Polyester Backbone Binder (e.g., Condensation Reaction Product, Etc.) Patents (Class 430/109.4)
  • Patent number: 8592124
    Abstract: A toner having: a peak temperature before fixation T1a of about 40° C. or more; and a peak temperature after fixation T1b that is lower than T1a by from about 10° C. to about 35° C.: T1a being a peak temperature of an endothermic peak occurring at the lowest temperature in a range of from 0° C. to 100° C. and obtained at a first warming-up step of a differential scanning calorimetry measurement that uses a toner before fixation as a sample; T1b being a peak temperature of an endothermic peak occurring at the lowest temperature within a range of from 0° C. to 100° C. and obtained at a first warming-up step of a differential scanning calorimetry measurement that uses a toner after fixation as a sample; and the toner after fixation being contained in a fixed image transferred from a transferring member and fixed on a recording medium, a maximum width of an image defect formed after conducting a folding test of the fixed image being 0.30 mm or less.
    Type: Grant
    Filed: July 7, 2008
    Date of Patent: November 26, 2013
    Assignee: Fuji Xerox Co., Ltd.
    Inventors: Yasuhiro Oya, Atsuhiko Eguchi
  • Patent number: 8592112
    Abstract: An orange toner including a binder resin containing a polyester resin having a dodecenyl succinic acid structure as a constituent unit; and C.I. Pigment Orange 38 in a blending amount of from 5% by mass to 18% by mass relative to the whole mass of the toner and a toner storage container for storing the same, an orange developer and a process cartridge for storing the same, a color toner set, and an image forming apparatus.
    Type: Grant
    Filed: March 25, 2011
    Date of Patent: November 26, 2013
    Assignee: Fuji Xerox Co., Ltd.
    Inventors: Satoshi Yoshida, Akira Matsumoto, Masanobu Ninomiya, Yusuke Ikeda
  • Patent number: 8586272
    Abstract: The present disclosure provides toner compositions able to prevent the formation of mold or bacterial growth during storage. In embodiments, toners may include at least one biocide that prevents the formation of mold and/or bacteria in a toner composition, including any emulsion that may be utilized in forming the toner composition. In embodiments, the biocide may also improve charging characteristics of the toner.
    Type: Grant
    Filed: July 28, 2009
    Date of Patent: November 19, 2013
    Assignee: Xerox Corporation
    Inventors: Kimberly D. Nosella, Maria N. V. McDougall, Melanie Lynn Davis
  • Patent number: 8586273
    Abstract: Disclosed is a binder resin for a toner containing at least a carboxyl group-containing vinyl resin (C), a glycidyl group-containing vinyl resin (E), a reaction product of the vinyl resins and a saturated crystalline polyester (S), wherein the saturated crystalline polyester (S) has a predetermined melting point and a predetermined metal component (M), and the binder resin for a toner has a predetermined loss modulus (G?) and a predetermined storage modulus (G?).
    Type: Grant
    Filed: November 15, 2010
    Date of Patent: November 19, 2013
    Assignee: Mitsui Chemicals, Inc.
    Inventors: Hiroshi Matsuoka, Hiroyuki Takei, Linwood Blanton Muire, III
  • Publication number: 20130302731
    Abstract: An object of the present invention is to provide a toner that produces an excellent bending resistance in the output image and that also exhibits an excellent low-temperature fixability and an excellent storage stability. This toner includes a binder resin and a thermoplastic elastomer having a crystalline part, wherein the binder resin and the thermoplastic elastomer in the toner are compatible with each other and the toner has a crystalline part originating from the thermoplastic elastomer.
    Type: Application
    Filed: May 2, 2013
    Publication date: November 14, 2013
    Applicant: CANON KABUSHIKI KAISHA
    Inventors: Hayato Ida, Takashi Hirasa, Ryo Natori, Junichi Tamura, Yuya Chimoto, Takaho Shibata
  • Patent number: 8580472
    Abstract: Disclosed is a polyester resin comprising the polycondensation product of (a) at least one diacid, acid ester, or diester; and (b) at least one diol; wherein either (i) at least one diacid, acid ester, or diester comprises a rosin diacid, rosin acid ester, or rosin diester; or (ii) at least one diol comprises a rosin diol, and wherein at least one of the rosin diacid, rosin acid ester, rosin diester, or rosin diol is either (A) an ester of a functionalized rosin or an ester of a reduced functionalized rosin, or (B) a dimerized rosin. Also disclosed is a toner composition comprising particles which comprise the disclosed polyester resin and an optional colorant.
    Type: Grant
    Filed: May 16, 2011
    Date of Patent: November 12, 2013
    Assignee: Xerox Corporation
    Inventors: Valerie M Farrugia, Ke Zhou, Guerino G Sacripante, Rina Carlini, Paul J Gerroir
  • Patent number: 8580471
    Abstract: A bio-toner for use in electrophotographic image forming that contains a bio-resin component that is at least partially derived from a renewable resource is provided. A method of making the bio-toner that contains a bio-resin component for use in electrophotographic image forming is also provided. A method for electrophotographic image formation using the bio-toner that contains a bio-resin is also provided.
    Type: Grant
    Filed: March 19, 2010
    Date of Patent: November 12, 2013
    Assignee: Mitsubishi Kagaku Imaging Corporation
    Inventors: Takeshi Owada, David Urban
  • Patent number: 8580469
    Abstract: Disclosed is a toner composition comprising: (a) a resin; and (b) a colorant which comprises: (1) Pigment Red 269; (2) Pigment Red 185; and (3) Pigment Red 122.
    Type: Grant
    Filed: December 15, 2011
    Date of Patent: November 12, 2013
    Assignee: Xerox Corporation
    Inventors: Grazyna E. Kmiecik-Lawrynowicz, Maura A. Sweeney, Mark E. Mang, Kirk L. Stamp, Robert D. Bayley
  • Patent number: 8580473
    Abstract: A toner includes a binder resin and a colorant. The binder resin contains a polyester resin A obtained by subjecting aromatic dicarboxylic acid, rosin, and trivalent or higher-valent alcohol as starting materials to polycondensation, a content of the rosin in a sum of the starting materials being 60% by weight or more, and a polyester resin B obtained by subjecting aromatic dicarboxylic acid and polyhydric alcohol as starting materials to polycondensation, the polyester resin B having a viscosity of 103 Pa·s or more and 105 Pa·s or less at a softening temperature of the polyester resin A, the polyester resin B being contained in an amount of 50 parts by weight or more and 200 parts by weight or less relative to 100 parts by weight of the polyester resin A.
    Type: Grant
    Filed: June 9, 2011
    Date of Patent: November 12, 2013
    Assignee: Sharp Kabushiki Kaisha
    Inventors: Satoru Ariyoshi, Yasuhiro Shibai, Nobuhiro Maezawa, Katsuru Matsumoto
  • Patent number: 8574803
    Abstract: Disclosed is a toner that includes a mixture of a bio-based amorphous polyester resin, a crystalline polyester resin, and a colorant.
    Type: Grant
    Filed: December 23, 2011
    Date of Patent: November 5, 2013
    Assignee: Xerox Corporation
    Inventors: Guerino G Sacripante, Ke Zhou, Rosa M Duque, Sonja Hadzidedic, Biritawit Asfaw
  • Patent number: 8574808
    Abstract: The present invention relates to a resin emulsion being produced by neutralizing a resin binder containing acid group with a basic compound in an aqueous medium wherein the resin binder containing acid group contains a polyester produced from a raw monomer composition containing a trivalent or higher-valent polyhydric alcohol in an amount of 1 to 15 mol %; a process for producing the resin emulsion; and a toner for electrophotography using the resin emulsion. In the resin emulsion of the present invention, a resin is readily emulsified therein even when using a crosslinked polyester as the resin, and the resin emulsion is substantially free from hydrolysis of the resin and can produce a toner having an excellent heat-resistant storage property.
    Type: Grant
    Filed: July 6, 2007
    Date of Patent: November 5, 2013
    Assignee: KAO Corporation
    Inventors: Hiroshi Mizuhata, Takashi Kubo, Takashi Mukai
  • Publication number: 20130288174
    Abstract: A toner is provided that exhibits a satisfactory heat-resistant storability and an excellent low-temperature fixability. The toner has toner particles each of which contains at least a binder resin and a wax, and is characterized in that this toner is obtained by attaching a metal compound to the surface of the toner particle and thereafter performing a surface treatment with a hot air current; the binder resin contains at least a polyester resin; and the metal compound is formed by coordinating or bonding a specific aromatic oxycarboxylic acid to a metal.
    Type: Application
    Filed: December 9, 2011
    Publication date: October 31, 2013
    Applicant: CANON KABUSHIKI KAISHA
    Inventors: Yoshiaki Shiotari, Hiroyuki Fujikawa, Kunihiko Nakamura, Nozomu Komatsu, Kosuke Fukudome, Takayuki Itakura
  • Patent number: 8568951
    Abstract: A toner including a main body particle, a layer B located overlying the main body particle, and a layer A located overlying the layer B is provided. The binder resin includes an amorphous resin and a crystalline resin. The layer B is comprised of particles of a resin B. The layer A is comprised of particles of a resin A. A method of manufacturing the above toner is also provided. The method includes dissolving or dispersing toner components in an organic solvent to prepare a toner components liquid. The toner components include the binder resin. The method further includes emulsifying the toner components liquid in an aqueous medium to prepare an emulsion. The aqueous medium contains the particles of the resins A and B. The method further includes removing the organic solvent from the emulsion and heating the emulsion.
    Type: Grant
    Filed: March 7, 2012
    Date of Patent: October 29, 2013
    Assignee: Ricoh Company, Ltd.
    Inventors: Masaki Watanabe, Hiroshi Yamashita, Satoyuki Sekiguchi
  • Patent number: 8568949
    Abstract: A toner for developing an electrostatic charge image which contains a polyester resin as a binder resin is provided. The toner has excellent toner properties including low temperature fixing properties, anti-blocking property and anti-offset property, etc. Also a polyester resin for a toner is provided, which is used in the above-mentioned toner. As the binder resin for toner, a polyester resin comprising (1) an aromatic dicarboxylic acid and (2) a disproportionated rosin as an acid component, and (3) a tri- or more-valent polyhydric alcohol as an alcohol component is used, wherein the molar ratio (3)/(1) of the alcohol component (3) and the acid component (1) is from 1.05 to 1.65 and the molar ratio (2)/(1) of the acid components (2) and (1) is from 0.40 to 2.60.
    Type: Grant
    Filed: June 9, 2009
    Date of Patent: October 29, 2013
    Assignee: Japan U-Pica Company Ltd.
    Inventors: Akira Yamane, Tetsuji Moroiwa, Koji Yamamoto
  • Patent number: 8568950
    Abstract: There is provided a polyester resin for a toner, including: a polycondensate of a polyvalent carboxylic acid component and a polyhydric alcoholic component, wherein the polyhydric alcoholic component contains a rosin diol represented by the following Formula (1) and a content of the rosin diol is 80 mole % to 100 mole % based on the total polyhydric alcoholic component. wherein, each of R1 and R2 independently represents a hydrogen atom or a methyl group; L1 represents a divalent linking group having the following Formula (I); each of L2 and L3 independently represents a divalent linking group selected from the group consisting of carbonyl groups, carboxyl groups, ether groups, sulfonyl groups, substituted or unsubstituted chained alkylene groups, substituted or unsubstituted cyclic alkylene groups, substituted or unsubstituted arylene groups, and combinations thereof; and each of A1 and A2 independently represents a rosin ester group.
    Type: Grant
    Filed: September 25, 2012
    Date of Patent: October 29, 2013
    Assignee: Fuji Xerox Co., Ltd.
    Inventors: Hirofumi Shiozaki, Sumiaki Yamasaki, Satoshi Hiraoka, Yuki Sasaki, Susumu Yoshino, Hirotaka Matsuoka, Emi Miyata
  • Publication number: 20130280648
    Abstract: A toner composition including at least one phosphorescent pigment that absorbs energy released by natural or artificial light, and is able to be seen in a dark environment through luminescence of a certain color created by the energy released as light, and a method of forming and using the toner are described. The phosphorescent toner has a particle size in the range of about 15-40 microns, which allows the toner to have the ability to absorb and then release the needed amount of light energy to be noticeable in a dark environment.
    Type: Application
    Filed: April 18, 2012
    Publication date: October 24, 2013
    Applicant: TROY GROUP, INC.
    Inventors: Carrie A. Gilson, Kevin L. Heilman, Michael R. Rlley
  • Patent number: 8563627
    Abstract: A process for making a self-emulsifying granule suitable for use in forming latex emulsions includes contacting a resin with a solid or highly concentrated surfactant, a solid neutralization agent and water in the absence of an organic solvent to form a mixture, melt mixing the mixture, and forming self-emulsifying granules of the melt mixed mixture. Self-emulsifying granules are also provided and configured to form a latex emulsion when added to water, which may then be utilized to form a toner.
    Type: Grant
    Filed: July 30, 2009
    Date of Patent: October 22, 2013
    Assignee: Xerox Corporation
    Inventors: Santiago Faucher, Joo T. Chung, Shigang Qiu, Fumii Higuchi
  • Patent number: 8563208
    Abstract: A toner for developing an electrostatic charge image includes: an amorphous polyester resin; a crystalline polyester resin; and a releasing agent, an amount of the releasing agent in the toner being from 5 to 15% by weight; an amount of the releasing agent present at a surface of the toner being from 10 to 35% by weight; and the toner showing at least one endothermic peak in each of a temperature range from 45 to 60° C., a temperature range from 65 to 80° C., and a temperature range from 85 to 100° C. in a temperature-rise process of differential scanning calorimetry of the toner.
    Type: Grant
    Filed: July 2, 2012
    Date of Patent: October 22, 2013
    Assignee: Fuji Xerox Co., Ltd.
    Inventors: Hiroshi Nakazawa, Masanobu Ninomiya, Hirokazu Hamano
  • Patent number: 8563207
    Abstract: Disclosed is a toner binder which has high storage stability and can achieve both of good low-temperature fixability and good hot offset resistance (a broadened fixing temperature range). Specifically disclosed is a toner binder comprising, as constituting units, a carboxylic acid component (x) and a polyol component (y), wherein the component (x) comprises two or more kinds of dicarboxylic acids (X1), selected from among aromatic dicarboxylic acids and ester-forming derivatives of the same, in a total amount of 80 mol % or more and a trivalent or higher polycarboxylic acid (x2); the component (y) comprises a polyester resin (P) which is constituted by a polyester resin (A) comprising 80 mol % or more of an aliphatic diol (y1) having 2 to 10 carbon atoms optionally together with a linear polyester resin (B); and the storage modulus at 150° C. [G?150] of resin (A) is 20000 dyn/cm2 or more and the ratio of [G?150] to the storage modulus as 180° C. [G?180] thereof, i.e., [G?150]/[G?180], is 15 of less.
    Type: Grant
    Filed: March 31, 2010
    Date of Patent: October 22, 2013
    Assignee: Sanyo Chemical Industries, Ltd.
    Inventors: Masashi Minaki, Shinichi Maeda, Mitsumasa Kamura, Shuichi Shinohara, Yuya Iwagoe
  • Patent number: 8563205
    Abstract: Provided is a magenta toner containing toner particles that contain a colorant and a binder resin, wherein the colorant contains C.I. Pigment Red 57:1 and C.I. Pigment Yellow 180, a mass ratio between the C.I. Pigment Red 57:1 and the C.I. Pigment Yellow 180 being 99:1 to 10000:1, and wherein the binder resin contains a polyester resin that has a repeating unit derived from bisphenol A ethylene oxide represented by formula (1): wherein each of m and n independently represents an integer of 2 to 4.
    Type: Grant
    Filed: September 2, 2011
    Date of Patent: October 22, 2013
    Assignee: Fuji Xerox Co., Ltd.
    Inventors: Eisuke Iwazaki, Shinya Sakamoto, Tsuyoshi Murakami, Satoshi Yoshida, Satoshi Inoue
  • Publication number: 20130273469
    Abstract: Provided is a toner binder which combines excellent low-temperature fixing properties and excellent hot-offset resistance (namely which permits a wide fixing-temperature range) and which exhibits excellent storage stability. The toner binder comprises (A) a polyester resin, (B) a specific crystalline resin and, if necessary, (C) a non-crystalline linear polyester resin. The polyester resin (A) comprises a carboxylic acid component (x) and a polyol component (y) as the essential constituent units, said component (x) comprising two or more kinds of dicarboxylic acids (x1) selected from among aromatic dicarboxylic acids and ester-forming derivatives thereof in a total amount of 80 mol % or more and further containing an at least trivalent polycarboxylic acid (x2) as another essential component, and said component (y) comprising a C2-10 aliphatic diol (y1) in an amount of 50 mol % or more. Further, the polyester resin (A) exhibits a storage modulus at 150° C.
    Type: Application
    Filed: October 6, 2011
    Publication date: October 17, 2013
    Applicant: SANYO CHEMICAL INDUSTRIES, LTD.
    Inventors: Takashi Akutagawa, Masakazu Iwata, Masaru Honda, Tomoyuki Ariyoshi
  • Publication number: 20130273470
    Abstract: The present invention relates to a toner for electrophotography including core-shell particles as a resin binder each including a core portion containing an amorphous resin (A) having a softening point of 105° C. or lower which is obtained by polycondensing a carboxylic acid component containing an alkenyl succinic acid with an alcohol component; and a shell portion containing an amorphous resin (B) obtained by polycondensing an alcohol component containing an aliphatic diol having 2 to 6 carbon atoms with a carboxylic acid component containing a trivalent or higher-valent polycarboxylic acid compound in an amount of 20 mol % or less. The toner for electrophotography according to the present invention is excellent in heat resistant storage property, low-temperature fusing property and durability.
    Type: Application
    Filed: March 14, 2013
    Publication date: October 17, 2013
    Applicant: Kao Corporation
    Inventors: Norihiro Fukuri, Osamu Yamashita, Hiroki Kubo, Shoichi Murata, Takahiro Yoshikawa
  • Patent number: 8557491
    Abstract: A toner according to the present invention contains at least a polyester resin as a binder resin, a colorant, a releasing agent, a fixing-assisting component, and a fatty acid, wherein the fixing-assisting component has a melting point of 60° C. to 120° C. and contains at least one of an esterified compound obtained by esterification of the fatty acid and an amide compound obtained by amidation of the fatty acid.
    Type: Grant
    Filed: July 27, 2009
    Date of Patent: October 15, 2013
    Assignee: Ricoh Company, Ltd.
    Inventors: Tsuyoshi Sugimoto, Naohito Shimota, Hiroshi Yamashita, Naohiro Watanabe, Shinichi Wakamatsu, Masaki Watanabe
  • Patent number: 8557493
    Abstract: Environmentally friendly toner particles are provided which may include a bio-based amorphous polyester resin, optionally in combination with another amorphous resin and/or a crystalline resin. Methods for providing these toners are also provided. In embodiments, the bio-based amorphous polyester resin is modified with a multi-functional bio-based acid, thereby providing acid-functionalized polyesters, which can be readily emulsified in emulsion aggregation processes for toner fabrication.
    Type: Grant
    Filed: December 21, 2010
    Date of Patent: October 15, 2013
    Assignee: Xerox Corporation
    Inventors: Valerie M. Farrugia, Guerino G. Sacripante, Sonja Hadzidedic
  • Publication number: 20130266896
    Abstract: An emulsion aggregation toner composition is disclosed that includes toner particles with at least one small crystalline molecule, such as a trans-cinnamic diester, at least one amorphous resin, optional waxes, coagulants, pigments, and combinations thereof. In other embodiments, the small crystalline molecule is biodegradable and can be made using raw materials derived from renewable resources. Such small crystalline molecules are also compatible with amorphous binder resins, to provide toner compositions with reduced minimum fusing temperatures without sacrificing electrical performance. Processes for preparing emulsion aggregation toner compositions are also described.
    Type: Application
    Filed: April 4, 2012
    Publication date: October 10, 2013
    Applicant: XEROX CORPORATION
    Inventors: Ke ZHOU, Adela GOREDEMA, Karen MOFFAT, Edward G. ZWARTZ, Mike HAWKINS, Rosa DUQUE, Guerino G. SACRIPANTE
  • Patent number: 8551681
    Abstract: An emulsion aggregation toner formulation for electrophotography and a method for preparation thereof. The emulsion aggregation toner formulation includes a polyester resin emulsion formed using an extruded polyester binder resin having a broad molecular weight distribution. The extruded polyester binder resin is formed using a plurality of polyester binder resins. Further, the emulsion aggregation toner formulation comprises at least one colorant dispersion and a wax dispersion.
    Type: Grant
    Filed: September 8, 2008
    Date of Patent: October 8, 2013
    Assignee: Lexmark International, Inc.
    Inventors: Michael James Bensing, Craig Michael Bertelsen, John Joseph Kraseski, Bryan Patrick Livengood, Jing X. Sun, Vincent Wen-Hwa Ting
  • Publication number: 20130260302
    Abstract: A toner, including: crystalline resin; non-crystalline resin; and a composite resin, wherein the crystalline resin is crystalline polyester resin (A), the non-crystalline resin comprises: non-crystalline resin (B) containing chloroform insoluble matter; and non-crystalline resin (C) having a softening temperature (T½) lower than that of the non-crystalline resin (B) by 25° C. or more, an absolute value |Tgc?Tgb| of a difference between a glass transition temperature (Tgc) of non-crystalline resin (C) and a glass transition temperature (Tgb) of non-crystalline resin (B) is 10° C. or lower, wherein the composite resin is composite resin (D) containing a condensation polymerization resin unit and an addition polymerization resin unit, and the toner has a molecular weight distribution having a main peak in 1,000 to 10,000 and a half width of 15,000 or less, where the molecular weight distribution is obtained by gel permeation chromatography (GPC) of tetrahydrofuran (THF) soluble matter of the toner.
    Type: Application
    Filed: March 14, 2013
    Publication date: October 3, 2013
    Inventors: Hisashi Nakajima, Saori Yamada, Masashi Nagayama, Mariko Takii, Shinya Hanatani
  • Publication number: 20130260298
    Abstract: A toner including: a binder resin; and a colorant, wherein the toner is obtained by dispersing or emulsifying an oil phase in an aqueous solvent containing an organic sulfonic acid salt and an inorganic salt, the oil phase including the binder resin and the colorant dissolved or dispersed in an organic solvent, wherein the binder resin comprises a crystalline resin in an amount of 50% by mass or more relative to the binder resin, and wherein the toner has an average circularity of 0.980 or less.
    Type: Application
    Filed: March 8, 2013
    Publication date: October 3, 2013
    Inventors: Suzuka AMEMORI, Masahide YAMADA, Shinya NAKAYAMA, Yukiko NAKAJIMA
  • Publication number: 20130260297
    Abstract: A toner including a colorant, a resin, and a volatile organic compound in an amount from 1 to 200 ?g/g is provided. The toner has a softening index Ct within a range from 70 to 100° C.
    Type: Application
    Filed: February 1, 2013
    Publication date: October 3, 2013
    Inventor: Hideki SUGIURA
  • Patent number: 8546056
    Abstract: A toner including a colorant and a binder resin is provided. The binder resin includes a polyester resin having a glass transition temperature of 18 to 40° C., a weight average molecular weight of 10,000 to 100,000, and a flow beginning temperature of 70 to 120° C. The toner has a volume average particle diameter of 3 to 10 ?m.
    Type: Grant
    Filed: March 5, 2012
    Date of Patent: October 1, 2013
    Assignee: Ricoh Company, Ltd.
    Inventors: Susumu Chiba, Hiroshi Yamashita, Masaki Watanabe, Satoyuki Sekiguchi, Daisuke Asahina
  • Patent number: 8546054
    Abstract: An electrophotographic toner includes a binder resin, a colorant, and a releasing agent, wherein the electrophotographic toner has a complex viscosity (?) of 4e2 Pa·s to 8e3 Pa·s at a temperature range of 120 to 160° C. and an angular velocity range of 1.6 to 10 rad/s, a rate of change of the complex viscosity of 165 to 185 Pa·s/° C. at 1.6 rad/s, and 70 to 80 Pa·s/° C. at 10 rad/s within the temperature range, a stress relaxation of 1.0 e3 to 4.5 e4 Pa at a relaxation time of 0.05 to 0.3 seconds under a temperature range of 120 to 160° C., and a rate of change of the stress relaxation (?G/?T) of 785 to 1000 Pa/° C. at 0.05 seconds and 190 to 215 Pa/° C. at 0.3 seconds within the temperature range above.
    Type: Grant
    Filed: September 29, 2008
    Date of Patent: October 1, 2013
    Assignee: Samsung Electronics Co., Ltd.
    Inventors: Jae-hyeuk Jeong, Duck-hee Lee, Deuck-woo Jang, Jung-ik Choi, Soon-cheol Jeong, Hae-ree Joo
  • Patent number: 8546055
    Abstract: A toner containing at least a binder resin, releasing agent, and colorant, wherein the binder resin contains polyester resin (A), polyester resin (B), and polyester resin (C), which is prepared by condensation-polymerizing (i) an alcohol component containing an alkylene oxide adduct of bisphenol compound and (ii) a carboxylic acid component; at least one of the polyester resin (A) and polyester resin (B) is a polyester resin prepared by condensation-polymerizing (i) the alcohol component substantially composed of only aliphatic alcohol and containing 1,2-propanediol in an amount of 65 mole % or more of a divalent alcohol component and (ii) the carboxylic acid component; and a softening point Tm(A) of the polyester resin (A) is 10 C or more higher than Tm(B) of the polyester resin (B), and the absolute difference between Tm(C) of the polyester resin (C) and the Tm(B) is 5° C. or less.
    Type: Grant
    Filed: September 2, 2009
    Date of Patent: October 1, 2013
    Assignee: Ricoh Company, Ltd.
    Inventors: Shinya Nakayama, Hisashi Nakajima, Saori Yamada, Mitsuo Aoki, Hyo Shu, Hiroyuki Kishida
  • Publication number: 20130252167
    Abstract: A toner comprising toner particles, each of which contains a binder resin and a colorant, wherein the binder resin includes a resin having an endothermic peak at a temperature of 55° C. to 120° C. in a DSC curve; the toner has a softening point Tm of 90° C. to 140° C.; in the viscoelastic characteristic of the toner measured at a frequency of 6.28 rad/sec, the storage elastic modulus at a temperature of 180° C. is 1.0×102 Pa to 1.0×104 Pa; in a chart with the temperature on the x-axis and tan ? on the y-axis, tan ? has a peak having a peak top in the range of 50° C. to 70° C.; tan ? (P) at the peak top temperature is 2.0 to 10.0; the ratio of the tan ? (P) at the peak top temperature to tan ? (Tm) at a temperature of Tm (tan ? (P)/tan ? (Tm)) is in the range of 2.5 to 8.0.
    Type: Application
    Filed: December 13, 2011
    Publication date: September 26, 2013
    Applicant: CANON KABUSHIKI KAISHA
    Inventors: Shuhei Moribe, Katsuhisa Yamazaki, Daisuke Yoshiba, Toru Takahashi, Daisuke Tsujimoto, Masami Fujimoto
  • Publication number: 20130252156
    Abstract: An electrostatic charge image developing toner includes toner particles that contain a binder resin having a carboxyl group, in which the carboxyl group in the binder resin present on the surfaces of the toner particles forms an alkaline earth metal salt, and an amount of the alkaline earth metal which is detected through ion chromatography of the toner particles is in a range of from 1.00×10?10 mol/g to 0.90×10?6 mol/g.
    Type: Application
    Filed: August 2, 2012
    Publication date: September 26, 2013
    Applicant: FUJI XEROX CO., LTD.
    Inventors: Satoshi KAMIWAKI, Akira MATSUMOTO, Yukiaki NAKAMURA, Masanobu NINOMIYA, Yusuke IKEDA
  • Publication number: 20130252166
    Abstract: An electrostatic charge image developer includes a toner for developing an electrostatic charge image, containing toner particles including a polyester resin having a rosin skeleton and an external additive, and a carrier having core material particles and a coating resin layer which coats the surface of the core material particles, in which the hardness of the coating resin layer is from 1.2 times to 2.0 times that of the toner particles.
    Type: Application
    Filed: June 27, 2012
    Publication date: September 26, 2013
    Applicant: FUJI XEROX CO., LTD.
    Inventor: Kazuhiko YANAGIDA
  • Publication number: 20130252160
    Abstract: A toner for forming an electrophotographic image is provided, wherein the toner includes at least four types of binder resins, wherein the binder resins includes at least: a crystalline polyester resin (A); a non-crystalline resin (B); a non-crystalline resin (C); and a composite resin (D) which includes a condensation polymerization resin unit and an addition polymerization resin unit, wherein the non-crystalline resin (B) includes a chloroform insoluble matter, wherein the non-crystalline resin (C) has a softening temperature (T½) lower than that of the non-crystalline resin (B) by 25° C. or more, and wherein the toner has a main peak between 1,000 to 10,000 in a molecular weight distribution obtained by GPC from a tetrahydrofuran soluble matter, and the toner has a half-value width of the molecular weight distribution of 15,000 or less.
    Type: Application
    Filed: September 14, 2012
    Publication date: September 26, 2013
    Inventors: Masashi NAGAYAMA, Mitsuo Aoki, Hisashi Nakajima, Saori Yamada, Mariko Takii
  • Publication number: 20130244167
    Abstract: A toner including a binder resin having a glass transition temperature (Tg) observed at least at one point from 25 to 65° C. in a differential scanning calorimeter at a rate of temperature increase of 5° C./min, wherein the toner has a structure in which a structure appearing as a high phase difference image is dispersed in a structure appearing as a low phase difference image in a two-dimensional phase difference image observed by tapping mode AFM, and an X-ray diffraction chart in which a peak originated from an crystalline resin is observed in a range of a diffraction angle 2? of from 20 to 25°, and wherein a ratio (I1/I2) of an intensity of the peak originated from an crystalline resin to an intensity (I2) of a halo originated from an amorphous composition is from 0.2 to 1.
    Type: Application
    Filed: January 31, 2013
    Publication date: September 19, 2013
    Inventors: Daiki YAMASHITA, Yoshihiro Moriya, Yukiko Nakajima, Taichi Nemoto, Yoshitaka Yamauchi, Keiji Makabe, Masahide Yamada, Suzuka Amemori
  • Publication number: 20130244157
    Abstract: A toner, including: a binder resin; releasing agent-encapsulating capsules; and a colorant, wherein the releasing agent-encapsulating capsules each include: a capsule formed of a resin (I) which is different from the binder resin; and a releasing agent (RA) which is encapsulated in the capsule, and the releasing agent-encapsulating capsules exist in the binder resin, and wherein 50% to 100% of the releasing agent-encapsulating capsules exist in a region from a surface of the toner to a depth of 0.10 times a volume-average particle diameter of the toner.
    Type: Application
    Filed: March 11, 2013
    Publication date: September 19, 2013
    Inventors: Ryota INOUE, Hiroaki Katoh, Masahiro Seki, Shun Saito, Yoshitaka Sekiguchi, Yoshihiro Mikuriya, Kazuoki Fuwa, Satoshi Ogawa, Tomohiro Fukao, Takayuki Nakamura
  • Publication number: 20130244162
    Abstract: A toner, including: a binder resin; and a colorant, wherein the binder resin contains: a crystalline polyester resin (A); a non-crystalline resin (B); and a composite resin (C), where the composite resin (C) contains a condensation polymerization resin unit and an addition polymerization resin unit, wherein the toner contains chloroform insoluble matter in an amount of 1% by mass to 30% by mass, wherein the toner has a molecular weight distribution having a main peak in a range of 1,000 to 10,000 and a half width of 15,000 or less, where the molecular weight distribution is obtained through gel permeation chromatography (GPC) of tetrahydrofuran soluble matter of the toner, and wherein the toner has an endothermic peak in a range of 90° C. to 130° C. in measurement through differential scanning calorimetry (DSC).
    Type: Application
    Filed: March 14, 2013
    Publication date: September 19, 2013
    Inventors: Saori Yamada, Hisashi Nakajima, Masashi Nagayama, Shinya Hanatani, Mariko Takii, Yoshitaka Sekiguchi
  • Publication number: 20130244168
    Abstract: A toner including a resin particle (C) is provided. The resin particle (C) includes a resin particle (B) and; a resin particle (A) or covering layer (P) that is adhered to a surface of the resin particle (B). The resin particle (B) includes a resin (b) having a polyhydroxycarboxylic acid skeleton. The resin particle (A) or covering layer (P) includes a resin (a). The resin (a) is a polyester resin having a polybasic acid unit and a polyol unit and has a weight average molecular weight within a range from 9,500 to 100,000.
    Type: Application
    Filed: February 6, 2013
    Publication date: September 19, 2013
    Inventors: Daiki YAMASHITA, Shinya Nakayama, Atsushi Yamamoto, Yukiko Nakajima, Akiyoshi Sabu, Yoshihiro Moriya, Hideyuki Santo
  • Publication number: 20130244169
    Abstract: To provide a toner, which contains: a binder resin; a colorant; and wax, wherein the toner has Ta of 30° C. to 55° C., and Tb—Ta of 8° C. to 25° C., where Ta is a glass transition temperature of the toner determined from a constant heating component of a DSC curve of the toner obtained in a second heating process of temperature modulated differential scanning calorimetry, and Tb is a glass transition temperature of the toner determined from a constant heating component of a DSC curve of the toner obtained in a first heating process of temperature modulated differential scanning calorimetry.
    Type: Application
    Filed: November 2, 2011
    Publication date: September 19, 2013
    Inventors: Azumi Miyaake, Hideki Sugiura, Yuka Mizoguchi
  • Patent number: 8535864
    Abstract: A magenta toner including toner particles containing a colorant and a binder resin is provided. The colorant contains C.I. Pigment Red 122 and C.I. Pigment Yellow 180 and a mass ratio of the C.I. Pigment Red 122 and the C.I. Pigment Yellow 180 is in the range of 99:1 to 10000:1. The binder resin contains a polyester resin and a polyester resin having a repeating unit obtained from a Bisphenol A alkylene oxide adduct expressed by the following chemical formula is used as the polyester resin: wherein m and n independently represent an integer of 2 to 4, and x and y independently represent a positive number.
    Type: Grant
    Filed: January 18, 2012
    Date of Patent: September 17, 2013
    Assignee: Fuji Xerox Co., Ltd.
    Inventors: Eisuke Iwazaki, Yuki Takamiya, Satoshi Inoue
  • Publication number: 20130236828
    Abstract: A toner including a binder resin and a colorant, the toner having a core-shell structure containing a core and a shell, wherein the binder resin contains a crystalline polyester resin and a non-crystalline polyester resin, wherein a ratio (A/B) of a mass (A) of the crystalline polyester resin to a mass (B) of the non-crystalline polyester resin is 5/95 to 75/25, and wherein a ratio (Ds/Dc) of a hardness (Ds) of the shell to hardness (Dc) of the core is 1.05 to 1.50 where the hardnesses (Ds) and (Dc) are measured with a scanning probe microscope.
    Type: Application
    Filed: November 2, 2011
    Publication date: September 12, 2013
    Inventors: Yuka Mizoguchi, Hideki Sugiura, Azumi Miyaake
  • Publication number: 20130236827
    Abstract: A toner to develop an electrostatic charge image, the toner including at least a binder resin, a colorant, and a releasing agent, wherein a weight average molecular weight of the toner measured by using a gel permeation chromatography (GPC) method on a tetrahydrofuran (THF) soluble fraction is in a range of about 30,000 to about 80,000 g/mol, wherein a molecular weight distribution curve of the toner obtained by using the GPC method on the THF soluble fraction has at least one peak in a molecular weight range of 100 to 1,000 g/mol, a peak in a molecular weight range of 1,000 to 5,000 g/mol, and a main peak in a molecular weight range of 5,000 to 20,000 g/mol, a method of preparing the toner, a device to supply the toner, and an apparatus and method of forming an image by using the toner. The toner has more than certain levels of low-temperature fixability, an anti-hot-offset property, a charging ability, a gloss property, and a heat storage ability.
    Type: Application
    Filed: March 7, 2013
    Publication date: September 12, 2013
    Applicant: SAMSUNG ELECTRONICS CO., LTD.
    Inventors: Takeshi YOSHIDA, Sung-jin PARK, Yo-da SHIN, Hwoing-woon LEE, Jin-mo HONG
  • Publication number: 20130236826
    Abstract: A toner for electrophotography, which is prepared by a method including dissolving or dispersing a toner composition including at least a binder resin, or binder resin and a binder resin precursor as a resin component; and a colorant in an organic solvent to form an oil phase; emulsifying or dispersing the oil phase in an aqueous medium to form an emulsion dispersion comprising emulsified particles; converging the emulsified particles to granulate mother toner particles, including controlling a temperature of the emulsion dispersion to control a circularity of the mother toner particles; and removing the organic solvent, wherein the resin component includes a crystalline resin in an amount not less than 50% by weight, and the mother toner particles have an average circularity of from 0.940 to 0.980.
    Type: Application
    Filed: December 10, 2012
    Publication date: September 12, 2013
    Inventors: Keiji MAKABE, Masahide Yamada, Shinya Nakayama, Atsushi Yamamoto, Hideyuki Santo, Yukiko Nakajima, Daiki Yamashita, Kazumi Suzuki, Tatsuya Morita, Shingo Sakashita
  • Patent number: 8530131
    Abstract: Toner particles are provided which may, in embodiments, include a core and a shell, one or both of which may include a polyester gel. The gel in the shell and/or core may prevent a crystalline resin in the core from migrating to the toner surface.
    Type: Grant
    Filed: August 27, 2008
    Date of Patent: September 10, 2013
    Assignee: Xerox Corporation
    Inventors: Ke Zhou, Karen Ann Moffat, Maria N. V. McDougall, Edward G. Zwartz, Paul J. Gerroir
  • Patent number: 8530126
    Abstract: Toners are provided. In one aspect a toner comprises, particles of at least one toner resin having particle diameters greater than about 20 microns, a first particulate addenda on the toner particles having a BET surface area of less than 60 m2/g of the toner particle; and a second particulate addenda on the toner particles having a BET surface of more than 120 m2/g.
    Type: Grant
    Filed: October 26, 2010
    Date of Patent: September 10, 2013
    Assignee: Eastman Kodak Company
    Inventors: Dinesh Tyagi, Muhammed Aslam, Donald S. Rimai
  • Patent number: 8524434
    Abstract: A toner having a toner particle including a core particle obtained by polymerizing a polymerizable monomer composition containing at least a polymerizable monomer, a colorant, a release agent, a polar resin, and a crystalline polyester in an aqueous medium and an outer shell formed by fixing resin fine particles to the surface of the core particle, wherein the resin constituting the resin fine particles is an amorphous resin and the acid value of the resin fine particles is 4.0 to 50.0 mgKOH/g.
    Type: Grant
    Filed: June 9, 2011
    Date of Patent: September 3, 2013
    Assignee: Canon Kabushiki Kaisha
    Inventors: Tsuneyoshi Tominaga, Ryoichi Fujita, Tsutomu Shimano
  • Publication number: 20130224648
    Abstract: Electrostatic image developing toner particles including: a crystalline polyester resin; a non-crystalline polyester resin; a releasing agent; and a colorant, wherein the electrostatic image developing toner particles have a glass transition temperature of 40° C. to 60° C. where the glass transition temperature is measured with a differential scanning calorimeter (DSC), and wherein the electrostatic image developing toner particles have an adhesive force between the toner particles of 1.4 mN to 2.2 mN where the adhesive force between the toner particles is measured after the electrostatic image developing toner particles have been stored at 50° C.
    Type: Application
    Filed: November 9, 2011
    Publication date: August 29, 2013
    Inventors: Takahiro Honda, Osamu Uchinokura, Junichi Awamura, Satoshi Ogawa, Satoshi Kojima, Teruki Kusahara, Daisuke Inoue, Daisuke Ito, Tsuneyasu Nagatomo, Masaki Watanabe
  • Patent number: 8518621
    Abstract: A toner for electrostatic image development containing a resin binder, a negatively chargeable charge control agent, and a positively chargeable charge control agent, wherein the resin binder contains at least one polyester, wherein a carboxylic acid component of the polyester contains isophthalic acid and/or an ester thereof and fumaric acid and/or an ester thereof, provided that if two or more polyesters are used, the carboxylic acid component is taken as an overall component, and wherein the negatively chargeable charge control agent contains a metal-containing azo dye and/or a metal complex of salicylic acid, and wherein the toner has a softening point of from 90° to 120° C. The toner for electrostatic image development of the present invention can be suitably used in developing latent images formed in, for example, electrophotography, an electrostatic recording method, an electrostatic printing method, or the like.
    Type: Grant
    Filed: January 19, 2010
    Date of Patent: August 27, 2013
    Assignee: Kao Corporation
    Inventors: Satoshi Kunii, Masahito Yamazaki, Yoshihiro Fukushima