Identified Imaging Member Outermost Layer Patents (Class 430/123.42)
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Patent number: 8835084Abstract: An electrophotographic photoreceptor including an electroconductive substrate, a charge generation layer located overlying the electroconductive substrate, a hole transport layer located on the charge generation layer, and a hole transport protective layer located on the hole transport layer. The hole transport protective layer includes a three-dimensionally crosslinked material obtained by irradiating a composition including at least a radically polymerizable hole transport compound with ultraviolet rays or electron beams so that the radically polymerizable hole transport compound causes chain polymerization. In addition, the protective layer includes a specific cyano-containing styryl aromatic compound or a specific cyano-containing distyryl aromatic compound.Type: GrantFiled: September 22, 2011Date of Patent: September 16, 2014Assignee: Ricoh Company, Ltd.Inventors: Kazukiyo Nagai, Tetsuro Suzuki, Hongguo Li
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Publication number: 20140178810Abstract: An image bearing member includes a substrate, and a photosensitive layer overlying the substrate, wherein an uppermost surface layer of the image bearing member has a hydrocarbon compound represented by the following Chemical Formula 1; and a three-dimensionally cross-linked polymer formed by polymerization reaction of a charge transport compound having three or more [tetrahydro-2H-pyran-2-yl)oxy]methyl groups linked with aromatic rings, wherein, in the polymerization reaction, part of the three or more [(tetrahydro-2H-pyran-2-yl)oxy]methyl groups is severed and detached from the charge transport compound, Ph1-Q1-Ph2-Q2-Ph3??Chemical Formula 1 where Q1 and Q2 independently represent methylene groups or ethylene groups, Ph1 and Ph3 independently represent phenyl groups with which one or two methyl groups are bonded, and Ph2 represents a phenylene group or a phenylene group having one methyl group.Type: ApplicationFiled: December 4, 2013Publication date: June 26, 2014Inventors: Kazukiyo NAGAI, Yuuji Tanaka, Tetsuro Suzuki, Yuusuke Koizuka
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Patent number: 8758971Abstract: An image-forming method uses an electrophotographic photosensitive member having a surface layer formed of a hydrogenated amorphous silicon carbide in which a ratio of the number of carbon atoms to the sum of the number of silicon atoms and the number of the carbon atoms in the surface layer is 0.61 or more and 0.75 or less, and the sum of the atomic density of the silicon atoms and the atomic density of the carbon atoms in the surface layer is 6.60×1022 atoms/cm3 or more, and the peak wavelength of pre-exposure light is shorter than the peak wavelength of image exposure light.Type: GrantFiled: December 16, 2009Date of Patent: June 24, 2014Assignee: Canon Kabushiki KaishaInventors: Kazuyoshi Akiyama, Shigenori Ueda, Daisuke Tazawa, Tomohito Ozawa
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Patent number: 8685611Abstract: In an electrophotographic photosensitive member having a photoconductive layer and, provided on the photoconductive layer, a surface layer constituted of a hydrogenated amorphous silicon carbide, the ratio of the number of atoms of carbon atoms (C) to the sum of the number of atoms of silicon atoms (Si) and number of atoms of carbon atoms (C), C/(Si+C), in the surface layer is from 0.61 or more to 0.75 or less, and the sum of atom density of the silicon atoms and atom density of the carbon atoms in the surface layer is 6.60×1022atom/cm3 or more.Type: GrantFiled: October 26, 2012Date of Patent: April 1, 2014Assignee: Canon Kabushiki KaishaInventors: Tomohito Ozawa, Kazuyoshi Akiyama, Yuu Nishimura
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Patent number: 8597862Abstract: A positive charging single-layer electrophotographic photoconductor configured to serve as an image-bearing member for use in an image-forming apparatus includes a photosensitive layer on a conductive base, including a charge-generating material, a hole-transport material, an electron-transport material, and a binder resin, in which the photosensitive layer has a polysiloxane oil, with the amount of the polysiloxane oil being in the range of about 0.005% by mass to about 0.021% by mass with respect to the total mass of materials.Type: GrantFiled: June 2, 2011Date of Patent: December 3, 2013Assignee: KYOCERA Document Solutions Inc.Inventors: Kuboshima Daisuke, Shishido Makoto, Yamamoto Yohei, Shimizu Tomofumi, Miyamoto Eiichi
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Patent number: 8507170Abstract: An image-forming method includes forming an electrostatic image on an electrostatic image bearing member which has been charged; developing the electrostatic image to form a toner image; transferring the toner image on the electrostatic image bearing member with or without mediating an intermediate transferring member onto a transfer material; and fixing the toner image on the transfer material. The electrostatic image bearing member is a photosensitive member obtained by sequentially laminating a photoconductive layer and a surface layer formed of hydrogenated amorphous silicon carbide, and a sum of an atomic density of silicon atoms and an atomic density of carbon atoms in the surface layer of the photosensitive member is 6.60×1022 atoms/cm3 or more. The toner has a binder resin and magnetic iron oxide particles, and the magnetic iron oxide particles contain Fe(2+) at a content of 20.0 mass % or more and 25.0 mass % or less.Type: GrantFiled: July 24, 2009Date of Patent: August 13, 2013Assignee: Canon Kabushiki KaishaInventors: Tooru Takahashi, Katsuhisa Yamazaki, Syuhei Moribe, Daisuke Yoshiba, Masami Fujimoto
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Patent number: 8372571Abstract: Provided is a method for forming an image containing the steps of: supplying a clear toner on a surface of an image forming support; heating the supplied clear toner on the surface of the image forming support to melt; close contacting the surface of the image forming support supplied with the clear toner with a belt; and cooling the clear toner in a state of close contacting with the belt so as to form a clear toner layer on the image forming support, wherein the aforesaid clear toner contains at least a resin formed with a polymerizable monomer represented by Formula (1) and a vinyl monomer, Formula (1): H2?CR1—COOR2, wherein R1 represents a hydrogen atom or a methyl group; and R2 represents a chain alkyl group having 12 to 22 carbon atoms, or a cyclic alkyl group.Type: GrantFiled: September 21, 2010Date of Patent: February 12, 2013Assignee: Konica Minolta Business Technologies, Inc.Inventors: Takao Yamanouchi, Kazue Nakamura, Ryuichi Hiramoto, Michiyo Fujita
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Electrophotographic photoconductor, and image forming apparatus and process cartridge using the same
Patent number: 8192904Abstract: An electrophotographic photoconductor including: an outermost layer, wherein the outermost layer comprises an amino group-containing acryl-modified polyorganosiloxane, wherein the amino group-containing acryl-modified polyorganosiloxane is a copolymer in which a polyorganosiloxane represented by the following structural formula (1) and an acrylic monomer are graft-polymerizedType: GrantFiled: June 15, 2007Date of Patent: June 5, 2012Assignees: Ricoh Company, Ltd., Nissin Chemical Industry Co., Ltd.Inventors: Kazukiyo Nagai, Hongguo Li, Tetsuro Suzuki, Harukazu Okuda -
Patent number: 8163456Abstract: An image forming method and image forming apparatus based on the application thereof wherein comet-like deposits do not appear on the surface of the photoreceptor even after prolonged use of small-diameter toner, and there is no dropout or damage on the photoreceptor surface in the image forming process using an intermediate transfer member. This image forming method contains a process wherein the toner developed on an electrophotographic photoreceptor is transferred onto an intermediate transfer member, and the toner contains at least a metallic oxide and metallic soap added as external additive agents, and the protective layer contains a resin component obtained by reaction of at least a curable compound, and alumina particles.Type: GrantFiled: March 25, 2009Date of Patent: April 24, 2012Assignee: Konica Minolta Business Technologies, Inc.Inventors: Hirofumi Hayata, Masahiko Kurachi, Toshiyuki Fujita
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Patent number: 8007970Abstract: Present embodiments pertain to an improved electrostatographic imaging member having low contact friction surfaces to ease sliding mechanical interaction and suppressing abrasion/wear failure and methods of preparing thereof. The improved imaging member has layers comprising one or two low surface energy polymeric materials that enhance the physical and mechanical functions and reduce the layers surface contact friction of the imaging member to extend service life.Type: GrantFiled: April 7, 2008Date of Patent: August 30, 2011Assignee: Xerox CorporationInventor: Robert C. U. Yu
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Patent number: 7986910Abstract: The present invention provides a lubricant coater including an applying member for applying a lubricant powder on a surface of an image bearing member, wherein the lubricant powder contains paraffin as a main component, and the lubricant coatability of the applying member is controlled such that a maximum thickness of a lubricant film formed on the image bearing member, which is obtained after the lubricant powder is continuously applied on the surface of the image bearing member for 120 minutes, is 0.25 ?m or less.Type: GrantFiled: July 22, 2008Date of Patent: July 26, 2011Assignee: Ricoh Company, Ltd.Inventors: Toshiyuki Kabata, Kumiko Hatakeyama, Masahide Yamashita
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Patent number: 7964327Abstract: An electrophotographic photoreceptor, including an electroconductive substrate; and a photosensitive layer, located overlying the electroconductive substrate, wherein an outermost layer of the electrophotographic photoreceptor includes an amine compound and a charge transport material, and wherein the amine compound includes an amine site having an electrostatic potential with a dimensionless unit not greater than ?0.27.Type: GrantFiled: June 13, 2007Date of Patent: June 21, 2011Assignee: Ricoh Company Ltd.Inventors: Masanobu Gondoh, Akihiro Sugino, Hideo Nakamori, Shinji Nohsho, Tomoyuki Shimada, Takaaki Ikegami
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Patent number: 7897314Abstract: A photoconductor containing an optional supporting substrate, a photogenerating layer, a charge transport layer or layers, and an overcoating layer containing a crosslinked mixture of a POSS component, a melamine polymer, and a charge transport like a hole transport compound.Type: GrantFiled: August 31, 2009Date of Patent: March 1, 2011Assignee: Xerox CorporationInventors: Jin Wu, Kenny-Tuan T Dinh, Jennifer A Coggan, Marc J Livecchi, Edward C Savage, Michael E Zak
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Patent number: 7842443Abstract: A method for evaluating an electrophotographic photoconductor in terms of filming occurrence is provided that comprises irradiating UV rays having a wavelength of 200 nm to 420 nm onto the electrophotographic photoconductor and measuring fluorescence emitted from the electrophotographic photoconductor.Type: GrantFiled: November 27, 2006Date of Patent: November 30, 2010Assignee: Ricoh Company, Ltd.Inventors: Junichi Yamazaki, Shigemitsu Nakatsugawa, Kenji Maeda
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Patent number: 7740998Abstract: A positively chargeable developer is provided which is capable of providing stable image quality without causing any image defect even in long-term use. The developer includes at least positively chargeable toner particles each containing at least a binder resin and magnetic iron oxide, silica and an inorganic fine powder. A unconfined yield strength at a major consolidation stress of 5 kPa of the developer is in the range of 0.1 to 2.5 kPa, and a unconfined yield strength at a major consolidation stress of 20 kPa of the developer is in the range of 2.5 to 5.5 kPa.Type: GrantFiled: February 16, 2006Date of Patent: June 22, 2010Assignee: Canon Kabushiki KaishaInventors: Katsuhisa Yamazaki, Daisuke Yoshiba, Masami Fujimoto
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Patent number: 7682766Abstract: In an image forming method in which a toner image, which is visualized via an electrostatic latent image formed on an electrophotographic photoreceptor, employing a developer incorporating toner, is transferred onto a recording material followed by fixing, and any residual toner remaining on the electrophotographic photoreceptor is removed, an image forming method in which an electrophotographic photoreceptor and a toner which satisfy specified requirements are employed and image formation is carried out while feeding a surface energy lowering agent from the developer onto the aforesaid electrophotographic photoreceptor, and an image forming apparatus employing the same.Type: GrantFiled: April 18, 2007Date of Patent: March 23, 2010Assignee: Konica Minolta Business Technologies, Inc.Inventors: Shingo Fujimoto, Takao Yamanouchi, Hirofumi Koga, Masaaki Kondo, Shiro Hirano, Junya Onishi
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Patent number: 7670743Abstract: An image is formed by projecting an image by way of an image irradiating device onto an image bearing member configured to operate at a linear velocity of at least 300 mm/sec, and which is constructed of(i) an electroconductive substrate having an image bearing surface that has an established surface charge having an electric field intensity of at least 32.Type: GrantFiled: January 14, 2008Date of Patent: March 2, 2010Assignee: Ricoh Company, Ltd.Inventors: Katsuichi Ohta, Tatsuya Niimi, Nozomu Tamoto
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Patent number: 7659044Abstract: A photoconductor comprising a photosensitive layer disposed on a support, wherein the photosensitive layer has a crosslinked layer and the crosslinked layer is produced by curing a dispersion in which at least one of an acryl-modified polyoraganosiloxane having a radical reactivity and an acryl-modified polyoraganosiloxane having an amine structure is dispersed in a radical polymerizable monomer.Type: GrantFiled: July 5, 2005Date of Patent: February 9, 2010Assignees: Ricoh Company, Ltd., Nissin Chemical Industry Co., Ltd.Inventors: Hongguo Li, Kazukiyo Nagai, Tetsuro Suzuki, Yasuo Suzuki, Harukazu Okuda, Masahide Hatanaka
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Patent number: 7655373Abstract: A method for forming images including a) depositing an electrostatic latent image on a charge retentive surface of a photoreceptor member having a substrate; a charge transport layer with charge transport materials; and an overcoat layer positioned on the charge transport layer, wherein the overcoat layer includes a crosslinkable alcohol-soluble polyamide; and wherein the overcoat layer further includes additives having titanium dioxide, silica, a crosslinking agent, a deletion control agent, and a charge transport molecule; and b) applying a developer material via a development component to the charge-retentive surface to develop the electrostatic latent image to form a developed image on the charge-retentive surface, wherein the developer material comprises emulsion aggregation toner, and further wherein at least one of the additives create a texturized surface on the charge retentive surface thereby reducing the contact area between the emulsion aggregation toners and the charge retentive surface enablingType: GrantFiled: December 14, 2007Date of Patent: February 2, 2010Assignee: Xerox CorporationInventors: Kenny-Tuan T. Dinh, Timothy J. Fuller, Paul J. DeFeo, Damodar M. Pai, John F. Yanus, Linda L. Ferrarese, Cindy C. Chen
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Patent number: 7572564Abstract: The present invention relates to a toner for electrostatic image development, comprising a crystalline ester compound synthesized by polymerizing a carboxylic acid component with an alcohol component, a non-crystalline resin, a colorant and a releasing agent, wherein the weight-average molecular weight of the crystalline ester compound is 5000 or less, and the number of carbon atoms in at least one component selected from the carboxylic acid component and the alcohol component is 10 or more.Type: GrantFiled: April 12, 2006Date of Patent: August 11, 2009Assignee: Fuji Xerox Co., Ltd.Inventors: Shuji Sato, Shigeru Hayashi, Katsumi Daimon
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Patent number: 7560216Abstract: An image-fixing method contains: passing a recording medium bearing an image through a nip between two or more fixing members to fix the image onto the recording medium; and ejecting the recording medium along with the fixing member contacting with a non-image-bearing surface of the recording medium, wherein the fixing member contacting with an image-bearing surface of the recording medium has a lower surface hardness than that of the fixing member contacting with the non-image-bearing surface, the image is comprised of a toner containing toner particles, each toner particle contains wax having an aliphatic hydrocarbon chain, and polyester resin having an aromatic ring, a total amount of the wax in the toner particle is 1 to 20 mass %, determined by DSC, an amount of the wax located in the specific region of the toner particle is 0.05 to 0.40 that is an intensity ratio (P2850/P828) determined by FTIR-ATR, and the wax is partially or entirely encapsulated in the toner particle as dispersed particles.Type: GrantFiled: September 7, 2005Date of Patent: July 14, 2009Assignee: Ricoh Company, Ltd.Inventors: Tsunemi Sugiyama, Yohichiroh Watanabe, Hiroshi Yamashita
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Patent number: 7556903Abstract: An electrophotographic photoreceptor including an electroconductive substrate and a photosensitive layer overlying the electroconductive substrate. An outermost layer of the electrophotographic photoreceptor is a crosslinked layer including a radical polymerizing monomer having three or more functional groups without a charge transporting structure. The outermost layer also includes a radical polymerizing compound having one functional group with a charge transporting structure and a reactive silicone compound having a radical polymerizing functional group.Type: GrantFiled: September 20, 2004Date of Patent: July 7, 2009Assignee: Ricoh Company LimitedInventors: Yoshiki Yanagawa, Hiroshi Ikuno, Hongguo Li, Kazukiyo Nagai, Hiroshi Tamura, Tetsuro Suzuki
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Patent number: 7482106Abstract: An image forming method comprising steps of forming a toner image by developing by a toner a latent image on a photoreceptor comprised of a layer formed on a substrate, transferring the toner image onto a recording medium on which the toner image is recorded and fixing, wherein the average circular degree of the toner is not less than 0.94, and the toner contains a wax comprising an ester of a carboxylic acid having carbon atoms of not less than 16 or an ester of an alcohol having carbon atoms of not less than 16, and the layer is a layer to be contacted to the toner in the developing step and contains an inorganic fine particles having a number average of primary particle diameter of approximately not less than 1 nm and less than 100 nm.Type: GrantFiled: March 15, 2004Date of Patent: January 27, 2009Assignee: Konica Minolta Holdings, Inc.Inventors: Hideo Yoshizawa, Akihiko Itami
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Patent number: 7473509Abstract: A toner image is formed while a developing sleeve is rotated in a direction counter to that of an organic photoreceptor at the developing section and a surface layer of the organic photoreceptor contains metal oxide particles which have a number average primary particle diameter of 3 to 150 nm and are chosen from metal of the 3rd or 4th cycle of a periodic table.Type: GrantFiled: October 26, 2005Date of Patent: January 6, 2009Assignee: Konica Minolta Business Technologies, Inc.Inventors: Akihiko Itami, Masao Asano, Hiroshi Yamazaki
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Patent number: 7439002Abstract: A silicone overcoat (SOC) layer having a crosslinked polysiloxane composition comprising a perfluoropolyether segment are disclosed. The polysiloxane composition is the product of the hydrolysis and condensation of a SOC formulation comprising a perfluoropolyether compound, an aromatic silicon-containing compound, and a silicon-containing hole transport compound. An electrophotographic imaging member having such a SOC layer has improved properties.Type: GrantFiled: July 12, 2005Date of Patent: October 21, 2008Assignee: Xerox CorporationInventors: Nan-Xing Hu, John Graham, Ah-Mee Hor, Yvan Gagnon, Cheng-Kuo Hsiao
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Patent number: 7416823Abstract: An electrophotographic photoconductor having at least a photoconductive layer on an electrically conductive support, in which a surface layer of the photoconductive layer can be obtained by curing at least a free-radical-polymerizable monomer having no charge transporting structure, represented by general formula (A) and a one-functional free-radical-polymerizable compound having a charge transporting structure, wherein R71, R72, R73, R74, R75, and R76 are described in the specification.Type: GrantFiled: January 13, 2005Date of Patent: August 26, 2008Assignee: Ricoh Company, Ltd.Inventors: Yoshiki Yanagawa, Hiroshi Ikuno, Hongguo Li, Kazukiyo Nagai, Hiroshi Tamura, Tetsuro Suzuki, Naohiro Toda, Yoshiaki Kawasaki
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Patent number: 7390600Abstract: An object is to provide a latent electrostatic image bearing member that can provide high-quality images for prolonged periods, owing to photosensitive layers and crosslinked surface layers having excellent flaw and wear resistance and appropriate electric properties, image forming method, image forming apparatus and process cartridge that employ latent electrostatic image bearing member respectively. Accordingly, provided is a latent electrostatic image bearing member that comprises a support and at least a photosensitive layer and a crosslinked surface layer disposed on the support, wherein the crosslinked surface layer comprises a reactant from radical polymerizable compounds having three or more functionalities with no charge transport structure and radical polymerizable compounds having one functionality with charge transport structure, and at least two different antioxidants.Type: GrantFiled: September 2, 2005Date of Patent: June 24, 2008Assignee: Ricoh Company, Ltd.Inventors: Naohiro Toda, Hiroshi Tamura, Yoshiki Yanagawa, Tetsuro Suzuki
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ELECTROPHOTOGRAPHIC PHOTOCONDUCTOR, AND IMAGE FORMING APPARATUS AND PROCESS CARTRIDGE USING THE SAME
Publication number: 20070292780Abstract: An electrophotographic photoconductor including: an outermost layer, wherein the outermost layer comprises an amino group-containing acryl-modified polyorganosiloxane, wherein the amino group-containing acryl-modified polyorganosiloxane is a copolymer in which a polyorganosiloxane represented by the following structural formula (1) and an acrylic monomer are graft-polymerized.Type: ApplicationFiled: June 15, 2007Publication date: December 20, 2007Inventors: Kazukiyo Nagai, Hongguo Li, Tetsuro Suzuki, Harukazu Okuda -
Publication number: 20070254233Abstract: In an image forming method in which a toner image, which is visualized via an electrostatic latent image formed on an electrophotographic photoreceptor, employing a developer incorporating toner, is transferred onto a recording material followed by fixing, and any residual toner remaining on the electrophotographic photoreceptor is removed, an image forming method in which an electrophotographic photoreceptor and a toner which satisfy specified requirements are employed and image formation is carried out while feeding a surface energy lowering agent from the developer onto the aforesaid electrophotographic photoreceptor, and an image forming apparatus employing the same.Type: ApplicationFiled: April 18, 2007Publication date: November 1, 2007Applicant: KONICA MINOLTA BUSINESS TECHNOLOGIES, INC.Inventors: Shingo FUJIMOTO, Takao YAMANOUCHI, Hirofumi KOGA, Masaaki KONDO, Shiro HIRANO, Junya ONISHI
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Publication number: 20070202425Abstract: Disclosed is a toner used for an image forming apparatus, comprising an organic photoreceptor as a latent image supporting material and a cleaning blade for removing a residual toner on the organic photoreceptor after a transfer process, wherein the friction coefficient between the organic photoreceptor and the toner is from 0.30 to 0.65, the toner contains at least one kind of inorganic fine particles on the surface, and one of the inorganic fine particles is made of silica.Type: ApplicationFiled: February 26, 2007Publication date: August 30, 2007Inventors: Kousuke Satou, Naruo Yabe