Tubular-shaped Solid Electrolyte Patents (Class 429/497)
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Patent number: 11799119Abstract: A manifold includes a first manifold main body and a second manifold main body. The first manifold main body includes a first gas chamber configured to communicate with a first gas channel. The second manifold main body includes a second gas chamber configured to communicate with a second gas channel. The second manifold main body is disposed in the first manifold main body.Type: GrantFiled: October 27, 2020Date of Patent: October 24, 2023Assignee: NGK INSULATORS, LTD.Inventors: Noriyuki Ogasawara, Yuki Tanaka, Masayuki Shinkai, Hirofumi Kan, Makoto Ohmori
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Patent number: 11682777Abstract: A multifunctional manifold for use with electrochemical devices having a spiral cross-section, such as spiral solid-oxide fuel cells, includes an interface that is configured to be placed in operative communication with such devices. The interface includes a fuel interface section and an oxidant interface section that are each configured as spirals. The spiral interface sections also include channels that are configured to be placed in operative communication with corresponding spiral channels of the electrochemical device to deliver operating gases, such as fuel gas and oxidant gas, thereto. In addition to delivering operating gases to the fuel cells, the multifunctional manifold is also configured to act as an electrical current collector and a heat exchanger.Type: GrantFiled: December 12, 2017Date of Patent: June 20, 2023Assignees: Kent State University, YANHAI POWER TECHNOLOGY, LLCInventors: Yanhai Du, Aliia Mubarak Moh Maar
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Patent number: 11264633Abstract: A manifold includes first and second manifold main bodies. The first manifold main body includes a gas supply chamber that is connected to a first gas channel and the second manifold main body includes a gas collection chamber that is connected to a second gas channel. The first manifold main body includes a top plate, a first bottom plate, and a first side plate. The top plate includes a first through hole for connecting the first gas channel and the gas supply chamber. The second manifold main body includes the top plate, a second bottom plate, and a second side plate. The top plate also includes a second through hole for connecting the second gas channel and the gas collection chamber. The first bottom plate and the second bottom plate are constituted by members that are separate from each other.Type: GrantFiled: September 3, 2019Date of Patent: March 1, 2022Assignee: NGK INSULATORS, LTD.Inventors: Noriyuki Ogasawara, Yuki Tanaka, Masayuki Shinkai, Hirofumi Kan, Makoto Ohmori
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Patent number: 10944115Abstract: A cathode layer and a membrane electrode assembly of a solid oxide fuel cell are provided. The cathode layer consists of a plurality of perovskite crystal films, and the average change rate of linear thermal expansion coefficients of these perovskite crystal films is about 5% to 40% along the thickness direction. The membrane electrode assembly includes the above-mentioned cathode layer, and the linear thermal expansion coefficients of these perovskite crystal films are reduced towards the solid electrolyte layer of the membrane electrode assembly.Type: GrantFiled: January 24, 2019Date of Patent: March 9, 2021Assignee: Industrial Technology Research InstituteInventors: Tzu-Chi Chou, Kuo-Chuang Chiu, Tzu-Yu Liu, Yung-Hsiang Juan, Ying-Hao Chu
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Patent number: 9017900Abstract: A method, according to one embodiment, includes acquiring a structure having an ionically-conductive, electrically-resistive electrolyte/separator layer covering an inner or outer surface of a carbon-containing electrically-conductive hollow fiber and a catalyst along one side thereof, adding an anode that extends along at least part of a length of the structure, and adding a cathode that extends along at least part of the length of the structure, the cathode being on an opposite side of the hollow fiber as the anode.Type: GrantFiled: June 2, 2014Date of Patent: April 28, 2015Assignee: Lawrence Livermore National Security, LLCInventors: Kevin C. Langry, Joseph C. Farmer
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Patent number: 8993195Abstract: A fuel cell includes a unit cell, a cell fixing member and a welding portion. The unit cell includes a first electrode layer, an electrolyte layer surrounding the first electrode layer, a second electrode layer surrounding the electrolyte layer while exposing an end portion of the electrolyte layer, and a coating layer formed by coating a mixture of ceramic and metal on the exposed end portion of the electrolyte layer. The cell fixing member includes a flow tube inserted into the unit cell, a fixing tube provided to an outside of the flow tube, and a connecting portion connecting the fixing tube and the flow tube to each other and to restrict an insertion depth of the electrolyte layer and the first electrode layer. The welding portion fixes and seals the coating layer and the inner circumferential surface of the fixing tube to each other.Type: GrantFiled: October 20, 2010Date of Patent: March 31, 2015Assignee: Samsung SDI Co., Ltd.Inventors: Jun-Won Suh, Ho-Jin Kweon
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Patent number: 8962202Abstract: The present invention provides a large-scale solid oxide fuel cell stack and a method of manufacturing the stack. In the present invention, a segmented cell tube (103a, 103b) is formed in such a way that unit cells connected to each other are formed on a cylindrical or flat tubular porous support (101). A reformer tube (102) is configured such that reforming catalyst (3) is provided in a support (101). The cell tube and the reformer tube are disposed at positions spaced apart from each other such that an air passage is formed on the outer surface of the reformer tube. A cell module (105) is formed by arranging the tubes such that a fuel gas flow passage is formed between the tubes. The solid oxide fuel cell stack is formed by integrating cell modules with each other.Type: GrantFiled: June 9, 2011Date of Patent: February 24, 2015Assignee: Postech Academy-Industry FoundationInventor: Jong Shik Chung
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Patent number: 8962209Abstract: Fuel cell devices and systems are provided. In certain embodiments, the devices include a ceramic support structure having a length, a width, and a thickness. A reaction zone positioned along a portion of the length is configured to be heated to an operating reaction temperature, and has at least one active layer therein comprising an electrolyte separating first and second opposing electrodes, and active first and second gas passages adjacent the respective first and second electrodes. At least one cold zone positioned from the first end along another portion of the length is configured to remain below the operating reaction temperature. An artery flow passage extends from the first end along the length through the cold zone and into the reaction zone and is fluidicly coupled to the active first gas passage, which extends from the artery flow passage toward at least one side. The thickness of the artery flow passage is greater than the thickness of the active first gas passage.Type: GrantFiled: December 26, 2012Date of Patent: February 24, 2015Inventors: Alan Devoe, Lambert Devoe
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Patent number: 8936888Abstract: A solid oxide fuel cell system includes a first fuel cell tube, a flame tip protection member and a current conduction member. The first fuel cell tube has a flame end. The flame end has exit opening. The fuel cell tube is configured to deliver combustible gas to the flame tip region generating a flame kernel. The flame protection member is configured to inhibit at least one of mass transfer and heat transfer between the fuel cell tube and the flame tip region. The current conduction member is disposed through the exit opening of the flame end of the first fuel cell tube.Type: GrantFiled: February 1, 2010Date of Patent: January 20, 2015Assignee: Adaptive Materials, Inc.Inventors: Aaron T. Crumm, Timothy LaBreche
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Patent number: 8927162Abstract: The present invention comprises fuel cells 84 disposed within a fuel cell module 2, a reformer 20, a reformer temperature sensor 148 for detecting a reforming state temperature, and a control section 110 for controlling the operation of the fuel cell module. The control section prohibits the normal startup POX and executes a restart control different from the normal startup POX when the reforming state temperature is at least in a high temperature region within the POX temperature band in a state in which the operation of the solid oxide fuel cell module is stopped.Type: GrantFiled: March 31, 2010Date of Patent: January 6, 2015Assignee: Toto Ltd.Inventors: Yousuke Akagi, Naoki Watanabe, Shuichiro Saigan, Nobuo Isaka
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Patent number: 8906561Abstract: A bio-fuel cell includes at least one bio-fuel cell element. The bio-fuel cell element includes an anode, a cathode, an anode container filled with the bio-fuel, a proton exchange membrane sandwiched between the anode and the cathode, and a guide plate. The cathode includes a catalyst layer. The catalyst layer includes a number of tube carriers having electron conductibility, a number of catalyst particles uniformly adsorbed on inner wall of each of the tube carriers, and proton conductor filled in each of the tube carriers. The tube carriers cooperatively define a number of reaction gas passages. One end of each of the tube carriers connects with the proton exchange membrane. The guide plate is disposed on a surface of the cathode away from the proton exchange membrane.Type: GrantFiled: December 29, 2011Date of Patent: December 9, 2014Assignees: Tsinghua University, Hon Hai Precision Industry Co., Ltd.Inventors: Zhi-Xiang Liu, Cheng Wang, Zong-Qiang Mao
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Patent number: 8865367Abstract: Provided is a gas decomposition component that employs an electrochemical reaction and can have high treatment performance, in particular, an ammonia decomposition component. The gas decomposition component includes a MEA 7 including a solid electrolyte 1 and an anode 2 and a cathode 5 that are disposed so as to sandwich the solid electrolyte; Celmets 11s electrically connected to the anode 2; a heater 41 that heats the MEA; and an inlet 17 through which a gaseous fluid containing a gas is introduced into the MEA, an outlet 19 through which the gaseous fluid having passed through the MEA is discharged, and a passage P extending between the inlet and the outlet, wherein the Celmets 11s are discontinuously disposed along the passage P and, with respect to a middle position 15 of the passage, the length of the Celmets disposed is larger on the side of the outlet than on the side of the inlet.Type: GrantFiled: June 6, 2011Date of Patent: October 21, 2014Assignee: Sumitomo Electric Industries, Ltd.Inventors: Chihiro Hiraiwa, Masatoshi Majima, Tetsuya Kuwabara, Tomoyuki Awazu, Toshio Ueda, Toshiyuki Kuramoto
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Patent number: 8859162Abstract: Disclosed herein is a fuel cell module. The fuel cell module according to preferred embodiments of the present invention includes: a first support part including a first body part surrounding one side of an outer peripheral surface of a fuel cell and a first connection part formed on one side of the first body part in a longitudinal direction; a second support part including a second body part surrounding the other side of the outer peripheral surface of the fuel cell and the second connection part formed on one side of the second body part in a longitudinal direction; and a fixing part passing through the first connection part and the second connection part to connect and fix the first connection part and the second connection part to each other.Type: GrantFiled: November 27, 2012Date of Patent: October 14, 2014Assignee: Samsung Electro-Mechanics Co., Ltd.Inventors: Jai Hyoung Gil, Kyong Bok Min, Jong Ho Chung, Jong Sik Yoon, Eon Soo Lee
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Publication number: 20140295319Abstract: A fuel cell device is provided having an active central portion with an anode, a cathode, and an electrolyte therebetween. At least three elongate portions extend from the active central portion, each having a length substantially greater than a width transverse thereto such that the elongate portions each have a coefficient of thermal expansion having a dominant axis that is coextensive with its length. A fuel passage extends from a fuel inlet in a first elongate portion into the active central portion in association with the anode, and an oxidizer passage extends from an oxidizer inlet in a second elongate portion into the active central portion in association with the cathode. A gas passage extends between an opening in the third elongate portion and the active central portion. For example, the passage in the third elongate portion may be an exhaust passage for the spent fuel and/or oxidizer gasses.Type: ApplicationFiled: May 6, 2014Publication date: October 2, 2014Inventors: Alan Devoe, Lambert Devoe
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Patent number: 8841044Abstract: Disclosed herein is a solid oxide fuel cell, including: a unit cell; a current collector formed in a flat shape having a first surface and a second surface, the first surface including a groove formed in a thickness direction so as to receive the unit cell therein; and a circular support member formed between the first surface and the second surface of the current collector, wherein the support member is provided in plural, and the support members for respective regions have different diameters.Type: GrantFiled: February 29, 2012Date of Patent: September 23, 2014Assignee: Samsung Electro-Mechanics Co., Ltd.Inventors: Jong Ho Chung, Jai Hyung Gil, Kyong Bok Min, Jong Sik Yoon, Eon Soo Lee
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Patent number: 8822102Abstract: A manifold device for a tube type solid oxide fuel cell including a manifold body including at least one of a first opening for fluid inflow and a second opening for fluid outflow; at least one of a first manifold unit in the manifold body, the first manifold unit distributing fluid flowing in the first opening portion into channels, and a second manifold unit in the manifold body, the second manifold unit integrating fluid flowing in channels out to the second opening; and a plurality of tube type ports, each tube type port having a tube type body contacting and protruding from an outer surface of the manifold body, being connected to and in fluid communication with the channels, and including a heat interception unit in a portion of the tube type body.Type: GrantFiled: September 21, 2010Date of Patent: September 2, 2014Assignee: Samsung SDI Co., Ltd.Inventor: Jun-Won Suh
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Patent number: 8802322Abstract: An interconnecting-type solid oxide fuel cell is disclosed. The fuel cell includes a unit cell, a first current collecting member, a first insulating member, and a second current collecting member. The unit cell has a first electrode layer, an electrolyte layer, and a second electrode layer sequentially formed from an inside thereof, and has an interconnector configured for electrical connection to the first electrode layer and exposed to an outside thereof in a state in which the interconnector is insulated from the second electrode layer. The first current collecting member is formed on an outside of the interconnector and configured to collect current. The first insulating member is formed on an outside of the first current collecting member. The second current collecting member is wound around an outer circumferential surface of the second electrode layer and an outside of the first insulating member.Type: GrantFiled: August 15, 2012Date of Patent: August 12, 2014Assignee: Samsung SDI Co., Ltd.Inventors: Duk-Hyoung Yoon, Sang-Jun Kong, Tae-Ho Kwon, Kwang-Jin Park, Gyu-Jong Bae, Hyun Soh, Young-Sun Kwon
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Patent number: 8771899Abstract: According to one embodiment, a system includes a structure having an ionically-conductive, electrically-resistive electrolyte/separator layer covering an inner or outer surface of a carbon-containing electrically-conductive hollow fiber and a catalyst coupled to the hollow fiber, an anode extending along at least part of a length of the structure, and a cathode extending along at least part of the length of the structure, the cathode being on an opposite side of the hollow fiber as the anode. In another embodiment, a method includes acquiring a structure having an ionically-conductive, electrically-resistive electrolyte/separator layer covering an inner or outer surface of a carbon-containing electrically-conductive hollow fiber and a catalyst along one side thereof, adding an anode that extends along at least part of a length of the structure, and adding a cathode that extends along at least part of the length of the structure on an opposite side as the anode.Type: GrantFiled: February 16, 2010Date of Patent: July 8, 2014Assignee: Lawrence Livermore National Security, LLC.Inventors: Kevin C. Langry, Joseph C. Farmer
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Patent number: 8748052Abstract: An electricity storage system comprising a reversible fuel cell having a first electrode and a second electrode separated by an ionically conducting electrolyte, and at least two chambers adapted to hold fuel and/or a reaction product, wherein the system is substantially closed and at least one reactant for discharge is hydrogen or oxygen.Type: GrantFiled: February 7, 2007Date of Patent: June 10, 2014Assignee: The University Court of the University of St. AndrewsInventors: John Thomas Sirr Irvine, Julie Margaret Nairn, Paul Alexander Conner, James Rennie, Alan Feighery, Frances Gwyneth Elaine Jones, Kelcey Lynn Eccleston, Pierrot Sassou Attidekou
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Patent number: 8722278Abstract: Disclosed is a solid oxide fuel cell that has a high initial power generation performance and a good power generation durability. The fuel cell comprises at least a fuel electrode, an electrolyte, an air electrode, and a current collecting part disposed on the air electrode, wherein the current collecting part comprises an electroconductive metal and an oxide, the electroconductive metal is silver and palladium, the oxide is a perovskite oxide, and the content of the oxide is more than 0 (zero) and less than 0.111 in terms of weight ratio to the electroconductive metal.Type: GrantFiled: October 15, 2009Date of Patent: May 13, 2014Assignee: Toto Ltd.Inventors: Hiroshi Niimi, Akira Kawakami, Yutaka Momiyama, Shuichiro Saigan
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Patent number: 8709675Abstract: The fuel cell base module stacking structure has large compactness, very litte ohmic losses and ease as for implementing the seal of the assembly. It consists of a concentric stack of several fuel cell base cells each consisting on either side of an interconnector (24) sandwiching an anode (21), an electrolyte (22) and a cathode (23), each cell being thereby placed upon each other. The module is completed with two cases for distributing combustible gases. Application to gas fuel cells of the SOFC type.Type: GrantFiled: October 27, 2005Date of Patent: April 29, 2014Assignee: Commissariat a l'Energie AtomiqueInventors: Damien Gallet, Franck Blein, Jean-Luc Sarro
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Patent number: 8709674Abstract: A plurality of tubular solid oxide fuel cells are embedded in a solid phase porous foam matrix that serves as a support structure for the fuel cells. The foam matrix has multiple regions with at least one property differing between at least two regions. The properties include porosity, electrical conductivity, and catalyst loading.Type: GrantFiled: December 15, 2005Date of Patent: April 29, 2014Assignee: Alberta Research Council Inc.Inventors: Partho Sarkar, Mark Richardson, Luis Yamarte
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Patent number: 8652707Abstract: Tubular ceramic structures of non-circular cross section, e.g., anode components of tubular fuel cells of non-circular cross section, are manufactured by applying ceramic-forming composition to the external non-circular surface of the heat shrinkable polymeric tubular mandrel component of a rotating mandrel-spindle assembly, removing the spindle from said assembly after a predetermined thickness of tubular ceramic structure of non-circular cross section has been built up on the mandrel and thereafter heat shrinking the mandrel to cause the mandrel to separate from the tubular ceramic structure of non-circular cross section.Type: GrantFiled: September 1, 2011Date of Patent: February 18, 2014Assignee: WATT Fuel Cell Corp.Inventors: Caine Finnerty, Benjamin Emley
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Patent number: 8647482Abstract: The present invention discloses an electrochemical-catalytic converter, which can remove nitrogen oxides (NOx), carbon monoxide (CO), hydrocarbons (HCs) and particulate matter (PM) in exhaust gas. The electrochemical-catalytic converter comprises a cell module, wherein nitrogen oxides are decomposed to form nitrogen through electrochemical promotion, and wherein carbon monoxide, hydrocarbons and particulate matter are catalyzed to form carbon dioxide and water by an oxidation catalyst.Type: GrantFiled: March 1, 2011Date of Patent: February 11, 2014Assignee: National Tsing Hua UniversityInventor: Ta-Jen Huang
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Patent number: 8642229Abstract: The present invention is an electrochemical reactor unit in which a plurality of electrochemical reactor cells constituted by a tube are housed in a porous material body having a heat releasing function and a current collecting function, these are electrically connected in series, and a fuel manifold is mounted to the connected electrochemical reactor cells; an electrochemical reactor module that comprises a plurality of the units which are arranged in fuel supply holes, and a structure supplying air directly to the entire electrochemical reactor module; and an electrochemical reaction system in which such an electrochemical reactor module is utilized.Type: GrantFiled: May 20, 2009Date of Patent: February 4, 2014Assignee: National Institute of Advanced Industrial Science and TechnologyInventors: Toshio Suzuki, Toshiaki Yamaguchi, Yoshinobu Fujishiro, Masanobu Awano
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Patent number: 8614026Abstract: Fuel cell devices and fuel cell systems are provided. In certain embodiments, the fuel cell devices may include one or more active layers containing active cells that are connected electrically in series. In certain embodiments, the fuel cell devices include an elongate ceramic support structure the length of which is the greatest dimension such that the coefficient of thermal expansion has only one dominant axis coextensive with the length. In certain embodiments, a reaction zone is positioned along a first portion of the length for heating to a reaction temperature, and at least one cold zone is positioned along a second portion of the length for operating below the reaction temperature. There are one or more gas passages, each having an associated anode or cathode.Type: GrantFiled: July 24, 2012Date of Patent: December 24, 2013Inventors: Alan Devoe, Lambert Devoe
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Patent number: 8603699Abstract: A proton conductive electrolyte (20) is made of AB(1-x)MxO3 structure perovskite, and is characterized in that: the B is Ce; the M is a metal having valence that is smaller than +4; and an average of an ion radius of the M is less than an ion radius of Tm3+ and more than 56.4 pm.Type: GrantFiled: February 27, 2007Date of Patent: December 10, 2013Assignee: Toyota Jidosha Kabushiki KaishaInventors: Naoki Ito, Hiroshige Matsumoto, Tatsumi Ishihara
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Publication number: 20130288150Abstract: Disclosed herein are fuel cell elements including at least one electronically conductive layer and an ion conductive layer. The fuel cell elements can have a tubular cross-section or an enclosed cross-section of another shape. Also disclosed is an assembly of fuel cell elements to form cell tubes and stacks of such fuel cell elements or cell tubes. Fuel cell elements, or cell tubes, or stacks thereof can also be used as an electrolyser. Further disclosed are methods of making such fuel cell elements, cell tubes and stacks thereof, as well as methods of using the same.Type: ApplicationFiled: December 23, 2011Publication date: October 31, 2013Applicant: GARAL PTY LTDInventors: Alastair M. Hodges, Garry Chambers
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Patent number: 8535846Abstract: A fuel cell includes a stack structure composed of fuel cell units with current collectors between the fuel cell units, a casing housing the stack structure, and a gas flow-regulating member provided in a gap between the casing and the stack structure. The fuel cell unit includes: a cell plate which holds at least one cell and has a gas introduction hole for one of fuel gas and air; and a separator plate which has a gas introduction hole for the one of the fuel gas and the air. The casing introduces the other of the fuel gas and the air via a gas introduction portion and flows the other gas to a gas discharge portion. The gas flow-regulating member guides the other gas to the gas discharge portion through the current collectors.Type: GrantFiled: November 21, 2006Date of Patent: September 17, 2013Assignee: Nissan Motor Co., Ltd.Inventors: Keiko Kushibiki, Tatsuya Yaguchi, Shigeo Ibuka, Hirokazu Komatsu, Yasushi Nakajima
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Publication number: 20130171542Abstract: A gas decomposition component includes a cylindrical membrane electrode assembly (MEA) including a first electrode layer, a cylindrical solid electrolyte layer, and a second electrode layer in order from an inside toward an outside, in a layered structure, wherein an end portion of the cylindrical MEA is sealed, a gas guide pipe is inserted through another end portion of the cylindrical MEA into an inner space of the cylindrical MEA to form a cylindrical channel between the gas guide pipe and an inner circumferential surface of the cylindrical MEA, and a gas flowing through the gas guide pipe toward the sealed portion is made to flow out of the gas guide pipe in a region near the sealed portion so that a flow direction of the gas is reversed and the gas flows through the cylindrical channel in a direction opposite to the flow direction in the guide pipe.Type: ApplicationFiled: October 13, 2011Publication date: July 4, 2013Applicant: SUMITOMO ELECTRIC INDUSTRIES, LTD.Inventors: Chihiro Hiraiwa, Masatoshi Majima, Tetsuya Kuwabara, Tomoyuki Awazu, Naho Mizuhara, Toshio Ueda, Hideyuki Doi, Toshiyuki Kuramoto
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Publication number: 20130130137Abstract: The present invention relates to a stack for a solid oxide fuel cell and a manufacturing method thereof, and more specifically, to a stack for a high-capacity solid oxide fuel cell and a manufacturing method thereof, in which cell modules comprising a flat-tubular reformer integrated with flat-tubular reactors are electrically connected to form a cell bundle. In a cell module of the stack for the solid oxide fuel cell according to the invention, at least one flat-tubular reactor is stacked on a flat-tubular reformer, wherein the flat-tubular reformer is closed at one side and has formed therein at least one first channel extending to the outside; the flat-tubular reactor is closed at one side and has formed therein at least one second channel extending to the outside; reaction units and air channels are formed on the outside of the flat-tubular reactor; and the first channel and the second channel communicate with each other.Type: ApplicationFiled: March 3, 2011Publication date: May 23, 2013Inventor: Jong Shik Chung
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Publication number: 20130122400Abstract: Disclosed herein is a fuel cell including a unit cell having a electrolytic layer, a first electrode layer formed inside the electrolytic layer, and a second electrode layer formed outside the electrolytic layer. The fuel cell further includes an inner tube positioned inside the unit cell and extending in a longitudinal direction of the unit cell, the inner tube configured to fluidly connect the unit cell with another unit cell, and the inner tube having a variable outer diameter along the longitudinal direction of the unit cell. The fuel cell may be configured to improve fuel or oxidizer flow efficiency. The fuel cell may be configured to maintain flow rate for and improve rection time of fuel or oxidizer during operation of the fuel cell.Type: ApplicationFiled: July 10, 2012Publication date: May 16, 2013Applicant: SAMSUNG SDI CO., LTD.Inventors: Tae-Ho KWON, Sang-Jun KONG, Hyun SOH, Kwang-Jin PARK, Gyu-Jong BAE, Duy-Hyoung YOON, Young-Sun KWON
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Patent number: 8361672Abstract: A tubular fuel cell including: a center support member made from a wire rod; an electrolyte layer formed upon the outside of the center support member; an outer circumferential support member disposed between the center support member and the electrolyte layer, and which is made from a wire rod; a catalyst layer formed upon the outer circumferential surface of the outer circumferential support member, and that is in contact with the electrolyte layer; and an auxiliary outer circumferential support member provided between the center support member and the outer circumferential support member, and which is made from a wire rod.Type: GrantFiled: November 9, 2006Date of Patent: January 29, 2013Assignee: Toyota Jidosha Kabushiki KaishaInventors: Masahiro Imanishi, Haruyuki Nakanishi, Naoto Yoda
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Publication number: 20130011767Abstract: Disclosed is a structure of a solid oxide fuel cell, including a porous tubular anode support having a plurality of through holes, and an electrolyte layer and a cathode layer sequentially formed on the inner surface of the tubular anode support, so that fuel flows via the plurality of through holes and air flows through the inside of the cathode layer, thus increasing a diffusion rate of fuel and air to thereby increase the reaction rate, resulting in excellent cell performance. This structure eliminates the flow of fuel and air around the outside of the fuel cell, thus preventing the formation of an oxidizing atmosphere at the inside and outside of the tubular cell, thereby increasing lifespan of the cell and ensuring cell reliability.Type: ApplicationFiled: September 14, 2012Publication date: January 10, 2013Applicant: SAMSUNG ELECTRO-MECHANICS CO., LTD.Inventors: Jae Hyoung GIL, Jae Hyuk JANG, Kyong Bok MIN, Sung Han KIM, Eon Soo LEE
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Patent number: 8343686Abstract: Tubular objects having two or more concentric layers that have different properties are joined to one another during their manufacture primarily by compressive and friction forces generated by shrinkage during sintering and possibly mechanical interlocking. It is not necessary for the concentric tubes to display adhesive-, chemical- or sinter-bonding to each other in order to achieve a strong bond. This facilitates joining of dissimilar materials, such as ceramics and metals.Type: GrantFiled: July 28, 2006Date of Patent: January 1, 2013Assignee: The Regents of the University of CaliforniaInventors: Lutgard DeJonghe, Craig Jacobson, Michael Tucker, Steven Visco
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Patent number: 8343689Abstract: A solid oxide fuel cell includes a plurality of tubes, with each tube including an anode, a cathode and an electrolyte, A mechanically compliant anode current collector is associated with each tube. An interconnect portion may be attached to the anode current collector. A cathode current collector is also associated with each tube. The interconnect portion provides an oxygen barrier between the anode current collector and the cathode current collector.Type: GrantFiled: December 4, 2006Date of Patent: January 1, 2013Assignee: Adaptive Materials, Inc.Inventors: Aaron Crumm, Quinlan Y. Shuck, Jonathan R. Rice
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Patent number: 8313874Abstract: Disclosed is a structure of a solid oxide fuel cell, including a porous tubular anode support having a plurality of through holes, and an electrolyte layer and a cathode layer sequentially formed on the inner surface of the tubular anode support, so that fuel flows via the plurality of through holes and air flows through the inside of the cathode layer, thus increasing a diffusion rate of fuel and air to thereby increase the reaction rate, resulting in excellent cell performance. This structure eliminates the flow of fuel and air around the outside of the fuel cell, thus preventing the formation of an oxidizing atmosphere at the inside and outside of the tubular cell, thereby increasing lifespan of the cell and ensuring cell reliability.Type: GrantFiled: October 30, 2009Date of Patent: November 20, 2012Assignee: Samsung Electro-Mechanics Co., Ltd.Inventors: Jae Hyoung Gil, Jae Hyuk Jang, Kyong Bok Min, Sung Han Kim, Eon Soo Lee
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Patent number: 8309270Abstract: The present teachings relate to solid oxide fuel cell systems featuring a novel design that provides improved thermal management of the system. The solid oxide fuel cell systems disclosed include gas channeling features that regulate the temperature of local areas of the system and protect thermal-sensitive current collection elements.Type: GrantFiled: August 3, 2007Date of Patent: November 13, 2012Assignee: CP SOFC IP, LLCInventors: Caine Finnerty, Charles Robinson
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Patent number: 8309271Abstract: A tubular fuel cell comprises a cylindrical internal electrode having electrical conductivity, a lamination of a first catalytic layer, an electrolytic layer, and a second catalytic layer laminated in that order on an outer circumferential surface of the internal electrode, and an electrically conductive exterior coil wound around an outer circumferential surface of the second catalytic layer. The tubular fuel cell further comprises an electrically conductive spacer which has an outside diameter greater than that of the exterior coil.Type: GrantFiled: August 3, 2006Date of Patent: November 13, 2012Assignee: Toyota Jidosha Kabushiki KaishaInventors: Masaki Terada, Yukihisa Katayama, Hirokazu Ishimaru, Yuichiro Hama
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Patent number: 8304136Abstract: Disclosed is a solid oxide fuel cell bundle, including a plurality of fuel cells each having a polygonal tubular support an outer surface of which has a plurality of planes, an outer connector formed on one plane among the plurality of planes of the tubular support, a plurality of unit cells respectively formed on two or more remaining planes of the tubular support except for the one plane, and inner connectors for connecting the unit cells and the outer connector in series, wherein the fuel cells is connected in series in such a manner that the outer connector of a fuel cell is bonded to the unit cell of an additional fuel cell, and the unit cells are connected in series, thus exhibiting excellent cell performance and high power density per unit volume, and maintaining high voltage upon collection of current to thereby reduce power loss due to electrical resistance.Type: GrantFiled: November 3, 2009Date of Patent: November 6, 2012Assignee: Samsung Electro-Mechanics Co., Ltd.Inventors: Eon Soo Lee, Jae Hyuk Jang, Jae Hyoung Gil, Kyong Bok Min, Sung Han Kim, Hong Ryul Lee
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Patent number: 8288055Abstract: A fuel cell stack configured to input raw fuel from a fuel source to produce electrical energy includes a fuel cell comprising an anode, an electrolyte, and a cathode. The anode defines an anode chamber, and a hydrogen separation member is disposed within the anode chamber. The hydrogen separation member has a first side and a second side. The first side of the hydrogen separation member defines a raw fuel chamber. The hydrogen separation member transfer hydrogen between the first side and the second side to provide hydrogen fuel to the anode of the fuel cell, while inhibiting the transportation of gas molecules between the first side and the second side.Type: GrantFiled: January 20, 2009Date of Patent: October 16, 2012Assignee: Adaptive Materials, Inc.Inventors: John W. Halloran, Timothy LaBreche, Shaowu Zha, Aaron T. Crumm
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Patent number: 8283084Abstract: There is provided a hollow-shaped membrane electrode assembly for a fuel cell capable of improving power density per unit volume, wherein the hollow-shaped membrane electrode assembly for a fuel cell comprises a hollow solid electrolyte membrane, an outer electrode layer formed on the outer circumferential surface of the solid electrolyte membrane and an inner electrode layer formed on the inner circumferential surface of the solid electrolyte membrane, and wherein the hollow-shaped membrane electrode assembly for a fuel cell is formed in the shape of a spiral.Type: GrantFiled: February 3, 2006Date of Patent: October 9, 2012Assignee: Toyota Jidosha Kabushiki KaishaInventors: Shigeaki Murata, Haruyuki Nakanishi, Masahiro Imanishi, Yoshihisa Tamura
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Patent number: 8211587Abstract: A plasma sprayed ceramic-metal fuel electrode is provided. The fuel electrode has particular application in connection with a solid oxide fuel cell used within a power generation system. The fuel cell advantageously comprises an air electrode, an electrolyte formed on at least a portion of the air electrode, a plasma sprayed ceramic-metal fuel electrode formed on at least a portion of the electrolyte, and an interconnect layer to connect adjacent cells in a generator.Type: GrantFiled: September 16, 2003Date of Patent: July 3, 2012Assignee: Siemens Energy, Inc.Inventors: Roswell J. Ruka, George R. Folser, Srikanth Gopalan
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Patent number: 8197976Abstract: A solid oxide fuel cell system including a main plate, an inner cylinder attached to the main plate, an intermediate cylinder attached to the main plate such that the intermediate cylinder contains a cathode air stream, and an outer cylinder attached to the main plate. An exhaust annular gap is formed between the intermediate and outer cylinders such that hot exhaust gases flow through the exhaust annular gap and heat is transferred from the hot exhaust gases to the cathode air stream. The solid oxide fuel cell system may also include a two-stage tail gas combustor.Type: GrantFiled: January 4, 2008Date of Patent: June 12, 2012Assignee: Protonex Technology CorporationInventors: Joseph C. Poshusta, Ames Kulprathipanja, Christine M. Martin, Jerry L. Martin
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Patent number: 8187560Abstract: Steam, partial oxidation and pyrolytic fuel reformers (14 or 90) with rotating cylindrical surfaces (18, 24 or 92, 96) that generate Taylor Vortex Flows (28 or 98) and Circular Couette Flows (58, 99) for extracting hydrogen from hydrocarbon fuels such as methane (CH4), methanol (CH3OH), ethanol (C2H5OH), propane (C3H8), butane (C4H10), octane (C8H18), kerosene (C12H26) and gasoline and hydrogen-containing fuels such as ammonia (NH3) and sodium borohydride (NaBH4) are disclosed.Type: GrantFiled: May 20, 2010Date of Patent: May 29, 2012Assignee: Global Energy Science, LLCInventor: Halbert Fischel
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Publication number: 20120129078Abstract: A fuel cell module having a composite collector includes a hollow, cylindrical unit cell including a first electrode layer, an electrolyte layer, and a second electrode layer arranged in a radial direction of the hollow, cylindrical unit cell; a current collector including a metal material mesh or conducting line located on an outer circumference of the second electrode layer; and a plurality of auxiliary current collectors including ceramic material powders located on a surface of the current collector.Type: ApplicationFiled: September 22, 2011Publication date: May 24, 2012Inventors: Jan-Dee Kim, Jun-Won Suh, Seung-Tae Lee, Ho-Jin Kweon
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Patent number: 8182959Abstract: The present teachings relate to an electrochemical cell having a closed Fermat spiral shape. The electrochemical cell comprises an anode, a cathode, an electrolyte, a fuel channel, an oxidant channel, and optionally a reforming layer. The electrochemical cell can be made through extrusion, gel-casting, or 3-D printing. The electrochemical cell can be a solid oxide fuel cell.Type: GrantFiled: November 6, 2007Date of Patent: May 22, 2012Assignee: CP SOFC IP, LLCInventors: Yanhai Du, Caine Finnerty
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Patent number: 8173292Abstract: A solid battery includes at least either one of a positive electrode and a negative electrode comprising bars of an active material of the electrode and bars of a solid electrolyte of the electrode arranged alternately in such a manner that each of the bars of the active material of the electrode is disposed adjacent to each of the bars of the solid electrolyte of the electrode, and a solid electrolyte constituting a separator and having a plane to which the bars of the active material and the bars of the solid electrolyte of the electrode are disposed in a crossing direction. There is also provided a method for manufacturing an electrode of such solid battery.Type: GrantFiled: January 30, 2009Date of Patent: May 8, 2012Assignee: Ohara Inc.Inventor: Takashi Kato
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Patent number: 8173317Abstract: In a fuel cells power generation system provided with a power generation module having a plurality of fuel cells, the structure is made such that a cross sectional area of at least one of a fuel flow path and an air flow path is larger in an inner portion of the power generation module and smaller in an outer portion thereof. Accordingly, gas tends to flow through the inner portion of the power generation module, a gas flow rate is quickened, and it is possible to uniformize a molar flow rate of the fuel and the air supplied to the fuel cell, even in a state in which a temperature distribution of the module is not uniform within the power generation module.Type: GrantFiled: January 26, 2007Date of Patent: May 8, 2012Assignee: Hitachi, Ltd.Inventors: Akira Gunji, Hiromi Tokoi, Shin Takahashi
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Patent number: 8097384Abstract: A solid oxide fuel cell (400) is made having a tubular, elongated, hollow, active section (445) which has a cross-section containing an air electrode (452) a fuel electrode (454) and solid oxide electrolyte (456) between them, where the fuel cell transitions into at least one inactive section (460) with a flattened parallel sided cross-section (462, 468) each cross-section having channels (472, 474, 476) in them which smoothly communicate with each other at an interface section (458).Type: GrantFiled: July 8, 2008Date of Patent: January 17, 2012Assignee: Siemens Energy, Inc.Inventors: Paolo R. Zafred, Robert Draper