With Solid Electrolyte Patents (Class 429/465)
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Patent number: 12191535Abstract: A separator plate (1) for media guiding in a fuel cell, with at least one through-opening (2, 3, 4, 5, 6, 7) for supplying and at least one through-opening (2, 3, 4, 5, 6, 7) for discharging a medium, with a channel structure (12) for uniformly guiding the medium, as well as with distribution regions (9) which connect the through-openings (2, 3, 4, 5, 6, 7) with the channel structure (12). At least one of the distribution regions (9) surrounds at least one of the through-openings (2, 3, 4, 5, 6, 7) associated with it around the entire perimeter.Type: GrantFiled: March 16, 2020Date of Patent: January 7, 2025Assignee: cellcentric GmbH & Co. KGInventors: Philipp Hausmann, Markus Schudy
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Patent number: 12166251Abstract: Disclosed are a method for manufacturing a polymer electrolyte membrane for fuel cells in which a plurality of porous reinforcement films and ionomer layers are continuously disposed or stacked, and a polymer electrolyte membrane for fuel cells manufactured thereby. The polymer electrolyte membrane for fuel cells includes the porous reinforcement films, thus having excellent mechanical stiffness and improved physical durability. Further, the polymer electrolyte membrane for fuel cells includes an ionomer layer including a catalyst for decomposing peroxide configured to block gas crossover and may thus minimize performance degradation due to gas crossover and prevent an electrical short, and the polymer electrolyte membrane for fuel cells makes it easy to adjust the position of the ionomer layer in the electrolyte membrane in the thickness direction and may thus effectively mitigate gas crossover.Type: GrantFiled: July 29, 2020Date of Patent: December 10, 2024Assignees: Hyundai Motor Company, Kia Motors CorporationInventors: Jong Kil Oh, Sae Hoon Kim, Bo Ki Hong
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Patent number: 12132243Abstract: A fuel cell stack has a plurality of fuel cells arranged in a row, each of them comprising a membrane separating the electrodes, with ports for the respective supply and drainage of a fuel and an oxidizer and with a tensioning device for pressing the fuel cells together, wherein the tensioning device is formed by a band and spring system having an integrated force transducer, the signal of which can be relayed to a controller for determining the moisture content based on the moisture-dependent swelling behavior of the membrane of each fuel cell. A fuel cell device with such a fuel cell stack as well as a motor vehicle having such a fuel cell device are also provided.Type: GrantFiled: October 9, 2020Date of Patent: October 29, 2024Assignee: AUDI AGInventor: Michael Brechter
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Patent number: 12132242Abstract: A fuel cell stack includes: a cell stack body including a plurality of power generation cells stacked together; and a stack case accommodating the cell stack body. Each of the power generation cells includes a membrane electrode assembly and separators sandwiching the membrane electrode assembly therebetween.Type: GrantFiled: December 3, 2021Date of Patent: October 29, 2024Assignee: Honda Motor Co., Ltd.Inventors: Hideharu Naito, Satoshi Kasagami
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Patent number: 12119526Abstract: A metal support for an electrochemical element has a plate shape as a whole, and is provided with a plurality of penetration spaces 1c that pass through the metal support from a front face 1a to a back face. The front face 1a is a face to be provided with an electrode layer. A region of the front face 1a provided with the penetration spaces is a hole region, and openings of the penetration spaces formed in the front face are front-side openings. An aperture ratio that is a ratio of the front-side openings to the hole region is 0.1% or more and 7.0% or less.Type: GrantFiled: March 29, 2019Date of Patent: October 15, 2024Assignee: Osaka Gas Co., Ltd.Inventors: Mitsuaki Echigo, Hisao Ohnishi, Kazuyuki Minami, Yuji Tsuda, Kyohei Manabe, Osamu Yamazaki
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Patent number: 12116146Abstract: A system for thermal management ground service equipment and a method of use is disclosed. The system may include ground service equipment, wherein the ground service equipment may be configured to manage a temperature of a power source of an electric aircraft. The ground service equipment may include a coolant source, wherein the coolant source may include a reservoir containing a coolant. The ground service equipment may include a coolant heating system, wherein the coolant heating system may be configured to increase thermal energy of the coolant. The coolant heating system may include an electric resistance heating element. The system may include a controller communicatively connected to the ground service equipment, wherein the controller may be configured to receive an optimal temperature of the coolant and control the electric resistance heating element of the coolant heating system to increase the thermal energy of the coolant to the optimal temperature.Type: GrantFiled: March 15, 2023Date of Patent: October 15, 2024Assignee: BETA Air, LLCInventors: John Charles Palombini, Jake Pill
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Patent number: 12087985Abstract: In a fuel cell stack, a plurality of projections are provided on a surface of a first end plate opposite to a cell stack body. The projections have support surfaces oriented in a stacking direction. The plurality of projections are overlapped with, or adjacent to the flow field seal as viewed in the stacking direction, and the support surfaces of the plurality of projections are positioned on a single plane surface perpendicular to the stacking direction.Type: GrantFiled: November 19, 2021Date of Patent: September 10, 2024Assignee: Honda Motor Co., Ltd.Inventor: Hideharu Naito
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Patent number: 12080921Abstract: The invention relates to a distributor structure (12, 20), particularly a bipolar plate for a stack structure (10) of a fuel cell or of an electrolyser. The distributor structure (12, 20) comprises a channel structure (48) that interacts with at least one polymer membrane (16). The distributor structure (12, 20) is designed as a plastic part (40) that has electrically conductive properties.Type: GrantFiled: November 28, 2019Date of Patent: September 3, 2024Assignee: Robert Bosch GmbHInventors: Rainer Seitz, Achim Eisemann, Alexander Eifert, Andre Neidhardt, Arne Stephen Fischer, Christoph Haluschka, Felix Wald, Friedrich Kneule, Jan Hendrik Ohs, Laszlo Hagymasi, Laura Bauer, Rolf Lernbecher, Stefan Grosse, Stefan Schoenbauer
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Patent number: 12068509Abstract: A solid oxide fuel cell or solid oxide electrolyzer includes a plurality of fuel cell layers stacked along a stacking axis. Each fuel cell layer including a stacked arrangement of elements including a cathode, an anode, an electrolyte located between the anode and the cathode, a support layer positioned at the anode opposite the electrolyte, and a separator plate located at the support layer opposite the anode. The separator plate is configured to contact the cathode of an adjacent fuel cell layer of the plurality of fuel cell layers. The separator plate defines a plurality of anode flow channels configured to deliver a fuel therethrough and a plurality of cathode flow channels configured to deliver an air flow therethrough. The separator plate is formed from a bulk metallic glass material.Type: GrantFiled: April 20, 2021Date of Patent: August 20, 2024Assignee: HAMILTON SUNDSTRAND CORPORATIONInventors: Tianli Zhu, Paul Sheedy, John A. Sharon
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Patent number: 12027739Abstract: The present invention relates to the field of fuel cell stacks and stack tower or module, in particular to a sealing structure for stack tower and a stack tower. The sealing structure comprises a first component, a second component and a mica spacer, the first component and the second component are opposite to each other, the mica spacer is disposed between the first component and the second component, sealing part is arranged between the mica spacer and at least one of the first component and the second component, and the sealing part comprises a glass ceramic layer and an outer circumferential ceramic cement ring surrounding the glass cement layer; the sealing structure for stack tower has excellent sealing performance and service durability for a fuel cell system.Type: GrantFiled: April 30, 2021Date of Patent: July 2, 2024Assignees: China Energy Investment Corporation Limited, Shenhua New Energy Co., Ltd., National Institute of Clean And-Low-Carbon EnergyInventors: Zhien Liu, Dajun Li, Ying Zhang, Weihua Zhou, Xia Yang, Yuqiong Zhang, Jason Wang, Changlei Liu, Brandon Ohara
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Patent number: 11990650Abstract: An assembly for an electrochemical system, which comprises a first separator plate, a second separator plate, and a membrane electrode assembly arranged between the separator plates for forming an electrochemical cell between the separator plates. A stack comprising a plurality of such assemblies, and an electrochemical system comprising a plurality of such assemblies and/or a stack. The electrochemical system may be a fuel cell system, an electrochemical compressor, an electrolyzer, a redox flow battery, or a humidifier for an electrochemical system.Type: GrantFiled: November 10, 2021Date of Patent: May 21, 2024Assignee: REINZ-DICHTUNGS-GMBHInventor: André Speidel
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Patent number: 11955675Abstract: A fuel cell system includes a membrane electrode assembly, a first plate separator and a second plate separator on opposite sides of the membrane electrode assembly. The first plate separator and the second plate separator have exterior ends away from the membrane electrode assembly. A first gas diffusion layer is located between the first plate separator and the membrane electrode assembly. A second gas diffusion layer is located between the second plate separator and the membrane electrode assembly. The sub-gasket extends from the membrane electrode assembly laterally toward at least one of the exterior ends. A first seal is located between the first plate separator and the sub-gasket. A conductive trace is attached to the sub-gasket and extends on the sub-gasket from an exterior side of the first seal to a location on an interior side of the first seal.Type: GrantFiled: May 12, 2022Date of Patent: April 9, 2024Assignee: PLUG POWER INC.Inventors: Jon Owejan, Edward Snyder, Glenn White
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Patent number: 11949131Abstract: The disclosure relates to a bipolar plate for an electrochemical system, and to an electrochemical system comprising a plurality of bipolar plates. The electrochemical system may be, for example, a fuel cell system, an electrochemical compressor, a redox flow battery, or an electrolyser. The bipolar plate comprising separator plates, an inlet, and an outlet. A separator plate comprising an active region.Type: GrantFiled: June 3, 2021Date of Patent: April 2, 2024Assignee: REINZ-DICHTUNGS-GMBHInventors: Ahmet Oruc, Bernd Gaugler
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Patent number: 11933177Abstract: A ventilation system including a building having a space inside, a subterranean facility arranged in a basement of the building and having a subterranean space inside, a communication passage establishing communication between the space and the subterranean space, and a ventilation hole establishing communication between an earth outside the building and the subterranean space is provided. A fuel cell unit having an exhaust port is arranged in the subterranean space. The communication passage has a lateral wall protruding downward from a ceiling of the subterranean space. The lateral wall is arranged on the exhaust port side when the communication passage is arranged on a straight line linking the exhaust port and a second opening portion of the ventilation hole on the subterranean space side. The lateral wall is arranged on the straight line side when the communication passage is arranged at a position spaced apart from the straight line.Type: GrantFiled: June 1, 2021Date of Patent: March 19, 2024Assignee: TOYOTA JIDOSHA KABUSHIKI KAISHAInventor: Masayuki Ito
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Patent number: 11916239Abstract: An embodiment apparatus for fabricating a membrane-electrode-subgasket assembly includes a feeding unit including a sheet feeding roller configured to feed a membrane-electrode assembly sheet having catalyst layers provided on both surfaces thereof, a cutting unit including a cutting roller and a support roller configured to rotate in engagement with the cutting roller, wherein the cutting roller is configured to punch portions outside each of the catalyst layers, a first pressing unit including a suction roller and a first hot roller, and a second pressing unit including second hot rollers.Type: GrantFiled: October 26, 2021Date of Patent: February 27, 2024Assignees: Hyundai Motor Company, Kia CorporationInventors: Min Jin Kim, Ki Sub Lee, Yong Min Kim
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Patent number: 11876265Abstract: In order to improve usability of hybrid or fully electric aircraft, a fuel cell having improved efficiency and increased volume/weight specific energy density is provided. The fuel cell has a self-supporting membrane structure that is formed as a triply periodic level surface, which separates a first cavity supplied with gaseous fuel from a second cavity supplied with gaseous oxidizer in a gas-sealed manner while connecting the cavities in an ion-conductive manner.Type: GrantFiled: August 31, 2021Date of Patent: January 16, 2024Assignee: Airbus Defence and Space GmbHInventors: Kristian Zimmermann, Stephan Friedl, Christian Metzner
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Patent number: 11862803Abstract: A radical scavenger, a manufacturing method therefor, a membrane-electrode assembly including the radical scavenger, and a fuel cell including the membrane-electrode assembly are disclosed. The membrane-electrode assembly contains an ion exchange membrane; catalyst electrodes disposed on both surfaces of the ion exchange membrane, respectively; and a radical scavenger disposed at any one position selected from the group consisting of in the catalyst electrodes, in the ion exchange membrane, between the ion exchange membrane and the catalyst electrodes, and a combination thereof.Type: GrantFiled: September 28, 2018Date of Patent: January 2, 2024Inventors: Jun-Young Kim, Moo-Seok Lee, Hee-Tak Kim, Seongmin Yuk, Dong-Hyun Lee
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Patent number: 11791474Abstract: The present disclosure relates to an electrolyte membrane for fuel cells including a hydrogen peroxide generating catalyst and a hydrogen peroxide decomposing catalyst, the electrolyte membrane exhibiting highly improved durability, and a method of manufacturing the same. Specifically, the electrolyte membrane includes a support and a catalyst particle including a catalyst metal supported by the support, the catalyst metal including one selected from the group consisting of a first metal having catalyst activity to generate hydrogen peroxide, a second metal having catalyst activity to decompose hydrogen peroxide, and a combination thereof.Type: GrantFiled: October 23, 2020Date of Patent: October 17, 2023Assignees: HYUNDAI MOTOR COMPANY, KIA MOTORS CORPORATIONInventors: Byoungsu Kim, Bo Ki Hong
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Patent number: 11777119Abstract: In a tubular body mounting step, a tubular body is connected to a first end constituting member and a second end constituting member of a fuel cell stack, respectively. At this time, a first opening and a second opening formed at both ends of the tubular body are closed by the first end constituting member and the second end constituting member, respectively. Accordingly, the fuel cell stack is surrounded by the tubular body. A gap is formed between the outer wall of unit cells of the fuel cell stack and the inner wall of the tubular body. In a determination step, a test gas is supplied into the fuel cell stack. Further, whether the test gas exists in the gap is determined.Type: GrantFiled: January 28, 2022Date of Patent: October 3, 2023Assignee: Honda Motor Co., Ltd.Inventor: Takahiro Tanaka
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Patent number: 11757122Abstract: An electrochemical module including, a stack obtained by stacking, in a predetermined stacking direction, a plurality of electrochemical elements having a configuration in which an electrode layer, an electrolyte layer, and a counter electrode layer are formed along a substrate, via an annular sealing portion through which first gas, that is one of reducing component gas and oxidative component gas, flows; a container including an upper cover for pressing a first flat face in the stacking direction of the stack and a lower cover for pressing a second flat face on a side opposite to the first flat face, the stack clamped between the upper cover and the lower cover; an elastic lower plate-like member arranged between the first flat face and the upper cover; and a first gas supply portion and a first gas discharge portion connected to the second flat face in communication with the annular sealing portion.Type: GrantFiled: March 27, 2020Date of Patent: September 12, 2023Assignee: Osaka Gas Co., Ltd.Inventors: Norihisa Shinke, Kazuyuki Minami, Mitsuaki Echigo
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Patent number: 11728501Abstract: A fuel cell includes: an electrolyte layer; a base electrode formed on one side of the electrolyte layer; and a catalyst electrode formed on the other side of the electrolyte layer to be apart from the base electrode with the electrolyte layer interposed therebetween. The catalyst electrode includes: a first electrode portion that covers a part of the electrolyte layer; and a second electrode portion that covers a part of a surface of the first electrode portion to form an electrode portion interface in contact with the first electrode portion.Type: GrantFiled: May 15, 2020Date of Patent: August 15, 2023Assignee: FOUNDATION FOR RESEARCH AND BUSINESS, SEOUL NATIONAL UNIVERSITY OF SCIENCE AND TECHNOLOGYInventors: Ji Hwan An, Jeong Woo Shin, Sung Je Lee, Seong Kook Oh, Jin Geun Yu
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Patent number: 11697157Abstract: The invention relates to an Incineration apparatus, comprising a fluidized bed redox reactor (2) having—a reaction chamber (8) with particulate matter and—a fluidized bottom with at least one reducing agent inlet (9) for a gas to fluidize the particulate matter.Type: GrantFiled: August 28, 2019Date of Patent: July 11, 2023Assignee: DOOSAN LENTJES GMBHInventors: Oguzhan Narin, Björn Brosch, Andreas Karpinski
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Patent number: 11695127Abstract: A bipolar plate for use in a fuel cell stack includes a first delimiting surface and a second delimiting surface that is arranged parallel to the first delimiting surface, wherein the delimiting surfaces are arranged spaced apart from one another and define an intermediate space, wherein the bipolar plate includes at least one fuel cell section having a flow field that has depressions that protrude into the intermediate space and is provided so as to make direct contact with a fuel cell, and the bipolar plate includes at least one cooling section that extends therefrom along the delimiting surfaces, wherein at least one heat pipe is arranged in the intermediate space and extends so as to transfer heat from the fuel cell section into the cooling section.Type: GrantFiled: March 11, 2020Date of Patent: July 4, 2023Inventors: Christian Wolff, Claus Hoffjann
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Patent number: 11581561Abstract: A cell includes an element portion including a first electrode layer, a solid electrolyte layer that contains Zr and that is located above the first electrode layer, an intermediate layer that contains CeO2 containing a rare earth element other than Ce and that is located above the solid electrolyte layer, and a second electrode layer located above the intermediate layer. The intermediate layer includes a first intermediate layer and a second intermediate layer that contains Zr and Ce and that is located at at least a portion between the first intermediate layer and the solid electrolyte layer. In a plan view from the second electrode layer, the second intermediate layer located at an outer peripheral portion of the intermediate layer includes a portion with a thickness greater than the second intermediate layer overlapping a center of the second electrode layer. A cell stack device, a module, and a module housing device include a plurality of the cells.Type: GrantFiled: May 26, 2020Date of Patent: February 14, 2023Assignee: KYOCERA CorporationInventor: Takahiro Okamoto
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Patent number: 11557774Abstract: A metal separator is applied to a fuel cell. A method of producing the metal separator involves performing a plate processing step of forming a bead base, and a rubber seal forming step of providing a rubber seal by screen printing for the bead base formed in the plate processing step. The rubber seal forming step includes a first protrusion forming step of forming a first protrusion at the central part in the width direction of a top portion of the bead base, in a cross sectional view taken along a thickness direction of the rubber seal, and a second protrusion forming step of forming a second protrusion configured to cover the first protrusion after the first protrusion forming step.Type: GrantFiled: March 11, 2021Date of Patent: January 17, 2023Assignee: Honda Motor Co., Ltd.Inventors: Kazuo Nunokawa, Yasunori Murakami
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Patent number: 11557771Abstract: In order to provide an electrochemically active unit for an electrochemical device including a membrane electrode assembly, at least one gas diffusion layer and a seal that is linked to at least one of the at least one gas diffusion layers, in the manufacture whereof as even as possible a construction of the penetration region in which the gas diffusion layer of the electrochemically active unit is penetrated by the sealing material of the seal over the periphery of the gas diffusion layer is achievable, the seal includes a linking region, a distribution region and a connection region that connects the linking region and the distribution region to one another, wherein the connection region has a minimum height that is less than a quarter of the maximum height of the distribution region and less than a quarter of the maximum height of the linking region.Type: GrantFiled: January 23, 2020Date of Patent: January 17, 2023Assignee: EKPO Fuel Cell Technologies GmbHInventors: Peter Stahl, Juergen Kraft, Karsten Dahl, Oliver Fink, Alexander Groeh
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Patent number: 11532825Abstract: A fuel cell comprises an anode, a cathode, and a solid electrolyte layer disposed between the anode and the cathode. The cathode includes a main phase configured by a perovskite oxide including at least one of La or Sr at the A site and that is expressed by the general formula ABO3, and a secondary phase configured by strontium oxide. The occupied surface area ratio of the secondary phase in a cross section of the cathode is greater than or equal to 0.05% and less than or equal to 3%.Type: GrantFiled: October 7, 2016Date of Patent: December 20, 2022Assignee: NGK INSULATORS, LTD.Inventors: Shinji Fujisaki, Noriyuki Ogasawara, Makoto Ohmori
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Patent number: 11476490Abstract: A cell stack device according to the present disclosure includes: a cell stack comprising a plurality of cells; and a manifold configured to supply reaction gas to the plurality of cells, wherein each of the plurality of cells includes: an element part comprising: a fuel electrode layer that is located on the fuel electrode layer; a solid electrolyte layer that is located on the fuel electrode layer; a middle layer that is located on the solid electrolyte layer; and an air electrode layer that is located on the middle layer, the middle layer including: a first middle layer bonded to the solid electrolyte layer; and a second middle layer bonded to the air electrode layer; and a non-element part of the cell that comprises the entire cell excluding the air electrode layer, the non-element part located at least at a first of both ends of the plurality of cells in a longitudinal direction, and the plurality of cells is fixed to the manifold at least at the first end by a sealing material located between the manifoType: GrantFiled: March 13, 2019Date of Patent: October 18, 2022Assignee: KYOCERA CorporationInventor: Kazuya Imanaka
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Patent number: 11462749Abstract: A unit cell for a fuel cell stack including an anode catalyst layer separated by a polymer electrolyte membrane from a cathode catalyst layer, a first cell end plate separated by a first gas diffusion layer from the anode catalyst layer, and a second cell end plate separated by a second gas diffusion layer from the cathode catalyst layer, wherein the first cell end plate, the second cell end plate, or both include a matrix of electrically-conducting protrusions thereof.Type: GrantFiled: December 31, 2019Date of Patent: October 4, 2022Assignee: Robert Bosch GmbHInventors: Soo Kim, Nathan Craig, Nikhil Ravi, Jake Christensen
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Patent number: 11456475Abstract: A method for manufacturing a membrane assembly for a fuel cell, which membrane assembly includes a membrane with a catalyst layer and a frame arranged on the same side of the membrane and a gap between the catalyst layer and the frame. To allow an easy and cost-effective way for manufacturing such a membrane assembly, the manufacturing method may include the following steps: positioning a first decal layer, which is made of the same material as the first catalyst layer, on the first side of the membrane in a way that the first decal layer overlaps the frame, positioning a second decal layer, which is made of the same material as the second catalyst layer, on the second side of the membrane, pressing the first decal layer and the second decal layer against each other with the membrane and the frame positioned in-between.Type: GrantFiled: March 9, 2020Date of Patent: September 27, 2022Assignees: cellcentric GmbH & Co. KG, Ford Motor CompanyInventors: Owen Thomas, Keping Wang, Carmen Chuy, Yunsong Yang
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Patent number: 11430998Abstract: A fuel cell stack is described. The fuel cell stack comprises an interconnect assembly comprising a cathode-side interface coupled to an interconnect via a first joint, and an anode-side interface coupled to the interconnect via a second joint, the interconnect assembly having a first coefficient of thermal expansion (CTE) at an interface side of the interconnect assembly. The fuel cell stack further comprises a fuel cell element coupled to the interconnect assembly at the interface side via a hermetic seal, the fuel cell element having a second CTE at the interface side, the first CTE and the second CTE satisfying a predetermined CTE matching condition.Type: GrantFiled: January 6, 2020Date of Patent: August 30, 2022Assignee: THE BOEING COMPANYInventors: Marianne E. Mata, Ali Yousefiani, Adam J. Lang, Bruno Zamorano Senderos, Chellappa Balan
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Patent number: 11374242Abstract: Methods and apparatus for decoupling reactant activation and reaction completion. Various embodiments of the present disclosure leverage electrodynamic inversion principles to provide fuel cell-like operation. In one exemplary embodiment a fuel cell-like apparatus is configured to: create reactant ions (e.g., fuel ions, oxidant ions, etc.) in isolation, transport the reactant ions to a reaction interface, enable a chemical reaction, harvest the resulting electrical current, and eliminate the exhaust products. The exemplary fuel cell-like device decouples the reactants from directly powering the load. Notably, the redox reaction is allowed to proceed at a reaction interface rather than directly at the anode and cathode.Type: GrantFiled: April 5, 2020Date of Patent: June 28, 2022Inventor: Mark Minto
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Patent number: 11355773Abstract: A fuel cell stack has a prevention dam formed outside an alignment pin, such that a sealing material, which has viscosity and fluidity at a sealing temperature of a fuel cell, may be prevented from coming into contact with and adhering to the alignment pin, and pressure applied from the outside may be uniformly applied to the fuel cell stack.Type: GrantFiled: July 2, 2018Date of Patent: June 7, 2022Assignee: LG CHEM, LTD.Inventors: Sanghyun Park, Kwangwook Choi, Sanghyeok Im, Tai Min Noh, Kwangyeon Park, Daehwan Kim
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Patent number: 11349130Abstract: A method of producing an infiltrated solid oxide fuel cell (SOFC) layer. The method begins by infiltrating a solution containing a solute into a SOFC layer to produce a primary SOFC layer. The primary SOFC layer is then dried in a heated environment, wherein the heated environment ranges in temperature from about 25° C. to about 100° C. to produce a dry primary SOFC layer. The dry primary SOFC layer is then cooled at a rate less than about 5° C./min to room temperature to produce a cooled primary SOFC layer. The cooled primary SOFC layer is then heated to a temperature greater than 500° C. then quenching to a temperature from about 10° C. to about 30° C. to produce an infiltrated SOFC layer.Type: GrantFiled: December 11, 2019Date of Patent: May 31, 2022Assignee: Phillips 66 CompanyInventors: Ye Lin, Ying Liu, Mingfei Liu
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Patent number: 11335931Abstract: Disclosed is a composite polymer electrolyte membrane comprising: a support membrane; a metal ion-blocking layer stacked on the support membrane; a stabilization layer; and a protecting layer, wherein the support membrane includes a cation conductive polymer.Type: GrantFiled: November 22, 2019Date of Patent: May 17, 2022Assignee: KOREA INSTITUTE OF SCIENCE AND TECHNOLOGYInventors: Ji Hun Ahn, Heung Yong Ha, Sheeraz Mehboob
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Patent number: 11322766Abstract: A solid oxide fuel cell including a hydrocarbon reforming catalyst and a method for forming the solid oxide fuel cell are provided. An exemplary solid oxide fuel cell includes a cell. The cell includes a filled metal substrate including holes substantially filled with a permeable material that includes a hydrocarbon reforming catalyst, wherein the filled metal substrate has a front facing a fuel flow and a back facing an electrochemical stack. A permeable layer is formed on the back of the filled metal substrate that is in contact with the permeable material of the filled holes. The cell includes an anode layer proximate to the permeable layer, an electrolyte layer proximate to the anode layer, a diffusion barrier proximate to the anode layer, and a cathode proximate to the diffusion barrier.Type: GrantFiled: May 28, 2020Date of Patent: May 3, 2022Inventors: Kunho Lee, Sai P. Katikaneni
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Patent number: 11309549Abstract: The invention relates to a bipolar plate (40) for a fuel cell, comprising a first distributing region (50) for distributing a fuel to a first electrode (21) and a second distributing region (60) for distributing an oxidant to a second electrode (22). At least one woven fabric (80) is provided in at least one of the distributing regions (50, 60). The invention further relates to a fuel cell, comprising at least one membrane electrode assembly (10) having a first electrode (21) and a second electrode (22), which are separated from each other by a membrane (18), and comprising at least one bipolar plate (40) according to the invention.Type: GrantFiled: November 30, 2017Date of Patent: April 19, 2022Assignee: Robert Bosch GmbHInventors: Ulrich Berner, Jan Hendrik Ohs, Stefan Schoenbauer
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Patent number: 11309551Abstract: The present invention relates to a separator plate for an electro-chemical system. The separator plate comprises: a first passage; an active region with structures for guiding a reaction medium along a first flat face of the separator plate and guiding a coolant along a rear face of the active region on the second flat face of the separator plate; a bead formed in the separator plate for sealing at least the active region; and barrier elements formed in the separator plate, which reduce or prevent a flow of reaction medium on the first flat face of the separator plate along the bead and past the active region. The separator plate fully encloses the first passage and the active region together and that at least one of the barrier elements is at least in parts sunk.Type: GrantFiled: May 30, 2018Date of Patent: April 19, 2022Assignee: Reinz-Dichtungs-GmbHInventors: Thomas Stöhr, Claudia Kunz
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Patent number: 11302948Abstract: Disclosed are redox flow battery membranes, redox flow batteries incorporating the membranes, and methods of forming the membranes. The membranes include a polybenzimidazole gel membrane that is capable of incorporating a high liquid content without loss of structure that is formed according to a process that includes in situ hydrolysis of a polyphosphoric acid solvent. The membranes are imbibed with a redox flow battery supporting electrolyte such as sulfuric acid and can operate at very high ionic conductivities of about 100 mS/cm or greater. Redox flow batteries incorporating the PBI-based membranes can operate at high current densities of about 100 mA/cm2 or greater.Type: GrantFiled: September 13, 2019Date of Patent: April 12, 2022Assignee: University of South CarolinaInventors: Brian C. Benicewicz, Laura Murdock, Lihui Wang, Fei Huang, Andrew Pingitore
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Patent number: 11296332Abstract: A cell may include a columnar support having a first main face and a second main face; and an element comprising a first electrode layer, a solid electrolyte layer, and a second electrode layer laminated in sequence on the first main face of the support. The porosity of at least one of the two end portions of the support in the longitudinal direction L may be lower than that of the central portion of the support in the longitudinal direction L.Type: GrantFiled: May 19, 2020Date of Patent: April 5, 2022Assignee: KYOCERA CorporationInventor: Makoto Koi
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Patent number: 11283096Abstract: A method for fabricating an electrochemical sensor material includes positioning sheets of molded graphene nanoplatelets on each side of a proton exchange membrane and integrating graphene nanoplatelets into regions of the proton exchange membrane adjacent its surfaces by applying heat to increase the temperature of the proton exchange membrane to its glass transition temperature and applying compressive pressure to press a portion of each sheet of molded graphene nanoplatelets into the softened polymeric material of the proton exchange membrane. Following application of heat and pressure, the proton exchange membrane is cooled and excess graphene material is exfoliated. Electrochemical sensor components are cut from the material and electrochemical devices and systems are constructed therefrom.Type: GrantFiled: May 22, 2019Date of Patent: March 22, 2022Assignee: Arborsense, Inc.Inventors: Girish Kulkarni, Donald Kahaian
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Patent number: 11276903Abstract: An electricity storage device according to one embodiment is an electricity storage device in which a plurality of bipolar electrodes in which a positive electrode layer is provided on one surface of a collector plate and a negative electrode layer is provided on the other surface of the collector plate are stacked via separators and includes a plurality of spacers arranged along peripheral edges of the collector plates between the respective collector plates adjacent to each other in a stacking direction and a resin frame covering outer peripheries of the plurality of spacers.Type: GrantFiled: June 20, 2017Date of Patent: March 15, 2022Assignee: KABUSHIKI KAISHA TOYOTA KIDOSHOKKIInventors: Kojiro Tamaru, Takayuki Hirose, Atsuhiko Nishii, Satoshi Endo, Tomohiro Nakamura
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Patent number: 11276869Abstract: This disclosure relates to a hydrogen fuel cell stack with one or more hydrogen fuel cell (102) having in turn a proton exchange membrane (104), a hydrogen reaction layer (112) and an oxygen reaction layer (116) within a pair of bipolar plates (106). At least a bipolar plate (106) comprises a channel (108) inside for hydrogen inflow. Additionally, this disclosure relates to a method of upgrading a hydrogen fuel cell stack, said method comprising inserting a channel (108) for hydrogen inflow inside at least a bipolar plate (106).Type: GrantFiled: March 31, 2017Date of Patent: March 15, 2022Assignee: The Boeing CompanyInventors: José Antonio Blanco, Nieves Lapeña, Jose L. Lemus, Enrique Emilio Serrot Hauke, Eduardo G. Ferreyra
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Patent number: 11228040Abstract: The invention relates to a gas distributor plate for a fuel cell, comprising a first distribution structure for distributing a fuel to a first electrode and a second distribution structure (60) for distributing an oxidation agent to a second electrode. According to the invention, there is at least one wire element (80) in at least one of the distribution structures (60). The invention further relates to a fuel cell, which comprises at least one membrane electrode unit having a first electrode and a second electrode, which are separated from each other by a membrane, and at least one gas distribution plate according to the invention.Type: GrantFiled: December 19, 2017Date of Patent: January 18, 2022Assignee: ROBERT BOSCH GMBHInventor: Alexander Eifert
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Patent number: 11145870Abstract: A method of producing an infiltrated solid oxide fuel cell (SOFC) layer. The method begins by infiltrating a solution containing a solute into a SOFC layer to produce a primary SOFC layer. The primary SOFC layer is then dried in a heated environment, wherein the heated environment ranges in temperature from about 25° C. to about 100° C. to produce a dry primary SOFC layer. The dry primary SOFC layer is then cooled at a rate less than about 5° C./min to room temperature to produce a cooled primary SOFC layer. The cooled primary SOFC layer is then heated to a temperature greater than 500° C. then quenching to a temperature from about 10° C. to about 30° C. to produce an infiltrated SOFC layer.Type: GrantFiled: December 11, 2019Date of Patent: October 12, 2021Assignee: Phillips 66 CompanyInventors: Ye Lin, Ying Liu, Mingfei Liu
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Patent number: 11108060Abstract: A fuel cell stack structure in which unit cells are stacked includes first window frames and second window frame. The second window frames each have an area larger than an area of a first window frame and are periodically disposed at a predetermined interval in a direction in which the unit cells are stacked. Heat movement is promoted, a temperature deviation in the fuel cell stack structure is mitigated, and a temperature distribution is uniformized.Type: GrantFiled: July 18, 2018Date of Patent: August 31, 2021Assignee: LG CHEM, LTD.Inventors: Tai Min Noh, Jaesung Kim, Sanghyeok Im, Kwangyeon Park, Ye Hoon Im, Kwangwook Choi, Junwon Choi
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Patent number: 11063278Abstract: A method for making contact with a plurality of separator plates of a fuel cell system includes the steps of: inserting at least one connecting element of a cell voltage monitoring system between two directly adjacent separator plates so that two connecting parts of the connecting element that are able to move with respect to one another are arranged at least in certain regions between the directly adjacent separator plates; and relatively moving the two connecting parts that are able to move with respect to one another so that at least one first connecting part of the connecting parts moves at least in sections toward a separator plate of the directly adjacent separator plates.Type: GrantFiled: December 5, 2018Date of Patent: July 13, 2021Assignee: Bayerische Motoren Werke AktiengesellschaftInventors: Marco Hausrath, Florian Kriesch, Stefan Haase
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Patent number: 11043683Abstract: A fuel cell system includes a fuel cell stack that produces electric power and water through an electro-chemical reaction of hydrogen and air. A controller of the fuel cell system calculates an amount of water in the fuel cell stack based on output power of the fuel cell stack and a maximum amount of residual water to which the amount of water in the fuel cell stack converges over time. The fuel cell system may detect the amount of water in the fuel cell stack in real time.Type: GrantFiled: July 31, 2018Date of Patent: June 22, 2021Assignees: HYUNDAI MOTOR COMPANY, KIA MOTORS CORPORATIONInventors: Sung Ho Lee, Jong Jin Yoon
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Patent number: 10998558Abstract: Fuel cell stack assemblies (100) have a positive end plate (200) and a negative end plate (300), The end plates (200, 300) can be formed from a central structural element (220, 320) with an insulating end plate cover (210, 310) and an insulating end plate manifold (230, 330). A plurality of cathode plates (150) and a plurality of fuel cell assemblies (250) can be arranged in a stack having an alternating pattern of cathode plates (150) and fuel cell assemblies (250), with the positive end plate (200) and the negative end plate (300) provided on either end of the stack of cathode plates and fuel cell assemblies.Type: GrantFiled: April 16, 2019Date of Patent: May 4, 2021Assignee: Intelligent Energy LimitedInventors: Stephen Longley, Jonathan Cole
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Patent number: 10971293Abstract: A spin-orbit-torque magnetization rotational element includes: a spin-orbit torque wiring layer which extends in an X direction; and a first ferromagnetic layer which is laminated on the spin-orbit torque wiring layer, wherein the first ferromagnetic layer has shape anisotropy and has a major axis in a Y direction orthogonal to the X direction on a plane in which the spin-orbit torque wiring layer extends, and wherein the easy axis of magnetization of the first ferromagnetic layer is inclined with respect to the X direction and the Y direction orthogonal to the X direction on a plane in which the spin-orbit torque wiring layer extends.Type: GrantFiled: December 17, 2018Date of Patent: April 6, 2021Assignee: TDK CORPORATIONInventors: Tomoyuki Sasaki, Yohei Shiokawa