Metal Oxide Conmpound Adjuvant (e.g., Ai2o3'tio2'etc.) Patents (Class 430/108.6)
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Patent number: 7892715Abstract: A color toner for electro printing, which comprises from 10 to 50 parts by mass of fine inorganic pigment particles, from 5 to 40 parts by mass of a heat decomposable binder resin having an acid value of at least 5, and from 40 to 85 parts by mass of glass frit, per 100 parts by mass of the total solid content of the toner.Type: GrantFiled: September 29, 2006Date of Patent: February 22, 2011Assignee: Asahi Glass Company, LimitedInventors: Naoki Okahata, Satoshi Kashiwabara, Kazuo Sunahara
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Patent number: 7887985Abstract: A carrier and a two-component developer are provided. A coating resin layer for coating a core material contains fine particles of titanium oxide which comprise an anatase-type crystal and a rutile-type crystal, and a carrier coating amount of the coating resin layer falls in a range of from 5% by weight to 20% by weight. In addition, a content rate of the rutile-type crystal falls in a range of from 5% to 20% on the basis of the total amount of crystal, and the weight of the fine particles of titanium oxide falls in a range of from 5% by weight to 50% by weight relative to the weight of the core material. Further, the primary particle size of the fine particles of titanium oxide falls in a range of from 40 nm to 80 nm.Type: GrantFiled: December 27, 2007Date of Patent: February 15, 2011Assignee: Sharp Kabushiki KaishaInventor: Toru Nishikawa
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Publication number: 20110014559Abstract: The present disclosure provides violet toners and methods for their production. In embodiments, methods of the present disclosure include systems which may be utilized to predict the color properties of a violet toner, thereby permitting adjustment of the pigment loading and/or target mass per unit area.Type: ApplicationFiled: July 20, 2009Publication date: January 20, 2011Applicant: XEROX CORPORATIONInventors: Jordan H. Wosnick, Suxia Yang, Richard P.N. Veregin, Karen A. Moffat
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Publication number: 20110008722Abstract: Toners are provided which include a resin including at least one baroplastic polymer. The baroplastic polymer, in embodiments, may be a block copolymer with discrete low glass transition temperature (Tg) domains and high Tg domains that plasticize one another at ambient temperature when subjected to pressures of from about 500 psi (about 3.45 MPa) to about 10,000 psi (about 69 MPa), enabling them to be extruded and molded without heat. The resulting polymers, in turn, may then be utilized to form toners.Type: ApplicationFiled: July 10, 2009Publication date: January 13, 2011Applicant: XEROX CORPORATIONInventors: Jordan H. Wosnick, Karen Ann Moffat
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Patent number: 7862977Abstract: A method to form an image using a trickle developing system, wherein (a) the toner comprises colorant particles with a volume median diameter of 3 to 8 ?m having first inorganic particles on surfaces of the colorant particles to form toner particles; (b) the carrier comprises magnetic particles with a weight average particle diameter (D4) of 20 to 40 ?m having second inorganic particles on surfaces of the magnetic particles to form carrier particles; and (c) an area ratio of element (A) based on a total area of surfaces of the carrier particles is 0.5 to 3.0 area % determined by using an X-ray analysis, provided that element (A) represents one or more elements commonly contained in the first inorganic particles and in the second inorganic particles.Type: GrantFiled: April 3, 2007Date of Patent: January 4, 2011Assignee: Konica Minolta Business Technologies, Inc.Inventors: Makoto Kobayashi, Yoshiyasu Matsumoto
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Patent number: 7865114Abstract: An image forming apparatus including an image bearing member, a charging device, an irradiating device, a developing device, a transfer device, a fixing device, and a cleaning device, wherein the image bearing member includes a substrate on which a photosensitive layer and a cross-linked surface layer are accumulated and the cross-linked surface layer comprises a cross-linked material formed by curing a monomer having at least three radical polymerizable function groups without a charge transport structure and a radical polymerizable compound having a charge transport structure by a photo-energy irradiation device, wherein the toner has a volume average particle diameter of from 1 to 5 ?m and an average circularity of from 0.95 to 0.Type: GrantFiled: November 21, 2007Date of Patent: January 4, 2011Assignee: Ricoh Company LimitedInventors: Masahiko Ishikawa, Masami Tomita, Yoshiaki Kawasaki
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Publication number: 20100330490Abstract: A positively-chargeable toner for developing electrostatic images which can prevent damage of photosensitive members and filming due to an external additive, can impart a stable charge property and flowability to toner particles over time, and thus hardly causes deterioration of image quality due to fog, blur, white streaks or the like, and therefore is excellent in printing durability even if continuous printing of plural prints is performed is provided. A positively-chargeable toner for developing electrostatic images of the present invention is a positively-chargeable toner for developing electrostatic images comprising colored resin particles containing a colorant and a binder resin, and an external additive, wherein the external additive contains magnesium silicate having negatively charging ability, with a Mohs hardness of 3 or less and a number average primary particle diameter in the range from 1 to 15 ?m.Type: ApplicationFiled: February 27, 2008Publication date: December 30, 2010Applicant: ZEON CORPORATIONInventor: Osamu Ieda
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Publication number: 20100330487Abstract: Coated phosphorescent pigments are provided which may be utilized in toner compositions. In embodiments, the phosphorescent pigment may be coated by a powder coating process. The large pigment particles may be dry blended with dried resin latex particles, thereby coating the pigment surface, followed by heating and shearing in a rotary kiln or extruder to melt the toner resin and fuse it to the pigment surface. The resulting coated particles may be utilized with other toners, in embodiments color toners, to provide phosphorescent images.Type: ApplicationFiled: June 29, 2009Publication date: December 30, 2010Applicant: XEROX CORPORATIONInventors: Richard P.N. Veregin, Eric Rotberg, Michael S. Hawkins, Cuong Vong, Jordan H. Wosnick
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Patent number: 7858281Abstract: A developer comprised of a toner and at least one external surface additive, wherein an acid-base interaction has an Interaction Surface Parameter (ISP) of greater than 0, and wherein ISP is defined by the following equation: [(Ka)toner×(Kb)additive]+[(Kb)toner×(Ka)additive]?[(Ka)toner×(Ka)additive]?[(Kb)toner×(Kb)additive], wherein Ka is the Lewis acid value and Kb is the Lewis base value.Type: GrantFiled: November 21, 2007Date of Patent: December 28, 2010Assignee: Xerox CorporationInventors: Richard P. N. Veregin, Maria N. V. McDougall
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Patent number: 7855042Abstract: To provide a developer and an image forming method with each of which a high-resolution, high-definition image can be stably obtained over a long time period irrespective of an environment. The present invention provides a developer including at least: toner particles each containing at least a binder resin; and a composite inorganic fine powder, the developer being characterized in that: the composite inorganic fine powder has a peak at a Bragg angle (2?±0.20 deg) of each of 32.20 deg, 25.80 deg, and 27.50 deg in a CuK? characteristic X-ray diffraction pattern; and the half width of the X-ray diffraction peak at a Bragg angle (2?±0.20 deg) of 32.20 deg is 0.20 to 0.30 deg.Type: GrantFiled: May 30, 2007Date of Patent: December 21, 2010Assignee: Canon Kabushiki KaishaInventors: Takakuni Kobori, Kenji Okado, Masami Fujimoto, Katsuhisa Yamazaki, Syuhei Moribe, Daisuke Yoshiba
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Patent number: 7851116Abstract: Toner including toner particles having a calcium-containing material at least in a surface portion of the toner particle, wherein the toner particles contain calcium in an amount of from 20 ppm to about 300 ppm of calcium by dry weight of the toner. Developer including a carrier and a toner, wherein the toner includes toner particles having a calcium-containing material at least in a surface portion of the toner particles. In an emulsion aggregation process for making toner particles, the toner particles are treated with calcium. The addition of calcium to the toner particles improves toner performance by lowering cohesion and charging, thereby generating an image of high gloss.Type: GrantFiled: October 30, 2006Date of Patent: December 14, 2010Assignee: Xerox CorporationInventors: Richard P. N. Veregin, Allan K. Chen, Cuong Vong, Vladislav Skorokhod, Eric M. Strohm, Michael S. Hawkins, Christine D. Anderson, Richard Fong, Nancy S. Hunt, Vincenzo G. Marcello
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Patent number: 7846632Abstract: The toner of the present invention, comprising a colored resin particle and an external additive, wherein said external additive contains a silica fine particle (A) having a Dv50/Dv10 of 1.8 or more, in which Dv10 represents a particle diameter at which a volume cumulative total from small particle diameter side is 10% and Dv50 represents a particle diameter at which the mentioned volume cumulative total is 50%, a volume average particle diameter in the range from 0.1 to 1.0?, and a sphericity in the range from 1 to 1.3. The toner of the present invention cause less fog, and excellent resolution on the printed image, excellent in cleaning property, and cause less filming.Type: GrantFiled: June 11, 2004Date of Patent: December 7, 2010Assignee: Zeon CorporationInventor: Hiroshi Nakatani
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Publication number: 20100304288Abstract: A toner comprising toner particles, wherein a surface-treated titanate compound is contained on the surface of parent toner particles comprising a resin and a colorant, and the titanate compound having a carbon amount of not less than 0.15% by mass and not more than 0.50% by mass.Type: ApplicationFiled: May 26, 2010Publication date: December 2, 2010Applicant: KONICA MINOLTA BUSINESS TECHNOLOGIES, INC.Inventors: Masahiro Anno, Kazuyoshi Goan, Makoto Nomiya, Kouji Sugama, Masahiro Matsuoka
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Patent number: 7838193Abstract: A toner including toner particles including a binder resin, a colorant and a release agent, and an external additive including a first particulate inorganic material having a formula of MgxSiyOx+2y where each of x and y is an integer, and a number average secondary particle diameter of from 0.02 ?m to 2 ?m, wherein the first atomic ratio (Mg/Si)s in a surface portion of the first particulate inorganic material is not greater than (preferably less than) the second atomic ratio (Mg/Si)e in the entire first particulate inorganic material. Alternatively, a toner including toner particles including a binder resin and a colorant, and an external additive which includes a particulate inorganic material having a formula of MgxSiyOx+2y where each of x and y is an integer and which has a surface treated with a fatty acid.Type: GrantFiled: February 1, 2007Date of Patent: November 23, 2010Assignee: Ricoh Company LimitedInventors: Masayuki Hagi, Takuya Kadota, Hiroaki Katoh, Atsushi Yamamoto, Katsunori Kurose, Yoshihiro Mikuriya, Masahide Inoue, Hideaki Yasunaga, Minoru Nakamura, Yoshimichi Ishikawa, Hiroyuki Murakami
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Publication number: 20100272471Abstract: Provided are an electrophotographic toner and an electrophotographic image forming apparatus using the same. The electrophotographic toner includes: parent toner particles including a binder resin, a colorant, a releasing agent, and a charge control agent; and barium titanate external additives having an average primary particle diameter in the range of about 50 to about 150 nm, an average shape factor (SF1) in the range of about 100 to about 120, a shape factor in the range of about 0.96 to about 1, and an aspect ratio in the range of about 0.89 to about 1, and added to the surface of the parent toner particles.Type: ApplicationFiled: December 17, 2008Publication date: October 28, 2010Applicant: SAMSUNG FINE CHEMICALS CO., LTD.Inventors: Woo Young Yang, Keon II Kim, Dae II Hwang, Jae Bum Park, II Sun Hwang, Jun-Hee Lee, Jae Kwang Hwang, Dong Won Kim, Duck Kyun Ahn
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Publication number: 20100261113Abstract: A toner includes toner base particles containing at least a binder resin, a coloring agent, and a release agent and having a volume-average particle size of 2 to 6 ?m; a small particle size silica having an average particle size of 7 to 15 nm; a large particle size silica having an average particle size of 50 to 400 nm; and a small particle size transition alumina obtained by a dawsonite method and having an average particle size of 7 to 20 nm.Type: ApplicationFiled: April 14, 2010Publication date: October 14, 2010Applicant: SEIKO EPSON CORPORATIONInventors: Tomohiro ARUGA, Hideki OKADA, Yoichi YAMADA, Daisuke MATSUMOTO
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Publication number: 20100261112Abstract: A toner includes toner base particles containing at least a binder resin, a coloring agent, and a release agent and having a volume-average particle size of 2 to 6 ?m; at least two types of silica each having a different average particle size; at least one type of electron-conductive oxide semiconductor fine particles selected from titania, transition alumina, zinc oxide, and tin oxide; and at least one type of ion-conductive oxide semiconductor fine particles selected from cerium oxide and stabilized zirconia.Type: ApplicationFiled: April 13, 2010Publication date: October 14, 2010Applicant: SEIKO EPSON CORPORATIONInventors: Tomohiro ARUGA, Yoichi YAMADA, Daisuke MATSUMOTO
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Publication number: 20100261109Abstract: A toner includes toner base particles containing at least a binder resin, a coloring agent, and a release agent; and alumina fine particles whose phase angle (?) is |80°| or less at an alternating current frequency of 1 to 10 kHz in an alternating current impedance method.Type: ApplicationFiled: April 9, 2010Publication date: October 14, 2010Applicant: SEIKO EPSON CORPORATIONInventors: Hideki OKADA, Tomotaka MORI, Tomohiro ARUGA
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Patent number: 7811734Abstract: Hydrophobic inorganic fine particles are provided which: does not cause melt adhesion of toner to a photosensitive member and contamination of a contact charging member; imparts excellent flowability, charging performance and durability to toner even after the toner is stored in a high-temperature, high-humidity environment over a long time period; and does not cause dripping of toner and contamination with the toner. The hydrophobic inorganic fine particles are obtained by subjecting inorganic fine particles to surface treatment with silicone oil and then with a silane compound and/or a silazane compound, or by subjecting inorganic fine particles to surface treatment with a silane compound and/or a silazane compound in the presence of silicone oil, and further subjecting the inorganic fine particles thus surface-treated to surface treatment with silicone oil.Type: GrantFiled: September 18, 2009Date of Patent: October 12, 2010Assignee: Canon Kabushiki KaishaInventors: Yoshihiro Ogawa, Yusuke Hasegawa, Kouji Nishikawa, Miho Okazaki, Yoshitaka Suzumura, Takashige Kasuya
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Publication number: 20100248118Abstract: The present disclosure provides toners and processes for making said toners. In embodiments, the toners are invisible when viewed under natural light, but possess a UV additive that renders them visible when exposed to UV light of a specific wavelength. By selecting the appropriate UV additive and ionic crosslinker, with optional chelating agent, the gloss of the toner may be tailored to match the gloss of any substrate, such as paper, to which the toner is to be applied, thereby further enhancing its invisibility under visible light.Type: ApplicationFiled: March 26, 2009Publication date: September 30, 2010Applicant: Xerox CorporationInventors: Yi Xin Gong, Shigang Qiu, Daryl W. Vanbesien, Gabriel Iftime, Edward Graham Zwartz, Karen Ann Moffat, Richard P.N. Veregin
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Publication number: 20100239969Abstract: A bio-toner for use in electrophotographic image forming that contains a bio-resin component that is at least partially derived from a renewable resource is provided. A method of making the bio-toner that contains a bio-resin component for use in electrophotographic image forming is also provided. A method for electrophotographic image formation using the bio-toner that contains a bio-resin is also provided.Type: ApplicationFiled: March 19, 2010Publication date: September 23, 2010Applicant: MITSUBISHI KAGAKU IMAGING CORPORATIONInventors: Takeshi OWADA, David Urban
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Publication number: 20100239971Abstract: A toner for electrophotography includes toner particles containing at least a binder resin and a colorant, to which strontium titanate and hydrophobic silica as external additives are admixed, wherein the strontium titanate has a BET specific surface area of 20-50 m2/g and contains particles in a rectangular parallelepiped shape and wherein the hydrophobic silica contains hydrophobic silica A that has at least a BET specific surface area of 150-300 m2/g and the surface of which has been treated with an aminosilane and hexamethyldisilazane and hydrophobic silica B that has at least a BET specific surface area of 90-150 m2/g and the surface of which has been treated with hexamethyldisilazane.Type: ApplicationFiled: September 3, 2008Publication date: September 23, 2010Applicant: Tomoegawa Co., Ltd.Inventors: Tohru Moriya, Hitoshi Onoda, Kazuyoshi Hattori, Yoshihito Suwa
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Publication number: 20100233608Abstract: An electrostatic image developing carrier includes a ferrite particle that contains from about 1.0% by weight to about 14.0% by weight of elemental magnesium, wherein an average distribution ratio D of the elemental magnesium in the ferrite particle is from about 1.1 to about 2.0, wherein the average distribution ratio D is defined as an average value of D? of at least 50 ferrite particles, wherein D? is defined as W1/W2, wherein W1 is a weight ratio of elemental magnesium content Mg to elemental iron content Fe, Me/Fe, in a whole cross-section of the ferrite particle, and W2 is a weight ratio of elemental magnesium content Mg to elemental iron content Fe, Me/Fe, in a square, the two opposite vertices of which are located at two points on a diameter of a circle circumscribing the cross-section, each being half a radius distant from the center of the circumscribing circle.Type: ApplicationFiled: September 10, 2009Publication date: September 16, 2010Applicant: FUJI XEROX CO., LTD.Inventors: Yosuke TSURUMI, Rieko KATAOKA
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Publication number: 20100233607Abstract: A toner for developing electrostatic images which is obtained by melt mixing at least a binder resin and a coloring agent, forming a powder material by pulverizing the obtained mixture after cooling and removing rough particles and fine particles from the formed powder material by classification, wherein inorganic fine particles having a roundness of 1.00 to 1.30, an average of the diameter of primary particles of 0.05 to 0.45 ?m and a ratio of a standard deviation to the average of the diameter of primary particles of 0.25 or smaller are added as an external additive, and a process for producing a toner for developing electrostatic images which comprises melt mixing at least a binder resin and a coloring agent, forming a powder material by pulverizing the obtained mixture after cooling, rounding the powder material by a heat treatment and adding the above inorganic fine particles to the rounded powder material.Type: ApplicationFiled: January 25, 2007Publication date: September 16, 2010Applicant: IMEX CO., LTD.Inventors: Shigetoshi Asano, Shuzo Nakayama, Masashi Ueda, Katsutoshi Saito, Kazuma Okamura
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Publication number: 20100215408Abstract: A developer has a molecular weight distribution of its tetrahydrofuran soluble portion measured by a gel permeation chromatography. In the molecular weight distribution, the main peak is in a range from 2×103 to 3×104 weight-average molecular weight (Mw), the shoulder peak is in a range from 200 to 500 Mw, and a half-value width of the main peak is equal to or less than 50000. A glass-transition temperature Tg of the developer is a range from 55° C. to 80° C.Type: ApplicationFiled: February 16, 2010Publication date: August 26, 2010Applicant: OKI DATA CORPORATIONInventor: Yuki MATSUURA
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Publication number: 20100203439Abstract: Environmentally friendly toner particles are provided which may, in embodiments, include a bio-based amorphous polyester resin, optionally in combination with another amorphous resin and/or a crystalline resin. Toner particles may, in embodiments, have a core-shell configuration, with the shell formed of the bio-based amorphous polyester resin, the amorphous polyester resin, the crystalline polyester resin, or combinations thereof.Type: ApplicationFiled: February 6, 2009Publication date: August 12, 2010Applicant: Xerox CorporationInventors: Ke Zhou, Richard P.N. Veregin, Gwynne McAneney-Lannen, Edward G. Zwartz, Maria N.V. McDougall, Guerino Sacripante, Karen A. Moffat
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Publication number: 20100196815Abstract: Electrostatic charge image developing toner Electrostatic charge image developing toner containing external additives comprising pyrogenically prepared surface modified silicon-dioxide-titanium mixed oxides.Type: ApplicationFiled: March 27, 2007Publication date: August 5, 2010Applicant: EVONIK DEGUSSA GMBHInventors: Kai Schumacher, Paul Brandl, Akira Inoue, Yuki Amano
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Publication number: 20100183689Abstract: The present invention relates to a method of manufacturing titania nanoparticles, and specifically to a method of manufacturing titania nanoparticles wherein the particle size is uniform, it is possible to manufacture monodisperse particles without aggregation among particles, a uniform coating can be applied, that is suitable to large-scale production, and that can obtain high-resolution images by maintaining the toner electric charge and electric charge distribution; and the developer included in said titania nanoparticles.Type: ApplicationFiled: March 30, 2010Publication date: July 22, 2010Applicant: Sukgyung AT Co., Ltd.Inventor: Hyung Sup Lim
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Patent number: 7759036Abstract: The object of the invention is to provide a toner enabling excellent transferring properties, cleanability, and fixability and forming a high-precision image without substantially degraded image quality even after printed on a number of sheets of paper. The invention also provides the toner-production method, an image forming apparatus, an image forming method, and a process cartridge. To this end, the present invention provides a toner which comprises toner-base particles containing a binder resin and a filler, and inorganic fine particles, in which the filler is included in a filler-layer in the vicinity of surfaces of the toner-base particles, the number average particle diameter of the primary particles of the inorganic fine particles is 90 nm to 300 nm, and the average circularity of the toner is 0.95.Type: GrantFiled: August 4, 2005Date of Patent: July 20, 2010Assignee: Ricoh Company, Ltd.Inventors: Tomoko Utsumi, Satoshi Mochizuki, Hideki Sugiura, Tomoyuki Ichikawa, Minoru Masuda, Shinya Nakayama
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Patent number: 7749671Abstract: To provide a toner containing at least a toner base containing a binder resin and a colorant, and an inorganic fine particle, wherein the inorganic fine particle contains a compound oxide expressed by the following Composition Formula (1): [M1]aSibOc??Composition Formula (1) where “M1” represents a metal element selected from Sr, Mg, Zn, Co, Mn and Ce, “a” and “b” each represents an integer of 1 to 9 and “c” represents an integer of 3 to 9, wherein an average primary particle diameter of the compound oxide is 0.02 ?m to 1.5 ?m, and an average secondary particle diameter of the compound oxide is 0.08 ?m to 3.5 ?m, where the secondary particle is an aggregate of the primary particles.Type: GrantFiled: September 15, 2006Date of Patent: July 6, 2010Assignee: Ricoh Company, Ltd.Inventors: Atsushi Yamamoto, Masahide Inoue, Chiyoshi Nozaki, Minoru Nakamura, Masayuki Hagi, Yoshihiro Mikuriya, Tsuyoshi Nozaki, Hiroaki Kato, Takuya Kadota, Katsunori Kurose, Hideaki Yasunaga, Yoshimichi Ishikawa
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Publication number: 20100159377Abstract: The present invention is directed to surface treatment of toner particles and the toner developers used for the dry development of electrostatic charge images.Type: ApplicationFiled: December 18, 2008Publication date: June 24, 2010Inventors: Patrick M. Lambert, Bret Johnston
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Publication number: 20100159378Abstract: This invention provides a toner with improved charge and charge stability by suitable addition of extra particulate additives (EPA) such as aluminum cerium oxide and/or cerium zirconium oxide. The additives may be combined with toner in a conical mixer having selected temperature control. The invention also provides toner which may provide reduced print quality defects such as ghosting or residual image and fade-to-color.Type: ApplicationFiled: December 19, 2008Publication date: June 24, 2010Inventors: Kasturi Rangan Srinivasan, Rick Owen Jones
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Patent number: 7740998Abstract: A positively chargeable developer is provided which is capable of providing stable image quality without causing any image defect even in long-term use. The developer includes at least positively chargeable toner particles each containing at least a binder resin and magnetic iron oxide, silica and an inorganic fine powder. A unconfined yield strength at a major consolidation stress of 5 kPa of the developer is in the range of 0.1 to 2.5 kPa, and a unconfined yield strength at a major consolidation stress of 20 kPa of the developer is in the range of 2.5 to 5.5 kPa.Type: GrantFiled: February 16, 2006Date of Patent: June 22, 2010Assignee: Canon Kabushiki KaishaInventors: Katsuhisa Yamazaki, Daisuke Yoshiba, Masami Fujimoto
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Patent number: 7741001Abstract: A process for preparing a toner for electrostatic image development, the process comprising the steps of: (S1) mixing an aqueous pigment dispersion and an aqueous resin particle dispersion containing self-dispersible polyester resin particles as a binder resin to prepare a mixture; and (S2) adding a polyvalent metal salt as a flocculant to the mixture while stirring to form aggregates of the pigment bonded to the resin particles, wherein the self-dispersible polyester resin is prepared by reacting a carboxylic acid compound with an alcohol compound inclusive of a polyhydric alcohol, the carboxylic acid compound being one or more of a polycarboxylic acid having three or more carboxyl groups and its anhydride.Type: GrantFiled: April 3, 2006Date of Patent: June 22, 2010Assignee: Sharp Kabushiki KaishaInventor: Takanori Kamoto
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Patent number: 7723001Abstract: An electrophotographic toner includes toner parent particles containing a binder resin, a colorant and a charge control agent; and an external additive added to the surface of the toner parent particles. The toner further includes positively chargeable silica and polymer beads in addition to large particle diameter silica, small particle diameter silica and titanium oxides. Thus, the toner can maintain its charge quantity and distribution stably even during environmental changes and after long image printing times, thereby preventing the contamination of the non-image part and the filming.Type: GrantFiled: July 23, 2007Date of Patent: May 25, 2010Assignee: Samsung Electronics Co., Ltd.Inventor: Sang-woo Kim
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Publication number: 20100104968Abstract: A polymerized toner is provided. The polymerized toner comprises a reactive anionic surfactant having at least one reactive functional group. The reactive anionic surfactant is added simultaneously with a dispersant to prepare an aqueous dispersion or is added within 2 hour after a polymerization reaction of a monomer mixture is initiated in an aqueous dispersion. This simultaneous or rapid addition allows the reactive anionic surfactant to be dispersed on the surface of the toner particles. The reactive anionic surfactant is located over the entire surface of the toner particles to increase the surface charge density of the toner, achieving good charge stability and excellent imaging characteristics.Type: ApplicationFiled: October 23, 2009Publication date: April 29, 2010Inventors: Dong Jin Park, Chang Soon Lee, Wook Jang, Yu Na Kim, Jung Woo Kim
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Patent number: 7704661Abstract: A toner is provided which has toner particles and a fine silica powder mixed by external addition to the toner particles. The toner has a weight average particle diameter of 4.0 to 9.0 ?m. The fine silica powder is subjected to hydrophobic treatment with dimethylsilicone oil, and has, in particle size distribution based on volume, a peak at which cumulative frequency is largest, in the measurement range of 0.02 ?m to 1,000.00 ?m; the cumulative frequency of 0.10 ?m to less than 1.00 ?m being 7.0% or less, and, the fine silica powder fulfills the following conditions: 1) A+B?93.0; 2) 0.45?A/B?6.00; and 3) the value of [(carbon content of the treated fine silica powder)/(BET specific surface area of fine silica powder before hydrophobic treatment)] is 0.030 or more to 0.055 or less.Type: GrantFiled: September 21, 2009Date of Patent: April 27, 2010Assignee: Canon Kabushiki KaishaInventors: Naotaka Ikeda, Shinya Yachi, Katsuyuki Nonaka, Emi Watanabe, Koji Abe, Nobuhisa Abe
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Patent number: 7695882Abstract: The present invention relates to controlling the mass flow of toner in an image forming device or a toner cartridge. The toner composition includes extra particulate additives including a conductive additive. The extra particulate additives may also include relatively small silica particles or relatively large silica.Type: GrantFiled: February 1, 2007Date of Patent: April 13, 2010Assignee: Lexmark International, Inc.Inventors: Scott Moreland Broce, Robert Joseph Firmature, Yueping Fu, Matthew David Heid, Lance Tisdale Hoshiko, James Craig Minor, Karen Eileen Zrebiec
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Patent number: 7695880Abstract: A toner, and an electrophotographic apparatus and an electrophotographic process cartridge using the toner are provided having excellent charge stability without adversely affecting electric properties of the toner even when used for a long period of time and having excellent image density stability without bringing about image deletion and blurring. The toner includes colored particles containing at least a binder resin and a colorant, and two or more external additives. At least one of the external additives includes hydrophobic treated mesoporous particles, and the mesoporous particles are inorganic particles of at least one type selected from the group consisting of silica, titanium oxide, alumina, cerium oxide, and strontium titanate.Type: GrantFiled: May 29, 2007Date of Patent: April 13, 2010Assignee: Canon Kabushiki KaishaInventor: Kimihiro Yoshimura
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Publication number: 20100080916Abstract: A paper sizing or coating composition is provided, which includes: a first binder resin, which is compatible with dry toner binder resin; a second binder resin, which is compatible with liquid toner binder resin, and which is different from the first binder resin; a first pigment, which has a BET surface area of from greater than zero to about 35 m2/g; and a second pigment, which has a BET surface area of about 35 m2/g or greater, and which is different from the first pigment. Recording sheets which include the composition, methods of making the composition and recording sheets, and methods for making an image are provided.Type: ApplicationFiled: September 11, 2009Publication date: April 1, 2010Applicant: INTERNATIONAL PAPER COMPANYInventors: Jay C. Song, Sen Yang, Michelle X. Wang, Pat Morabito
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Patent number: 7687213Abstract: The present invention provides a custom color toner having a first particle size. Colored particles are attached to the surface of the base toner in an amount sufficient to provide a predetermined color to the base toner. The colored particles have a second particle size less than the first particle size.Type: GrantFiled: August 28, 2006Date of Patent: March 30, 2010Assignee: Eastman Kodak CompanyInventors: Lloyd A. Lobo, Eric C. Stelter
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Publication number: 20100075242Abstract: A toner for electrostatic image development containing (a) a toner matrix particle containing a resin binder, and (b) an external additive added to the toner matrix particles, wherein the resin binder contains a polyester A obtained by polycondensing an alcohol component and a carboxylic acid component containing isophthalic acid and/or an ester thereof, and wherein the external additive contains fine silica particles containing a metal or a metal oxide; and A method of forming fixed images including the step of applying the toner for electrostatic image development to an image-forming apparatus according to a non-contact fusing method. The toner for electrostatic image development of the present invention is suitably used in developing latent images formed in, for example, electrophotography, an electrostatic recording method, an electrostatic printing method, or the like.Type: ApplicationFiled: September 14, 2009Publication date: March 25, 2010Applicant: KAO CORPORATIONInventors: Satoshi Kunii, Masahito Yamazaki
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Publication number: 20100040968Abstract: A toner composition and method of providing such composition which may be used in a printer or printer cartridge. The composition may include toner particles mixed with silica particles having a primary particle size in the range of 30 nm to 60 nm present in the range of 0.1 to 2.0% by weight of the toner composition and silica particles having a primary particle size in the range of 60 nm to 150 nm present in the range of 0.1 to 2% by weight of the toner composition.Type: ApplicationFiled: August 12, 2008Publication date: February 18, 2010Inventors: Ligia Aura Bejat, Rick Owen Jones, Bryan Patrick Livengood, Kasturi Rangan Srinivasan, Devon Jean Vaccaro Strain
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Publication number: 20100015421Abstract: When color images are printed on a substantially transparent substrate, such as a transparency film, or on a highly colored substrate, the color properties of image may be compromised. When color images are printed on a substantially transparent substrate, the images do not have the maximum possible color saturation because a large portion of the incident light is not reflected back. As a result, images appear to be dull and lower in contrast. When color images are printed on highly colored substrates, the color properties of the image are also influenced by the color of the substrate. In order to enable printing on such substrates, an opaque toner was developed which comprises predispersed inorganic filler with a refractive index of greater than 1.75.Type: ApplicationFiled: May 29, 2009Publication date: January 21, 2010Inventors: Dinesh Tyagi, Louise Granica
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Publication number: 20100009280Abstract: Treated metal oxide particles include metal oxide particles treated with at least a charge modifying agent. The charge modifying agent is represented by the following formula: An-Zc-Yb—Ar(EW)a wherein Ar represents an aromatic group, EW represents an electron withdrawing group, Y represents a spacer group, Z represents an alkylene group, An represents an anchor group, a is an integer from 1 to 5, b is 0 or 1, and c is 0 or 1. The treated metal oxide particles may also be treated with a second charge modifying agent or with a hydrophobicity-imparting agent. A toner composition including toner particles and treated metal oxide particles is also disclosed.Type: ApplicationFiled: July 9, 2008Publication date: January 14, 2010Inventors: Jinsong Liu, Hairuo Tu, Dmitry Fomitchev
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Publication number: 20090311618Abstract: Provided is a non-magnetic mono-component color toner with improved charge properties by surface modification with a charge control agent. The color toner is prepared by spheroidizing toner core particles including a binder and a colorant in the presence of 0.5 to 3 parts by weight of a charge control agent and coating the resultant spherical toner core particles with a first spherical organic powder with an average particle size of 50 to 120 nm, a second spherical organic powder with an average particle size of 600 to 1,000 nm, silica with an average particle size of 5 to 20 nm, and titanium dioxide with an average particle size of 300 to 1,000 nm. The color toner exhibits excellent surface charge properties (e.g., a narrow charge distribution, high chargeability, and good charge maintenance capability), thereby ensuring low image/background contamination, high transfer efficiency, good image density and long-term stability.Type: ApplicationFiled: June 15, 2009Publication date: December 17, 2009Inventors: Chang-Soon Lee, Hyeung-Jin Lee, Je-Sik Jung
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Publication number: 20090280422Abstract: A toner for development of electrostatic images, comprising colored resin particles containing a binder resin and a colorant, and an external additive, wherein the external additive contains fine particles of an inorganic layered clay compound, and the inorganic layered clay compound is an intercalation compound with a quaternary ammonium ion intercalated between layers of the inorganic layered clay compound or has an interlayer distance of 1.5 to 4 nm.Type: ApplicationFiled: June 19, 2007Publication date: November 12, 2009Applicant: Zeon CorporationInventor: Kazuya Shiokawa
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Patent number: 7611815Abstract: An external additive for a toner for electrophotography which contains oxide fine particles which contain silicon, in which the oxide fine particles have a primary particle diameter of 30 nm to 300 nm in number average, a standard deviation ? of a particle size distribution of the primary particle diameter satisfies a relation of: R/4???R, in which the R expresses the primary particle diameter, the oxide fine particles are substantially spherical having a circularity SF1 defined as equation (1) of 100 to 130 and a circularity SF2 defined as equation (2) of 100 to 125; SF1=(L2/A)×(?/4)×100??equation (1) SF2=(P2/A)×(1/4?)×100??equation (2), in the equations, “L” expresses the absolute maximum length of the oxide fine particles; “A” expresses a projected area of the oxide fine particles; and “P” expresses a maximum perimeter of the oxide fine particles.Type: GrantFiled: July 15, 2003Date of Patent: November 3, 2009Assignee: Ricoh Company, Ltd.Inventors: Hideki Sugiura, Satoshi Mochizuki, Kazuhiko Umemura, Shinya Nakayama, Yasuo Asahina
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Patent number: 7608377Abstract: To provide an image forming method including forming a latent electrostatic image on a latent electrostatic image bearing member, developing the latent electrostatic image using a toner to form a visible image, transferring the visible image to a recording medium, and fixing a transfer image transferred on the recording medium, wherein the toner includes a toner base particle containing at least a binder resin, a colorant and an inorganic fine particle, and a charge control agent; and wherein the condition Xsurf>Xtotal is satisfied (where Xsurf is an average proportion of the inorganic fine particles in a near-surface region of the toner base particle, Xtotal is an average proportion of inorganic fine particles in the whole toner base particle.Type: GrantFiled: September 12, 2006Date of Patent: October 27, 2009Assignee: Ricoh Company, Ltd.Inventors: Shinya Nakayama, Hisashi Nakajima, Hideki Sugiura, Fumihiro Sasaki, Akihiro Kotsugai, Satoshi Mochizuki
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Patent number: 7601472Abstract: Toner compositions have a post-blended particulate additive which comprises aluminum oxide and aluminum hydroxide with, optionally, a third component such as silica or a wax, which is a tribo-charging additive which, upon tribo-charging of the toner particles, shifts the charge distribution in either the positive or negative direction. As well as providing toner compositions having adequate fluidity, the use of pre-extrusion charge-control additives can be avoided. There are also advantages, for example, in terms of charge distribution characteristics, stability of charge distribution, and avoidance of matting effects. Developer compositions are formed by admixture with suitable carrier particles.Type: GrantFiled: August 1, 2003Date of Patent: October 13, 2009Assignee: Akzo Nobel Coatings International B.V.Inventor: Kevin Jeffrey Kittle