Plural Chemically Specified Polymeric Binders In Single Layer Patents (Class 428/844.7)
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Patent number: 11421179Abstract: Low-friction fluorinated coatings are disclosed herein. A preferred low-friction material contains a low-surface-energy fluoropolymer having a surface energy between about 5 mJ/m2 to about 50 mJ/m2, and a hygroscopic material that is covalently connected to the fluoropolymer in a triblock copolymer, such as PEG-PFPE-PEG. The material forms a lubricating surface layer in the presence of humidity. An exemplary copolymer comprises fluoropolymers with average molecular weight from 500 g/mol to 20,000 g/mol, wherein the fluoropolymers are (?,?)-hydroxyl-terminated and/or (?,?)-amine-terminated, and wherein the fluoropolymers are present in the triblock structure T-(CH2—CH2—O)—CH2—CF2—O—(CF2—CF2—O)m(CF2—O)n—CF2—CH2—(O—CH2—CH2)p-T where T is a hydroxyl or amine terminal group, p=1 to 50, m=1 to 100, and n=1 to 100. The copolymer also contains isocyanate species and polyol or polyamine chain extenders or crosslinkers possessing a functionality of preferably 3 or greater.Type: GrantFiled: March 13, 2020Date of Patent: August 23, 2022Assignee: HRL Laboratories, LLCInventors: Andrew P. Nowak, Adam F. Gross, Elena Sherman
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Patent number: 11247228Abstract: Some variations provide a method of forming a transparent icephobic coating, comprising: obtaining a hardenable precursor comprising a first component and a plurality of inclusions containing a second component, wherein one of the first component or the second component is a low-surface-energy polymer, and the other is a hygroscopic material; applying mechanical shear and/or sonication to the hardenable precursor; disposing the hardenable precursor onto a substrate; and curing the hardenable precursor to form a transparent icephobic coating. The coating contains a hardened continuous matrix containing regions of the first component separated from regions of the second component on an average length scale of phase inhomogeneity from 10 nanometers to 10 microns, such as less than 1 micron, or less than 100 nanometers. The transparent icephobic coating may be characterized by a light transmittance of at least 50% at wavelengths from 400 nm to 800 nm, through a 100-micron coating.Type: GrantFiled: October 29, 2018Date of Patent: February 15, 2022Assignee: HRL Laboratories, LLCInventors: April R. Rodriguez, Andrew P. Nowak, Adam F. Gross
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Patent number: 11053355Abstract: Some variations provide a segmented copolymer composition comprising: fluoropolymer first soft segments that are (?,?)-hydroxyl-terminated and/or (?,?)-amine-terminated; polyester or polyether second soft segments that are (?,?)-hydroxyl-terminated and/or (?,?)-amine-terminated; isocyanate species possessing an isocyanate functionality of 2 or greater; and polyol or polyamine chain extenders or crosslinkers, wherein the molar ratio of the second soft segments to the first soft segments is less than 2.0. Exemplary segmented copolymers are disclosed. The segmented copolymer composition may be present in a low-friction, low-adhesion coating. Such a coating may be characterized by a coefficient of friction, measured at 90% relative humidity, less than 0.7. Such a coating may be characterized by an average kinetic delay of surface ice formation of at least 10 minutes at ?10° C. These coatings are useful as bugphobic and icephobic coatings.Type: GrantFiled: August 13, 2018Date of Patent: July 6, 2021Assignee: HRL Laboratories, LLCInventors: Adam F. Gross, Andrew P. Nowak
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Patent number: 11014859Abstract: A composition that includes a fuel and a perfluoropolyether (PFPE) is disclosed. The composition may be used as a flare composition in a countermeasure device. Countermeasure devices including the flare composition are also disclosed, as are methods of forming grains of the countermeasure device.Type: GrantFiled: February 1, 2019Date of Patent: May 25, 2021Assignee: Northrop Grumman Systems CorporationInventors: Daniel B. Nielson, Curtis W. Fielding
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Patent number: 10865267Abstract: This invention provides durable, low-ice-adhesion coatings with excellent ice-adhesion reduction. Some variations provide a low-ice-adhesion composition comprising a composite material containing at least a first-material phase and a second-material phase that are nanophase-separated on a length scale from 10 nanometers to less than 100 nanometers, wherein the first-material phase and the second-material phase further are microphase-separated on a length scale from 0.1 microns to 100 microns. The larger length scale of separation is driven by an emulsion process, which provides microphase separation that is in addition to classic molecular-level phase separation. The composite material has a glass-transition temperature above ?80° C. The coatings may be characterized by an AMIL Centrifuge Ice Adhesion Reduction Factor up to 100 or more. These coatings are useful for aerospace surfaces and many other applications.Type: GrantFiled: September 27, 2018Date of Patent: December 15, 2020Assignee: HRL Laboratories, LLCInventors: Andrew P. Nowak, April R. Rodriguez, Elena Sherman, Adam F. Gross
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Patent number: 10354789Abstract: An electronic device including a core, at least a wire and a magnetic material is provided. The core includes a pillar, a top board and a bottom board. The pillar is disposed between the top board and the bottom board. An area of the top board is smaller than an area of the bottom board. A winding space is formed among the top board, the bottom board and the pillar. The wire is winded around the pillar and located in the winding space. The magnetic material fills the winding space to encapsulate the wire. The magnetic material includes a resin and a metallic powder, wherein an average particle diameter of the magnetic powder is smaller than 20 ?m.Type: GrantFiled: December 11, 2013Date of Patent: July 16, 2019Assignee: CYNTEC CO., LTD.Inventors: Tsung-Chan Wu, Roger Hsieh, Yi-Min Huang, Lan-Chin Hsieh, Yu-Ching Kuo
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Patent number: 9963623Abstract: A reactive hot melt (RHM) composition is provided as a mixture of a urethane prepolymer which is a reaction product of at least one crystallizable polyol, a perfluoropolyether polyol, and at least one isocyanate, a filler material, and a teachable plasticizer consisting of an aliphatic ester of a carboxylic acid.Type: GrantFiled: October 3, 2014Date of Patent: May 8, 2018Assignee: LUNA INNOVATIONS INCORPORATEDInventors: James Thomas Garrett, Robert James Klein
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Patent number: 8124256Abstract: A magnetic recording medium with excellent high density recording performances and good durability comprising a non-magnetic substrate, a non-magnetic layer containing a non-magnetic powder and a binder formed on the non-magnetic substrate, and a magnetic layer having a thickness of less than 100 nm and containing a substantially particulate non-magnetic powder, a substantially particulate magnetic powder having an average particle size of less than 25 nm, and a binder, wherein an average particle size R of the non-magnetic powder contained in the magnetic layer and a thickness D of the magnetic powder satisfy the following relationship: 0.88?R/D?2.5.Type: GrantFiled: August 11, 2005Date of Patent: February 28, 2012Assignee: Hitachi Maxell, Ltd.Inventors: Sadamu Kuse, Kazuhiko Nakiri
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Patent number: 7115331Abstract: A dual-layer magnetic recording medium including a non-magnetic substrate having a front side and a back side, a lower support layer formed over the front side and a magnetic upper recording layer formed over the lower layer, wherein the magnetic layer contains a volume concentration of at least about 35% of a magnetic metallic particulate pigment having a coercivity of at least about 2000 Oersteds (Oe), and a binder system for the pigment. The magnetic recording medium exhibits an orientation ratio greater than 2.0, a pulsewidth (PW50) value of less than about 500 nm, and a remanence-thickness product, Mr*t, of less than about 5.0 memu/cm2.Type: GrantFiled: March 24, 2005Date of Patent: October 3, 2006Assignee: Imation Corp.Inventor: Bruce H. Edwards