Organic Fluorine Compound Adjuvant Containing Either Nitrogen Or Phosphorus Patents (Class 430/108.15)
  • Patent number: 10353309
    Abstract: Provided is an electrostatic image developing toner comprising a toner base particle containing a binder resin and a releasing agent, wherein the binder resin comprises an amorphous vinyl resin and a crystalline polyester resin; a weight-average molecular weight of the electrostatic image developing toner is in the range of 50000 to 90000, when calculated from a chromatogram which represents a molecular weight distribution and is measured by gel permeation chromatography; a ratio of content of a resin component having a molecular weight of 100000 or more is in the range of 10 to 20% by area, in the chromatogram which represents the molecular weight distribution; the crystalline polyester resin has a melting point in the range of 65 to 85° C.; and, a ratio of content of the crystalline polyester resin in the binder resin is in the range of 5 to 20% by mass.
    Type: Grant
    Filed: September 17, 2018
    Date of Patent: July 16, 2019
    Assignee: KONICA MINOLTA, INC.
    Inventors: Kouji Sugama, Hiroshi Nagasawa, Anju Hori, Noboru Ueda
  • Patent number: 10146146
    Abstract: A toner comprising a toner particle containing a binder resin, a wax, and inorganic fine particles, wherein the binder resin contains a crystalline polyester resin and an amorphous polyester resin, and, in a cross section of the toner particle, when Sc represents an area taken up by the crystalline polyester resin and S1 represents an area taken up by the inorganic fine particles that are present in the crystalline polyester resin portion, Sc and S1 satisfy the relationship S1/Sc?0.2.
    Type: Grant
    Filed: April 24, 2017
    Date of Patent: December 4, 2018
    Assignee: CANON KABUSHIKI KAISHA
    Inventors: Nozomu Komatsu, Takeshi Hashimoto, Masayuki Hama, Takakuni Kobori, Ichiro Kanno, Yuto Onozaki, Hitoshi Sano, Akifumi Matsubara, Hiroyuki Fujikawa, Tsubasa Fujisaki
  • Patent number: 10133200
    Abstract: Provided is an electrostatic image developing toner comprising a toner base particle containing a binder resin and a releasing agent, wherein the binder resin comprises an amorphous vinyl resin and a crystalline polyester resin; a weight-average molecular weight of the electrostatic image developing toner is in the range of 50000 to 90000, when calculated from a chromatogram which represents a molecular weight distribution and is measured by gel permeation chromatography; a ratio of content of a resin component having a molecular weight of 100000 or more is in the range of 10 to 20% by area, in the chromatogram which represents the molecular weight distribution; the crystalline polyester resin has a melting point in the range of 65 to 85° C.; and, a ratio of content of the crystalline polyester resin in the binder resin is in the range of 5 to 20% by mass.
    Type: Grant
    Filed: June 1, 2016
    Date of Patent: November 20, 2018
    Assignee: KONICA MINOLTA, INC.
    Inventors: Kouji Sugama, Hiroshi Nagasawa, Anju Hori, Noboru Ueda
  • Patent number: 10088766
    Abstract: A layered inorganic mineral including a surface treated with a fluorine-containing compound, where the layered inoganic mineral that can be favorably used for a toner that is excellent in high charging ability, charging stability, and low temperature fixing ability, and that can exhibits high reliability during cleaning.
    Type: Grant
    Filed: November 30, 2015
    Date of Patent: October 2, 2018
    Assignee: Ricoh Company, Ltd.
    Inventors: Hideyuki Santo, Tsuyoshi Sugimoto, Shinya Nakayama, Suzuka Amemori, Hiroshi Yamada, Ryuta Chiba, Kohsuke Nagata
  • Patent number: 9785072
    Abstract: An electrophotographic toner which is excellent in grindability, fixing property and durability by being obtained via a step of melt-kneading a mixture containing an amorphous bioplastic having a weight-average molecular weight (Mw) of 55000 to 120000, a terpene phenol resin, and a styrene acrylic resin having a weight-average molecular weight (Mw) of 85500 to 118000 so as to obtain a kneaded mixture, and a step of grinding the kneaded mixture after hardening.
    Type: Grant
    Filed: March 20, 2015
    Date of Patent: October 10, 2017
    Assignee: CASIO COMPUTER CO., LTD.
    Inventors: Kenji Kihira, Hideki Ikeda, Yuichiro Iegaki, Yuta Kan, Hideki Hasegawa
  • Publication number: 20150030976
    Abstract: A black toner for developing a latent electrostatic image, including: a toner base containing a pigment, a binder resin, a releasing agent, a compound containing fluorine and a compound containing sulfur; and an external additive, wherein the toner contains the external additive on a surface of the toner base, and wherein an amount of the fluorine in the toner base is 200 ppm by mass to 600 ppm by mass as measured by combustion-ion chromatography, and an amount of the sulfur in the toner base is 1,000 ppm by mass to 1,500 ppm by mass as measured by the combustion-ion chromatography.
    Type: Application
    Filed: February 28, 2013
    Publication date: January 29, 2015
    Inventors: Kei Yokokawa, Yasuaki Iwamoto, Takahiro Kadota
  • Patent number: 8568947
    Abstract: Disclosed is a green toner for developing a static latent image containing a binder resin and a colorant, and the colorant contains C.I. Solvent Green 5 and colorant compound X represented by Formula (1), and content ratio of C.I. Solvent Green 5 in whole amount of the colorant is 5 to 50% by weight, in the Formula (1), M1 is a metal atom of Group 14, Q is independently a monovalent substituent, m and n are each 0 or 1, at least one of m and n is 1, and A is independently an atomic group forming an aromatic ring which may have a substituent.
    Type: Grant
    Filed: February 13, 2012
    Date of Patent: October 29, 2013
    Assignee: Konica Minolta Business Technologies, Inc.
    Inventors: Yohei Ohno, Hajime Tadokoro, Kaori Matsushima, Hiroyuki Yasukawa, Ito Koga
  • Publication number: 20130177843
    Abstract: The present invention provides a charge control agent containing, as an active substance(s), one or two or more thiazolidinedione derivatives represented by the following formula (1), where R1 represents a hydrogen atom, etc.; R2 represents a hydrogen atom, a linear or branched alkyl group having 1 to 8 carbon atoms which may have a substituent, etc.; R3 to R7, which may be identical to or different from each other, represent a hydrogen atom, a chlorine atom, a linear or branched alkyl group having 1 to 8 carbon atoms which may have a substituent, etc., and may be joined to each other to form a ring; and V, W, X, Y and Z represent a carbon atom or a nitrogen atom, and 0 to 3 of any of V, W, X, Y and Z are nitrogen atoms which do not have the substituents of R3 to R7.
    Type: Application
    Filed: September 1, 2011
    Publication date: July 11, 2013
    Applicant: HODOGAYA CHEMICAL CO., LTD.
    Inventors: Ikuo Kimura, Motonori Tsuji, Masami Ito, Masaya Tojo, Kanae Hiraishi
  • Publication number: 20130177844
    Abstract: The present invention provides a positive-charge control agent containing, as an active substance(s), one or two or more rhodanine compounds represented by the following formula (1). wherein R1 represents a hydrogen atom, etc.; R2 represents a hydrogen atom, etc.; and R3 to R7, which may be identical to or different from each other, represent a hydrogen atom, a cyano group, a trifluoromethyl group, a nitro group, etc. R2 to R7 may be joined to each other to form a ring. V, W, X, Y and Z represent a carbon atom or a nitrogen atom and 0 to 3 of V, W, X, Y and Z are nitrogen atoms, with the proviso that at least one of R3 to R7 is a linear or branched alkyl group having 1 to 4 carbon atoms substituted with three or more fluorine atoms etc.
    Type: Application
    Filed: November 22, 2011
    Publication date: July 11, 2013
    Applicant: HODOGAYA CHEMICAL CO., LTD.
    Inventors: Masateru Yasumura, Masami Ito, Ikuo Kimura, Masaya Tojo, Kanae Hiraishi, Masaki Okubo
  • Publication number: 20130157190
    Abstract: [Problems] To provide a charge control agent which contains no heavy metal component, therefore, does not adversely affect the environment and, besides, is colorless or is light-colored lending itself well to be applied to colored toners, and is little affected by the environmental conditions, and exhibits the effect of imparting high charging power even when it is used for polymerized toners. [Means for Solution] The charge control agent comprises a barbituric acid derivative represented by the following general formula (1): wherein R1 to R8 are alkyl groups, cycloalkyl groups or aryl groups, V, W, X, Y and Z are carbon atoms or nitrogen atoms, at least two of which being carbon atoms, and p, q, r, s and t are the numbers of 0 or 1.
    Type: Application
    Filed: September 2, 2011
    Publication date: June 20, 2013
    Applicant: HODOGAYA CHEMICAL CO., LTD.
    Inventors: Ikuo Kimura, Masami Ito, Masaya Tojou, Kanae Hiraishi, Masafumi Asakai
  • Publication number: 20120322002
    Abstract: The invention provides a toner composition comprising resin particles, a colorant, and a toner additive, wherein the toner additive comprises carbon-silica dual phase particles, wherein the carbon-silica dual phase particles comprise aggregates of carbon black comprising at least one silicon-containing region, and wherein the carbon-silica dual phase particles are distributed on the surface of the resin particles. The invention also provides a method of preparing the aforesaid toner composition.
    Type: Application
    Filed: June 16, 2011
    Publication date: December 20, 2012
    Inventors: Hairuo Tu, Dmitry Fomitchev, Jinsong Liu, Zhifeng Li, James Boswell
  • Publication number: 20120315576
    Abstract: The present invention provides a charge control agent containing, as an active substance(s), one or two or more rhodanine compounds represented by the following formula (1). where R1 represents a hydrogen atom, etc.; R2 represents a hydrogen atom, a linear or branched alkyl group having 1 to 8 carbon atoms which may have a substituent, a substituted or unsubstituted heterocyclic group, etc.; R3 to R7, which may be identical to or different from each other, represent a hydrogen atom, a linear or branched alkyl group having 1 to 10 carbon atoms which may have a substituent, a linear or branched alkyloxy group having 1 to 20 carbon atoms which may have a substituent, etc., and may be joined to each other to form a ring; and V, W, X, Y and Z represent a carbon atom or a nitrogen atom, and 0 to 3 of any of V, W, X, Y and Z are nitrogen atoms which do not have the substituents of R3 to R7.
    Type: Application
    Filed: February 21, 2011
    Publication date: December 13, 2012
    Applicant: HODOGAYA CHEMICAL CO., LTD.
    Inventors: Masateru Yasumura, Masami Ito, Masaya Tojo, Kanae Hiraishi, Masaki Okubo, Hideyuki Otsuka
  • Patent number: 8329368
    Abstract: An electrophotographic toner is disclosed. The toner contains a compound of Formula X-1 and a copper complex compound represented by the following Formula (1), which are defined detain in the specification.
    Type: Grant
    Filed: March 11, 2009
    Date of Patent: December 11, 2012
    Assignee: Konica Minolta Business Technologies, Inc.
    Inventors: Koji Daifuku, Ryohei Iwamoto, Keiko Ishidai, Kimihiko Ookubo, Kaori Ono, Issei Nakahara
  • Publication number: 20120219892
    Abstract: Disclosed is a green toner for developing a static latent image containing a binder resin and a colorant, and the colorant contains C.I. Solvent Green 5 and colorant compound X represented by Formula (1), and content ratio of C.I. Solvent Green 5 in whole amount of the colorant is 5 to 50% by weight, in the Formula (1), M1 is a metal atom of Group 14, Q is independently a monovalent substituent, m and n are each 0 or 1, at least one of m and n is 1, and A is independently an atomic group forming an aromatic ring which may have a substituent.
    Type: Application
    Filed: February 13, 2012
    Publication date: August 30, 2012
    Applicant: KONICA MINOLTA BUSINESS TECHNOLOGIES, INC.
    Inventors: Yohei OHNO, Hajime TADOKORO, Kaori MATSUSHIMA, Hiroyuki YASUKAWA, Ito KOGA
  • Publication number: 20120045718
    Abstract: Disclosed is a cyan toner for developing an electrostatic image containing a cyan colorant, and the cyan colorant comprises colorant compound X represented by Formula (1) and colorant compound Y represented by Formula (2). wherein M1 is a metal atom of Group 14, Q is independently a monovalent substituent, m and n are each 0 or 1, at least one of m and n is 1, and A is independently an atomic group forming an aromatic ring which may have a substituent, wherein, M2 is Zn or Al, and A is independently an atomic group forming an aromatic ring which may have a substituent.
    Type: Application
    Filed: July 29, 2011
    Publication date: February 23, 2012
    Applicant: KONICA MINOLTA BUSINESS TECHNOLOGIES, INC.
    Inventors: Hiroyuki YASUKAWA, Hajime TADOKORO, Kaori MATSUSHIMA, Ito KOGA, Yohei OHNO
  • Patent number: 7943279
    Abstract: A copper complex compound represented by Formula (1) is disclosed. in the formula, groups represented by R is a substituent, n is an integer of from 1 to 5 and the total carbon number contained in (R) n is 14 or more. A toner for electrophotography containing the compound is also disclosed.
    Type: Grant
    Filed: March 11, 2009
    Date of Patent: May 17, 2011
    Assignee: Konica Minolta Business Technologies, Inc.
    Inventors: Koji Daifuku, Ryohei Iwamoto, Keiko Ishidai, Kimihiko Ookubo, Kaori Ono, Issei Nakahara
  • Publication number: 20110086302
    Abstract: An emulsion aggregation toner composition includes toner particles including: an unsaturated polymeric resin, such as amorphous resins, crystalline resins, and combinations thereof; an optional colorant; an optional wax; an optional coagulant; and an IR absorber. The use of an IR absorber may permit formation of color toners that have uniform gloss and crease properties, i.e., the IR absorbers may prevent gloss and crease differences between color and black toners.
    Type: Application
    Filed: October 9, 2009
    Publication date: April 14, 2011
    Applicant: XEROX CORPORATION
    Inventors: Ke Zhou, Edward Graham Zwartz, Karen Ann Moffat, Guerino G. Sacripante, T. Brian McAneney, Jordan H. Wosnick, Valerie M. Farrugia
  • Publication number: 20100183967
    Abstract: A toner including a binder resin comprising a resin (a) comprising a polyhydroxycarboxylic acid skeleton formed from an optically-active monomer. The polyhydroxycarboxylic acid skeleton has a weight average molecular weight of from 7,000 to 60,000. The binder resin comprises the polyhydroxycarboxylic acid skeleton in an amount of from 10 to 90% by weight. The optical purity X (%) of the polyhydroxycarboxylic acid skeleton represented by the following formula is 80% or less: X(%)=|X(L-isomer)?X(D-isomer)| wherein X(L-isomer) and X(D-isomer) represent molar ratio (%) of L-isomer and D-isomer of the optically-active monomer, respectively.
    Type: Application
    Filed: December 30, 2009
    Publication date: July 22, 2010
    Inventors: Akiyoshi Sabu, Akihiro Kotsugai, Ryota Inoue, Keiko Osaka, Shingo Sakashita, Yukiko Nakajima, Satoshi Mochizuki
  • Patent number: 7745084
    Abstract: A toner including a binder resin and a colorant, wherein a pellet of the toner which is prepared by applying a pressure of 15 kg/cm2 to the toner has a tensile strength of from 900 Pa to 10,000 Pa, and wherein the toner has a methanol wettability of from 25 to 65% by volume, wherein the methanol wettability is measured by a method in which the toner is dispersed in a mixture solvent of water and methanol, and methanol is added to the toner dispersion while checking the transparency of the dispersion to determine a transparency fall starting point, wherein the methanol wettability is defined as {Vm/(Vm+Vw)}×100, wherein Vm represents a total volume (ml) of methanol in the dispersion at the transparency dropping point, and Vw represents the total volume of the pure water added.
    Type: Grant
    Filed: July 21, 2005
    Date of Patent: June 29, 2010
    Assignee: Ricoh Company Limited
    Inventors: Hideki Sugiura, Hitoshi Iwatsuki
  • Publication number: 20090233208
    Abstract: A copper complex compound represented by Formula (1) is disclosed. in the formula, groups represented by R is a substituent, n is an integer of from 1 to 5 and the total carbon number contained in (R) n is 14 or more. A toner for electrophotography containing the compound is also disclosed.
    Type: Application
    Filed: March 11, 2009
    Publication date: September 17, 2009
    Applicant: KONICA MINOLTA BUSINESS TECHNOLOGIES, INC.
    Inventors: Koji DAIFUKU, Ryohei IWAMOTO, Keiko ISHIDAI, Kimihiko OOKUBO, Kaori ONO, Issei NAKAHARA
  • Publication number: 20090123861
    Abstract: An electrophotographic toner containing a resin and a colorant is disclosed. The colorant is represented by the formula in the formula, M1 is a silicon atom (Si), a germanium atom (Ge) and a tin atom (Sn); Z is independently a chlorine atom, a hydroxy group, an alkoxy group having 1 to 8 carbon atoms, or an aryloxy group having 6 to 8 carbon atoms; and A1, A2, A3 and A4 are each independently an atomic group defined in the specification.
    Type: Application
    Filed: November 7, 2008
    Publication date: May 14, 2009
    Applicant: KONICA MINOLTA BUSINESS TECHNOLOGIES, INC.
    Inventors: Mikio Kouyama, Kenji Hayashi, Tomoko Sakimura, Hiroyuki Yasukawa, Hiroaki Obata, Natsuko Kusaka
  • Patent number: 7442481
    Abstract: A composition comprising a toner binder and a charge control agent comprising a sulfonation product of Solvent Blue 23, wherein from greater than 0 up to 30 mole % of the Solvent Blue 23 is sulfonated.
    Type: Grant
    Filed: April 27, 2004
    Date of Patent: October 28, 2008
    Assignees: XSYS Print Solutions US LLC, Morimura Chemicals Ltd
    Inventors: Gary Don Ellis, Rhonda Sue Bartram, Edward William da Ponte, Toshihiko Oguchi, Timothy Alan Overway, Keiki Suganami
  • Publication number: 20080227013
    Abstract: A toner including a fluorine-containing compound partially comprising a quaternary ammonium group at the surface thereof, which is prepared by a method, including dispersing or emulsifying an oil phase including toner constituents including a pigment, and at least one member selected from the group consisting of modified layered inorganic minerals partially including a quaternary alkylammonium group and toner constituent precursors in an aqueous medium, wherein the toner constituents includes the modified layered inorganic mineral in an amount of from 0.05 to 2% by weight and the toner includes a fluorine atom in an amount of from 0.02 to 0.075 K cps when measured with a fluorescent X-ray.
    Type: Application
    Filed: February 22, 2008
    Publication date: September 18, 2008
    Inventors: Takuya KADOTA, Chiyoshi Nozaki, Katsunori Kurose, Tsuyoshi Nozaki, Hiroyuki Murakami, Mitsuyo Matsumoto, Yoshimichi Ishikawa, Atsushi Yamamoto
  • Patent number: 7416601
    Abstract: Black perylene pigments which comprise one of the isomers of the formula Ia or Ib in which R1, R2 are each independently phenylene, naphthylene or pyridylene, each of which may be mono- or polysubstituted by C1-C12-alkyl, C1-C6-alkoxy, hydroxyl, nitro, and/or halogen; X is halogen; n Is from 0 to 4, or comprises a mixture of both isomers and has a blackness value ?210 in an alkyd/melamine baking varnish.
    Type: Grant
    Filed: February 4, 2005
    Date of Patent: August 26, 2008
    Assignee: BASF Aktiengesellschaft
    Inventors: Peter Erk, Andreas Stohr, Arno Boehm, Walter Kurtz, Jin Mizuguchi, Benno Sens
  • Patent number: 7261989
    Abstract: The object of the present invention is to provide a toner which has sufficiently high chargeability and less toner spent to a carrier or the like even when several tens of thousands of image sheets are output, is capable of keeping high-charge property and flowability without causing substantial background smear or toner fogging, excels in low-temperature fixing property and hot-offset property, and has a wide range of fixing temperature as well as to provide a developer, an image forming apparatus, a process cartridge, and an image forming method using the toner for developing electrostatic images. The toner of the present invention comprises a colorant, and a resin, and a fluoride compound, in which the fluoride compound exists on the surfaces of toner particles, and the atomic number ratio (F/C) of fluoride atoms to carbon atoms existing on the surfaces of the toner particles is 0.010 to 0.054.
    Type: Grant
    Filed: April 10, 2006
    Date of Patent: August 28, 2007
    Assignee: Ricoh Company, Ltd.
    Inventors: Hideki Sugiura, Satoshi Mochizuki, Yasuaki Iwamoto, Yasuo Asahina, Hisashi Nakajima, Tomoyuki Ichikawa, Shinya Nakayama, Masayuki Ishii, Tomoko Utsumi, Koichi Sakata
  • Patent number: 7198874
    Abstract: The present invention relates to a toner useful, for example, for visualizing an electrostatic latent image formed on an image bearing member by a method such as electrophotography and electrostatic recording methods.
    Type: Grant
    Filed: April 4, 2006
    Date of Patent: April 3, 2007
    Assignee: Ricoh Company, Ltd.,
    Inventors: Takuya Saito, Hiroshi Yamashita, Yohichiroh Watanabe, Tsunemi Sugiyama
  • Patent number: 7083888
    Abstract: An external additive for electrostatically charged image developing toner is provided. The additive includes spherical hydrophobic fine silica particles having primary particles with a particle diameter of from 0.01 to 5 ?m and having been treated with a compound selected from the group consisting of a quaternary ammonium salt compound, a fluoroalkyl-group- or fluoroalkenyl-group- containing betaine compound and a silicone oil. The fine silica particles fulfill conditions (i) and (ii), as described in the disclosure. The external additive does not react or has no interaction with an organic photoreceptor and therefore change in quality does not occur or the photoreceptor is not scraped. Furthermore, it has a good flowability and therefore adhesion of a toner to the photoreceptor does not occur.
    Type: Grant
    Filed: September 6, 2001
    Date of Patent: August 1, 2006
    Assignee: Shin-Etsu Chemical Co., Ltd.
    Inventors: Muneo Kudo, Masaki Tanaka
  • Patent number: 7074535
    Abstract: The present invention relates to a toner useful, for example, for visualizing an electrostatic latent image formed on an image bearing member by a method such as electrophotography and electrostatic recording methods. In addition, the present invention also relates, without limitation, to a developer including a toner, a developing method using a toner and a method of preparing the toner.
    Type: Grant
    Filed: March 18, 2004
    Date of Patent: July 11, 2006
    Assignee: Ricoh Company, Ltd.
    Inventors: Takuya Saito, Hiroshi Yamashita, Yohichiroh Watanabe, Tsunemi Sugiyama
  • Patent number: 6620568
    Abstract: The present invention discloses a flash fixing color toner for use in an image forming process, which comprises a binder resin, a coloring agent, and an infrared absorbent, wherein negative ions form part of the infrared absorbent, and the negative ions include toluenesulfonic acid ion (C6H4(CH3)SO3−), nitric acid ion (NO3−) or hexafluorophosphoric acid ion (PF6−). Further, the present invention discloses an image forming process, which is characterized by using the flash fixing color toner.
    Type: Grant
    Filed: June 6, 2001
    Date of Patent: September 16, 2003
    Assignee: Fuji Xerox Co., Ltd.
    Inventors: Yasushige Nakamura, Shinichi Yaoi
  • Publication number: 20030129516
    Abstract: In a color toner for forming an image, comprising at least a binder resin and a colorant, light-absorbing fine composite particles comprising core particles and at least two coating layers having different refractive indexes laminated on the surface of the core particles or other IR-absorbing compounds such as an azulene compound having a specific structure are used as an infrared absorbing compound. The color toner is used in an electrophotographic color image forming apparatus using a photofixing system for fixing a toner image.
    Type: Application
    Filed: March 27, 2002
    Publication date: July 10, 2003
    Applicant: Fujitsu Limited
    Inventors: Yasushige Nakamura, Shinichi Yaoi, Tomoaki Tanaka, Yoshimichi Katagiri, Seijiro Ishimaru, Satoshi Takezawa, Sadaaki Yoshida