Sacrificial Component Patents (Class 428/933)
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Patent number: 9005767Abstract: A billet includes a solid steel body and an alloy cladding. The cladding may include a square tube in which the body is inserted with an interface at which the cladding becomes bonded to the body when the billet is heated and rolled or otherwise worked into a ferrous product. At least one element composed of a mass of finely divided scavenging aluminum, titanium or magnesium, is placed in the tube adjacent the body and separate from the interface. The elements are advantageously compressed into briquettes which scavenge oxygen from residual air at the interface to prevent oxidation of the cladding at the interface. The tube may be closed to prevent gases outside the billet from penetrating to the interface. Alternatively, reliance may be placed on the briquettes to scavenge oxygen from the residual air and also from atmospheric air and furnace gases before they can penetrate to the interface.Type: GrantFiled: October 19, 2010Date of Patent: April 14, 2015Assignee: Cladinox International LimitedInventor: Antonino Giorgio Cacace
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Patent number: 8986850Abstract: Various illustrative embodiments of a multi-layer brazing sheet are provided. The multi-layer brazing sheet demonstrates improved corrosion resistance on its exposed air side surface.Type: GrantFiled: March 16, 2012Date of Patent: March 24, 2015Assignee: Alcoa, Inc.Inventors: Stephen F. Baumann, Raymond J. Kilmer, Baolute Ren
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Patent number: 8668993Abstract: Disclosed is an aluminum alloy clad material which includes a core material; a sacrificial anode material on one surface of the core material; and a filler material on the other surface of the core material and composed of an Al—Si alloy, in which the core material contains 0.3 to 2.0 percent by mass of Mn, 0.15 to 1.6 percent by mass of Si, 0.1 to 1.0 percent by mass of Cu, and 0.1 to 1.0 percent by mass of Mg, with the remainder including Al and inevitable impurities, the sacrificial anode material contains 7.0 to 12.0 percent by mass of Zn, 0.3 to 1.8 percent by mass of Mn, and 0.3 to 1.2 percent by mass of Si, with the remainder including Al and inevitable impurities, and has a thickness of 10 to 30 ?m. The sacrificial anode material shows resistance to both local corrosion and general corrosion.Type: GrantFiled: July 15, 2010Date of Patent: March 11, 2014Assignee: Kobe Steel, Ltd.Inventors: Akihiko Tatsumi, Shinji Sakashita, Satoshi Yoshida, Shimpei Kimura
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Patent number: 8524377Abstract: An aluminum alloy clad sheet for heat exchangers includes a core layer, a sacrificial layer disposed on one side of the core layer, and a brazing layer of an Al—Si alloy disposed on the other side of the core layer, wherein the core layer contains Si: 0.15% to 1.6% by mass, Mn: 0.3% to 2.0% by mass, Cu: 0.1% to 1.0% by mass, Ti: 0.02% to 0.30% by mass, and the remainder of Al and incidental impurities, and the sacrificial layer contains Zn: 4.0% to 10.0% by mass, Cr: 0.01% to 0.5% by mass, and the remainder of Al and incidental impurities.Type: GrantFiled: January 19, 2010Date of Patent: September 3, 2013Assignee: Kobe Steel, Ltd.Inventors: Nobuhiro Kobayashi, Shinji Sakashita, Toshiki Ueda
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Patent number: 8501327Abstract: An aluminum alloy clad sheet for heat exchangers includes a core layer, a sacrificial layer disposed on one side of the core layer, and a brazing layer of an Al—Si alloy disposed on the other side of the core layer, wherein the core layer contains Si: 0.15% to 1.6% by mass, Mn: 0.3% to 2.0% by mass, Cu: 0.1% to 1.0% by mass, Ti: 0.02% to 0.30% by mass, and the remainder of Al and incidental impurities, and the sacrificial layer contains Zn: 4.0% to 10.0% by mass, Cr: 0.01% to 0.5% by mass, and the remainder of Al and incidental impurities.Type: GrantFiled: May 24, 2012Date of Patent: August 6, 2013Assignee: Kobe Steel, Ltd.Inventors: Nobuhiro Kobayashi, Shinji Sakashita, Toshiki Ueda
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Patent number: 8349470Abstract: The exemplary embodiments relate to a multilayer aluminum alloy sheet material suitable for fabrication into coolant-conveying tubes, headers and the like used for heat exchangers, and to the tubes and headers, etc., fabricated from the sheet. The multi-layer metal sheet has a core layer of aluminum alloy having first and second sides. The first side has an interlayer made of a Zn-containing aluminum alloy positioned between a Zn-containing outer layer and the core layer. The alloy of the outer layer is more electronegative than the alloy of the interlayer. The alloy of the interlayer is preferably more electronegative than the alloy of the core layer. The first side clad in this way is the side intended for exposure to the coolant, and provides good resistance to corrosion and erosion.Type: GrantFiled: December 17, 2009Date of Patent: January 8, 2013Assignee: Novelis Inc.Inventors: Pierre Henri Marois, Kevin Michael Gatenby, Thomas L. Davisson, Andrew D. Howells, Ian Smith
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Patent number: 8283049Abstract: An aluminum brazing sheet has a core material made of an aluminum alloy and a cladding material cladded on at least one side of the core material and made of an aluminum alloy having a potential lower than that of the core material. The cladding material is made of an aluminum alloy consisting essentially of 0.4 to 0.7 mass % of Mg, 0.5 to 1.5 mass % of Si, and 0.4 to 1.2 mass % of Mn, the remainder being Al and unavoidable impurities. Zn in the amount of 6 mass % or less is added in accordance with need. An aluminum brazing sheet having not only high strength but also less pressure adhesion failure and excellent productivity can be obtained.Type: GrantFiled: September 26, 2003Date of Patent: October 9, 2012Assignee: Kobe Steel, Ltd.Inventors: Susumu Saisho, Toshiki Ueda, Fumihiro Sato
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Patent number: 8092593Abstract: Compositions for fabricating architectural works wherein the compositions utilize one or more cement materials, additives, fibers and recycled glass. Exemplary cement materials include Portland cement, calcium aluminate, fly ash and/or E glass. Exemplary additives include boric acid, citric acid, lithium, plasticizer and/or methylcellulose ethers. Exemplary fibers include polyvinyl alcohol (PVA) and/or micro-fibers. Crushed recycled glass is used as an aggregate or non-reactive material. Other ingredients may be used including: sodium hydroxide, potassium hydroxide and hydrated lime to alter the PH; ferrous sulfate, mono-potassium phosphate, or manganese carbonate and magnesium sulfate as color enhancements; and/or pozzolans (Vcas) to neutralize the ASR efflorescence.Type: GrantFiled: June 17, 2010Date of Patent: January 10, 2012Inventor: Melvin Scott McCombs
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Patent number: 7951463Abstract: In an Al composite material collapsible in the presence of moisture, the external surface of small pieces or powder constructed from a single or a plurality of crystalline grains of Al or an Al alloy is covered with a film of a low melting point metal or alloy selected from the group consisting of In, Sn, combinations of In and Sn, and alloys thereof. The content of the foregoing low melting point metal or alloy ranges from 0.1 to 20% by mass on the basis of the total mass of the composite material. A component member for a film-forming chamber is also provided, which is provided with a water-collapsible Al film on the surface thereof. Film-forming operations are continued over a long period of time using the component member for a film-forming chamber provided with the water-collapsible Al film and then film-forming materials can be recovered from the component member on which the film-forming materials are deposited in a substantial thickness.Type: GrantFiled: March 4, 2005Date of Patent: May 31, 2011Assignee: Ulvac, Inc.Inventors: Akisuke Hirata, Shinji Isoda, Yutaka Kadowaki, Katsuhiko Mushiake
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Patent number: 7771839Abstract: An aluminum alloy brazing sheet which has a clad of a sacrificial anode material/a core alloy/an intermediate material/a filler alloy, wherein number density ratios N1/N2 and N1/N3 each are 1.5 or more, in which a number density ((the number of grains)/?m3) of an intermetallic compound having a sphere-equivalent grain diameter of 0.1 ?m or less present in the core alloy, the intermediate material, and the sacrificial anode material, is represented by N1, N2, and N3, respectively.Type: GrantFiled: December 6, 2006Date of Patent: August 10, 2010Assignees: Furukawa-Sky Aluminum Corp., Denso CorporationInventors: Atsushi Fukumoto, Akio Niikura, Kenji Negura, Keiichi Okazaki, Tatsuo Ozaki, Toshihide Ninagawa
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Patent number: 7749613Abstract: A multi-layer aluminum brazing sheet including a core layer, interliner, braze clad layer and a sacrificial layer, in which the post-braze strength of the brazing sheet is optimized by controlling the manganese (Mn), silicon (Si), copper (Cu) and magnesium (Mg) contents of the core layer and the Mn, Si and Cu content of the interliner and the Mn, Si and Zn content of the sacrificial layer and the specifics of the braze thermal cycle. The brazing sheet maintains corrosion resistance, while optimizing post-braze strength, by utilizing 0.5 wt. % to 1.2 wt. % Cu in the interliner. Further, the interliner and sacrificial layer of the brazing sheet contain low or no magnesium to maintain the brazing sheet's braze-ability.Type: GrantFiled: April 21, 2006Date of Patent: July 6, 2010Assignees: Alcoa Inc., Kobe Steel Ltd.Inventors: Fumihiro Koshigoe, Akihiro Tsuruno, Toshiki Ueda, Stephen F. Baumann
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Patent number: 7627356Abstract: A multifilament high temperature superconductor with thick, striated stabilizer is disclosed, including a substrate, a buffer layer, a multifilament superconductor layer, and at least one thick stabilizer layer. Also disclosed are components incorporating superconducting tapes and methods for manufacturing same.Type: GrantFiled: July 14, 2006Date of Patent: December 1, 2009Assignee: SuperPower, Inc.Inventors: Xun Zhang, Venkat Selvamanickam
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Patent number: 7374827Abstract: A metallurgical product consists essentially of a core aluminum alloy, purposefully tailored through chemistry and processing route to resist recrystallization during the brazing cycle to intentionally exploit the higher strengths immediately after brazing of a deformed and recovered microstructure, the core aluminum alloy being bonded on one side to an aluminum alloy interliner designed to be resistant to localized erosion, which, in turn, is bonded to a 4xxx calling alloy.Type: GrantFiled: October 12, 2005Date of Patent: May 20, 2008Assignee: Alcoa Inc.Inventor: Raymond J. Kilmer
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Patent number: 7247392Abstract: An aluminum alloy heat exchanger having a tube composed of a thin aluminum alloy clad material, wherein, in the clad material, one face of an aluminum alloy core material containing Si 0.05–1.0 mass % is clad with an Al—Si-series filler material containing Si 5–20 mass %, and the other face is clad with a sacrificial material containing Zn 2–10 mass % and/or Mg 1–5 mass %, and wherein an element diffusion profile of the clad material by EPMA satisfies (1) and/or (2): L-LSi-LZn?40(?m) ??(1) L-LSi-LMg?5(?m) ??(2) wherein L is a tube wall thickness (?m); LSi is a position (?m) indicating an amount of Si diffused from the filler material; and LZn and LMg each represent a region (?m) indicating an amount of Zn or Mg diffused from the sacrificial material, respectively; and a method of producing the heat exchanger.Type: GrantFiled: November 30, 2004Date of Patent: July 24, 2007Assignees: Furukawa-Sky Aluminum Corp., Denso CorporationInventors: Kazumitsu Sugano, Noriyuki Yamada, Akio Niikura, Yoshiaki Ogiwara, Masaki Shimizu, Kenji Negura, Sunao Fukuda, Yoshihiko Kamiya
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Patent number: 6921584Abstract: The invention relates to a series of extra strong and durable aluminium alloy brazing sheets with enhanced corrosion resistance for brazed heat exchangers. The alloy sheets are based on recycled materials and are suitable for manufacturing of fins, welded tubes, headers and sideplates. The alloy sheets showed improved corrosion performance with respect to pitting corrosion, excellent high temperature sagging resistance and post braze strength, and a good brazeability. By optimising the material combination of fin, tube, header and sideplates it is possible to produce a heat exchanger with adequate corrosion performance in SWAAT.Type: GrantFiled: May 3, 2002Date of Patent: July 26, 2005Assignee: Norsk Hydro ASAInventors: Morten Syslak, Gro Stakkestad, Jon Dag Evensen, Xiao-Jun Jiang, Børge Bjørneklett
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Patent number: 6911267Abstract: The present invention is directed to a brazing sheet comprising an aluminum 3xxx series core alloy wherein at least one side thereof is provided with an aluminum clad material comprising from 0.7-2.0% Mn and 0.7-3.0.0% Zn, wherein the clad is capable of being used as an Inner-liner of a heat exchange product. In one embodiment one side of the core alloy is provided a material that comprises from 0.7-2.0% Mn and 0.7-3.0% Zn and the other side of the core is provided with an aluminum alloy comprising at least 5.5% Si. Thee are further provided methods for preparing brazing sheets as described herein as well as methods for use of brazing sheet materials including as tube stock and as heat exchangers, as well as other applications.Type: GrantFiled: September 10, 2003Date of Patent: June 28, 2005Assignee: Pechiney Rolled ProductsInventors: H. Scott Goodrich, Scott L. Palmer, Gregory R. Johnson, Zayna M. Connor
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Patent number: 6794022Abstract: A metal plate coated with a lubricating resin is coated with a lubricating resin having a modified polyamide ({circle around (1)}) and a crosslinking curing agent ({circle around (2)}) of the modified polyamide ({circle around (1)}) on at least one side face of the metal plate. At this time, the compounding ratio of the modified polyamide ({circle around (1)}) and the above-described crosslinking curing agent ({circle around (2)}) is preferably (60:40) to (15:85) by mass ratio converted to solid content. Furthermore, according to requirement, an inorganic powder filler ({circle around (3)}) may be added to the resin composition.Type: GrantFiled: April 6, 2001Date of Patent: September 21, 2004Assignees: Kabushiki Kaisha Kobe Seiko Sho, Sun Aluminum Industries Co., Ltd.Inventors: Naoya Fujiwara, Eiichiro Yoshikawa, Hiroshi Kawai, Mikio Ono, Yasuhiro Okamura
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Publication number: 20040121181Abstract: A method for protection of submerged marine surfaces from bio-fouling which is carried out by spraying the surface to be protected with a solvent free, zinc or zinc based alloy coating produced by a thermal spray process.Type: ApplicationFiled: August 29, 2002Publication date: June 24, 2004Inventor: Edwin Young Call
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Patent number: 6696168Abstract: A composite strip of compacted powders, which has a three layers structure, is continuously obtained by means of a rolling machine for powder compacting. The composite strip is sintered at a temperature of 460° C. to 550° C. to form a sintered composite strip. The sintered composite strip is continuously bonded by rolling to a steel strip. The bonded composite strip is optionally subjected to a heat treatment of heating at a temperature of 250° C. to 400° C. followed by heating to a temperature of 400° C. to 510° C., holding the strip under the temperature for not less than 30 seconds, and rapidly cooling down to 300° C. at a cooling rate of not lower than 50° C./minute, whereby obtaining a multi-layered composite material consisting of the steel strip, a sintered bonding layer, a sintered sliding layer and a sintered sacrificial layer.Type: GrantFiled: April 29, 2002Date of Patent: February 24, 2004Assignee: NDC Company Ltd.Inventors: Yasukuni Hasegawa, Koue Ohkawa, Hiroyuki Sugawara
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Patent number: 6667115Abstract: The present invention is directed to a brazing sheet comprising an aluminum 3xxx series core alloy, wherein at least one side thereof is provided with an aluminum clad material comprising 0.7-2.0% Mn and 0.7-3.0% Zn, wherein the clad is capable of being used as an inner-liner of a heat exchanger product. In one embodiment, one side of the core alloy is provided with a material that comprises 0.7-2.0% Mn and 0.7-3.0% Zn and the other side of the core is provided with an aluminum alloy comprising at least 5.5% Si. There are further provided methods for preparing brazing sheets as described herein as well as methods for use of brazing sheet materials including as tube stock and as heat exchangers, as well as other applications.Type: GrantFiled: January 16, 2002Date of Patent: December 23, 2003Assignee: Pechiney Rolled ProductsInventors: H. Scott Goodrich, Scott L. Palmer, Gregory R. Johnson, Zayna M. Connor
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Patent number: 6649282Abstract: A tin-plating or aluminum-plating surface treated steel material with excellent corrosion resistance containing an intermetallic compound composed of one or more Group IIa (alkaline earth metal) elements and one or more Group IVb elements in a tin-based plating layer or aluminum-based plating layer on the surface of a steel material. For a tin-based plating layer, the long diameter of the intermetallic compound massive bodies is 1 82 m or greater and the short diameter/long diameter ratio is at least 0.4. For an aluminum-based plating layer, the long diameter of the intermetallic compound massive bodies is 10 &mgr;m or greater and the short diameter/long diameter ratio is at least 0.4.Type: GrantFiled: December 26, 2001Date of Patent: November 18, 2003Assignee: Nippon Steel CorporationInventors: Shinichi Yamaguchi, Jun Maki, Teruaki Izaki, Masao Kurosaki, Hisaaki Sato, Hidetoshi Shindo, Seiji Sugiyama
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Patent number: 6627330Abstract: An aluminum alloy brazing sheet has a quad-layer structure made of an outer filler material, intermediate layer material, core material, and inner filler material. The core material contains 0.5-1.6% of Mn, 0.10-0.50% of Cu, 0.05-0.50% of Mg, and 0.06-0.30% of Ti, and, as impurities, 0.5% or less of Fe, 0.5% or less of Si, and 0.1% or less of Zn, with the remainder being Al and unavoidable impurities; the intermediate layer material contains 0.2-1.5% of Mg and at least one of 0.5-4% of Zn, 0.005-0.2% of In, and 0.01-0.2% of Sn, and, as impurities, 0.3% or less of Si, 0.3% or less of Fe, 0.05% or less of Cu, 0.05% or less of Mn, and 0.3% or less of Ti, with the remainder being Al and unavoidable impurities. The thickness of the intermediate layer material is 50 &mgr;m or more and no more than the thickness of the core material. The outer filler material and the inner filler material are Al—Si—Mg alloys, the outer filler material, preferably including at least one of 0.005-0.2% of In and 0.01-0.Type: GrantFiled: June 19, 2000Date of Patent: September 30, 2003Assignees: Sumitomo Light Metal Industries, Ltd., Denso CorporationInventors: Masaki Shimizu, Haruhiko Miyachi, Toshihiko Fukuda, Hiroshi Ikeda, Yoshifusa Shoji
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Patent number: 6613452Abstract: A system and method for producing a corrosion-resistant article includes a metal substrate and a multi-layer resistant coating disposed over the metal substrate. The coating is operable to resist corrosion and hydrogen embrittlement of the metal substrate. The coating includes a first layer comprising a material galvanically similar to the metal substrate. The coating also includes a second layer disposed over the first layer. The second layer comprises a metal anodic to the metal substrate. The corrosion resistant article may also include a corrosion resistant interface layer at the boundary of the first and second layers. The interface layer may be formed by diffusing a portion of the second layer into the first layer.Type: GrantFiled: January 16, 2001Date of Patent: September 2, 2003Assignee: Northrop Grumman CorporationInventor: John Douglas Weir
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Patent number: 6610422Abstract: The method for manufacturing coated steel sheet has the steps of: immersing a steel sheet in a hot-dip coating bath to form an Al—Zn base coating layer containing 20 to 95 mass % Al on the steel sheet, forming a passivated layer on the coating layer; and applying thermal history to the coating layer. The thermal history is applied immediately after the steel sheet left the hot-dip coating bath or in a temperature range of from T(° C.) between 130° C. and 300° C. to 100° C.Type: GrantFiled: September 26, 2002Date of Patent: August 26, 2003Assignee: NKK CorporationInventors: Toshihiko Ooi, Takafumi Yamaji, Keiji Yoshida, Yuichiro Tanaka, Junichi Inagaki, Masaaki Yamashita, Yasuhiro Majima, Nobuyuki Ishida, Yuichi Fukushima, Norio Inoue, Shinji Hori
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Patent number: 6555251Abstract: A four layer composite including a first interliner positioned between a 4xxx series braze clad and a core alloy and a second interliner positioned on the opposite side of the core alloy from the first interliner. At least one of the first and second interliners has higher amounts of Si than that of the core alloy adjacent thereto. The higher Si content interliner preferably contains about 0.02-1.1 wt. % Si.Type: GrantFiled: December 19, 2001Date of Patent: April 29, 2003Assignee: Alcoa Inc.Inventor: Raymond J. Kilmer
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Patent number: 6528183Abstract: Clad sheet made up of a core sheet and a cladding layer on one or two core sheet surfaces. The core sheet is formed of an alloy having the composition (% by weight) Si: 0.7-1.3, Mg: 0.6-1.2, Cu: 0.5-1.1, Mn: 0.15-1.0, Zn<0.5, Fe<0.5, Zr<0.2, Cr<0.25, other elements <0.05 each and <0.15 total, the remainder aluminum. The cladding is formed of an AlZn alloy having a thickness of between 1 and 15% of the clad sheet thickness, having the composition (% by weight) Zn: 0.25-0.7, Fe<0.40, Si<0.40, Cu, Mn, Mg, V or Ti <0.10, other elements <0.05 each and 0.15 total.Type: GrantFiled: July 5, 2001Date of Patent: March 4, 2003Assignee: Pechiney RhenaluInventors: Ronan Dif, Bernard Bes, Philippe Lassince, Herve Ribes
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Publication number: 20030012972Abstract: A composite strip of compacted powders, which has a three layers structure, is continuously obtained by means of a rolling machine for powder compacting. The composite strip is sintered at a temperature of 460° C. to 550° C. to form a sintered composite strip. The sintered composite strip is continuously bonded by rolling to a steel strip. The bonded composite strip is optionally subjected to a heat treatment of heating at a temperature of 250° C. to 400° C. followed by heating to a temperature of 400° C. to 510° C., holding the strip under the temperature for not less than 30 seconds, and rapidly cooling down to 300° C. at a cooling rate of not lower than 50° C./minute, whereby obtaining a multi-layered composite material consisting of the steel strip, a sintered bonding layer, a sintered sliding layer and a sintered sacrificial layer.Type: ApplicationFiled: April 29, 2002Publication date: January 16, 2003Inventors: Yasukuni Hasegawa, Koue Ohkawa, Hiroyuki Sugawara
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Patent number: 6465113Abstract: An aluminum alloy brazing sheet having a four-layered structure, of sheet thickness 0.2 mm or less, and having a core alloy, a filler alloy of an Al—Si alloy on one surface of the core alloy, a sacrificial anode material of an Al—Zn alloy on the other surface of the core alloy, and an intermediate layer between the core alloy and sacrificial anode material, wherein the core alloy is composed of an Al alloy containing given amounts of Si, Fe, Mn, and Cu, with the balance being made of Al and unavoidable impurities, and wherein the intermediate layer is composed of an Al alloy containing given amounts of Si, Fe, Mn, and Cu, with the balance being made of Al and unavoidable impurities.Type: GrantFiled: August 9, 2001Date of Patent: October 15, 2002Assignees: The Furukawa Electric Company, Ltd., Denso CorporationInventors: Noriyuki Yamada, Takeyoshi Doko, Yoshiaki Ogiwara, Satoshi Tanaka, Sunao Fukuda, Yoshihiko Kamiya, Masaki Shimizu, Kenji Negura
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Patent number: 6451453Abstract: Strip or drawn tube for the manufacture of a brazed heat exchanger, formed from an aluminum alloy containing Si, Cu and Mn, with optional amounts of Mg, Fe, Zn and Ti, where Fe≦Si, and Cu+Mg>0.4. In the form of a strip, the alloy may be coated on one or both surfaces with an aluminum brazing alloy.Type: GrantFiled: July 20, 2000Date of Patent: September 17, 2002Assignee: Pechiney RhenaluInventors: Jean-Claude Kucza, Ravi Shahani, Bruce Morere, Jean-Luc Hoffmann
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Patent number: 6403232Abstract: A core material of an aluminum brazing sheet restricts Mg to less than 0.3 wt % and Fe to not more than 0.2 wt %, and contains more than 0.2 wt % and not more than 1.0 wt % of Cu, 0.3 to 1.3 wt % of Si, 0.3 to 1.5 wt % of Mn and the balance of Al and inevitable impurities. A brazing filler material is formed on one surface of the core material by Al—Si based aluminum alloy. Also, a cladding material is formed on the other surface of the core material, and contains less than 0.2 wt % of Si, 2.0 to 3.5 wt % of Mg, not less than 0.5 wt % and less than 2.0 wt % of Zn and the balance of Al and inevitable impurities. Further, the value (cladding material hardness)/(the core material hardness) that is a ratio of the hardness of the cladding material to the hardness of the core material is not more than 1.5.Type: GrantFiled: July 25, 2001Date of Patent: June 11, 2002Assignees: Kobe Alcoa Transportation Products Ltd., Denso CorporationInventors: Tadashi Okamoto, Osamu Takezoe, Takahiko Nagaya, Yasuaki Isobe, Taketoshi Toyama, Sunao Fukuda
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Publication number: 20020037426Abstract: An aluminum alloy brazing sheet having a four-layered structure, of sheet thickness 0.2 mm or less, and having a core alloy, a filler alloy of an Al—Si alloy on one surface of the core alloy, a sacrificial anode material of an Al—Zn alloy on the other surface of the core alloy, and an intermediate layer between the core alloy and sacrificial anode material, wherein the core alloy is composed of an Al alloy containing given amounts of Si, Fe, Mn, and Cu, with the balance being made of Al and unavoidable impurities, and wherein the intermediate layer is composed of an Al alloy containing given amounts of Si, Fe, Mn, and Cu, with the balance being made of Al and unavoidable impurities.Type: ApplicationFiled: August 9, 2001Publication date: March 28, 2002Inventors: Noriyuki Yamada, Takeyoshi Doko, Yoshiaki Ogiwara, Satoshi Tanaka, Sunao Fukuda, Yoshihiko Kamiya, Masaki Shimizu, Kenji Negura
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Publication number: 20020037425Abstract: A brazing sheet product and a method of manufacturing a brazing sheet product in which a layer comprising nickel is plated onto a surface of a clad layer made of an aluminium-silicon alloy containing silicon in the range of 2 to 18 weight %, wherein the surface is pre-treated by application of a bonding layer comprising zinc or tin. The application of the bonding layer may be by a zincate or a stannate treatment. The use of lead to promote wetting during brazing can be reduced or avoided, or other elements such as bismuth can be used.Type: ApplicationFiled: May 19, 2000Publication date: March 28, 2002Inventors: Joop Nicolaas Mooij, Adrianus Jacobus Wittebrood, Jacques Hubert Olga Joseph Wijenberg
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Patent number: 6361882Abstract: A high-strength aluminum alloy clad material for heat exchangers which excels in corrosion resistance and formability before brazing and has improved strength after brazing. The aluminum alloy clad material is made up of a core material and a brazing material, with one or both sides of the core material clad with the brazing material. The core material is made up of an aluminum alloy containing from 0.3% to less than 0.6% of Mn, from more than 0.6% to 1.0% of Cu, less than 0.1% of Si, 0.3% or less of Fe, and from 0.06% to 0.35% of Ti, with the remainder being Al and impurities; and the brazing material used to clad the core material is made up of an Al—Si aluminum alloy in which the Ca content is limited to 0.006% or less.Type: GrantFiled: October 31, 2000Date of Patent: March 26, 2002Assignee: Sumitomo Light Metal Industries, Ltd.Inventors: Yoshifusa Shoji, Kohichi Maeda, Toshihiko Fukuda
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Patent number: 6337147Abstract: Improved shape and strength of the weld in a welded structure are obtained by use of a weldable aluminum product comprising a structural component which is a sheet, a plate or an extruded body and is made of an aluminum alloy containing not more than 1.5 wt % Zn. This component has, adhered on at least one side, a cladding layer made of an AA7xxx-series alloy having a corrosion potential lower than that of the alloy of the structural component. The alloy of the structural component is preferably an AA5xxx-series alloy containing Mg in the range 2 to 6 wt %.Type: GrantFiled: March 17, 2000Date of Patent: January 8, 2002Assignee: Corus Aluminium Walzprodukte GmbHInventors: Alfred Johann Peter Haszler, Klaus Alfons Mechsner
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Patent number: 6316126Abstract: An aluminum alloy clad material for heat exchangers exhibiting excellent erosion-corrosion resistance, corrosion resistance, pitting resistance, and brazability, which is suitably used as an aluminum alloy clad sheet for forming a constituent member, in particular, a tube for an aluminum heat exchanger such as a radiator and heater, and as a pipe for circulating a working fluid in the aluminum heat exchanger or a pipe connected to the heat exchangers. The aluminum alloy clad sheet comprises a sacrificial anode material clad on one side of a core material, wherein the core material comprises an Al—Mn alloy and the sacrificial anode material comprises an aluminum alloy, for example, an aluminum alloy comprising 3.0-12.0% of Si with the remaining portion consisting of Al and impurities, or an aluminum alloy comprising 3.0-12.0% of Si, 1-10% of Zn, and 0.15-1.2% of Fe with the remaining portion consisting of Al and impurities.Type: GrantFiled: October 14, 1999Date of Patent: November 13, 2001Assignees: Denso Corporation, Sumitomo Light Metal Industries, Ltd.Inventors: Yoshiharu Hasegawa, Haruhiko Miyachi, Hisao Kato, Hirokazu Tanaka, Hiroshi Ikeda, Yoshifusa Shoji
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Patent number: 6309761Abstract: A process in which a steel is dipped in an aluminum-based bath wherein the composition and mean temperature of the bath and the immersion temperature of the steel are adjusted to obtain, in the immersion zone of the steel, a local bath temperature and composition resulting in an equilibrium with the solid phase designated as &thgr;≡FeAl3. Dipping is performed at a temperature higher than the temperatures normally employed in the art and a coating is obtained having at the interface with the steel an alloy layer significantly smaller in thickness than the art. The coating obtained better resists cracking and corrosion.Type: GrantFiled: February 18, 2000Date of Patent: October 30, 2001Assignee: SollacInventors: Philippe Guesdon, Jean-Pierre Godin, Eric Lesueur
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Publication number: 20010009724Abstract: Deposition of metal in a preferred shape, including coatings on parts, or stand-alone materials, and subsequent heat treatment to provide improved mechanical properties. In particular, the method gives products with relatively high yield strength. The products often have relatively high elastic modulus, and are thermally stable, maintaining the high yield strength at temperatures considerably above 25° C. This technique involves depositing a material in the presence of a selected additive, and then subjecting the deposited material to a moderate heat treatment. This moderate heat treatment differs from other commonly employed “stress relief” heat treatments in using lower temperatures and/or shorter times, preferably just enough to reorganize the material to the new, desired form. Coating and heat treating a spring-shaped substrate provides a resilient, conductive contact useful for electronic applications.Type: ApplicationFiled: January 29, 2001Publication date: July 26, 2001Inventors: Jimmy Kuo-Wei Chen, Benjamin N. Eldridge, Thomas H. Dozier, Junjye J. Yeh, Gayle J. Herman
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Patent number: 6261706Abstract: An aluminum alloy clad material for heat exchangers exhibiting superior strength after brazing and excellent corrosion resistance is provided. The aluminum alloy clad material comprises a sacrificial anode material which is clad on one side of a core material, wherein the core material comprises an aluminum alloy comprising 0.3-2.0% of Mn, 0.25-1.0% of Cu, 0.3-1.1% of Si, and 0.05-0.35% of Ti with the remaining portion consisting of aluminum and impurities, the sacrificial anode material comprises an aluminum alloy comprising 1.5-8% of Zn, 0.01-0.8% of Si, and 0.01-0.3% of Fe with the remaining portion consisting of aluminum and impurities, and the total number of particles of Si compounds and Fe compounds with a particle diameter (circle equivalent diameter) of 1 &mgr;m or more present in the sacrificial anode material matrix is 2×104 or less per 1 mm2. The clad material is suitably used as a tube material or header plate material for automotive heat exchangers such as a radiator or heater core.Type: GrantFiled: October 6, 1999Date of Patent: July 17, 2001Assignees: Denso Corporation, Sumitomo Light Metal Industries, Ltd.Inventors: Sunao Fukuda, Yoshihiko Kamiya, Taketoshi Toyama, Hirokazu Tanaka, Hiroshi Ikeda, Yoshifusa Shoji
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Patent number: 6209816Abstract: Various parts in an assembly of parts are made of differing metals having incompatible ionization characteristics. Any two parts which have incompatible ionization characteristics are separated from one another such that corrosion inducing contact therebetween is eliminated. Therefore, the possibility of electrolytical corrosion can be reduced. For example, in one embodiment a spool assembly in a spinning reel includes a spool (12) made of a magnesium alloy mounted on a spool shaft (16). The spool shaft (16) is made of a stainless steel. Stainless steel and the magnesium alloy have ionization characteristics that are not compatible, leading to possible electrolytic corrosion therebetween. However, a sleeve (20) is disposed between the spool (12) and spool shaft (16). The sleeve (20) is made of an aluminum alloy that has ionization characteristics that are compatible with both the magnesium alloy and stainless steel.Type: GrantFiled: December 7, 1998Date of Patent: April 3, 2001Assignee: Shimano Inc.Inventors: Yasuhiro Hitomi, Ken'ichi Kawasaki, Yasushi Nishimura
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Patent number: 6143428Abstract: Magnesium materials or components made of magnesium materials are protected against corrosion by a surface coating made of an alloy. The protective alloy coating contains a base alloy component A and at least one additive alloying component B. The base alloy component A is either titanium, or zirconium or magnesium. The alloying component B is selected from the following group: alkali metals, alkaline earth metals, rare-earth metals, yttrium, metals of the groups IIb, IIIa, IVa, and Va of the fourth or higher period of the periodic table of elements, and manganese.Type: GrantFiled: July 26, 1999Date of Patent: November 7, 2000Assignee: DaimlerChrysler AGInventors: Heike Bommer, Felix Nitschke
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Patent number: 6129143Abstract: A brazing sheet which has an excellent corrosion resistance and cladding rolling property, and is formed from a four layer aluminum alloy cladding member, and a heat exchanger of aluminum alloy, in which the brazing sheet is used, are provided. The brazing sheet is suitable for use as a member in the fluid path of an aluminum heat exchange for a car, and particularly, as a core plate of a drawn cup type heat exchanger. In the brazing sheet, one side of a core member is cladded with an intermediate member less noble than a core member, and the other side of both the core member and the intermediate member are cladded with Al--Si--Mg type cladding member, wherein the core member is of an aluminum alloy containing 0.5 to 1.6% of Mn, 0.15 to 0.35% of Cu, 0.05 to 0.50% of Mg, 0.06 to 0.30% of Ti, and the remainder being Al and unavoidable impurities, and the intermediate member contains 0.5 to 1.2% of Mn and the remainder being aluminum and unavoidable impurities, and 0.05 to 1.Type: GrantFiled: August 5, 1997Date of Patent: October 10, 2000Assignees: Denso Corporation, Sumitomo Light Metal Industries, Ltd.Inventors: Yoshiharu Hasegawa, Haruhiko Miyachi, Yuji Suzuki, Hiroshi Ikeda, Hirokazu Tanaka, Takahiro Koyama, Koji Hirao
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Patent number: 6063510Abstract: The present invention relates to an Al alloy brazing sheet for use in vacuum brazing, which is applied to manufacture a heat exchanger having a tank portion and a refrigerant passage respectively formed by bonding press-formed brazing sheets together by means of vacuum brazing. The brazing sheet includes an Al alloy core material having a composition consisting of 0.5 to 2.0 mass % (hereinafter abbreviated simply as %) of Mn, 0.1 to 1.0% of Cu, 0.05 to 0.5% of Mg and 0 to 0.3%. of Ti, with the remainder being Al and inevitable impurities. An Al--Si--Mg alloy brazing filler metal or an alloy brazing filler metal prepared by further adding 0.05 to 1.0% of Sn to the Al--Si--Mg alloy brazing filler metal, is clad on both surfaces of the sheet to a thickness of 5 to 20% the total sheet thickness. An intermediate layer consisting of an Al alloy having a composition consisting of 0.5 to 2.0% of Mn, 0.05 to 0.5% of Mg and 0 to 0.Type: GrantFiled: March 4, 1997Date of Patent: May 16, 2000Assignee: The Furukawa Electric Co., Ltd.Inventors: Yoshihito Inabayashi, Hiroshi Kano, Noboru Soga, Haruhiko Miyachi, Eiichi Torigoe
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Patent number: 5989735Abstract: A coating for protecting metal components against corrosion in a saline atmosphere comprises at least one layer of a tin/zinc alloy containing between 8% and 35% by weight of zinc deposited on a sublayer of an alloy of zinc/nickel containing between 10% and 16% by weight of nickel, the thickness proportion of the two alloys forming the coating being two-thirds in the case of the zinc/nickel alloy and one-third in the case of the tin/zinc alloy. The coating may also include an external chromate film.Type: GrantFiled: May 18, 1998Date of Patent: November 23, 1999Assignee: Societe Nationale d'Etude et de Construction de Moteurs d'Aviation "SNECMA"Inventors: Michel Ruimi, Jean-Paul Guerbert-Jubert
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Patent number: 5744255Abstract: A typical aluminum alloy brazing material includesover 7.0 wt. % and not more than 12.0 wt. % of Si: over 0.1 wt. % and not more than 8.0 wt. % of Cu. over 0.05 wt. % and not more than 0.5 wt. % or Fe, further at least one kind selected from a group consisting of over 0.5 wt. % and not more than 5.5 wt. % of Zn. over 0.002 wt. % and not more than 0.3 wt % of In and over 0.002 wt. % and not more than 0.3 wt. % of Sn, and the balance of Al an inevitable impurities. A typical cladded aluminum alloy brazing sheet with a three-layer structure includes a brazing material, a core material comprising over 0.6 wt. % and not more than 2.5 wt. % of Si, over 0.5 wt. % and not more 2.5 wt. % of Cu, over 0.05 wt. % and not more than 2.0 wt. % of Mn, and the balance of Al and inevitable impurities, and a sacrificial material comprising at least one kind selected from a group consisting of over 0.5 wt. % and not more than 6.0 wt. % of Zn. over 0.002 wt. % and not more than 0.3 wt. % of In, and over 0.002 wt.Type: GrantFiled: September 3, 1996Date of Patent: April 28, 1998Assignees: Furukawa Electric Co., Ltd., Nippondenso Co., Ltd.Inventors: Takeyoshi Doko, Koji Okada, Tokinori Onda, Hiroaki Takeuchi, Yoji Hirano
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Patent number: 5654084Abstract: An enhanced protective coating to prevent interaction between constituents of the environment and devices that can be damaged by those constituents. This coating is provided by applying a synergistic combination of diffusion barrier and physical barrier materials. These materials can be, for example, in the form of a plurality of layers of a diffusion barrier and a physical barrier, with these barrier layers being alternated. Further protection in certain instances is provided by including at least one layer of a getter material to actually react with one or more of the deleterious constituents. The coating is illustrated by using alternating layers of an organic coating (such as Parylene-C.TM.) as the diffusion barrier, and a metal coating (such as aluminum) as the physical barrier. For best results there needs to be more than one of at least one of the constituent layers.Type: GrantFiled: July 22, 1994Date of Patent: August 5, 1997Assignee: Martin Marietta Energy Systems, Inc.Inventor: Charles M. Egert
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Patent number: 5564496Abstract: A composite parting sheet is disclosed for separating hot and cold layers in a heat exchanger core. Known parting sheets being primarily aluminum are subject to leakage due to corrosion and failure resulting from thermal fatigue stress. The composite sheet of the present invention includes a first aluminum outer layer, a second aluminum outer layer and a central metallic layer between and in contact with the first and second aluminum outer layers so that the central metallic layer comprises a continuous, uninterrupted layer between the first and second outer layers, and the central metallic layer is a metal that is more noble than aluminum, such as nickel. Corrosion penetrating either of the outer layers to produce a pin hole preferentially corrodes aluminum over the central metallic layer. Therefore, the corrosion expands sideways upon contact with the central metallic layer, and the pin hole does not penetrate the layer or the parting sheet, thereby inhibiting corrosion induced leakage.Type: GrantFiled: November 1, 1994Date of Patent: October 15, 1996Assignee: United Technologies CorporationInventors: Bernard S. Blum, Mark Zaffetti
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Patent number: 5449563Abstract: Reinforcing steel bar (rebar) in reinforced concrete is inhibited from corrosion by attaching a zinc wire, such as by welding, soldering or co-extrusion, along the length of the rebar. Zinc wire attached to the rebar provides galvanic protection to the steel to prevent iron corrosion and subsequent deterioration of the reinforced concrete.Type: GrantFiled: May 20, 1994Date of Patent: September 12, 1995Assignee: Cominco Ltd.Inventor: Xiaoge G. Zhang
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Patent number: 5350791Abstract: Substantially improved retention of hydrophilicity after exposure to high temperature can be provided on a metal substrate, particularly an aluminum alloy of the type used for heat exchanger fins by an aqueous liquid hydrophilicizing treatment composition containing acrylic and/or methacrylic acid polymer or copolymer, polyether alcohol, and alkali metal silicate. The treatment composition may also contain an anti-microbial agent and additional alkalinizer. The hydrophilicizing treatment is preferably applied over a conventional conversion coating, particularly a chromium phosphate or chromium oxide conversion coating.Type: GrantFiled: May 14, 1993Date of Patent: September 27, 1994Assignee: Henkel CorporationInventor: Chi-Fan Hsu
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Patent number: 5292595Abstract: A clad aluminum alloy material having high strength and high corrosion resistance for a heat exchanger, which is composed of a core material made of an aluminum alloy consisting of 0.3 to 2.0% of Mn, 0.25 to 0.8% of Cu, 0.05 to 1.0% of Si and 0.5% or less of Mg with the balance consisting of Al and unavoidable impurities; a sacrificial anode material bonded to one surface of the core material, the sacrificial anode material being made of an aluminum alloy consisting of 1.0 to 2.5% of Mg and 0.05 to less than 0.20% of Si with the balance consisting of Al and unavoidable impurities; and a cladding bonded to the other surface of the core material, the cladding being made of a brazing filler metal consisting of an Al-Si-base aluminum alloy. In the clad aluminum alloy materials, the core material may further include 0.35% or less of Ti and the sacrificial anode material may further include 3.0% or less of Zn or at least one member selected from the group consisting of 0.2% or less of In, 0.2% or less of Sn and 0.Type: GrantFiled: February 17, 1993Date of Patent: March 8, 1994Assignee: Sumitomo Light Metal Industries, Ltd.Inventors: Shigenori Yamauchi, Yoshifusa Shoji, Kenji Kato, Yuji Suzuki, Chian T. Su, Mituo Hashiura, Sunao Fukuda
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Patent number: 5268236Abstract: A composite aluminum plate suitable for making targets for coating processes, and methods for making them are disclosed. The plate comprises a surface layer of pure aluminum or an alloy of pure aluminum, and a supporting layer made of a hardenable aluminum alloy having a Brinell hardness index HB of at least about 50 after being heat-treated under suitable conditions. The targets made are suitable for physical or sputter coating processes such as cathodic sputtering and magnetron sputtering.Type: GrantFiled: June 21, 1991Date of Patent: December 7, 1993Assignee: Vereinigte Aluminum-Werke AGInventors: Christian M. Dumont, Norberg W. Schmitz, Hans Quaderer