Imagewise Heating, Element Or Image Receiving Layers Therefor Or Imagewise Vapor And Gas Transfer Process, Element Or Image Receiving Layer Therefor Patents (Class 430/200)
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Patent number: 5043317Abstract: A yellow dye-donor element for thermal dye transfer comprises a support having thereon a dye layer comprising a mixture of yellow dyes dispersed in a polymeric binder, at least one of the yellow dyes having the formula: ##STR1## wherein R.sup.1 is a substituted or unsubstituted alkyl group of from 1 to about 10 carbon atoms; a substituted or unsubstituted cycloalkyl group of from about 5 to about 7 carbon atoms; an allyl group; a substituted or unsubstituted aryl group; or a substituted or unsubstituted hetaryl group of from about 5 to about 10 atoms;R.sup.2 is any of the groups for R.sup.1 or represents the atoms which when taken together with Z form a 5- or 6-membered ring;Z is hydrogen; any of the groups for R.sup.1 ; alkoxy; halogen; aryloxy; or represents the atoms which when taken together with R.sup.2 forms a 5- or 6-membered ring;each Y independently represents any of the groups for R.sup.Type: GrantFiled: December 14, 1990Date of Patent: August 27, 1991Assignee: Eastman Kodak CompanyInventors: Derek D. Chapman, Steven Evans
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Patent number: 5041413Abstract: A yellow dye-donor element for thermal dye transfer comprises a support having thereon a dye layer comprising a mixture of yellow dyes dispersed in a polymeric binder, at least one of the yellow dyes having the formula: ##STR1## wherein: each R.sup.1 independently represents a substituted or unsubstituted alkyl group of from 1 to about 10 carbon atoms, a cycloalkyl group of from about 5 to about 7 carbon atoms; a substituted or unsubstituted allyl group; an aryl group of from about 6 to about 10 carbon atoms; a hetaryl group of from 5 to 10 atoms; acyl; arylsulfonyl; aminocarbonyl; aminosulfonyl; fluorosulfonyl; halogen; nitro; alkylthio; or arylthio;or any two adjacent R.sup.1 's together represent the atoms necessary to form a 5- or 6-membered fused ring;n represents an integer from 0-4;R.sup.2 represents hydrogen; a substituted or unsubstituted alkyl, cycloalkyl, allyl, aryl or hetaryl group as described above for R.sup.Type: GrantFiled: December 14, 1990Date of Patent: August 20, 1991Assignee: Eastman Kodak CompanyInventors: Steven Evans, Derek D. Chapman
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Patent number: 5041412Abstract: A yellow dye-donor element for thermal dye transfer comprises a support having thereon a dye layer comprising a mixture of yellow dyes dispersed in a polymeric binder, at least one of the yellow dyes having the formula: ##STR1##Type: GrantFiled: December 14, 1990Date of Patent: August 20, 1991Assignee: Eastman Kodak CompanyInventors: Derek D. Chapman, Steven Evans
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Patent number: 5041411Abstract: A yellow dye-donor element for thermal dye transfer comprises a support having thereon a dye layer comprising a mixture of yellow dyes dispersed in a polymeric binder, at least one of the yellow dyes having the formula: ##STR1##Type: GrantFiled: December 14, 1990Date of Patent: August 20, 1991Assignee: Eastman Kodak CompanyInventors: Derek D. Chapman, Steven Evans
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Patent number: 5037799Abstract: A yellow dye-donor element for thermal dye transfer comprises a support having thereon a dye layer comprising a mixture of yellow dyes dispersed in a polymeric binder, at least one of the yellow dyes having the formula: ##STR1## wherein: R.sup.1 represents hydrogen or halogen;each R.sup.2 independently represents hydroxy, alkoxy, aryloxy, acyloxy, aminocarbonyl, carbamoyloxy, halogen, aryl, hetaryl, cyano, acylamido, alkoxycarbonyl, alkylthio, arylthio, alkylsulfonyl, arylsulfonyl, alkylsulfonamido or arylsulfonamido; or any two adjacent R.sup.2 's together represent the atoms necessary to complete a 5- or 6-membered fused saturated or aromatic ring;Y represents H or OH; andn is an integer from 0 to 4;or any two adjacent R.sup.1 's together represent the atoms necessary to form a 5- or 6-membered fused ring;n represents an integer from 0-4; and at least one of the other of the dyes having the formula: ##STR2## wherein: R.sup.3 and R.sup.Type: GrantFiled: December 14, 1990Date of Patent: August 6, 1991Assignee: Eastman Kodak CompanyInventors: Derek D. Chapman, Steven Evans
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Patent number: 5035977Abstract: A dye-donor element for laser-induced thermal dye transfer comprising a support having thereon a dye layer and an infrared-absorbing material which is different from the dye in the dye layer, and wherein the infrared-absorbing material is an oxonol dye. In a preferred embodiment, the oxonol dye has the following formula: ##STR1## wherein: R.sup.1, R.sup.2 and R.sup.3 each independently represents hydrogen, halogen, cyano, alkoxy, aryloxy, acyloxy, aryloxycarbonyl, alkoxycarbonyl, carbamoyl, sulfonyl, acyl, acylamido, alkylamino, arylamino or a substituted or unsubstituted alkyl, aryl or hetaryl group; or any two of said R.sup.1, R.sup.2 and R.sup.3 groups may be joined together to complete a 5- to 7-membered substituted or unsubstituted carbocyclic or heterocyclic ring; or either R.sup.1 or R.sup.2 may be joined to R.sup.4 or R.sup.6 to complete a 5- to 7-membered substituted or unsubstituted carbocyclic or heterocyclic ring; or R.sup.2 or R.sup.3 may be joined to R.sup.5 or R.sup.Type: GrantFiled: June 16, 1989Date of Patent: July 30, 1991Assignee: Eastman Kodak CompanyInventors: Charles D. DeBoer, Steven Evans
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Patent number: 5036040Abstract: A dye-donor element for laser-induced thermal dye transfer comprising a support having thereon a dye layer comprising a polymeric binder, an image dye and an infrared-absorbing material which is different from the image dye in the dye layer, and wherein the infrared-absorbing material is a nickel-dithioene dye complex which is located coextensively with the image dye in the dye layer, the dye complex having the following formula: ##STR1## wherein: each R.sup.1 and R.sup.2 independently represents a substituted or unsubstituted alkyl group having from 1 to about 0 carbon atoms or one of R.sup.1 and R.sup.2, but not both simultaneously, represents a substituted or unsubstituted aryl or hetaryl group having from about 5 to about 10 atoms; or R.sup.1 and R.sup.Type: GrantFiled: April 20, 1990Date of Patent: July 30, 1991Assignee: Eastman Kodak CompanyInventors: Derek D. Chapman, Charles D. DeBoer
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Patent number: 5034303Abstract: A dye-donor element for laser-induced thermal dye transfer comprising a support having thereon a dye layer and an infrared-absorbing material which is different from the dye in the dye layer, and wherein the infrared-absorbing material is a trinuclear cyanine dye. In a preferred embodiment, the trinuclear cyanine dye has the following formula: ##STR1## wherein: R.sup.1, R.sup.2 and R.sup.3 each independently represents a substituted or unsubstituted alkyl or cycloalkyl group having from 1 to about 6 carbon atoms or an aryl or hetaryl group having from about 5 to about 10 atoms;R.sup.4, R.sup.5, R.sup.6, R.sup.7 and R.sup.8 each independently represents hydrogen, halogen, cyano, alkoxy, aryloxy, acyloxy, aryloxycarbonyl, alkoxycarbonyl, sulfonyl, carbamoyl, acyl, acylamido, alkylamino, arylamino or a substituted or unsubstituted alkyl, aryl or hetaryl group;or any of said R.sup.4, R.sup.5, R.sup.6, R.sup.7 and R.sup.8 groups may be combined with R.sup.1, R.sup.2 or R.sup.Type: GrantFiled: June 16, 1989Date of Patent: July 23, 1991Assignee: Eastman Kodak CompanyInventors: Steven Evans, Charles D. DeBoer
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Patent number: 5028579Abstract: An image forming method, comprising: providing a recording medium including a substrate and a transfer recording layer disposed thereon, the transfer recording layer being capable of changing its transfer characteristic when provided with light and heat energies; imparting heat energy to the transfer recording layer and imparting light energy to the transfer recording layer at an elevated temperature under such a condition that at least one of the light and heat energies corresponds to a recording information signal, thereby to form a transferable image in the transfer recording layer; and transferring the transferable image in the transfer recording layer to a transfer-receiving medium wherein at least light energy is imparted to the transfer recording layer prior to the formation of the transferable image.Type: GrantFiled: July 7, 1989Date of Patent: July 2, 1991Assignee: Canon Kabushiki KaishaInventors: Toshiharu Inui, Masanori Takenouchi
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Patent number: 5026606Abstract: Film suitable for thermal imaging comprising (1) a substrate formed from a flexible material, (2) a layer of thermally imageable material applied to at least one major surface of the substrate, and (3) a release coating overlying the layer of imageable material, the release coating being the hydrosilation product of (a) a polyorganohydrosiloxane, (b) an ethylenically-unsaturated perfluoropolyether monomer, and (c) an effective amount of a hydrosilation catalyst. Preferably, the film is transparent to visible light. The coating is sufficiently flexible so that the film bearing it can be imaged in commercially available infrared copying machines. Toner powder from plain paper copies will not stick to this coating when the imaging film is processed in a conventional thermal imaging apparatus.Type: GrantFiled: August 4, 1986Date of Patent: June 25, 1991Assignee: Minnesota Mining and Manufacturing CompanyInventors: Russell R. Isbrandt, Chung I. Young
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Patent number: 5026679Abstract: A cyan dye-donor element for thermal dye transfer comprising a support having thereon a dye layer comprising a mixture of cyan dyes dispersed in a polymeric binder, at least one of the cyan dyes having the formula: ##STR1## and at least one of the other of the dyes having the formula: ##STR2##Type: GrantFiled: November 21, 1990Date of Patent: June 25, 1991Assignee: Eastman Kodak CompanyInventors: Steven Evans, Derek D. Chapman
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Patent number: 5024990Abstract: A cyan dye-donor element for thermal dye transfer comprising a support having thereon a dye layer comprising a mixture of cyan dyes dispersed in a polymeric binder, at least one of the cyan dyes having the formula: ##STR1## and at least one of the other of the dyes having the formula: ##STR2##Type: GrantFiled: October 31, 1990Date of Patent: June 18, 1991Assignee: Eastman Kodak CompanyInventors: Derek D. Chapman, Steven Evans
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Patent number: 5023229Abstract: A magenta dye-donor element for thermal dye transfer comprises a support having thereon a dye layer comprising a mixture of a yellow dye and a magenta dye dispersed in a polymeric binder, the magenta dye having the formula: ##STR1## wherein: R.sup.1 is a substituted or unsubstituted alkyl or allyl group of from 1 to about 6 carbon atoms;X is an alkoxy group of from 1 to about 4 carbon atoms or represents the atoms which when taken together with R.sup.2 forms a 5- or 6-membered ring;R.sup.2 is any of the groups for R.sup.1 or represents the atoms which when taken together with X forms a 5- or 6-membered ring;R.sup.3 is a substituted or unsubstituted alkyl group of from 1 to about 6 carbon atoms, or a substituted or unsubstituted aryl group of from about 6 to about 10 carbon atoms;J is CO, CO.sub.2, --SO.sub.2 -- or CONR.sup.5 --;R.sup.Type: GrantFiled: October 31, 1990Date of Patent: June 11, 1991Assignee: Eastman Kodak CompanyInventors: Steven Evans, Derek D. Chapman
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Patent number: 5019480Abstract: A dye-donor element for laser-induced thermal dye transfer comprising a support having thereon a dye layer and an infrared-absorbing material which is different from the dye in the dye layer, and wherein the infrared-absorbing material is an indene-bridged-polymethine dye. In a preferred embodiment, the indene-bridged-polymethine dye has the following formula: ##STR1## wherein: R represents a substituted or unsubstituted alkyl or cycloalkyl group having from 1 to about 6 carbon atoms or an aryl or hetaryl group having from about 5 to about 10 atoms; R.sup.1, R.sup.2, R.sup.3, R.sup.4 and R.sup.5 each independently represents hydrogen, halogen, cyano, alkoxy, aryloxy, acyloxy, aryloxycarbonyl, alkoxycarbonyl, sulfonyl, carbamoyl, acyl, acylamido, alkylamino, arylamino or a substituted or unsubstituted alkyl, aryl or hetaryly group; or any two of said R, R.sup.1, R.sup.2, R.sup.3, R.sup.4 and R.sup.Type: GrantFiled: June 16, 1989Date of Patent: May 28, 1991Assignee: Eastman Kodak CompanyInventors: Charles D. DeBoer, Steven Evans
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Patent number: 5019549Abstract: These is disclosed donor elements for laser-induced thermal imaging processes containing infra-red absorbing squarylium dyes of the following structure: ##STR1## wherein R.sup.1, R.sup.2, R.sup.3, and R.sup.4 are each independently alkyl groups of from one to eight carbon atoms.Type: GrantFiled: October 25, 1990Date of Patent: May 28, 1991Inventors: Reid E. Kellogg, Evan D. Laganis, Sheau-Hwa Ma
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Patent number: 5017547Abstract: This invention relates to a process of forming a laser-induced thermal dye transfer image comprising:(a) contacting at least one dye-donor element comprising a support having thereon a dye layer and an infrared-absorbing material with a dye-receiving element comprising a support having thereon a polymeric dye image-receiving layer, said dye-donor and dye-receiver being separated by a finite distance to create a space;(b) imagewise-heating said dye-donor element by means of a laser; and(c) transferring a dye image to said dye-receiving element to form said laser-induced thermal dye transfer image,and wherein a vacuum is applied to said space between said donor and said receiver in order to minimize the mean free path the vaporized dye molecules travel without collision with other molecules for transfer to said receiver.Type: GrantFiled: June 26, 1990Date of Patent: May 21, 1991Assignee: Eastman Kodak CompanyInventor: Charles D. DeBoer
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Patent number: 5017452Abstract: A method for forming images on plain paper is disclosed, comprising the steps of: image-wise exposing an imaging sheet, said imaging sheet comprising a support having a layer of photosensitive microcapsules on the surface thereof, said microcapsules containing a photohardenable or photosoftenable composition including a photoinitiator, and a color precursor; assembling said image-wise exposed imaging sheet with a sheet of plain paper; subjecting said assembly of said imaging sheet and said plain paper to a uniform rupturing force to cause said photosensitive microcapsules to rupture and transfer an image-wise pattern of said color precursor to said plain paper thereby forming a latent image thereon; separating said imaging sheet from said plain paper; assembling said plain paper bearing said latent image with a developer-donor sheet comprising a support having a layer of a developer on the surface thereof to form a second assembly; subjecting said second assembly to a uniform force to transfer said developerType: GrantFiled: December 20, 1989Date of Patent: May 21, 1991Assignee: The Mead CorporationInventor: Lyudmila Feldman
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Patent number: 5015552Abstract: A transfer recording medium comprising a transfer recording layer is provided. The transfer recording layer causes an irreversible change in transfer characteristic when provided with plural kinds of energies such as heat, light and pressure energies. Such plural energies are applied to the transfer recording layer with at least one energy applied imagewise to provided a transferable portion or latent image portion in the transfer recording layer. The transferable portion is then transferred to a medium such as plain paper. The provision of plural kinds of energies aids in realization of high quality multi-color transfer image in a compact apparatus through functional separation of image formation and transfer operations. Further, even a multi-color image can be obtained through a single transfer step.Type: GrantFiled: June 29, 1989Date of Patent: May 14, 1991Assignee: Canon Kabushiki KaishaInventors: Yasuyuki Tamura, Shuzo Kaneko
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Patent number: 4988665Abstract: A thermally-transferred color filter array element comprising a transparent support having thereon a thermally-transferred image comprising a repeating mosaic pattern of colorants in a receiving layer, one of the colorants being a phenyl or thienyl azoaniline blue dye. In a preferred embodiment, the dye has the following formula: ##STR1## wherein R.sup.1 and R.sup.2 each independently represents hdyrogen; a substituted or unsubstituted alkyl group of from 1 to about 6 carbon atoms; a cycloalkyl group of from about 5 to about 7 carbon atoms; or a substituted or unsubstituted aryl or hetaryl group of from about 6 to about 10 carbon atoms;R.sup.3 represents hydrogen or a substituted or unsubstituted alkyl or alkoxy group of from 1 to about 10 carbon atoms;R.sup.2 may be taken together with R.sup.1 to form a 5- or 6-membered ring;R.sup.1 or R.sup.2 may be combined with R.sup.Type: GrantFiled: May 18, 1989Date of Patent: January 29, 1991Assignee: Eastman Kodak CompanyInventors: Helmut Weber, Steven Evans
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Patent number: 4973572Abstract: A dye-donor element for laser-induced thermal dye transfer comprising a support having thereon a dye layer comprising a polymeric binder and an infrared-absorbing material which is different from the dye in the dye layer, and wherein the infrared-absorbing material is a cyanine dye having a solution absorption maximum in methanol of between about 700 nm and 900 nm and having the following formula: ##STR1## wherein: R.sup.1 and R.sup.2 each independently represents a substituted or unsubstituted alkyl group;R.sup.3, R.sup.4, R.sup.5, R.sup.6, R.sup.7, and R.sup.8 each independently represents hydrogen or a substituted or unsubstituted alkyl group;or any two of said R.sup.1, R.sup.2, R.sup.3, R.sup.4, R.sup.5, R.sup.6, R.sup.7 and R.sup.8 groups may be joined together, directly or through one or more methyne or methylene groups to complete a substituted or unsubstituted carbocyclic or heterocyclic ring of 5 to 9 members;Z.sup.1 and Z.sup.Type: GrantFiled: January 10, 1990Date of Patent: November 27, 1990Assignee: Eastman Kodak CompanyInventor: Charles D. DeBoer
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Patent number: 4965242Abstract: A process of preparing a color filter array element for use in making a color liquid crystal display device comprising:(a) overlaying a dye-receiving element with a dye-donor element, the dye-receiving element comprising a dimensionally-stable temporary support having thereon, in order, a polymeric alignment layer, a transparent conducting layer and a dye-receiving layer;(b) imagewise heating the dye-donor element to transfer a dye image in a repeating mosaic pattern to the dye-receiving layer;(c) removing the dye-donor element from contact with the dye-receiving element;(d) laminating a transparent permanent support to the dye-receiving layer containing the dye image in a repeating mosaic pattern; and(e) removing the temporary support to expose one surface of the polymeric alignment layer, thereby forming the color filter array element.Type: GrantFiled: December 11, 1989Date of Patent: October 23, 1990Assignee: Eastman Kodak CompanyInventors: Charles D. DeBoer, Richard T. Klingbiel
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Patent number: 4963458Abstract: A light-sensitive image forming method using a recording element which comprises a recording layer on a support is disclosed. The recording layer contains at least two active components of a photopolymerizable composition such as a polymerizable compound and a polymerization initiator, both of which are essential for a photopolymerization reaction. The components are separated from each other by the shell of microcapsules in such manner that at least one component is contained in the microcapsules which are dispersed in the recording layer and the other component is arranged outside of the microcapsule. The image forming method comprises the steps of: heating the recording element to form the photopolymerizable composition in the recording layer; and imagewise exposing to light the recording element to imagewise polymerize the photopolymerizable composition.Type: GrantFiled: September 6, 1988Date of Patent: October 16, 1990Assignee: Fuji Photo Film Co., Ltd.Inventors: Shunichi Ishikawa, Fumiaki Shinozaki
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Patent number: 4962081Abstract: A thermally-transferred color filter array element comprising a transparent support having thereon a thermally-transferred image comprising a repeating mosaic pattern of colorants in a polycarbonate binder having a T.sub.g greater than about 200.degree. C.Type: GrantFiled: April 6, 1989Date of Patent: October 9, 1990Assignee: Eastman Kodak CompanyInventors: Daniel J. Harrison, Helmut Weber, Paul D. Yacobucci
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Patent number: 4952552Abstract: A dye-donor element for laser-induced thermal dye transfer comprising a support having thereon a dye layer which also contains an infrared-absorbing material which is different from the dye, and wherein the infrared-absorbing material is a quinoid dye derived from an anthraquinone or naphthoquinone having the following formula: ##STR1## wherein: Z represents the atoms necessary to complete a 5- to 7-membered substituted or unsubstituted carbocyclic or heterocyclic ring;each R independently represents hydrogen, a substituted or unsubstituted alkyl or alkoxy group having from 1 to about 6 carbon atoms or an aryl or hetaryl group having from about 5 to about 10 atoms;m is 4; andn is 2.Type: GrantFiled: January 10, 1990Date of Patent: August 28, 1990Assignee: Eastman Kodak CompanyInventors: Derek D. Chapman, Charles D. DeBoer
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Patent number: 4950639Abstract: A dye-donor element for laser-induced thermal dye transfer comprising a support having thereon a dye layer and an infrared-absorbing material which is different from the dye in the dye layer, and wherein the infrared-absorbing material is a bis(aminoaryl)polymethine dye. In a preferred embodiment, the bis(aminoaryl)polymethine dye has the following formula: ##STR1## wherein R.sup.1, R.sup.2 and R.sup.3 each independently represents hydrogen, halogen, cyano, alkoxy, aryloxy, acyloxy, aryloxycarbonyl, alkoxycarbonyl, sulfonyl, carbamoyl, acyl, acylamido, alkylamino, arylamino or a substituted or unsubstituted alkyl, aryl or hetaryl group; or any two of said R.sup.1, R.sup.2 and R.sup.3 groups may be joined together or with an adjacent aromatic ring to complete a 5- to 7-membered substituted or unsubstituted carbocyclic or heterocyclic ring;R.sup.4, R.sup.5, R.sup.6 and R.sup.Type: GrantFiled: June 16, 1989Date of Patent: August 21, 1990Assignee: Eastman Kodak CompanyInventors: Charles D. DeBoer, Steven Evans
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Infrared absorbing merocyanine dyes for dye-donor element used in laser-induced thermal dye transfer
Patent number: 4950640Abstract: A dye-donor element for laser-induced thermal dye transfer comprising a support having thereon a dye layer and an infrared-absorbing material which is different from the dye in the dye layer, and wherein the infrared-absorbing material is a merocyanine dye. In a preferred embodiment, the merocyanine dye has the following formula: ##STR1## wherein R represents a substituted or unsubstituted alkyl group having from 1 to about 6 carbon atoms or a substituted or unsubstituted aryl or hetaryl group having from about 5 to about 10 atoms;R.sup.1, R.sup.2, R.sup.3, and R.sup.4 each independently represents hydrogen, halogen, cyano, alkoxy, aryloxy, acyloxy, aryloxycarbonyl, alkoxycarbonyl, sulfonyl, carbamoyl, acyl, acylamido, alkylamino, arylamino or a substituted or unsubstituted alkyl, aryl or hetaryl group; or any two of said R, R.sup.1,R.sup.2, R.sup.3 and R.sup.Type: GrantFiled: June 16, 1989Date of Patent: August 21, 1990Assignee: Eastman Kodak CompanyInventors: Steven Evans, Charles D. DeBoer -
Patent number: 4948778Abstract: A dye-donor element for laser-induced thermal dye transfer comprising a support having thereon a dye layer and an infrared-absorbing material which is different from the dye in the dye layer, and wherein the infrared-absorbing material is an oxyindolizine dye. In a preferred embodiment, the oxyindolizine dye has the following formula: ##STR1## wherein R.sup.1 and R.sup.2 each independently represents a substituted or unsubstituted alkyl group having from 1 to about 6 carbon atoms or an aryl, cycloalkyl or hetaryl group having from about 5 to about 10 atoms;R.sup.3, R.sup.4, R.sup.5, R.sup.6 and R.sup.7 each independently represents hydrogen, halogen, cyano, alkoxy, aryloxy, acyloxy, aryloxycarbonyl, alkoxycarbonyl, sulfonyl, carbamoyl, acyl, acylamido, alkylamino, arylamino or a substituted or unsubstituted alkyl, aryl or hetaryl group;or any two of said R.sup.3, R.sup.4, R.sup.5, R.sup.6 and R.sup.Type: GrantFiled: June 20, 1989Date of Patent: August 14, 1990Assignee: Eastman Kodak CompanyInventor: Charles D. DeBoer
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Patent number: 4948777Abstract: A dye-donor element for laser-induced thermal dye transfer comprising a support having thereon a dye layer and an infrared-absorbing material which is different from the dye in the dye layer, and wherein the infrared-absorbing material is a bis(chalcogenopyrylo)polymethine dye. In a preferred embodiment, the bis(chalcogenopyrylo)polymethine dye has the following formula: ##STR1## wherein: R.sup.1, R.sup.2 and R.sup.3 each independently represents hydrogen, halogen, cyano, alkoxy, aryloxy, acyloxy, aryloxycarbonyl, alkoxycarbonyl, sulfonyl, carbamoyl, acyl, acylamido, alkylamino, arylamino or a substituted or unsubstituted alkyl, aryl or hetaryl group; or any two of said R.sup.1, R.sup.2 and R.sup.3 groups may be joined together to form a 5- to 7-membered substituted or unsubstituted carboxyclic or heterocyclic ring; or R.sup.1 may be joined to Z.sup.1 to form a fused 5- or 7-membered substituted or unsubstituted carbocyclic or heterocyclic ring; or R.sup.3 may be joined to Z.sup.Type: GrantFiled: June 16, 1989Date of Patent: August 14, 1990Assignee: Eastman Kodak CompanyInventors: Steven Evans, Charles D. DeBoer
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Patent number: 4948776Abstract: A dye-donor element for laser-induced thermal dye transfer comprising a support having thereon a dye layer and an infrared-absorbing material which is different from the dye in the dye layer, and wherein the infrared-absorbing material is a chalcogenopyrylo-arylidene dye. In a preferred embodiment, the chalcogenopyrylo-arylidene dye has the following formula: ##STR1## wherein: R.sup.1 and R.sup.2 each independently represents hydrogen, halogen, cyano, alkoxy, aryloxy, acyloxy, aryloxycarbonyl, alkoxycarbonyl, sulfonyl, carbamoyl, acyl, acylamido, alkylamino, arylamino or a substituted or unsubstituted alkyl, aryl or hetaryl group; or any of R.sup.1 and R.sup.2 may be joined together or with an adjacent aromatic ring to complete a 5- to 7-membered substituted or unsubstituted carbocyclic or heterocyclic ring;R.sup.3 and R.sup.6 each independently represents R.sup.1 or the atoms necessary to complete a 5- to 7-membered fused substituted or unsubstituted carbocyclic or heterocyclic ring;R.sup.4 and R.sup.Type: GrantFiled: June 16, 1989Date of Patent: August 14, 1990Assignee: Eastman Kodak CompanyInventors: Steven Evans, Charles D. DeBoer
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Patent number: 4948695Abstract: This invention relates to a photosensitive heat-transfer recording sheet and a photosensitive pressure-sensitive recording sheet both using photocurable microcapsules. These sheets enable transfer of multi-color images onto plain papers and accordingly have a very important industrial significance under the present situation where duplicate recording of color images is required.Type: GrantFiled: May 25, 1989Date of Patent: August 14, 1990Assignee: Mitsubishi Paper Mills, Ltd.Inventors: Toshihiko Matsushita, Shigetoshi Hiraishi, Sadao Morishita
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Patent number: 4946827Abstract: A glass-to-polycarbonate adhesive for a color filter array element for use in making a color liquid crystal display device comprising a glass support having thereon an adhesive layer and a polycarbonate dye-receiving layer, the adhesive layer comprising either(a) a polymer comprising the units of a linear polyester containing one or more substituted or unsubstituted aromatic diacids condensed with two or more substituted or unsubstituted aliphatic diols, said linear polyester having the formula: ##STR1## wherein: m is 100 to 90 mole %;n+p=m with the provision that each of n and p is at least 20 mole %; andQ and R each independently represents a different substituted or unsubstituted difunctional linking group;(b) a polymer comprising units of a linear polyester containing one or more substituted or unsubstituted aromatic diacids and one or more alicyclic diacids condensed with one or more aliphatic diols, said linear polyester having the formula: ##STR2## wherein m+k is 100 to 90 mole %;k is 5 to 50 mole %;n=Type: GrantFiled: December 11, 1989Date of Patent: August 7, 1990Assignee: Eastman Kodak CompanyInventors: Daniel J. Harrison, Paul D. Yacobucci
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Patent number: 4923860Abstract: A method of making an array of a repeating mosaic pattern of colorants carried on a support using(a) a plurality of donor materials each comprising a radiation-absorbing material and, respectively, a sublimable dye of a different color, and(b) a receiver element comprising a support having thereon a dye-receiving layer,wherein each donor material is in turn brought into face-to-face contact with the receiver and exposed patternwise to a high-intensity light source to transfer the desired pattern of dye to the receiver layer.Type: GrantFiled: September 18, 1989Date of Patent: May 8, 1990Assignee: Eastman Kodak CompanyInventor: Michael J. Simons
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Patent number: 4915519Abstract: An improved apparatus and process are described in which a direct negative is formed using commercially available multi-stylus recording heads. A negative precursor comprised of a transparent support and an opaque thermoplastic ink layer carried thereon, is brought into contact with an ink receiving medium comprised of a resistive layer and a thin conductive ink receiving layer thereon. Electrical currents are provided by the recording styli of the multi-stylus recording head to the resistive layer to provide sufficient heat to soften regions of the opaque ink brought into contact with the conductive layer, by which regions of said opaque ink are transferred to the ink receiving conductive layer. In this manner, a pattern of opaque ink regions is removed from the surface of said transparent support, whereby a direct negative is formed having light opaque and light transparent regions.Type: GrantFiled: October 30, 1987Date of Patent: April 10, 1990Assignee: International Business Machines Corp.Inventors: Ali Afzali-Ardakani, Mukesh Desai, Keith S. Pennington
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Patent number: 4897335Abstract: A light-sensitive material comprising a light-sensitive layer which contains silver halide, a reducing agent and a polymerizable compound provided on a support, characterized in that the silver halide and the polymerizable compound are together contained in microcapsules which are dispersed in the light-sensitive layer, and the light-sensitive layer further contains dispersed grains of a hydrophobic organic base compound and/or base precursor having a melting point of from 80.degree. to 180.degree. C. which are arranged outside of the microcapsules.Type: GrantFiled: March 11, 1987Date of Patent: January 30, 1990Assignee: Fuji Photo Film Co., Ltd.Inventor: Fujio Kakimi
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Patent number: 4857386Abstract: An inkable sheet comprises a base sheet, such as a PET film, having on a surface thereof an ink-absorbent resin layer comprising a vinyl pyrrolidone polymer and an acrylic or methacrylic polymer.Type: GrantFiled: February 3, 1987Date of Patent: August 15, 1989Assignee: Imperial Chemical Industries PLCInventors: Alan Butters, Diana C. Blackmore, Darrin J. Page
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Patent number: 4840870Abstract: In a heat-transfer image-receiving element adapted to have a superposed relation, at least during a heat-transfer processing, with a heat-transfer element containing a heat-transferable dye donator, wherein said heat-transfer image-receiving element comprises at least one of compounds having the following general Formula (I), (II) or (III) and at least one of compounds having the following general Formula (IV) ##STR1## wherein R.sub.1, R.sub.1 ', R.sub.3, R.sub.3 ' and R.sub.5 each is a hydrogen atom, alkyl, alkenyl, cycloalkyl, phenyl, naphthyl, heterocyclic, acyl, alkylsulfonyl, arylsulfonyl or aralkylsulfonyl group; R.sub.2, R.sub.4, R.sub.4 ', R.sub.6 and R.sub.7 each is a hydrogen atom, a halogen atom, or a monovalent organic group, l is an integer of from 1 to 4, q is an integer of from 1 to 6, m, n and p each is an integer of from 1 to 3, provided if the l, m, n, p and q each is an integer of not less than 2, the R.sub.2, R.sub.4, R.sub.4 ', R.sub.6 and R.sub.Type: GrantFiled: March 14, 1988Date of Patent: June 20, 1989Assignee: Konishiroku Photo Industry Co., Ltd.Inventors: Masaru Iwagaki, Toyoaki Masukawa, Tawara Komamura, Wataru Ishikawa, Kimie Hoshino
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Patent number: 4816371Abstract: A method for forming images which comprises image-wise exposing a photosensitive material to heat while simultaneously exposing said material to non-infrared actinic radiation, said material including a support and a layer of microcapsules containing an image-forming agent and a radiation curable composition on the surface of said support; said radiation curable composition being liquid at ambient temperatures and being substantially unhardened in the areas in which said material is simultaneously exposed to said heat and radiation and being substantially hardened in the areas in which said material is not simultaneously exposed to said heat and radiation; and subjecting said microcapsules to a uniform rupturing force such that said microcapsules image-wise release said image-forming agent.Type: GrantFiled: September 1, 1987Date of Patent: March 28, 1989Assignee: The Mead CorporationInventors: Richard F. Wright, Paul C. Adair
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Patent number: 4816367Abstract: A multicolor imaging material comprises a substrate, a capsule layer made up of a plurality of heat-meltable microcapsules including color former and a developer material layer. When the laser beams having wavelengths of .lambda..sub.1, .lambda..sub.2, and .lambda..sub.3 are applied to the multicolor imaging material according to the signals corresponding to three primary colors, the heat-meltable microcapsules for individual colors independently generate heat, thereby causing the heat-meltable substance to be melted. This brings about the reaction of the color formers for individual colors with the developer to developer colors, thereby forming a color image comprised of cyan, magenta and yellow.Type: GrantFiled: September 8, 1987Date of Patent: March 28, 1989Assignee: Seiko Instruments Inc.Inventors: Hiromichi Sakojiri, Hiroshi Takahashi
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Patent number: 4788128Abstract: A transfer printing medium comprising a substrate supporting a thermal transfer dye and a radiation absorber positioned to provide thermal energy to the transfer dye when subjected to radiation within a predetermined absorption waveband, has a radiation absorber which is an infra-red absorbing poly(substituted)phthalocyanine compound in which each of at least five of the peripheral carbon atoms in the 1, 4, 5, 8, 9, 12, 13 or 16 positions (the "3,6-positions") of the phthalocyanine nucleus, as shown in Formula I, is linked by an atom from Group VB or Group VIB of the Periodic Table, other than oxygen, to a carbon atom of an organic radical. In preferred compounds each of the eight 3,6-positions is linked by an atom from Group VB or Group VIB, especially sulphur, selenium or nitrogen, to an organic radical.Type: GrantFiled: October 20, 1986Date of Patent: November 29, 1988Assignee: Imperial Chemical Industries PLCInventor: William A. Barlow
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Patent number: 4764444Abstract: A color transfer imaging element comprising a support having thereon an imaging layer comprising a thermographic, photothermographic, or electrographic material capable of forming an image which absorbs or scatters light or infrared radiation, and a dye layer from which a dye image can be transferred to an image receiver when the imaging element is overall exposed to radiation that is absorbed or scattered by the imaged areas of the imaging layer, thereby causing imagewise heating of the dye. The dye layer is positioned relative to the other layers so as to allow this imagewise transfer of dye to the image receiver.Type: GrantFiled: October 16, 1986Date of Patent: August 16, 1988Assignee: Eastman Kodak CompanyInventors: Michael J. Simons, Roland G. Willis, Donald M. Harvey
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Patent number: 4621040Abstract: A method for forming an image which comprises imagewise exposing an imaging element with a laser, said imaging element comprising a support carrying on a first surface, in sequence, a layer of microcapsules containing an ink, and a laser-absorptive, ink barrier layer; superposing an imaging-receiving layer adapted to receive ink from said microcapsules over said imaging element and rupturing said microcapsules; whereby ink from said microcapsules in the exposed areas of the imaging element diffuses to said superposed receiving layer forming an image corresponding to the laser exposure.Type: GrantFiled: October 21, 1985Date of Patent: November 4, 1986Assignee: Polaroid CorporationInventor: Michael S. Viola
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Patent number: 4613553Abstract: Metallic salts of organic charge-transfer agents, such as TCNQ, TNAP, TCNE and DDQ and their derivatives, can be processed by an electron beam for a variety of useful electronic and optical applications. The metallic charge transfer salts can be used to deposit high resolution conductive lines directly without developing solutions or subsequent metallization steps. The compounds can also be employed in the conventional manner as resists for doping (i.e., ion diffusion or implantation) and to diffuse metals into substrates. In particular, electronic devices, optical devices and image-storage devices are disclosed which can be formed by simple electron beam processed of metal charge-transfer salt films deposited on substrates.Type: GrantFiled: May 31, 1985Date of Patent: September 23, 1986Assignee: Brown University Research FoundationInventors: William M. Risen, Jr., Efstratios I. Kamitsos
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Patent number: 4585722Abstract: Optical recording medium includes a substrate, a coloring agent layer formed on the substrate, a light absorber layer formed on the coloring agent layer and a developer layer formed on the light absorber layer. The coloring agent layer is separated from the developer layer by the light absorber layer and the lamination layer composed of these layers has a uniform thickness. The optical recording medium is produced by vacuum depositing a coloring agent, a light absorber and a developer successively on the substrate to form a multi-layer construction, the substrate being capable of transmitting visible light and near infrared light. Alternatively, the optical recording medium contains a plurality of lamination layers mentioned above. The optical recording medium has a high contrast and achieves a high speed multi-color recording.Type: GrantFiled: February 20, 1985Date of Patent: April 29, 1986Assignee: Nippon Telegraph & Telephone Public CorporationInventors: Akira Morinaka, Shigeru Oikawa, Hirotsugu Sato
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Patent number: 4568621Abstract: Processes for thermal transfer printing are disclosed which comprise electroerosion printing to produce an image bearing element and exposing the imaged element to irradiation so as to permit transfer of thermographic ink from an associated ink layer or ink-containing element onto an ink receiving substrate thus producing copies of the image carried by the image bearing element. Also, described are products for use in such processes.Type: GrantFiled: October 22, 1984Date of Patent: February 4, 1986Assignee: International Business Machines CorporationInventors: Ari Aviram, Mitchell S. Cohen
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Patent number: 4507483Abstract: 3-[(Substituted-amino)(aryl or heteroaryl)methyl]-1H-indoles which are useful as color-formers in pressure-sensitive carbonless duplicating systems and thermal marking systems are prepared by reacting 3-[(arylsulfonyl)(aryl or heteroaryl)methyl]-1H-indoles with amines or precursors thereof in the presence of a base.Type: GrantFiled: March 9, 1983Date of Patent: March 26, 1985Assignee: The Hilton-Davis Chemical Co.Inventors: Paul J. Schmidt, William M. Hung
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Patent number: 4482608Abstract: Coating for infrared transparency films and thermally imageable films and films prepared with such coating. The coating comprises a copolymer formed from (a) at least one fluorocarbon monomer and (b) at least one monomer which imparts hardness to the copolymer. The coating serves to prevent the transfer of toner powder from an original which is in actuality an electrophotographic copy to the transparency film. The copolymer may contain from about 12 percent to about 85 percent fluorocarbon monomer, the remainder being the monomer which imparts hardness to the coating. Suitable monomers for imparting hardness to the copolymer include acrylates, methacrylates, acrylamides, methacrylamides, acrylonitriles, methacrylonitriles, and styrenes.Type: GrantFiled: July 26, 1982Date of Patent: November 13, 1984Assignee: Minnesota Mining and Manufacturing CompanyInventors: Russell R. Isbrandt, Robert D. Lowery
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Patent number: 4388387Abstract: A process for forming color images which comprises providing a light absorbing dye layer or a dye containing layer on a base, at least the surface of which is composed of a transparent dye accepting polymer through which dyes are capable of thermally diffusing, imagewise exposing the dye layer or the dye containing layer to light having a high energy density such that a dye image is formed in the dye accepting polymer in the exposed area by thermal diffusion of the dye, and thereafter removing the dye or the dye containing layer in the unexposed areas.Type: GrantFiled: March 26, 1980Date of Patent: June 14, 1983Assignee: Fuji Photo Film Co., Ltd.Inventor: Masayoshi Tsuboi
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Patent number: 4388362Abstract: A releasable heat-sensitive recording paper is disclosed wherein a heat-sensitive color forming layer and a protective layer are laminated in succession on the surface of a substrate, said color forming layer consisting essentially of a leuco dye and an acidic substance, said protective layer consisting essentially of a water soluble resin, and further a required pattern is printed on this protective layer with an ultraviolet setting type printing ink, while a pressure-sensitive adhesive layer is formed on the back of the substrate and the thus formed layer is covered with a releasable paper.Type: GrantFiled: October 8, 1981Date of Patent: June 14, 1983Assignee: Ricoh Co., Ltd.Inventors: Susumu Iwata, Keiichi Maruta, Yukihiro Yuyama
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Patent number: 4387153Abstract: The invention relates to a dry transfer process which employs ultraviolet light and photosensitive materials.The transfer materials used comprise a donor complex layer (c) and a receptor layer (c1). The donor complex layer (c) comprises a carrier (1), a priming layer (2), signs or imprints (3) produced by means of a colorless color-producing material, and a barrier layer (4) which is degradable under the action of ultraviolet light. The receptor layer (c1) comprises a carrier 6 coated with a layer (5) comprising a color developer.The transferred symbols or images (7) are obtained without the physical passage of an element or of an image from the donor layer to the receptor layer; their quality is comparable to that of printed characters.Type: GrantFiled: October 15, 1981Date of Patent: June 7, 1983Assignee: Mecanorma S.A.Inventor: Mark P. Bonneron
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Patent number: 4374691Abstract: A composite material and method for forming graphics such as letters or numbers that are pressure transferable to a substrate. The composite material includes an accepting tape including a layer of latent adhesive material on a receiving web, and a friable slightly adhesive layer lightly adhered to a donor web. When the layers are pressed together and the composite material is selectively heated in graphic patterns, corresponding portions of the adhesive material and friable layer adhere together so that upon subsequent separation of the layer of adhesive and the donor web portions of the friable layer transfer to the accepting tape in the heated areas to provide graphics. When the graphics are then positioned against a substrate and are pressed against the substrate by rubbing pressure applied through the receiving web, the adhesive layer will tear around the graphic and separate from the receiving web over the graphic so that the graphic will be transferred to the substrate.Type: GrantFiled: May 9, 1980Date of Patent: February 22, 1983Assignee: Minnesota Mining and Manufacturing CompanyInventor: Jan D. Vanden Bergh