Expanded Metal Patents (Class 429/242)
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Patent number: 6737196Abstract: A lithium (Li) polymer battery is provided. The Li polymer battery includes: a positive plate including a positive collector having a plurality of openings and a positive active material layer on at least one surface of the positive collector; a negative plate including a negative collector in a foil form, and a negative active material layer on at least on surface of the negative collector; and a separator between the positive and negative plates, for insulating the positive and negative plates.Type: GrantFiled: October 12, 1999Date of Patent: May 18, 2004Assignee: Samsung Display Devices Co., Ltd.Inventors: Youn-han Chang, Jung-ho Kim
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Patent number: 6733926Abstract: An electrode component for an electrochemical cell or a capacitor is described wherein the electrode is produced by physical vapor depositing an electrode active material onto a substrate to coat the substrate. The thusly produced electrode is useful as a cathode in a primary electrochemical cell and as a cathode and an anode in a secondary cell, and as an electrode in an electrochemical capacitor and an electrolytic capacitor.Type: GrantFiled: December 12, 2001Date of Patent: May 11, 2004Assignee: Wilson Greatbatch Ltd.Inventors: Barry C. Muffoletto, Ashish Shah, Neal N. Nesselbeck
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Patent number: 6682851Abstract: Concave portions and convex portions are formed on a peripheral surface of a thin metal sheet by applying a pressing force thereto while the metal sheet is being embossed; pores are each formed on an apex of each of the concave portions and convex portions and burrs each projecting outward from a peripheral edge of each of the pores are generated by the pressing force; the metal sheets having the concave portions and convex portions formed thereon are layered on each other; the burr at the apex of each convex portion of a lower-layer metal sheet is interlocked with the burr at the apex of each concave portion of an upper-layer metal sheet adjacent to the lower-layer metal sheet to integrate the metal sheets with each other; and an active substance is charged into spaces between the upper-layer metal sheet and the lower-layer metal sheet through an aperture at the apex of each of the concave portions and convex portions.Type: GrantFiled: April 11, 2002Date of Patent: January 27, 2004Assignee: Katayama Special Industries, Ltd.Inventor: Hirofumi Sugikawa
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Patent number: 6678926Abstract: An improved apparatus and method for making lead-acid storage battery plates comprising an alignment puncher for creating a plurality of alignment holes in a lead strip as the lead strip is progressively expanded and cut into a grid like pattern on an expander die system. The alignment of the lead strip is accomplished by inserting at least one alignment pin into at least one of the plurality of alignment holes that have been punched into the lead strip as the lead strip is progressively expanded and cut into a plurality of wire-like segments along opposing edges of the lead strip. After each cut, the alignment pin retracts while the lead strip is indexed.Type: GrantFiled: June 22, 2001Date of Patent: January 20, 2004Assignee: Delphi Technologies, Inc.Inventor: Jimmy H. Watters
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Patent number: 6653013Abstract: A battery comprising an electricity-generating element comprising a strip-form positive electrode, a strip-form negative electrode, and a strip-form separator, said positive electrode and said negative electrode being spirally wound through said separator and said positive electrode and said negative electrode respectively having current collecting lugs protruding from a side thereof, wherein the pitches of the current collecting lugs become longer toward the outer periphery side, and the at least one current collecting lug that located on the outer side has a larger width than that located on the inner side. In this battery, the electricity-generating element has at least one current collecting lug which has a larger width than the adjacent current collecting lug located on the inner side thereof.Type: GrantFiled: November 1, 2001Date of Patent: November 25, 2003Assignee: Japan Storage Battery Co., Ltd.Inventor: Makoto Hisai
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Patent number: 6620506Abstract: Fluid permeable graphite article in the form of a perforated flexible graphite sheet having increased electrical and thermal conductivity transverse to the surfaces of the sheet.Type: GrantFiled: September 26, 2002Date of Patent: September 16, 2003Assignee: Advanced Energy Technology Inc.Inventors: Robert Angelo Mercuri, Thomas William Weber, Michael Lee Warddrip
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Publication number: 20030157406Abstract: An anode comprises one or more sheets of expanded zinc mesh. The thickness and mesh size of the expanded zinc mesh may vary. A single sheet of zinc mesh may be coiled, forming continuous electrical contact with itself. Alternatively, a single sheet of zinc mesh may be folded into layers, each layer in electrical contact with its adjacent layers. A third alternative is the use of two or more sheets of zinc mesh, layered on top of each other so that each layer is in electrical contact with adjacent layers. These zinc mesh anodes are combined with a casing, a cathode, an electrolyte solution, and a separator between the cathode and anode to manufacture electrochemical cells.Type: ApplicationFiled: February 15, 2002Publication date: August 21, 2003Applicant: Alltrista Zinc Products, L.P.Inventors: Jack T. West, Jim Dyer, Albert H. Giles, Jon Headrick, Johnny Smelcer, Randy Beets
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Publication number: 20030134202Abstract: A lithium (Li) polymer battery is provided. The Li polymer battery includes: a positive plate including a positive collector having a plurality of openings and a positive active material layer formed on at least one surface of the positive collector; a negative plate including a negative collector in a foil form, and a negative active material layer formed on at least on surface of the negative collector; and a separator between the positive and negative plates, for insulating the positive and negative plates.Type: ApplicationFiled: October 12, 1999Publication date: July 17, 2003Inventors: YOUN-HAN CHANG, JUNG-HO KIM
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Publication number: 20030096170Abstract: A storage battery is provided in which an expand grid is improved with respect to the widths of grid wires 1b, the sectional areas of nodes 1e, and the shapes of meshes 1c, whereby the productivity of the expand grid can be enhanced and the life performance can be improved.Type: ApplicationFiled: November 21, 2002Publication date: May 22, 2003Applicant: Japan Storage Battery Co., Ltd.Inventors: Yoshiomi Fujiwara, Hiroyuki Tanaka
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Publication number: 20030082455Abstract: The invention provides a grid for a battery plate in which, when a metal sheet is formed into a grid-like shape, rupture due to torsion or stress concentration does not occur in a basal portion of a wire which is drawn out from a node of the grid, thereby preventing corrosion due to electrolyte from advancing so as not to cause a crack of corrosion in an early stage. The invention provides also a battery using the grid for a battery plate, a method of producing the grid for a battery plate, and a battery using it.Type: ApplicationFiled: June 20, 2002Publication date: May 1, 2003Applicant: Japan Storage Battery Co., Ltd.Inventors: Yoshiomi Fujiwara, Ken Sawai
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Patent number: 6541157Abstract: It is intended to provide a nonaqueous electrolyte battery that satisfies both of a large discharge capacity and a superior cycle life characteristic by developing a novel negative electrode material. A nonaqueous electrolyte battery uses a negative electrode active material that is a compound expressed by Formula (1): AzMXy (1) where A is at least one element selected from the alkali metals, M is at least one element selected from the group consisting of Ti, V, Cr, Mn, Fe, Co, Ni, Cu, Ru, Rh, Pd, Os, Ir, Pt, and Mg, X is at least one element selected from the group consisting of B, N, Al, Si, P, Ga, Ge, As, In, Sn, Sb, Pb, and Bi, 0≦z≦20, and 0.2≦y≦6.Type: GrantFiled: August 9, 2000Date of Patent: April 1, 2003Assignee: Kabushiki Kaisha ToshibaInventors: Hiroki Inagaki, Norio Takami, Tatsuoki Kohno, Tomokazu Morita
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Patent number: 6506484Abstract: Fluid permeable graphite article in the form of a perforated flexible graphite sheet having increased electrical and thermal conductivity transverse to the surfaces of the sheet.Type: GrantFiled: January 24, 2000Date of Patent: January 14, 2003Assignee: Graftech Inc.Inventors: Robert Angelo Mercuri, Thomas William Weber, Michael Lee Warddrip
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Publication number: 20020197530Abstract: A rechargeable battery having an anode comprising a powdery composite material, said powdery composite material comprising a plurality of powdery composites having a structure comprising a core whose surface is covered by a coat layer, said core comprising an alloy particle of an alloy capable of reversibly storing and releasing hydrogen as a main component, said alloy containing at least one kind of a metal element selected from the group consisting of Zr, Ti and V as a main constituent element, and said coat layer comprising a hydrous oxide (including a hydroxide) of a metal element having an affinity with oxygen which is greater than that of any of said metal elements as the main constituent element of said alloy.Type: ApplicationFiled: March 8, 2002Publication date: December 26, 2002Inventors: Atsushi Tani, Soichiro Kawakami
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Patent number: 6479179Abstract: Microthin sheet technology is disclosed by which superior batteries are constructed which, among other things, accommodate the requirements for high load rapid discharge and recharge, mandated by electric vehicle criteria. The microthin sheet technology has process and article overtones and can be used to form corrugated thin electrodes used in batteries of various kinds and types, such as spirally-wound batteries, bipolar batteries, lead acid batteries, silver/zinc batteries, and others. Superior high performance battery features include: (a) minimal ionic resistance; (b) minimal electronic resistance; (c) minimal polarization resistance to both charging and discharging; (d) improved current accessibility to active material of the electrodes; (e) a high surface area to volume ratio; (f) high electrode porosity (microporosity); (g) longer life cycle; (h) superior discharge/recharge characteristics; (i) higher capacities (A·hr); and (j) high specific capacitance.Type: GrantFiled: January 5, 2000Date of Patent: November 12, 2002Assignee: Bipolar Technolgies CorporationInventor: Rodney M. LaFollette
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Patent number: 6461771Abstract: The basket weave structures has a lattice construction surrounded by a frame and comprising first strand structures intersecting second strand structures to provide a plurality of diamond-shaped openings or interstices bordered by the strands. The strand structures intersect or join with each other at junctions thereby forming the current collector as an integral unit.Type: GrantFiled: June 20, 2000Date of Patent: October 8, 2002Assignee: Wilson Greatbatch Ltd.Inventors: Christine A. Frysz, Dominick J. Frustaci, Joseph M. Probst, William C. Thiebolt, III, William M. Paulot
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Patent number: 6455201Abstract: Concave portions and convex portions are formed on a peripheral surface of a thin metal sheet by applying a pressing force thereto while the metal sheet is being embossed; pores are each formed on an apex of each of the concave portions and convex portions and burrs each projecting outward from a peripheral edge of each of the pores are generated by the pressing force; the metal sheets having the concave portions and convex portions formed thereon are layered on each other; the burr at the apex of each convex portion of a lower-layer metal sheet is interlocked with the burr at the apex of each concave portion of an upper-layer metal sheet adjacent to the lower-layer metal sheet to integrate the metal sheets with each other; and an active substance is charged into spaces between the upper-layer metal sheet and the lower-layer metal sheet through an aperture at the apex of each of the concave portions and convex portions.Type: GrantFiled: June 7, 1999Date of Patent: September 24, 2002Assignee: Katayama Special Industries, Ltd.Inventor: Hirofumi Sugikawa
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Patent number: 6451472Abstract: A lithium polymer battery having a positive electrode including a positive electrode current collector and positive electrode sheets on at least one surface of the positive electrode current collector, the positive electrode sheets having a positive electrode active material layer as a main component, a negative electrode including a negative electrode current collector and negative electrode sheets on at least one surface of the negative electrode current collector, the negative electrode sheets having a negative electrode active material layer as a main component, and a separator interposed between the positive electrode and the negative electrode, for insulating the electrodes from each other. The positive electrode and the negative electrode of the lithium polymer battery each include a plate and are wound with the separator interposed therebetween.Type: GrantFiled: April 3, 2000Date of Patent: September 17, 2002Assignee: Samsung SDI Co., Ltd.Inventors: Youn-han Chang, Jung-ho Kim
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Patent number: 6447957Abstract: A collector for a secondary battery includes a metal foil having throughholes shaped or arranged to achieve an increased hole area ratio to improve an active material's adhesion thereto. A throughhole in the metal foil has a largest dimension of at least 1.55 mm, and the foil has a hole area ratio of at least 40%, and a thickness of at least 5 &mgr;m and at most 200 &mgr;m. The throughhole has a peripheral shape including two substantially straight sides that extend along lines intersecting with each other on their respective extensions to form an acute angle at a corner of the throughhole. To form the metal foil, a resist film with a predetermined pattern is arranged on a solid foil, and is used as a mask to etch the foil to provide the plurality of throughholes penetrating the foil.Type: GrantFiled: April 5, 2000Date of Patent: September 10, 2002Assignee: Toyo Aluminum Kabushiki KaishaInventors: Hiroyuki Sakamoto, Hiroshi Tada, Toshihisa Tamai
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Patent number: 6410181Abstract: An alkali metal electrochemical cell, and particularly a lithium oxyhalide cell, is described. The oxyhalide cell also exhibits superior restart characteristics by the provision of a MANNIGLASS 1200 separator.Type: GrantFiled: May 2, 2000Date of Patent: June 25, 2002Assignee: Wilson Greatbatch Ltd.Inventors: David M. Spillman, Esther S. Takeuchi
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Patent number: 6410189Abstract: This invention provides a polymer rechargeable battery, which is obtained by integrally holding a separator, which comprises a polymer and a plasticizer, between positive and negative electrodes and then replacing the plasticizer with an electrolyte solution. The positive and negative electrodes are provided with current collectors obtained by etching metal-foil base materials, respectively. This invention also provides such current collectors. The polymer rechargeable battery according to this invention is excellent in impedance characteristic, load characteristic and the like.Type: GrantFiled: December 23, 1999Date of Patent: June 25, 2002Assignee: Tokai Aluminum Fiol Co., Ltd.Inventors: Kazunori Yamada, Toshiaki Watanabe, Shuhel Kubota, Shizuo Sugawara
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Patent number: 6399253Abstract: A collector, an electrode and a secondary battery adopting the same. The secondary battery includes: an electrode assembly having electrodes obtained by attaching an active material sheet to at least one side of a flat collector with a plurality of through holes formed in a predetermined pattern, and a separator interposed between the electrodes; a case for sealing the electrode assembly; and tabs connected to terminals of the electrode assembly and extended outwards the case, wherein the through holes have a regular polygonal shape and the rib widths among the through holes are equal.Type: GrantFiled: April 10, 2000Date of Patent: June 4, 2002Assignee: Samsung SDI Co., Ltd.Inventors: Youn-han Chang, Jung-ho Kim
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Publication number: 20020064711Abstract: A method for making positive grids for lead-acid batteries from calcium-tin-silver lead-based alloys comprises casting an alloy strip and then rolling the strip at a temperature between about the solvus temperature and the peritectic temperature of the alloy, quenching the rolled strip, then, preferably, heat aging at a temperature of 200° F. to 500° F., and fabricating into the positive grid, such grids having enhanced mechanical and high temperature corrosion resistance characteristics.Type: ApplicationFiled: November 30, 2001Publication date: May 30, 2002Applicant: GNB Technologies, Inc.Inventor: Purushothama Rao
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Patent number: 6385829Abstract: A lead-acid battery electrode plate is manufactured by consecutively supplying a lead or lead alloy sheet; leaving a part in the vicinity of the center of the sheet as a non-expansion portion and expanding both sides like mesh to form a grid body; filling active material paste into the grid body; and cutting the grid body to predetermined dimensions. In the lead-acid battery electrode plate, the non-expansion portion forms a current collector part of the electrode plate along an expansion portion in an up and down direction of the electrode plate. One or more openings are made in a part of the non-expansion portion. A part of the non-expansion portion is projected above the position of an upper margin of the cut expansion portion as a current collector lug part. When the current collector lug part is placed upside, the expansion direction is the width direction of the electrode plate.Type: GrantFiled: June 13, 2001Date of Patent: May 14, 2002Assignee: Japan Storage Battery Co., Ltd.Inventors: Takao Omae, Akira Kamada, Masashi Watanabe
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Patent number: 6383675Abstract: In one embodiment, the present invention relates to a third electrode for use in a metal-air tricell comprising a support structure coated with a layer of a lanthanum nickel compound and at least one metal mixture, wherein the mixture is adhered to the support structure without the use of an adhesive. In another embodiment, the present invention relates to a metal-air tricell comprising: an air electrode; a metal electrode; and a third electrode, wherein the third electrode comprises a support structure coated with a mixture of a lanthanum nickel compound and at least one metal, wherein the mixture is adhered to the support structure without the use of an adhesive.Type: GrantFiled: April 20, 2000Date of Patent: May 7, 2002Assignee: Zinc Air Power CorporationInventor: Zhimin Zhong
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Patent number: 6367131Abstract: A method for producing a grid for a lead storage battery has a first step, a second step and a cooling step performed between the first and second step. In the first step, lead alloy is sequentially rolled over a plurality of rolls. In the second step, the rolled sheet obtained at the first step is machined to produce a grid for a lead storage battery. In the cooling step, the rolled sheet is cooled so that (1) the surface temperature thereof is 10° C. or lower at least once and (2) the total time during which the rolled sheet is exposed to an atmosphere of higher than 10° C. is 10 hours or less.Type: GrantFiled: July 13, 2000Date of Patent: April 9, 2002Assignee: Japan Storage Battery Co., Ltd.Inventors: Takao Omae, Shigeharu Osumi, Kenji Yamanaka, Masahiko Kosai
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Patent number: 6368751Abstract: An electrochemical cathode includes a porous metal foam substrate, formed with a network of interconnected pores. An active layer and a hydrophobic microporous gas diffusion layer are both disposed on one or more surfaces of the metal foam substrate. The metal foam substrate serves as the current collector of the cathode. The microporous layer is a plastic material such as a fluoropolymer (i.e., PTFE). The cathode also includes a particulate microstructure reinforced by relatively strong bonding provided by sintering a polymeric binder within the three-dimensional interconnected porosity of the metal foam substrate. The reactive layers are preferably fabricated from the same material as binder. This advantageously enables a single roll pressing operation to simultaneously impregnate the binder into the substrate and form the reactive layers thereon.Type: GrantFiled: October 8, 1999Date of Patent: April 9, 2002Assignee: Reves, Inc.Inventors: Wayne Yao, Tsepin Tsai
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Publication number: 20020037455Abstract: A nickel-series rechargeable battery whose cathode active material comprising a material containing an amorphous phase-bearing nickel hydroxide particulate which in X-ray diffraction using K&agr;-rays of Cu as a radiation source, has a diffraction peak of a (001) face appeared near a diffraction angle 2&thgr;=19° having a half-value width of more than 1.2° and has a diffraction peak of a (101) face appeared near a diffraction angle 2&thgr;=38° having a half-value width of more than 1.5°. A process for the production of said rechargeable battery.Type: ApplicationFiled: June 15, 2001Publication date: March 28, 2002Inventors: Atsushi Tani, Soichiro Kawakami
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Publication number: 20020034684Abstract: A separator for lead storage batteries is formed from a strip material, having main ribs arranged at regular intervals on the base sheet of the separator as spacers with respect to the positive electrode and reinforcing ribs which lie close together and are of a lower height than the main ribs arranged in the region which covers the lateral electrode edge. In the region of the reinforcing ribs, an additional rib which is of the same height as the main ribs bears against the lateral edge of the positive electrode and may be arranged symmetrically with respect to the main ribs, is provided at each separator edge, parallel to the main ribs.Type: ApplicationFiled: August 29, 2001Publication date: March 21, 2002Applicant: VB Autobatterie GmbHInventor: Frank Muller-Rinke
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Patent number: 6338918Abstract: An electrode comprises a porous three-dimensional conductive support and at least one reinforcing metal band fixed along a longitudinal edge portion of the support and having a coefficient of elongation to rupture equal to at least 20% in a direction parallel to the edge portion of the support. Two longitudinal edge portions of the band are bent against the same face of the band, at least part of whose surface is pressed against the support.Type: GrantFiled: December 21, 1999Date of Patent: January 15, 2002Assignee: AlcatelInventors: Georges Caillon, Rémi Najean, Christian Pineau, Christian Dupuy, Jérôme Mazalrey, Jean-Yves Kerybin
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Patent number: 6338919Abstract: A lead-acid battery electrode plate is manufactured by consecutively supplying a lead or lead alloy sheet; leaving a part in the vicinity of the center of the sheet as a non-expansion portion and expanding both sides like mesh to form a grid body; filling active material paste into the grid body; and cutting the grid body to predetermined dimensions. In the lead-acid battery electrode plate, the non-expansion portion forms a current collector part of the electrode plate along an expansion portion in an up and down direction of the electrode plate. One or more openings are made in a part of the non-expansion portion. A part of the non-expansion portion is projected above the position of an upper margin of the cut expansion portion as a current collector lug part. When the current collector lug part is placed upside, the expansion direction is the width direction of the electrode plate.Type: GrantFiled: January 21, 2000Date of Patent: January 15, 2002Assignee: Japan Storage Battery Co., Ltd.Inventors: Takao Omae, Akira Kamada, Masashi Watanabe
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Patent number: 6332900Abstract: An electrode component for an electrochemical cell or a capacitor is described wherein the electrode is produced by physical vapor depositing an electrode active material onto a substrate to coat the substrate. The thusly produced electrode is useful as a cathode in a primary electrochemical cell and as a cathode and an anode in a secondary cell, and as an electrode in an electrochemical capacitor and an electrolytic capacitor.Type: GrantFiled: February 7, 2000Date of Patent: December 25, 2001Assignee: Wilson Greatbatch Ltd.Inventors: Barry C. Muffoletto, Ashish Shah, Neal Nesselbeck
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Publication number: 20010042288Abstract: A lead-acid battery electrode plate is manufactured by consecutively supplying a lead or lead alloy sheet; leaving a part in the vicinity of the center of the sheet as a non-expansion portion and expanding both sides like mesh to form a grid body; filling active material paste into the grid body; and cutting the grid body to predetermined dimensions. In the lead-acid battery electrode plate, the non-expansion portion forms a current collector part of the electrode plate along an expansion portion in an up and down direction of the electrode plate. One or more openings are made in a part of the non-expansion portion. A part of the non-expansion portion is projected above the position of an upper margin of the cut expansion portion as a current collector lug part. When the current collector lug part is placed upside, the expansion direction is the width direction of the electrode plate.Type: ApplicationFiled: June 13, 2001Publication date: November 22, 2001Applicant: JAPAN STORAGE BATTERY CO., LTD.Inventors: Takao Omae, Akira Kamada, Masashi Watanabe
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Patent number: 6291104Abstract: A lead-acid storage battery uses as a current collector an expanded grid produced by processing a belt shaped material formed of lead or lead alloys. Strand of a grid for negative electrodes have a twist. The extent of the negative electrode's grid is larger than that of the positive electrode's grid. Accordingly, degradation of output characteristics in the domain deep in the depth of discharge is prevented and further high rate discharge cycle life characteristics are improved.Type: GrantFiled: October 28, 1998Date of Patent: September 18, 2001Assignee: Matsushita Electric Industrial Co., Ltd.Inventors: Yasuyuki Yoshihara, Kazuyoshi Yonezu, Go Kashio, Fumiaki Seta
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Publication number: 20010012589Abstract: A lead-acid storage battery includes a positive electrode, a negative electrode and an electrolyte material. The foregoing negative electrode has a first grid with a first grid geometry and a first active material provided on the above first grid. The foregoing positive electrode has a second grid with a second grid geometry and a second active material provided on the above second grid. A first mesh area of the foregoing first grid is smaller than a second mesh area of the foregoing second grid, thereby achieving an excellent high rate discharge cycle life.Type: ApplicationFiled: October 28, 1998Publication date: August 9, 2001Inventors: YASUYUKI YOSHIHARA, YOSHIHIRO MURATA, TAKASHI HATTORI, AKIRA INANOBE
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Patent number: 6265099Abstract: An electrochemical generator comprising thin films including a positive electrode and its collector, and a sheet of a host metal intended to later on constitute a negative electrode, as well as an electrolyte which is conductive towards alkaline ions and also a source of alkali ions. The sheet of the host metal has voids whose quantity and arrangement are capable of locally absorbing any lateral expansion of the sheet of host metal and thereby substantially preventing all cumulative change in the plane of the sheet of host metal when there is an initial formation of alloy in the sheet between the host metal and an alkali metal which is brought about by the alkaline ions. A method of manufacturing such a generator is also described.Type: GrantFiled: April 13, 1998Date of Patent: July 24, 2001Assignee: Hydro-QuébecInventors: Michel Gauthier, Michel Armand, Karim Zaghib, Sylvain Poirier, Roger Bellemare
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Patent number: 6248476Abstract: A novel air cathode and the metal air cells made therewith are provided. With a conductive air diffusion layer of carbon black and polymeric materials, the current collecting substrate is disposed on one side of the air diffusion layer while the active layer is on the other side of the air diffusion layer. The current collecting substrate is in good contact with both the air diffusion layer and the cathode can of the cell, and it has absolutely no direct contact with the active layer. The performance of cells made therewith are significantly improved in high drain discharge situations and the internal impedance of the cells is reduced.Type: GrantFiled: June 25, 1999Date of Patent: June 19, 2001Inventors: Fajiong Sun, Fang Wang
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Patent number: 6245462Abstract: A battery grid, suitable for use in a lead-acid battery, with a grid upper portion having a grid wires defining a first grid pattern, and a grid lower portion electrically connected to the grid upper portion. The grid lower portion having grid wires defining a second grid pattern, wherein the first grid pattern is different from said second grid pattern to improve the conductivity of the grid.Type: GrantFiled: May 20, 1999Date of Patent: June 12, 2001Assignee: Johnson Controls Technology CompanyInventors: Wen-Hong Kao, Edward N. Mrotek
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Patent number: 6243932Abstract: A manufacturing method for an expanded grid includes the steps of: (a) supplying a thin plate of band form from the longitudinal direction, (b) forming a plurality of intermittent cuts parallel to the edge in a first region, excluding the central portion, of the thin plate of band form, (c) bending the central portion at a desired angle, and (d) expanding and developing the cuts in the width direction, while moving sequentially in the longitudinal direction the thin plate having the first region forming the plurality of cuts and the central portion not having the cuts, in which the first track distance of the outermost side portion of the first region having the cuts developed and formed is nearly the same distance as the track distance of the central portion. The plane distortion of the grid is eliminated, the width dimension of the grid is stable, and the quality of the electrode plate using such grid is enhanced. Further, local stress concentration of the grid is suppressed.Type: GrantFiled: August 27, 1998Date of Patent: June 12, 2001Assignee: Matsushita Electric Industrial Co., Ltd.Inventors: Go Kashio, Akira Iwamura
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Patent number: 6187473Abstract: A cylindrical alkaline storage battery including a spiraled electrode body composed of a pair of opposed electrodes spirally rolled up through a separator and coupled within a cylindrical casing, at least one of the electrodes being in the form of a non-sintered type electrode composed of an active material retention substrate of three dimensionally meshed structure impregnated with paste of an active material, and a current collector formed with a disc portion for connection to one end portion of the non-sintered type electrode and a lead portion for connection to a terminal, wherein the one end portion of the non-sintered type electrode is formed without impregnation of the paste of the active material, and wherein a perforated sheet metal welded to the one end portion of the non-sintered type electrode is welded at its side edge to the disc portion of the current collector.Type: GrantFiled: November 18, 1998Date of Patent: February 13, 2001Assignee: Sanyo Electric Co., Ltd.Inventors: Shigeto Tamezane, Takaaki Ikemachi, Takashi Yamaguchi, Satoshi Narukawa
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Patent number: 6180285Abstract: A battery has an organic electrolyte, a negative electrode having at least one metal out of alkaline metal and alkaline metal alloy, and a positive electrode including a conductive core having at least one metal out of porous metal plate and metal mesh, wherein an active material covers the core. At least a part of one side of the core is exposed from the active material at a position confronting the negative electrode, and the width of narrowest part of the metal is greater than the thickness of the negative electrode. In this constitution, the discharge reaction is delayed in the exposed portion of the core of the positive electrode. By this delay in discharge reaction, the electric connection of the negative electrode is maintained up to the end of discharge. Hence, voltage drop at the end of discharge is suppressed. As a result, the battery having an excellent discharge capacity up to the end of the discharge is obtained.Type: GrantFiled: July 31, 1998Date of Patent: January 30, 2001Assignee: Matsushita Electric Industrial Co., Ltd.Inventors: Masahiko Yoshida, Fumio Daio
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Patent number: 6117593Abstract: Arc spray deposition of molten metal droplets on plastic electrodes creates a tight bonded adhesion and increases the surface area contact between collector and electrode. This is especially efficacious for lithium secondary batteries which are known to flex during charge and discharge cycles leading to battery failure. The strength of the bonding interaction, and a resistance to stress cracking are observed when a perforated or expanded metal strip is utilized to reinforce the arc spray deposited metal collector.Type: GrantFiled: June 15, 1998Date of Patent: September 12, 2000Assignee: Johnson Manufacturing, LLCInventors: Timothy J. Stachoviak, Joseph P. Nestler, Daniel A. Schneider, Shirley A. Craanen, Amy K. Lawrence
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Patent number: 6114066Abstract: A method and apparatus for producing lead storage batteries are provided. sentially grid-shaped lead electrodes are produced and are provided with a pasty, active mass. Immediately thereafter separator material is provided on both sides of the electrodes. The electrodes are stacked, electrically connected, and placed in a housing to form a cell unit, which is subsequently stored to effect curing of the pasty, active mass.Type: GrantFiled: March 9, 1998Date of Patent: September 5, 2000Assignee: Accumulatorenwerke Hoppecke Carl Zoellner & Sohn GmbH & Co. KGInventors: Werner Nitsche, Norbert Lahme, Gunter Sassmannshausen
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Patent number: 6110622Abstract: A current collector in the form of a conductive substrate subjected to a special chemical etch on both major surfaces to provide a "basket weave" structure, is described. The basket weave structures has a lattice construction surrounded by a frame and comprising first strand structures intersecting second strand structures to provide a plurality of diamond-shaped openings or interstices bordered by the strands. The strand structures intersect or join with each other at junctions thereby forming the current collector as an integral unit.Type: GrantFiled: July 22, 1998Date of Patent: August 29, 2000Assignee: Wilson Greatbatch Ltd.Inventors: Christine A. Frysz, Dominick J. Frustaci, Joseph M. Probst, William C. Thiebolt, III, William M. Paulot
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Patent number: 6037081Abstract: A slit is formed in a clad sheet integrating a thin layer of lead alloy containing at least one of tin and antimony at least on one side ot a parent material made of lead or lead-calcium system alloy. The clad sheet is processed by expanding to twist the rib of the formed grid, and the thin layer of the lead alloy containing at least one of tin and antimony is spirally oriented in multiple directions, as the positive electrode plate. An expanded grid is thus formed. In this manner charging reception characteristics after long-term storage following deep discharge at high temperature ot a lead-acid battery are improved.Type: GrantFiled: September 9, 1998Date of Patent: March 14, 2000Assignee: Matsushita Electric Industrial Co., LtdInventors: Go Kashio, Yasuyuki Yoshihara
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Patent number: 5993999Abstract: A current collector for an electrode with two halves. The current collector has a first layer positioned on the first half of the electrode, a second layer positioned on the second half of said electrode, and a third layer positioned between the first and the second halves of the electrode.Type: GrantFiled: May 15, 1998Date of Patent: November 30, 1999Assignee: AER Energy Resources, Inc.Inventors: Miranda Rivers, Lawrence A. Tinker
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Patent number: 5981107Abstract: To obtain a lithium ion secondary battery having excellent charge and discharge characteristics in which electric connection between active material layers and a separator can be maintained without requiring a strong armor metal case, so that it can be made into thin forms having large energy density. Convex parts and concave parts are formed on at least two surfaces among surfaces of a positive electrode active material layer 7 and a negative electrode active material layer 9 both adjacent to a separator 4 and surfaces of the separator 4 facing both of the active material layers 7, 9, and these three means are bonded and closely adhered by an adhesive resin layer 11 and electrically connected by keeping a lithium ion-containing electrolytic solution in the separator 4 and voids 12 formed by a bonded surface 11a of the convex parts and the concave parts.Type: GrantFiled: December 15, 1997Date of Patent: November 9, 1999Assignee: Mitsubishi Denki Kabushiki KaishaInventors: Kouji Hamano, Hisashi Shiota, Shou Shiraga, Shigeru Aihara, Yasuhiro Yoshida, Michio Murai, Takayuki Inuzuka
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Patent number: 5965295Abstract: An alkaline secondary battery comprising a positive electrode, a negative electrode, and an alkaline electrolyte, wherein the positive electrode comprises a conductive substrate and a mixture held by the conductive substrate, the mixture containing nickel hydroxide and a conductive cobalt compound, and the positive electrode has pores, substantially all of the pores each having a diameter with a range of 0.0001 .mu.m to 10 .mu.m.Type: GrantFiled: June 13, 1997Date of Patent: October 12, 1999Assignee: Toshiba Battery Co., Ltd.Inventors: Naomi Bando, Tetsuya Yamane, Masayoshi Hiruma, Makoto Wakabayashi, Kunihiko Miyamoto, Takeshi Fukuju, Ken Komiyama, Hiroshi Kaneko, Ken-ichi Kanno
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Patent number: 5948566Abstract: The use of a continuous process for making a directly cast strip to provide a thickness satisfactory for industrial cells and batteries for stationary and motive power applications is disclosed, the thickness of the strip being at least 0.060 inch, and the process providing a visually crack-free surface in the transverse direction of the directly cast strip, the strip being lead or a lead-based alloy, such as, for example, calcium-tin-silver.Type: GrantFiled: September 4, 1997Date of Patent: September 7, 1999Assignee: GNB Technologies, Inc.Inventors: Steven R. Larsen, Andrew Foote
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Patent number: 5874186Abstract: A lead-acid cell or battery includes positive plates made from a lead-based alloy containing calcium, tin, and silver in amounts selected based upon the type of application and the plate fabrication method utilized, starting, lighting and ignition battery grids being directly cast and having calcium present in an amount of 0.03% to 0.050%, tin in an amount of 0.65% to 1.25%, and silver in an amount of from 0.018% to 0.030%, and the grids used in sealed, lead-acid cells comprising, when made by gravity casting, from about 0.035% to 0.055% calcium, 0.95% to 1.45% tin, and 0.018% to 0.030% silver, and, when made by continuous strip casting, calcium in the range of from 0.030% to 0.050%, tin in the range of from 0.95% to 1.25%, and silver in the range of from 0.017% to 0.030%, all of the alloy percentages being based upon the total weight of the grid.Type: GrantFiled: June 11, 1997Date of Patent: February 23, 1999Assignee: GNB Technologies, Inc.Inventors: Purushothama Rao, Thomas F. Uhlemann
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Patent number: 5858575Abstract: Pb-Ca battery grids are dipped into a bath of molten Pb-Sn or Pb-Ag to prolong the useful life of the battery as determined by the high temperature SAE J240 test.Type: GrantFiled: May 30, 1997Date of Patent: January 12, 1999Assignee: General Motors CorporationInventor: Yu-Lin Chen