Materials Chemically Specified Patents (Class 429/245)
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Patent number: 8679677Abstract: The electrochemical device includes a composite electrode. The composite electrode has a working electrode that includes a current collector. A reference electrode is immobilized on the current collector. The reference electrode includes a reference active medium on a reference current collector. The reference current collector is electrically insulated from the current collector. A top surface of the reference electrode is substantially flush with a top surface of the working electrode. The top surface of the reference electrode is a surface of the reference electrode that is substantially parallel to the reference current collector.Type: GrantFiled: December 21, 2009Date of Patent: March 25, 2014Assignee: Quallion LLCInventors: Ryo Tamaki, Mikito Nagata, Hisashi Tsukamoto
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Publication number: 20140079984Abstract: A non-aqueous secondary battery includes: a positive-electrode collector layer; a positive-electrode layer formed on one surface of the positive-electrode collector layer; a negative-electrode collector layer; a negative-electrode layer formed on one surface of the negative-electrode collector layer so as to be opposed to the positive-electrode layer; a separator provided between the positive-electrode layer and the negative-electrode layer; and a positive-electrode-side insulating layer and a negative-electrode-side insulating layer respectively formed on another surface of the positive-electrode collector layer and another surface of the negative-electrode collector layer. Circumferential inner surfaces of peripheral edges of the positive-electrode collector layer and the negative-electrode collector layer are joined with a sealing agent including at least a positive-electrode fusion layer, a gas barrier layer, and a negative-electrode fusion layer.Type: ApplicationFiled: May 10, 2012Publication date: March 20, 2014Inventors: Hiroshi Kajitani, Kentaro Nakahara, Takanori Nishi, Shigeyuki Iwasa, Haruyuki Yoshigahara, Yoichi Shimizu
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Patent number: 8669006Abstract: A nonaqueous electrolyte secondary battery, having an internal resistance of 10 m? or less as an alternating-current impedance value of 1 kHz, comprises a metal outer container, a nonaqueous electrolyte contained in the container, a positive electrode contained in the container, a negative electrode contained in the container, a separator interposed between the negative electrode and the positive electrode, a negative electrode lead having one end connected to the negative electrode, and a negative electrode terminal attached to the outer container so as to be connected electrically to the other end of the negative electrode lead, at least the surface of the negative electrode terminal which is connected to the negative electrode lead being formed of aluminum alloy with an aluminum purity of less than 99 wt. % containing at least one metal selected from the group consisting of Mg, Cr, Mn, Cu, Si, Fe and Ni.Type: GrantFiled: May 21, 2013Date of Patent: March 11, 2014Assignee: Kabushiki Kaisha ToshibaInventors: Norio Takami, Hiroki Inagaki, Yoshinao Tatebayashi
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Publication number: 20140065457Abstract: The disclosed embodiments provide a battery cell. The battery cell includes an electrode containing an active material and a continuous substrate. The continuous substrate includes a first thickness to maintain a tensile strength of the continuous substrate and a second thickness that is less than the first thickness to accommodate the active material. The first and second thicknesses may thus improve the energy density and/or rate capability of the battery cell without producing manufacturing defects associated with the use of thinner electrode substrates in battery cells.Type: ApplicationFiled: August 28, 2012Publication date: March 6, 2014Applicant: APPLE INC.Inventors: Ramesh C. Bhardwaj, Sheba Devan
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Patent number: 8663841Abstract: A power storage device in which charge capacity and discharge capacity are high and deterioration in battery characteristics due to charge/discharge is small is provided. A power storage device in which charge capacity and discharge capacity are high and output characteristics are excellent is provided. A power storage device in which charge capacity and discharge capacity are high and cycle characteristics are excellent is provided. A power storage device includes a negative electrode. The negative electrode includes a current collector, an active material including a plurality of protrusions protruding from the current collector and an outer shell in contact with and attached to surfaces of the plurality of protrusions, and graphene in contact with and attached to the outer shell. Axes of the plurality of protrusions are oriented in the same direction. A common portion may be provided between the current collector and the plurality of protrusions.Type: GrantFiled: September 13, 2012Date of Patent: March 4, 2014Assignee: Semiconductor Energy Laboratory Co., Ltd.Inventors: Ryota Tajima, Takeshi Osada
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Publication number: 20140057170Abstract: A negative electrode for a rechargeable lithium battery includes an active material layer including a non-carbon-based negative active material, and a first binder having high-strength; a conductive layer including a conductive material and a second binder; and a current collector. The conductive layer is interposed between the active material layer and the current collector.Type: ApplicationFiled: March 14, 2013Publication date: February 27, 2014Applicant: Samsung SDI Co., Ltd.Inventors: Jun-Kyu Cha, Myoung-Sun Kim, Young-su Kim, Ki-Jun Kim
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Publication number: 20140057178Abstract: An anode of a lithium battery includes a carbon nanotube film structure and an anode active material. The carbon nanotube film structure includes a number of carbon nanotubes joined by van der Waals force therebetween. The anode active material is located on surface of the carbon nanotubes to form a tubular structure.Type: ApplicationFiled: April 24, 2013Publication date: February 27, 2014Applicants: HON HAI PRECISION INDUSTRY CO., LTD., TSINGHUA UNIVERSITYInventors: XING-FENG HE, YANG WU, JIA-PING WANG, KAI-LI JIANG, SHOU-SHAN FAN
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Patent number: 8652686Abstract: A composite solid electrolyte includes a monolithic solid electrolyte base component that is a continuous matrix of an inorganic active metal ion conductor and a filler component used to eliminate through porosity in the solid electrolyte. In this way a solid electrolyte produced by any process that yields residual through porosity can be modified by the incorporation of a filler to form a substantially impervious composite solid electrolyte and eliminate through porosity in the base component. Methods of making the composites are also disclosed. The composites are generally useful in electrochemical cell structures such as battery cells and in particular protected active metal anodes, particularly lithium anodes, that are protected with a protective membrane architecture incorporating the composite solid electrolyte.Type: GrantFiled: November 9, 2012Date of Patent: February 18, 2014Assignee: PolyPlus Battery CompanyInventors: Steven J. Visco, Lutgard C. De Jonghe, Yevgeniy S. Nimon
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Patent number: 8637189Abstract: An electrode sheet includes a sheet of metal foil, at least one region coated with at least one active material layer subjected to working by rolling, the at least one coated region being provided in at least one central portion of the sheet of metal foil, at least one region uncoated with the at least one active material layer, the at least one uncoated region being provided in at least one edge portion of the sheet of metal foil, and at least one region subjected to working by drawing, the at least one drawn region being provided in at least a portion of the at least one uncoated region.Type: GrantFiled: August 5, 2011Date of Patent: January 28, 2014Assignee: GS Yuasa International Ltd.Inventors: Kazuya Okabe, Yoshikatsu Ohtani, Yoshihiro Takaura
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Publication number: 20140017550Abstract: A lithium ion battery includes at least one battery cell. The battery cell includes a cathode electrode, an anode electrode, and a separator. The separator is sandwiched between the cathode electrode and the anode electrode. At least one of the cathode electrode and the anode electrode includes a current collector. The current collector includes a graphene layer and a carbon nanotube layer.Type: ApplicationFiled: October 29, 2012Publication date: January 16, 2014Inventors: JIA-PING WANG, KAI-LI JIANG, SHOU-SHAN FAN
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Patent number: 8623555Abstract: In one aspect of the present invention, an electrode useable in an electrochemical cell includes an electrically conductive substrate, nanostructured current collectors in electrical contact with the conductive substrate, and nanoparticles of a ternary orthosilicate composite coated on the nanostructured current collectors. The ternary orthosilicate composite comprises Li2MnxFeyCozSiO4, where x+y+z=1.Type: GrantFiled: May 25, 2012Date of Patent: January 7, 2014Assignee: Vanderbilt UniversityInventors: Weng Poo Kang, Supil Raina, Shao-Hua Hsu, Siyu Wei
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Publication number: 20130337303Abstract: The disclosed embodiments relate to the manufacture of a battery cell. The battery cell includes a set of layers including a cathode and an anode. The cathode includes a cathode substrate with a thickness in the range of 8-10 microns and a cathode active material. The anode includes an anode substrate with a thickness in the range of 4-6 microns and an anode active material. The cathode active material is coated on the cathode substrate at a rate of 2 mm/min to 3 mm/min, and the anode active material is coated on the anode substrate at a rate of 2 mm/min to 3.8 mm/min. Such substrate thicknesses and coating speeds may increase the energy density of the battery cell over that of a conventional battery cell with thicker cathode and anode substrates while avoiding manufacturing defects associated with the use of thinner substrates in battery cells.Type: ApplicationFiled: June 18, 2012Publication date: December 19, 2013Applicant: APPLE INC.Inventors: Ramesh C. Bhardwaj, Taisup Hwang
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Patent number: 8609279Abstract: A rechargeable lithium battery including a negative electrode made by depositing a noncrystalline thin film composed entirely or mainly of silicon on a current collector, a positive electrode and a nonaqueous electrolyte, characterized in that said nonaqueous electrolyte contains carbon dioxide dissolved therein.Type: GrantFiled: June 3, 2004Date of Patent: December 17, 2013Assignee: Sanyo Electric Co., Ltd.Inventors: Daizo Jito, Noriyuki Tamura, Nobuhiro Sakitani, Hiroshi Minami, Hiromasa Yagi, Maruo Kamino, Katsunobu Sayama, Yoshio Kato, Shigeki Matsuta
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Publication number: 20130309591Abstract: High surface area energy chips that can be used to make high surface area electrodes and methods for making high surface area energy chips are described. The energy chips comprise a monolithic conductive material comprising an open network of pores having an average pore diameter between about 0.3 nm and 30 nm. The conductive material forms a thin chip having a thickness of about 300 microns or less, and the thickness across different portions of the chip varies by less than 10% of the thickness. The high surface area energy chips may be used as electrodes in a variety of energy storage devices and systems such as capacitors, electric double layer capacitors, batteries, and fuel cells.Type: ApplicationFiled: April 25, 2013Publication date: November 21, 2013Applicant: NANOTUNE TECHNOLOGIES CORP.Inventors: Kuan-Tsae HUANG, Shiho WANG, Cheuk Wun WONG, Jaspal SINGH, Yudi YUDI
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Insulator component design for maintaining electrode assembly compression in prismatic medical cells
Patent number: 8580439Abstract: An electrochemical cell comprising a conductive casing housing an electrode assembly provided with a stack holder surrounding the electrode assembly is described. The stack holder is of a shape memory material that serves to maintain the anode and cathode in a face-to-face close physical proximity alignment throughout discharge. This is particularly important in later stages of cell life. As the cell discharges, anode active material is physically moved from the anode to intercalate with the cathode active material. As this mass transfer occurs, the cathode becomes physically larger and the anode smaller. This can lead to gaps forming between the anode and the cathode. However, the stack holder inhibits the formation of such gaps by maintaining a compressive force on the electrode assembly throughout cell discharge.Type: GrantFiled: September 17, 2009Date of Patent: November 12, 2013Assignee: Greatbatch Ltd.Inventors: Donald F. Kaiser, Gregory A. Voss -
Patent number: 8574767Abstract: Thin-film electrodes and battery cells, and methods of fabrication. A thin film electrode may be fabricated from a non-metallic, non-conductive porous support structure having pores with micrometer-range diameters. The support may include a polymer film. A first surface of the support is metalized, and the pores are partially metallized to create metal tubes having a thickness within a range of 50 to 150 nanometers, in contact with the metal layer. An active material is disposed within metalized portions of the pores. An electrolyte is disposed within non-metalized portions of the pores. Active materials may be selected to create an anode and a cathode. Non-metalized surfaces of the anode and cathode may be contacted to one another to form a battery cell, with the non-metalized electrolyte-containing portions of the anode facing the electrolyte-containing portions of the cathode pores. A battery cell may be fabricated as, for example, a nickel-zinc battery cell.Type: GrantFiled: May 18, 2010Date of Patent: November 5, 2013Assignee: The Johns Hopkins UniversityInventors: Rengaswamy Srinivasan, Jeffrey P. Maranchi, Lance M. Baird, Ryan M. Deacon, Arthur S. Francomacaro, Paul J. Biermann, Craig B. Leese, Gary E. Peck
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Patent number: 8563173Abstract: An electrochemical cell in one embodiment includes a negative electrode including a form of lithium, a positive electrode spaced apart from the negative electrode, an electrolyte, a separator positioned between the negative electrode and the positive electrode, and a current collector in the negative electrode, the current collector including a substrate material and a coating material on the surface of the substrate material, wherein the coating material does not include a form of lithium.Type: GrantFiled: May 8, 2009Date of Patent: October 22, 2013Assignee: Robert Bosch GmbHInventors: Boris Kozinsky, John F. Christensen, Nalin Chaturvedi, Jasim Ahmed
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Patent number: 8563178Abstract: A negative electrode for a lithium (Li) secondary battery, a method of forming the same, and a secondary battery, the negative electrode including a tin (Sn) based current collector layer; and a multilayer film on the Sn based current collector, the multilayer film having two or more layers, wherein the multilayer film includes at least one porous layer.Type: GrantFiled: September 21, 2010Date of Patent: October 22, 2013Assignee: Samsung SDI Co., Ltd.Inventors: Kyu-Nam Joo, Tae-Sik Kim, Beom-Kwon Kim
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Patent number: 8557413Abstract: A method of charging and discharging a lithium secondary battery in which a negative electrode comprises an active material including silicon provided on a current collector which is a metal which does not form an alloy with lithium. The method is characterized in that the lithium secondary battery is charged and discharged within a range of state of charge (SOC) at which no peak corresponding to a compound of lithium and silicon is observed in an X-ray diffraction pattern during charging using CuK?-radiation as the X-ray source.Type: GrantFiled: March 24, 2004Date of Patent: October 15, 2013Assignee: Sanyo Electric Co., Ltd.Inventors: Noriyuki Tamura, Maruo Kamino, Shin Fujitani
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Patent number: 8546025Abstract: Disclosed is a lithium ion secondary battery, in which comprises a vinyl alcohol polymer or a derivative thereof in an amount of 0.3 mg or more per 1 mAh of battery capacity in terms of a vinyl alcohol unit moiety content. The lithium ion secondary battery can decrease the battery voltage under high-temperature conditions and cannot be recharged after being exposed to high-temperature conditions.Type: GrantFiled: August 21, 2008Date of Patent: October 1, 2013Assignees: Japan Vilene Company, Ltd., National Institute of Advanced Industrial Science and TechnologyInventors: Masanao Tanaka, Tatsuo Nakamura, Hiroshi Ohnishi, Yuka Kondo, Koji Kimura, Te Hyon Cho, Tetsuo Sakai
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Patent number: 8546017Abstract: Provided is a composite for anode material, a method of manufacturing the composite for anode material, and a cathode and a lithium battery that includes the composite for anode material, and more particularly, to a composite for anode material that has a large charge and discharge capacity and a high capacity retention, a method of manufacturing the composite for anode material, and a cathode and a lithium battery that includes the composite for anode material. Also, the composite for anode material in which Si or Si and carbon are distributed in silicon oxide particles is provided.Type: GrantFiled: May 30, 2008Date of Patent: October 1, 2013Assignee: Samsung SDI Co., Ltd.Inventors: Sang-kook Mah, Han-su Kim
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Patent number: 8541134Abstract: In an electrode according to the present invention including a three-dimensional network aluminum porous body as a base material, the electrode is a sheet-shaped electrode, and a cell of the three-dimensional network aluminum porous body has an elliptic shape having a minor axis in the thickness direction of the electrode in a cross section parallel to the longitudinal direction and thickness direction of the electrode, and a cell of the three-dimensional network aluminum porous body has an elliptic shape having a minor axis in the thickness direction of the electrode in a cross section parallel to the width direction and thickness direction of the electrode. The electrode is preferably obtained by subjecting the three-dimensional network aluminum porous body to at least a current collecting lead welding step, an active material filling step and a compressing step.Type: GrantFiled: August 8, 2012Date of Patent: September 24, 2013Assignees: Sumitomo Electric Industries, Ltd., Sumitomo Electric Toyama Co., Ltd.Inventors: Akihisa Hosoe, Kazuki Okuno, Hajime Ota, Koutarou Kimura, Kengo Goto, Hideaki Sakaida, Junichi Nishimura
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Publication number: 20130209869Abstract: A novel hybrid lithium-ion anode material based on coaxially coated Si shells on vertically aligned carbon nanofiber (CNF) arrays. The unique cup-stacking graphitic microstructure makes the bare vertically aligned CNF array an effective Li+ intercalation medium. Highly reversible Li+ intercalation and extraction were observed at high power rates. More importantly, the highly conductive and mechanically stable CNF core optionally supports a coaxially coated amorphous Si shell which has much higher theoretical specific capacity by forming fully lithiated alloy. Addition of surface effect dominant sites in close proximity to the intercalation medium results in a hybrid device that includes advantages of both batteries and capacitors.Type: ApplicationFiled: February 27, 2013Publication date: August 15, 2013Inventor: Ronald A. Rojeski
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Patent number: 8501353Abstract: An object is to improve characteristics of a power storage device and achieve a long lifetime. In the case where a lithium nitride is used for a negative electrode active material of a power storage device, a plurality of lithium nitride layers with different lithium concentrations are stacked. For example, in the case where a first lithium nitride layer and a second lithium nitride layer are stacked over a current collector, lithium is contained in the first lithium nitride layer at a lower concentration than lithium contained in the second lithium nitride layer. In this case, a concentration of a transition metal of the first lithium nitride layer is higher than a concentration of the transition metal of the second lithium nitride layer. Note that another alkali metal may be used instead of lithium.Type: GrantFiled: September 27, 2010Date of Patent: August 6, 2013Assignee: Semiconductor Energy Laboratory Co., Ltd.Inventors: Tamae Moriwaka, Tatsuya Takahashi
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Publication number: 20130196231Abstract: A battery may include a first electrode and a second electrode. In some examples, the first electrode may include a metal substrate including a major surface, where a plurality of tunnels extend into the major surface, and an electrode composition is deposited onto the major surface of the metal substrate, where a portion of the electrode composition is positioned within the plurality of tunnels. The battery may be positioned within a housing of an implantable medical device (IMD).Type: ApplicationFiled: January 27, 2012Publication date: August 1, 2013Applicant: MEDTRONIC, INC.Inventor: Christian S. Nielsen
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Patent number: 8497041Abstract: An electrochemical cell includes a cathode containing an aluminum current collector, a positive lead coupled to the cathode current collector an anode, and an electrolyte including from greater than 0.075 M to less than 0.2 M of a bis(oxalate)borate salt and a second lithium salt. The positive lead may include a metal selected from aluminum, titanium, and steel. The anode may include lithium, graphite, and a lithiated metal oxide. The aluminum current collector has an aluminum surface having at least one dimension greater than 1 millimeter.Type: GrantFiled: September 12, 2012Date of Patent: July 30, 2013Assignee: The Gillette CompanyInventors: Dana Alexa Totir, Kirakodu S. Nanjundaswamy, Michael Pozin
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Patent number: 8475957Abstract: The present invention relates to a negative electrode structure for use in a non-aqueous electrolyte secondary battery and a method of making such negative electrode structure. The negative electrode structure comprises: a monolithic anode comprising a semiconductor material, and a uniform ion transport structure disposed at the monolithic anode surface for contacting a non-aqueous electrolyte, wherein the uniform ion transport structure serves as a current collector and the negative electrode structure does not contain another current collector. The present invention also relates to a battery comprising the negative electrode structure of the present invention, a cathode, and a non-aqueous electrolyte.Type: GrantFiled: April 17, 2009Date of Patent: July 2, 2013Assignee: Enovix CorporationInventors: Murali Ramasubramanian, Robert M. Spotnitz, Nirav S. Shah, Ashok Lahiri
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Patent number: 8465875Abstract: It is an object of the present invention to provide a sheet-shaped three-dimensional network aluminum porous body for a current collector which is suitably used for electrodes for nonaqueous electrolyte batteries and electrodes for capacitors, an electrode and a capacitor each using the same. In such a three-dimensional network aluminum porous body for a current collector, the aluminum porous body has been made to have a compressive strength in a thickness direction of 0.2 MPa or more in order to efficiently fill an active material into the sheet-shaped three-dimensional network aluminum porous body.Type: GrantFiled: May 30, 2012Date of Patent: June 18, 2013Assignees: Sumitomo Electric Industries, Ltd., Sumitomo Electric Toyama Co., Ltd.Inventors: Akihisa Hosoe, Kazuki Okuno, Hajime Ota, Koutarou Kimura, Kengo Goto, Hideaki Sakaida, Junichi Nishimura
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Patent number: 8465871Abstract: The present invention provides electrochemical cells and batteries having one or more electrically conductive tabs and carbon sheet current collectors, where the tabs are connected to the carbon sheet current collectors; and methods of connecting the tabs to the carbon based current collectors. In one embodiment, the electrically conductive tabs are metallic tabs.Type: GrantFiled: January 4, 2012Date of Patent: June 18, 2013Assignee: Leyden Energy, Inc.Inventors: Marc Juzkow, Aakar Patel, Jun Lui, Konstantin Tikhonov, Michael Erickson, Hashmat Haidari, Thomas Nagy, Hongli Dai
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Patent number: 8460827Abstract: A rechargeable battery including a cathode and an anode each capable of inserting and extracting an electrode reaction material, and including an electrolyte, in which the anode includes an anode current collector which is formed by including a current collector body. The anode current collector is provided thereon with an active anode material layer, and a plurality of conductive particles disposed on the surface of the current collector body with the surface facing the active anode material layer. The plurality of conductive particles is formed to include spherical particles and plate-like particles. Since a tridimensional structure having irregularities is formed on the surface of the current collector body with the spherical particles and plate-like particles, anchoring effects are greatly increased. As a result, the adhesion of the active anode material layer to the anode current collector is considerably improved.Type: GrantFiled: February 25, 2010Date of Patent: June 11, 2013Assignee: Sony CorporationInventors: Masayuki Iwama, Kenichi Kawase, Takakazu Hirose
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Publication number: 20130143124Abstract: The invention relates to electrochemical electrodes containing branched nanostructures having increased surface area and flexibility. These branched nanostructures allow for higher anode density, resulting in the creation of smaller, longer-lasting, more efficient batteries which require less area for the same charging capacity. Also disclosed are methods for creating said branched nanostructures and electrodes.Type: ApplicationFiled: August 23, 2011Publication date: June 6, 2013Applicant: THE RESEARCH FOUNDATION OF STATE UNIVERSITY OF NEW YORKInventors: Jae Ho Lee, Isaac Lund
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Patent number: 8455138Abstract: An anode including: an anode active material; a first binder coating layer formed on the anode active material; a second binder coating layer formed on the first binder coating layer; and a collector, wherein the first binder coating layer has an elasticity higher than the second binder layer and the second binder coating layer is adapted to combine the anode active material with the collector. In the anode, the first binder coating layer that has the relatively high elasticity on the anode active material can tolerate a change in volume of the anode active material. Therefore, a lithium battery that uses the anode has improved cyclic properties and a relatively long lifespan.Type: GrantFiled: September 1, 2006Date of Patent: June 4, 2013Assignee: Samsung SDI Co., Ltd.Inventors: Gue-sung Kim, Jin-hwan Park
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Publication number: 20130136968Abstract: A lithium cell is described having a cathode structure made of a base material which conducts electrons and Li ions. The cathode structure includes a continuous substrate, which provides a continuous base area, starting from which a plurality of crosspieces extends. The crosspieces provide crosspiece surfaces, starting from which carrier structures extend. The carrier structures provide carrier surfaces on which active material is distributed. In addition, an accumulator is also described in which a plurality of lithium cells is stacked. A method for producing a lithium cell is also described.Type: ApplicationFiled: November 8, 2010Publication date: May 30, 2013Inventors: Leonore Glanz, Ulrich Eisele
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Publication number: 20130130119Abstract: A negative electrode collector using a copper-covered steel foil for carrying a negative electrode active material for lithium ion secondary batteries has a steel sheet as the core material thereof and has, on both surfaces thereof, a copper covering layer having a mean thickness tCu of from 0.02 to 5.0 ?m on each surface, and of which the total mean thickness, t, including the copper covering layer 7 is from 3 to 100 ?m with tCu/t of at most 0.3. The steel sheet can be common steel, austenitic stainless steel, or ferritic stainless steel. The copper covering layer can be a copper electroplating layer (including one rolled after plating). On the surface of the copper covering layer, for example, a carbon-based active material layer that has been densified through strong roll pressing is formed, and the copper-covered steel foil and the carbon-based active material layer constitute the negative electrode collector.Type: ApplicationFiled: January 9, 2013Publication date: May 23, 2013Inventors: Sho MAJIMA, Takao Tsujimura, Takeshi Shimizu, Yoshikazu Morita, Takahiro Fujii, Norihiro Kon, Yoshie Yoshida
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Patent number: 8445139Abstract: The disclosure relates to bipolar cells including electrodes surrounding a collector. Embodiments of the bipolar cells include a collector containing a high-polymer material. The disclosure also relates to bipolar electrode batteries containing bipolar cells including a collector body containing electrically conductive high-polymer or electrically conductive particles distributed in a high-polymer. By adding such high molecular weight polymer material to the collector, the weight of the collector may be reduced and the output power density per weight of the battery may be improved. The disclosure further relates to methods of forming collecting bodies and electrodes for bipolar cells using an inkjet printing method. Bipolar cells according to the present invention may be used to fabricate batteries such as lithium ion batteries, which may be connected to form battery modules used, for example, to provide electrical power for a motor vehicle.Type: GrantFiled: December 7, 2005Date of Patent: May 21, 2013Assignee: Nissan Motor Co., Ltd.Inventors: Kenji Hosaka, Osamu Shimamura, Hideaki Horie, Takamitsu Saito, Takuya Kinoshita, Takaaki Abe, Naoto Kiriu
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Publication number: 20130122359Abstract: A positive electrode plate for a lithium ion secondary battery is made of aluminum and includes a positive current collecting foil made of aluminum, in which at least a main surface portion constituting a main surface is porous, a positive active material layer formed on the main surface portion of the positive current collecting foil, and a coating layer, having electrical conductivity and corrosion resistance, formed between the positive current collecting foil and the positive active material layer to directly coat the main surface of the positive current collecting foil.Type: ApplicationFiled: January 8, 2010Publication date: May 16, 2013Inventors: Takayasu Sato, Yuichiro Imamura, Yuki Matsushita
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Publication number: 20130108922Abstract: A lithium ion secondary battery, which uses a negative electrode wherein an active material is deposited on a collector, and which is characterized in that no wrinkles are formed on the collector, the collector does not fracture, the adhesion between the active material and the collector is high, and stable performance can be maintained for a long period of time; an electrode for the secondary battery; and an electrolytic copper foil that constitutes the electrode. Specifically disclosed is an electrolytic copper foil for a lithium ion secondary battery, in which a surface-roughened layer of copper or copper alloy particles having a particle diameter of 0.1-3 ?m is formed on both surfaces of an untreated copper foil by roughening treatment by means of electrolysis, and the surface-roughened layers on both surfaces have a surface roughness Rz of 1.0-5 ?m and a surface roughness Ra of 0.25-0.Type: ApplicationFiled: June 28, 2011Publication date: May 2, 2013Applicant: Furukawa Electric Co., Ltd.Inventors: Kensaku Shinozaki, Akitoshi Suzuki
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CATHODE CURRENT COLLECTOR FOR ELECTRICAL ENERGY STORAGE DEVICE AND METHOD FOR MANUFACTURING THE SAME
Publication number: 20130101902Abstract: Disclosed is a cathode current collector for an electrical energy storage device and a method for manufacturing the same, which improves adhesion between a current collector and an electrode material and provide a high reaction surface area, thereby improving the performance of the electrical energy storage. In particular, a first alumina film is formed on the surface of an aluminum foil using an anodic oxidation process. Next, the first alumina film formed on a surface of the aluminum foil is removed through etching and a second alumina film is formed on the surface of the aluminum foil, from which the first alumina film is removed, using the anodic oxidation process again. Subsequently, a carbon layer is coated on a surface of the aluminum foil on which the second alumina film is formed.Type: ApplicationFiled: January 11, 2012Publication date: April 25, 2013Applicant: HYUNDAI MOTOR COMPANYInventors: Sam Ick Son, Hee Yeon Ryu, Dae Gun Jin -
Publication number: 20130095389Abstract: The disclosed embodiments provide a battery cell. The battery cell includes a cathode current collector containing graphene, a cathode active material, an electrolyte, an anode active material, and an anode current collector. The graphene may reduce the manufacturing cost and/or increase the energy density of the battery cell.Type: ApplicationFiled: October 13, 2011Publication date: April 18, 2013Applicant: APPLE INC.Inventors: Ramesh C. Bhardwaj, Richard M. Mank
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Publication number: 20130071755Abstract: Disclosed is a copper foil for a negative electrode collector capable of simultaneously achieving high capacity and long life charge/discharge cycles in a secondary battery, wherein the front and back surfaces are of a uniform shape and, for example, the properties of a silicon active material of a lithium ion secondary battery are sufficiently realized; and a negative electrode using the copper foil. In one embodiment, a first roughened layer of metallic copper is formed by pulse cathode electrolysis roughening treatment on the surface of an untreated rolled copper foil base material of oxygen-free copper in a first roughening treatment tank (1) filled with a copper-sulphuric acid electrolyte (12), and a second copper-plate layer is formed on the surface of the first roughened layer by smooth copper plating treatment in a second copper plating treatment tank (2) filled with a copper-sulphuric acid electrolyte (22).Type: ApplicationFiled: February 25, 2011Publication date: March 21, 2013Applicant: Furukawa Electric Co., LTD.Inventor: Ryoichi Oguro
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Publication number: 20130071735Abstract: The disclosure describes compositions and methods for producing a change in the voltage at which hydrogen gas is produced in a lead acid battery. The compositions and methods relate to producing a concentration of one or more metal ions in the lead acid battery electrolyte.Type: ApplicationFiled: September 21, 2011Publication date: March 21, 2013Applicant: Hollingsworth & Vose CompanyInventors: John Wertz, Christopher Campion
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Patent number: 8399134Abstract: A lead acid battery includes a housing and at least one cell disposed within the housing. Each cell includes at least one positive plate and at least one negative plate and an electrolyte disposed in a volume between the positive and negative plates. The at least one negative plate includes a current collector, consisting essentially of a layer of carbon foam disposed on a substrate, and a chemically active material disposed on the current collector.Type: GrantFiled: November 20, 2007Date of Patent: March 19, 2013Assignee: Firefly Energy, Inc.Inventors: Kurtis C. Kelley, Matthew J. Maroon
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Patent number: 8389161Abstract: A nonaqueous electrolyte secondary battery includes a positive electrode 4 including a positive electrode current collector and a positive electrode mixture layer including a positive electrode active material and a binder, the positive electrode mixture layer being provided on the positive electrode current collector, a negative electrode 5, a porous insulating layer 6 interposed between the positive electrode 4 and the negative electrode 5, and a nonaqueous electrolyte. The tensile extension of the positive electrode 4 is equal to or higher than 3.0%. The charge end voltage in normal operation of the nonaqueous electrolyte secondary battery is equal to or higher than 4.3 V.Type: GrantFiled: January 22, 2009Date of Patent: March 5, 2013Assignee: Panasonic CorporationInventors: Atsushi Ueda, Yoshiyuki Muraoka
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Publication number: 20130052538Abstract: An electrochemical energy storage device includes a cathode, an anode, and an electrolyte disposed between the cathode and the anode. The anode includes a capacitive material as a majority component, and further includes an electrochemically active material as a minority component, such that an operating potential of the anode is configured according to a reaction potential of the electrochemically active material.Type: ApplicationFiled: May 29, 2012Publication date: February 28, 2013Inventors: Mauro Pasta, Colin Wessells, Robert A. Huggins, Yi Cui
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Patent number: 8383190Abstract: A process for forming a protective layer on a metal surface includes the steps of: providing a metal material having an oxygen containing layer; applying at least two compounds to the oxygen containing layer of the metal material wherein a first compound applied is a molecularly large compound; and applying at least a second compound to the oxygen containing layer of the metal material wherein the second compound is molecularly small.Type: GrantFiled: July 27, 2010Date of Patent: February 26, 2013Assignee: Toyota Motor Engineering & Manufacturing North America, Inc.Inventors: John Muldoon, Monique Richard, Kimber L. Stamm, Emilyne E. Nicolas
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Patent number: 8383272Abstract: A secondary battery that has superior safety and is able to provide more favorable cycle characteristics is provided. A laminated body in which a cathode and an anode are layered with a separator impregnated with an electrolytic solution in between is contained in a package can and a package cup. In the anode, an anode active material layer containing an anode active material such as silicon is provided on an anode current collector in which projection sections are formed on a base material. The base material contains carbon and sulfur respectively having a content ratio of 100 ppm or less, and contains crystallites having an average diameter of from 0.01 ?m to 5 ?m both inclusive.Type: GrantFiled: October 22, 2009Date of Patent: February 26, 2013Assignee: Sony CorporationInventors: Masayuki Iwama, Kenichi Kawase
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Publication number: 20130040195Abstract: In an electrode according to the present invention including a three-dimensional network aluminum porous body as a base material, the electrode is a sheet-shaped electrode, and a cell of the three-dimensional network aluminum porous body has an elliptic shape having a minor axis in the thickness direction of the electrode in a cross section parallel to the longitudinal direction and thickness direction of the electrode, and a cell of the three-dimensional network aluminum porous body has an elliptic shape having a minor axis in the thickness direction of the electrode in a cross section parallel to the width direction and thickness direction of the electrode. The electrode is preferably obtained by subjecting the three-dimensional network aluminum porous body to at least a current collecting lead welding step, an active material filling step and a compressing step.Type: ApplicationFiled: August 8, 2012Publication date: February 14, 2013Applicants: SUMITOMO ELECTRIC TOYAMA CO., LTD., SUMITOMO ELECTRIC INDUSTRIES, LTD.Inventors: Akihisa HOSOE, Kazuki OKUNO, Hajime OTA, Koutarou KIMURA, Kengo GOTO, Hideaki SAKAIDA, Junichi NISHIMURA
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Publication number: 20130040229Abstract: Cohesive carbon assemblies are prepared by obtaining a functionalized carbon starting material in the form of powder, particles, flakes, loose agglomerates, aqueous wet cake, or aqueous slurry, dispersing the carbon in water by mechanical agitation and/or refluxing, and substantially removing the water, typically by evaporation, whereby the cohesive assembly of carbon is formed. The method is suitable for preparing free-standing, monolithic assemblies of carbon nanotubes in the form of films, wafers, discs, fiber, or wire, having high carbon packing density and low electrical resistivity. The method is also suitable for preparing substrates coated with an adherent cohesive carbon assembly. The assemblies have various potential applications, such as electrodes or current collectors in electrochemical capacitors, fuel cells, and batteries, or as transparent conductors, conductive inks, pastes, and coatings.Type: ApplicationFiled: August 10, 2012Publication date: February 14, 2013Inventors: Leonid GRIGORIAN, Sean Imtiaz BRAHIM
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Patent number: 8372543Abstract: Disclosed are copper foil or net comprising a Cu-nitrile compound complex formed on the surface thereof, a method for preparing the same, and a lithium secondary battery that comprises an electrode using the same copper foil or net as a collector. The lithium secondary battery, which uses a copper collector comprising a Cu-nitrile compound complex formed on the surface thereof through the application of a certain voltage level, can prevent the corrosion of Cu occurring at a voltage of 3.6V or higher under overdischarge conditions away from the normal drive condition, and thus can significantly improve the capacity restorability after overdischarge.Type: GrantFiled: May 1, 2012Date of Patent: February 12, 2013Assignee: LG CHEM, Ltd.Inventors: Young Soo Kim, Soon Ho Ahn, Mi Young Son
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Patent number: 8372542Abstract: An improved Ni—Zn cell with a negative electrode substrate plated with tin or tin and zinc during manufacturing has a reduced gassing rate. The copper or brass substrate is electrolytic cleaned, activated, electroplated with a matte surface to a defined thickness range, pasted with zinc oxide electrochemically active material, and baked. The defined plating thickness range of 40-80 ?In maximizes formation of an intermetallic compound Cu3Sn that helps to suppress the copper diffusion from under plating layer to the surface and eliminates formation of an intermetallic compound Cu6Sn5 during baking to provide adequate corrosion resistance during battery operation.Type: GrantFiled: April 20, 2012Date of Patent: February 12, 2013Assignee: PowerGenix Systems, Inc.Inventors: Feng Feng, Jeffrey Phillips, Samaresh Mohanta, Jeff Barton, Zeiad M. Muntasser