Alcohol Feedstock Patents (Class 429/424)
  • Patent number: 11362354
    Abstract: A fuel cell system that includes a fuel cell body that is formed by a membrane electrode assembly including an anode catalyst and a cathode catalyst between which an electrolyte membrane is sandwiched and a pair of separators forming an anode-catalyst-side flow channel and a cathode-catalyst-side flow channel, a fuel supply system configured to supply fuel gas to the fuel cell body, an oxidant supply system configured to supply oxidant gas to the fuel cell body, a control device that controls these supply systems in accordance with an operating state of the fuel cell system and a catalyst deterioration recovery device that recovers deterioration of the anode catalyst.
    Type: Grant
    Filed: August 12, 2016
    Date of Patent: June 14, 2022
    Assignee: NISSAN MOTOR CO., LTD.
    Inventor: Yoshitaka Ono
  • Patent number: 11289726
    Abstract: A hybrid fuel cell system includes a fuel supply system including a fuel tank, a start-up subsystem, a reforming subsystem and a depressurization system. The reforming subsystem is to receive fuel and to reform fuel to generate a hydrogen enriched gases and steam mixture. The hybrid fuel cell system includes a water supply system that provides water for the steam generator. The water supply system includes a water condenser directly downstream from the reforming subsystem that is in fluid communication with the hydrogen enriched gases and steam mixture to condense the hydrogen enriched gases and steam mixture into water and hydrogen enriched gases. The depressurization system is to reduce a pressure of the hydrogen enriched gases. The hybrid fuel cell system includes a fuel cell stack downstream from the depressurization system and having an anode inlet in fluid communication with the depressurization system to receive the hydrogen enriched gases.
    Type: Grant
    Filed: November 6, 2019
    Date of Patent: March 29, 2022
    Assignee: HONEYWELL INTERNATIONAL INC.
    Inventors: Daguang Zheng, Dacong Weng
  • Patent number: 11251448
    Abstract: A method for determining a sealing tightness of a fuel cell stack includes providing of fuel into a cathode space, sealed off gas-tight against further components of a cathode subsystem, formed at least partly by the fuel cell stack, and detecting of a value which is indicative of a pressure change in the cathode space, where a cathode test pressure in the cathode space is higher than a pressure outside the fuel cell stack.
    Type: Grant
    Filed: July 9, 2019
    Date of Patent: February 15, 2022
    Assignee: Bayerische Motoren Werke Aktiengesellschaft
    Inventors: Volker Formanski, Norbert Frisch, Martin Thomas
  • Patent number: 11217810
    Abstract: A preparation method of a direct ethanol fuel cell includes synthesizing electrolytes, preparing a cathode and an anode, and clamping the electrolytes between the cathode and the anode to get direct ethanol fuel cell. The electrolytes are synthesized by polymerizing sodium acrylate with an initiator to get a hydrogel, and the hydrogel is soaked in a harsh alkaline solution. The cathode is synthesized by coating N,S codoped carbon catalyst onto a current collector, where the N,S codoped carbon catalyst is synthesized by mixing and preheating silica powder, sucrose and trithiocyanuric acid to get a mixed powder, and mixing and heating the mixed powder with poly tetra fluoroethylene so as to get the N,S codoped carbon catalyst. The anode is synthesized by coating Pt-Ru/C catalyst onto a current collector.
    Type: Grant
    Filed: November 22, 2019
    Date of Patent: January 4, 2022
    Assignee: HARBIN INSTITUTE OF TECHNOLOGY, SHENZHEN
    Inventors: Yan Huang, Jiaqi Wang
  • Patent number: 11168390
    Abstract: A new technique, referred to as PSBEE, is disclosed and enables fabrication of freestanding nanomembranes. The PSBEE technique enables fabrication and synthesis of nanomembranes comprising 2D high entropy alloys and 2D metallic glasses and may be extended to ceramics and semiconductors, thereby enabling the fabrication of large-scale freestanding nanomembranes across a wide range of materials, including those deemed to have a great potential for future functional and structural use. To form nanomembranes using PSBEE, a plurality of membranes may be prepared and subjected to thermoplastic compression. Afterwards, one of the membranes may be removed and the remaining membranes may undergo additional thermoplastic compression in the presence of a Si substrate. Once a threshold level of smoothness is achieved, a coating or film may be applied and then separated from the final plate.
    Type: Grant
    Filed: May 22, 2019
    Date of Patent: November 9, 2021
    Assignee: City University of Hong Kong
    Inventors: Yong Yang, Tianyu Wang, Zhaoyi Ding, Quanfeng He
  • Patent number: 11108067
    Abstract: A fuel cell system that supplies fuel gas and oxidant gas to a fuel cell stack and causes the fuel cell stack to generate power includes a tank that stores aqueous solution containing oxygen-containing fuel, and a reformer that reforms mixed gas obtained as the aqueous solution is vaporized, and generates the fuel gas. The fuel cell system also includes an actuator that supplies the mixed gas to the reformer, a heating device that heats the reformer, a detecting unit that estimates or detects a concentration of the oxygen-containing fuel in the mixed gas that is supplied to the reformer, and a controller programmed to control operations of the actuator and the heating device so that the fuel cell generates power. The controller is programmed to increase a thermal dose to the reformer from the heating device or reduces a supply amount of the mixed gas to the reformer by the actuator when the concentration of the oxygen-containing fuel is high, compared to when the concentration is low.
    Type: Grant
    Filed: July 28, 2017
    Date of Patent: August 31, 2021
    Assignee: NISSAN MOTOR CO., LTD.
    Inventor: Fumio Kagami
  • Patent number: 11050071
    Abstract: There is provided an inspection method for a fuel cell or a fuel cell stack that ensures performing a leakage inspection minutely in a shorter time compared with the conventional inspection. The inspection method includes an enclosing step, an external leakage inspection step, and a communication leakage inspection step. The enclosing step encloses a first gas passage, a second gas passage, and a refrigerant passage in the fuel cell or the fuel cell stack to form three sections. The three sections are a first section, a second section, and a third section independent of one another. The external leakage inspection step simultaneously supplies an inspection gas to two or more sections among the three sections for pressure boosting to perform an inspection for leakage of the inspection gas from the two or more sections after boosting pressures to an outside.
    Type: Grant
    Filed: December 26, 2019
    Date of Patent: June 29, 2021
    Assignee: TOYOTA JIDOSHA KABUSHIKI KAISHA
    Inventor: Katsumi Sato
  • Patent number: 10879545
    Abstract: A fuel cell system includes: a fuel cell; an air passage including an air supply passage and an air exhaust passage; an air inlet valve configured to open and close the air supply passage; an air outlet valve configured to open and close the air exhaust passage; a hydrogen gas passage including a hydrogen gas supply passage and a hydrogen gas exhaust passage; a hydrogen gas inlet valve configured to open and close the hydrogen gas supply passage; a hydrogen gas outlet valve configured to open and close the hydrogen gas exhaust passage; a hydrogen gas pressure sensor configured to obtain a pressure of gas in the hydrogen gas passage disposed downstream of the hydrogen gas inlet valve and upstream of the hydrogen gas outlet valve; and a controller.
    Type: Grant
    Filed: August 8, 2018
    Date of Patent: December 29, 2020
    Assignee: Toyota Jidosha Kabushiki Kaisha
    Inventor: Makoto Takeyama
  • Patent number: 10669164
    Abstract: The disclosed embodiments relate to a system that performs low-temperature desalination. During operation, the system feeds cold saline water through a liquid-cooling system in a computer data center, wherein the cold saline water is used as a coolant, thereby causing the cold saline water to become heated saline water. Next, the system feeds the heated saline water into a vacuum evaporator comprising a water column having a headspace, which is under a negative pressure due to gravity pulling on the heated saline water in the water column. This negative pressure facilitates evaporation of the heated saline water to form water vapor. Finally, the system directs the water vapor through a condenser, which condenses the water vapor to produce desalinated water.
    Type: Grant
    Filed: January 31, 2018
    Date of Patent: June 2, 2020
    Assignee: Oracle International Corporation
    Inventors: Kenny C. Gross, Sanjeev Sondur
  • Patent number: 10593975
    Abstract: A catalytic burner arrangement is provided including at least a catalytic burner unit with a housing having a reaction chamber in which a catalyst is arranged, wherein the catalyst is adapted to react a fuel, particularly a hydrogen containing fluid, with an oxidant, particularly air, for producing heat, the housing having a fluid inlet for supplying a fluid stream into the housing and a find outlet for exiting a fluid stream from the housing, and the catalytic burner arrangement further includes a mixing unit forming a mixing chamber in which fuel and oxidant are mixed, wherein the mixing device includes a fuel inlet, an oxidant inlet and an fuel-oxidant-mixture outlet, and wherein the fluid inlet of the catalytic burner unit merges with the fuel-oxidant-outlet of the mixing unit for transferring the fuel-oxidant-mixture from the mixing chamber to the reaction chamber of the catalytic burner unit wherein the fuel-oxidant-outlet of the mixing chamber is pipe-shaped and extents into the mixing chamber of the m
    Type: Grant
    Filed: December 2, 2015
    Date of Patent: March 17, 2020
    Assignee: POWERCELL SWEDEN AB
    Inventors: Per Ekdunge, Federico Ghirelli, Ida Toftefors
  • Patent number: 10593976
    Abstract: A catalytic burner arrangement including at least a catalytic burner unit with a housing having a reaction chamber in which a catalyst is arranged is provided wherein the catalyst is adapted to react a fuel, particularly a hydrogen containing fluid, with an oxidant, particularly air, for producing heat, the housing having a fluid inlet for supplying a fluid stream into the housing and a fluid outlet for exiting a fluid stream from the housing, and the catalytic burner arrangement further includes a mixing unit forming a mixing chamber in which fuel and oxidant are mixed, wherein the mixing device includes a fuel inlet, an oxidant inlet and an fuel-oxidant-mixture outlet, and wherein the fluid inlet of the catalytic burner unit merges with the fuel-oxidant-outlet of the mixing unit for transferring the fuel-oxidant-mixture from the mixing chamber to the reaction chamber of the catalytic burner unit wherein the fuel inlet of the mixing chamber is arranged upstream of the oxidant inlet of the mixing unit.
    Type: Grant
    Filed: December 2, 2015
    Date of Patent: March 17, 2020
    Assignee: POWERCELL SWEDEN AB
    Inventors: Per Ekdunge, Federico Ghirelli, Ida Toftefors
  • Patent number: 10497943
    Abstract: A core-shell catalyst includes a porous, palladium-based core particle and a catalytic layer on the particle. The particle can be made by providing a precursor particle that has palladium interspersed with a sacrificial material. At least a portion of the sacrificial material is then removed such that the remaining precursor particle is porous.
    Type: Grant
    Filed: December 3, 2012
    Date of Patent: December 3, 2019
    Assignee: Audi AG
    Inventors: Minhua Shao, Brandon Howard Smith
  • Patent number: 10439240
    Abstract: A flow battery system and method of operating the system minimizes performance losses. The flow battery system includes at least one cell, a first tank including a liquid electrolyte, a pump operably connected to the first tank and to the at least one cell, and a second electrolyte tank operably connected to the at least one cell. The flow battery system further includes a memory including program instructions stored therein, at least one sensor configured to a generate at least one signal associated with a sensed condition of the battery system, and a controller operably connected to the at least one sensor, the pump, and the memory and configured to execute the program instructions to determine a dead zone condition exists based upon the at least one signal, and control the pump to pulse flow of the liquid electrolyte to the at least one cell based upon the determination.
    Type: Grant
    Filed: November 21, 2014
    Date of Patent: October 8, 2019
    Assignee: Robert Bosch GmbH
    Inventors: Edward Knudsen, Paul Albertus
  • Patent number: 10403914
    Abstract: An integrated fuel cell control system is provided. The integrated fuel cell control system includes at least one sensor, at least one hydrogen on/off valve, and a fuel control unit (FCU). The FCU is configured to directly operate the at least one sensor and the at least one hydrogen on/off valve in real time and to determine a supply pressure of hydrogen supplied to a fuel cell. Thereby, noise between controllers may be removed and costs may be reduced.
    Type: Grant
    Filed: September 30, 2016
    Date of Patent: September 3, 2019
    Assignee: Hyundai Motor Company
    Inventors: Ji Tae Kim, Kyu Il Lee, Keun Bong Ham
  • Patent number: 10359754
    Abstract: A fuel cell system in which power generation is performed by a fuel cell, comprising: a power generation controller that performs: first control in which at least one of power control for preventing generated power from exceeding an upper limit value, voltage control for preventing generated voltage from falling below a lower limit value and current control for preventing generated current from exceeding an upper limit value is performed and second control in which the generated voltage is prevented from exceeding an upper limit value; and a priority instructor that instructs the power generation controller to prioritize the first control over the second control when the first control and the second control collide with each other.
    Type: Grant
    Filed: October 26, 2015
    Date of Patent: July 23, 2019
    Assignee: Toyota Jidosha Kabushiki Kaisha
    Inventors: Yutaka Tano, Mitsuhiro Nada, Tomohiko Kaneko, Yohei Okamoto
  • Patent number: 10258961
    Abstract: A reactor includes a plurality of reaction side flow passages through which a reaction fluid flows, a catalyst (catalyst structure) disposed inside the reaction side flow passages to accelerate the reaction of the reaction fluid, a plurality of heat medium side flow passages which are alternately stacked with the reaction side flow passages, and through which a heat medium flows, and a suppression flow passage which is disposed adjacent to a surface of the reaction side flow passage, the heat medium side flow passages being not stacked on the surface, and through which flows a suppression fluid suppressing the heat dissipation to the outside from the reaction fluid flowing through the reaction side flow passage, or the heat transfer from the outside to the reaction fluid.
    Type: Grant
    Filed: November 28, 2016
    Date of Patent: April 16, 2019
    Assignee: IHI CORPORATION
    Inventor: Koki Hamada
  • Patent number: 10177391
    Abstract: A fuel cell system including a fuel cell that receives a supply of an anode gas and a cathode gas and generates power is provided. The fuel cell system includes a water content calculation unit configured to calculate a water content of the fuel cell, an internal impedance calculation unit configured to calculate an internal impedance of the fuel cell, and a starting temperature calculation unit configured to calculate a fuel cell temperature at a start of the system, based on the water content of the fuel cell as of a last time the system was stopped, and the internal impedance of the fuel cell at the start of the system.
    Type: Grant
    Filed: August 10, 2012
    Date of Patent: January 8, 2019
    Assignee: NISSAN MOTOR CO., LTD.
    Inventors: Michihiko Matsumoto, Kiyoshi Hoshi, Tetsuya Aoki
  • Patent number: 10141587
    Abstract: A fuel cell system includes a supply unit configured to supply cathode gas to a fuel cell, a bypass valve configured to bypass the cathode gas to be supplied to the fuel cell by the supply unit, a detection unit configured to detect a state of the cathode gas to be supplied to the fuel cell without being bypassed by the bypass valve, a pressure adjusting unit configured to adjust a pressure of the cathode gas to be supplied to the fuel cell, a calculation unit configured to calculate a target flow rate and a target pressure of the cathode gas to be supplied to the fuel cell according to an operating state of the fuel cell, an operating state control unit configured to control an operation amount of at least one of the pressure adjusting unit and the supply unit on the basis of a flow rate and the pressure of the cathode gas detected by the detection unit and the target flow rate and the target pressure calculated by the calculation unit, a bypass valve control unit configured to open and close the bypass valv
    Type: Grant
    Filed: August 20, 2014
    Date of Patent: November 27, 2018
    Assignee: NISSAN MOTOR CO., LTD.
    Inventors: Yoshitomo Asai, Hiroshi Takeda
  • Patent number: 10103388
    Abstract: Disclosed is a method for producing a fine catalyst particle comprising a palladium-containing particle and a platinum outermost layer covering the palladium-containing particle, wherein a first composite body containing palladium and platinum is formed by mixing the palladium-containing particle with a first solution in which a platinum compound is dissolved, and then covering at least part of a surface of the palladium-containing particle with platinum; wherein a second composite body containing palladium, platinum and copper is formed by mixing the first composite body with a second solution in which a copper compound is dissolved, and then covering at least part of a surface of the first composite body with copper using copper underpotential deposition; and wherein the copper in the second composite body is substituted with platinum derived from a third solution in which a platinum compound is dissolved.
    Type: Grant
    Filed: May 13, 2013
    Date of Patent: October 16, 2018
    Assignee: TOYOTA JIDOSHA KABUSHIKI KAISHA
    Inventors: Keiichi Kaneko, Tsugio Fujisawa, Noriyuki Kitao, Makoto Adachi
  • Patent number: 10090548
    Abstract: A fuel cell system includes a desulfurizer that removes a sulfur compound in a raw material, a fuel cell unit that performs electric-power generation using fuel obtained by reforming a raw material from which the sulfur compound is removed and electric-power generation air supplied, a combustion exhaust gas passage through which combustion exhaust gas generated by combusting fuel not utilized for the electric-power generation in the fuel cell unit is emitted, a combustion exhaust gas container that is connected to the combustion exhaust gas passage and accommodates the desulfurizer inside the combustion exhaust gas container, a purifier that removes carbon monoxide included in the combustion exhaust gas, and an air heat exchanger that performs heat exchange of the combustion exhaust gas and the electric-power generation air supplied to the fuel cell unit.
    Type: Grant
    Filed: October 27, 2015
    Date of Patent: October 2, 2018
    Assignee: PANASONIC INTELLECTUAL PROPERTY MANAGEMENT CO., LTD.
    Inventors: Hiromi Kita, Kunihiro Ukai, Toru Sukawa
  • Patent number: 10044044
    Abstract: The present invention is related to fuel cells and fuel cell cathodes, especially for fuel cells using hydrogen peroxide, oxygen or air as oxidant. A supported electrocatalyst (204) or unsupported metal black catalyst (206) of cathodes according to an embodiment of the present invention is bonded to a current collector (200) by an intrinsically electron conducting adhesive (202). The surface of the electrocatalyst layer is coated by an ion-conducting ionomer layer (210). According to an embodiment of the invention these fuel cells use cathodes that employ ruthenium alloys RuMeIMeII such as ruthenium-palladium-iridium alloys or quaternary ruthenium-rhenium alloys RuMeIMeIIRe such as ruthenium-palladium-iridium-rhenium alloys as electrocatalyst (206) for hydrogen peroxide fuel cells. Other embodiments are described and shown.
    Type: Grant
    Filed: January 3, 2016
    Date of Patent: August 7, 2018
    Inventor: Friedrich Wilhelm Wieland
  • Patent number: 10026968
    Abstract: A method for producing a fuel cell electrode catalyst, including a step (I) of bringing an aqueous solution of a transition metal compound (1) into contact with ammonia and/or ammonia water to generate a precipitate (A) containing an atom of the transition metal, a step (II) of mixing at least the precipitate (A), an organic compound (B), and a liquid medium (C) to obtain a catalyst precursor liquid, and a step (IV) of subjecting the solid in the catalyst precursor liquid to heat treatment at a temperature of 500 to 1200° C. to obtain an electrode catalyst; a portion or the entirety of the transition metal compound (1) being a compound containing a transition metal element of group 4 or group 5 of the periodic table; and the organic compound (B) being at least one selected from sugars and the like.
    Type: Grant
    Filed: January 4, 2012
    Date of Patent: July 17, 2018
    Assignee: SHOWA DENKO K.K.
    Inventors: Masaki Horikita, Kunchan Lee, Yasuaki Wakizaka, Takashi Sato
  • Patent number: 9691508
    Abstract: A method for determining a state of operational readiness of a fuel cell backup system of a nuclear reactor system includes monitoring a readiness state of a fuel cell system associated with a nuclear reactor system, and providing a readiness determination of the fuel cell system by comparing the monitored state of readiness of the fuel cell system to an established operating readiness state, the established operating readiness state a function of at least one characteristic of the nuclear reactor system. An apparatus includes a fuel cell monitoring system configured to monitor a readiness state of a fuel cell system associated with a nuclear reactor system, and a readiness determination system configured to provide a readiness determination of the fuel cell system by comparing the monitored state of readiness of the fuel cell system to an established operating readiness state.
    Type: Grant
    Filed: November 2, 2010
    Date of Patent: June 27, 2017
    Assignee: TerraPower, LLC
    Inventors: Roderick A. Hyde, Clarence T. Tegreene, Joshua C. Walter
  • Patent number: 9614235
    Abstract: A fuel cell system is provided in which the concentration increase of discharged fuel gas is inhibited even when abnormality is detected in a discharge unit. A fuel cell system in which a fuel gas discharged from a discharge unit (SV5) is diluted with an oxidizing gas (14) and discharged comprises an abnormality detection unit (205) for detecting an operation abnormality of the discharge unit (SV5), and a change unit (206, 207) for changing the supplied quantity of the oxidizing gas when an abnormality of the discharge unit (SV5) is detected, and the concentration of the diluted (14) and discharged fuel gas is changed and inhibited by changing the supplied quantity of the oxidizing gas.
    Type: Grant
    Filed: March 24, 2005
    Date of Patent: April 4, 2017
    Assignee: TOYOTA JIDOSHA KABUSHIKI KAISHA
    Inventor: Naoki Kanie
  • Patent number: 9515334
    Abstract: Fuel cell systems and methods for controlling the operation of components of the fuel cell system, which may include a fuel source and a fuel cell stack. In some examples, a fuel source is adapted to provide supply fuel to a fuel cell stack at a supply pressure. The fuel cell stack produces electric current at a production amperage. In some examples, a control system is adapted to control operation of the fuel cell stack based on a pressure detected at the fuel cell stack. In some examples, a target production amperage is determined based on the detected pressure, such that when electric current is produced at the target production amperage for the detected pressure, the fuel cell stack consumes a predetermined proportion of the supply fuel.
    Type: Grant
    Filed: June 24, 2011
    Date of Patent: December 6, 2016
    Assignee: DCNS
    Inventors: David J. Edlund, Arne LaVen, Mesa Scharf
  • Patent number: 9502727
    Abstract: In a fuel cell system that includes a reformer adapted to reform a feedstock, and a fuel cell that uses fuel gas contained in the reformed gas produced by this reformer to generate electricity, aims to improve generation efficiency in the fuel cell through a relatively simple feature. The fuel cell system includes a feedstock supplying section such as a pressurizing pump for supplying the feedstock to the reformer; a burner adapted to combust the fuel gas that was not consumed by electricity generation in the fuel cell, and heat the reformer; a temperature sensor for sensing the temperature of the burner; and a control unit adapted to control on the basis of the sensed temperature the feed rate of the feedstock supplied from the feedstock supplying section to the reformer, so as to maintain the temperature of the reformer within a prescribed temperature range optimized for reforming the feedstock.
    Type: Grant
    Filed: July 22, 2009
    Date of Patent: November 22, 2016
    Assignee: TOYOTA JIDOSHA KABUSHIKI KAISHA
    Inventor: Takatoshi Masui
  • Patent number: 9269970
    Abstract: The present invention provides a fuel cell system, and the fuel cell system comprises a fuel cell, an after burner, a heat exchanger and a reformer. The after burner connects with the fuel cell to receive rest-bar of the fuel cell and produce a gas with high temperature. The heat exchanger comprises a first heat exchanging unit and a second heat exchanging unit connected with the first heat exchanging unit, and the second heat exchanging unit connects with a fuel input pipe for receiving the fuel. The reformer connects with the after burner, the first heat exchanging unit and the second heat exchanging unit separately.
    Type: Grant
    Filed: June 7, 2013
    Date of Patent: February 23, 2016
    Assignee: National Chiao Tung University
    Inventors: Tsung-Lin Chen, Chien-Chang Wu
  • Patent number: 9231265
    Abstract: A fuel cell for a portable electronic device having a liquid fuel reservoir (100) wherein at least a part of the inner surface (103) and a part of an outer surface (104) of the fuel reservoir wall (102) are gas permeable, wherein said wall is adapted such that the area of the open parts of the inner surface (103) of the wall is larger than the area of the open parts of said outer surface (104) of the wall, wherein said wall is porous and adapted to allow gas to enter said wall and to be transported along said wall in a direction substantially parallel with the plane of the wall and to leave said wall, and wherein said wall is adapted such that the inner surface is hydrophobic. The invention further provides a portable electronic device and a method of manufacturing a liquid fuel reservoir.
    Type: Grant
    Filed: July 13, 2011
    Date of Patent: January 5, 2016
    Assignee: TEKNOLOGISK INSTITUT
    Inventors: Torsten Lund-Olesen, Christian Kallesoee, Jan Harry Hales, Leif Hoejslet Christensen
  • Patent number: 9178231
    Abstract: A system has: a stack having anodes supplied with anode fluid and cathodes supplied with cathode fluid; an evaporating portion generating steam by evaporating water; a water deliverer delivering the water to the evaporating portion; and a reforming portion producing the anode fluid through steam-reforming on fuel using the steam generated by the evaporating portion. A controller executes a determination process that determines whether an open circuit voltage of the stack increases while the water is temporarily fed to the evaporating portion, when the stack is restarted from a state where power generation of the stack is suspended but the temperature of the evaporating portion is a reference temperature being capable of generating steam, and if the open circuit voltage has increased or is on an increase, the controller executes a restart process for resuming the power generation of the stack.
    Type: Grant
    Filed: December 16, 2011
    Date of Patent: November 3, 2015
    Assignee: TOYOTA JIDOSHA KABUSHIKI KAISHA
    Inventor: Kouichiro Horiuchi
  • Publication number: 20140308597
    Abstract: The invention provides a process for producing H2 by steam reforming of methanol, which process comprises contacting a gas phase comprising (a) CH3OH and (b) H20 with a solid catalyst, which solid catalyst comprises a mixed metal oxide, which mixed metal oxide comprises copper, zinc and gallium, wherein the atomic percentage of copper relative to the total number of metal atoms in the oxide is from 20 at. % to 55 at. %. The solid catalyst itself is also an aspect of the present invention, as is a process for producing the catalyst, which process comprises: (1) a co-precipitation step, comprising contacting: (a) a solution of copper nitrate, zinc nitrate and gallium nitrate, wherein the atomic percentage of copper relative to the total number of metal atoms in said solution is from 20 at. % to 55 at.
    Type: Application
    Filed: July 6, 2012
    Publication date: October 16, 2014
    Applicant: Isis Innovation Limited
    Inventor: Shik Chi Edman Tsang
  • Patent number: 8821832
    Abstract: The invention relates to a fuel processor that produces hydrogen from a fuel. The fuel processor comprises a reformer and a heater. The reformer includes a catalyst that facilitates the production of hydrogen from the fuel; the heater provides heat to the reformer. Multipass reformer and heater chambers are described that reduce fuel processor size. Single layer fuel processors include reformer and heater chambers in a compact form factor that is well suited for portable applications. Some fuel processors described herein place an electrically resistive material in contact with a thermally conductive material to heat fuel entering the fuel processor. This is particularly useful during start-up of the fuel processor. Fuel processors described may also include features that facilitate assembly.
    Type: Grant
    Filed: December 5, 2011
    Date of Patent: September 2, 2014
    Assignee: UltraCell, L.L.C.
    Inventors: Jennifer E. Brantley, Ian W. Kaye, Arpad Somogyvari, Gerry Tucker, Fan Liang Chan
  • Patent number: 8758951
    Abstract: A continuous coal electrolytic cell for the production of pure hydrogen without the need of separated purification units Electrodes comprising electrocatalysts comprising noble metals electrodeposited on carbon substrates are also provided. Also provided are methods of using the electrocatalysts provided herein for the electrolysis of coal in acidic medium, as well as electrolytic cells for the production of hydrogen from coal slurries in acidic media employing the electrodes described herein. Further provided are catalytic additives for the electro-oxidation of coal. Additionally provided is an electrochemical treatment process where iron-contaminated effluents are purified in the presence of coal slurries using the developed catalyst.
    Type: Grant
    Filed: May 8, 2006
    Date of Patent: June 24, 2014
    Assignee: Ohio University
    Inventor: Gerardine Botte
  • Patent number: 8662024
    Abstract: The present description relates to operation and control of a fuel reformer. In one embodiment, an engine constituent is adjusted in response to limiting an amount of reformate supplied to the engine during a condition of reformer degradation. The approach can improve engine operation. In this way, consequences of reformate system degradation may be reduced by limiting use of the reformate system after degradation is detected.
    Type: Grant
    Filed: August 21, 2012
    Date of Patent: March 4, 2014
    Assignee: Ford Global Technologies, LLC
    Inventor: Thomas G. Leone
  • Patent number: 8652693
    Abstract: A reformer including a vaporization part provided with a supply port through which raw fuel is supplied, the supply port being provided at a central section of a tubular container; and reforming parts provided at both sides of the container, each reforming part containing reforming catalyst that reforms the raw fuel that flows into the reforming part from the vaporization part into fuel gas and provided with a fuel-gas supply port through which the fuel gas is discharged.
    Type: Grant
    Filed: March 24, 2009
    Date of Patent: February 18, 2014
    Assignee: KYOCERA Corporation
    Inventors: Mitsuhiro Nakamura, Takashi Ono
  • Patent number: 8586003
    Abstract: Method of producing hydrogen from methanol comprising providing a feed mixture of methanol and water at high pressure, delivering the feed mixture to a reactor chamber (5) equipped with an internal heat exchanger, wherein said feed mixture is heated by heat exchange with an outgoing reformed mixture from the reactor chamber, and wherein said outgoing reformed mixture is simultaneously cooled by said feed mixture.
    Type: Grant
    Filed: January 5, 2010
    Date of Patent: November 19, 2013
    Assignee: Aquarden Technologies APS
    Inventor: Zhuoyan Cai
  • Patent number: 8377601
    Abstract: The direct oxidation fuel cell of the present invention is provided with: a membrane electrode assembly including an anode, a cathode, and an electrolyte membrane interposed between the anode and the cathode; an anode-side separator having a fuel flow channel for supplying fuel to the anode; and a cathode-side separator having an oxidant flow channel for supplying oxidant to the cathode, in which the anode includes an anode catalyst layer disposed at the side of the electrolyte membrane and an anode diffusion layer disposed at the side of the anode-side separator. The anode diffusion layer includes a water repellent layer disposed at the side of the anode catalyst layer and including a first conductive agent and a first water repellent agent; and a substrate layer disposed at the side of the anode-side separator, and the porosity of the substrate layer is higher at the downstream side than at the upstream side of the fuel flow.
    Type: Grant
    Filed: July 7, 2009
    Date of Patent: February 19, 2013
    Assignee: Panasonic Corporation
    Inventors: Hiroaki Matsuda, Hideyuki Ueda, Takashi Akiyama
  • Patent number: 8303840
    Abstract: A primary battery includes a cathode having an acid-treated manganese dioxide, an anode, a separator between the cathode and the anode, and an alkaline electrolyte.
    Type: Grant
    Filed: March 12, 2010
    Date of Patent: November 6, 2012
    Assignee: The Gillette Company
    Inventors: Kirakodu S. Nanjundaswamy, Fan Zhang, Yichun Wang, James J. Cervera, Jennifer A. Nelson, Gary A. Miller, Rimma A. Sirotina
  • Patent number: 8282907
    Abstract: Hydrogen generators and processes for operating hydrogen generators using partial oxidation/steam reforming of fuel are provided that can achieve desirable Net Hydrogen Efficiencies over a range of fuels and hydrogen product production rates and purities. Superheated steam for the reformer feed is provided through indirect heat exchange with the reformate and through indirect heat exchange with a flue gas. The relative portions of superheated steam from each heat exchange is adjusted to enhance Net Hydrogen Efficiency as a demand condition such as hydrogen product production rate or purity changes, and cooler oxygen-containing gas is used to avoid precombustion temperatures in the reformer feed.
    Type: Grant
    Filed: July 6, 2007
    Date of Patent: October 9, 2012
    Assignee: Hyradix, Inc.
    Inventors: Kishore J. Doshi, Robert J. Sanger
  • Patent number: 8247132
    Abstract: Provided are a heat recovery apparatus recovering heat generated from a membrane electrode assembly (MEA) and transmitting the heat to a fuel spreader so that a temperature difference between the MEA and the fuel spreader inside a fuel cell is reduced, and a fuel cell having the heat recovery apparatus. The fuel spreader supplies fuel having a uniform concentration to the MEA through the heat recovery apparatus, so that a fuel cell having a reduced total volume, a stable performance, and increased energy efficiency can be provided.
    Type: Grant
    Filed: May 14, 2008
    Date of Patent: August 21, 2012
    Assignee: Samsung SDI Co., Ltd.
    Inventors: Jinho Kim, Jae-yong Lee, Kyung-hwan Choi, Lei Hu
  • Patent number: 8202638
    Abstract: A fuel processing method for a solid oxide fuel cell stack comprising the steps of: (a) supplying a feed stream comprising ethanol to a methanation reactor containing catalytic material for the methanation of ethanol; (b) processing the feed stream in the methanation reactor under adiabatic conditions to produce an effluent fuel comprising methane; (c) transferring the effluent fuel comprising methane to the anode of a solid oxide fuel cell stack comprising at least one solid oxide fuel cell; (d) providing the cathode of the solid oxide fuel cell stack with an oxygen-containing gas; and (e) converting the fuel comprising methane and the oxygen-containing gas to electricity in the solid oxide fuel cell stack.
    Type: Grant
    Filed: September 27, 2005
    Date of Patent: June 19, 2012
    Assignee: Haldor Topsoe A/S
    Inventors: John Bøgild Hansen, Søren Dahl
  • Patent number: 8186315
    Abstract: A hydrogen fuel system for an internal combustion engine includes a water reservoir and a fuel cell in fluid communication with the water reservoir. An oxygen line is fluidly coupled to the hydrogen fuel cell and receives and transports oxygen away from the fuel cell. A hydrogen line is fluidly coupled to the fuel cell and receives and transports hydrogen away from the fuel cell. An engine gas interface is fluidly coupled to the oxygen line and the hydrogen line, and operatively coupled to an engine intake. The engine gas interface receives oxygen and hydrogen from the oxygen and hydrogen lines, and introduces the hydrogen and oxygen into the engine intake. A vibration sensor is operatively coupled to the engine gas interface to detect engine vibration of the internal combustion engine, and deactivates the fuel when the sensor does not detect vibration from the engine.
    Type: Grant
    Filed: October 31, 2008
    Date of Patent: May 29, 2012
    Inventors: Arthur Jeffs, Heber Barlow
  • Patent number: 8187560
    Abstract: Steam, partial oxidation and pyrolytic fuel reformers (14 or 90) with rotating cylindrical surfaces (18, 24 or 92, 96) that generate Taylor Vortex Flows (28 or 98) and Circular Couette Flows (58, 99) for extracting hydrogen from hydrocarbon fuels such as methane (CH4), methanol (CH3OH), ethanol (C2H5OH), propane (C3H8), butane (C4H10), octane (C8H18), kerosene (C12H26) and gasoline and hydrogen-containing fuels such as ammonia (NH3) and sodium borohydride (NaBH4) are disclosed.
    Type: Grant
    Filed: May 20, 2010
    Date of Patent: May 29, 2012
    Assignee: Global Energy Science, LLC
    Inventor: Halbert Fischel
  • Publication number: 20120086385
    Abstract: A power system is provided which includes hydrogen production via reformation of gaseous or liquid hydrocarbons and/or alcohol feedstocks, in combination with high temperature PEM fuel cells which function as a power source, particularly for beverage and/or water cooler appliances, refrigerators or freezers and methods of use thereof.
    Type: Application
    Filed: October 7, 2011
    Publication date: April 12, 2012
    Applicants: Frigoglass S.A.I.C., Advent Technologies, HELBIO S.A. Hydrogen and Energy Production Systems
    Inventors: Spyridon Masouras, Maria Michalopoulou, Nikolaos Triantafyllopoulos, Nora Gourdoupi, Thomas Halkides, Andreas Stavrakas
  • Patent number: 8053130
    Abstract: A fuel cell system that includes a liquid fuel tank containing a non-sulfur-containing liquid fuel and water; a reformer generating a hydrogen-rich gas from the liquid fuel and water received from the liquid fuel tank; a reformer burner heating the reformer by burning a gaseous fuel received from a gaseous fuel tank, and a fuel cell stack generating electrical energy from the hydrogen-rich gas received from the reformer. The liquid fuel tank is connected to the gaseous fuel tank, and the liquid fuel mixed with water is supplied to the reformer by the pressure of the gaseous fuel tank.
    Type: Grant
    Filed: January 26, 2007
    Date of Patent: November 8, 2011
    Assignee: Samsung SDI Co., Ltd.
    Inventors: Soon-ho Kim, Doo-hwan Lee, Hyun-chul Lee
  • Publication number: 20110223503
    Abstract: The present invention discloses an electrode structure capable of separately delivering gas and fluid which is applied to a passive fuel cell. The electrode structure includes an electrode portion and a water removal plate, and the electrode portion is adjacent to the water removal plate. The water removal plate includes a first surface, a second surface opposite to the first surface, a plurality of gas passages passing from the first surface to the second surface, and a plurality of liquor passages disposed on the first surface. The surfaces of the gas passages are treated with hydrophobic treatment, and the surfaces of the liquor passages are treated with hydrophilic treatment.
    Type: Application
    Filed: March 8, 2011
    Publication date: September 15, 2011
    Applicant: NATIONAL TSING HUA UNIVERSITY
    Inventors: Fan Gang Tseng, Hsien Chih Peng, Po Hung Chen
  • Patent number: 7998630
    Abstract: According to one embodiment, a fuel cell includes a fuel tank that stores a liquid fuel, a power generation section including an anode and a cathode, a first fuel supply section that supplies the liquid fuel from the fuel tank to the anode, an oxygen supply section that supplies oxygen to the cathode, and a second fuel supply section that supplies the liquid fuel from the fuel tank to the cathode. The power generation section generates power by a chemical reaction of the liquid fuel and the oxygen.
    Type: Grant
    Filed: March 26, 2007
    Date of Patent: August 16, 2011
    Assignee: Kabushiki Kaisha Toshiba
    Inventor: Tomohiro Hirayama
  • Publication number: 20110129746
    Abstract: A thermal management system for high-temperature fuel cell mainly comprises a first mixer to introduce external fuel to a reformer, a reformer to adjust the gaseous fuel to a proper composition ratio and output the fuel to the anode input of the fuel cell, a second mixer to introduce external ambient air to the cathode input of the fuel cell, a cathode thermal cycle pipeline to deliver the high-temperature air from the cathode output of the fuel cell to pass through the second mixer and the reformer and also heat the second mixer and the reformer to recover the heat, an anode thermal cycle pipeline to introduce the water steam from the anode output of fuel cell, remaining fuel and thermal energy to the first mixer to mix with incoming fuel, and provide sufficient water-to-carbon ratio and the inlet temperature required for the reformer.
    Type: Application
    Filed: December 1, 2009
    Publication date: June 2, 2011
    Inventors: Dung-Di Yu, Yung-Neng Cheng, Ruey-Yi Lee
  • Patent number: 7914933
    Abstract: A process and apparatus for producing hydrogen for a fuel cell by (a) reacting a fuel comprising a hydrocarbon and/or an oxygenate with steam, under steam reforming conditions in a reforming reactor to produce a product stream comprising hydrogen, (b) feeding at least part of the hydrogen produced in step a) to a fuel cell, to produce electric power and a waste stream comprising hydrogen, (c) reacting at least part of the waste stream from step b) with an oxygen-containing gas in a combustion reactor, and (d) using the heat energy produced in step c) to supply energy to the steam reforming reaction in step a) in which the combustion reactor is positioned within the reforming reactor to facilitate heat transfer between the stages.
    Type: Grant
    Filed: May 29, 2002
    Date of Patent: March 29, 2011
    Assignee: GM Global Technology Operations LLC
    Inventors: Leslie William Bolton, William Terence Woodfin
  • Patent number: 7909987
    Abstract: For manufacturing micro-structured reactors with passageways loaded with catalyst using the pre-coat method, a method is provided which comprises the following method steps: a) producing reactor layers having bonding areas as well as passageway areas in which the passageways are formed, b) applying at least one bonding layer onto the reactor layers in the bonding areas, c) loading the reactor layers in the passageway areas with the catalyst and d) bonding the reactor layers, the bonding layer being applied and masked before the reactor layers are loaded with the catalyst. As a result, it is ensured that the efficiency of the catalyst will not be affected during manufacturing. The reactor may be used as a methane and methanol reformer in particular.
    Type: Grant
    Filed: February 22, 2007
    Date of Patent: March 22, 2011
    Assignee: Atotech Deutschland GmbH
    Inventors: Olaf Kurtz, Ralph Herber, Christian Madry, Gerd Schäfer
  • Patent number: 7892696
    Abstract: By providing a coloring agent, which is brought in contact with the liquid fuel leaked from an outer peripheral portion of the liquid fuel holding section that is configured to hold the liquid fuel and by which the contact portion is changed in color, in at least part of the outer peripheral portion, the leakage of the liquid fuel from the liquid fuel holding section can be visually detected swiftly and easily without providing any special detection device.
    Type: Grant
    Filed: May 2, 2005
    Date of Patent: February 22, 2011
    Assignee: Panasonic Corporation
    Inventors: Makoto Iyoda, Hiroto Inoue, Suguru Nakao, Yukihiro Iwata, Yasuo Yokota, Toshiaki Takasu