With Molten Electrolyte Patents (Class 429/464)
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Patent number: 12126064Abstract: A metal support-type fuel cell that has a configuration in which a fuel cell element is supported by a metal support, and is capable of reasonably and effectively utilizing an internal reforming reaction even when an anode layer provided in the fuel cell element has a thickness of several tens of micron order is obtained. A fuel cell element is formed in a thin layer shape on a metal support, an internal reforming catalyst layer for producing hydrogen from a raw fuel gas by a steam reforming reaction is provided in a cell unit, and an internal reformed fuel supply path for discharging steam generated by a power generation reaction from an anode layer to lead the steam to the internal reforming catalyst layer, and leading the produced hydrogen to the anode layer is provided.Type: GrantFiled: March 29, 2019Date of Patent: October 22, 2024Assignee: Osaka Gas Co., Ltd.Inventors: Mitsuaki Echigo, Hisao Onishi, Noritoshi Shinke, Yuji Tsuda
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Patent number: 12087978Abstract: A multiple perforation plate for fuel cell separators includes virtual flow path hole central lines spaced apart from each other at a constant interval in a length direction corresponding to a flow direction of reaction gas and formed in a width direction perpendicular to the flow direction of the reaction gas, a plurality of flow path holes formed at a constant interval on the flow path hole central lines in the width direction, and expansion parts formed at both sides of a middle point of each of the flow path holes in the width direction so as to have a greater width in the length direction than that of other points of each of the flow path holes.Type: GrantFiled: June 14, 2021Date of Patent: September 10, 2024Assignees: Hyundai Motor Company, Kia CorporationInventors: Woo Chul Shin, Kyung Min Kim
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Patent number: 11888187Abstract: Molten carbonate fuel cells (MCFCs) are operated to provide enhanced CO2 utilization. This can increase the effective amount of carbonate ion transport that is achieved. The enhanced CO2 utilization is enabled in part by operating an MCFC under conditions that cause transport of alternative ions across the electrolyte. The amount of alternative ion transport that occurs during enhanced CO2 utilization can be mitigated by using a more acidic electrolyte.Type: GrantFiled: November 26, 2019Date of Patent: January 30, 2024Assignees: ExxonMobil Technology and Engineering Company, FuelCell Energy, Inc.Inventors: Abdelkader Hilmi, Timothy A. Barckholtz, Jonathan Rosen, Heather A. Elsen, Gabor Kiss, Carl A. Willman, Chao-Yi Yuh, Hossein Ghezel-Ayagh, Timothy C. Geary
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Patent number: 11728502Abstract: A method for replenishing an electrolyte of a molten carbonate fuel cell stack includes: preparing an electrolyte colloidal solution containing 10% to 20% of the electrolyte and having a viscosity of 200 to 800 Pa·s; replenishing the electrolyte of the cell stack using the electrolyte colloidal solution prepared in step 1 to allow the electrolyte to adhere to an electrode and an internal channel of the cell stack; discharging excess electrolyte colloidal solution in the cell stack; and drying and discharging water or an organic solvent in the cell stack under an inert gas condition to complete replenishment of the electrolyte of the cell stack, and performing a discharge performance test.Type: GrantFiled: October 27, 2021Date of Patent: August 15, 2023Assignee: HUANENG CLEAN ENERGY RESEARCH INSTITUTEInventors: Jian Cheng, Ruiyun Zhang, Chengzhuang Lu, Hao Li, Shisen Xu, Baomin Wang, Guanjun Yang
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Patent number: 9236640Abstract: In an F-type electrochemical cell 20, in a casing 21, a positive electrode 23 in which carbon dioxide gas is used as a positive electrode active material and a negative electrode 25 are placed so as to face each other with a separator 27 therebetween, and an electrolyte solution 28 is injected between the positive electrode 23 and the negative electrode 25. A tank 30 storing carbon dioxide gas is connected to the positive electrode 23, and carbon dioxide gas is supplied to the positive electrode 23 through a holding member 29. By supplying carbon dioxide gas to the positive electrode in such a manner, the cell can be operated as a battery. Furthermore, when used a primary battery, carbon dioxide can be immobilized in the battery, which is desirable.Type: GrantFiled: September 14, 2010Date of Patent: January 12, 2016Assignee: KABUSHIKI KAISHA TOYOTA CHUO KENKYUSHOInventors: Kensuke Takechi, Tohru Shiga
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Publication number: 20150093676Abstract: Systems and methods are provided for incorporating molten carbonate fuel cells into a heat recovery steam generation system (HRSG) for production of electrical power while also reducing or minimizing the amount of CO2 present in the flue gas exiting the HRSG. An optionally multi-layer screen or wall of molten carbonate fuel cells can be inserted into the HRSG so that the screen of molten carbonate fuel cells substantially fills the cross-sectional area. By using the walls of the HRSG and the screen of molten carbonate fuel cells to form a cathode input manifold, the overall amount of duct or flow passages associated with the MCFCs can be reduced.Type: ApplicationFiled: July 8, 2014Publication date: April 2, 2015Applicant: EXXONMOBIL RESEARCH AND ENGINEERING COMPANYInventors: Paul J. Berlowitz, Timothy Andrew Barckholtz, Frank H. Hershkowitz
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Patent number: 8911915Abstract: The present invention provides a hydrocarbon composite electrolyte membrane for a fuel cell, which is formed of an inexpensive hydrocarbon electrolyte membrane to ensure mechanical and thermochemical stability. The present invention provides a hydrocarbon composite electrolyte membrane for a fuel cell, the hydrocarbon composite electrolyte membrane including at least one composite electrolyte membrane layer having a structure in which graphene nanostructures are impregnated into a hydrocarbon electrolyte membrane.Type: GrantFiled: December 7, 2011Date of Patent: December 16, 2014Assignees: Hyundai Motor Company, Kia Motors CorporationInventor: Hoon Hui Lee
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Patent number: 8846264Abstract: A cell unit of a fuel cell includes a first membrane electrode assembly, a first metal separator, a second membrane electrode assembly, and a second metal separator. Resin frame members are provided at the outer ends of the first and second membrane electrode assemblies. Coolant connection channels including a plurality of grooves is formed in each of the resin frame members. The grooves of the coolant connection channels of the cell unit and grooves of coolant connection channels of a cell unit that is adjacent to the cell unit in the stacking direction are offset from each other, and are not overlapped with each other in the stacking direction.Type: GrantFiled: May 16, 2012Date of Patent: September 30, 2014Assignee: Honda Motor Co., Ltd.Inventors: Kentaro Ishida, Shuhei Goto, Narutoshi Sugita, Tetsuya Nakamura
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Patent number: 8785342Abstract: The present invention provides a catalyst carrier having excellent durability and capable of attaining high catalytic ability without increasing the specific surface area thereof, and a catalyst obtainable by using the catalyst carrier. The catalyst carrier of the present invention comprises a metal oxycarbonitride, preferably the metal contained in the metal oxycarbonitride comprises at least one selected from the group consisting of niobium, tin, indium, platinum, tantalum, zirconium, copper, iron, tungsten, chromium, molybdenum, hafnium, titanium, vanadium, cobalt, manganese, cerium, mercury, plutonium, gold, silver, iridium, palladium, yttrium, ruthenium, lanthanum, cerium, praseodymium, neodymium, promethium, samarium, europium, gadolinium, terbium, dysprosium, holmium, erbium, thulium, ytterbium, lutetium, and nickel. Moreover, the catalyst of the present invention comprises the catalyst carrier and a catalyst metal supported on the catalyst carrier.Type: GrantFiled: August 20, 2013Date of Patent: July 22, 2014Assignee: Showa Denko K.K.Inventors: Ryuji Monden, Tadatoshi Kurozumi, Toshikazu Shishikura
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Patent number: 8497047Abstract: A solid oxide fuel cell stack obtainable by a process comprising the use of a glass sealant with composition 50-70 wt % SiO2, 0-20 wt % Al2O3, 10-50 wt % CaO, 0-10 wt % MgO, 0-6 wt % (Na2O+K2O), 0-10 wt % B2O3, and 0-5 wt % of functional elements selected from TiO2, ZrO2, F, P2O5, MoO3, Fe2O3, MnO2, La. Sr—Mn—O perovskite (LSM) and combinations thereof.Type: GrantFiled: March 12, 2010Date of Patent: July 30, 2013Assignee: Topsoe Fuel Cell A/SInventors: Jørgen Gutzon Larsen, Christian Olsen, Marie Drejer Jensen
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Patent number: 8415039Abstract: An apparatus including at least one electrochemical flow cell in which the electrochemical flow cell includes an anode electrode, a cathode electrode and a reaction zone between the anode and the cathode. The electrochemical flow cell also includes an electrolyte storage reservoir configured to hold a molten salt electrolyte and a gas generated during charging of the at least one electrochemical flow cell and at least one conduit configured to supply the molten salt electrolyte and the gas from the storage reservoir to the at least one electrochemical flow cell. The electrochemical flow cell also includes at least one pump configured to pump the molten salt electrolyte from the storage reservoir to the reaction zone.Type: GrantFiled: February 28, 2011Date of Patent: April 9, 2013Assignee: Primus Power CorporationInventors: Gerardo Jose la O', Rick Winter
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Patent number: 8383283Abstract: A fuel cell includes an electrolyte matrix having a cathode side with a cathode disposed thereon and an anode side with an anode receiving portion and a sealing portion positioned peripherally to the anode receiving portion. The anode receiving portion has an anode disposed thereon. A fuel conduit has one or more one sealing platforms and having an opening extending through the fuel conduit. The anode is positioned in the opening. The fuel cell includes one or more devices for preventing the occurrence an electrical short circuit between the cathode and the sealing platform. The device for preventing the electrical short circuit is aligned with the sealing portion and sealing platform and is positioned on the electrolyte matrix, the cathode and/or the sealing platform.Type: GrantFiled: April 15, 2009Date of Patent: February 26, 2013Assignee: FuelCell Energy, Inc.Inventors: Chao-yi Yun, Mohammad Farooque, Abdelkader Hilmi, Richard Johnsen, Gengfu Xu
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Patent number: 8283078Abstract: A system for preparing particulate carbon fuel and using the particulate carbon fuel in a fuel cell. Carbon particles are finely divided. The finely dividing carbon particles are introduced into the fuel cell. A gas containing oxygen is introduced into the fuel cell. The finely divided carbon particles are exposed to carbonate salts, or to molten NaOH or KOH or LiOH or mixtures of NaOH or KOH or LiOH, or to mixed hydroxides, or to alkali and alkaline earth nitrates.Type: GrantFiled: December 16, 2011Date of Patent: October 9, 2012Assignee: Lawrence Livermore National Security, LLCInventors: John F. Cooper, Nerine Cherepy
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Patent number: 8163198Abstract: A process for producing a lithium-containing composite oxide having a large volume capacity density, high safety, excellent durability for charge/discharge cycles, and excellent low temperature characteristics. An oxide of general formula LipNxMyOzFa (wherein N is at least one of Co, Mn or Ni, M is at least one of Al, an alkali earth metal element, a transition metal element other than N, 0.9?p?1.2, 0.97?x?1.00, 0?y?0.03, 1.9?z?2.2, x+y=1 and 0?a?0.02) can be produced.Type: GrantFiled: November 15, 2007Date of Patent: April 24, 2012Assignee: AGC Seimi Chemical Co., Ltd.Inventors: Naoshi Saito, Takeshi Kawasato, Tokumitsu Kato, Kazushige Horichi
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Patent number: 8062779Abstract: A method of making an anode element for use in a fuel cell, comprising providing a first amount of Ni—Al alloy material having a predetermined aluminum content, providing a second amount of Ni—Cr alloy material having a predetermined chromium content, providing at least one additive component, mixing the Ni—Al alloy material, the Ni—Cr alloy material and the at least one additive component to produce a slurry and forming the slurry into the anode element.Type: GrantFiled: October 5, 2006Date of Patent: November 22, 2011Assignee: FuelCell Energy, Inc.Inventors: Abdelkader Hilmi, Chao-Yi Yuh, Mohammad Farooque
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Patent number: 7989120Abstract: Provided is a high-temperature fuel cell separator. The fuel cell separator includes a fuel gas flow path containing hydrogen, an oxidant gas flow path containing mainly an oxygen component being supplied from an oxygen/nitrogen separator of a system and participating in electrochemical reactions, and a cooling gas flow path containing a nitrogen component to remove heat produced upon power generation of a fuel cell. Such a configuration provides a high-temperature fuel cell separator which is capable of improving efficiency of an overall fuel cell system through improved performance of a fuel cell stack due to increased oxygen partial pressure and which is also capable of improving reliability of the fuel cell stack through inhibition of the occurrence of a high-temperature region resulting from heat produced upon power generation of a fuel cell, by means of a flow of cooling gas containing a nitrogen component.Type: GrantFiled: December 22, 2008Date of Patent: August 2, 2011Assignee: Korea Electric Power CorporationInventors: Do Hyung Kim, Beom Joo Kim, Jung Hyun Lee, Seung Won Kang, Hee Chun Lim, Byung Soo Jung
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Publication number: 20110151349Abstract: A double-electrolyte fuel-cell is presented for generating electrical energy from chemical fuel. The fuel-cell includes an anode, a cathode as well as both an anion-conducting electrolyte and a cation-conducting electrolyte. A fuel-cell stack is also presented consisting of a plurality of double-electrolyte fuel-cells.Type: ApplicationFiled: June 10, 2009Publication date: June 23, 2011Applicant: TECHNION RESEARCH & DEVELOPMENT FOUNDATION LTD.Inventor: Yoed Tsur
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Patent number: 7897290Abstract: The invention relates to a device and a method for determining the operating parameters of individual cells (2) or short stacks (10) of fuel cells, preferably of medium-temperature or high-temperature fuel cells.Type: GrantFiled: February 10, 2005Date of Patent: March 1, 2011Assignee: AVL List GmbHInventors: Herbert Thanner, Martin Schüssler
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Patent number: 7855028Abstract: Disclosed is a separator plate for a molten carbonate fuel cell, which functions to reform a fuel gas while allowing it to efficiently flow therein and thereout, thus producing hydrogen and carbon dioxide, which are then supplied into an anode, and which functions to realize the electrical connection between the anode and the cathode. In the center plate, having a central portion and peripheral portions of the separator plate, the central portion has gas flow paths, that is, guide protrusions and guide grooves, and the peripheral portions are formed into sidewall parts through a folding process, and thus the number of constituents of the separator plate is minimized, thereby reducing the area to be welded. Further, the sidewall parts are integrally structured with the center plate, thereby increasing airtightness and solving problems of corrosion which may be caused in the welded area.Type: GrantFiled: February 9, 2007Date of Patent: December 21, 2010Assignee: Doosan Heavy Industries & Construction Co., Ltd.Inventors: Bo-Hyun Ryu, Boo-Ho Yoon, Dong-Woo Kang, Kil-Ho Moon, In-Gab Chang, Gi-Pung Lee, Yun-Sung Kim