Abstract: A method for the treatment of wood by a wood preserving agent in a liquid or paste-like form, to be positioned (inserted) in a recess in the wood, which recess is subsequently sealed off.The wood preserving agent contains a water-expelling agent, a water-repellent agent and a biocide.

Abstract: A wood preservative composition comprising 2-mercaptobenzothiazole or its salt and 2,5-dichloro-4-bromophenol or its salt exerts an unexpected synergistic wood preservative effect against wood destroying fungi and termites.

Abstract: A wet-felted mat of wood fibers is acetylated by coating the mat with a quantity of acetic anhydride ranging from 5 to 70% by volume of the mat and heating the mat at a temperature of from 150.degree. to 300.degree. F. while confining substantially all of the acetic anhydride within the mat for about 20 to 120 minutes. The acetylated mat is pressed into hardboard which may be bent into a variety of loops, spirals, helices, and other curvilinear shapes to make articles of furniture, protective packaging products and the like.

Abstract: This invention relates to new and improved chlorinated phenol water soluble wood treating compositions and methods for preservation of wood or products made from wood. In the general practice of this invention, wooden objects are treated with water soluble wood treating and preserving solutions consisting of blends of from 0.1% to about 50% by weight of a chlorophenol selected from a group consisting of pentachlorophenol and tetrachlorophenol and mixtures thereof, from about 1% to about 97% by weight aliphatic alcohols having from 1 to 6 carbon atoms and mixtures thereof, from about 0.2% to about 35% of a fatty acid amine oxide or a mixture of fatty acid amine oxides and other amines, and from about 1% to about 97% by weight water.

Abstract: This invention relates to new and improved chlorinated phenol water soluble wood treating compositions and methods for preservation of wood or products made from wood. In the general practice of this invention, wooden objects are treated with water soluble wood treating and preserving solutions consisting of blends of from 0.1% to about 50% by weight of a chlorophenol selected from a group consisting of pentachlorophenol and tetrachlorophenol and mixtures thereof, from about 1% to about 97% by weight aliphatic alcohols having from 1 to 6 carbon atoms and mixtures thereof, from about 0.2% to about 35% of a fatty acid amine oxide or a mixture of fatty acid amine oxides and other amines, and from about 1% to about 97% by weight water.

Abstract: Lumber, which is substantially warp-free and check-free and has a reduced susceptibility to decay and insect damage, particularly red alder, beech, birch, cottonwood, maple, oak, aspen and hemlock, is produced by felling the tree, preferably when in substantially full leaf; long butting the tree trunk; sealing the butt end surface to deter decay and attack by insects, and reducing the sap content by allowing the unlimbed tree to age for a minimum of six weeks; sawing the tree into lumber; purging additional sap from the lumber by soaking it with high-pressure water sprays periodically for a minimum of three days; and drying the lumber. Mold and other deterioration is deterred in wood chips which are to be stored by soaking, pressing and washing them.

Abstract: Wood is beneficiated by treating the wood with an agent capable of forming a borate ester linkage between hydroxyl groups of the cell wall constituents of the wood, and thereafter treating the wood with an aldehyde to effect aldehyde cross-linking of cell wall structural constituents of the wood. Suitable borate ester forming agents include boric acid, lower polyalkyl borate esters, mono- and di-substituted derivatives of boric acid and/or the borate esters, and compounds capable of forming these agents in situ under the prevailing reaction conditions.

Abstract: Disclosed herein are certain novel compounds which are mostly properly designated as 3-isothiazolones. These compounds and compositions containing them exhibit a broad spectrum of biocidal properties and are particularly effective for the control of microorganisms.

Abstract: A wood-polymer composite is prepared by impregnating a wood substrate with a liquid dicyclopentenyl acrylate or methacrylate monomer of the formula ##STR1## wherein R is hydrogen or methyl, R' and each R" are independently hydrogen, chloride or bromide, n is 0 or 1, and the dashed line is an optional chemical bond with the provisoes that when the dashed line is present, n is 0, and when the dashed line is absent, n is 1, and curing the resulting monomer-impregnated wood substrate by either heating same in the presence of a catalytic amount of a thermal initiator, such as a peroxide, or by exposing same to high-energy radiation, such as .gamma.-rays. The wood-polymer composite is relatively hard and shows good resistance to hydrocarbon attack.

Abstract: Impregnated wood containing a polymer which is produced in the wood from the polymerization of a monomer and/or prepolymer having aliphatic multiple bonds and crosslinked organopolysiloxanes.The polymer impregnated wood is prepared by impregnating the wood with a mixture containing a monomer and/or prepolymer containing aliphatic multiple bonds which is capable of free radical polymerization and a crosslinkable organopolysiloxane and thereafter the monomer and/or prepolymer is polymerized and the organopolysiloxane is crosslinked in the wood.

Abstract: Fungicidal compositions comprising at least one organometallic compound of aluminum and/or boron, at least one divalent metal and at least one carboxylic acid group. The compositions are useful in preserving timber.

Abstract: The present invention relates to antifouling paints for marine use comprising a conventional paint base containing as active ingredient a compound of the formula ##STR1## wherein X is selected from chlorine and bromine,Y is selected from hydrogen and lower alkyl, andZ is selected from --COOR wherein R is lower alkyl, and --CN, possibly in combination with a conventional antifouling agent, and to the protection of marine structures and marine vessels which comprises applying such an antifouling paint to such structures and vessels.

Abstract: A guanidine phosphate composition containing both monoquanidine phosphate and diguanidine phosphate and characterized by a weight loss of less than 1% when heated for one hour at 220.degree. C. is prepared by mixing together about equimolar quantities of phosphoric acid and cyanoguanidine and heating this reaction mixture with agitation in the presence of a surfactant to a temperature in the range of 200.degree. C. to 240.degree. C. Agitation is continued for two hours at 200.degree. C. or until foaming stops (about one hour at 240.degree. C.). The guanidine phosphate composition so obtained may be applied to cellulosic materials to render them fire retardant.

Abstract: A method for the treatment of wood by a wood preserving agent in a liquid or paste-like form, to be positioned (inserted) in a recess in the wood, which recess is subsequently sealed off.The wood preserving agent contains a water-expelling agent, a water-repellent agent and a biocide.

Abstract: An artificial lumber board comprises a plurality of elongated wood strips having medial body portions of different thicknesses and tapered tip end portions being thinner and more flexible than the medial portions wherein the wood strips are aligned longitudinally in the board and compressed. The compressed wood strips lap and bend over one another to form generally continuous sinuous wood grain-like structures extending along the board with the tapered tip portions providing generally point contact fitting of the wood strips with one another reducing the presence of void spaces in the board.

Abstract: A wood-polymer composite is prepared by impregnating a wood substrate with a liquid dicyclopentenyl acrylate or methacrylate monomer of the formula ##STR1## wherein R is hydrogen or methyl, R' and each R" are independently hydrogen, chloride or bromide, n is 0 or 1, and the dashed line is an optional chemical bond with the provisoes that when the dashed line is present, n is 0, and when the dashed line is absent, n is 1, and curing the resulting monomer-impregnated wood substrate by either heating same in the presence of a catalytic amount of a thermal initiator, such as a peroxide, or by exposing same to high-energy radiation, such as .gamma.-rays. The wood-polymer composite is relatively hard and shows good resistance to hydrocarbon attack.

Abstract: Alined wood particles and an adhesive binder comprise the faces of a sandwiched, laminate-like structure formed in a one-step pressing and heating operation, the interior of which is made of randomly oriented wood particles and an adhesive binder, exhibiting light weight and greater bending strength than known particleboards constructed from heavy hardwoods such as red oak.

Abstract: An improved wood textile bobbin having a single protective wear resistant coating, the coating when applied having the ability to rapidly form a tack free outer surface and cure to a desirable working surface over woods or wood grains that have been previously unusable, wherein the composition for the coating is made up of from about 40 to 65 percent solids consisting of a ricinoleic acid/diphenylmethane diisocyanate prepolymer (MDI) and a moisture activated, blocked, hydroxyl functional acrylic resin, the balance being a solvent in which the solids are dissolved for the purpose of applying the composition to the outer surface of the bobbin substrate.

Abstract: The penetration properties of creosote and pentachlorophenol oil-borne wood preservative compositions are improved by adding to such compositions an N,N-dimethylamide of a carboxylic acid containing 18 carbon atoms and at least 1 carbon to carbon double bond.

Abstract: A dry wood material free from seasoning check is produced with good yield from undried wood material with water content of 50 to 200% by drying the undried wood material while controlling the rate of evaporation of water from the undried wood material by providing on its surface a barrier layer having a water vapor permeability in the specific range from 10 to 100 g/m.sup.2.day.

Abstract: Pressure treatment of fire unstable materials by an intumescent fire retardant composition which is injected or insinuated into the surface of fire unstable materials results in a fire and flameproof structure with a high capacity to withstand prolonged exposure to flame and heat.

Abstract: Wood is impregnated with a solution of tannic acid followed by impregnation with a solution of a metal in the form of a salt. The metal selected is one that will complex with both the impregnated tannic acid and the wood.

Abstract: A process for inhibiting the staining of film-forming finishes applied to a tannin-containing wood substrate comprises applying to the wood substrate, prior to or concurrently with the surface film, an aqueous formulation containing a stain-inhibiting amount of magnesium hydroxide having a high surface area, thereby forming a leach-resistant magnesium hydroxide-tannin complex.

Abstract: Composites of wood cellulose and certain polymeric compositions are formed at the surface of wooden articles and have the property of ready sandability to a smooth, low porosity state, thus making the surface ideal for a variety of wood finishing operations.

Abstract: Structural wood paneling or other molded wood compositions consisting of finely divided wood chips, flour, or strands are bound together and hot pressed with a modified novolac resin which is the cured product of a prepolymer made from an aralkyl ether or halide with a phenol and a hardening agent such as hexamethylene tetramine. The fire resistance of these articles is further improved by incorporating in the binder certain inorganic fillers, especially a mixture of ammonium oxalate and ammonium phosphate.

Abstract: A continuous composite sheet material is formed of a genuine wood sheet bonded by a layer of adhesive to a thermally weldable, thermoplastic synthetic resin carrier sheet. This composite sheet is especially useful as a covering for a profiled structure used in furniture construction or interior decoration.

Abstract: An intumescent composition comprising a cyclic nitrogen compound, an acid selected from the group consisting of phosphorous acid, phosphoric acid, and mixtures thereof, water, and an hydroxy-containing organo-phosphorus compound, wherein:(a) said cyclic nitrogen compound is ##STR1## wherein a, b, and c are integers selected from the group consisting of 1 and 2, a plus b plus c equal about 3 to 6, and X, X', and X" are independently selected from the group consisting of hydrogen and --CH.sub.3 ;(b) said hydroxy-containing organo-phosphorus compound is selected from the group consisting of ##STR2## and mixtures thereof, wherein d is an integer of from 0 to 2, e is an integer of from 0 to 2, f is an integer of from 1 to 3, and d plus e plus f equal 3; z is an integer of 0 to 1; x is an integer of 1 to 2, y is an integer of 1 to 2, and x plus y plus z equal 3; R.sup.1, R.sup.2, and R.sup.

Abstract: A process for the preparation of lignocellulosic composite using urea-formaldehyde adhesive is described characterized by treating the lignocellulosic constituents with ammonium-base lignosulfonate prior to pressing to decrease the emission of formaldehyde.

Abstract: Fire-retardant compositions consisting essentially of an inorganic, fire-retardant phosphate salt and a binder of a poly-2-oxazoline having a weight average molecular weight of at least about 1,000 and at least about 40 percent phosphorylated are applied to wood or wood products by an improved method comprising admixing with a solution of the composition, either prior to or simultaneously with the application of the composition to the wood or wood product, an anionic or nonionic organic phosphate ester surfactant, such as Victawet.RTM. 35B. The use of these surfactants increases the rate and extent of penetration of the fire-retardant composition into the wood.

Abstract: A hardener composition for precondensates or liquid resins containing resorcinol and formaldehyde or resorcinol-phenol and formaldehyde and a method for glueing by using them. The hardener composition contains powdered paraformaldehyde suspended in a suspending agent that includes a precondensate of ketone and formaldehyde, which precondensate preferably contains water as a dilution media.

Abstract: What is disclosed is a method of fabricating wood composite panels having enhanced fire retardancy. The panels so fabricated have hard, durable finished surfaces which allow machine finishing without the concurrent loss in fire retardancy due to the finishing operation.

Abstract: Provided is an anti-fouling paint composition for preventing for an extended period of time fouling of submersed or submerged objects or marine structures. The paint composition comprises as an anti-fouling agent a copolymer comprised of (i) units of the formula: ##STR1## wherein R' is H or CH.sub.3 and R.sub.1, R.sub.2 and R.sub.3 are the same or different and selected from (Cl to 8) alkyl groups and a phenyl group, (ii) units of the formula: ##STR2## wherein R" is H or CH.sub.3, n is an integer of 2 to 4, R.sub.4 is Cl or (Cl to 4) alkyl group, R.sub.5 is Cl or Br and R.sub.6 is H, Cl or Br, and (iii) units of the formula: ##STR3## wherein R'" is H or CH.sub.3 and R.sub.7 is (Cl to 8) alkyl group.

Abstract: A chipboard beam made of glue coated chips has top and bottom layers extending for the full length of the beam consisting of elongated chips, that may be for example as much as 5cm in length oriented with their fibers in the longitudinal direction of the beam. The middle layer is made of flat chips having random fiber orientations in a vertical plane parallel to the long dimension of the beam. The chips are glued together under heat and pressure in a press, with the result that there is great coherence both between and within the layers. The pressing is done with the wider cross-sectional dimension of the beam horizontal, so that at this stage the layers of chips are side-by-side longitudinal stringers.

Abstract: Veneer production from softwood logs is improved by adding at least about 0.003% of urea to the hot water soaking vats prior to peeling the veneer from the logs. Enhanced results are achieved when urea is added together with a base such as sodium hydroxide.

Abstract: Cellulosic materials such as paper, wood, cotton, rayon and the like are rendered flame retardant by the intimate association therewith of an effective flame retardant amount of a reaction product of aqueous solution of sulfamic acid and an alkylene oxide e.g., ethylene oxide. Amounts of said reaction product of at least, and preferably in excess of, 0.5 percent by weight are generally effective to render the cellulosic material flame retardant. Preferably the reaction product is rendered neutral before or after application to the cellulosic material in order that the material be rendered noncorrosive and nonirritating in nature.

Abstract: A cork wall covering includes a sheet of cork sandwiched between and adhesively secured to a backing material on one side and a polymerized vinyl resin material on the opposite or facing side.

Abstract: Tannin migration in tannin-containing wood substrates, such as redwood and cedar, is inhibited by treating said substrate with an aqueous solution of polyalkylenimine, such as polyethylenimine.

Abstract: A liquid phenol-formaldehyde-resorcinol resin is made by reacting principally monomeric methylolphenols, free formaldehyde and resorcinol in an aqueous solution. The ratios of formaldehyde combined with phenol in the methylolphenols, the free formaldehyde and resorcinol are critical within given ranges. A base resin product is obtained which may be further modified in various ways to form adhesive resins. One modification involves further advancement of the base resin to increase molecular weight. When this adhesive resin is combined with an appropriate hardener, such as an aldehyde, the resulting adhesives exhibit a range of versatility previously unknown in any one product. These adhesives may be used for finger jointing wood members or for room temperature cure or preheat laminating of wood. By simply varying pH of one adhesive resin within narrow limits, a range of cure times from about a minute to well over an hour can be achieved.

Abstract: The new compound 1,3-dithiolo(4,5-b)pyrazin-2-ylidene-propanedinitrile 4-oxide is prepared by reacting substantially equimolar proportions of di-(sodiomercapto)methyleneamalononitrile with 2,3-dichloropyrazine 1-oxide. The compound has fungicidal, algicidal and marine antifoulant utility.

Abstract: Leaching of a fire retardant salt, such as a mixture of ammonium phosphates, impregnated into a wood substrate is inhibited by a process comprising:A. impregnating the wood substrate with an aqueous solution of a cyclic sulfonium zwitterion (CSZ), exemplified by structural formula (I), andB. curing the resulting CSZ-impregnated wood substrate. ##STR1## CSZ impregnation of the wood substrate can be either concurrent with or subsequent to the fire retardant salt impregnation of same. This process provides a significant degree of leach protection to otherwise very leachable fire retardant salts.

Abstract: The new compound 1,3-dithiolo(4,5-b)pyrazin-2-ylidene-propanedinitrile 4-oxide is prepared by reacting substantially equimolar proportions of di-(sodiomercapto)methylenemalononitrile with 2,3-dichloropyrazine 1-oxide. The compound has fungicidal, algicidal and marine antifoulant utility.

Abstract: The new compound 1,3-dithiolo(4,5-b)pyrazin-2-ylidene-propanedinitrile 4-oxide is prepared by reacting substantially equimolar proportions of di-(sodiomercapto)methylenemalononitrile with 2,3-dichloropyrazine 1-oxide. The compound has fungicidal, algicidal and marine antifoulant utility.

Abstract: Cellulosic substrates, e.g. wood, textiles or paper, have increased fire resistance when treated with an aqueous solution of a polyalkylenepolyamine (e.g. polyethylenimine) and a mixture of mono- and diammonium phosphate.

Abstract: Shims having improved torque retention, tensile strength, resistance to deformation, and low water absorption are formed from a resin-impregnated, cellulosic fiberboard, soaked in a solution of about 1 to about 20% by volume of methylene-bis-(4-phenyl isocyanate), and cured.

Abstract: A translucent panel is made up of one or more pieces of translucent wood. Each piece of wood is cut to less than one-half inch in thickness in the direction of the grain of the wood and is then impregnated with an initially liquid polymerizable material curable to a translucent solid. The influx of this material into the cells of the wood is induced by a sequence of intermiscible liquids, and/or by vacuum, with provision being made for the clearing of air bubble accumulation as the liquid displaces the entrained air in the wood. The absorbed material is cured so that the tubular cell structure of the wood is filled with a translucent solid, thereby causing the wood to become translucent. The completed panel is installed in proximity to a light source to form a light fixture.

Abstract: There is disclosed compatible, homogeneous blends comprised of from 90 to 10 percent by weight, based on the total weight of the blend of an essentially unplasticized polyvinyl chloride having an intrinsic viscosity ranging from 0.6 to 1.0 and from 10 to 90 percent by weight, based on the total weight of the blend, of an essentially noncrystallizable copolyester having an intrinsic viscosity ranging from 0.5 to 1.10 and a softening point ranging from 70.degree. C. to 220.degree. C.

Abstract: An improved wood textile bobbin which is provided with two layers of protective coatings, the first layer being made up of ricinoleate diphenyl methane diisocyanate prepolymer (MDI) trifunctional polyether polyol (TPP), and the second layer being composed of MDI, TPP, acrylic copolymer, and to a process for producing such a bobbin.

Abstract: A water-based coating composition comprising (1) a low soap level acrylic ester interpolymer latex, (2) a fatty acid soap emulsified vinyl chloride polymer latex having substantially uniform particle size, (3) a water reducible thermoset resin, and (4) pigment(s) in an about 5% to about 60% pigment volume concentration, is an improved coating composition for hardboard.

Abstract: A system comprising an epoxy resin and a particular type of amine curing agent makes it possible to apply a coating to a wet or moist surface, even to a surface under water. These amine curing agents are substantially insoluble in water and are not water-sensitive. The amines which are used in this coating as a curing agent (in the form of a reaction product with a smaller amount of an epoxy resin to make an amine adduct) are of the formula: ##EQU1## in which R is chosen from the group consisting of alkyl radicals having at least eight carbon atoms, and alkyl ether radicals of which one of the alkyl radicals has at least eight carbon atoms. The adduct of amine and epoxy resin is used as the curing agent for the main part of the epoxy resin.

Abstract: Objects which are designed to be submersed or submerged are rendered antiling by using an organotin polymer wherein the tin is chemically combined in or bonded to the polymer. The polymer inhibits fouling of the exposed surface of the object while minimizing the effect on the surrounding environment due to reduced leaching of the organometallic compound from the polymer.