Comprising A Carbonate Patents (Class 429/478)
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Patent number: 11374235Abstract: An anode of a fuel cell has an anode current collector defining an inlet configured to receive fuel gas and an outlet configured to output the fuel gas, a barrier that divides an active area of the anode current collector into a first area and a second area, and a flow passage configured to allow a flow of fuel gas from the inlet through the first area and the second area to the outlet. An obstacle is located in the flow passage in an inactive area of the anode current collector and is configured to change a flow direction of the fuel gas in the flow passage from the first area to the second area to achieve intra-cell mixing of the fuel gas.Type: GrantFiled: November 26, 2019Date of Patent: June 28, 2022Assignee: FuelCell Energy, Inc.Inventor: Hossein Ghezel-Ayagh
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Patent number: 10985384Abstract: A cathode current collector is made from a composite material including a first metallic layer made of a first metal and a second metallic layer made of a second metal different from the first metal. The first metallic layer is cladded with the second metallic layer. The first metallic layer is configured to form a conductive oxide corrosion layer in the presence of oxygen, molten carbonate electrolyte, or a combination thereof. The second metallic layer is corrosion resistant.Type: GrantFiled: January 11, 2018Date of Patent: April 20, 2021Assignee: FuelCell Energy, Inc.Inventors: Ling Chen, Chao-Yi Yuh
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Patent number: 10957918Abstract: A method of making an electrolyte matrix includes: preparing a slurry comprising a support material, a coarsening inhibitor, an electrolyte material, and a solvent; and drying the slurry to form an electrolyte matrix. The support material comprises lithium aluminate, the coarsening inhibitor comprises a material selected from the group consisting of MnO2, Mn2O3, TiO2, ZrO2, Fe2O3, LiFe2O3, and mixtures thereof, and the coarsening inhibitor has a particle size of about 0.005 ?m to about 0.5 ?m.Type: GrantFiled: July 24, 2020Date of Patent: March 23, 2021Assignee: FuelCell Energy, Inc.Inventors: Abdelkader Hilmi, Arun Surendranath, Chao-Yi Yuh, Mohammad Farooque
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Patent number: 10494707Abstract: Provided is an austenitic stainless steel for a fuel cell including, in weight %, C: 0.05% to 0.09%, Si: 0.5% or less (0 excluded), Mn: 2.5% to 5.0%, Cr: 21% to 23%, Ni: 10% to 12%, Nb: 0.2% to 0.7%, N: 0.25% or less (0 excluded), Al: 0.2% or less (0 excluded), S: 0.003% or less (0 excluded), B: 0.01% or less (0 excluded), the remainder being Fe and unavoidable impurities.Type: GrantFiled: December 22, 2015Date of Patent: December 3, 2019Assignee: POSCOInventors: Kwang Min Kim, Jong Hee Kim, Ki Hoon Jo, Bo Sung Seo
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Patent number: 10455852Abstract: A defrosting tray includes a metal substrate, a thermal conductive ceramic coating formed on the top surface of the metal substrate, and an inorganic nanocoating formed on a top surface of the thermal conductive ceramic coating. The thermal conductive ceramic coating is configured to enhance a heat transfer capability of the metal substrate. In particular, the first ceramic coating and the first inorganic nanocoating together define a defrosting surface with sub-micron pyramidal arrays.Type: GrantFiled: April 13, 2016Date of Patent: October 29, 2019Inventor: Meng-Hsiu Hsieh
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Patent number: 10381655Abstract: A novel method to modify the surface of lanthanum and strontium containing cathode powders before or after sintering by depositing layers of gadolinium doped ceria (GDC) and/or samarium doped ceria or similar materials via atomic layer deposition on the powders. The surface modified powders are sintered into porous cathodes that have utility enhancing the electrochemical performance of the cathodes, particularly for use in solid oxide fuel cells. Similar enhancements are observed for surface treatment of sintered cathodes.Type: GrantFiled: July 13, 2016Date of Patent: August 13, 2019Assignee: Sonata Scientific LLCInventors: Jeffrey F. Roeder, Anthony F. Zeberoff, Peter C. Van Buskirk
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Patent number: 10276875Abstract: An anode for a molten carbonate fuel cell (MCFC) having improved creep property by adding CeO2 and/or Cr for imparting creep resistance to nickel-aluminum alloy and nickel as materials for an anode is provided. Improved sintering property, creep property and increased mechanical strength of a molten carbonate fuel cell may be obtained accordingly.Type: GrantFiled: December 9, 2016Date of Patent: April 30, 2019Assignee: Korean Institute of Science and TechnologyInventors: Hyung Chul Ham, Min-Jae Lee, Chang-Whan Lee, Seong Cheol Jang, Sun-Hee Choi, Hyun Seo Park, Chang Won Yoon, Sung Pil Yoon, Jonghee Han, Suk Woo Nam, Tae Hoon Lim, Jin Young Kim
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Patent number: 9627728Abstract: A rechargeable electrochemical battery cell includes a molten carbonate salt electrolyte whose anion transports oxygen between a metal electrode and an air electrode on opposite sides of the electrolyte, where the molten salt electrolyte is retained inside voids of a porous electrolyte supporting structure sandwiched by the electrodes, and the molten salt includes carbonate including at least one of the alkaline carbonate including Li2Co2, NA2CO2, and K2CO2, having a melting point between 400° C. and 800° C.Type: GrantFiled: November 2, 2012Date of Patent: April 18, 2017Assignee: SIEMENS AKTIENGESELLSCHAFTInventor: Chun Lu
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Patent number: 9496576Abstract: The present invention relates to a thin and in principle unsupported solid oxide cell, comprising at least a porous anode layer, an electrolyte layer and a porous cathode layer, wherein the anode layer and the cathode layer comprise an electrolyte material, at least one metal and a catalyst material, and wherein the overall thickness of the thin reversible cell is about 150 ?m or less, and to a method for producing same. The present invention also relates to a thin and in principle unsupported solid oxide cell, comprising at least a porous anode layer, an electrolyte layer and a porous cathode layer, wherein the anode layer and the cathode layer comprise an electrolyte material and a catalyst material, wherein the electrolyte material is doper zirconia, and wherein the overall thickness of the thin reversible cell is about 150 ?m or less, and to a method for producing same.Type: GrantFiled: November 23, 2007Date of Patent: November 15, 2016Assignee: Technical University of DenmarkInventors: Peter Halvor Larsen, Soeren Linderoth, Peter Vang Hendriksen
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Patent number: 9225030Abstract: The present disclosure relates to a solid oxide fuel cell. The solid oxide fuel cell includes an electrolyte comprising a mixed proton and carbonate ion conductor. The mixed proton and carbonate ion conductor includes a proton conducting ceramic impregnated with impregnated with a molten carbonate.Type: GrantFiled: June 20, 2012Date of Patent: December 29, 2015Assignee: University of South CarolinaInventors: Kevin Huang, Xue Li
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Patent number: 9160023Abstract: The present invention relates to an electrolyte-impregnated, reinforced matrix for molten carbonate fuel cells and a manufacturing method thereof. According to the invention, the electrolyte-impregnated matrix, which comprises both the electrolyte and the reinforcing particles including a metal and an oxide, is manufactured by adding the electrolyte, as required per unit cell of a fuel cell, and the reinforcing particles including the metal and the oxide, to a slurry during the matrix preparation step, and subjecting the resulting slurry to a tape casting process. By doing so, the matrix stacking operation is facilitated, and the matrix manufacturing process is simplified. In addition, cracking caused by the difference in thermal expansion coefficient between an electrolyte sheet and the matrix can be suppressed, and thermal shock occurring during operation of the fuel cell stack can be reduced, thus improving the performance and lifetime of the fuel cell.Type: GrantFiled: October 29, 2009Date of Patent: October 13, 2015Assignee: DOOSAN HEAVY INDUSTRIES & CONSTRUCTION CO., LTD.Inventors: Mi Young Shin, Bo Hyun Ryu, Hwan Moon, Ju Young Youn, Chang Sung Jun, Tae Won Lee, Kil Ho Moon
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Patent number: 9065127Abstract: Systems and methods for sintering and conditioning fuel cell stacks utilizing channel guides, baffles, and internal compression systems are provided. Sintering and conditioning may be performed utilizing a fuel cell column cartridge assembly and fuel cell stacks may be sintered and conditioned at the system level during the same annealing cycle on the same support.Type: GrantFiled: February 15, 2013Date of Patent: June 23, 2015Assignee: BLOOM ENERGY CORPORATIONInventors: Matthias Gottmann, Nathan Ben Erlin, Kurt Risic, Stephen Couse, David Edmonston
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Patent number: 8999598Abstract: Disclosed is a molten carbonate fuel cell comprising a reinforced lithium aluminate matrix, a cathode, an anode, a cathode frame channel and an anode frame channel, wherein at least one of the cathode frame channel and the anode frame channel is filled with a lithium source. Disclosed also are a method for producing the same, and a method for supplying a lithium source. The molten carbonate fuel cell in which a lithium source is supplied to an electrode has high mechanical strength and maintains stability of electrolyte to allow long-term operation.Type: GrantFiled: January 18, 2012Date of Patent: April 7, 2015Assignee: Korea Institute of Science & TechnologyInventors: Sung Pil Yoon, In Hwan Oh, Jong Hee Han, Suk Woo Nam, Seong Cheol Jang, Shin Ae Song, Tae Won Lee, In Gab Chang, Bo Hyun Ryu
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Publication number: 20150093676Abstract: Systems and methods are provided for incorporating molten carbonate fuel cells into a heat recovery steam generation system (HRSG) for production of electrical power while also reducing or minimizing the amount of CO2 present in the flue gas exiting the HRSG. An optionally multi-layer screen or wall of molten carbonate fuel cells can be inserted into the HRSG so that the screen of molten carbonate fuel cells substantially fills the cross-sectional area. By using the walls of the HRSG and the screen of molten carbonate fuel cells to form a cathode input manifold, the overall amount of duct or flow passages associated with the MCFCs can be reduced.Type: ApplicationFiled: July 8, 2014Publication date: April 2, 2015Applicant: EXXONMOBIL RESEARCH AND ENGINEERING COMPANYInventors: Paul J. Berlowitz, Timothy Andrew Barckholtz, Frank H. Hershkowitz
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Patent number: 8936887Abstract: A composite electrolyte membrane for a fuel cell with a controlled phosphoric acid-based material retention ratio. The composite electrolyte membrane includes an electrolyte membrane containing a compound having a phosphoric acid-based material-containing functional group. Also disclosed are a method for manufacturing the composite electrolyte membrane, and a fuel cell including the composite electrolyte membrane.Type: GrantFiled: February 3, 2012Date of Patent: January 20, 2015Assignee: Samsung Electronics Co., Ltd.Inventors: Seong-woo Choi, Dae-jong Yoo, Ki-hyun Kim
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Patent number: 8932779Abstract: A device for a solid oxide fuel cell or a solid oxide electrolysis cell includes an integral one-piece construction of a current collector and a manifold. The device eliminates the need for a brazing or thermal bonding process for joining the manifold with the current collector, and thus makes it possible to prevent breakdown of the junction formed between the manifold and the current collector, which can lead to gas leakage through the junction, and thus can be used for a long period of time.Type: GrantFiled: August 15, 2012Date of Patent: January 13, 2015Assignee: Korea Institute of Energy ResearchInventors: Sun-Dong Kim, Doo-Won Seo, In-Sub Han, Ji-Haeng Yu, Se-Young Kim, Sang-Kuk Woo
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Patent number: 8557468Abstract: A high-performance carbonate electrolyte for use in a molten carbonate fuel cell comprising a cathode electrode, an anode electrode, an electrolyte matrix and at least a cathode current collector abutting said cathode electrode, the high-performance carbonate electrolyte comprising: a first carbonate electrolyte stored in at least the cathode electrode of the molten carbonate fuel cell comprising a mixture of eutectic Li/Na carbonate electrolyte doped with one or more additive materials and one or more lithium precursors, wherein the additive materials include one or more of Rb2CO3, Cs2CO3, BaCO3, La2O3, Bi2O3, Ta2O5 and mixtures thereof, and a second carbonate electrolyte stored in at least the cathode current collector, the second carbonate electrolyte having a composition that is the same or different from the first carbonate electrolyte.Type: GrantFiled: July 21, 2010Date of Patent: October 15, 2013Assignee: FuelCell Energy, Inc.Inventors: Abdelkader Hilmi, Chao-Yi Yuh, Mohammad Farooque
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Publication number: 20130224621Abstract: A molten carbonate fuel cell, which makes a separator unnecessary, cuts down the number of components, and markedly reduces the costs, is provided. In the cell, a cathode, an electrolyte plate holding an electrolyte, and an anode are provided concentrically with a tube body, the electrolyte plate is held by the anode, and the electrolyte plate is sandwiched between the anode and the cathode, so that the cell is constructed without the use of a separator.Type: ApplicationFiled: February 26, 2013Publication date: August 29, 2013Applicant: CENTRAL RESEARCH INSTITUTE OF ELECTRIC POWER INDUSTRYInventor: CENTRAL RESEARCH INSTITUTE OF ELECTRIC POWER INDUSTRY
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Publication number: 20130143142Abstract: The present invention discloses a novel BZCYYb-carbonate composite electrolyte and method for making the same. The BZCYYb is porous, and the lithium-potassium carbonate is infiltrated or entrained within the pores of the BZCYYb to have better conductivity at the phase boundaries.Type: ApplicationFiled: August 28, 2012Publication date: June 6, 2013Applicants: GEORGIA TECH RESEARCH CORPORATION, PHILLIPS 66 COMPANYInventors: Mingfei LIU, Meilin LIU, Ting HE
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Patent number: 8435694Abstract: A molten carbonate fuel cell cathode having a cathode body and a coating of a mixed oxygen ion conductor materials. The mixed oxygen ion conductor materials are formed from ceria or doped ceria, such as gadolinium doped ceria or yttrium doped ceria. The coating is deposited on the cathode body using a sol-gel process, which utilizes as precursors organometallic compounds, organic and inorganic salts, hydroxides or alkoxides and which uses as the solvent water, organic solvent or a mixture of same.Type: GrantFiled: January 12, 2004Date of Patent: May 7, 2013Assignee: FuelCell Energy, Inc.Inventors: Abdelkader Hilmi, Chao-Yi Yuh
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Patent number: 8383283Abstract: A fuel cell includes an electrolyte matrix having a cathode side with a cathode disposed thereon and an anode side with an anode receiving portion and a sealing portion positioned peripherally to the anode receiving portion. The anode receiving portion has an anode disposed thereon. A fuel conduit has one or more one sealing platforms and having an opening extending through the fuel conduit. The anode is positioned in the opening. The fuel cell includes one or more devices for preventing the occurrence an electrical short circuit between the cathode and the sealing platform. The device for preventing the electrical short circuit is aligned with the sealing portion and sealing platform and is positioned on the electrolyte matrix, the cathode and/or the sealing platform.Type: GrantFiled: April 15, 2009Date of Patent: February 26, 2013Assignee: FuelCell Energy, Inc.Inventors: Chao-yi Yun, Mohammad Farooque, Abdelkader Hilmi, Richard Johnsen, Gengfu Xu
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Patent number: 8367265Abstract: A solid oxide fuel cell includes an anode layer, an electrolyte layer over the anode layer, and a cathode layer over the electrolyte layer. At least one of the anode layer and the cathode layer defines a gas manifold. The gas manifold includes a gas inlet, defined by an edge of the anode layer or cathode layer, a gas outlet, defined by the same or a different edge of the anode layer or cathode layer, and a plurality of gas flow channels in fluid communication with the gas inlet and gas outlet. The gas flow channels can have diameters that conduct flow of gas from the gas inlet at substantially equal flow rates among the gas flow channels.Type: GrantFiled: December 15, 2009Date of Patent: February 5, 2013Assignee: Saint-Gobain Ceramics & Plastics, Inc.Inventors: James A. Salvatore, Vignesh Rajamani, Abhijit Dutta
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Patent number: 8338041Abstract: To provide a reformer that uses a relatively inexpensive granular catalyst and can provide a more uniform temperature distribution in a catalyst bed while suppressing increase in the size of the reformer and the required power and size of an auxiliary machine, and a more compact indirect internal reforming high temperature fuel cell while suppressing increase in cost. A reformer that produces a hydrogen-containing gas from a hydrocarbon-based fuel by a steam reforming reaction has a reactor vessel and a reforming catalyst bed packed with a granular catalyst having steam reforming activity in the reactor vessel, the reformer has a partition plate that divides the reforming catalyst bed into at least two sections, the partition plate has a thermal conductivity higher than effective thermal conductivity of the catalyst bed, and the partition plate extends in the reactor vessel from a part which is at a higher temperature in a rated operation to a part which is at a lower temperature in rated operation.Type: GrantFiled: May 15, 2008Date of Patent: December 25, 2012Assignee: Nippon Oil CorporationInventor: Susumu Hatada
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Patent number: 8283078Abstract: A system for preparing particulate carbon fuel and using the particulate carbon fuel in a fuel cell. Carbon particles are finely divided. The finely dividing carbon particles are introduced into the fuel cell. A gas containing oxygen is introduced into the fuel cell. The finely divided carbon particles are exposed to carbonate salts, or to molten NaOH or KOH or LiOH or mixtures of NaOH or KOH or LiOH, or to mixed hydroxides, or to alkali and alkaline earth nitrates.Type: GrantFiled: December 16, 2011Date of Patent: October 9, 2012Assignee: Lawrence Livermore National Security, LLCInventors: John F. Cooper, Nerine Cherepy
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Publication number: 20120231364Abstract: Provided is a cathode for molten carbonate fuel cells, including a porous nickel-based electrode containing nickel particles, and metal particles coated on the electrode, wherein at least a part of the metal particles are attached to the surface of the nickel particles. A method for preparing the same is also provided. The cathode for molten carbonate fuel cells accelerates the cathodic oxygen reduction and reduces polarization resistance occurring at the cathode, thereby providing a fuel cell with improved performance even at low temperature. Additionally, it is possible to improve the service life of a molten carbonate fuel cell due to such low operation temperature.Type: ApplicationFiled: January 19, 2012Publication date: September 13, 2012Applicant: KOREA INSTITUTE OF SCIENCE AND TECHNOLOGYInventors: Jong Hee HAN, Shin Ae SONG, Sung Pil YOON, Suk Woo NAM, Tae Hoon LIM, In Hwan OH, Dae Ki CHOI, Seong Ahn HONG, Chang Won YOON
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Patent number: 8182962Abstract: The present invention relates to a fuel cell separator plate comprising at least one separator sheet and at least one flange suitable to be fixed on the side of the separator sheet by means of shape-coupling. The invention also relates to a fuel cell comprising said separator sheet, preferably a molten carbonate fuel cell (MCFC). The invention also relates to a stack of these fuel cells being electrically coupled to each other.Type: GrantFiled: April 21, 2005Date of Patent: May 22, 2012Assignee: Ansaldo Fuels S.p.A.Inventors: Sergio Fasce, Lorenzo Tosonotti, Maurizio Zappaterra
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Patent number: 8163437Abstract: A molten carbonate fuel cell anode comprising a porous anode body, which comprises a nickel-based alloy and at least one ceramic additive dispersed throughout the anode body. The amount of the ceramic additive in the anode body is between 5 and 50% by volume. The nickel-based alloy is Ni—Cr or Ni—Al, and the ceramic additive is one of CeO2, yttrium doped ceria, yttrium doped zirconia, TiO2, Li2TiO3, LiAlO2 and La0.8Sr0.2CoO3.Type: GrantFiled: March 25, 2008Date of Patent: April 24, 2012Assignee: FuelCell Energy, Inc.Inventors: Abdelkader Hilmi, Chao-Yi Yuh, Mohammad Farooque
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Patent number: 8110314Abstract: A system and a method for suppressing the build up of metal carbonates in the electrolyte, using a porous cell separator is used to allow the use of different electrolyte compositions around the anode (anolyte) and the cathode (catholyte). This cell configuration enables the oxygen cathode to operate in a molten hydroxide electrolyte, and the carbon anode to operate in mixed carbonate-hydroxide melt, so that most of the advantages of using a molten hydroxide electrolyte will be retained.Type: GrantFiled: June 20, 2005Date of Patent: February 7, 2012Assignee: Scientific Applications and Research Associates, Inc.Inventors: Strahinja Zecevic, Edward Patton, Parviz Parhami
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Publication number: 20120021328Abstract: A high-performance carbonate electrolyte for use in a molten carbonate fuel cell comprising a cathode electrode, an anode electrode, an electrolyte matrix and at least a cathode current collector abutting said cathode electrode, the high-performance carbonate electrolyte comprising: a first carbonate electrolyte stored in at least the cathode electrode of the molten carbonate fuel cell comprising a mixture of eutectic Li/Na carbonate electrolyte doped with one or more additive materials and one or more lithium precursors, wherein the additive materials include one or more of Rb2CO3, Cs2CO3, BaCO3, La2O3, Bi2O3, Ta2O5 and mixtures thereof, and a second carbonate electrolyte stored in at least the cathode current collector, the second carbonate electrolyte having a composition that is the same or different from the first carbonate electrolyte.Type: ApplicationFiled: July 21, 2010Publication date: January 26, 2012Inventors: ABDELKADER HILMI, Chao-Yi Yuh, Mohammad Farooque
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Patent number: 8101305Abstract: A system for preparing particulate carbon fuel and using the particulate carbon fuel in a fuel cell. Carbon particles are finely divided. The finely dividing carbon particles are introduced into the fuel cell. A gas containing oxygen is introduced into the fuel cell. The finely divided carbon particles are exposed to carbonate salts, or to molten NaOH or KOH or LiOH or mixtures of NaOH or KOH or LiOH, or to mixed hydroxides, or to alkali and alkaline earth nitrates.Type: GrantFiled: March 4, 2011Date of Patent: January 24, 2012Assignee: Lawrence Livermore National Security, LLCInventors: John F. Cooper, Nerine Cherepy
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Publication number: 20110287333Abstract: The present invention relates to an electrolyte-impregnated, reinforced matrix for molten carbonate fuel cells and a manufacturing method thereof. According to the invention, the electrolyte-impregnated matrix, which comprises both the electrolyte and the reinforcing particles including a metal and an oxide, is manufactured by adding the electrolyte, as required per unit cell of a fuel cell, and the reinforcing particles including the metal and the oxide, to a slurry during the matrix preparation step, and subjecting the resulting slurry to a tape casting process. By doing so, the matrix stacking operation is facilitated, and the matrix manufacturing process is simplified. In addition, cracking caused by the difference in thermal expansion coefficient between an electrolyte sheet and the matrix can be suppressed, and thermal shock occurring during operation of the fuel cell stack can be reduced, thus improving the performance and lifetime of the fuel cell.Type: ApplicationFiled: October 29, 2009Publication date: November 24, 2011Applicant: DOOSAN HEAVY INDUSTRIES & CONSTRUCTION CO., LTD.Inventors: Mi Young Shin, Bo Hyun Ryu, Hwan Moon, Ju Young Youn, Chang Sung Jun, Tae Won Lee, Kil Ho Moon
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Publication number: 20110250521Abstract: Disclosed herein is a method of manufacturing an anode for in-situ sintering for a molten carbonate fuel cell, in which an anode green sheet is prepared using a slurry, and then a reinforcing layer is placed on the anode green sheet and then pressed, thereby improving the mechanical stability of a fuel cell stack and the long term stability of an anode, and an anode manufactured using the method.Type: ApplicationFiled: February 26, 2009Publication date: October 13, 2011Applicant: DOOSAN HEAVY INDUSTRIES & CONSTRUCTION CO., LTDInventors: Hwan Moon, Bo Hyun Ryu, Jang Yong You, Ju Young Youn, Mi Young Shin, Woon Yong Choi, Tae Won Lee, In Gab Chang, Kil Ho Moon
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Patent number: 7998627Abstract: A system for preparing particulate carbon fuel and using the particulate carbon fuel in a fuel cell. Carbon particles are finely divided. The finely dividing carbon particles are introduced into the fuel cell. A gas containing oxygen is introduced into the fuel cell. The finely divided carbon particles are exposed to carbonate salts, or to molten NaOH or KOH or LiOH or mixtures of NaOH or KOH or LiOH, or to mixed hydroxides, or to alkali and alkaline earth nitrates.Type: GrantFiled: July 14, 2008Date of Patent: August 16, 2011Assignee: Lawrence Livermore National Security, LLCInventors: John F. Cooper, Nerine Cherepy
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Publication number: 20110177422Abstract: Reaction mechanisms in a fuel cell device are disclosed. In one aspect of the present disclosure, the fuel cell includes a composite cathode element that is vertically oriented. The composite cathode element further comprises a porous matrix holding electrolyte, a cathode, and/or a cathode current collector. One embodiment of the fuel cell further includes, an anode chamber coupled to the composite cathode element, the anode chamber being vertically oriented. During operation, fuel injected into the fuel cell is oxidized in the anode chamber by oxidizer ions are generated from oxidizer gas. The oxidizer gas can include a mixture of oxygen and carbon dioxide or just oxygen.Type: ApplicationFiled: January 15, 2010Publication date: July 21, 2011Applicant: 4D Power, LLCInventors: Ronald H. Wolk, Iouri I. Balachov, J. Robert Selman
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Patent number: 7981563Abstract: A direct carbon fuel cell having an anode electrode of carbon particles pre-wetted with carbonate, a cathode electrode, and an electrolyte layer disposed between the anode electrode and the cathode electrode and containing a molten carbonate. The fuel cell includes a wicking feature whereby excess carbonate produced during the operation of the fuel cell is removed. The use of carbonate pre-wetted carbon particles as the anode provides a network of empty voids, facilitating the removal of CO2 gas from the cell, thereby enhancing fuel cell performance.Type: GrantFiled: November 26, 2007Date of Patent: July 19, 2011Assignee: Gas Technology InstituteInventors: Estela T. Ong, Kevin Krist, Chakravarthy Sishtla
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Publication number: 20110151349Abstract: A double-electrolyte fuel-cell is presented for generating electrical energy from chemical fuel. The fuel-cell includes an anode, a cathode as well as both an anion-conducting electrolyte and a cation-conducting electrolyte. A fuel-cell stack is also presented consisting of a plurality of double-electrolyte fuel-cells.Type: ApplicationFiled: June 10, 2009Publication date: June 23, 2011Applicant: TECHNION RESEARCH & DEVELOPMENT FOUNDATION LTD.Inventor: Yoed Tsur
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Patent number: 7919214Abstract: Carbonate fuel cathode side hardware having a thin coating of a conductive ceramic formed from one of Perovskite AMeO3, wherein A is at least one of lanthanum and a combination of lanthanum and strontium and Me is one or more of transition metals, lithiated NiO (LixNiO, where x is 0.1 to 1) and X-doped LiMeO2, wherein X is one of Mg, Ca, and Co.Type: GrantFiled: May 25, 2005Date of Patent: April 5, 2011Assignee: FuelCell Energy, Inc.Inventors: Gengfu Xu, Chao-Yi Yuh
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Patent number: 7914946Abstract: Carbonate fuel cathode side hardware having a thin coating of a conductive ceramic formed from one of LSC (La0.8Sr0.2CoO3) and lithiated NiO (LixNiO, where x is 0.1 to 1).Type: GrantFiled: June 15, 2004Date of Patent: March 29, 2011Assignee: FuelCell Energy, Inc.Inventors: Gengfu Xu, Chao-Yi Yuh
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Patent number: 7862938Abstract: A fuel cell and heat engine hybrid system using a high-temperature fuel cell having an anode compartment adapted to receive fuel from a fuel supply path and to output anode exhaust gas and a cathode compartment adapted to receive oxidant gas and to output cathode exhaust gas. A heat engine assembly is adapted to receive oxidant gas and a further gas comprising one of the anode exhaust gas and a gas derived from the anode exhaust gas and to cause oxidation of the further gas and generate output power, the heat engine also generating heat engine exhaust including oxidant gas. The heat engine exhaust is then used to provide oxidant gas to the cathode compartment of the fuel cell.Type: GrantFiled: April 10, 2007Date of Patent: January 4, 2011Assignee: FuelCell Energy, Inc.Inventor: Hossein Ghezel-Ayagh
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Publication number: 20100196778Abstract: The present invention provides a method of manufacturing a porous metal electrode for a molten carbonate fuel cell using a dry process. According to the method of manufacturing a porous metal electrode of the present invention, in the press process for controlling the thickness of dry-cast metal powder and rearranging the dry-cast metal powder, the microstructure of the porous metal electrode can be controlled, and the uniformity of the thickness of the porous metal electrode can also be controlled. Therefore, the method of manufacturing a porous metal electrode according to the present invention can be used to manufacture both an anode and a cathode.Type: ApplicationFiled: December 29, 2008Publication date: August 5, 2010Applicant: DOOSAN HEAVY INDUSTRIES & CONSTRUCTION CO., LTD.Inventors: Ju Young Youn, Bo Hyun Ryu, Jang Yong Yoo, Mi Young Shin, Hwan Moon, Woon Yong Choi, Tae Won Lee, In Gab Chang, Kil Ho Moon
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Patent number: 7767359Abstract: A device for producing water on board an aircraft includes at least one high temperature fuel cell entirely or partially integrated into a combustion chamber arrangement of a gas turbine aircraft engine. The combination of at least one fuel cell and a gas turbine engine is adapted to operate exclusively with hydrogen and atmospheric oxygen, and is embodied in an aircraft propulsion engine and/or an auxiliary power unit used for producing compressed air for a cabin and a power supply of the aircraft. The at least one high temperature fuel cell is fed with pure hydrogen on an anode side and with air on a cathode side. The combustion chambers of the turbine engine are fed with an air-hydrogen mixture, whereby at least the hydrogen supply can be regulated or completely shut off.Type: GrantFiled: October 21, 2003Date of Patent: August 3, 2010Assignee: Airbus Deutschland GmbHInventors: Claus Hoffjann, Hans-Juergen Heinrich