Dry Toner Containing A Chemically Identified Magnetic Component Patents (Class 430/106.1)
  • Patent number: 7252915
    Abstract: The present invention relates to a magnetic mono-component toner composition, and more particularly to a mono-component toner composition that comprises magnetic toner particle comprising a binder resin, a magnetic component, and a charge control agent; a hydrophobic treated silica having a specific surface area of 20 to 80 m2/g; a hydrophobic treated silica having a specific surface area of 130 to 230 m2/g; and a metal oxide fine powder. A magnetic mono-component toner composition of the present invention has such good flowability that it provides smooth toner supply even when the developing roller surface has been worn due to long time use, and it has such excellent uniform chargeability that it prevents image deterioration (“wave” patterns of toner may form on developing roller, that is, magnetic sleeve) by forming an uniform toner layer on the developing roller.
    Type: Grant
    Filed: December 24, 2002
    Date of Patent: August 7, 2007
    Assignee: LG Chem, Ltd.
    Inventors: Won-Sup Lee, Chang-Soon Lee, In-Hee Lim
  • Publication number: 20070148576
    Abstract: The present invention provides a toner for electrostatic charge development comprising an amorphous polyester resin, a releasing agent, and magnetic metal particles covered with a resin the main component of which is a crystalline polyester resin.
    Type: Application
    Filed: August 10, 2006
    Publication date: June 28, 2007
    Applicant: FUJI XEROX CO., LTD.
    Inventors: Takao Ishiyama, Hiroshi Nakazawa, Masanobu Ninomiya
  • Patent number: 7208252
    Abstract: Magnetic toner compositions, conductive developer compositions, and methods for producing images in a hybrid jumping development system, more specifically, in a magnetic ink character recognition system, are disclosed. The developer compositions contain coated magnetic toner particles and coated carrier particles. The toner compositions include a resin, colorant, wax, magnetic component, and surface additives of coated silica, titania, and zinc stearate.
    Type: Grant
    Filed: June 30, 2004
    Date of Patent: April 24, 2007
    Assignee: Xerox Corporation
    Inventors: Michael L. Grande, William H. Hollenbaugh, Jr.
  • Patent number: 7160660
    Abstract: In a magnetic toner having toner particles containing at least a binder resin and a magnetic material, the binder resin is chiefly composed of a resin having a polyester unit synthesized using as a catalyst a tin compound represented by the following Formula (1), and the magnetic material has a number-average particle diameter of form 0.1 ?m to 0.3 ?m: (RCOO)2Sn??Formula (1) wherein R represents an alkyl group having 5 to 15 carbon atoms. This magnetic toner can attain a stable image density without dependence on environment and enables formation of high-grade images over a long period of time without causing scratches of latent image bearing members.
    Type: Grant
    Filed: April 6, 2004
    Date of Patent: January 9, 2007
    Assignee: Canon Kabushiki Kaisha
    Inventors: Tadashi Dojo, Nene Shibayama, Yuichi Mizoo, Yusuke Hasegawa
  • Patent number: 7122286
    Abstract: A toner for developing a latent electrostatic image to a toner image, including a binder resin, and a magnetic material which is blackened by coating the surface of a magnetic powder with a coloring agent, the magnetic material being in an amount of 10 wt.% to 40 wt.% of the entire weight of the toner, a method of forming an image, using a two-component developer containing the toner, an image formation apparatus using the two-component developer, and a toner container containing therein the toner, and an image formation apparatus equipped with the toner container are proposed.
    Type: Grant
    Filed: April 5, 2001
    Date of Patent: October 17, 2006
    Assignee: Ricoh Company, Ltd.
    Inventors: Masanori Suzuki, Yohichiroh Watanabe, Masahide Yamashita, Kazuhito Watanabe, Keiko Shiraishi, Kohki Katoh
  • Patent number: 7118728
    Abstract: A method for making ferrite powder may include providing ferrite feed materials in a form of particles having different sizes and irregular shapes, and exposing the ferrite feed materials to a plasma to provide a more spherical shape to irregularly shaped particles to thereby make the ferrite powder. An apparatus for making ferrite powder may include a feeder for ferrite feed materials and a plasma generator for exposing the ferrite feed materials to a plasma.
    Type: Grant
    Filed: May 7, 2003
    Date of Patent: October 10, 2006
    Assignee: Steward Advanced Materials, Inc.
    Inventors: Henry G. Paris, Danny R. Smith
  • Patent number: 7033720
    Abstract: Development systems and methods for developing using magnetic toner are disclosed. The present invention further discloses developers used in development systems as well as the toner used in developer for magnetic ink character recognition printing. With respect to the development system, a development system is disclosed which includes a supply of dry developer mixture which contains magnetic toner particles and hard magnetic carrier particles. The development system further includes a non-magnetic, cylindrical shell for transporting the developer between the supply and the development zone, wherein the shell can be rotatable or stationary. A rotating magnetic core of a pre-selected magnetic field strength and means for rotating at least the magnetic core to provide for the transport of the toner particles from the shell to an electrostatic image also provided as part of the development system.
    Type: Grant
    Filed: June 2, 2004
    Date of Patent: April 25, 2006
    Assignee: Eastman Kodak Company
    Inventors: Thomas A. Jadwin, John F. Crichton, Robert D. Fields, Eric C. Stelter
  • Patent number: 7016632
    Abstract: Development systems and methods for developing using chemically prepared toners are disclosed. The present invention further discloses developers used in development systems. The use of chemically prepared toners with hard magnetic carrier particles with a non-magnetic, cylindrical shell for transporting developers provides excellent benefits with respect to image quality by reducing granularity and by providing a typically constant, stable developer life as shown by the consistent level of charge to mass over time during operation.
    Type: Grant
    Filed: June 23, 2003
    Date of Patent: March 21, 2006
    Assignee: Eastman Kodak Company
    Inventors: Jan Bares, James H. Anderson, Matthew Ezenyilimba, William K. Goebel
  • Patent number: 6953646
    Abstract: A toner comprises toner particles comprising at least a binder resin, a colorant, and a sulfur-containing resin, in which the toner particles comprise the sulfur-containing resin so as to satisfy a relation of; 0.50?IS/TS?0.95 where TS denotes a content of sulfur in the toner particles, and IS denotes a content of sulfur in isopropyl alcohol insoluble components of the toner particles, whereby it is possible to obtain a high quality image having an excellent developing resistance regardless of the surrounding conditions and a uniform charge amount distribution regardless of processing speed.
    Type: Grant
    Filed: May 14, 2003
    Date of Patent: October 11, 2005
    Assignee: Canon Kabushiki Kaisha
    Inventors: Tadashi Doujo, Yuichi Mizoh, Nene Shibayama, Yusuke Hasegawa
  • Patent number: 6916586
    Abstract: The toner for electrostatic charged image development of the present invention is characterized in that it contains at least a binder resin, a mold releasing agent and magnetic metal particles, and the solubility of the magnetic metal particles in a 1 mol/l aqueous HNO3 solution at 50° C. is 500 mg/g·l or less.
    Type: Grant
    Filed: September 5, 2003
    Date of Patent: July 12, 2005
    Assignee: Fuji Xerox Co., Ltd.
    Inventors: Takao Ishiyama, Hiroshi Nakazawa, Shuji Sato, Yosuke Tsurumi, Yasuhiro Arima, Takashi Imai
  • Patent number: 6875549
    Abstract: A toner showing a high transferability and suitable for use in cleanerless image forming system is formed of toner particles comprising at least a binder resin and magnetic iron oxide. The toner is characterized by a specific circularity distribution relative to its weight-average particle size and a controlled degree of surface-exposed magnetic iron oxide providing an extract solution with hydrochloric acid showing an absorbance of 1.0-2.5 at a wavelength of 340 nm. The toner is suitably produced by a production system including a rotary mechanical pulverizer and a one-pass surface treatment apparatus for continuously applying a mechanical impact force to pulverized toner particles therein.
    Type: Grant
    Filed: April 8, 2002
    Date of Patent: April 5, 2005
    Assignee: Canon Kabushiki Kaisha
    Inventors: Katsuhisa Yamazaki, Hirohide Tanikawa, Hiroshi Yusa, Takashige Kasuya, Yoshihiro Ogawa, Shuhei Moribe
  • Patent number: 6873814
    Abstract: A developing device including a developer containing magnetic toner grains and includes a main pole for development disposed in a sleeve. Flux density generated by the magnetic pole in a direction normal to the surface of the sleeve outside of the surface has an attenuation ratio of 50% or above. The toner grains have a weight mean grain size of 6.0 ?m to 8.0 ?m while the toner grains having grain sizes of 5 ?m and below occupy 40% to 80% of the entire developer. The toner grains have magnetization strength of 10 emu/g to 25 emu/g in a magnetic field of 5 kOe or magnetization strength of 7 emu/g to 20 emu/g in a magnetic field of 1 kOe. The toner grains reduce toner scattering and image defects despite that they are magnetic, thereby implementing ultrahigh resolution.
    Type: Grant
    Filed: November 1, 2002
    Date of Patent: March 29, 2005
    Assignee: Ricoh Company, Ltd.
    Inventors: Tokuya Ohjimi, Fumihiro Sasaki, Hiroto Higuchi, Maiko Kondo, Toshio Koike, Atsushi Sampe, Masayuki Yamane, Kunihiro Ohyama, Junichi Sano, Takeyoshi Sekine
  • Patent number: 6852460
    Abstract: A toner, such as an electrostatic latent image developing toner and a MICR toner, has an even charge distribution, and exhibits balanced charging characteristics without decreases in frictional electrification or increases in charge, as well as superior fluidity, environmental independence, and durability. This is achieved by treating toner particles, which include binder resin and magnetic particles, with an external additive particle that is one of: a combination of rutile-type titanium oxide and anatase-type titanium oxide; and rutile-type titanium oxide that falls in a range of 5 to 10% by volume when a total volume of the toner is regarded as being 100%.
    Type: Grant
    Filed: April 23, 2002
    Date of Patent: February 8, 2005
    Assignee: Kyocera Corporation
    Inventors: Yukinori Nakayama, Yojiro Sato, Hiroaki Moriyama, Masaki Ishii, Noriya Okamoto
  • Publication number: 20040234880
    Abstract: The present invention relates to a magnetic toner composition, and more particularly to a magnetic toner composition having an improved chargeability and excellent uniform chargeability, and that is capable of reducing a difference in electrostatic charge between a toner remaining in a cartridge or in a developing unit and that of a newly supplied toner. A magnetic toner composition of the present invention comprises magnetic toner particulate comprising a binder resin and a magnetic substance, a conductive fine powder having a specific surface area of 30 to 300 m2/g, a hydrophobic silica having a specific surface area of 100 to 240 m2/g, and an inorganic fine powder having an average diameter of 0.1 to 4.O&mgr;m.
    Type: Application
    Filed: August 15, 2003
    Publication date: November 25, 2004
    Inventors: In-Hee Lim, Chang-Soon Lee, Won-Sup Lee
  • Publication number: 20040229142
    Abstract: In a magnetic toner having toner particles containing at least a binder resin and a magnetic material, the binder resin is chiefly composed of a resin having a polyester unit synthesized using as a catalyst a tin compound represented by the following Formula (1), and the magnetic material has a number-average particle diameter of form 0.1 &mgr;m to 0.
    Type: Application
    Filed: April 6, 2004
    Publication date: November 18, 2004
    Inventors: Tadashi Dojo, Nene Shibayama, Yuichi Mizoo, Yusuke Hasegawa
  • Publication number: 20040219447
    Abstract: Development systems and methods for developing using magnetic toner are disclosed. The present invention further discloses developers used in development systems as well as the toner used in developer for magnetic ink character recognition printing. With respect to the development system, a development system is disclosed which includes a supply of dry developer mixture which contains magnetic toner particles and hard magnetic carrier particles. The development system further includes a non-magnetic, cylindrical shell for transporting the developer between the supply and the development zone, wherein the shell can be rotatable or stationary. A rotating magnetic core of a pre-selected magnetic field strength and means for rotating at least the magnetic core to provide for the transport of the toner particles from the shell to an electrostatic image also provided as part of the development system.
    Type: Application
    Filed: June 2, 2004
    Publication date: November 4, 2004
    Inventors: Thomas A. Jadwin, John F. Crichton, Robert D. Fields, Eric C. Stelter
  • Publication number: 20040219095
    Abstract: This invention relates to a process for producing magnetite particles having a coercivity of 6.366 kA/m to 10.345 kA/m (=80 to 130 Oe) and an octahedral particle shape, comprising heating an alkaline component and an iron(II) component in the form of an aqueous solution to a temperature of 50° C. to 100° C., whereby the molar ratio of iron(II) component to one equivalent of alkaline component is 0.38 to 0.45, and treating the suspension with an oxidizing agent at a rate of oxidation of 20 to 50 mol. % Fe(II)/h until the iron compound has an Fe(III) content of more than 65 mol. %, and then again adding an Fe(II) component in the form of an aqueous solution at a molar ratio of Fe(II) to one equivalent of total alkaline component used is 0.47 to 0.49, and treating the suspension with an oxidizing agent, at a rate of oxidation is 20 to 50 mol. % Fe(II)/h until the iron compound has an Fe(III) content of more than 65 mol.
    Type: Application
    Filed: June 9, 2004
    Publication date: November 4, 2004
    Inventor: Ulrich Meisen
  • Patent number: 6806010
    Abstract: The invention relates to a toner containing low-silicon magnetite particles.
    Type: Grant
    Filed: August 28, 2001
    Date of Patent: October 19, 2004
    Assignee: Bayer Aktiengesellschaft
    Inventor: Ulrich Meisen
  • Publication number: 20040191656
    Abstract: The toner for electrostatic charged image development of the present invention is characterized in that it contains at least a binder resin, a mold releasing agent and magnetic metal particles, and the solubility of the magnetic metal particles in a 1 mol/l aqueous HNO3 solution at 50° C. is 500 mg/g·l or less.
    Type: Application
    Filed: September 5, 2003
    Publication date: September 30, 2004
    Applicant: Fuji Xerox Co., Ltd.
    Inventors: Takao Ishiyama, Hiroshi Nakazawa, Shuji Sato, Yosuke Tsurumi, Yasuhiro Arima, Takashi Imai
  • Patent number: 6797448
    Abstract: Development systems and methods for developing using toner are disclosed. The present invention further discloses developers used in development systems. With respect to the development system, a development system is disclosed which includes a supply of dry developer mixture which contains toner particles and hard magnetic carrier particles. The development system further includes a non-magnetic, cylindrical shell for transporting the developer between the supply and the development zone, wherein the shell can be rotatable or stationary. A rotating magnetic core of a pre-selected magnetic field strength and means for rotating at least the magnetic core to provide for the transport of the toner particles from the shell to an electrostatic image also provided as part of the development system. The development system of the present invention further includes a fuser roll which is coated with a silicone rubber or other low surface energy elastomer or resin.
    Type: Grant
    Filed: May 3, 2002
    Date of Patent: September 28, 2004
    Assignee: Eastman Kodak Company
    Inventors: Robert D. Fields, Thomas J. Foster, Paul L. Nielsen, Thomas A. Jadwin, Dinesh Tyagi
  • Patent number: 6790575
    Abstract: A two component developer comprising a magnetic toner containing a binder resin and a magnetic particle, and a magnetic carrier containing a magnetic particle, wherein the magnetic toner has an average particle diameter of 4.0 to 10.0 &mgr;m, and contains 5 to 80 No. % of toner particles having particle diameter of 5 &mgr;m or less, and exhibits magnetization of 10 to 25 emu/g under magnetic field of 5 kiloersteds.
    Type: Grant
    Filed: March 21, 2002
    Date of Patent: September 14, 2004
    Assignee: Ricoh Company, Ltd.
    Inventors: Fumihiro Sasaki, Hiroaki Matsuda, Bing Shu, Maiko Kondo, Hiroshi Nakai, Hiroto Higuchi, Yasuaki Iwamoto, Yoshihiro Suguro, Hiroyuki Yoshikawa, Masahide Yamashita, Kazuyuki Yazaki
  • Patent number: 6780557
    Abstract: A toner comprising a resin binder comprising a crystalline resin having a ratio of a softening point to a maximal peak temperature of heat of fusion of 0.6 or more and less than 1.1, and an amorphous hybrid resin having a ratio of a softening point to a maximal peak temperature of heat of fusion of from 1.1 to 4.0; and a colorant, wherein the amorphous hybrid resin comprises two polymerization resin components each having an independent reaction path, said two polymerization resin components being partially chemically bonded to each other, wherein at least one polymerization resin component is the same as that of the crystalline resin, and wherein a weight ratio of the crystalline resin to the amorphous hybrid resin (crystalline resin/amorphous hybrid resin) is from 1/99 to 50/50. The toner can be used for developing electrostatic latent images formed in electrophotography, electrostatic recording method, electrostatic printing, and the like.
    Type: Grant
    Filed: September 27, 2002
    Date of Patent: August 24, 2004
    Assignee: Kao Corporation
    Inventors: Hiroyuki Kawaji, Tetsuya Ueno, Yasunori Inagaki
  • Patent number: 6766136
    Abstract: Development systems and methods for developing using magnetic toner are disclosed. The present invention further discloses developers used in development systems as well as the toner used in developer for magnetic ink character recognition printing. With respect to the development system, a development system is disclosed which includes a supply of dry developer mixture which contains magnetic toner particles and hard magnetic carrier particles. The development system further includes a non-magnetic, cylindrical shell for transporting the developer between the supply and the development zone, wherein the shell can be rotatable or stationary. A rotating magnetic core of a pre-selected magnetic field strength and means for rotating at least the magnetic core to provide for the transport of the toner particles from the shell to an electrostatic image also provided as part of the development system.
    Type: Grant
    Filed: March 31, 2003
    Date of Patent: July 20, 2004
    Assignee: Eastman Kodak Company
    Inventors: Thomas A. Jadwin, John F. Crichton, Robert D. Fields, Eric C. Stelter
  • Patent number: 6733940
    Abstract: The present invention provides a toner for MICR suitable for use in a printer for a non-magnetic monocomponent developing system, which does not produce scratches on a developing sleeve when used in the printer for the non-magnetic monocomponent developing system and has a resistance against sliding friction with a magnetic head, and also causes no reading errors because of a proper signal strength and imparts satisfactory image characteristics (for example, with respect to image density and fogging). The toner comprises a binder resin, a magnetic material and a wax, and has a BET specific surface area within a range from 0.70 to 1.00 m2/g.
    Type: Grant
    Filed: April 2, 2002
    Date of Patent: May 11, 2004
    Assignee: Tomoegawa Paper Co., Ltd.
    Inventors: Masamoto Terao, Akira Fujiwara
  • Publication number: 20040081905
    Abstract: A toner of the present invention comprises at least a binder resin comprising as a main component a polyester resin, a wax, and a colorant, in which in case of measuring a wettability of the toner with respect to a mixed solvent of methanol and water in terms of an optical transimittance at an optical wavelength of 780 nm, a methanol concentration of the mixed solvent is in a range of 45 to 65% by volume when an optical transmittance is 80% and 10%, respectively; a melt index (MI) is of 0.1 to 10 g/10 min at a temperature of 125° C.
    Type: Application
    Filed: September 25, 2003
    Publication date: April 29, 2004
    Inventors: Syuhei Moribe, Hiroshi Yusa, Takashige Kasuya, Yoshihiro Ogawa
  • Publication number: 20040081904
    Abstract: An electrostatic developing toner which can effectively suppress image fogging*1 by setting a ratio (d/D) of the average particle diameter D of the toner and the average particle diameter d of iron oxide particles contained in the toner as a colorant to within a predetermined range, and by setting the value of a ratio (&sgr;r/&sgr;s) between the residual magnetization rr and saturation magnetization &sgr;s of the iron oxide particles to a predetermined value or less, is provided. The value of the ratio (d/D) of the average particle diameter D of the toner and the average particle diameter d of iron oxide particles contained in the toner as a colorant is set to within the range of 0.01-0.03, and the value of the ratio (&sgr;r/&sgr;s) between the residual magnetization &sgr;r and saturation magnetization &sgr;s of the iron oxide particles is set to 0.3 or less.
    Type: Application
    Filed: September 22, 2003
    Publication date: April 29, 2004
    Applicant: BROTHER KOGYO KABUSHIKI KAISHA
    Inventors: Jun Ikami, Masateru Kawamura
  • Publication number: 20040053153
    Abstract: An electrophotographic toner for visualizing an electrostatic latent image formed by an electrophotographic process, an electrostatic printing process, an electrostatic recording process, etc., which is produced in consideration of the environment and safety. The electrophotographic toner includes a fixing resin and a colorant. The electrophotographic toner is a black toner using a titanium compound containing no carbon black as the colorant. The electrophotographic toner may be an electrophotographic two-component black toner using magnetic iron oxide containing no carbon black as the colorant.
    Type: Application
    Filed: September 11, 2003
    Publication date: March 18, 2004
    Applicant: Hitachi Printing Solutions, Ltd.
    Inventors: Shigenori Yaguchi, Ryuuichi Shimizu, Hiroshi Ueno
  • Patent number: 6703176
    Abstract: A toner contains at least a bonding resin and a coloring agent, and has a weight mean particle size from 5 &mgr;m to 12 &mgr;m; not less than 90% by number of particles not less than 3 &mgr;m have a circularity “a” not less than 0.900; a cut ratio Z and a weight mean size X of the toner are related as: cut ratio Z≦5.3×X; and a relationship of particles Y having a circularity of not less than 0.950 and a weight mean size X is Y≧e5.51×X−0.645 where X is 5 to 12 &mgr;m.
    Type: Grant
    Filed: May 23, 2002
    Date of Patent: March 9, 2004
    Assignee: Canon Kabushiki Kaisha
    Inventors: Takeshi Naka, Yuichi Mizoo, Satoshi Matsunaga, Masami Azuma, Takashige Kasuya, Tadashi Dojo, Tsuneo Nakanishi, Nene Shibayama, Katsuhisa Yamazaki, Yusuke Hasegawa
  • Publication number: 20040043317
    Abstract: An electrophotographic toner containing: a fixing resin, a colorant, and wax. The wax at least contains hydrocarbon wax having a number-average molecular weight of not higher than 600, and polyethylene wax having a number-average molecular weight of not higher than 600, a melting viscosity of lower than 15 mPa·s at 140° C. and a crystallinity of lower than 95%. A ratio of the hydrocarbon wax to the polyethylene wax is in a range of from 1:10 to 2:1. A maximum of absorption peaks in a heat-up time absorption calorie curve in a DSC curve of the toner measured by a differential scanning calorimeter is at a temperature not higher than 75° C. An onset temperature in absorption of heat is not higher than 65° C.
    Type: Application
    Filed: September 2, 2003
    Publication date: March 4, 2004
    Applicant: Hitachi Printing Solutions, Ltd.
    Inventors: Shigenori Yaguchi, Ryuuichi Shimizu, Junji Kobayashi, Tadahiro Kaneko, Nobuyoshi Hoshi, Tsuneaki Kawanishi
  • Publication number: 20040013962
    Abstract: A toner comprises toner particles comprising at least a binder resin, a colorant, and a sulfur-containing resin, in which the toner particles comprise the sulfur-containing resin so as to satisfy a relation of; 0.50≦IS/TS≦0.95 where TS denotes a content of sulfur in the toner particles, and IS denotes a content of sulfur in isopropyl alcohol insoluble components of the toner particles, whereby it is possible to obtain a high quality image having an excellent developing resistance regardless of the surrounding conditions and a uniform charge amount distribution regardless of processing speed.
    Type: Application
    Filed: May 14, 2003
    Publication date: January 22, 2004
    Inventors: Tadashi Doujo, Yuichi Mizoh, Nene Shibayama, Yusuke Hasegawa
  • Patent number: 6677092
    Abstract: A magnetic toner for MICR printers is provided with a binder resin, magnetic powder, and metal oxide particles which are in the outer surface of each toner base particle made from the binder resin and the magnetic powder, the metal oxide particles having a volume resistivity of 1×105 to 1×1011 &OHgr;·cm. A developer containing this MICR toner makes it possible to provide superior image density and reading precision, even after 150,000 to 300,000 sheets of A-4 paper have been continuously printed.
    Type: Grant
    Filed: April 23, 2001
    Date of Patent: January 13, 2004
    Assignee: Kyocera Corporation
    Inventor: Takaaki Arai
  • Patent number: 6653036
    Abstract: A magnetic toner includes a magnetic toner particle containing a binding resin and a magnetic material. The magnetic material includes a magnetic iron oxide containing 0.10% to 4.00% by weight of an element &agr; belonging to the third period to the seventh period with an atomic number of 11 to 103 and having an electronegativity of 1.0 to 2.5. The solubility S1 of &agr; in the magnetic material at an iron solubility of 0% to 20% is from 10% to less than 44% and the solubility S2 of &agr; at an iron solubility of 80% to 100% is from 5% to less than 30%. The magnetic material contains at least 60% by number of multinuclear magnetic iron oxide particles or at least 60% by number of polyhedral magnetic iron oxide particles having faces at ridgeline portions of hexahedron and/or octahedron multinuclear magnetic iron oxide particles.
    Type: Grant
    Filed: September 16, 1998
    Date of Patent: November 25, 2003
    Assignee: Canon Kabushiki Kaisha
    Inventors: Hirohide Tanikawa, Masami Fujimoto, Takakuni Kobori, Hiroyuki Fujikawa
  • Patent number: 6653035
    Abstract: A magnetic toner exhibiting stable performances under various environmental conditions is formed of toner particles each comprising at least a binder resin and iron oxide dispersed therein. Relative to the dry specific gravity (A) of the magnetic toner, the magnetic toner is characterized by a specific gravity distribution of toner particle fractions obtainable through wet sedimentation and including: at most 15 wt. % of a fraction having a specific gravity of above (A)×1.000 and at most (A)×1.025, 0.1-20 wt. % of a fraction having a specific gravity of above (A)×0.975 and at most (A)×1.000, at least 30 wt. % of a fraction having a specific gravity of above (A)×0.950 and at most (A)×0.975, 0.1-20 wt. % of a fraction having a specific gravity of above (A)×0.925 and at most (A)×0.950, and at most 15 wt. % of a fraction having a specific gravity of above (A)×0.900 and at most (A)×0.925.
    Type: Grant
    Filed: July 26, 2002
    Date of Patent: November 25, 2003
    Assignee: Canon Kabushiki Kaisha
    Inventors: Keiji Komoto, Tatsuya Nakamura, Tatsuhiko Chiba, Michihisa Magome, Akira Hashimoto, Takeshi Kaburagi, Eriko Yanase
  • Patent number: 6650858
    Abstract: A developing apparatus includes a first developing system for developing a latent image formed on an image bearing member with a first developer including magnetic toner. The first developing system includes a first developer carrying member for carrying and feeding the first developer to the image bearing member and a first magnetic field generating device disposed in the first developer carrying member. The developing apparatus further includes a second developing system develops a latent image formed on the image bearing member with a second developer including a magnetic carrier and non-magnetic toner while the developer contacts the image bearing member. The second developing system includes a second developer carrying member for carrying and feeding the developer to the image bearing member and a second magnetic field generating device disposed in the second developer carrying member. A magnetization intensity M&sgr; (Am2/kg) of the magnetic toner in an external magnetic field of 795.
    Type: Grant
    Filed: July 1, 2002
    Date of Patent: November 18, 2003
    Assignee: Canon Kabushiki Kaisha
    Inventor: Yuji Bessho
  • Patent number: 6638674
    Abstract: A magnetic toner is formed of magnetic toner particles each comprising a binder resin, an iron oxide, a sulfur-containing polymer, and inorganic fine powder blended with the magnetic toner particles, the toner having a weight-average particle size (D4) of 3-10 &mgr;m, and either (a) an average circularity of at least 0.970, and a magnetization of 10-50 Am2/kg (emu/g) at a magnetic field of 79.6 kA/m (1000 oersted), or (b) toner particles which retain carbon in an amount of A and iron in an amount of B at surfaces thereof, satisfying: B/A<0.001, and containing at least 50% by number of magnetic toner particles of D/C≦0.02, wherein C represents a particle projection area-equivalent circle diameter and D represents a minimum distance between a surface of the magnetic toner particle and iron oxide particles contained therein.
    Type: Grant
    Filed: July 25, 2001
    Date of Patent: October 28, 2003
    Assignee: Canon Kabushiki Kaisha
    Inventors: Keiji Komoto, Tsuyoshi Takiguchi, Tatsuhiko Chiba, Michihisa Magome, Akira Hashimoto, Takeshi Kaburagi, Eriko Yanase
  • Patent number: 6638675
    Abstract: Black magnetic toner comprising: a binder resin, and black magnetic composite particles comprising: magnetic iron oxide particles having an average particle diameter of 0.055 to 0.95 &mgr;m; a coating layer formed on the surface of said magnetic iron oxide particles, comprising at least one organosilicon compound selected from the group consisting of: (1) organosilane compounds obtainable from alkoxysilane compounds, (2) polysiloxanes or modified polysiloxanes, and (3) fluoroalkyl organosilane compounds obtainable from fluoroalkylsilane compounds; and a carbon black coat formed on said coating layer comprising said organosilicon compound, in an amount of 1 to 25 parts by weight based on 100 parts by weight of said magnetic iron oxide particles. Such a black magnetic toner can be free from being deteriorated in electric resistance due to the existence of the carbon black coat, and as a result, is suitable as a high-resistance or insulated magnetic toner.
    Type: Grant
    Filed: May 10, 2002
    Date of Patent: October 28, 2003
    Assignee: Toda Kogyo Corporation
    Inventors: Kazuyuki Hayashi, Hiroko Morii, Yasuyuki Tanaka, Seiji Ishitani
  • Publication number: 20030190541
    Abstract: Development systems and methods for developing using magnetic toner are disclosed. The present invention further discloses developers used in development systems as well as the toner used in developer for magnetic ink character recognition printing. With respect to the development system, a development system is disclosed which includes a supply of dry developer mixture which contains magnetic toner particles and hard magnetic carrier particles. The development system further includes a non-magnetic, cylindrical shell for transporting the developer between the supply and the development zone, wherein the shell can be rotatable or stationary. A rotating magnetic core of a pre-selected magnetic field strength and means for rotating at least the magnetic core to provide for the transport of the toner particles from the shell to an electrostatic image also provided as part of the development system.
    Type: Application
    Filed: March 31, 2003
    Publication date: October 9, 2003
    Inventors: Thomas A. Jadwin, John F. Crichton, Robert D. Fields, Eric C. Stelter
  • Patent number: 6630275
    Abstract: A magnetic toner is formed of magnetic toner particles each comprising at least a binder resin and a magnetic iron oxide. The magnetic toner is provided with improved developing performances by realizing an appropriate surface-exposure state of the magnetic iron oxide, which is represented by a wettability characteristic in methanol/water mixture liquids of the magnetic toner such that it shows a transmittance of 80% for light at a wavelength of 780 nm at a methanol concentration in a range of 65-75% and a transmittance of 20% at a methanol concentration in a range of 66-76%.
    Type: Grant
    Filed: March 13, 2002
    Date of Patent: October 7, 2003
    Assignee: Canon Kabushiki Kaisha
    Inventors: Kaori Hiratsuka, Hirohide Tanikawa, Tsutomu Onuma, Nobuyuki Okubo, Tsuneo Nakanishi
  • Publication number: 20030165758
    Abstract: A multi-layered toner comprises a core containing a first binder resin, and a covering layer containing a second binder resin having an acid value differing from that of the first binder resin. A magnetic powder is contained in at least one of the core and the covering layer.
    Type: Application
    Filed: February 28, 2002
    Publication date: September 4, 2003
    Applicant: TOSHIBA TEC KABUSHIKI KAISHA
    Inventor: Takashi Urabe
  • Patent number: 6610451
    Abstract: Development systems and methods for developing using magnetic toner are disclosed. The present invention further discloses developers used in development systems as well as the toner used in developer for magnetic ink character recognition printing. With respect to the development system, a development system is disclosed which includes a supply of dry developer mixture which contains magnetic toner particles and hard magnetic carrier particles. The development system further includes a non-magnetic, cylindrical shell for transporting the developer between the supply and the development zone, wherein the shell can be rotatable or stationary. A rotating magnetic core of a pre-selected magnetic field strength and means for rotating at least the magnetic core to provide for the transport of the toner particles from the shell to an electrostatic image also provided as part of the development system.
    Type: Grant
    Filed: December 26, 2000
    Date of Patent: August 26, 2003
    Assignee: Heidelberger Druckmaschinen AG
    Inventors: Thomas A. Jadwin, John F. Crichton, Robert D. Fields, Eric C. Stelter
  • Patent number: 6593048
    Abstract: A two-component developer includes at least a magnetic toner and a magnetic carrier. The magnetic toner has magnetic particles coated with a carbon black layer. The magnetic toner adheres to the magnetic carrier due to the magnetic interaction.
    Type: Grant
    Filed: October 22, 2001
    Date of Patent: July 15, 2003
    Assignee: Ricoh Company, Ltd.
    Inventors: Fumihiro Sasaki, Yasuaki Iwamoto, Hiroaki Matsuda, Hiroshi Nakai, Hiroto Higuchi, Hyou Shu, Maiko Kondo
  • Publication number: 20030096184
    Abstract: A toner comprising a resin binder comprising a crystalline resin having a ratio of a softening point to a maximal peak temperature of heat of fusion of 0.6 or more and less than 1.1, and an amorphous hybrid resin having a ratio of a softening point to a maximal peak temperature of heat of fusion of from 1.1 to 4.0; and a colorant, wherein the amorphous hybrid resin comprises two polymerization resin components each having an independent reaction path, said two polymerization resin components being partially chemically bonded to each other, wherein at least one polymerization resin component is the same as that of the crystalline resin, and wherein a weight ratio of the crystalline resin to the amorphous hybrid resin (crystalline resin/amorphous hybrid resin) is from 1/99 to 50/50. The toner can be used for developing electrostatic latent images formed in electrophotography, electrostatic recording method, electrostatic printing, and the like.
    Type: Application
    Filed: September 27, 2002
    Publication date: May 22, 2003
    Inventors: Hiroyuki Kawaji, Tetsuya Ueno, Yasunori Inagaki
  • Publication number: 20030091918
    Abstract: A magnetic toner with a negative polarity for developing latent electrostatic images is made of toner particles, each toner particle containing a binder resin, a magnetic powder, and a charge control agent, the surface of the magnetic toner satisfying the relationship of 2×10−7≦C/Sw≦10×10−7, provided C≦8×10−3, wherein C is an amount (g/g) of the charge control agent dissolved in a solvent comprising water and methanol, and Sw is a specific surface area (cm2/cm3) of the toner particles determined from a weight-average particle diameter of the toner particles. An image forming apparatus has an electrostatic image bearing member, and a unit for developing the electrostatic image with the above magnetic toner, the unit having a developer holding member provided with a magnet, and a developer container.
    Type: Application
    Filed: September 20, 2002
    Publication date: May 15, 2003
    Inventors: Osamu Uchinokura, Tomio Kondou
  • Patent number: 6562532
    Abstract: Black magnetic toner comprising: a binder resin; and black magnetic composite particles having an average particle diameter of 0.06 to 1.0 &mgr;m comprising: magnetic iron oxide particles, a coating layer formed on the surface of the magnetic iron oxide particles, comprising at least one organosilicon compound selected from the group consisting of: (1) organosilane compounds obtainable from alkoxysilane compounds, and (2) polysiloxanes or modified polysiloxanes, and a single carbon black coat formed on the coating layer comprising the organosilicon compound, in an amount of 26 to 55 parts by weight based on 100 parts by weight of the magnetic iron oxide particles.
    Type: Grant
    Filed: February 12, 2002
    Date of Patent: May 13, 2003
    Assignee: Toda Kogyo Corporation
    Inventors: Kazuyuki Hayashi, Hiroko Morii, Yasuyuki Tanaka, Seiji Ishitani
  • Publication number: 20030073021
    Abstract: A two component developer comprising a magnetic toner containing a binder resin and a magnetic particle, and a magnetic carrier containing a magnetic particle, wherein the magnetic toner has an average particle diameter of 4.0 to 10.0 &mgr;m, and contains 5 to 80 No. % of toner particles having particle diameter of 5 &mgr;m or less, and exhibits magnetization of 10 to 25 emu/g under magnetic field of 5 kiloersteds.
    Type: Application
    Filed: March 21, 2002
    Publication date: April 17, 2003
    Inventors: Fumihiro Sasaki, Hiraoki Matsuda, Bing Shu, Maiko Kondo, Hiroshi Nakai, Hiroto Higuchi, Yasuaki Iwamoto, Yoshihiro Suguro, Hiroyuki Yoshikawa, Masahide Yamashita, Kazuyuki Yazaki
  • Publication number: 20030073016
    Abstract: Black magnetic toner comprising:
    Type: Application
    Filed: May 10, 2002
    Publication date: April 17, 2003
    Applicant: Toda Kogyo Corp.
    Inventors: Kazuyuki Hayashi, Hiroko Morll, Yasuyuki Tanaka, Seiji Ishitani
  • Publication number: 20030064309
    Abstract: A magnetic toner exhibiting stable performances under various environmental conditions is formed of toner particles each comprising at least a binder resin and iron oxide dispersed therein. Relative to the dry specific gravity (A) of the magnetic toner, the magnetic toner is characterized by a specific gravity distribution of toner particle fractions obtainable through wet sedimentation and including: at most 15 wt. % of a fraction having a specific gravity of above (A)×1.000 and at most (A)×1.025, 0.1-20 wt. % of a fraction having a specific gravity of above (A)×0.975 and at most (A)×1.000, at least 30 wt. % of a fraction having a specific gravity of above (A)×0.950 and at most (A)×0.975, 0.1-20 wt. % of a fraction having a specific gravity of above (A)×0.925 and at most (A)×0.950, and at most 15 wt. % of a fraction having a specific gravity of above (A)×0.900 and at most (A)×0.925.
    Type: Application
    Filed: July 26, 2002
    Publication date: April 3, 2003
    Inventors: Keiji Komoto, Tatsuya Nakamura, Tatsuhiko Chiba, Michihisa Magome, Akira Hashimoto, Takeshi Kaburagi, Eriko Yanase
  • Patent number: 6537716
    Abstract: A toner for developing electrostatic images is comprised of a binder resin and a wax. The binder resin contains as a primary component a polyester resin having a soft segment. The wax has, in its endothermic peaks at the time of temperature rise and exothermic peaks at the time of temperature drop in the DSC curve measured using a differential scanning calorimeter; (i) an endothermic onset temperature within the range of from 50° C. to 110° C.; (ii) at least one endothermic peak P1 within the range of from 70° C. to 130° C. at the time of temperature rise; and (iii) a maximum exothermic peak at the time of temperature drop, within the range of plus-minus 9° C. of the endothermic peak P1.
    Type: Grant
    Filed: December 4, 1996
    Date of Patent: March 25, 2003
    Assignee: Canon Kabushiki Kaisha
    Inventors: Shinji Doi, Hirohide Tanikawa, Hiroaki Kawakami, Masatsugu Fujiwara, Tsutomu Onuma
  • Publication number: 20030054275
    Abstract: A magnetic toner contains, as a magnetic powder, magnetic iron oxide having an octahedral particle shape and an average particle diameter of 0.21 &mgr;m or larger and containing 18% or more by weight of FeO. The magnetic toner is so prepared as to have a bulk density A (g/cm3) and a magnetic powder content B (% by weight) that fulfill the formulae 0.8≦A/B×100≦1.6 and 35≦B≦50. This alleviates the reddishness of images produced with the magnetic toner, and alleviates the disturbance of a thin toner layer on a developing sleeve and thus the fogging resulting therefrom.
    Type: Application
    Filed: August 15, 2002
    Publication date: March 20, 2003
    Inventors: Hiroko Sugimoto, Takashi Nagai, Toru Takatsuna, Seiji Kikushima
  • Publication number: 20030054278
    Abstract: A toner contains at least a bonding resin and a coloring agent, and has the following characteristics (i) to (iv):
    Type: Application
    Filed: May 23, 2002
    Publication date: March 20, 2003
    Inventors: Takeshi Naka, Yuichi Mizoo, Satoshi Matsunaga, Masami Azuma, Takashige Kasuya, Tadashi Dojo, Tsuneo Nakanishi, Nene Shibayama, Katsuhisa Yamazaki, Yusuke Hasegawa