.5 mole per 1 mole of the phenol used for the preparation of the composition which is used alone or in combination thereof with other basic compound.

Abstract: The addition of a water-absorbent, finely divided powder to a phenolic resole resin provides a stabilized resin composition which cures in the presence of an acid catalyst at ambient temperatures to a relatively thick coating having a reduced number of defects, e.g., pinholes and blistering. For example, a resole resin composition containing a stabilizing amount of fumed silica can be blended with a mixture of benzene sulfonyl cloride and trichloroacetic acid, applied to a substrate and cured to form an essentially defect-free coating.

Abstract: Films consisting essentially of alpha-olefin polymers, such as normally solid polypropylene consisting essentially of recurring propylene units and having a substantial crystalline polypropylene content, and in particular isotactic polypropylene, are coated with a ketonic resin resulting from the polycondensation of aldehydes with ketones, which coating renders the films readily thermoweldable and/or impervious to gases, vapors and the like. The coated films are useful for the manufacture of containers, covers, small bags, vessels and in general for the manufacture of articles useful in the packaging industry.

Abstract: An electrically heated laminated aircraft glazing including at least two sheets of glass and an interposed non-brittle thermoplastic interlayer. A bus bar and an electrically conducting film are located on the inwardly disposed surface of one of the sheets and the bus bar covered with a thin layer of polyisobutylene resin. Additional layers of polyisobutylene resin are provided between the interlayer material and selected glass areas to prevent delamination and cold chipping of the glazing with subsequent moisture ingress and bus bar failure.

Abstract: In reinforced phenolic resin laminates coated with a surface layer on at least one side, the improvement wherein said surface layer consists essentially of a furan resin coating which is directly bonded to the reinforced phenolic resin laminate, thereby removing surface irregularities in the resultant laminate.

Abstract: A thick-walled, seamless, rigid conduit having a substantially uniform wall thickness which is not less than about 0.5 percent of the outside diameter consisting essentially of an oriented crystalline thermoplastic polymer characterized by a structure comprised of radially compressed discrete, platelet-like spherulitic crystalline aggregates and having a combination of good ultimate tensile strength and low temperature tensile impact strength is described.The conduit is fabricated by solid state hydrostatic extrusion of a substantially non-oriented semi-crystalline thermoplastic polymer preform which may contain up to about 60 weight percent filler. The polymer is substantially simultaneously elongated in both circumferential and axial directions by compressive forces with the circumferential elongation being at least 100 percent.

Abstract: A graphite refractory article having a dense structure with a low porosity, which has a chemical composition consisting essentially of:100 wt. parts of natural flake graphite, as the carbonaceous raw material, comprising at least 70 wt. % flake graphite having a particle size within the range of from 0.1 to 3 mm and up to 30 wt. % flake graphite having a particle size of under 0.1 mm; from 4 to 10 wt. parts of powdery phenol resin as the binder; and, incidental impurities;said graphite refractory article being obtained by press-forming a dry mixture having said chemical composition under a forming pressure of from 700 to 2,000 kg/cm.sup.

Abstract: Air drying compositions comprising an unsaturated oil modified resin and an unsaturated condensate of an alkoxy-methylmelamine, an allylic alcohol and an acrylamide. The unsaturated melamine condensate contains allylic and acrylamide moieties in the ratio of about 3:1 to about 1:3, at least about 0.75 allylic moieties and no more than about 3 acrylamide moieties per melamine ring and a total of allylic and acrylamide moieties in the range of about 2 to about 4 per melamine ring.

Abstract: Yellowing resistant, durable antistatic soil release agent: ##STR1## wherein X is resin moiety having amino nitrogens and 4 to 6 methylenes, each methylene being attached to amino nitrogen;Y.sub.1 is O(C.sub.2 H.sub.4 O).sub.5-20 R.sub.1 ; R.sub.1 is C.sub.1-5 alkyl;Y.sub.2 is O(C.sub.2 H.sub.4 O).sub.5-88 R.sub.2 ; R.sub.2 is C.sub.6-20 alkyl; ##STR2## R.sub.3 is C.sub.4-20 alkyl, C.sub.4-20 alkenyl or benzyl; R.sub.4 is C.sub.1-4 alkyl, A.crclbar. is anion, each of m and n is at least 1 and their sum is 12 to 100;each of a and b is 0 to 2 and their sum is 0 to 2;c is 1 to 2;a plus b plus c is 1 to 4;said agent having HLB of 14.5 to 18.0, Brookfield viscosity (20 weight % aqueous solution viscosity at 20.degree. C.) of 0.250 to 16.000 pascal seconds, electrical resistivity (Keithley Log R) on polyester fabric (20.+-.2% RH, 23.+-.1.degree. C.) less than 13.00 initially and 14.

Abstract: Contrast enhancement filter having first and second transparent glass substrates with first and second surfaces with the first surface of each facing the medium in which the filter is disposed. A sheet-like circular polarizer is provided formed of stretched plastic members covered by layers of cellulose acetate butyrate. The circular polarizer is disposed between the first and second glass substrates and faces the second surfaces of the glass substrates. A dried plastisol primer layer is disposed on the surface of the layers of cellulose acetate butyrate facing the glass substrates. First and second layers of polyvinyl butyral adhesive secure the layers of cellulose acetate butyrate carried by the circular polarizer with the primer layers thereon to the second surfaces of the glass substrates. An anti-reflection coating is disposed on the first surface of the first substrate.

Abstract: A thermally-expandable sealant for joints, cavities or holes, which foams in the event of a fire and thereby effects a seal, comprising as a carrier a fleece or fabric made of glass or plastic, which is coated with a composition based upon expandable graphite and containing, per 100 parts by weight of expandable graphite, 10 to 30 parts by weight of polychlorobutadiene, 1 to 40 parts by weight of an alkylphenol/formaldehyde resin and 1 to 3 parts by weight of stabilizers known per se, and optionally, up to 30 parts by weight of inorganic fibers and up to 80 parts by weight of aluminium hydroxide. A process for sealing joints, cavities or holes using the sealant is also disclosed.

Abstract: A waterproofing sheet material useful for example as a free floating membrane or flashing material in roofing applications, a pond liner, or a gasketing material, composed of from about 15 wt. % to about 80 wt. % of an ingredient selected from the group consisting of:(a) homopolymers of alkadienes and substituted alkadienes(b) addition copolymers of alkadienes with unsaturated monomers(c) homopolymers of alkenes and substituted alkenes selected from the group consisting of polyethylene, chlorosulfonated polyethylene and polyisobutylene(d) resin acids and resin acid derivatives(e) highly aromatic bituminous materials, and(f) pine oiland from about 85 wt. % to about 20 wt. % of a plasticized polyvinyl butyral resin. Minor amounts of fatty acids and paraffin wax may be added to improve low temperature properties and to facilitate processing a hot melt admixture of the ingredients into a sheet.

Abstract: A waterproofing sheet material useful for example as a free floating membrane or flashing material in roofing applications, a pond liner, or a gasketing material, composed of from about 15 wt. % to about 80 wt. % of an ingredient selected from the group consisting of:(a) homopolymers of alkadienes and substituted alkadienes(b) addition copolymers of alkadienes with unsaturated monomers(c) homopolymers of alkenes and substituted alkenes selected from the group consisting of polyethylene, chlorosulfonated polyethylene and polyisobutylene(d) resin acids and resin acid derivatives(e) highly aromatic bituminous materials, and(f) pine oiland from about 85 wt. % to about 20 wt. % of a plasticized polyvinyl butyral resin. Minor amounts of fatty acids and paraffin wax may be added to improve low temperature properties and to facilitate processing a hot melt admixture of the ingredients into a sheet.

Abstract: A cellulosic fiber containing board is molded at a temperature of at least 525.degree. F. to provide a relatively high density skin on at least one surface.A fibrous composition, including cellulosic fibers, is consolidated to form a blank having a density of less than 35 pounds/cubic foot. The blank is then cut to a shape larger in at least two of its three dimensions than corresponding dimensions of a mold cavity when said mold is in a closed position.Urea is then included in at least a surface layer of fibers of the blank in an amount of at least 5% based on the dry weight of the fibers contacted with urea, and thereafter the cut blank is molded to form a contoured product having a skin on at least one surface thereof, the skin defined by a thickness of material on said surface of said product having a density greater than the material on which the skin is formed.

Abstract: Polyglutaraldehyde (PGL) is polymerized in aqueous base or in aqueous highly polar solvent basic media to prepare powders, castable films or coatings for substrates such as amine substituted microbeads. PGL microspheres can be prepared by suspension polymerization in presence of a surfactant or by precipitating PGL from solution containing surfactant. Magnetic PGL microspheres are formed by suspension polymerization in the presence of magnetic particles such as iron oxide. Polyglutaraldehyde can be converted to a fluorescent polymer by reaction with m-aminophenol or other reagent. Proteins can be readily covalently bound to the polyglutaraldehyde.

Abstract: A novel release sheet comprising a web of paper having a water absorption of at least about 200 seconds which has been sized on at least one side thereof with a water-soluble, alkaline earth or earth metal salt, e.g. a calcium salt such as calcium chloride and then coated on said sized side with a film of a mixture of a salt of alginic acid, such as sodium alginate, and either (1) a triglyceride or (2) hydrolyzed or non-hydrolyzed lecithin, and a method of producing decorative laminates therewith.

Abstract: Flameproof and fireproof products are formed from a fire-unstable material coated with a polymeric material which is capable of intumescing beginning at a low temperature and has adhesive qualities in conjunction with the fire-unstable material. Upon the application of heat or flame to the products, the coating material copiously intumesces to form a protective thermal insulating foam barrier which prevents the fire-unstable material from igniting or degrading to the point of evolving flammable gases or losing its dimensional stability. Continued application of heat or flame will cause the foam to char but will not destroy the products for a suprisingly long time. The polymeric coating material comprises the resinous reaction product of phosphoric acid and a reducing sugar with a hardener and containing at least one modifying agent capable of rendering the coating material highly and permanently intumescent at a low initiating temperature even after prolonged storage of the flameproof and fireproof product.

Abstract: A melamine-formaldehyde resin useful for making coated wood-based materials and laminates and having a prolonged pot life comprises (a) melamine-formaldehyde precondensation product wherein the molar ratio of melamine:formaldehyde is 1:1.4 to 1:2.6 (b) 0.1 to 1.0% by weight based on total solids, of an amine of the formula ##STR1## wherein R.sup.1 and R.sup.2 are each identical or different alkyl having 1 to 4 carbon atoms and R.sup.3 is 2-hydroxyethyl, 2-(2-hydroxyethoxy)-ethyl, 3-hydroxy-1-propyl, 3-hydroxy-2-propyl, 2,3-dihydroxypropyl or--CH.sub.2 CH.sub.2 --NR.sup.1 R.sup.2,wherein said amine may be present entirely or partially in the form of its reaction product with the melamine-formaldehyde pre-condensation product.