Carbon-based Material Patents (Class 429/521)
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Patent number: 11923526Abstract: Provided is a process for producing a thin film graphene-bonded metal foil current collector for a battery or supercapacitor, said process comprising: (a) providing a graphene suspension comprising graphene sheets dispersed in a liquid medium; (b) operating a micro-gravure coater to deposit a layer of the graphene suspension onto at least one of the two primary surfaces of a metal foil to form a wet layer of graphene deposited thereon; and (c) removing said fluid medium from the deposited wet layer to form a dry layer of graphene, having a layer thickness from 1 nm to 100 nm. Optionally, the process may include heat treating the dry layer of graphene at a temperature from 35° C. to 3,000° C.Type: GrantFiled: May 11, 2020Date of Patent: March 5, 2024Assignee: Global Graphene Group, Inc.Inventors: Aruna Zhamu, Yanbo Wang, Bor Z. Jang
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Patent number: 8993197Abstract: A bipolar plate for a fuel cell comprises a substrate formed of stainless steel; an oriented amorphous carbon film formed at least on a surface of the substrate facing an electrode, and containing C as a main component, 3 to 20 at. % of N, and more than 0 at. % and not more than 20 at. % of H, and when the total amount of the C is taken as 100 at. %, the amount of C having an sp2 hybrid orbital (Csp2) being not less than 70 at. % and less than 100 at. %, and (002) planes of graphite being oriented along a thickness direction; a mixed layer generated in an interface between the substrate and the oriented amorphous carbon film and containing at least one kind of constituent atoms of each of the substrate and the oriented amorphous carbon film; and a plurality of projections protruding from the mixed layer into the oriented amorphous carbon film and having a mean length of 10 to 150 nm.Type: GrantFiled: December 24, 2010Date of Patent: March 31, 2015Assignee: Toyota Jidosha Kabushiki KaishaInventors: Takashi Iseki, Kazuyuki Nakanishi, Yasuhiro Ozawa, Yuka Yamada, Hajime Hasegawa, Masafumi Koizumi, Katsutoshi Fujisawa, Naoki Ueda, Hirohiko Hisano
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Patent number: 8974983Abstract: An electrical conductive member includes: an electrical conductive structure including: a substrate; an electrical conductive carbon layer provided on at least one surface of the substrate and containing electrical conductive carbon; and a middle layer interposed between the substrate and the electrical conductive carbon layer. An intensity ratio R (ID/IG) of a D-band peak intensity (ID) to a G-band peak intensity (IG) measured by a Raman scattering spectroscopic analysis in the electrical conductive carbon layer is between 1.4 and 1.9.Type: GrantFiled: October 20, 2009Date of Patent: March 10, 2015Assignee: Nissan Motor Co., Ltd.Inventors: Tomokatsu Himeno, Atsushi Miyazawa, Motoki Yaginuma, Keisuke Yamamoto, Keiji Okada, Tsutomu Yamazaki, Yasuhiro Numao, Toshihiko Tsuda
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Patent number: 8956785Abstract: A flow field plate for fuel cell applications includes a metal with a non-crystalline carbon layer disposed over at least a portion of the metal plate. The non-crystalline carbon layer includes an activated surface which is hydrophilic. Moreover, the flow field plate is included in a fuel cell with a minimal increase in contact resistance. Methods for forming the flow field plates are also provided.Type: GrantFiled: July 17, 2013Date of Patent: February 17, 2015Assignee: GM Global Technology Operations LLCInventors: Gayatri Vyas Dadheech, Thomas A. Trabold, Youssef M. Mikhail, Mahmoud H. Abd Elhamid
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Patent number: 8865372Abstract: A lamellar structure graphite foil is used as a material for a separator for a fuel cell, and a hydrophobic layer is formed by impregnation on flow-field channels of the graphite foil. Such a separator is manufactured by forming the flow field channel by etching the graphite foil formed with the mask pattern thereon and forming a hydrophobic layer by impregnation. According to such a separator, performance of a fuel cell stack is enhanced and the manufacturing process of a separator is simplified.Type: GrantFiled: August 3, 2004Date of Patent: October 21, 2014Assignee: Fuelcell Power, Inc.Inventors: Ho-Suk Kim, Byung-Sun Hong, Mee-Nam Shinn
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Patent number: 8785077Abstract: Various embodiments of the present invention provide a fuel cell connection component, including an interconnect or a current collector. The fuel cell connection component includes conductive fibers oriented at an angle of less than about 90° to at least one electrode in the fuel cell. The fuel cell connection component provides an electrically conductive pathway from the at least one electrode of the fuel cell to an external circuit or to an electrode of a different fuel cell. Embodiments of the present invention also provide fuel cells that include the fuel cell connection component, including fuel cell layers, and methods of making the same.Type: GrantFiled: June 29, 2011Date of Patent: July 22, 2014Assignee: Societe BICInventors: Jeremy Schrooten, Mark Petersen, Jean-Louis Iaconis, David Lo, Paul Sobejko
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Patent number: 8758951Abstract: A continuous coal electrolytic cell for the production of pure hydrogen without the need of separated purification units Electrodes comprising electrocatalysts comprising noble metals electrodeposited on carbon substrates are also provided. Also provided are methods of using the electrocatalysts provided herein for the electrolysis of coal in acidic medium, as well as electrolytic cells for the production of hydrogen from coal slurries in acidic media employing the electrodes described herein. Further provided are catalytic additives for the electro-oxidation of coal. Additionally provided is an electrochemical treatment process where iron-contaminated effluents are purified in the presence of coal slurries using the developed catalyst.Type: GrantFiled: May 8, 2006Date of Patent: June 24, 2014Assignee: Ohio UniversityInventor: Gerardine Botte
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Publication number: 20140106257Abstract: Cohesive carbon assemblies are prepared by obtaining a carbon starting material in the form of powder, particles, flakes, or loose agglomerates, dispersing the carbon in a selected organic solvent by mechanical mixing and/or sonication, and substantially removing the organic solvent, typically by evaporation, whereby the cohesive assembly of carbon is formed. The method is suitable for preparing free-standing, monolithic assemblies of carbon nanotubes in the form of films, wafers, or discs, having high carbon packing density and low electrical resistivity. The method is suitable for preparing adherent cohesive carbon assemblies on substrates comprising various materials. The assemblies have various potential applications, such as electrodes or current collectors in electrochemical capacitors, fuel cells, and batteries, or as electromagnetic interference shielding materials.Type: ApplicationFiled: December 13, 2013Publication date: April 17, 2014Applicant: YAZAKI CORPORATIONInventors: Satyabrata RAYCHAUDHURI, Yongan YAN, Leonid GRIGORIAN
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Patent number: 8697311Abstract: An arrangement for interconnecting electrochemical cells of the type having a membrane electrode assembly (MEA) interposed between an anode gas diffusion layer (208) and a cathode gas diffusion layer (210), and first and second current collectors coupled to said anode and cathode gas diffusion layers (GDL), respectively, wherein the first current collector extends from the anode side of one cell to the cathode side of an adjacent cell, and wherein the cell components are clamped together. The first current collector (206) which is in contact with the anode gas diffusion layer (GDL; 208) of a first electrochemical cell (200a) is configured to be connected to the cathode side of a second, adjacent electrochemical cell (200b) via an inert and electrically conductive member (204b), without being in electrochemical contact with the electrochemically active components of the adjacent cell.Type: GrantFiled: August 20, 2008Date of Patent: April 15, 2014Assignee: myFC ABInventors: Anders Lundblad, Henrik Ekstrom, Eric Jonsson
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Publication number: 20140030636Abstract: In general, in one aspect, a graphene film is used as a protective layer for current collectors in electrochemical energy conversion and storage devices. The graphene film inhibits passivation or corrosion of the underlying metals of the current collectors without adding additional weight or volume to the devices. The graphene film is highly conductive so the coated current collectors maintain conductivity as high as that of underlying metals. The protective nature of the graphene film enables less corrosion resistant, less costly and/or lighter weight metals to be utilized as current collectors. The graphene film may be formed directly on Cu or Ni current collectors using chemical vapor deposition (CVD) or may be transferred to other types of current collectors after formation. The graphene film coated current collectors may be utilized in batteries, super capacitors, dye-sensitized solar cells, and fuel and electrolytic cells.Type: ApplicationFiled: July 26, 2012Publication date: January 30, 2014Applicant: Bluestone Global TechInventors: Xin Zhao, Yu-Ming Lin
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Patent number: 8609297Abstract: A connecting structure of a flat fuel cell assembly. The assembly includes a plurality of fuel cells, each of which has a membrane electrode assembly with an anode, a proton exchange membrane and a cathode combined. Two conductive nets are attached to the surfaces of the anode and the cathode of each membrane electrode assembly by thermosetting adhesive and heat pressing to collect and transmit electrons.Type: GrantFiled: June 29, 2004Date of Patent: December 17, 2013Assignee: Industrial Technology Research InstituteInventors: Yeu-Shih Yen, Chiou-Chu Lai, Ju-Pei Chen, Shu-Chen Huang, Ku-Yin Ka
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Patent number: 8592098Abstract: Disclosed are a metal separator for fuel cells, which exhibits excellent properties in terms of corrosion resistance, electrical conductivity and durability, and a method of manufacturing the same. The metal separator for fuel cells includes a separator-shaped metal matrix and a coating layer formed on the metal matrix. The coating layer has a concentration gradient of a carbon element C and a metal element Me according to a thickness thereof such that the carbon element C becomes gradually concentrated in the coating layer with increasing distance from the metal matrix, and the metal element Me becomes gradually concentrated in the coating layer with decreasing distance from the metal matrix.Type: GrantFiled: March 21, 2011Date of Patent: November 26, 2013Assignee: Hyundai HyscoInventors: Yoo-Taek Jeon, Eun-Young Kim, Yeon-Soo Jeong, Ki-Jung Kim, Man-Been Moon
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Patent number: 8592096Abstract: A separator plate for a fuel cell is provided, including a substrate having a radiation-cured first flow field layer disposed thereon. A method for fabricating the separator plate is also provided. The method includes the steps of providing a substrate; applying a first radiation-sensitive material to the substrate; placing a first mask between a first radiation source and the first radiation-sensitive material, the first mask having a plurality of substantially radiation-transparent apertures; and exposing the first radiation-sensitive material to a plurality of first radiation beams to form a radiation-cured first flow field layer adjacent the substrate. A fuel cell having the separator plate is also provided.Type: GrantFiled: September 12, 2012Date of Patent: November 26, 2013Assignee: GM Global Technology Operations LLCInventors: Jeffrey A. Rock, Yeh-Hung Lai, Keith E. Newman, Gerald W. Fly, Alan J. Jacobsen, Peter D. Brewer, William B. Carter
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Patent number: 8546046Abstract: A method for fabricating a bi-polar plate of a fuel cell and the bi-polar plate thereof are presented. A graphite film is formed first. Next, a polymeric material added with electrically conductive powder is coated on a surface of a metal substrate. The graphite film is disposed on the polymeric material and the polymeric material is hardened to form an adhesive layer, such that the graphite film is attached on the surface of the metal substrate.Type: GrantFiled: February 18, 2010Date of Patent: October 1, 2013Assignee: Industrial Technology Research InstituteInventors: Wen-Lin Wang, Chun-Hsing Wu, Kan-Lin Hsueh, Huan-Ruei Shiu, Wen-Chen Chang, Fang-Hei Tsau, Lung-Yu Sung
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Patent number: 8518229Abstract: An integrated electrode-current collector sheet includes a current collector including uneven portions disposed on at least one side of the current collector; and an active material layer disposed on the current collector, the active material layer at least partially covering the uneven portions. In addition, disclosed are a capacitive deionization device and an electric double layer capacitor including the integrated electrode-current collector sheet.Type: GrantFiled: July 31, 2009Date of Patent: August 27, 2013Assignee: Samsung Electronics Co., Ltd.Inventors: Ho-jung Yang, Hyo-rang Kang, Tae-won Song, Chang-hyun Kim
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Publication number: 20130209919Abstract: Performance, properties and stability of bifunctional air electrodes may be improved by using modified current collectors, and improving water wettability of air electrode structures. This invention provides information on creating non-corroding, electrically rechargeable, bifunctional air electrodes. In some embodiments, this bifunctional air electrode includes a corrosion-resistant outer layer and an electrically conductive inner layer. In some embodiments, this bifunctional air electrode includes titanium suboxides formed by reducing titanium dioxide. Titanium suboxides may be corrosion-resistant and electrically conductive.Type: ApplicationFiled: August 9, 2011Publication date: August 15, 2013Applicant: Eos Energy Storage, LLCInventors: Steven Amendola, Michael Binder, Phillip J. Black, Stefanie Sharp-Goldman, Lois Johnson, Michael Kunz, Michael Oster, Tesia Chciuk, Regan Johnson
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Patent number: 8497050Abstract: A flow field plate for fuel cell applications includes a metal with a non-crystalline carbon layer disposed over at least a portion of the metal plate. The non-crystalline carbon layer includes an activated surface which is hydrophilic. Moreover, the flow field plate is included in a fuel cell with a minimal increase in contact resistance. Methods for forming the flow field plates are also provided.Type: GrantFiled: July 29, 2008Date of Patent: July 30, 2013Assignee: GM Global Technology Operations LLCInventors: Gayatri Vyas Dadheech, Thomas A. Trabold, Youssef M. Mikhail, Mahmoud H. Abd Elhamid
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Patent number: 8486582Abstract: A surface modification to prevent oxide scale spallation is disclosed. The surface modification includes a ferritic stainless steel substrate having a modified surface. A cross-section of the modified surface exhibits a periodic morphology. The periodic morphology does not exceed a critical buckling length, which is equivalent to the length of a wave attribute observed in the cross section periodic morphology. The modified surface can be created using at least one of the following processes: shot peening, surface blasting and surface grinding. A coating can be applied to the modified surface.Type: GrantFiled: September 24, 2012Date of Patent: July 16, 2013Assignee: Battelle Memorial InstituteInventors: Elizabeth V. Stephens, Xin Sun, Wenning Liu, Jeffry W. Stevenson, Wayne Surdoval, Mohammad A. Khaleel
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Patent number: 8470489Abstract: Disclosed herein is a method of producing bipolar plates. In one embodiment, is method for producing bipolar plates, the method comprising (a) providing an electrically conductive sheet; and (b) cutting through the sheet to create therein at least one opening for a fluid, where the cut sheet includes a plurality of elongate parallel oxidant flow openings and where at least one oxidant inlet manifold opening and at least one oxidant outlet manifold opening are located at the ends of the elongate oxidant flow openings and in communication therewith.Type: GrantFiled: June 16, 2010Date of Patent: June 25, 2013Assignee: EnergyOr Technologies Inc.Inventor: Thomas Jones
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Patent number: 8349517Abstract: A method of coating a surface of a fuel cell plate is disclosed herein, and involves forming a sol gel mixture by mixing a weak acid and a composition including at least two metal oxide precursors. One of the metal oxide precursors is configured to be hydrolyzed by the weak acid to form a mixed metal oxide framework with an other of the metal oxide precursors having at least one organic functional group that is not hydrolyzed by the weak acid. The mixture is applied to the surface, and is condensed by exposure to air at least one predetermined temperature and for a predetermined time. The sol gel mixture is immersed in water at a predetermined temperature and for a predetermined time to form a porous, hydrophilic, and conductive film on the surface.Type: GrantFiled: April 23, 2009Date of Patent: January 8, 2013Assignee: GM Global Technology Operations LLCInventors: Wen Li, Ping Liu, Jennifer J. Zinck, Tina T. Salguero, Richard H. Blunk
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Patent number: 8343452Abstract: A gas diffusion media for a fuel cell, such as a proton exchange membrane fuel cell, is provided. The gas diffusion media includes carbonizable acrylic pulp fibers instead of conventional phenolic resin as a binder material. The acrylic fibers are mixed with the carbon fiber dispersion during the papermaking step, thus eliminating the phenolic resin impregnation step typically associated with conventional gas diffusion media manufacturing processes. The mat is then cured and carbonized to produce gas diffusion media.Type: GrantFiled: March 20, 2006Date of Patent: January 1, 2013Assignee: GM Global Technology Operations LLCInventors: Chunxin Ji, Gerald J. Fleming, Margaret Fleming, legal representative, Mark Mathias
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Publication number: 20120315570Abstract: A collector for a fuel cell and a fuel cell are provided. The collector for a fuel cell comprises a conductive material and silicon carbide, wherein the conductive material is disposed in the silicon carbide. The collector for a fuel cell according to the present invention has excellent electrical conductivity both at a high temperature of 850° C. or more and at room temperature because it includes a conductive material and silicon carbide.Type: ApplicationFiled: February 10, 2012Publication date: December 13, 2012Applicant: KOREA INSTITUTE OF ENERGY RESEARCHInventors: Sun-Dong KIM, Doo-Won SEO, In-Sub HAN, Se-Young KIM, Ji-Haeng YU, Sang-Kuk WOO
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Patent number: 8323851Abstract: A fuel cell stack that includes a non-permeable shim plate positioned between a composite unipolar plate and a terminal plate at both ends of the stack, where the shim plate is made of a non-corrosive material, such as stainless steel, titanium or sealed graphite. Because the shim plate is non-permeable, it prevents cooling fluid that diffuses through the unipolar plate from contacting the terminal plate, which would otherwise corrode the terminal plate. The shim plate can be coated with a conductive material, such as gold, platinum, ruthenium oxide or mixtures thereof, to reduce its contact resistance.Type: GrantFiled: May 15, 2006Date of Patent: December 4, 2012Assignee: GM Global Technology Operations LLCInventors: Benno Andreas-Schott, Roger M. Brisbane, Mahmoud H. Abd Elhamid
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Patent number: 8309272Abstract: A solid oxide cell is provided which, after short-time activation, can generate electricity at a high power density over a prolonged period. This cell can be constituted so as to eliminate the necessity of carrier gas introduction during power generation and, hence, can more easily realize a size reduction in power generation systems. The solid oxide cell at least has an anode having an anode material, a cathode having a cathode material, and an electrolyte disposed between the anode and the cathode and including an ionically conductive solid oxide, wherein the anode material includes a composite metal oxide or a cermet, solid carbon is deposited on the anode material during activation and at least the following reaction schemes (1) and (2) are utilized at the anode during power generation to generate electricity.Type: GrantFiled: February 27, 2007Date of Patent: November 13, 2012Assignees: Tokyo Institute of Technology, Mitsubishi Chemical CorporationInventors: Manabu Ihara, Shinichi Hasegawa, Keiji Yamahara
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Patent number: 8252484Abstract: A high-performance separator for a fuel cell is provided that includes an electrically conducting flow path part and an integrated insulating outer circumferential part surrounding the flow path part. The flow path part includes an electrically conducting resin composition including a carbonaceous material (A) and a thermoplastic resin composition (B) at a mass ratio (A)/(B) of 1 to 20 with the total mass of (A) and (B) accounting for 80 to 100 mass % in the composition. The flow path part has a corrugated shape having a recess and a projection on each of front and back surfaces thereof, where the recess constitutes a groove for a flow path, and a thickness of 0.05 to 0.5 mm and a maximum thickness/minimum thickness ratio of 1 to 3. The insulating outer circumferential part includes an insulating thermoplastic resin composition having a volume resistivity of 1010 ?cm or more.Type: GrantFiled: September 27, 2007Date of Patent: August 28, 2012Assignees: Showa Denko K.K., Honda Motor Co., Ltd.Inventors: Tadashi Iino, Zenichiro Izumi, Yukihito Tanaka, Toshiki Kawamura
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Patent number: 8252483Abstract: A lightweight, compact high-performance fuel cell separator is provided with enhanced output density and capable of being stacked without a gas seal member. Embodiments include a separator having a corrugated electrically conducting flow path. A recess and projection are formed on front and rear surfaces, each constituting a gas flow path alternately arrayed abreast in a plane.Type: GrantFiled: September 27, 2007Date of Patent: August 28, 2012Assignees: Showa Denko K.K., Honda Motor Co., Ltd.Inventors: Tadashi Iino, Zenichiro Izumi, Yukihito Tanaka, Toshiki Kawamura
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Publication number: 20120183887Abstract: The oriented amorphous carbon film contains C as a main component, 3 to 20 at. % of N, and more than 0 at. % and not more than 20 at. % of H, and when the total amount of the C is taken as 100 at. %, the amount of C having an sp2 hybrid orbital (Csp2) being not less than 70 at. % and less than 100 at. %, and (002) planes of graphite being oriented along a thickness direction. This film has a novel structure and exhibits a high electric conductivity. This film can be formed by DC plasma CVD method in which an electric discharge is generated by applying a voltage of not less than 1500 V to reaction gas including at least one kind of compound gas selected from gas of a carbocyclic compound containing Csp2 and gas of an N-containing heterocyclic compound containing Csp2, and nitrogen and/or silicon, and nitrogen gas.Type: ApplicationFiled: December 24, 2010Publication date: July 19, 2012Applicant: KABUSHIKI KAISHA TOYOTA CHUO KENKYUSHOInventors: Takashi Iseki, Yuka Yamada, Kazuyuki Nakanishi, Yasuhiro Ozawa, Shingo Ohta
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Patent number: 8221938Abstract: One exemplary embodiment includes a fuel cell component having comprising a carbon chain, and a material grafted to the coating/surface, wherein the material includes ionic or polar groups. One embodiment includes composite plates which include carbon that can be activated and treated to make their surface hydrophilic.Type: GrantFiled: August 8, 2008Date of Patent: July 17, 2012Assignee: GM Global Technology Operations LLCInventors: Mahmoud H. Abd Elhamid, Youssef M. Mikhail, Gayatri Vyas Dadheech
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Publication number: 20120164555Abstract: According to an aspect of the present invention, there is provided a collector member 10 comprising a sheet-shaped base material 11 having a carbon-containing fiber 11a and catalyst particles 12 adhered to an outer periphery of the fiber 11a, containing a noble metal or an alloy thereof, and having an average particle diameter of 0.1 to 2 ?m.Type: ApplicationFiled: March 12, 2012Publication date: June 28, 2012Applicant: KABUSHIKI KAISHA TOSHIBAInventors: Mutsuki YAMAZAKI, Yoshihiko Nakano, Wu Mei
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Patent number: 8197714Abstract: The invention provides an electrically conductive composite having high conductivity, hermeticity, high mechanical strength, low surface roughness, lightweight, and thin profile. The composite comprises a rubber modified with vinyl ester resin. After curing in mold, the composite may serve as a bipolar plate in a fuel cell. For example, the bipolar plate is combined with a membrane electrode assembly (MEA) to form a proton exchange membrane fuel cell (PEMFC).Type: GrantFiled: December 19, 2006Date of Patent: June 12, 2012Assignee: Industrial Technology Research InstituteInventors: Min-Yu Yen, Jiann-Jong Su, Jen-Dong Hwang, Yi-Yie Yan
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Publication number: 20120088186Abstract: The invention relates to a catalyst, to the use thereof for the electrochemical conversion of methane to methanol and for the direct electrochemical conversion of methane to CO2. The invention also relates to an electrode, in particular for a fuel cell including such a catalyst, as well as to a method for manufacturing such an electrode. The invention further relates to a fuel cell including said catalyst or said electrode. The catalyst according to the invention includes a platinum precursor (II), and optionally a metal-ion precursor M supported by particles of a heteropolyanion (HPA). The invention can be used in particular in the field of the electrochemical oxidation of methane into methanol or CO2.Type: ApplicationFiled: April 23, 2010Publication date: April 12, 2012Applicants: UNIVERSITE PARIS SUD XI, CENTRE NATIONAL DE LA RECHERCHE SCIENTIFIQUEInventor: Yu-Wei Lu
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Patent number: 8124297Abstract: This invention intends to improve the catalyst efficiency by sufficiently providing a triple phase boundary where reaction gas, catalysts, and electrolytes meet in carbon nanohorns. With the utilization of the resulting MEA, the electrode reactions are allowed to effectively proceed, and the power generation efficiency of a fuel cell is improved to result in a solid polymer fuel cell with excellent properties. Such solid polymer fuel cell comprises electrodes having a catalyst layer comprising: a carrier comprising a carbon nanohorn aggregate; catalytic metals supported on the carrier comprising a carbon nanohorn aggregate; and polymer electrolytes coating the carrier comprising a carbon nanohorn aggregate, wherein the proportion of the polymer electrolyte to the carbon nanohorn aggregate is 0.32:1 to 0.70:1 by weight.Type: GrantFiled: March 1, 2007Date of Patent: February 28, 2012Assignee: Toyota Jidosha Kabushiki KaishaInventors: Sreekumar Kurungot, Hirokazu Ishimaru
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Patent number: 8110315Abstract: A monopolar membrane-electrode assembly includes an electrolyte membrane with a plurality of cell regions, an anode supporting body and a cathode supporting body on both sides of the electrolyte membrane, respectively having a plurality of apertures corresponding to the cell regions, a plurality of anode and cathode current collectors, each including a current collecting portion to correspond to each aperture of the respective anode or cathode supporting body to collect current, a conducting portion connected to a side of the current collecting portion, and a connecting line that connects the conducting portion to an outside terminal, a plurality of anode and cathode electrodes respectively formed on the and the cathode current collecting portions, and a circuit unit connected to the connecting lines of the anode current collectors and the cathode current collectors, wherein the cells are connected in series or parallel, or electrically separated through the circuit unit.Type: GrantFiled: February 5, 2007Date of Patent: February 7, 2012Assignee: Samsung SDI Co., Ltd.Inventors: Jae-yong Lee, Jin-ho Kim, Kyoung-hwan Choi
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Patent number: 8110248Abstract: A fuel cell structure comprises a diffusion layer and/or a catalyst layer which are made of a carbonaceous porous material having a nano-size structure, such as carbon nanowall (CNW). A method of manufacturing the structure is also disclosed. The structure and method simplify the process of manufacturing a fuel cell electrode comprised of an electrode catalyst layer and a gas diffusion layer. The electrical conductivity of the catalyst layer is increased and the diffusion efficiency of the diffusion layer is improved, whereby the electricity generation efficiency of the fuel cell can be improved.Type: GrantFiled: February 14, 2006Date of Patent: February 7, 2012Assignees: Toyota Jidosha Kabushiki KaishaInventors: Masaru Hori, Mineo Hiramatsu, Hiroyuki Kano, Satoshi Yoshida, Yukihisa Katayama, Toru Sugiyama
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Patent number: 8097385Abstract: The present disclosure provides for a bipolar plate assembly for use in a fuel cell stack. The bipolar plate assembly includes: (a) at least one flow field layer defining a flow field portion and a perimeter portion; (b) at least one core assembly including at least one porous carbon layer and at least one impermeable layer; and (c) a cathode side reactant and an anode side reactant. The at least a first flow field layer is made from a porous carbon material and the perimeter portion is impregnated with a polymer material. The porous carbon layer is joined to: (i) the at least one impermeable layer on a first side by an adhesive material; and (ii) the flow field layer perimeter on a second side by a second adhesive material. The at least a first flow field layer defines reactant inlet and outlet ports and reactant flow passageways for each of the cathode side reactant and the anode side reactant.Type: GrantFiled: June 12, 2007Date of Patent: January 17, 2012Assignee: University of ConnecticutInventors: H. Russell Kunz, Leonard Bonville, Rachid Zaffou, Ruichun Jiang, James Fenton
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Publication number: 20110305974Abstract: A main object of the present invention is to provide an air cathode with great discharged capacity per unit area. The present invention solves the above-mentioned problems by providing an air cathode used for a nonaqueous air battery, comprising: an air cathode current collector having a porous structure and an air cathode layer containing a conductive material and formed on the air cathode current collector, wherein the average supporting amount of the conductive material in a planar area of the air cathode is within a range of 0.3 mg/cm2 to 9.0 mg/cm2.Type: ApplicationFiled: March 6, 2009Publication date: December 15, 2011Applicant: TOYOTA JIDOSHA KABUSHIKI KAISHAInventor: Shinji Nakanishi
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Publication number: 20110294043Abstract: Electrodes for fuel cells including a quadrivalent metal element, a monovalent metal element or a divalent metal element, and phosphates, as well as fuel cells including the electrodes.Type: ApplicationFiled: April 7, 2011Publication date: December 1, 2011Applicant: Samsung Electronics Co., Ltd.Inventors: Tae-young KIM, Jung-seok Yi, Pil-won Heo
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Patent number: 8053141Abstract: The present invention relates to a contact plate for fuel cells with a coherent active area (11) on at least one side of the contact plate, wherein the active area (11) consists of a contact surface (2) which over the whole surface comprises a coating (4) of an electrically conductive, corrosion-resistant material, and of recesses (3) so that the recesses (3) form a channel structure, wherein the coating (4) furthermore at least in the bottom regions (5) of the recesses (3) is omitted. The invention further relates to a corresponding fuel cell or to a fuel cell stack with at least one such contact plate as well as to various methods for manufacturing such contact plates which may serve as bipolar plates as well as monopolar plates or end plates. With the contact plate according to the invention, one achieves an optimally reduced contact resistance with a minimal material expense for the coating (4).Type: GrantFiled: February 25, 2005Date of Patent: November 8, 2011Assignee: Reinz-Dichtungs-GmbHInventors: Dieter Grafl, Raimund Stroebel, Lothar Quick, Joachim Scherer, Christian Schleier, Bernd Gaugler
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Patent number: 8003279Abstract: An electrically conductive element for a proton exchange membrane fuel cell having low electrical contact resistance and high corrosion resistance. The conductive element comprises a corrosion susceptible metal substrate with a surface, which is preferably treated to activate the surface (i.e., to remove a passivation layer of oxides from the surface) with an acidic treatment solution. The treated surface is then overlaid with an electrically conductive, corrosion-resistant, protective coating to protect the substrate re-forming a passivation layer while exposed to the corrosive environment of the fuel cell.Type: GrantFiled: June 20, 2008Date of Patent: August 23, 2011Assignee: GM Global Technology Operations LLCInventor: Michael K. Budinski
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Patent number: 7981562Abstract: A fuel cell stack includes an electricity generating element, which generates electrical energy through a reaction of a fuel and oxygen. The electricity generating element includes a membrane-electrode assembly (MEA), a first separator positioned at a first side of the MEA and having a heat sink element positioned therein for dissipating heat generated through the reaction of the fuel and oxygen, and a second separator positioned at a second, opposite side of the MEA.Type: GrantFiled: July 3, 2006Date of Patent: July 19, 2011Assignee: Samsung SDI Co., Ltd.Inventor: Sang-Won Lee
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Patent number: 7977012Abstract: A method of coating a surface of a fuel cell plate is disclosed herein. The method involves forming a sol gel mixture including a metal oxide modified with at least one functional group, where the at least one functional group is configured to improve adhesion; and adding carbon modified with a hydrophilic functional group to the mixture, thereby forming a suspension. The suspension is applied to the surface of the fuel cell plate, and is activated to form a porous, hydrophilic, and conductive film on the surface of the fuel cell plate.Type: GrantFiled: April 23, 2009Date of Patent: July 12, 2011Assignee: GM Global Technology Operations LLCInventors: Wen Li, Ping Liu, Jennifer J. Zinck, Chaoyin Zhou, Tina T. Salguero
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Patent number: 7960071Abstract: Disclosed is a separator for a fuel cell made of a metal plate comprising both a cooling water flow field and a gas flow field formed on each surface thereof, wherein the separator consists of the joined metal plates for the cooling water flow fields to face each other, the surfaces of the joined metal plates are coated with TiN, a polymer electrolyte membrane fuel cell comprising the separator and a method for manufacturing the separator.Type: GrantFiled: December 13, 2004Date of Patent: June 14, 2011Assignee: Korea Institute of Science and TechnologyInventors: In-Hwan Oh, Eun Ae Cho, Sung-Goon Kang, Ui Sik Jeon, Heung Yong Ha, Seong Ahn Hong, Tae Hoon Lim, Suk-Woo Nam, Sung Pil Yoon, Jonghee Han
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Patent number: 7923170Abstract: The degree of freedom in the shape of channels in a separator is increased, enabling an optimum gas channel to be designed, enabling a sufficient supply of gas below gas channel ribs, and improving cell performance through the reduction in diffusion polarization. Drainage property is also improved and flooding is prevented, thereby reducing diffusion polarization and improving cell performance. Cell performance is also improved through the reduction of contact resistance. A fuel cell separator comprises a separator substrate on which gas channel ribs are formed through vapor-phase growth of a carbon-based porous material with a nanosize structure. An electrode structure for a fuel cell, methods of manufacturing the separator and the fuel cell, and a solid polymer fuel cell comprising the electrode structure.Type: GrantFiled: September 21, 2005Date of Patent: April 12, 2011Assignees: Toyota Jidosha Kabushiki KaishaInventors: Masaru Hori, Mineo Hiramatsu, Hiroyuki Kano, Yukihisa Katayama, Toru Sugiyama, Satoshi Yoshida
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Patent number: 7910259Abstract: A method of manufacturing an anode for a fuel cell including: performing an acid treatment for a carbon-based compound; washing the resultant obtained from the acid treatment with water and then performing a freeze-drying (lyophilization) process; forming a microporous diffusion layer by dispersing the lyophilized resultant in a solvent, coating the dispersed resultant on a porous carbon support, and drying; and forming a catalyst layer on top of the microporous diffusion layer, an anode for a fuel cell obtained according to the method herein, and a fuel cell using the same. An anode having improved efficiency on liquid fuel diffusion can be obtained when using the fuel diffusion layer including the microporous diffusion layer formed of the carbon-based compounds obtained after an acid treatment and a freeze-drying process according to the present invention. A fuel cell having improved performance can be manufactured by using such an anode.Type: GrantFiled: June 2, 2006Date of Patent: March 22, 2011Assignee: Samsung SDI Co., Ltd.Inventors: Seol-ah Lee, Seung-jae Lee, Chan-ho Pak, Ji-rae Kim, Dae-jong Yoo
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Patent number: 7867941Abstract: A sulfur-containing mesoporous carbon that has mesopores with an average diameter of 2 to 10 nm, a method of preparing the same, a catalyst containing the mesoporous carbon as a catalyst support, and a fuel cell using the catalyst in which the sulfur-containing mesoporous carbon has a good affinity for and adhesion to catalyst particles so as to strongly support the catalyst particles due to the sulfur atoms substituting for carbons in an OMC carbon skeleton structure. The growth of metal catalyst particles is prevented when heat-treating the metal catalyst particles. The catalyst using the sulfur-containing mesoporous carbon can be applied to a fuel cell to prevent a reduction in catalytic activity due to increased particle size by an accumulation of catalyst particles. The catalyst containing the sulfur-containing mesoporous carbon as a catalyst support can be used to manufacture a fuel cell having an improved performance.Type: GrantFiled: December 28, 2007Date of Patent: January 11, 2011Assignee: Samsung SDI Co., Ltd.Inventors: Sang Hoon Joo, Chan-ho Pak, Hyuk Chang, Ji-man Kim, Hyung-ik Lee
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Patent number: 7862956Abstract: A flexible flow field separator includes a substrate layer formed of a flexible material and having first and second surfaces. A structured flow field pattern is defined on the first surface of the substrate layer. The structured flow field pattern defines one or more fluid channels. The separator includes a first layer formed of one or more metals and disposed on the first surface of the substrate layer. The first layer is formed of an electrically conductive material. The separator further includes a second layer disposed on the second surface of the substrate layer. The second layer is formed of a flexible electrically conductive material. The first layer contacts the second layer at one or more locations to define an electrical connection between the first and second layers.Type: GrantFiled: December 29, 2004Date of Patent: January 4, 2011Assignee: 3M Innovative Properties CompanyInventors: Raymond P. Johnston, Mark K. Debe, Haiyan Zhang
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Patent number: 7851107Abstract: A low-cost fuel cell separator having a metallic substrate which is able to stably maintain low electric resistance (high electrical conductivity) and high corrosion resistance for a long period is provided. The separator has a metallic substrate having an oxide film forming a surface thereof and made from an oxidization of a metal of the substrate, and an electrically conductive thin film formed on a surface of the oxide film of the substrate. Due to this construction, low electric resistance (high electrical conductivity) is achieved by the electrically conductive thin film. Furthermore, even if the electrically conductive thin film has pinholes, the oxide film substantially prevents or reduces elution from the separator substrate, thereby achieving high corrosion resistance. Still further, since the oxide film is formed by oxidation of the substrate, the oxide film can be formed at a lower cost than an oxide film formed from a different metal.Type: GrantFiled: November 14, 2007Date of Patent: December 14, 2010Assignee: Toyota Jidosha Kabushiki KaishaInventor: Hiromichi Nakata
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Patent number: 7842433Abstract: A fuel cell separator plate comprising a portion in contact with an electrode, and a sealing portion provided around the contact portion, the contact portion having a larger surface roughness (Rmax) than that of the sealing portion. It is preferably a molded separator plate made of a composite carbon material comprising carbon and a thermosetting resin.Type: GrantFiled: October 24, 2002Date of Patent: November 30, 2010Assignee: Honda Giken Kogyo Kabushiki KaishaInventors: Yoshihiro Nakanishi, Yuichiro Kosaka, Kentaro Nagoshi
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Patent number: 7771891Abstract: Disclosed herein are an ionic conductor including a proton conductor, a process for production thereof, and an electrochemical device (such as fuel cell) with said ionic conductor, said ionic conductor being superior in ionic conductivity, water resistance, and film forming properties. The ionic conductor is formed from a polymer in which carbon clusters having ion dissociating functional groups are bonded to each other through connecting groups. The polymer is less water-soluble and more chemically stable than a derivative composed solely of carbon clusters; therefore, it permits many ion dissociating functional group to be introduced thereinto. Moreover, if ion dissociating functional groups are introduced into also the connecting group, it is possible to prevent the concentration of ion dissociating functional groups from decreasing as the result of polymerization. The polymer can be easily synthesized by simple condensation, substitution, and hydrolysis.Type: GrantFiled: December 19, 2008Date of Patent: August 10, 2010Assignee: Sony CorporationInventors: Koichiro Hinokuma, Bjoern Pietzak, Constance Gertrud Rost, Masafumi Ata, Yongming Li, Kazuaki Fukushima
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Patent number: 7740990Abstract: A separator material suitable for a polymer electrolyte fuel cell and a method of producing the same. The separator material exhibiting gas impermeability, strength, dimensional stability during long-term use, and only a small degree of dissolution of organic substances which hinder the cell reaction. The separator material includes a graphite/cured resin molded product produced by binding a graphite powder using a mixed resin prepared by mixing an epoxy resin with a specific epoxy equivalent and a phenolic resin with a specific hydroxyl equivalent at a specific equivalent ratio and adding an imidazole compound without an amino group as a curing accelerator. The graphite/cured resin molded product has, when immersed in hot water at 90° C., a water absorption elongation percentage after 500 hours of immersion of a specific value or less and an amount of ammonium ions dissolved and an amount of TOC dissolved after 50 hours of immersion of specific values or less.Type: GrantFiled: November 4, 2005Date of Patent: June 22, 2010Assignee: Tokai Carbon Co., Ltd.Inventors: Tomonori Tahara, Nobuyuki Hirano