Paper Patents (Class 428/530)
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Patent number: 4444943Abstract: A paper coating composition is described, containing a pigment and an aqueous binder as major components, and further containing a thermosetting resin in aqueous solution, obtained by reacting or mixing (Y) a water-soluble resin obtained by reacting urea, polyalkylenepolyamine, and dibasic carboxylic acid and reacting the resulting polyamidopolyurea with formaldehyde, (a) at least one alkylenediamine or polyalkylenepolyamine, and (b) epihalohydrin, or the reaction product between (Y) and (b) with (a).Type: GrantFiled: December 13, 1982Date of Patent: April 24, 1984Assignee: Sumitomo Chemical Company, LimitedInventors: Shigenao Kawakami, Terumasa Saka, Hisao Takagishi, Shigeru Ura, Mikio Iwata
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Patent number: 4440833Abstract: Increased elasticity of a laminate is obtained by adding 5-20% by weight of a blocked polyetherurethane component from a reaction product of polyethylene glycol, polypropylene glycol and p-nonylphenol with toluene-2,4-diisocyanate having the following composition:______________________________________ polyethylene glycol 15-20% by weight polypropylene glycol 50-60% by weight toluene-2,4-diisocyanate 8-12% by weight nonylphenol 10-15% by weight ______________________________________in the manufacture of a fire resistant laminate based on a cellulose-containing substrate material and an impregnating varnish made up of a phenol-resol with additives of plasticizers and flame retardants. A copper-laminated hard paper made of this phenolic resin laminate is distinguished by reduced punching resistance and stripping resistance.Type: GrantFiled: October 28, 1982Date of Patent: April 3, 1984Assignee: Dynamit Nobel AktiengesellschaftInventors: Arnold Franz, Siegfried Koepnick
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Patent number: 4439587Abstract: This invention provides a graft copolymer of at least one acrylic monomer and chlorinated natural or synthetic rubber, in which at least about 8 percent of the total weight of said graft copolymer is derived from acrylic acid, methacrylic acid, or both. It also provides aqueous dispersions of such graft copolymers and coating compositions containing them.Type: GrantFiled: March 8, 1982Date of Patent: March 27, 1984Assignee: Mobil Oil CorporationInventors: Carlos J. Martinez, Albert C. Chen
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Patent number: 4431213Abstract: A pressure-sensitive recording material which contains, on at least one support, at least one color former and one inorganic developer therefor applied in the form of coatings, said coatings additionally containing a urea-formaldehyde condensate with a BET specific surface area of 3 to 30 m.sup.2 /g.Type: GrantFiled: December 22, 1980Date of Patent: February 14, 1984Assignee: Ciba-Geigy AGInventors: Arnold Hofer, Rene Graf, James H. Astbury
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Patent number: 4424261Abstract: Hydroxyalkylmelamines are disclosed as ingredients in various resins which find use as the resin component of heat and pressure consolidated laminates, especially decorative laminates having either post-formability or a core having a color matching that of the decor sheet.Type: GrantFiled: September 23, 1982Date of Patent: January 3, 1984Assignee: American Cyanamid CompanyInventors: Ronald J. Keeling, Jin-Young K. Roe, Henry C. Mollmann
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Patent number: 4421792Abstract: A novel method for applying adjuvants to fabric employing a tumbler-type dryer is disclosed. To achieve uniform distribution in the dryer, the adjuvant, such as a fabric softening agent in accordance with the present invention, is combined with a distributing agent spreadable under the dryer conditions, the concentration of the distributing agent being at least about 5% by weight of the mixture of adjuvant and distributing agent. Novel compositions of matter and articles suitable for use in the practice of this invention are also disclosed.Type: GrantFiled: March 10, 1982Date of Patent: December 20, 1983Assignee: Lever Brothers CompanyInventors: Jerome Rudy, Anthony A. Rapisarda
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Patent number: 4419408Abstract: Compositions of matter having properties that make them strong adhesives to various substrates and especially for extrusion adhesion to various polar substrates. These compositions comprise blends of a graft copolymer of a polyethylene backbone grafted with at least one grafting monomer comprising one or more polymerizable ethylenically unsaturated carboxylic acids or the anhydrides of such acids blended with a blending resin that is a mixture of one or more high density polyethylenes and one or more polypropylenes. The disclosure also includes composite structures and their method of making comprising one or more substrates and a blend of the above as the adhesive in contact with and united with the substrate or substrates.Type: GrantFiled: December 23, 1982Date of Patent: December 6, 1983Assignee: Chemplex CompanyInventors: Seymour Schmukler, John Machonis, Jr., Mitsuzo Shida
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Patent number: 4419401Abstract: There is disclosed a flame retardant composition suitable for application to a variety of textile and textile related products. The formulation is a water based liquid polymeric concentrate comprising about 35-65 parts of ammonium phosphate, about 10-30 parts of ammonium sulfate, about 40-60 parts of an alkanolamine, about 40-60 parts of phosphoric acid, about 20-40 parts of an aldehyde, in 100-140 parts by weight of water.Type: GrantFiled: August 3, 1982Date of Patent: December 6, 1983Inventor: Glenn A. Pearson
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Patent number: 4405751Abstract: Aminoplastic resin dispersions which are stable to sedimentation are obtained by condensation of aldehydes with aminoplastic resin formers in an aqueous medium, in the presence of water-soluble compounds of the formulaR--X--(A--O).sub.m --B--NHCONH--Y].sub.nhaving the substituent meanings mentioned in the description. The condensation is preferably carried out in the presence of dyestuffs or optical brighteners which have groups capable of condensation. The dispersions obtained thereby are particularly suitable for whitening the coating compositions used in the paper industry, and for coating paper, wood, films and textile materials.Type: GrantFiled: March 8, 1982Date of Patent: September 20, 1983Assignee: Bayer AktiengesellschaftInventors: Hanns P. Muller, Kuno Wagner, Peter Mummenhoff, Gottfried Wallpott, Karlheinz Scheuss
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Patent number: 4404250Abstract: The invention relates to flame-retardant, high pressure consolidated articles containing an air-laid web and to a method of preparing such articles wherein boric acid or ammonium pentaborate is added as a flame-retardant additive.Type: GrantFiled: September 23, 1982Date of Patent: September 13, 1983Assignee: Formica CorporationInventor: Theodore R. Clarke
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Patent number: 4404252Abstract: A waferboard having at least one surface rendered water resistant and stabilized against wafer loss is disclosed. In the past heavy paper overlays have been used on panel surfaces. However, these paper overlays are specially treated non-porous paper and generally have to be specially applied by the addition of a glue. The waferboard of the present invention is formed of wood wafers bonded together in a hot press with adhesive resin and wax, and having a layer of porous paper bonded in the hot press to at least one surface of the waferboard. In one embodiment, the contours of the wood wafers on the surface of the waferboard are transmitted through the layer of porous paper.Type: GrantFiled: September 16, 1981Date of Patent: September 13, 1983Assignee: MacMillan Bloedel LimitedInventors: Bernard H. Hetzler, Hugh V. Martin
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Patent number: 4388374Abstract: Water reducible compositions useful as coating compositions for flexible substrates are prepard by reacting a glycidyl polyether of a dihydric phenol with a polyethylene glycol and ortho phosphoric acid.Type: GrantFiled: August 30, 1982Date of Patent: June 14, 1983Assignee: Celanese CorporationInventor: David A. Shimp
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Patent number: 4379553Abstract: An improvement in a bowling lane having a decorative laminate surface which improvement comprises incorporating into the core of the laminate a plurality of alternating layers of glass cloth and crepe paper, each core layer being impregnated with a thermosetting resin and an organic fire retardant material, contiguous and adjacent core layers being interlaminarly bonded to one another.Type: GrantFiled: October 28, 1981Date of Patent: April 12, 1983Assignee: General Electric CompanyInventor: Peter B. Kelly
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Patent number: 4379194Abstract: The invention relates to high pressure decorative laminates containing an air-laid web of fibers, filler and resin as a core and to a method of preparing such a decorative laminate from an assembly comprising said substrate and a thermosetting resin impregnated decor sheet.Type: GrantFiled: January 19, 1981Date of Patent: April 5, 1983Assignee: Formica CorporationInventors: Theodore R. Clarke, John F. Hosler
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Patent number: 4378446Abstract: Low viscosity, aqueous impregnating resin solution with improved stability containing 30-70% by weight of solid resin which comprises:(A) 80-98% by weight of a melamine-formaldehyde precondensate and(B) 2-20% by weight of a water soluble copolymer.Type: GrantFiled: May 22, 1981Date of Patent: March 29, 1983Assignee: Cassella AktiengesellschaftInventors: Wilhelm Adam, Curt A. Wagner, Renate Konrad, Friedrich Engelhardt, Ulrich Riegel, Georg W. Eckhardt, Steffen Piesch
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Patent number: 4374886Abstract: The use of a pigmented, fully-hydrolyzed polyvinyl alcohol modified melamine-formaldehyde resin coating in color registered decorative laminates provides improved laminates exhibiting pleasing aesthetics.Type: GrantFiled: October 30, 1980Date of Patent: February 22, 1983Assignee: Formica CorporationInventor: Ram S. Raghava
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Patent number: 4372583Abstract: A pressure-sensitive chromogenic copy system utilizing a color developer capable of reacting with a chromogen to form a color image, said color developer comprising an oligomeric aromatic carboxylic acid and the method of making such oligomer by reaction of the acid with an aldehyde under alkaline conditions.Type: GrantFiled: August 17, 1981Date of Patent: February 8, 1983Inventor: Anthony E. Vassiliades
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Patent number: 4370386Abstract: An electrical laminate comprising layers of an unsaturated polyester resin-impregnated fibrous cellulosic substrate is disclosed. The substrate is preimpregnated with a mixture and/or a condensate of an aminoplast with a higher fatty derivative having at least one functional group capable of condensation with the methylol group of aminoplast. The laminate exhibits improved moisture resistance and punchability.Type: GrantFiled: September 15, 1980Date of Patent: January 25, 1983Assignee: Kanegafuchi Kagaku Kogyo Kabushiki KaishaInventors: Masakazu Uekita, Yasuo Fushiki, Masaharu Abe
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Patent number: 4369286Abstract: Modified aminoplast resins based on melamine and formaldehyde or urea and formaldehyde, which contain, as modifiers, methylolmelamines having a molar ratio of melamine to formaldehyde of 1:3 to 1:6, which are etherified with mono-alcohols having 1 to 4 carbon atoms, in a ratio of melamine to alcohol of 1:2 to 1:6. These resins are used, in particular, for the production of decorative, glossy-surface laminations.Type: GrantFiled: November 3, 1981Date of Patent: January 18, 1983Assignee: Chemie Linz AktiengesellschaftInventors: Hubert Czepel, Friedl Heger, Wilhelm Dobramysl
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Patent number: 4361615Abstract: The invention relates to bowling lanes in which at least part of the lane approach surface and at least part of the lane surface proper is of a suitable decorative laminate panel, the foul line configuration being molded or incorporated in said laminate.Type: GrantFiled: May 12, 1981Date of Patent: November 30, 1982Assignee: General Electric CompanyInventor: Peter B. Kelly
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Patent number: 4355081Abstract: A curable resin, e.g., a phenol-aldehyde resin, of a resin impregnated cellulosic substrate, e.g., paper, is cured by contacting said substrate with high temperature steam in a continuous superheated state. The resulting product exhibits superior physical properties, e.g., improved wet properties such as boiled tensile strength.Type: GrantFiled: May 30, 1980Date of Patent: October 19, 1982Assignee: James River CorporationInventor: Homan B. Kinsley, Jr.
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Patent number: 4347274Abstract: Visible index strip rolls of a novel, cost effective construction; and methods and machinery for manufacturing those rolls.Type: GrantFiled: January 26, 1981Date of Patent: August 31, 1982Inventor: Alexander P. Janssen
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Patent number: 4343850Abstract: A decorated heat and pressure cured laminate, one of whose laminating sheets bears photoelectrographically applied indicia. The laminate at least also contains a thermosetting resin impregnated core adjacent to one surface of the photoelectrographic indicia bearing sheet. The laminate is cured at a temperature of about 300.degree.-350.degree. F. and at a pressure of about 1800-2000 p.s.i.Type: GrantFiled: March 21, 1980Date of Patent: August 10, 1982Assignee: The Vollrath CompanyInventors: Hal C. Kravig, John T. Van Drie
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Patent number: 4337291Abstract: A bowling lane having a decorative laminate surface in which the lane approach surface and the lane surface proper has a finish which provides a 60 degree gloss below about 30 in the machine direction as measured according to NEMA Standard 8-19-1964.Type: GrantFiled: March 6, 1980Date of Patent: June 29, 1982Assignee: General Electric CompanyInventor: Peter B. Kelly
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Patent number: 4336937Abstract: A panel suitable as a bowling lane surface comprising a melamine impregnated protective layer bonded under heat and pressure to a hardboard substrate. The melamine impregnated protective layer is comprised of one or more melamine resin impregnated decorative fibrous print sheets. The surface of the bowling lane so produced is characterized by a falling ball impact resistance of at least 60 inches, a wear rate of between about 0.02 and 0.05 and a Taber abrasion resistance at least about 400 cycles.Type: GrantFiled: October 2, 1979Date of Patent: June 29, 1982Assignee: General Electric CompanyInventor: Peter B. Kelly
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Patent number: 4327133Abstract: A novel method for applying adjuvants to fabric employing a tumbler-type dryer is disclosed. To achieve uniform distribution in the dryer, the adjuvant, such as a fabric softening agent in accordance with the present invention, is diluted with a distributing agent spreadable under the dryer conditions, the concentration of the distributing agent being at least about 5% by weight of the mixture of adjuvant and distributing agent, the adjuvant being present in an effective amount. Novel compositions of matter and articles suitable for use in the practice of this invention are also disclosed.Type: GrantFiled: June 20, 1980Date of Patent: April 27, 1982Assignee: Lever Brothers CompanyInventors: Jerome Rudy, Anthony A. Rapisarda
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Patent number: 4324832Abstract: What is disclosed is a method for making a synthetic veneer, which method comprises impregnating a fibrous web structure with an aqueous dispersion of a finely divided synthetic resin, said dispersion further containing a water-soluble aminoplast resin dissolved therein, and then drying the impregnated web structure by heating it, said synthetic resin being thermoplastically deformable and in a non-crosslinked condition at the beginning of the drying step, but comprising a plurality of groups capable of external crosslinking and which do crosslink during the drying step.Type: GrantFiled: January 18, 1980Date of Patent: April 13, 1982Assignee: Rohm GmbHInventors: Helmut Moroff, Hanns Boessler, Hans Hauser, Gerhard Ladisich
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Patent number: 4324420Abstract: Heat-sensitive recording or copying materials which contain in their color reactant system, as developers for the color-forming agent, at least one mono- or poly-aldehyde which is electronegatively substituted, especially by halogen, and/or the reaction products thereof with an organic compound containing hydroxyl groups, or the precursors thereof.Type: GrantFiled: January 11, 1980Date of Patent: April 13, 1982Assignee: Ciba-Geigy CorporationInventor: Horst Kosche
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Patent number: 4322475Abstract: Disclosed herein are certain novel compounds which are mostly properly designated as 3-isothiazolones. These compounds and compositions containing them exhibit a broad spectrum of biocidal properties and are particularly effective for the control of microorganisms.Type: GrantFiled: July 31, 1980Date of Patent: March 30, 1982Assignee: Rohm and Haas CompanyInventors: Sheldon N. Lewis, George A. Miller, Andrew B. Law
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Patent number: 4322468Abstract: Incorporating abrasive materials into the resin impregnated print sheet and thereafter applying a coating of a fully hydrolyzed polyvinyl alcohol modified melamine-formaldehyde resin results in an effective abrasion-resistant decorative laminate which eliminates the necessity for an overlay sheet containing abrasive materials and cellulosic fibers.Type: GrantFiled: October 30, 1980Date of Patent: March 30, 1982Assignee: Formica CorporationInventor: Ram S. Raghava
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Patent number: 4314002Abstract: This invention relates to insulating laminates which consists with several sheets of reinforcements (1) inpregnated with curable resin and layers (2) of cured resin located between each reinforcement. Metal clad laminates is also disclosed which is consisting with reinforcement (1), layers (2) of cured resin and metal foil (5) to be placed on the laminates. Each reinforcements (1) are substantially isolated by the resin layers (2).Type: GrantFiled: January 29, 1980Date of Patent: February 2, 1982Assignee: Kanegafuchi Kagaku Kogyo Kabushiki KaishaInventors: Masayuki Oizumi, Masana Goto, Minoru Ishiki, Shoji Uozumi
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Patent number: 4311748Abstract: The use of a fully-hydrolyzed polyvinyl alcohol modified melamine-formaldehyde resin coating for the print sheet in a decorative laminate eliminates the necessity for an overlay sheet without thereby imparting any deleterious effects to the laminate itself.Type: GrantFiled: October 20, 1980Date of Patent: January 19, 1982Assignee: Formica CorporationInventors: Donald J. Casey, Daniel M. Zavisza
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Patent number: 4307883Abstract: A two stage panel suitable as a bowling lane comprising a decorative laminate sheet bonded in situ to a substrate selected from the group consisting of natural wood, consolidated wood fibers, plywood, flakeboard, chipboard and hardwood. The plastic laminate sheet comprises a plurality of thermosetting resin impregnated core sheets, a melamine resin impregnated decorative fibrous print sheet and an overlying melamine resin containing protective layer. The surface of the bowling lane so produced is characterized by a falling ball impact resistance of at least 60 inches, a coefficient of friction of at least about 0.16 and a Taber abrasion resistance at least about 500 cycles.Type: GrantFiled: July 20, 1979Date of Patent: December 29, 1981Assignee: General Electric CompanyInventor: Peter B. Kelly
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Patent number: 4307148Abstract: A process for improving the flame-retardant properties of cellulose containing fibrous materials in the absence of halogen compounds which comprises treating said fibrous materials with an effective amount of a colloidal aqueous dispersion of an alkali metal polyantimonate containing a mole ratio of alkali metal to antimony in the dispersion of at least about 0.3:1, and drying said materials is described.Type: GrantFiled: August 20, 1979Date of Patent: December 22, 1981Assignee: The Harshaw Chemical CompanyInventor: Destin A. LeBlanc
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Patent number: 4288491Abstract: A laminated plastic material comprises surface layers of paper impregnated with amino formaldehyde resin and inner layers of paper containing a flame retardant material and impregnated with phenol formaldehyde resin. The flame retardant material is a product of interaction of an aluminum or copper compound with phosphoric acid and nitrogen bases and contains, in weight percent:______________________________________ P.sub.2 O.sub.5 total 37 to 63 P.sub.2 O.sub.5 water-soluble 0 to 6 NH.sub.3 3.Type: GrantFiled: March 13, 1979Date of Patent: September 8, 1981Inventors: Evgeny M. Surzhenko, Bronislav F. Basilaev, Roman V. Molotkov, Alexandr S. Madorsky, Grigory B. Shalun, Valentina B. Golynkina, Margarita A. Ershova, Irina P. Eliseeva, Nina E. Trukhtenkova, Sergei M. Gurylev, Diana L. Kopetskaya, Evgeny Y. Pechko, Albert S. Khlamenko, Viktor V. Magnitsky
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Patent number: 4285989Abstract: An electrographic recording material comprising a conductive paper support coated with an electrically insulating layer comprising an intimate blend of a polymeric binder and up to 500 parts of an inert finely divided pigment per 100 parts by weight of polymeric binder. The binder comprises poly(vinyl acetal) and an alkoxymethyl polyaminotriazine. The electrographic recording material exhibits improved resistance to curl when it is exposed to variable humidity conditions.Type: GrantFiled: May 11, 1979Date of Patent: August 25, 1981Assignee: Monsanto CompanyInventors: Walter J. Wilkinson, Irving Serlin
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Patent number: 4279959Abstract: Disclosed is a water-insoluble addition copolymer of an ethylenically unsaturated unsubstituted amide and at least one other ethylenically unsaturated monomer comprising sufficient amide groups mono-functionally bonded to a polyaldehyde to render the copolymer thermosettable. The copolymer is adapted for use as or for formulation in a binder. Such a binder is readily made from a copolymer latex and is useful in processes for the preparation of products such as nonwoven fabrics and bonded papers.Type: GrantFiled: December 28, 1979Date of Patent: July 21, 1981Assignee: Rohm and Haas CompanyInventors: Dominic R. Falgiatore, William D. Emmons
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Patent number: 4277529Abstract: There is disclosed bonded lightweight tissue paper having improved wet and dry tensile strength and excellent softness and absorbency. The paper is produced by a process which comprises applying a binder composition to a dry web of lightweight soft and absorbent tissue paper, wherein the binder composition comprises an aqueous mixture containing a cross-linkable latex, a cross-linking agent, urea, and a specific combination of inorganic salts.Type: GrantFiled: February 1, 1978Date of Patent: July 7, 1981Assignee: Johnson & JohnsonInventor: Norman J. Friedman
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Patent number: 4272569Abstract: The present invention resides broadly in a method for the preparation of paper having improved water and/or solvent resistance which comprises applying to a base paper a plastic particle containing formulation, and then wetting the formed coating with a solvent to which the plastic particles are sensitive. The present invention is particularly applicable to the preparation of electrostatic paper masters of improved water resistance for lithographic printing having a photoconductive layer and a barrier coat to which the photoconductive layer is applied. The barrier coat contains a binding amount of a binder resin and filler at least a portion of which is an amount of said plastic particles sensitive to the solvent system of the photoconductive layer, the amount of plastic particles and sensitivity being sufficient to materially increase water resistance.Type: GrantFiled: June 1, 1979Date of Patent: June 9, 1981Assignee: Allied Paper IncorporatedInventors: Michael J. Shaw, Robert J. Thiessen
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Patent number: 4271221Abstract: Aqueous coating compositions for use in the preparation of decorative sheets employed in heat and pressure consolidated decorative laminates, comprising a pigment, a pigment binder, and a dispersion of a urea-formaldehyde resin condensate or a melamine-formaldehyde resin condensate; such coating compositions comprising, as an additional component in the preferred embodiment, a thermoplastic resin which is non-film-forming at drying temperatures.Type: GrantFiled: August 1, 1979Date of Patent: June 2, 1981Assignee: Scott Paper CompanyInventor: William A. Hosmer
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Patent number: 4259425Abstract: An electrographic recording material comprising a conductive sheet support coated with an electrically insulating layer comprising an intimate blend of a polymeric binder and up to 500 parts of an inert finely divided pigment per 100 parts by weight of polymeric binder. The binder comprises from about 40 to about 90 parts by weight of a poly(vinyl acetal) and from about 10 to about 60 parts by weight of a polystyrene or a poly(.alpha.-methylstyrene). The electrographic recording material exhibits improved toner adhesion.Type: GrantFiled: May 11, 1979Date of Patent: March 31, 1981Assignee: Monsanto CompanyInventor: Irving Serlin
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Patent number: 4258103Abstract: Decorative, heat-and-pressure consolidated laminates comprising a decorative sheet impregnated with a thermosetting resin which does not undergo color deterioration during the consolidation step and a backing sheet, the outer surface of which has been coated prior to consolidation with a composition containing an inert filler, a non-thermoplastic adhesive, and a water-soluble thermosetting resin selected from the class consisting of urea-formaldehyde resin condensates and melamine-formaldehyde resin condensates; and processes for making such laminates.Type: GrantFiled: July 30, 1975Date of Patent: March 24, 1981Assignee: Scott Paper CompanyInventors: William A. Hosmer, William M. Bowler
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Patent number: 4256809Abstract: Ambient or low-temperature curable aqueous dispersions of (1) an emulsion polymer containing units polymerized from a monomer mixture of (a) from about 0.25% to about 10% by weight of a polymerizable aldehyde, (b) from about 0.5% to about 10% by weight of an ethylenically unsaturated carboxylic acid, and (c) up to about 99.25% by weight of at least one copolymerizable mono-ethylenically unsaturated monomer, with (2) a curing agent selected from the group of dicarboxylic acid bis-hydrazides and bis-hydrazones are disclosed. The dispersions are useful in leather treating compositions, especially in top coat compositions. A process for producing fully finished leather, or leather substitutes is also disclosed.Type: GrantFiled: February 2, 1979Date of Patent: March 17, 1981Assignee: Rohm and Haas CompanyInventors: Bjorn E. Larsson, Fred A. Desiderio
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Patent number: 4255171Abstract: The heat transfer medium for rotary air-to-air heat transferrers includes alternate planar and corrugated layers of a fiber-reinforced, heat-curable, organic resinous material. After corrugating and interleaving of the layers, the resultant structure is heated to cure the resin to a hardened state and the layers are bonded together at their points of contact to form a self-supporting, water-proof structure including a plurality of uniformly-spaced, tubular flow passages extending axially through the structure in parallel relationship parallel to the rotational axis of the transferrer. The surfaces of the flow passages exposed to air flow are coated with an aqueous coating solution containing a water-soluble hygroscropic material, such as lithium chloride, and a sufficient amount of a water-soluble wetting agent to provide a continuous film of the coating solution on these surfaces.Type: GrantFiled: August 17, 1978Date of Patent: March 10, 1981Assignee: Wehr CorporationInventor: Konstantins Dravnieks
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Patent number: 4247433Abstract: A method for preparing thermosettable urea-formaldehyde resins having a urea to formaldehyde molar ratio of 1:1 to 1:1.5 wherein urea and formaldehyde are first reacted in an aqueous solution at a molar ratio of 1:1.5 to 1:4 in the pH range between 7.5 to 10, and then condensing the reactants in a pH range from 4 to 6 to a precipitation number of 1:1.5 to 1:10, thereafter adjusting the pH to 7 to 10 and adding the remaining urea to obtain a molar ratio of 1:1 to 1:1.5 and continuing the reaction until a precipitation number of 1:0.5 to 1:3 is obtained. The products obtained have a uniform molecular weight and good penetration properties when used to impregnate supporting webs for coating wood-based panels.Type: GrantFiled: May 24, 1979Date of Patent: January 27, 1981Assignee: Th. Goldschmidt AGInventors: Eckehard Schamberg, Ulrich Holtschmidt, Dieter Hellwig
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Patent number: 4246153Abstract: An aqueous solution of a thermosetting resin which improves water resistance and ink receptivity of coated paper and gives coated paper emitting little or almost no formaldehyde odor is produced by a process comprising the steps,(1) a reaction of urea with a polyalkylenepolyamine,(2) dehydration-condensation of the resulting reaction product with a dibasic carboxylic acid,(3) a reaction of the resulting reaction product with urea to produce a polyureapolyamide, and(4) a reaction of the polyureapolyamide with formaldehyde in an aqueous medium under acidic condition, or under alkaline condition and then under acidic condition.Type: GrantFiled: July 3, 1979Date of Patent: January 20, 1981Assignee: Sumitomo Chemical Company, LimitedInventors: Hisao Takagishi, Haruo Tanaka
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Patent number: 4244990Abstract: The invention relates to a process for the production of a melamine resin coated paper for the formation of hot-molded, scratch resistant surface layers on laminate synthetic substances and wooden working materials, whereby the paper is preimpregnated with a urea resin or an aminoplast rich in urea and is then provided with an application of a melamine resin. At the same time, a solution of a resin is used for the preimpregnation of the paper, the degree of condensation of which is higher than the degree of condensation of the melamine resin to be used for the formation of the cover layer, and the preimpregnation is dried hot, to an extent that the preimpregnation resin is hardened to the point it is practically no longer soluble in the melamine resin.Type: GrantFiled: May 3, 1979Date of Patent: January 13, 1981Assignee: Osterreichische Haig-Werke AktiengesellschaftInventor: Herbert Mayerhoffer
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Patent number: 4243461Abstract: A novel method of releasing from one another in a press pack, a plurality of back-to-back heat and pressure consolidated resin-impregnated laminates, e.g. decorative laminates, metal clad laminates, veneer backs and the like, which method comprises utilizing, as a separator sheet, a web of phenol-formaldehyde resin-free paper having a water absorption of at least about 200 seconds which has been sized on at least one side thereof, from an aqueous mixture, a water-soluble, alkaline earth or earth metal salt, e.g. a calcium salt such as calcium chloride, then coated on said sized side with a film of a mixture of a salt of alginic acid, such as sodium alginate, and either (1) a triglyceride or (2) hydrolyzed or non-hydrolyzed lecithin.Type: GrantFiled: November 13, 1979Date of Patent: January 6, 1981Assignee: Formica CorporationInventors: Richard F. Jaisle, Kenneth D. Bunkowski
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Patent number: 4243716Abstract: A thermal sensitive paper having a heat sensitive layer containing a color-forming lactone compound and a phenol compound is amazingly lessened in possible deposition of its residue on the thermal head during the printing operation when finely divided urea-formaldehyde resin is incorporated in at least one of the heat sensitive layer, support and between said heat sensitive layer and support.Type: GrantFiled: July 18, 1978Date of Patent: January 6, 1981Assignee: Mitsubishi Paper Mills, Ltd.Inventors: Takao Kosaka, Yukio Tahara
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Patent number: RE31366Abstract: A melamine-formaldehyde resin useful for making coated wood-based materials and laminates and having a prolonged pot life comprises (a) melamine-formaldehyde precondensation product wherein the molar ratio of melamine:formaldehyde is 1:1.4 to 1:2.6 (b) 0.1 to 1.0% by weight based on total solids, of an amine of the formula ##STR1## wherein R.sup.1 and R.sup.2 are each identical or different alkyl having 1 to 4 carbon atoms and R.sup.3 is 2-hydroxyethyl, 2-(2-hydroxyethoxy)-ethyl, 3-hydroxy-1-propyl, 3-hydroxy-2-propyl, 2,3-dihydroxypropyl or--CH.sub.2 CH.sub.2 --NR.sup.1 R.sup.2,wherein said amine may be present entirely or partially in the form of its reaction product with the melamine-formaldehyde pre-condensation product.Type: GrantFiled: January 11, 1982Date of Patent: August 30, 1983Assignee: Cassella AktiengesellschaftInventors: Peter Dorries, Steffen Piesch, Alfons Wolf