Zirconium Oxide Patents (Class 429/496)
  • Patent number: 8617763
    Abstract: A solid oxide fuel cell (SOFC) includes a cathode electrode, a solid oxide electrolyte, and an anode electrode having a first portion and a second portion, such that the first portion is located between the electrolyte and the second portion. The anode electrode comprises a cermet comprising a nickel containing phase and a ceramic phase. The first portion of the anode electrode contains a lower porosity and a lower ratio of the nickel containing phase to the ceramic phase than the second portion of the anode electrode. The nickel containing phase in the second portion of the anode electrode comprises nickel and at least one other metal which has a lower electrocatalytic activity than nickel.
    Type: Grant
    Filed: August 5, 2010
    Date of Patent: December 31, 2013
    Assignee: Bloom Energy Corporation
    Inventors: Tad Armstrong, Emad El Batawi, Eric Petersen
  • Publication number: 20130337360
    Abstract: An SOFC component includes a first electrode, an electrolyte overlying the first electrode, and a second electrode overlying the electrolyte. The second electrode includes a bulk layer portion and a functional layer portion, the functional layer portion being an interfacial layer extending between the electrolyte and the bulk layer portion of the second electrode, wherein the bulk layer portion has a bimodal pore size distribution.
    Type: Application
    Filed: August 26, 2013
    Publication date: December 19, 2013
    Inventors: F. Michael Mahoney, John D. Pietras
  • Publication number: 20130316267
    Abstract: Provided is a solid electrolyte material which, while maintaining high oxygen ion conductivity, minimizes the decomposition of scandia caused by impurities such as silicon in the fuel gas, and improves intergranular strength in order to eliminate intergranular fracture caused by crystalline modification. The solid electrolyte material is a zirconia solid electrolyte material having scandia and a lanthanoid oxide and/or yttria dissolved therein, and has alumina further added thereto.
    Type: Application
    Filed: January 31, 2012
    Publication date: November 28, 2013
    Applicant: TOTO LTD.
    Inventors: Megumi Shimazu, Akira Ueno, Toshiya Abe, Motoyasu Miyao, Kenichi Hiwatashi
  • Patent number: 8592101
    Abstract: The invention relates to a method for manufacturing an electrolyte for an SOFC battery comprising a CVD (chemical vapor deposition) deposition step, on a substrate, of a stack of at least three layers of materials YSZ/X/YSZ, X being a different material than YSZ.
    Type: Grant
    Filed: August 24, 2009
    Date of Patent: November 26, 2013
    Assignee: Commissariat a l'Energie Atomique et aux Energies Alternatives
    Inventors: Sébastien Donet, Christelle Anglade, Bertrand Morel
  • Patent number: 8580456
    Abstract: A solid oxide fuel cell (SOFC) includes a cathode electrode, a solid oxide electrolyte, and an anode electrode. The electrolyte and/or electrode composition includes zirconia stabilized with (i) scandia, (ii) ceria, and (iii) at least one of yttria and ytterbia. The composition does not experience a degradation of ionic conductivity of greater than 15% after 4000 hrs at a temperature of 850° C.
    Type: Grant
    Filed: January 19, 2011
    Date of Patent: November 12, 2013
    Assignee: Bloom Energy Corporation
    Inventors: Tad Armstrong, Emad El Batawi, Martin Janousek, Manoj Pillai
  • Publication number: 20130280638
    Abstract: The present invention relates to a powder of molten grains of yttria-stabilised zirconia, said grains having the following chemical analysis, in weight percent on the basis of the oxides: ZrO2+HfO2: remainder up to 100%; 11.8%?Y2O3?18.6%; 0.07%?Al2O3?1.8%; TiO2?0.6%, provided that 0.5<Al2O3 0.3%?TiO2 if 0.6%<Al2O3; and other oxides: ?2.0%.
    Type: Application
    Filed: November 29, 2011
    Publication date: October 24, 2013
    Applicant: SAINT-GOBAIN CENTRE DE RECHERCHES ET D'ETUDES EUROPEEN
    Inventors: Caroline Levy, Samuel Marlin
  • Patent number: 8524419
    Abstract: An electrode support for fuel cells, the electrode support being made of a porous material having a Ni phase of Ni or NiO and an inorganic skeletal material phase, wherein an oxidation/reduction expansion-suppressing metal M of at least one selected from the group consisting of Fe, Co and Mn is solidly dissolved in the Ni phase or is biasedly distributed on the grain boundaries between the Ni phase and the inorganic skeletal material phase. The electrode support has its volume very little expanded or contracted even in an environment in which it is exposed to the reducing atmosphere and the oxidizing atmosphere alternately.
    Type: Grant
    Filed: August 2, 2005
    Date of Patent: September 3, 2013
    Assignee: Kyocera Corporation
    Inventors: Tetsuro Fujimoto, Shoji Yamashita
  • Publication number: 20130224628
    Abstract: A functional layer material for a solid oxide fuel cell (SOFC) including a ceria ceramic oxide and a metal oxide including a metal, except for zirconium, having a Vegard's slope X represented by Equation 1 and having an absolute value |X| of the Vegard's slope X, wherein 27×105?|X|?45×105: X=(0.0220ri+0.00015zi) ??(1), wherein ri is an ionic radius difference between the metal and Ce4+, and zi is a charge difference between the metal and Ce4+.
    Type: Application
    Filed: January 30, 2013
    Publication date: August 29, 2013
    Applicant: SAMSUNG ELECTRONICS CO., LTD.
    Inventor: Samsung Electronics Co., Ltd.
  • Patent number: 8512910
    Abstract: A solid oxide electrolyte including an oxygen ion conducting solid solution, wherein the solid solution is represented by Formula 1 below: Zr1-x-y-zMaxMbyMczO2-???Formula 1 wherein x is greater than 0 and less than about 0.3, y is greater than 0 and less than about 0.1, z is greater than 0 and less than about 0.1, ? is selected to make the solid solution ionically neutral, Ma, Mb, and Mc are each independently a metal selected from the group consisting of elements of Groups 3, Groups 5 through 13, and Group 14, and an ionic radius of each of Ma+3, Mb+3, and Mc+3 are different from each other.
    Type: Grant
    Filed: September 23, 2010
    Date of Patent: August 20, 2013
    Assignees: Samsung Electroncis Co., Ltd., Samsung SDI Co., Ltd., Industry-University Cooperation Foundation Hanyang University
    Inventors: Hee-jung Park, Sang-mock Lee, Chan Kwak, Soo-yeon Seo, Yong-ho Choa
  • Publication number: 20130196247
    Abstract: The present invention relates to a novel method for preparing a BZCYYb material to be used in a solid oxide fuel cell. In particular, the method comprises mixing particular nano-sized and micro-sized ingredients and the size selection provides greatly improved performance characteristics of the resulting material. In particular, barium carbonate powder, zirconium oxide powder having particle diameters in the nanometer range, and cerium oxide powder having particle diameter in the micrometer range are used together with ytterbium oxide powder, and yttrium oxide powder.
    Type: Application
    Filed: September 11, 2012
    Publication date: August 1, 2013
    Applicants: Georgia Tech Research Corporation, Phillips 66 Company
    Inventors: MingFei Liu, Meilin Liu, Ting He, Lei Yang
  • Patent number: 8498833
    Abstract: A method of inspecting a stack body of at least a porous layer and a dense layer comprises the first step of measuring the length of the stack body before the stack body is fired, the second step of measuring the length of the stack body after the stack body is fired, the third step of calculating a shrinkage rate of the stack body based on a first measured value from the first step and a second measured value from the second step, the fourth step of determining whether the calculated shrinkage rate of the stack body is acceptable or not based on the calculated shrinkage rate, the fifth step of calculating an S/N ratio of the stack body based on the first measured value and the second measured value, and the sixth step of determining whether the current-voltage characteristics of the stack body are acceptable or not based on the calculated S/N ratio.
    Type: Grant
    Filed: February 16, 2009
    Date of Patent: July 30, 2013
    Assignee: Honda Motor Co., Ltd.
    Inventors: Mari Maruyama, Ushio Harada, Hiroshi Ichikawa
  • Publication number: 20130189605
    Abstract: Provided are a ceria-based composition including ceria or metal-doped ceria, lithium salt, and optionally, bismuth oxide, ceria-based composite electrolyte powder, and a sintering method and sintered body using the same. Particularly, the lithium salt is present in an amount more than 0 wt % and equal to or less than 5 wt %, and bismuth oxide is present in an amount more than 0 wt % and equal to or less than 10 wt %. It is possible to reduce sintering temperature by adding a low-melting point and/or volatile compound to a ceria-based material. In this manner, it is possible to ensure a high composite sintering density, for example, of 95% or more even at a temperature, for example, of 1000° C. or lower, which is significantly lower than the conventional sintering temperature of 1500° C. in the case of a ceria-based material alone.
    Type: Application
    Filed: January 18, 2013
    Publication date: July 25, 2013
    Applicant: KOREA INSTITUTE OF SCIENCE AND TECHNOLOGY
    Inventor: Korea Institute of Science and Technology
  • Patent number: 8415071
    Abstract: An electrolyte membrane (11) includes: a filler (20); and a polymer electrolyte (22). A thickness of the electrolyte membrane (11) is 1 micrometer to 500 micrometer, a moisture content thereof is 10 mass % or more, and a ratio of a swelling ratio in a membrane surface direction (xy) thereof and a swelling ratio in a membrane thickness direction (z) thereof satisfies following Expression 1: where Lambda z is the swelling ratio in the membrane thickness direction (z), and Lambda xy is the swelling ratio in the membrane surface direction (xy). ? ? ? xy ? ? ? z < 0.3 [ Math .
    Type: Grant
    Filed: June 4, 2008
    Date of Patent: April 9, 2013
    Assignee: Nissan Motor Co., Ltd.
    Inventors: Shiro Tanaka, Hiroshi Tabata, Shuguo Zhang
  • Patent number: 8409323
    Abstract: A method and apparatus for controlling the electrical power applied to an electrically driven oxygen separation device having one or more composite membrane elements to separate oxygen from an oxygen containing feed. The composite membrane elements have a resistance increasing during the operation thereof that would act to reduce oxygen output if applied voltage were held constant. In order to increase the time interval for renewing the composite membrane elements, the electrical potential difference is controlled such that the electric current drawn by the elements remains at a substantially constant level by increasing the electrical potential difference as the resistance increases until a predetermined voltage level is reached. Once this level is obtained, the electrical potential difference is maintained at a constant level and the electric current being drawn and the oxygen output is allowed to decay to a predetermined low level after which the element or elements are replaced.
    Type: Grant
    Filed: April 7, 2011
    Date of Patent: April 2, 2013
    Assignee: Praxair Technology, Inc.
    Inventors: Michael J. Collins, David F. Suggs, Sadashiv M. Swami, Richard M. Kelly
  • Publication number: 20130034796
    Abstract: The electrolyte sheet for solid oxide fuel cell of the present invention has different surface roughnesses between the peripheral region and the region other than the peripheral region at least on one side. The surface roughness Ra(b) in the peripheral region is at least 0.05 ?m and less than 0.3 ?m. The surface roughness Ra(i) in the region other than the peripheral region is at least 0.2 ?m and at most 1.2 ?m. And, the ratio of Ra(i) to Ra(b) (Ra(i)/Ra(b)) is more than 1 and at most 4. Here, the surface roughness Ra(b) and the surface roughness Ra(i) are arithmetic mean roughness values and determined by an optical and laser-based non-contact three-dimensional profile measuring device in accordance with a German standard ‘DIN-4768’.
    Type: Application
    Filed: March 29, 2011
    Publication date: February 7, 2013
    Applicant: NIPPON SHOUKUBAI CO., LTD.
    Inventor: Kazuo Hata
  • Publication number: 20130022895
    Abstract: An ion-conducting membrane for fuel cell applications a first layer including a first ion-conducting polymer and nanofibers dispersed therein. The first layer includes a first side and a second side. A second layer is disposed over the first side of the first layer and includes a second ion-conducting polymer without nanofibers.
    Type: Application
    Filed: July 20, 2011
    Publication date: January 24, 2013
    Applicant: GM GLOBAL TECHNOLOGY OPERATIONS LLC
    Inventors: Ruichun Jiang, Timothy J. Fuller, Craig S. Gittleman
  • Patent number: 8357474
    Abstract: A solid oxide fuel cell electrolyte is fabricated by combining an yttria-stabilized zirconia powder with ?-Al2O3 having a d50 particle size in a range of between about 10 nm and about 200 nm and Mn2O3 to form an electrolyte precursor composition, and then sintering the electrolyte precursor composition to thereby form the electrolyte. The ?-Al2O3 and Mn2O3 can be present in the electrolyte precursor composition in an amount in a range of between about 0.25 mol % and about 5 mol %. The electrolyte can be a component of a solid oxide fuel cell of the invention.
    Type: Grant
    Filed: December 16, 2009
    Date of Patent: January 22, 2013
    Assignee: Saint-Gobain Ceramics & Plastics, Inc.
    Inventors: Yeshwanth Narendar, Guangyong Lin, Aravind Mohanram
  • Patent number: 8349511
    Abstract: A fuel cell is provided that includes an anode, a cathode, a solid electrolyte layer, a barrier layer, and an intermediate layer. The solid electrolyte layer includes zirconium and is provided between the anode and the cathode. The barrier layer includes cerium and is provided between the solid electrolyte layer and the cathode. The intermediate layer includes zirconium and cerium, and has a first surface facing the solid electrolyte layer, a second surface facing the barrier layer, and pores. The pore ratio of the intermediate layer is higher than the pore ratio of the barrier layer.
    Type: Grant
    Filed: June 14, 2011
    Date of Patent: January 8, 2013
    Assignee: NGK Insulators, Ltd.
    Inventors: Ayano Kobayashi, Shinji Fujisaki, Makoto Ohmori
  • Publication number: 20120328971
    Abstract: Provided are a solid electrolyte membrane useful in achieving strong electromotive force in a fuel battery, and a fuel battery cell produced with this membrane. The solid electrolyte membrane includes a substrate made of a sheet material and having a plurality of openings penetrating the substrate in its thickness direction, and a solid electrolyte layer provided on at least one of the faces of the substrate. The fuel battery cell includes a solid electrolyte membrane having the solid electrolyte layer on one of the faces of the substrate, and a catalyst layer containing a precious metal and provided on the other of the faces of the substrate, with the solid electrolyte layer and the catalyst layer being in contact with each other in the openings of the substrate.
    Type: Application
    Filed: March 1, 2011
    Publication date: December 27, 2012
    Applicants: NATIONAL UNIV. CORPORATION HOKKAIDO UNIV., SANTOKU CORPORATION
    Inventors: Motofumi Matsuda, Tadatoshi Murota, Tatsuya Takeguchi, Wataru Ueda
  • Patent number: 8334079
    Abstract: A solid oxide fuel cell has anode, cathode and electrolyte layers each formed essentially of a multi-oxide ceramic material and having a far-from-equilibrium, metastable structure selected from the group consisting of nanocrystalline, nanocomposite and amorphous. The electrolyte layer has a matrix of the ceramic material, and is impervious and serves as a fast oxygen ion conductor. The electrolyte layer has a matrix of the ceramic material and a dopant dispersed therein in an amount substantially greater than its equilibrium solubility in the ceramic matrix. The anode layer includes a continuous surface area metallic phase in which electron conduction is provided by the metallic phase and the multi-oxide ceramic matrix provides ionic conduction.
    Type: Grant
    Filed: April 30, 2004
    Date of Patent: December 18, 2012
    Assignee: NanoCell Systems, Inc.
    Inventors: Peter R. Strutt, Bernard H. Kear
  • Publication number: 20120308915
    Abstract: A cathode material for a fuel cell, the cathode material including a first metal oxide having a perovskite structure; and a second metal oxide having a spinel structure.
    Type: Application
    Filed: May 22, 2012
    Publication date: December 6, 2012
    Applicants: SAMSUNG ELECTRO-MECHANICS CO., LTD., SAMSUNG ELECTRONICS CO., LTD.
    Inventors: Hee-jung PARK, Soo-yeon SEO, Kyoung-seok MOON, Huangang SHI, Dengjie CHEN, Zongping SHAO
  • Patent number: 8323463
    Abstract: A composite oxygen transport membrane having a dense layer, a porous support layer and an intermediate porous layer located between the dense layer and the porous support layer. Both the dense layer and the intermediate porous layer are formed from an ionic conductive material to conduct oxygen ions and an electrically conductive material to conduct electrons. The porous support layer has a high permeability, high porosity, and a high average pore diameter and the intermediate porous layer has a lower permeability and lower pore diameter than the porous support layer. Catalyst particles selected to promote oxidation of a combustible substance are located in the intermediate porous layer and in the porous support adjacent to the intermediate porous layer. The catalyst particles can be formed by wicking a solution of catalyst precursors through the porous support toward the intermediate porous layer.
    Type: Grant
    Filed: December 15, 2010
    Date of Patent: December 4, 2012
    Assignee: Praxair Technology, Inc.
    Inventors: Gervase Maxwell Christie, Jamie Robyn Wilson, Bart Antonie van Hassel
  • Publication number: 20120276468
    Abstract: The invention provides a composition having the formula (I): xXO2.yY2O5, (wherein: 0.5<x<0.7; 0.3<y<0.5; X comprises one or more of silicon, titanium, germanium and zirconium; and Y comprises one or more of phosphorus, vanadium arsenic and antimony), or a hydrate thereof, in which the composition comprises more than 50 wt % or more of crystalline material.
    Type: Application
    Filed: November 29, 2010
    Publication date: November 1, 2012
    Applicant: University Court of the University of St Andrews
    Inventors: Pierrot Sassou Attidekou, John Thomas Sirr Irvine
  • Patent number: 8298721
    Abstract: A reversible solid oxide fuel cell obtainable by a method comprising the steps of: providing a metallic support layer; forming a cathode precursor layer on the metallic support layer; forming an electrolyte layer on the cathode precursor layer; sintering the obtained multilayer structure; in any order conducting the steps of: forming a cathode layer by impregnating the cathode precursor layer, and forming an anode layer on the electrolyte layer; characterised in that the method further comprises prior to forming said cathode layer, impregnating a precursor solution or suspension of a barrier material into the metallic support layer and the cathode precursor layer and subsequently conducting a heat treatment.
    Type: Grant
    Filed: August 27, 2008
    Date of Patent: October 30, 2012
    Assignee: Technical University of Denmark
    Inventor: Peter Halvor Larsen
  • Patent number: 8298716
    Abstract: In a process of manufacturing a membrane electrode assembly, seal-material flow holes (62a, 62b) in the form of through-holes are formed, separately from manifold holes (16a-16f), in the membrane electrode assembly prior to injection molding. When the membrane electrode assembly is placed in a mold for injection molding, the seal-material flow hole (62a) is located in a cavity (44a). When a seal material is supplied from a supply port (42) formed at a location where the manifold hole (16a) is formed, the seal material that flows toward the upper die (40a) passes the seal-material flow hole (62a) in the cavity (44a), and then flows toward the lower die (40b), so as to reduce the unevenness between the amounts of supply of the seal material to the upper die (40a) and the lower die (40b).
    Type: Grant
    Filed: March 13, 2007
    Date of Patent: October 30, 2012
    Assignee: Toyota Jidosha Kabushiki Kaisha
    Inventor: Tomoharu Sasaoka
  • Patent number: 8252477
    Abstract: A direct-flame fuel cell according to the invention has a cell in which a solid electrolyte 1 is sandwiched between an anode 2 and a cathode 3. The anode 2 contains one or more kinds of alkaline metal compounds or alkaline earth metal compounds which are effective in suppressing soot generation due to exposure to a flame. Where the anode 2 includes two or more layers 2a and 2b, the one or more kinds of alkaline metal compounds or alkaline earth metal compounds are contained in the outermost layer 2b.
    Type: Grant
    Filed: November 30, 2007
    Date of Patent: August 28, 2012
    Assignee: Shinko Electric Industries Co., Ltd.
    Inventors: Fumimasa Katagiri, Shigeaki Suganuma, Jun Yoshiike, Yasue Tokutake
  • Publication number: 20120141917
    Abstract: A proton-conducting solid oxide electrolyte membrane includes a nanoporous layer including a plurality of nanopores that penetrate from one surface to the other, and at least one proton conducting layer that fills the plurality of nanopores to have an interface in a direction perpendicular to either surface of the nanoporous layer.
    Type: Application
    Filed: June 24, 2011
    Publication date: June 7, 2012
    Applicants: The Board of Trustees of the Leland Stanford Jr. University, Samsung Electronics Co., Ltd.
    Inventors: Sang-kyun Kang, Turgut M. Gür, Friedrich B. Prinz, Joon-hyung Shim
  • Patent number: 8182959
    Abstract: The present teachings relate to an electrochemical cell having a closed Fermat spiral shape. The electrochemical cell comprises an anode, a cathode, an electrolyte, a fuel channel, an oxidant channel, and optionally a reforming layer. The electrochemical cell can be made through extrusion, gel-casting, or 3-D printing. The electrochemical cell can be a solid oxide fuel cell.
    Type: Grant
    Filed: November 6, 2007
    Date of Patent: May 22, 2012
    Assignee: CP SOFC IP, LLC
    Inventors: Yanhai Du, Caine Finnerty
  • Patent number: 8163438
    Abstract: A composite electrolyte membrane uses a metal-oxide hydrate which has a number of hydration water molecules of 2.7 or more and 10 or less and/or which is in the form of particles having a particle diameter of 1 nm or more and 10 nm or less. The composite electrolyte membrane exhibits its expected original performance, has both a high proton conductivity and a low methanol permeability, and provides a high-output membrane electrolyte assembly for a fuel cell.
    Type: Grant
    Filed: May 30, 2008
    Date of Patent: April 24, 2012
    Assignee: Hitachi, Ltd.
    Inventors: Takayuki Hirashige, Makoto Morishima, Mikio Kishimoto, Yuko Sawaki, Kazutaka Matsuo
  • Publication number: 20120094214
    Abstract: The present invention relates to a method for manufacturing a metal-oxide-based ceramic, including, in order, the step of inserting, into a flash sintering device, a nanocrystalline powder comprising crystallites and crystallite agglomerates of a ceramic of formula, Zr1-xMxO2, where M is chosen from yttrium, scandium and cerium, or Ce1-xM?xO2, where M? is chosen from gadolinium, scandium, samarium and yttrium, where x lies between 0 and 0.2, the powder having an average crystallite size of between 5 and 50 nm, an average crystallite agglomerate size of between 0.5 and 20 ?m, and a specific surface area of between 20 and 100 m2/g. The invention further includes the step of flash sintering the powder by applying a pressure of between 50 and 150 MPa, at a temperature of between 850° C. and 1400° C., for a time of between 5 and 30 minutes.
    Type: Application
    Filed: June 16, 2010
    Publication date: April 19, 2012
    Applicants: Universite Paul Sabatier Toulouse III, Electricite De France
    Inventors: Mohsine Zahid, Mathilde Rieu, Claude Estournes, Pascal Lenormand, Florence Ansart
  • Patent number: 8129069
    Abstract: A fuel cell component is made with a composite including a proton conducting polymer, a water insoluble proton conducting inorganic material, and a heteropolyacid immobilized by chemically bonding to the inorganic material. In another embodiment, the fuel cell component is made with a composite including a non-proton conducting polymer, a water insoluble inorganic material, and a heteropolyacid immobilized by chemically bonding to the inorganic material, the heteropolyacid causing the composite to show proton conductivity. In a further embodiment, the fuel cell component is made with a composite comprising a proton conducting polymer, a water insoluble proton conducting inorganic material, and a heteropolyacid immobilized by chemically bonding to the inorganic material, the composite having substantially identical structure of the unmodified heteropolyacid.
    Type: Grant
    Filed: September 29, 2006
    Date of Patent: March 6, 2012
    Assignee: Battelle Memorial Institute
    Inventors: Ramanathan S. Lalgudi, Jay R. Sayre, Bhima R. Vijayendran
  • Publication number: 20120003565
    Abstract: The present invention relates to a solid oxide fuel cell having a gradient structure in which pore size becomes gradually smaller from a porous electrode to an electrolyte thin film in order to form a dense electrolyte thin film of less than about 2 microns and preferably less than 1 micron on the porous electrode.
    Type: Application
    Filed: March 16, 2010
    Publication date: January 5, 2012
    Applicant: KOREA INSTITUTE OF SCIENCE AND TECHNOLOGY
    Inventors: Ji-Won Son, Ho-Sung Noh, Hae-Weon Lee, Jong Ho Lee, Hae-Ryoung Kim, Jong Cheol Kim
  • Publication number: 20110305972
    Abstract: A fuel cell is provided that includes an anode, a cathode, a solid electrolyte layer, a barrier layer, and an intermediate layer. The solid electrolyte layer includes zirconium and is provided between the anode and the cathode. The barrier layer includes cerium and is provided between the solid electrolyte layer and the cathode. The intermediate layer includes zirconium and cerium, and has a first surface facing the solid electrolyte layer, a second surface facing the barrier layer, and pores. The pore ratio of the intermediate layer is higher than the pore ratio of the barrier layer.
    Type: Application
    Filed: June 14, 2011
    Publication date: December 15, 2011
    Applicant: NGK Insulators, Ltd.
    Inventors: Ayano KOBAYASHI, Shinji FUJISAKI, Makoto OHMORI
  • Publication number: 20110305973
    Abstract: A fuel cell is provided that includes an anode, a cathode, a solid electrolyte layer, a barrier layer, and an buffer layer. The solid electrolyte layer includes zirconium and is provided between the anode and the cathode. The barrier layer includes cerium and is provided between the solid electrolyte layer and the cathode. The barrier layer has pores. The buffer layer includes zirconium and cerium and is provided between the barrier layer and the solid electrolyte layer. The barrier layer has a first barrier layer provided near to the buffer layer with a first pore ratio and a second barrier layer provided between the first barrier layer and the cathode with a second pore ratio. The first pore ratio of the first barrier layer is larger than the second pore ratio of the second barrier layer.
    Type: Application
    Filed: June 14, 2011
    Publication date: December 15, 2011
    Applicant: NGK Insulators, Ltd.
    Inventors: Ayano Kobayashi, Shinji Fujisaki, Makoto Ohmori
  • Patent number: 8067129
    Abstract: A solid oxide fuel cell (SOFC) includes a cathode electrode, an anode electrode, and a solid oxide electrolyte located between the anode electrode and the cathode electrode. The cathode electrode is a porous ceramic layer infiltrated with a cathode catalyst material, and the anode electrode is a porous ceramic layer infiltrated with an anode catalyst material, and the electrolyte is a ceramic layer having a lower porosity than the anode and the cathode electrodes. A ceramic reinforcing region may be located adjacent to the riser opening in the electrolyte.
    Type: Grant
    Filed: November 12, 2008
    Date of Patent: November 29, 2011
    Assignee: Bloom Energy Corporation
    Inventor: Stephen Couse
  • Publication number: 20110262839
    Abstract: A proton conducting electrolyte membrane comprising a ceramic electrolyte layer including an inorganic proton conductor and a ceramic protective layer formed on at least one surface of the ceramic electrolyte layer and having proton conductivity; a membrane electrode assembly including the proton conducting electrolyte membrane; and a proton conducting ceramic fuel cell including the membrane electrode assembly. In the proton conducting electrolyte membrane, the ceramic protective layer may have an improved chemical bond with the ceramic electrolyte layer compared with a Pd metal protective layer, such that interlayer delamination may be lessened. Also, compared with a Pd metal protective layer, the ceramic protective layer is more appropriate for ceramic electrolytes such as BYZ and BYC that transmit protons or simultaneously transmit protons and oxygen ions used in a fuel cell operating at a temperature range of about 200 to about 500° C., for example, about 250 to about 500° C.
    Type: Application
    Filed: April 22, 2011
    Publication date: October 27, 2011
    Applicants: The Board of Trustees of The Leland Stanford JR. University, Samsung Electronics Co., Ltd.
    Inventors: Sang-kyun Kang, Joong-Sun Park, Turgut M. Gür, Young-beom Kim, Friedrich B. Prinz, Joon-hyung Shim
  • Patent number: 8043764
    Abstract: A stack structure includes plate-like electrochemical cells of ceramic, each having a pair of main surfaces and a side surface, and plate-like retainer pieces. The cell includes a first electrode in contact with first gas, a solid electrolyte, and a second electrode in contact with second gas. The first electrode has a gas flow channel formed therein and adapted to allow flow of the first gas. The cell has gas inflow and outflow ports. The retainer piece includes a body portion having a through-hole formed therein, and a pair of protrusions protruding from the body portion. The retainer piece has a communication hole formed therein and adapted to establish communication between the through-hole and a space formed between the protrusions. The cell is held by the paired protrusions, thereby establishing communication between the gas inflow or outflow port of the cell and the communication hole of the retainer piece.
    Type: Grant
    Filed: January 26, 2010
    Date of Patent: October 25, 2011
    Assignee: NGK Insulators, Ltd.
    Inventors: Toshiaki Kuno, Takenori Ichigi, Keiichi Kanno, Makoto Ohmori, Masayuki Shinkai, Genta Terazawa
  • Patent number: 8039175
    Abstract: The present invention provides a method for producing a multilayer structure, comprising the steps of: providing a composition comprising a Fe—Cr alloy powder and at least one of the oxides of Fe, Cr, Ni, Co, Zn, Cu; forming a first layer of said composition; forming at least one additional layer on one side of said first layer; heat treating said layers in an oxygen-containing atmosphere; and sintering in a reducing atmosphere so as to provide a final alloy, wherein the amount of Fe in the final alloy of the first layer after the sintering step is in the range of from about 50-90% by weight, based on the total weight of the final alloy.
    Type: Grant
    Filed: January 12, 2006
    Date of Patent: October 18, 2011
    Assignee: Technical University of Denmark
    Inventors: Søren Linderoth, Peter Halvor Larsen
  • Publication number: 20110236795
    Abstract: A method of preparing a metal-doped oxide, the method including: preparing a precursor solution including a zirconium precursor or cerium precursor, a dopant metal precursor, a solvent, and a chloride salt; and heat-treating the precursor solution to prepare the metal-doped oxide.
    Type: Application
    Filed: January 20, 2011
    Publication date: September 29, 2011
    Applicants: SAMSUNG ELECTRONICS CO., LTD., SAMSUNG SDI CO., LTD.
    Inventors: Soo-yeon SEO, Hee-jung PARK, Chan KWAK, Sang-mock LEE, Dong-hee YEON
  • Patent number: 8021799
    Abstract: The embodiments generally relate to a high performance ceramic anode which will increase flexibility in the types of fuels that may be used with the anode. The embodiments further relate to high-performance, direct-oxidation SOFC utilizing the anodes, providing improved electro-catalytic activity and redox stability. The SOFCs are capable of use with strategic fuels and other hydrocarbon fuels. Also provided are methods of making the high-performance anodes and solid oxide fuel cells comprising the anodes exhibiting improved electronic conductivity and electrochemical activity.
    Type: Grant
    Filed: July 12, 2007
    Date of Patent: September 20, 2011
    Assignee: The Trustees Of The University Of Pennsylvania
    Inventors: Raymond J. Gorte, John M. Vohs, Michael D. Gross
  • Publication number: 20110195343
    Abstract: A solid oxide fuel cell (SOFC) or SOFC sub-component comprising a YSZ solid oxide electrolyte layer (10), a LSCF cathode layer (14) and a mixed phase layer (18) comprising at least zirconia and ceria between the electrolyte layer and the cathode layer, with the cathode layer in direct contact with the mixed phase layer, that is with no ceria, other than in the mixed phase layer, between the cathode layer and the electrolyte layer. One method of forming the SOFC or sub-component comprises applying a layer of ceria on the electrolyte layer (10), heating the electrolyte and ceria layers to form the mixed phase layer (18), and removing excess ceria from the surface of the mixed phase layer before applying the cathode layer (14).
    Type: Application
    Filed: October 9, 2009
    Publication date: August 11, 2011
    Applicant: CERAMIC FUEL CELLS LIMITED
    Inventors: Merrill Ruth Watts, Sudath Dharma Kumara Amarasinghe, Jonathan Gerald Love
  • Patent number: 7993499
    Abstract: The invention relates to membrane-electrode assemblies for the electrolysis of water (electrolysis MEAs), which contain an ion-conducting membrane having a front and rear side; a first catalyst layer on the front side; a first gas diffusion layer on the front side; a second catalyst layer on the rear side, and a second gas diffusion layer on the rear side. The first gas diffusion layer has smaller planar dimensions than the ion-conducting membrane, whereas the second gas diffusion layer has essentially the same planar dimensions as the ion-conducting membrane (“semi-coextensive design”). The MEAs also comprise an unsupported free membrane surface that yields improved adhesion properties of the sealing material. The invention also relates to a method for producing the MEA products. Pressure-resistant, gastight and cost-effective membrane-electrode assemblies are obtained, that are used in PEM water electrolyzers, regenerative fuel cells or in other electrochemical devices.
    Type: Grant
    Filed: July 14, 2004
    Date of Patent: August 9, 2011
    Assignee: Umicore AG & Co. KG
    Inventors: Ralf Zuber, Klaus Schaack, Sandra Wittpahl, Holger Dziallas, Peter Seipel, Pia Braun, Lutz Rohland
  • Publication number: 20110183233
    Abstract: A solid oxide fuel cell (SOFC) includes a cathode electrode, a solid oxide electrolyte, and an anode electrode. The electrolyte and/or electrode composition includes zirconia stabilized with (i) scandia, (ii) ceria, and (iii) at least one of yttria and ytterbia. The composition does not experience a degradation of ionic conductivity of greater than 15% after 4000 hrs at a temperature of 850° C.
    Type: Application
    Filed: January 19, 2011
    Publication date: July 28, 2011
    Applicant: Bloom Energy Corporation
    Inventors: Tad Armstrong, Emad El Batawi, Martin Janousek, Manoj Pillai
  • Publication number: 20110171560
    Abstract: The present invention provides a fuel cell in which electricity is generated and a paraffin is converted to an olefin. Between the anode and cathode compartment of the fuel cell is a ceramic membrane of the formula BaCe0.85-eAe LfY0.05-0.25 O(3-?) wherein A is selected from the group consisting of Hf and Zr and mixtures thereof, e is from 0.1 to 0.5, L is a lanthanide and f is from 0 to 0.25 and ? is the oxygen deficiency in the ceramic.
    Type: Application
    Filed: December 15, 2010
    Publication date: July 14, 2011
    Inventors: Jingli Luo, Karl Chuang, Alan Rodney Sanger
  • Patent number: 7927757
    Abstract: This invention concerns a high temperature fuel cell with mixed anionic and protonic conduction having a protonic conduction reforming membrane directly coupled to a solid oxide fuel cell with conduction by oxygen ions, enabling use of a gradually reforming anode generating carbon deposits to be avoided. The reverse operation of the present invention outside the reforming stage forms a high water temperature electrolyser to produce hydrogen efficiently without having to separate it from water as is the case with current systems.
    Type: Grant
    Filed: March 17, 2006
    Date of Patent: April 19, 2011
    Assignee: Armines
    Inventor: Alain Thorel
  • Publication number: 20110086290
    Abstract: An inorganic proton conductor and an electrochemical device using the inorganic proton conductor, the inorganic proton conductor including a tetravalent metallic element and an alkali metal.
    Type: Application
    Filed: July 12, 2010
    Publication date: April 14, 2011
    Applicant: Samsung Electronics Co. Ltd.
    Inventors: Tae-young KIM, Pil-won Heo, Sang-kyun Kang
  • Patent number: 7901837
    Abstract: The process described herein provides a simple and cost effective method for making crack free, high density thin ceramic film. The steps involve depositing a layer of a ceramic material on a porous or dense substrate. The deposited layer is compacted and then the resultant laminate is sintered to achieve a higher density than would have been possible without the pre-firing compaction step.
    Type: Grant
    Filed: December 5, 2006
    Date of Patent: March 8, 2011
    Assignee: The Regents of the University of California
    Inventors: Craig P. Jacobson, Steven J. Visco, Lutgard C. De Jonghe
  • Publication number: 20110027694
    Abstract: A solid oxide fuel cell with an electrolyte membrane having one or more layers with interfaces perpendicular to the surfaces of the membrane is provided. The layers can be deposited on vertical walls of holes in a nanoporous membrane until the layers fully fill the holes, thereby forming superlattices in the holes. The final shape of the superlattices in this example will be concentric, laminating layers as seen in a top view looking down on the membrane. According to one aspect, conventional electrodes can be deposited on both sides of the membrane for current collection and surface charge transfer reactions.
    Type: Application
    Filed: July 26, 2010
    Publication date: February 3, 2011
    Inventors: Cheng-Chieh Chao, Friedrich B. Prinz, Turgut M. Gür, Joon Hyung Shim
  • Patent number: 7879474
    Abstract: An interconnect structure is disclosed for use in solid oxide electrolytic devices that use chrome-containing components, such as solid oxide fuel cells and solid oxide oxygen-generators. The invention provides a reliable and durable interconnect for both structural and electrical components of such devices. In general, the interconnect structure relies on a dual-layer, high-temperature seal which provides an effective diffusion barrier for both chrome and oxygen. As a result of the described interconnect, corrosion or loss in electrical conductivity in such solid oxide electrolytic devices is avoided. Also, a novel structure for such solid oxide electrolytic devices is disclosed, which provides an economical and high-integrity structure that utilizes the disclosed interconnect structure. A result of the present invention is that thin film solid oxide fuel cells and solid oxide oxygen generators may be fabricated using only metal alloys as bulk components.
    Type: Grant
    Filed: October 29, 2007
    Date of Patent: February 1, 2011
    Inventor: Donald Bennett Hilliard
  • Patent number: 7862938
    Abstract: A fuel cell and heat engine hybrid system using a high-temperature fuel cell having an anode compartment adapted to receive fuel from a fuel supply path and to output anode exhaust gas and a cathode compartment adapted to receive oxidant gas and to output cathode exhaust gas. A heat engine assembly is adapted to receive oxidant gas and a further gas comprising one of the anode exhaust gas and a gas derived from the anode exhaust gas and to cause oxidation of the further gas and generate output power, the heat engine also generating heat engine exhaust including oxidant gas. The heat engine exhaust is then used to provide oxidant gas to the cathode compartment of the fuel cell.
    Type: Grant
    Filed: April 10, 2007
    Date of Patent: January 4, 2011
    Assignee: FuelCell Energy, Inc.
    Inventor: Hossein Ghezel-Ayagh