Abstract: A multi-chambered electrolyte storage tank for a redox flow battery system, may include first and second electrolyte chambers, and a bulkhead, wherein the first and second electrolyte chambers are fluidly coupled to first and second sides of a redox flow battery cell, respectively, the first and second electrolyte chambers include first and second liquid electrolyte volumes, respectively, and the first and second liquid electrolyte volumes are separated by the bulkhead positioned therebetween. In this way, manufacturing and operational complexity of a redox flow battery system can be reduced.

Abstract: An illustrative example fuel cell assembly includes at least one cooler and a plurality of fuel cells each having an anode and a cathode. Each of the anodes includes an anode flow plate configured to allow fuel to flow through the anode. The anode flow plates have a respective flow resistance that varies among at least some of the anodes based on a distance between the corresponding anode and the cooler.

Abstract: A membrane electrode assembly includes: an electrolyte membrane; a catalyst electrode layer including a cathode catalyst electrode disposed on the electrolyte membrane and an anode catalyst electrode disposed under the electrolyte membrane; and a sub-gasket disposed on the electrolyte membrane to be in contact with an edge of the catalyst electrode layer. Each of the sub-gasket includes a moisture drain hole penetrating the sub-gasket to expose a portion of the electrolyte membrane outside.

Abstract: A charger for charging an energy storage device having a core with an electrolyte, the charger including: a controller comprising hardware, the controller being configured to: obtain a measurement and/or approximation of a temperature of the electrolyte; determine whether the obtained temperature is below a predetermined threshold considered to at least reduce the charging efficiency of the energy storage device; and input a predetermined voltage and/or current input to terminals of the energy storage device causing internal components of the energy storage device to generate heat if the temperature is determined to be less than the predetermined threshold, wherein the energy storage device includes an internal surface capacitance, which can store electric field energy between internal electrodes of the energy storage device, and the controller is configured to input an AC current to the terminals with a frequency high enough to effectively short the internal surface capacitance.

Abstract: A method for charging an energy storage device having a core with an electrolyte. The method including: (a) obtaining one or more of a measurement or approximation of a temperature of the electrolyte; (b) determining whether the temperature obtained in step (a) is below a predetermined threshold considered to at least reduce the charging efficiency of the energy storage device; and (c) inputting one or more of a predetermined voltage and current input to terminals of the energy storage device causing internal components of the energy storage device to generate heat if the temperature is determined to be less than the predetermined temperature. Similarly, a method for discharging an energy storage device having an electrolyte is provided.

Abstract: A direct carbon fuel cell DCFC system (5), the system comprising an electrochemical cell, the electrochemical cell (10) comprising a cathode (30), a solid state first electrolyte (25) and an anode (20), wherein, the system further comprises an anode chamber containing a second electrolyte (125) and a fuel (120). The system, when using molten carbonate as second electrolyte, is preferably purged with CO2 via purge gas inlet (60).

Abstract: A liquid electrolyte fuel cell system (10) comprises at least one fuel cell with a liquid electrolyte chamber between opposed electrodes, the electrodes being an anode and a cathode, and means (30, 32) for supplying a gas stream to a gas chamber adjacent to the cathode and withdrawing a spent gas stream (38) from the gas chamber adjacent to the cathode, the system also comprising a liquid electrolyte storage tank (40), and means (42, 44, 47, 48) to circulate liquid electrolyte between the liquid electrolyte storage tank (40) and the fuel cells. In addition the system comprises a gas heater (50) and a humidification chamber (52) in the duct (36) leading to the said gas chamber, and means (53, 66, 68) to supply liquid electrolyte to the humidification chamber (52) so the gas is humidified by contact with the liquid electrolyte.

Abstract: Methods, systems and structures for monitoring, managing electrolyte concentrations in redox flow batteries are provided by introducing a first quantity of a liquid electrolyte into a first chamber of a test cell and introducing a second quantity of the liquid electrolyte into a second chamber of the test cell. The method further provides for measuring a voltage of the test cell, measuring an elapsed time from the test cell reaching a first voltage until the test cell reaches a second voltage; and determining a degree of imbalance of the liquid electrolyte based on the elapsed time.

Abstract: Systems and methods for the storage of energy that can be easily converted to electrical power are disclosed. A concentration battery includes a stack of alternating cation and anion exchange membranes separated from one another by alternating first and second spaces; a first reservoir containing a concentrated ionic solution; a second reservoir containing a dilute ionic solution; multiple spaced first fluid pathways in fluid communication with the first reservoir and configured to flow concentrated ionic solution flows into the first spaces; and multiple spaced second fluid pathways in fluid communication with the second reservoir and configured to flow dilute ionic solution flows into the second spaces. The fluid pathways may be configured to flow the ionic solutions in a common first direction. Electrodes at either end of the device in fluid communication with the concentrated ionic solution permit electrical energy to be applied or extracted. A related method is included.

Abstract: Taylor Vortex Flow galvanic electrochemical cells (100, 300, 500) such as batteries, flow cells and fuel cells for converting chemical energy into electrical energy and comprising a cylindrical spinning particulate filter (140, 230) between static cylindrical current collectors (106, 108) for use with electrolytes containing galvanic charge transfer particles (200, 242, 380, 420) functioning as numerous miniature electrodes and means for pumping electrolyte through the filter to produce accelerated reaction electrochemistry for higher cell power density are disclosed.

Abstract: A redox flow battery system includes a first flow compartment, a second flow compartment, an ion exchange membrane positioned between the first flow compartment and the second flow compartment, a first pump configured to pump a first half-cell electrolyte from a first storage tank to the first flow compartment, a second pump configured to pump a second half-cell electrolyte from a second storage tank to the second flow compartment, a first weight sensor configured to provide a first weight signal associated with the weight of the first storage tank and the first half-cell electrolyte within the first storage tank, a memory in which command instructions are stored, and a processor configured to execute the command instructions to obtain the first weight signal, and to control the first pump, current and voltage on terminals of flow battery based upon the obtained first weight signal.

Abstract: The invention provides a fuel cell comprising an anode in an anode region of the cell and a cathode in a cathode region of the cell, the anode being separated from the cathode by an ion selective polymer electrolyte membrane, the anode region of the cell being supplied in use thereof with an alcoholic fuel, the cathode region of the cell being supplied in use thereof with an oxidant, the cell being provided with means for generating an electrical circuit between the anode and the cathode and with a non-volatile redox couple in solution in flowing fluid communication with the cathode in the cathode region of the cell, the redox couple being at least partially reduced at the cathode in operation of the cell, and at least partially re-generated by reaction with the oxidant after such reduction at the cathode, the redox couple and/or the concentration of the redox couple in the catholyte solution being selected so that the current density generated by the cell in operation is substantially unaffected by the cross

Abstract: This underwater vehicle includes an electrolyte-activated electrochemical fuel cell to supply it with electrical power, which fuel cell includes: an electrochemical power production cell (3), a reservoir (4) to contain the electrolyte. means of circulation (7) of the electrolyte between the electrochemical cell (3) and the reservoir (4), comprising a semi-axial flow pump arranged axially in the reservoir and comprising a motorised wheel rotatably mounted in a diffuser, characterised in that the diffuser has the general shape of a dome to direct the flow of the electrolyte coming out of the pump in a direction substantially parallel to the axis of the pump, and thus of the reservoir.

Abstract: Taylor Vortex Flow fuel cells (102) for converting chemical energy into electrical energy and comprising a cylindrical rotating particulate filter (120) between cylindrical current collectors (106, 108) for use with electrolytes containing charged galvanic material particles that flow between the cylindrical current collectors (106, 108) and the filter (120) are disclosed.

Abstract: A system (10) for supplying a liquid electrolyte to cell stacks (32) arranged at a plurality of different heights comprises a plurality of constant head supply tanks (12) for containing liquid electrolyte, one for each of the different heights. Each such supply tank (12) is adapted to ensure that the surface of the liquid electrolyte is at atmospheric pressure, and to feed electrolyte to a cell stack, and incorporates an overflow duct (18) to keep the electrolyte at a constant level. For each supply tank (12) except the lowest, the overflow duct (18) supplies overflowing electrolyte to a supply tank at a lower height. The system also includes an electrolyte storage tank (20), and means (24, 26) to supply electrolyte from the storage tank (20) to the highest supply tank (12).

Abstract: A system for energy generation or storage on an electrochemical basis comprises at least one flow cell, each flow cell consisting of two half-cells through which differently charged electrolyte liquids (21, 22) flow and which are separated by means of a membrane, at least one electrode being disposed in each of these half-cells, and a tank being provided for each of the electrolyte liquids. In order to reduce or to completely eliminate the disadvantageous influence of the hydrogen formation in the cell, a common gas volume (23) connecting the tanks is provided, and at least one catalyst (24) for reducing the positive reaction partner of the redox pair in contact with the positive electrolyte liquid (22) and also with the common gas volume (23) is disposed in the tank for the positive electrolyte liquid (22).

Abstract: This invention is directed to aqueous redox flow batteries comprising ionically charged redox active materials and ionomer membranes, wherein the charge of the redox active materials is of the same sign as that of the ionomer, so as to confer specific improvements.

Abstract: This invention is directed to aqueous redox flow batteries comprising redox-active metal ligand coordination compounds. The compounds and configurations described herein enable flow batteries with performance and cost parameters that represent a significant improvement over that previous known in the art.

Abstract: The invention concerns flow batteries comprising: a first half-cell comprising: (i) a first aqueous electrolyte comprising a first redox active material; and a first carbon electrode in contact with the first aqueous electrolyte; (ii) a second half-cell comprising: a second aqueous electrolyte comprising a second redox active material; and a second carbon electrode in contact with the second aqueous electrolyte; and (iii) a separator disposed between the first half-cell and the second half-cell; the first half-cell having a half-cell potential equal to or more negative than about ?0.3 V with respect to a reversible hydrogen electrode; and the first aqueous electrolyte having a pH in a range of from about 8 to about 13, wherein the flow battery is capable of operating or is operating at a current density at least about 25 mA/cm2.

Abstract: The present invention relates to methods and systems related to fuel cells, and in particular, to direct carbon fuel cells. The methods and systems relate to cleaning and removal of components utilized and produced during operation of the fuel cell, regeneration of components utilized during operation of the fuel cell, and generating power using the fuel cell.

Abstract: A three-way diverter assembly with a movable member is provided. The three-way diverter assembly includes a housing having a first inlet, a second inlet, a first outlet, and a second outlet. The first inlet and the second inlet are adapted to receive a fluid. The movable member, disposed in the housing adjacent the first inlet, is rotatable about an axis from a first positional limit to a second positional limit, and selectively positional therebetween. Fuel cell systems having the three-way diverter assembly for regulating temperature and humidity of a fuel cell stack are also provided.

Abstract: Flowing electrolyte batteries capable of being selectively neutralized chemically; processes of selectively neutralizing flowing electrolyte batteries chemically; and processes of selectively restoring the electrical potential of flowing electrolyte batteries are disclosed herein.

Abstract: Galvanic electrochemical cells (100, 300, 700, 900) for converting chemical energy into electrical energy, such as batteries, flow cells and fuel cells with a cylindrical rotating filter (120X, 326, 726, 910) having ion-porous (120P, 326P, 726P, 910P) and ion-non-porous filter (120N, 326N, 726N, 910N) for use with both thixotropic and non-conducting electrolytes that generates fluid flows in electrolytes between static cylindrical current collector segments (106, 304X, 306X, 710X, 902X; 108, 314X, 316X, 712X, 906) and the filter (120, 326, 726, 910) are disclosed that generate electric currents varying in amplitude that can be converted into alternating current electricity.

Abstract: A fuel cell stack (10) comprises a plurality of fuel cells each with a chamber (K) for electrolyte with at least one inlet and at least one outlet, and at least one header (30) to supply electrolyte to all the cells in parallel, and means (14) to collect electrolyte that has flowed through the cells. For each cell, the electrolyte outlets (34) feed into an electrolyte flow channel arranged such that in use there is a free surface of electrolyte within the electrolyte flow channel, the electrolyte flow channel being separate from the corresponding electrolyte flow channels for other cells, but such that the free surfaces of all the electrolyte flow channels are at a common pressure. Electrolyte is maintained at a constant depth in this open flow channel by a weir (38), and then flows over the weir to trickle or drip down the outside of the stack.

Abstract: A system (10) for supplying a liquid electrolyte to cell stacks (32) arranged at a plurality of different heights comprises a plurality of constant head supply tanks (12) for containing liquid electrolyte, one for each of the different heights. Each such supply tank (12) is adapted to ensure that the surface of the liquid electrolyte is at atmospheric pressure, and to feed electrolyte to a cell stack, and incorporates an overflow duct (18) to keep the electrolyte at a constant level. For each supply tank (12) except the lowest, the overflow duct (18) supplies overflowing electrolyte to a supply tank at a lower height. The system also includes an electrolyte storage tank (20), and means (24, 26) to supply electrolyte from the storage tank (20) to the highest supply tank (12).

Abstract: A three-way diverter assembly with a movable member is provided. The three-way diverter assembly includes a housing having a first inlet, a second inlet, a first outlet, and a second outlet. The first inlet and the second inlet are adapted to receive a fluid. The movable member, disposed in the housing adjacent the first inlet, is rotatable about an axis from a first positional limit to a second positional limit, and selectively positional therebetween. Fuel cell systems having the three-way diverter assembly for regulating temperature and humidity of a fuel cell stack are also provided.

Abstract: Electrochemical cells (10), such as fuel cells (12) and fuel reformers (14), with rotating elements or electrodes (34, 24) that generate Taylor Vortex Flows (28, 50) and Circular Couette Flows (58) in fluids such as electrolytes and fuels are disclosed.

Abstract: An electrochemical cell system is configured to utilize an ionically conductive medium flowing through a plurality of electrochemical cells. One or more disperser chambers are provided to disrupt or minimize electrical current flowing between the electrochemical cells, such as between the cathode of one cell and the anode of a subsequent cell by dispersing the ionically conductive medium. Air is introduced into the disperser chamber to prevent the formation of foamed ionically conductive medium, which may reconnect the dispersed ionically conductive medium, allowing the current to again flow therethrough.

Abstract: An electrochemical method for providing hydrogen using ammonia, ethanol, or combinations thereof, comprising: forming an anode comprising a layered electrocatalyst, the layered electrocatalyst comprising at least one active metal layer deposited on a carbon support; providing a cathode comprising a conductor; disposing a basic electrolyte between the anode and the cathode; disposing a fuel within the basic electrolyte; and applying a current to the anode causing the oxidation of the fuel, forming hydrogen at the cathode.

Abstract: Electrochemical cells (100, 500, 600) for converting chemical energy into electrical energy, such as batteries (102), flow cells (502) and fuel cells (602) with a cylindrical rotating ion-permeable filter (120, 414, 520, 620) that generates Taylor Vortex Flows (144, 146, 404, 544, 546, 664, 666) and Circular Couette Flows (148, 150, 568, 570, 668, 670) in thixotropic catholytes and anolytes between a cylindrical current collector (106, 506, 606, 108, 508, 608) and the filter (120, 414, 520, 620) are disclosed.

Abstract: Electrochemical cells (10), such as fuel cells (12) and fuel reformers (14), with rotating elements or electrodes (34, 24) that generate Taylor Vortex Flows (28, 50) and Circular Couette Flows (58) in fluids such as electrolytes and fuels are disclosed.

Abstract: Electrochemical cells (100, 500, 600) for converting chemical energy into electrical energy, such as batteries (102), flow cells (502) and fuel cells (602) with a cylindrical rotating ion-permeable filter (120, 414, 520, 620) that generates Taylor Vortex Flows (144, 146, 404, 544, 546, 664, 666) and Circular Couette Flows (148, 150, 568, 570, 668, 670) in thixotropic catholytes and anolytes between a cylindrical current collector (106, 506, 606, 108, 508, 608) and the filter (120, 414, 520, 620) are disclosed.

Abstract: A metal halogen electrochemical energy cell system that generates an electrical potential. One embodiment of the system includes at least one cell including at least one positive electrode and at least one negative electrode, at least one electrolyte, a mixing venturi that mixes the electrolyte with a halogen reactant, and a circulation pump that conveys the electrolyte mixed with the halogen reactant through the positive electrode and across the metal electrode. Preferably, the positive electrode comprises porous carbonaceous material, the negative electrode comprises zinc, the metal comprises zinc, the halogen comprises chlorine, the electrolyte comprises an aqueous zinc-chloride electrolyte, and the halogen reactant comprises a chlorine reactant. Also, variations of the system and a method of operation for the systems.

Abstract: Electrochemical cells (10), such as fuel cells (12) and fuel reformers (14), with rotating elements or electrodes (34, 24) that generate Taylor Vortex Flows (28, 50) and Circular Couette Flows (58) in fluids such as electrolytes and fuels are disclosed.

Abstract: A fuel cell is provided, which includes a first plenum around an anode for receiving fuel, and a second plenum around a cathode for receiving oxygen. A fluid controller controls the supply of fuel to the first plenum or oxygen to the second plenum. A sensor detects the load on the fuel cell, and a controller controls the fluid controller in response to the load detected by the sensor. A method for controlling the output of a fuel cell is also provided, which includes the step of providing a fuel cell having a reaction area with an effective area where reactions may occur. The demand on the fuel cell is detected and the effective area of the reaction area is varied in response to the demand. Alternatively, the fuel cell may have an internal resistance, and the method may include varying the internal resistance in response to the demand.