As A Nitrogen- Or Phosphorus-containing Polymer Patents (Class 430/108.22)
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Patent number: 11934147Abstract: A toner comprising a toner particle comprising a binder resin and organosilicon polymer particles on a surface of the toner particle, wherein the binder resin comprising an amorphous resin and a crystalline polyester resin, an absolute value |SPcpes?SPsi| of a difference between an SP value (SPsi) of the organosilicon polymer particles and an SP value (SPcpes) of the crystalline polyester resin is not more than 2.00 (cal/cm3)1/2, and an amount of adsorbed water in the organosilicon polymer particles at a temperature of 30° C. and a humidity of 80% RH is not more than 20 mg/g.Type: GrantFiled: March 9, 2021Date of Patent: March 19, 2024Assignee: CANON KABUSHIKI KAISHAInventors: Yasuhiro Hashimoto, Koji Nishikawa, Yuujirou Nagashima, Tomoya Nagaoka
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Patent number: 11745148Abstract: The invention relates to membranes, monomers and polymers. The monomers can form polymers, which can be used for membranes. The membranes can be used in alkaline fuel cells, for water purification, for electrolysis, for flow batteries, and for anti-bacterial membranes and materials, as well as membrane electrode assemblies for fuel cells. In addition to the membranes, polymers and monomers and methods of using the membranes, the present invention also relates to methods of making the membranes, monomers and polymers.Type: GrantFiled: February 19, 2021Date of Patent: September 5, 2023Assignee: Colorado School of MinesInventors: Daniel M. Knauss, Derek J. Strasser
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Patent number: 11550235Abstract: An electrostatic image developing toner includes toner particles, an external additive A, and an external additive B. At least the external additive A is deposited on the surfaces of the toner particles. At least the external additive B is deposited on the external additive A. The external additive B includes an aggregate of two or more particles. The coverage of the toner particles with the external additive B is 3% by area or more with respect to the total surface area of the toner particles.Type: GrantFiled: July 30, 2020Date of Patent: January 10, 2023Assignee: FUJIFILM Business Innovation Corp.Inventors: Atsushi Sugawara, Yosuke Tsurumi, Yasuko Torii, Yoshimasa Fujihara, Moegi Iguchi
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Patent number: 11084935Abstract: Quinacridone pigments that are surface-functionalized with glycidyl methacrylate, maleic anhydride, or 4-methacryloxyethyl trimellitic anhydride to create a functionalized pigment. The functional groups are then activated to bond hydrophobic polymers, thereby coating the pigment with the hydrophobic polymers. The quinacridone pigments can be used for a variety of applications. They are well-suited for use in electro-optic materials, such as electrophoretic media for use in electrophoretic displays.Type: GrantFiled: April 13, 2020Date of Patent: August 10, 2021Assignee: E Ink CorporationInventors: Ziyan Wu, Jason D. Feick
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Patent number: 10662334Abstract: Quinacridone pigments that are surface-functionalized with glycidyl methacrylate, maleic anhydride, or 4-methacryloxyethyl trimellitic anhydride to create a functionalized pigment. The functional groups are then activated to bond hydrophobic polymers, thereby coating the pigment with the hydrophobic polymers. The quinacridone pigments can be used for a variety of applications. They are well-suited for use in electro-optic materials, such as electrophoretic media for use in electrophoretic displays.Type: GrantFiled: January 11, 2019Date of Patent: May 26, 2020Assignee: E Ink CorporationInventors: Ziyan Wu, Jason D. Feick
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Patent number: 10466608Abstract: Toner particles each include a toner mother particle and an external additive. The toner mother particle includes a toner core containing a binder resin and a shell layer covering a surface of the toner core. The external additive includes a plurality of external addition resin particles. The external addition resin particles are each present on a surface of the shell layer. The shell layer contains a specific vinyl resin. The toner core and each resin particle are bonded together through a covalent bond within the shell layer. A detachment rate of the resin particles is lower than 5%. The vinyl resin include constitutional units represented by formulas (1-1) to (1-3). The atomic groups X1 and X2 included in the constitutional units represented by the respective formulas (1-1) and (1-2) are each derived from N-methylol group and represented by —NHCH2O—.Type: GrantFiled: August 11, 2018Date of Patent: November 5, 2019Assignee: KYOCERA Document Solutions Inc.Inventor: Erika Tanaka
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Patent number: 10457773Abstract: A method of preparing a polyalkylene carbonate resin is provided. More particularly, a method of preparing a polyalkylene carbonate resin capable of preventing polymer degradation and improving physical properties and quality of a final resin product, in which, after polymerization of polyalkylene carbonate, by-products are removed by using a large amount of water to purify a reaction mixture, and in a subsequence process of removing a catalyst residue, a primary purification method is conducted by using a filter so that a content of the catalyst in the reaction mixture is less than 1% by weight, is provided.Type: GrantFiled: December 8, 2015Date of Patent: October 29, 2019Assignee: LG Chem, Ltd.Inventors: Jung Min Sohn, Seung Young Park, Jin Woo Lee, Yoon Jung Kim, Taek Jun Jung, Yun Ki Cho, Yong Hee An, Jun Wye Lee
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Patent number: 10254670Abstract: An electrostatic latent image developing toner includes a plurality of toner particles each including a toner mother particle and an external additive attached to a surface of the toner mother particle. The external additive includes a plurality of resin particles each containing first temperature responsive polymer domains and second temperature responsive polymer domains. The second temperature responsive polymer domains have a lower critical solution temperature (LCST) higher than that of the first temperature responsive polymer domains.Type: GrantFiled: March 23, 2018Date of Patent: April 9, 2019Assignee: KYOCERA Document Solutions Inc.Inventor: Yuma Uchihashi
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Patent number: 10228630Abstract: A toner comprising an external additive A, and a toner particle containing a binder resin and a colorant, wherein the external additive A: i) is an external additive that has a charge control agent on the surface thereof; ii) has a wall friction angle ? calculated from the following formula (1) of not more than 25.0° ?=?/5.0??formula (1); iii) has a number-average particle diameter (D1) of primary particles of at least 70 nm and not more than 500 nm; and iv) has a solidity as given by the following formula (2) of at least 0.40 and not more than 0.90 solidity=area of external additive A/area of region encompassed by envelope for external additive A?? formula (2).Type: GrantFiled: September 7, 2017Date of Patent: March 12, 2019Assignee: CANON KABUSHIKI KAISHAInventors: Takuya Mizuguchi, Kazuo Terauchi, Yojiro Hotta, Takeshi Naka, Motohide Shiozawa, Masami Fujimoto
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Patent number: 10196523Abstract: Quinacridone pigments that are surface-functionalized with glycidyl methacrylate, maleic anhydride, or 4-methacryloxyethyl trimellitic anhydride to create a functionalized pigment. The functional groups are then activated to bond hydrophobic polymers, thereby coating the pigment with the hydrophobic polymers. The quinacridone pigments can be used for a variety of applications. They are well-suited for use in electro-optic materials, such as electrophoretic media for use in electrophoretic displays.Type: GrantFiled: August 2, 2017Date of Patent: February 5, 2019Assignee: E Ink CorporationInventors: Ziyan Wu, Jason D. Feick
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Patent number: 10180650Abstract: An image forming apparatus includes an image holding member, a charging unit; an electrostatic image forming unit, a development unit, a transfer unit; a fixing unit, and a cleaning unit. A toner for electrostatic image development contains a binder resin containing an amorphous resin and a crystalline resin, and paraffin wax. The toner has a volume-average particle diameter of 6 ?m to 9 ?m, a shape factor SF1 of 140 or more, and a toluene insoluble content within a range of 25% to 40%. The melting temperature of the paraffin wax is 60° C. or more and 80° C. or less. The absolute value of difference between the melting temperature of the crystalline resin and the melting temperature of the paraffin is 10° C. or less.Type: GrantFiled: July 26, 2017Date of Patent: January 15, 2019Assignee: FUJI XEROX CO., LTD.Inventors: Masataka Kuribayashi, Masahiro Uchida, Takafumi Koide, Yusuke Fukuda, Katsuyuki Kitajima, Koji Funaba, Satomi Hara, Kana Yoshida
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Patent number: 10152008Abstract: An image forming apparatus includes an image holding member, a charging unit, an electrostatic charge image forming unit, a developing unit, a transfer unit, a fixing unit including a fixing belt, a pressurizing rotator that forms a nip by pressurizing an outer peripheral surface of the fixing belt, a sliding member that slides on an inner peripheral surface of the fixing belt in the nip, and a pressing member that presses the fixing belt in the direction of the pressurizing rotator, wherein a toner to be used includes a binder resin containing an amorphous resin and a crystalline resin and has specific physical properties described in the specification, and paraffin wax having a melting temperature of 60° C. to 80° C., and an absolute value of a difference between the melting temperature of the crystalline resin and the melting temperature of the paraffin wax is 10° C. or less.Type: GrantFiled: February 9, 2018Date of Patent: December 11, 2018Assignee: FUJI XEROX CO., LTD.Inventors: Kana Yoshida, Masataka Kuribayashi, Masahiro Uchida, Takafumi Koide, Yusuke Fukuda, Katsuyuki Kitajima, Koji Funaba, Satomi Hara
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Patent number: 10133221Abstract: An image forming apparatus includes a fixing unit including a fixing belt, a pressurizing rotator that forms a nip portion between the fixing belt and the pressurizing rotator by pressurizing an outer peripheral surface of the fixing belt, a first heating rotator that is provided so as to contact an inner peripheral surface of the fixing belt in the nip portion and heats the fixing belt, and a second heating unit that heats the fixing belt separately from the first heating rotator, wherein a toner to be used has physical properties described in the specification and includes an amorphous resin, a crystalline resin, and paraffin wax having a melting temperature of 60° C. to 80° C., and an absolute value of a difference in a melting temperature between the crystalline resin and the paraffin wax is 10° C. or less.Type: GrantFiled: February 13, 2018Date of Patent: November 20, 2018Assignee: FUJI XEROX CO., LTD.Inventors: Masahiro Uchida, Masataka Kuribayashi, Takafumi Koide, Yusuke Fukuda, Katsuyuki Kitajima, Satomi Hara, Kana Yoshida, Koji Funaba
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Patent number: 10081757Abstract: The present invention provides amidic polymers, which exhibit shale swelling inhibitor activity having improved biodegradability. The amidic polymers of the invention may be employed in a wide variety of compositions, particularly in subterranean drilling operations. Non-limiting generic structures of the amidic polymers are set out below: formula (1) wherein R1-R3 and integers m and n are defined herein.Type: GrantFiled: November 22, 2013Date of Patent: September 25, 2018Assignee: ISP INVESTMENTS LLCInventors: Cuiyue Lei, Osama M. Musa
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Patent number: 9977353Abstract: The present invention provides an electrophotographic electro-conductive member containing an ion-exchange group structure in an electro-conductive layer, whereby the bleeding of an ionic conductive agent to the surface of the electro-conductive layer is suppressed and reduction in electro-conductivity caused by electrification is low. For this purpose, the electrophotographic member of the present invention is an electrophotographic member having an electro-conductive mandrel and an electro-conductive layer, wherein the electro-conductive layer contains a resin having any one or more of partial structures represented by the specific formulas (1) to (7) in the molecule, and an anion.Type: GrantFiled: May 11, 2015Date of Patent: May 22, 2018Assignee: CANON KABUSHIKI KAISHAInventors: Satoru Nishioka, Kazuhiro Yamauchi, Masaki Yamada, Sosuke Yamaguchi, Taichi Shintou
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Patent number: 9958809Abstract: A magnetic carrier according to the present invention includes a magnetic carrier core and a resin covering layer formed on a surface of the magnetic carrier core, wherein the resin covering layer contains a resin component and an inorganic fine particle, the inorganic fine particle contains an oxide of a typical metal element or a carbonate of a typical metal element, a moisture adsorption rate of the inorganic fine particle when allowed to stand in an environment of a temperature of 30° C. and a humidity of 80% for 72 hours is 25.0% by mass or less, an electrical conductivity of the inorganic fine particle is 2.0×10?9 ?S/m or more and 2.5×10?5 ?S/m or less, and a degree of crystallinity of the inorganic fine particle is 60% or less.Type: GrantFiled: June 29, 2016Date of Patent: May 1, 2018Assignee: CANON KABUSHIKI KAISHAInventors: Nobuyoshi Sugahara, Yuto Onozaki, Hironori Minagawa, Wakashi Iida
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Patent number: 9958799Abstract: An electrostatic latent image developing toner includes a plurality of toner particles each having: a sea-like domain substantially formed from a plurality of resins including at least a polyester resin containing an alcohol component having a carbon number of 2-6; and a plurality of island-like domains distributed in an island-like pattern in the sea-like domain. The island-like domains are substantially formed from a resin containing a nigrosine pigment. A dispersion diameter of the island-like domains is 0.1-1.0 ?m. The polyester resin containing the alcohol component having a carbon number of 2-6 is contained in the sea-like domain in an amount of 5-50% by mass relative to a total amount of constituent resins (the plurality of resins). A ratio of an SP value of the resins forming the sea-like domain to an SP value of the resin forming the island-like domain is no greater than 0.98 or at least 1.20.Type: GrantFiled: February 8, 2017Date of Patent: May 1, 2018Assignee: KYOCERA Document Solutions Inc.Inventors: Toshiki Takemori, Yukinori Nakayama
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Patent number: 9952523Abstract: A toner including a toner particle containing a binder resin, a pigment, a pigment dispersant and an amorphous resin, in which the pigment dispersant has a rate of adsorption A1 (%) to the pigment of at least 80% and not more than 100%, the amorphous resin has a rate of adsorption A2 (%) to the pigment of at least 0% and not more than 60%, the binder resin has an Rf value (RfL) of at least 0.50 and not more than 1.00, and the amorphous resin has an Rf value (RfH) of at least 0.00 and not more than 0.35.Type: GrantFiled: February 16, 2016Date of Patent: April 24, 2018Assignee: CANON KABUSHIKI KAISHAInventors: Tsutomu Shimano, Kunihiko Nakamura, Kenta Kamikura
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Patent number: 9933718Abstract: A part material for printing three-dimensional parts with an electrophotography-based additive manufacturing system, the part material including a composition having a copolymer (including acrylonitrile units, butadiene units, and aromatic units), a charge control agent, and a heat absorber. The part material is provided in a powder form having a controlled particle size, and is configured for use in the electrophotography-based additive manufacturing system having a layer transfusion assembly for printing the three-dimensional parts in a layer-by-layer manner.Type: GrantFiled: September 8, 2016Date of Patent: April 3, 2018Assignee: Stratasys, Inc.Inventor: Trevor I. Martin
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Patent number: 9933716Abstract: The present invention relates to a toner for electrostatic charge image development, including toner base particles containing a binder resin containing as a main component a vinyl resin having a constitutional unit derived from a monomer having an acid group, and aluminum, wherein a concentration of the aluminum in the toner base particles, as measured by radio inductively coupled plasma emission spectral analysis, is from 900 to 2,200 ppm. According to the present invention, there is provided a means for improving the environmental stability of electrification, and the glossiness and the image density of the image to be formed in a good balance while maintaining sufficient low temperature fixability in a toner for electrostatic charge image development.Type: GrantFiled: September 28, 2016Date of Patent: April 3, 2018Assignee: KONICA MINOLTA, INC.Inventors: Shiro Hirano, Noboru Ueda, Kouji Sugama, Junya Onishi, Aya Shirai, Tatsuya Fujisaki
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Patent number: 9834683Abstract: The present invention provides a compound and a pigment dispersant, each of which improves the dispersibility of various types of pigments in a non-aqueous solvent and also provides a pigment composition, a pigment dispersion, and a toner, each of which has a preferable coloring power. The compound includes a polymer which has a monomer unit having a specific structure and also includes a specific partial structure.Type: GrantFiled: August 27, 2014Date of Patent: December 5, 2017Assignee: Canon Kabushiki KaishaInventors: Chiaki Nishiura, Yuki Tsujii, Yasuaki Murai, Takayuki Toyoda, Waka Hasegawa, Masanori Seki, Masashi Kawamura, Masashi Hirose, Ayano Mashida
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Patent number: 9785067Abstract: An electrostatic latent image developing toner includes a plurality of toner particles, The toner particles each include a toner mother particle and a plurality of external additive particles. The toner mother particle contains at least a hinder resin and a colorant. The external additive particles each include a first particle, a plurality of second particles disposed at a surface of the first particle, and the coat layer coating the first particle having the second particles.Type: GrantFiled: June 28, 2016Date of Patent: October 10, 2017Assignee: KYOCERA Document Solutions Inc.Inventor: Yukari Kida
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Patent number: 9772573Abstract: A toner includes a plurality of toner particles each having a core and a shell layer residing on a surface of the core. Each of the toner particles has a distribution of surface potential, as measured by a scanning probe microscope with respect to a 1 ?m2 region of the toner particle in a state where no external additive adheres thereto, satisfying that the surface potential is at least Vmin+?V×0.4 in at least 70% and no greater than 95% of the 1 ?m2 region, where ?V denotes a potential difference calculated by subtracting a minimum surface potential Vmin of the 1 ?m2 region from a maximum surface potential Vmax of the 1 ?m2 region.Type: GrantFiled: January 16, 2015Date of Patent: September 26, 2017Assignee: KYOCERA Document Solutions Inc.Inventor: Noriaki Sakamoto
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Patent number: 9760031Abstract: A method for preparing suspension polymerization toner of core-shell structure comprises following steps: 1) preparing a monomer oil phase containing a certain amount of polar resin forming toner soft core resin and aqueous dispersion liquid respectively; 2) adding the monomer oil phase into the aqueous dispersion liquid, transferring a mixture into a reactor after high-speed shearing and suspension granulation, and carrying out a first heating polymerization reaction to obtain toner particles of soft-core hard-shell structure; 3) taking the toner particles of soft-core hard-shell structure as a core layer, adding a cationic monomer component, and carrying out a second polymerization reaction through a water-soluble initiator to obtain the toner particles of soft-core hard-shell structure with dense charge surface layers uniformly distributed on outer surfaces; and 4) cleaning, filtering, and sufficiently drying a preceding product, and then adding silicon dioxide.Type: GrantFiled: April 2, 2013Date of Patent: September 12, 2017Assignee: SHENZHEN LEPUTAI TECHNOLOGY CO., LTDInventors: Zhijun Liu, Yuanyuan Zhang, Tiantian Pu, Xiao Yuan, Hong Meng, Hui Yang
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Patent number: 9715187Abstract: Provided are a method of producing a compound having a colorant structure suitable for a pigment dispersant, and a pigment dispersant, a pigment composition, a pigment dispersion, and a toner each containing the compound. The production method is a method of producing a compound in which a polymer portion and a colorant portion are bonded to each other through a linking group, the method including the steps of: (a) polymerizing a vinyl-based polymerizable monomer represented by the formula (A) with a radical initiator having a protective group by living radical polymerization to provide a polymer having the protective group at a terminal thereof; (b) hydrolyzing the protective group of the polymer having the protective group at a terminal thereof obtained by the step (a) to deprotect the polymer; and (c) bonding the deprotected polymer obtained by the step (b) and a colorant to each other through a covalent bond.Type: GrantFiled: March 30, 2015Date of Patent: July 25, 2017Assignee: CANON KABUSHIKI KAISHAInventors: Kosuke Mukumoto, Yasuaki Murai, Yuki Hasegawa, Takayuki Toyoda, Ayano Mashida, Waka Hasegawa, Chiaki Nishiura, Masanori Seki, Masashi Hirose
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Patent number: 9617388Abstract: A zwitterionic monomer and corresponding cyclopolymerized polyzwitterion (±) (PZ) (i.e. poly(Z-alt-SO2). Phosophonate ester hydroloysis in PZ gave a pH-responsive polyzwitterionic acid (±) (PZA). The PZA under pH-induced transformation was converted into polyzwitterion/anion (±?) (PZAN) and polyzwitterion/dianion (±=) (PZDAN).Type: GrantFiled: September 30, 2016Date of Patent: April 11, 2017Assignees: King Fahd University of Petroleum and Minerals, King Abdulaziz City for Science and TechnologyInventors: Shaikh Asrof Ali, Shamsuddeen Abdullahi Haladu
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Patent number: 9618865Abstract: A toner, including: a colorant; and a binder resin, wherein a spreadability of the toner under a non-pressurized condition is 1.20 to 2.50, wherein a common logarithm of a storage modulus at 100° C. (G?) of the toner is 4.0 [log Pa] to 5.0 [log Pa], and wherein a ratio of a loss modulus at 100° C. (G?) to the storage modulus at 100° C. (G?) of the toner (G?/G?=tan ?) is 1.1 to 2.2.Type: GrantFiled: March 13, 2014Date of Patent: April 11, 2017Assignee: Ricoh Company, Ltd.Inventors: Hideki Sugiura, Mio Kumai
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Patent number: 9580521Abstract: A zwitterionic monomer and corresponding cyclopolymerized polyzwitterion (±) (PZ) (i.e. poly(Z-alt-SO2). Phosophonate ester hydroloysis in PZ gave a pH-responsive polyzwitterionic acid (±) (PZA). The PZA under pH-induced transformation was converted into polyzwitterion/anion (±?) (PZAN) and polyzwitterion/dianion (±=) (PZDAN).Type: GrantFiled: September 30, 2016Date of Patent: February 28, 2017Assignees: King Fahd University of Petroleum and Minerals, King Abdulaziz City for Science and TechnologyInventors: Shaikh Asrof Ali, Shamsuddeen Abdullahi Haladu
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Patent number: 9482974Abstract: A part material for printing three-dimensional parts with an electrophotography-based additive manufacturing system, the part material including a composition having a copolymer (including acrylonitrile units, butadiene units, and aromatic units), a charge control agent, and a heat absorber. The part material is provided in a powder form having a controlled particle size, and is configured for use in the electrophotography-based additive manufacturing system having a layer transfusion assembly for printing the three-dimensional parts in a layer-by-layer manner.Type: GrantFiled: April 20, 2015Date of Patent: November 1, 2016Assignee: Stratasys, Inc.Inventor: Trevor I. Martin
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Patent number: 9235150Abstract: A magnetic one-component developing toner including a plurality of toner particles is provided. Each of the plurality of toner particles contains a binder resin including a polyester resin; and a magnetic powder. Water absorptions of the toner and the magnetic powder shown in an environment of 10° C. and 20% RH and in an environment of 28° C. and 80% RH respectively fall in predetermined ranges.Type: GrantFiled: March 14, 2014Date of Patent: January 12, 2016Assignee: KYOCERA Document Solutions Inc.Inventor: Akinori Koyama
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Patent number: 9201322Abstract: A positively chargeable toner for electrostatic image development according to the present disclosure is formed by aggregating at least binder resin-containing fine particles and colorant-containing fine particles in an aqueous medium in the presence of a dispersing agent and a metal ion to form fine particle aggregates and heating the fine particle aggregates to coalesce components in the fine particle aggregates. The binder resin used is a (meth)acrylic resin or styrene-(meth)acrylic resin having a certain quaternary ammonium group. The hydrophobicity (methanol wettability) is adjusted to a certain range.Type: GrantFiled: April 25, 2014Date of Patent: December 1, 2015Assignee: KYOCERA Document Solutions Inc.Inventor: Seiji Kikushima
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Patent number: 9134640Abstract: The present disclosure describes processes for making clear, high-gloss toners, including toner compositions resulting from such processes that find applications in overcoating and gloss enhancement.Type: GrantFiled: May 13, 2011Date of Patent: September 15, 2015Assignee: Xerox CorporationInventors: Maura Sweeney, Grazyna E. Kmiecik-Lawrynowicz, Robert D. Bayley, Dan Asarese
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Patent number: 9097999Abstract: Provided is a pigment dispersant for improving the dispersibility of an azo pigment for a water-insoluble solvent. More specifically, provided is a polyester, including at least one unit represented by one of the following formula (1) and the following formula (2): in the formula (1) and the formula (2): R1 represents an alkyl group having 1 to 6 carbon atoms or a phenyl group; R2 to R6 each represent a hydrogen atom, a COOR7 group, or a CONR8R9 group, provided that at least one of the R2 to R6 represents the COOR7 group or the CONR8R9 group; and the R7 to R9 each represent a hydrogen atom or an alkyl group having 1 to 3 carbon atoms.Type: GrantFiled: August 18, 2011Date of Patent: August 4, 2015Assignee: Canon Kabushiki KaishaInventors: Yasuaki Murai, Masashi Kawamura, Masatake Tanaka, Takayuki Toyoda, Yuki Hasegawa, Masashi Hirose, Takeshi Miyazaki
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Patent number: 9029056Abstract: Provided is a toner having high charging rapidity to reach a sufficient charging amount in a short time, high stability of charging from the initial stage to a time when a large amount of sheets is printed out, and high stability of charging under a high temperature and high humidity. In a toner including toner particles, each of which contains at least a binder resin, a colorant, and a charge controlling resin, the charge controlling resin is a copolymer of a structure A having at least a specific salicylic acid derivative structure and a structure B having sulfonic acid or sulfonic acid ester as a substituent.Type: GrantFiled: May 17, 2012Date of Patent: May 12, 2015Assignee: Canon Kabushiki KaishaInventors: Takashi Kenmoku, Hitoshi Itabashi, Akane Masumoto
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Patent number: 9029496Abstract: Provided is a liquid crystal polyester amide resin which has a good hue. Specific monomers are polymerized using a specific catalyst. The specific monomers are composed of: at least one kind of a monomer selected from among aromatic aminocarboxylic acids, aromatic hydroxyamines and aromatic diamines; and at least one kind of a monomer selected from among aromatic hydroxy carboxylic acids, aromatic dicarboxylic acids or aliphatic dicarboxylic acids, and aromatic diols or aliphatic diols. It is preferable that the content of the at least one kind of a monomer selected from among aromatic aminocarboxylic acids, aromatic hydroxyamines and aromatic diamines is from 0.1 mol % to 85 mol % (inclusive).Type: GrantFiled: October 12, 2012Date of Patent: May 12, 2015Assignee: Polyplastics Co., Ltd.Inventors: Toshinori Kawahara, Yoshiaki Taguchi
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Patent number: 9023565Abstract: A developer includes a toner containing at least a binder resin, wherein the toner has a molecular weight distribution Mz/Mw of 2.0 or smaller and a phase angle of viscoelasticity of 65° or greater.Type: GrantFiled: November 15, 2012Date of Patent: May 5, 2015Assignee: Oki Data CorporationInventor: Yoshihiro Hashimoto
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Patent number: 9023566Abstract: A part material for printing three-dimensional parts with an electrophotography-based additive manufacturing system, the part material including a composition having a copolymer (including acrylonitrile units, butadiene units, and aromatic units), a charge control agent, and a heat absorber. The part material is provided in a powder form having a controlled particle size, and is configured for use in the electrophotography-based additive manufacturing system having a layer transfusion assembly for printing the three-dimensional parts in a layer-by-layer manner.Type: GrantFiled: July 17, 2013Date of Patent: May 5, 2015Assignee: Stratasys, Inc.Inventor: Trevor I. Martin
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Patent number: 9012114Abstract: An electrostatic charge image developing toner includes toner particles; and an external additive that is externally added to surfaces of the toner particles, in which a content of nitrogen atoms on the surfaces of the toner particles is from 0.8 atomic % to 5.0 atomic % and a content of nitrogen atoms at a depth of 10 nm inside from the surfaces of the toner particles is 0.4 atomic % or less when measured by X-ray photoelectron spectroscopy.Type: GrantFiled: October 8, 2013Date of Patent: April 21, 2015Assignee: Fuji Xerox Co., Ltd.Inventors: Noriyuki Mizutani, Tsuyoshi Murakami, Yukiaki Nakamura, Satoshi Kamiwaki
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Publication number: 20150093699Abstract: A cyan toner comprising toner particles, each of which contains a binder resin, a compound in which a polymer portion is bound to an azo skeleton structure, and a phthalocyanine pigment serving as a colorant.Type: ApplicationFiled: December 5, 2014Publication date: April 2, 2015Inventors: Yasuaki Murai, Takayuki Toyoda, Waka Hasegawa, Yuki Hasegawa, Masashi Kawamura, Taiki Watanabe, Masanori Seki, Chiaki Nishiura, Ayano Mashida, Masashi Hirose
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Publication number: 20150086918Abstract: An electrostatic latent image developing toner includes toner particles. Each of the toner particles includes a toner core containing a binder resin and a releasing agent, and a shell layer coating the toner core. The releasing agent has a melting point Mpr of no less than 50° C. and no greater than 100° C. The releasing agent has a number average dispersion diameter of no less than 30 nm and no greater than 500 nm. The shell layer is made from a resin including a unit derived from a monomer of a thermosetting resin. The thermosetting resin is one or more amino resins from among a melamine resin, a urea resin, and a glyoxal resin.Type: ApplicationFiled: September 25, 2014Publication date: March 26, 2015Applicant: KYOCERA DOCUMENT SOLUTIONS INC.Inventors: Toshiki TAKEMORI, Masashi YAMASHITA, Hiroki UEMURA, Yukinori NAKAYAMA, Masaki OKITA
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Publication number: 20150079515Abstract: A toner comprising toner particles, each of which contains a binder resin, a compound in which a polymer portion is bound to an azo skeleton structure, and a magenta pigment.Type: ApplicationFiled: November 20, 2014Publication date: March 19, 2015Inventors: Takayuki Toyoda, Yasuaki Murai, Waka Hasegawa, Yuki Hasegawa, Masashi Kawamura, Taiki Watanabe, Masanori Seki, Chiaki Nishiura, Ayano Mashida, Masashi Hirose
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Publication number: 20150072282Abstract: An electrostatic latent image developing toner includes toner particles. Each toner particle includes a toner core containing a binder resin, a shell layer coating a surface of the toner core, and particulates having a higher hardness than the shell layer. Each shell layer contains a thermosetting resin, and the particulates are present within the shell layer. Preferably, the content of the particulates having a higher hardness than the shell layer is 0.1% by mass or more and 5.0% by mass or less with respect to a total amount of the toner particles.Type: ApplicationFiled: September 10, 2014Publication date: March 12, 2015Applicant: KYOCERA Document Solutions Inc.Inventor: Seiji OKADA
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Publication number: 20150072279Abstract: Developer includes a toner base particle and an outer additive agent attached to a surface of the toner base particle. The outer additive agent includes at least a composite oxide particle containing titanium dioxide and silicon dioxide and a melamine resin particle.Type: ApplicationFiled: September 10, 2014Publication date: March 12, 2015Inventor: Hideharu KUWABARA
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Publication number: 20150064618Abstract: A toner comprising toner particles, each of which contains a binder resin, a compound in which a polymer portion is bound to an azo skeleton structure are linked, and carbon black.Type: ApplicationFiled: November 10, 2014Publication date: March 5, 2015Inventors: Yuki Hasegawa, Yasuaki Murai, Waka Hasegawa, Takayuki Toyoda, Masashi Kawamura, Masatake Tanaka, Masashi Hirose
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Publication number: 20150056549Abstract: The present invention is a toner including toner particles prepared by forming particles of a polymerizable monomer composition including a polymerizable monomer, a pigment, a pigment dispersant and a crystalline polyester resin in an aqueous medium, and polymerizing the polymerizable monomer, wherein the polymerizable monomer is a polymerizable monomer for preparing a vinyl copolymer, the difference in an SP value between the pigment dispersant and the crystalline polyester resin is ?1.5 to +0.8, the difference in an SP value between the pigment dispersant an the vinyl copolymer is ?1.1 to +1.2, the pigment dispersant has a polymer component and an adsorbable component adsorbed to the pigment, the polymer component is a vinyl polymer, the polymer component of the pigment dispersant has a number average molecular weight of 3,000 to 20,000, and a rate of adsorption of the pigment dispersant to the pigment is 30% or more.Type: ApplicationFiled: August 21, 2014Publication date: February 26, 2015Inventors: Naotaka Ikeda, Yasuhiro Hashimoto, Yuhei Terui, Shohei Shibahara, Masanori Seki, Waka Hasegawa
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Patent number: 8951705Abstract: A development agent containing toner that contains a binder resin having a crystalline resin that has a urethane and/or urea bond in its main chain, a coloring agent, and an organically modified inorganic laminate compound in which organic ions are at least partially substituted for ions present between layers of the organically modified inorganic laminate compound, and toner carrier that contains a core material whose surface is coated with a coating layer having a condensed compound of a melamine resin and/or a guanamine resin and an acrylic resin having a hydroxyl group.Type: GrantFiled: March 4, 2013Date of Patent: February 10, 2015Assignee: Ricoh Company, Ltd.Inventors: Shinya Nakayama, Atsushi Yamamoto, Yukiko Nakajima, Masahide Yamada, Hideyuki Santo, Suzuka Amemori
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Publication number: 20150037724Abstract: An electrostatic latent image developing toner of the present disclosure contains a toner particle including a toner core containing a binder resin, and a shell layer coating a surface of the toner core. The shell layer is constituted by a resin containing a thermosetting resin. A zeta potential of the toner core measured in an aqueous medium adjusted to pH 4 is negative, and a zeta potential of the toner particle measured in an aqueous medium adjusted to pH 4 is positive. A pH at which the zeta potential of the toner particle measured in an aqueous medium is zero is 4.5 or higher and 7.0 or lower.Type: ApplicationFiled: July 28, 2014Publication date: February 5, 2015Applicant: KYOCERA Document Solutions Inc.Inventor: Takeo MIZOBE
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Patent number: 8940467Abstract: A toner is provided that, even in a small amount thereof, gives a satisfactory image density and that is free of image problems, e.g., fogging and offset resistance, even during long-term use and in a high-temperature, high-humidity environment. The toner contains a binder resin, a pigment, and a prescribed azo compound wherein, designating as (A) the solubility of the azo compound in a toluene-hexane solubility test and as (B) the solubility of the binder resin constituting the toner in the toluene-hexane solubility test, the (A) and the (B) satisfy the relationship |(B)?(A)|?60.Type: GrantFiled: February 26, 2013Date of Patent: January 27, 2015Assignee: Canon Kabushiki KaishaInventors: Yasuhiro Hashimoto, Takayuki Toyoda, Masashi Kawamura, Naotaka Ikeda, Hidekazu Fumita, Emi Watanabe, Yuhei Terui
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Publication number: 20150024320Abstract: An electrostatic latent image developing toner includes toner particles. The toner particles each include a toner core containing a binder resin and a shell layer coating the surface of the toner core. The binder resin contains an ethylene-unsaturated carboxylic acid copolymer. The shell layers contain a unit derived from a monomer of a thermosetting resin. The thermosetting resin is at least one resin selected from the group of amino resins consisting of a melamine resin, a urea resin, and a glyoxal resin.Type: ApplicationFiled: July 17, 2014Publication date: January 22, 2015Applicant: KYOCERA Document Solutions Inc.Inventor: Erika TANAKA
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Publication number: 20150024319Abstract: A part material for printing three-dimensional parts with an electrophotography-based additive manufacturing system, the part material including a composition having a copolymer (including acrylonitrile units, butadiene units, and aromatic units), a charge control agent, and a heat absorber. The part material is provided in a powder form having a controlled particle size, and is configured for use in the electrophotography-based additive manufacturing system having a layer transfusion assembly for printing the three-dimensional parts in a layer-by-layer manner.Type: ApplicationFiled: July 17, 2013Publication date: January 22, 2015Inventor: Trevor I. Martin