Identified Glass Transition Temperature (tg) Patents (Class 430/123.54)
  • Patent number: 9034548
    Abstract: A toner containing colorant, releasing agent, and binder resin containing crystalline polyester resin, and non-crystalline polyester resin containing urethane bond, urea bond, or both, the non-crystalline polyester resin containing first and second non-crystalline polyester resins, both containing urethane bond, or urea bond, or both, wherein monomers constituting the first non-crystalline polyester resin contains isocyanate monomer for forming the urethane bond, the urea bond, or the both, in an amount of 0.5 mol % or greater to total amount of the monomers, monomers constituting the second non-crystalline polyester resin contain isocyanate monomer for forming the urethane bond, the urea bond, or the both, in an amount of 0.5 mol % or greater to total amount of the monomers, the first non-crystalline polyester resin has Tg of ?60° C. or higher but lower than 10° C., and the second non-crystalline polyester resin has Tg of 30° C. or higher but lower than 70° C.
    Type: Grant
    Filed: December 10, 2012
    Date of Patent: May 19, 2015
    Assignee: Ricoh Company, Ltd.
    Inventors: Tatsuru Moritani, Hiroshi Yamashita, Tsuyoshi Sugimoto, Daisuke Asahina, Rintaro Takahashi, Susumu Chiba
  • Patent number: 8986916
    Abstract: A yellow toner including: a non-crystalline resin; C.I. Pigment Yellow 185; and a releasing agent, wherein the yellow toner has a glass transition temperature of more than 18° C. but less than 40° C.
    Type: Grant
    Filed: December 26, 2012
    Date of Patent: March 24, 2015
    Assignee: Ricoh Company, Ltd.
    Inventors: Hiroshi Yamashita, Masana Shiba, Satoyuki Sekiguchi, Yukari Fukuda, Daisuke Asahina, Rintaro Takahashi, Tsuyoshi Sugimoto
  • Patent number: 8940468
    Abstract: Disclosed is a process for production of a decolorable toner, including: aggregating dispersed fine particles of a color material comprising at least a color-forming compound, a color-developing agent and a decoloring agent with dispersed fine particles comprising at least a binder resin comprising a polyester resin to form aggregates in an aqueous medium, adding a reactive polymer having an oxazoline group in to the aqueous medium, and fusing the aggregates in the aqueous medium. As a result, it becomes possible to produce a decolorable toner which suppresses the generation of fine powder due to the release of fine particles of an erasable color material from the toner.
    Type: Grant
    Filed: June 29, 2012
    Date of Patent: January 27, 2015
    Assignee: Toshiba Tec Kabushiki Kaisha
    Inventors: Takayasu Aoki, Takafumi Hara, Tsuyoshi Itou, Masahiro Ikuta, Motonari Udo, Koji Shimokusa, Hiroshi Mizuhata
  • Patent number: 8895220
    Abstract: An emulsion aggregation toner formulation for electrophotography and a method for preparation thereof. The emulsion aggregation toner formulation includes a polyester resin emulsion formed using an extruded polyester binder resin having a broad molecular weight distribution. The extruded polyester binder resin is formed using a plurality of polyester binder resins. Further, the emulsion aggregation toner formulation comprises at least one colorant dispersion and a wax dispersion.
    Type: Grant
    Filed: August 29, 2013
    Date of Patent: November 25, 2014
    Assignee: Lexmark International, Inc.
    Inventors: Michael James Bensing, Craig Michael Bartelsen, John Joseph Kraseski, Bryan Patrick Livengood, Jing X. Sun, Vincent Wen-Hwa Ting
  • Patent number: 8735042
    Abstract: An electrostatic latent image developing toner includes: a release agent; a pigment; and a binder resin. The content of the pigment is from about 10% by weight to about 50% by weight, the glass transition temperature (Tg) of the toner is in the range of from about ?60° C. to about 20° C., and the Young's modulus at 20° C. is in the range of from about 1×100 MPa to about 1×103 MPa.
    Type: Grant
    Filed: January 31, 2012
    Date of Patent: May 27, 2014
    Assignee: Fuji Xerox Co., Ltd.
    Inventors: Satoshi Kamiwaki, Kiyohiro Yamanaka, Yusuke Ikeda, Koji Sasaki
  • Patent number: 8697324
    Abstract: Environmentally friendly toner particles are provided which may include a bio-based amorphous polyester resin including camphoric acid, optionally in combination with a crystalline resin. Methods for providing these toners are also provided.
    Type: Grant
    Filed: February 23, 2012
    Date of Patent: April 15, 2014
    Assignee: Xerox Corporation
    Inventors: Jordan H Wosnick, Valerie M Farrugia, Guerino G Sacripante
  • Patent number: 8592117
    Abstract: A toner including: a binder resin component; crystal nucleating agent; releasing agent; and colorant, wherein the binder resin component contains a crystalline polyester resin and a non-crystalline polyester resin, the crystal nucleating agent is at least one of an aliphatic ester compound and an aliphatic amide compound each having a melting point of 60° C. or higher but lower than 150° C., and wherein the toner satisfies Expressions (I) and (II): Tc>Tp+10??Expression (I) Tm>Tp+2??Expression (II) where Tp denotes lowest exothermic peak temperature [° C.] in 0° C. to 200° C. in DSC curve obtained DSC of the crystalline polyester resin, Tc denotes lowest exothermic peak temperature [° C.] in 0° C. to 200° C. in DSC curve obtained DSC of the crystal nucleating agent, and Tm denotes lowest exothermic peak temperature [° C.] in 0° C. to 200° C. in DSC curve through DSC of the mixture of the crystalline polyester resin and the crystal nucleating agent.
    Type: Grant
    Filed: December 23, 2011
    Date of Patent: November 26, 2013
    Assignee: Ricoh Company, Ltd.
    Inventors: Tsuyoshi Sugimoto, Hiroshi Yamashita, Daisuke Asahina, Masaki Watanabe, Satoyuki Sekiguchi, Rintaro Takahashi
  • Patent number: 8551681
    Abstract: An emulsion aggregation toner formulation for electrophotography and a method for preparation thereof. The emulsion aggregation toner formulation includes a polyester resin emulsion formed using an extruded polyester binder resin having a broad molecular weight distribution. The extruded polyester binder resin is formed using a plurality of polyester binder resins. Further, the emulsion aggregation toner formulation comprises at least one colorant dispersion and a wax dispersion.
    Type: Grant
    Filed: September 8, 2008
    Date of Patent: October 8, 2013
    Assignee: Lexmark International, Inc.
    Inventors: Michael James Bensing, Craig Michael Bertelsen, John Joseph Kraseski, Bryan Patrick Livengood, Jing X. Sun, Vincent Wen-Hwa Ting
  • Patent number: 8298741
    Abstract: An image forming apparatus includes plural developing units separately containing a toner A and a toner B that satisfy relationships (1) and (2) and have similar colors. The toner A and the toner B each contain a binder resin containing a polyester about 90 mass % or more of the binder resin, and about 90 mass % of the binder resin of the toner A and about 90 mass % of the binder resin of the toner B are the same resin. The polyester contains an amorphous polyester having an alkyl side chain and a crystalline polyester. The relationship (1) is Ta (toner A)>Tb (toner B) in terms of flow tester ½ effluent temperature. The relationship (2) is Aa (toner A)>Ab (toner B) in terms of an amount of an aluminum (with reference to net intensity) measured with fluorescent X-ray.
    Type: Grant
    Filed: October 21, 2010
    Date of Patent: October 30, 2012
    Assignee: Fuji Xerox Co., Ltd.
    Inventors: Satoshi Yoshida, Eisuke Iwazaki, Shintaro Anno
  • Publication number: 20120251941
    Abstract: The present invention relates to a polycarbonate of number average molecular weight from 500 to 10000, glass transition point from 30 to 80° C. and hydroxyl group value of 30 mg KOH/g or less and the use of said polycarbonate in a urethane modified resin used as an ingredient for the production of a toner or a developer for electronic copying purposes. The present invention also relates to a urethane modified resin obtainable by the reaction of a polymer mixture comprising a polycarbonate according to any of claims 1 to 5 and a polycondensed resin of glass transition point from 10 to 60° C. and hydroxyl group value from 20 to 100 mg KOH/g with a polyfunctional isocyanate compound wherein the ratio of polycarbonate and polycondensed resin is from 20:80 to 80:20 by weight and the molar ratio of isocyanate groups in the polyisocyanate compound to hydroxyl groups in the polymer mixture is between 0.4 to 1.
    Type: Application
    Filed: July 6, 2010
    Publication date: October 4, 2012
    Applicant: BASF SE
    Inventors: Yoshihisa Fujii, Hiroyasu Kanno, Torii Yoshinori, Ema Kenji
  • Patent number: 8168362
    Abstract: An electrostatic image developing toner includes a polyester resin, the electrostatic image developing toner having a sulfur element concentration S at % and a nitrogen element concentration N at % which satisfies 0.5?N/S?10, the nitrogen element concentration N being from 0.002 at % to 2.5 at %.
    Type: Grant
    Filed: September 28, 2007
    Date of Patent: May 1, 2012
    Assignee: Fuji Xerox Co., Ltd.
    Inventors: Fumiaki Mera, Hirotaka Matsuoka, Yasuo Matsumura
  • Patent number: 8043782
    Abstract: A toner for electrophotography is provided including a binder resin, a coloring agent, a charge controlling agent, and a releasing agent, wherein when the temperature of the toner is in the range from a temperature 40° C. lower than a fixing temperature of the toner to a temperature 10° C. lower than the fixing temperature of the toner, the D Log ?*/DT absolute value is 0.02 or more, when the temperature of the toner is in the range from a temperature 10° C. lower than the fixing temperature of the toner to a temperature 10° C. higher than the fixing temperature of the toner, the D Log ?*/DT absolute value is 0.005 or less, and the complex viscosity (?*) of the toner at a fixing temperature and an angular velocity of a fixing heat roller is in the range from about 5.0×101 Pa·s to 1.0×102 Pa·s. The toner has excellent fixing properties so that the quality of an image can be stabilized, and cause less contamination.
    Type: Grant
    Filed: January 18, 2008
    Date of Patent: October 25, 2011
    Assignee: Samsung Electronics Co., Ltd.
    Inventor: Jae-hyeuk Jeong
  • Patent number: 8017290
    Abstract: Objects of the present invention are to provide an image forming method and image forming apparatus which can secure stable toner transferability, prevent reverse transfer of the toner back to a latent image bearing member, have excellent fixing ability and produce high-quality images. The image forming method includes a one-component developing step with a toner and transferring step with an intermediate transfer member, wherein the developing step uses a developing roller having a diameter of 8 mm to 15 mm, and the toner has an adherence Fh (nN) of the toner to a flat surface satisfying the relation represented by the formula (1) and adherence Fr (mN) among the toner particles satisfying the relation represented by the formula (2): 15?Fh?50??(1) 100?Fr?400??(2).
    Type: Grant
    Filed: March 6, 2008
    Date of Patent: September 13, 2011
    Assignee: Ricoh Company, Ltd.
    Inventors: Minoru Nakamura, Akira Izutani
  • Patent number: 7935470
    Abstract: A toner for electrophotography is provided including a binder resin, a colorant, a charge control agent, and a release agent, wherein a glass transition temperature (Tg) is over 55° C., a molecular weight distribution (MWD) is in the range of about 4.5 to 5.5 when a weight average molecular weight is in the range of about 45,000 to 55,000, and a compression elastic modulus is about 750 MPa or higher at room temperature. Mechanical properties of toner can be obtained at room temperature by controlling rheological properties of toner. The developing properties and fixing properties of toner for electrophotography can be improved by lowering viscosity at a high temperature, and thus image quality can be stabilized.
    Type: Grant
    Filed: November 8, 2007
    Date of Patent: May 3, 2011
    Assignee: Samsung Electronics Co., Ltd.
    Inventors: Jae-hyeuk Jeong, Kyung-yol Yon, Min-young Cheong, Kyeong Pang, Yo-da Shin, Hae-ree Joo
  • Patent number: 7914964
    Abstract: An image forming method of forming images on both sides of a recording sheet; comprising the steps of: fixing a first toner image on a first surface a recording sheet; and fixing a second toner image on a second surface of the recording sheet; wherein in two-component developer includes toner particles each containing a binder resin having a glass transition temperature Tg° C. and a colorant and carrier particles in each on which magnetic powder is dispersed in a binder resin including a phenol formaldehyde obtained by a polymerization process, and the first toner image is fixed with first heat in such a way that the surface temperature of the first surface of the recording sheet is a temperature in a range of Tg° C. or more and lower than 100° C.
    Type: Grant
    Filed: July 20, 2007
    Date of Patent: March 29, 2011
    Assignee: Konica Minolta Business Technologies, Inc.
    Inventors: Hiroshi Yamazaki, Ken Ohmura
  • Patent number: 7790343
    Abstract: A process includes developing toner images on a photoconductor, transferring to an intermediate transfer belt and a transferring-and-fixing roller. The toner images are transferred to and fixed to a paper simultaneously while the paper moves between the transferring-and-fixing roller and a pressure roller which is pressed against the transferring-and-fixing roller. After transfer process to the paper, residual toner particles remaining on the transferring-and-fixing roller are removed by a cleaning roller. In order to achieve a cleanability from the transferring-and-fixing roller and prevent the intermediate belt from becoming too high temperature, the elastic modulus of the toner particles measured when the toner particles are heated is greater than the elastic modulus of the toner particles when cooled in a temperature range where the glass transition temperature and 10° C. lower than the melting temperature of the toner particles.
    Type: Grant
    Filed: January 31, 2007
    Date of Patent: September 7, 2010
    Assignee: Ricoh Company, Ltd.
    Inventors: Kazumi Suzuki, Hiromitsu Takagaki, Takashi Fujita, Atsushi Nakafuji, Hiromi Tamura, Shin Kayahara, Tsuyoshi Sugimoto, Takashi Seto, Katsuaki Miyawaki
  • Patent number: 7625684
    Abstract: A toner for electrophotography containing a resin binder and a colorant, wherein the resin binder contains a polyester in an amount higher than 50% by weight of the resin binder, wherein the polyester is obtained by polycondensing an alcohol component containing 60% by mol or more of an aliphatic diol having 3 to 10 carbon atoms and a carboxylic acid component comprising 80% by mol or more of an aromatic dicarboxylic acid compound, the polyester having an index of crystallinity of from 0.6 to 1.5, and a glass transition temperature of 0° C. or more and less than 40° C. The toner for electrophotography of the present invention can be used for, for example, developing electrostatic latent images formed in electrophotography, electrostatic recording method, electrostatic printing method, or the like.
    Type: Grant
    Filed: July 5, 2005
    Date of Patent: December 1, 2009
    Assignee: Kao Corporation
    Inventors: Nobumichi Kamiyoshi, Koji Shimokusa, Takashi Yamaguchi, Shinichi Sata
  • Patent number: 7588874
    Abstract: A toner for developing an electrostatic image is provided, which contains at least a binder resin, a colorant and a releasing agent, the releasing agent, has an endothermic peak temperature measured by a differential scanning calorimeter of from 60 to 100° C., and an endothermic amount a of the releasing agent per unit weight (J/g) at temperatures equal to or lower than a glass transition onset temperature of the binder resin measured by a differential scanning calorimeter, a total endothermic amount b of the releasing agent per unit weight (J/g) and a volume average particle diameter c(?m) of the toner has the relationship: 0.05?(a/b)×c?0.6.
    Type: Grant
    Filed: August 12, 2004
    Date of Patent: September 15, 2009
    Assignee: Fuji Xerox Co., Ltd.
    Inventors: Kazufumi Tomita, Yosuke Tsurumi, Shuji Sato, Akira Matsumoto, Hiroshi Nakazawa
  • Patent number: 7575841
    Abstract: The present invention provides a toner for electrophotography having a capsule structure including a core and a shell that covers the core, wherein the core contains a colorant, a releasing agent, an amorphous resin, and a block polymer containing a crystalline part and an amorphous part, the weight-average molecular weight of the block polymer is 10,000 or more, the weight-average molecular weight of the resin used in formation of the amorphous part of the block polymer is 1000 to 5000, and the weight-average molecular weight of the resin used in formation of the crystalline part of the block polymer is at least 2 times the weight-average molecular weight of the resin used in formation of the amorphous part of the block polymer, a method of manufacturing the same, a developer for electrophotography including the toner and a carrier, and an image forming method using the developer for electrophotography.
    Type: Grant
    Filed: December 6, 2005
    Date of Patent: August 18, 2009
    Assignee: Fuji Xerox Co., Ltd.
    Inventors: Katsumi Daimon, Kazufumi Tomita, Moegi Iguchi, Yasuo Matsumura, Yusuke Ikeda, Shigeru Hayashi, Shuji Sato, Takashi Imai, Yosuke Tsurumi, Hiroshi Nakazawa
  • Patent number: 7541128
    Abstract: A toner composition including toner particles including a binder resin including a modified polyester resin, and a second resin having a weight average molecular weight of from 2,000 to 10,000; a colorant; a release agent; and a particulate material which is present at least a surface portion of the toner particles while embedded into the surface portion, wherein the binder resin has a glass transition temperature not lower than 35° C. and lower than 55° C., and wherein the particulate material has an average particle diameter of from 0.002 to 0.2 times that of the toner particles. A developer including the toner composition and a carrier having a layer thereon which includes at least an acrylic resin and a silicone resin, and a method for fixing an image of the toner composition are also provided.
    Type: Grant
    Filed: September 26, 2003
    Date of Patent: June 2, 2009
    Assignee: Ricoh Company Limited
    Inventors: Yohichiroh Watanabe, Masanori Suzuki, Tsunemi Sugiyama, Hiroshi Yamashita, Takuya Saito, Naohiro Watanabe, Masami Tomita, Shigeru Emoto, Shinichiro Yagi, Hiroshi Yamada, Toshiki Nanya, Tadao Takigawa
  • Patent number: 7507514
    Abstract: Toner containing binder resin constituted of plural types of copolymers comprising a vinyl type polymerizing monomer, wherein at least one of the copolymers comprising a vinyl type polymerizing monomer is one formed by utilizing a monomer provided with at least two polar groups.
    Type: Grant
    Filed: June 6, 2005
    Date of Patent: March 24, 2009
    Assignee: Konica Minolta Business Technologies, Inc.
    Inventors: Tomoko Tanma, Meizo Shirose, Asao Matsushima
  • Patent number: 7396630
    Abstract: A toner composition including toner particles including a binder resin including a modified polyester resin, and a second resin having a weight average molecular weight of from 2,000 to 10,000; a colorant; a release agent; and a particulate material which is present at least a surface portion of the toner particles while embedded into the surface portion, wherein the binder resin has a glass transition temperature not lower than 35° C. and lower than 55° C., and wherein the particulate material has an average particle diameter of from 0.002 to 0.2 times that of the toner particles. A developer including the toner composition and a carrier having a layer thereon which includes at least an acrylic resin and a silicone resin, and a method for fixing an image of the toner composition are also provided.
    Type: Grant
    Filed: October 11, 2006
    Date of Patent: July 8, 2008
    Assignee: Ricoh Company Limited
    Inventors: Yohichiroh Watanabe, Masanori Suzuki, Tsunemi Sugiyama, Hiroshi Yamashita, Takuya Saito, Naohiro Watanabe, Masami Tomita, Shigeru Emoto, Shinichiro Yagi, Hiroshi Yamada, Toshiki Nanya, Tadao Takigawa
  • Patent number: 7378213
    Abstract: A process contains in which heating and fixing an image of a toner on a recording medium is performed by heating one or more heat-transfer media by a heating element, and pressing the recording medium bearing the toner image to one of the heat-transfer media. At least one of the heat-transfer media is a belt heat-transfer medium with or without the application of an oil whose amount is 4 mg or less per A4 size, and the toner contain a binder resin and a releasing agent, has a weight-average particle diameter Dv of 3.0 to 7.0 ?m, a particle diameter distribution Dv/Dn of 1.00 or more and 1.25 or less, wherein Dn is a number-average particle diameter, and an average shape factor SF-1 of 100 to 150 and contains toner particles having a shape factor SF-1 of 160 or more in an amount of 10% by number or less.
    Type: Grant
    Filed: December 9, 2003
    Date of Patent: May 27, 2008
    Assignee: Ricoh Company, Ltd.
    Inventors: Masami Tomita, Hiroaki Matsuda
  • Publication number: 20070254229
    Abstract: A toner composition includes a styrene-based polymer resin, a crystalline polyester wax, a second wax different from the crystalline polyester wax, a colorant, and a coagulant.
    Type: Application
    Filed: August 14, 2006
    Publication date: November 1, 2007
    Applicant: XEROX CORPORATION
    Inventors: Raj D. PATEL, Edward G. ZWARTZ, T. Brian MCANENEY, Edward C. HANZLIK, Alan R. KUNTZ
  • Publication number: 20070218386
    Abstract: A process includes developing toner images on a photoconductor, transferring to an intermediate transfer belt and a transferring-and-fixing roller. The toner images are transferred to and fixed to a paper simultaneously while the paper moves between the transferring-and-fixing roller and a pressure roller which is pressed against the transferring-and-fixing roller. After transfer process to the paper, residual toner particles remaining on the transferring-and-fixing roller are removed by a cleaning roller. In order to achieve a cleanability from the transferring-and-fixing roller and prevent the intermediate belt from becoming too high temperature, the elastic modulus of the toner particles measured when the toner particles are heated is greater than the elastic modulus of the toner particles when cooled in a temperature range where the glass transition temperature and 10° C. lower than the melting temperature of the toner particles.
    Type: Application
    Filed: January 31, 2007
    Publication date: September 20, 2007
    Inventors: Kazumi Suzuki, Hiromitsu Takagaki, Takashi Fujita, Atsushi Nakafuji, Hiromi Tamura, Shin Kayahara, Tsuyoshi Sugimoto, Takashi Seto, Katsuaki Miyawaki