Imagewise Heating, Element Or Image Receiving Layers Therefor Or Imagewise Vapor And Gas Transfer Process, Element Or Image Receiving Layer Therefor Patents (Class 430/200)
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Patent number: 6878495Abstract: A method is described for producing image data to be used by a laser thermal transfer apparatus having a multiple channel printhead of laser beams for transferring different organic material with dopants from a donor onto on OLED substrate to form different color emissive sites on the substrate.Type: GrantFiled: October 15, 2003Date of Patent: April 12, 2005Assignee: Eastman Kodak CompanyInventors: Andrea S. Rivers, Roger A. Braden, Michael L. Boroson
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Patent number: 6872500Abstract: An element for making patterns on an electroconductive substrate, the element comprising a support, on which is disposed: a) a conductive layer containing an electrically conductive polymer, a polyanion and a conductivity enhancing agent; and b) a mixing layer containing a thermally mobile material; wherein, upon imagewise heating the mixing layer, the thermally mobile material mixes with the conductive layer, thereby causing the initial surface resistivity (SR) of the conductive layer to imagewise increase from an initial value SRi, which is lower than 105?/square, to SRi?, ? being at least 102.Type: GrantFiled: August 26, 2003Date of Patent: March 29, 2005Assignee: Eastman Kodak CompanyInventors: Mitchell S. Burberry, Charles C. Anderson, Mark Lelental
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Patent number: 6866979Abstract: A thermal transfer donor element is provided which comprises a support, a light-to-heat conversion layer, an interlayer, and a thermal transfer layer. When the above donor element is brought into contact with a receptor and imagewise irradiated, an image is obtained which is free from contamination by the light-to-heat conversion layer. The construction and process of this invention is useful in making colored images including applications such as color proofs and color filter elements.Type: GrantFiled: December 1, 2003Date of Patent: March 15, 2005Assignee: 3M Innovative Properties CompanyInventors: Jeffrey C. Chang, John S. Staral, William A. Tolbert, Martin B. Wolk, Claire A. Jalbert, Hsin-hsin Chou
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Patent number: 6864033Abstract: A multicolor image-forming material comprising: an image-receiving sheet comprising an image-receiving layer; and at least four thermal transfer sheets each comprising a support, a photothermal converting layer and an image-forming layer, and each having a different color, wherein an image is formed by the method comprising the steps of: superposing each one of the at least four thermal transfer sheets on the image-receiving sheet to be in a state of the image-forming layer being in contact with the image-receiving layer; and irradiating the thermal transfer sheet with a laser beam to transfer an image in an area of the image-forming layer subjected to irradiation onto the image-receiving layer, and a ratio of the reflection optical density (ODr) of the image-forming layer to a thickness of the image-forming layer (?m unit) is 1.50 or more to 1, and a contact angle in relation to water of the image-forming layer and the image-receiving layer is from 7.0 to 120.0°.Type: GrantFiled: January 23, 2002Date of Patent: March 8, 2005Assignee: Fuji Photo Film Co., Ltd.Inventors: Hideyuki Nakamura, Mitsuru Yamamoto, Kazuhito Miyake, Shinichi Yoshinari, Akira Hatakeyama
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Patent number: 6864034Abstract: A transfer device in which a material which transmits a laser beam LB is employed as an upper mold, and a photothermal conversion layer is formed thereon. A transfer film, at which a transfer material layer is formed, and a workpiece are superposed and pressured between the upper mold and a lower mold. During this pressuring, the laser beam is irradiated in accordance with a pattern of an organic electroluminescent light-emitting layer that is to be formed on the workpiece. Thus, the photothermal conversion layer is heated and the transfer material layer is softened. As a result, the transfer material layer is cleaved and detached from a temporary support, and a component in the transfer material layer that is to form the organic electroluminescent light-emitting layer is transferred to the workpiece. Accordingly, efficient transfer processing is enabled when a transfer material is transferred to a transfer object by a thermal imaging process.Type: GrantFiled: November 7, 2003Date of Patent: March 8, 2005Assignee: Fuji Photo Film Co., Ltd.Inventors: Hiroyuki Nishida, Keisuke Endo
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Patent number: 6855636Abstract: The present invention provides a process for selectively thermally transferring insulators onto organic electroluminescent stacks or layers to electronically isolate adjacent devices upon deposition of electrode material. This can allow the formation of top electrodes for a plurality of organic electroluminescent devices on a substrate via one deposition step to form a single common top electrode or a plurality of electrodes patterned by shadowing due to the presence of the insulators.Type: GrantFiled: October 31, 2002Date of Patent: February 15, 2005Assignee: 3M Innovative Properties CompanyInventors: Steven D. Theiss, Ha T. Le, William A. Tolbert, Martin B. Wolk, Paul F. Baude
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Patent number: 6855473Abstract: The present invention relates to a method for image formation using an intermediate transfer recording medium. An object of the present invention is to provide an intermediate transfer recording medium and a method for image formation which can yield a thermally transferred image possessing excellent various fastness properties even under severe service conditions, can transfer a protective layer onto an image on the object without transfer failure in an accurate and simple manner, and, in addition, can yield a highly lightfast image which is not deteriorated upon exposure to ultraviolet light. The intermediate transfer recording medium comprises: a sheet substrate provided with a resin layer; and a transparent sheet provided with a receptive layer, the sheet substrate provided with the resin layer having been put on top of the transparent sheet provided with the receptive layer so that the transfer sheet faces the resin layer.Type: GrantFiled: April 12, 2002Date of Patent: February 15, 2005Assignee: Dai Nippon Printing Co., Ltd.Inventors: Kozo Odamura, Katsuyuki Oshima, Takayuki Imai, Shinji Kometani, Masayasu Yamazaki
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Patent number: 6855474Abstract: A donor element for proofing having at least a transfer material disposed on a substrate for the preparation of a digital halftone proof having consistent dot density characteristics over time. The donor element includes a transfer material having a donor binder, a cationic infrared absorbing dye, a thermally activated crosslinking agent and a dispersible material The donor element can also include a distinct, intermediate transfer layer disposed between the substrate and the transfer material. The donor element can be used in conjunction with a receptor element to provide a thermal imaging system.Type: GrantFiled: May 3, 2004Date of Patent: February 15, 2005Assignee: Kodak Polychrome Graphics LLCInventors: Kevin M. Kidnie, M. Zaki Ali, Pao C. Vang
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Patent number: 6852355Abstract: Processes for effecting thermal transfer of electroactive organic material are disclosed wherein unwanted portions of a layer of electroactive organic material supported by a donor element are removed or transferred from the layer by thermal transfer, particularly laser-induced thermal transfer, leaving a desired pattern of the electroactive organic material on the donor element. The electroactive organic material may be an organic material exhibiting electroluminescence, charge transport, charge injection, electrical conductivity, semiconductivity and/or exciton blocking. The layer of electroactive organic material may comprise more than one layer of different types of electroactive organic material. The exposure pattern is a negative image of the desired pattern. The electroactive organic material of the desired pattern is not, therefore, exposed to the heat which can cause decomposition.Type: GrantFiled: February 19, 2002Date of Patent: February 8, 2005Assignee: E. I. du Pont de Nemours and CompanyInventor: Graciela B. Blanchet-Fincher
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Patent number: 6844128Abstract: In one method of making an organic electroluminescent device, a transfer layer is solution coated on a donor substrate. The transfer layer includes an amorphous, non-polymeric, organic matrix with a light emitting material disposed in the matrix. The transfer layer is then selectively patterned on a receptor. Examples of patterning methods include laser thermal transfer or thermal head transfer. The method and associated materials can be used to form, for example, organic electroluminescent devices.Type: GrantFiled: February 5, 2004Date of Patent: January 18, 2005Assignee: 3M Innovative Properties CompanyInventors: Yong Hsu, Martin B. Wolk
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Publication number: 20040259021Abstract: The present invention relates to an image transfer element for thermally induced image transfer, a laser assemblage and a process for producing a thermal image. More particularly, the present invention relates to an image transfer element comprising a colorant layer that contains a metal salt, a laser assemblage containing the image transfer element and process for producing a thermal image utilizing the image transfer element.Type: ApplicationFiled: June 18, 2004Publication date: December 23, 2004Inventors: Easley Wallace, Gregory C. Weed
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Patent number: 6830863Abstract: A multicolor image-forming material comprises: an image-receiving sheet having an image-receiving layer; and at least four thermal transfer sheets each including a support, a light-to-heat converting layer and an image-forming layer, in which each of the thermal transfer sheets has a different color, wherein an image is formed by: superposing the image-forming layer in each of the at least four thermal transfer sheets on the image-receiving layer in the image-receiving sheet, in which the image-forming layer is opposed to the image-receiving layer; irradiating the image-forming layer in the thermal transfer sheet with a laser beam; and transferring the irradiated area of the image-forming layer onto the image-receiving layer in the image-receiving sheet, and each of the light-to-heat converting layers in the at least four thermal transfer sheets has a ratio of an optical density (OD) to a layer thickness: OD/layer thickness (&mgr;m unit) of 0.57 or more.Type: GrantFiled: January 25, 2002Date of Patent: December 14, 2004Assignee: Fuji Photo Film Co., Ltd.Inventors: Naotaka Wachi, Akihiro Shimomura, Kazuhito Miyake, Yasutomo Goto, Mitsuru Yamamoto
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Patent number: 6824950Abstract: A method for forming an organic light-emitting device with improved performance including forming an anode over a substrate and providing a donor element including light-emitting materials and positioning such donor element in a material-transferring relationship with the substrate. The device also including illuminating the donor element with radiation to cause the transfer of light-emitting material to deposit the light-emitting material and form a light-emitting layer the anode and forming a performance-enhancing layer over the light-emitting layer including one or more chemical reducing materials selected to improve the performance of the organic light-emitting device. The device further includes forming an electron-transporting layer over the performance-enhancing layer and forming a cathode over the electron-transporting layer.Type: GrantFiled: February 14, 2003Date of Patent: November 30, 2004Assignee: Eastman Kodak CompanyInventors: Michael L. Boroson, Liang-Sheng Liao
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Publication number: 20040232943Abstract: This invention discloses a releasable adhesion layer having good adhesion during high temperature fabrication process in the absence of light, and delaminating at a lower temperature in the presence of light. One embodiment of this invention is a film of polymer whose thermal decomposition temperature changes drastically upon photoexposure. These materials, prior to photoexposure, can withstand temperatures in the range of approximately 200° C. to 300° C. without decomposition, yet decompose at around 100° C. with photoexposure. The releasable adhesion layer can be used in a thermal transfer element, sandwiching a donor substrate and a transfer layer having a plurality of multicomponent transfer units. In the absence of light, the releasable adhesion layer can sustain high temperature processing of these multicomponent transfer units. By photoexposing according to a pattern, the photoexposed multicomponent transfer units can be selectively released at a low temperature to transfer to a receptor.Type: ApplicationFiled: May 23, 2003Publication date: November 25, 2004Inventors: James Sheats, Tue Nguyen
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Patent number: 6818363Abstract: A thermally imageable layer comprising an aqueous dispersion containing an immiscible compound, typically a near infrared absorber, and a dispersant, typically an acrylic polymer, which layer is useful in laser induced colorant transfer processes.Type: GrantFiled: October 24, 2002Date of Patent: November 16, 2004Assignee: E. I. du Pont de Nemours and CompanyInventors: Graciela Beatriz Blanchet Fincher, Ronald J. Convers, Gregory C. Weed
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Publication number: 20040224248Abstract: A multicolor image-forming material comprising: an image-receiving sheet comprising a support and an image-receiving layer; and at least four thermal transfer sheets each comprising a support, a light-to-heat converting layer and an image-forming layer, and each having a different color, wherein an image is formed by the method comprising the steps of: superposing each one of the at least four thermal transfer sheets on the image-receiving sheet to be in a state of the image-forming layer being in contact with the image-receiving layer; and irradiating the thermal transfer sheet with a laser beam to transfer an image in an area of the image-forming layer subjected to irradiation onto the image-receiving layer, and at least one layer selected from layers comprised in the image-receiving sheet and the at least four thermal transfer sheets comprises a fluorine-series surface active agent which is a homopolymer comprising a polymerizable monomer represented by the formula (1) and having a weight average molecularType: ApplicationFiled: June 10, 2004Publication date: November 11, 2004Applicant: FUJI PHOTO FILM CO., LTD.Inventors: Akihiro Shimomura, Hideyuki Nakamura, Shinichi Yoshinari
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Patent number: 6815141Abstract: A method of producing an organic LED display panel, which includes: a step of preparing a donor film by forming a transfer film on a base film comprising at least a foundation film and a light-to-heat conversion layer and a step of combining the donor film with a substrate and irradiating the donor film with one of a light beam and a heat radiation beam to pattern-transfer the transfer film from the donor film onto the substrate, wherein surfaces of the base film and the substrate which are to be brought into contact with the transfer film are hydrophilic or hydrophobic, and have water contact angles &thgr;1 and &thgr;2, respectively, which satisfy the following expression (I): &thgr;1−&thgr;2<50 degrees (I)Type: GrantFiled: May 16, 2002Date of Patent: November 9, 2004Assignee: Sharp Kabushiki KaishaInventors: Yoshimasa Fujita, Kimitaka Ohhata
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Patent number: 6811946Abstract: A multicolor image-forming material comprising: an image-receiving sheet comprising a support and an image-receiving layer; and at least four thermal transfer sheets each comprising a support, a light-to-heat converting layer and an image-forming layer, and each having a different color, wherein an image is formed by the method comprising the steps of: superposing each one of the at least four thermal transfer sheets on the image-receiving sheet to be in a state of the image-forming layer being in contact with the image-receiving layer; and irradiating the thermal transfer sheet with a laser beam to transfer an image in an area of the image-forming layer subjected to irradiation onto the image-receiving layer, and at least one layer selected from layers comprised in the image-receiving sheet and the at least four thermal transfer sheets comprises a fluorine-series surface active agent which is a homopolymer comprising a polymerizable monomer represented by the formula (1) and having a weight average molecularType: GrantFiled: March 18, 2002Date of Patent: November 2, 2004Assignee: Fuji Photo Film Co., Ltd.Inventors: Akihiro Shimomura, Hideyuki Nakamura, Shinichi Yoshinari
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Patent number: 6811938Abstract: A method of aligning a substrate for use in manufacture of OLED displays with a laser which produces a beam that causes the transfer of organic material from a donor element to the substrate, including providing at least one fiducial mark on the substrate; positioning the substrate relative to the laser and providing relative movement between the substrate and the laser and the laser beam until the laser beam impinges upon the fiducial mark; and detecting when the laser beam impinges upon the fiducial mark and determining the position and orientation of the substrate.Type: GrantFiled: August 29, 2002Date of Patent: November 2, 2004Assignee: Eastman Kodak CompanyInventors: Lee W. Tutt, Mark D. Bedzyk
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Patent number: 6805979Abstract: A transfer film comprising a base film, a transfer layer, and a transfer auxiliary layer formed between the base film and the transfer layer so as to be in contact with at least the transfer layer, this transfer auxiliary layer having a melting point or a glass transition temperature lower than that of the transfer layer, wherein at least a portion of the transfer layer can be thermally transferred onto a substrate.Type: GrantFiled: May 2, 2002Date of Patent: October 19, 2004Assignee: Sharp Kabushiki KaishaInventors: Takashi Ogura, Shinji Yamana, Tomonori Akai
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Patent number: 6800429Abstract: An imaging material comprising a support having disposed thereon: a) at least one image-formning layer, and b) at least one transparent electrically conductive antistatic layer that comprises electronically conductive polymer particles, a neutral-charge conductivity enhancer, and a polymeric binder comprising gelatin or gelatin derivatives.Type: GrantFiled: December 26, 2001Date of Patent: October 5, 2004Assignee: Eastman Kodak CompanyInventors: Mark Lelental, Charles C. Anderson, John M. Pochan, James L. Wakley, James F. Elman
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Publication number: 20040180284Abstract: A multicolor imaging system is described wherein at least two, and preferably three, different image-forming layers of a thermal imaging member are addressed at least partially independently by a thermal printhead or printheads from the same surface of the imaging member by controlling the temperature of the thermal printhead(s) and the time thermal energy is applied to the image-forming layers. Each color of the thermal imaging member can be printed alone or in selectable proportion to the other color(s). Novel thermal imaging members are also described.Type: ApplicationFiled: March 23, 2004Publication date: September 16, 2004Applicant: Polaroid CorporationInventors: Jayprakash C. Bhatt, Brian D. Busch, Daniel P. Bybell, F. Richard Cottrell, Anemarie DeYoung, Chien Liu, Stephen J. Telfer, Jay E. Thornton, William T. Vetterling
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Patent number: 6790594Abstract: Making a high absorption donor substrate for providing one or more OLED materials to an OLED device by: providing an absorber anti-reflection layer over a transparent support element, the anti-reflection layer having the real portion of its index of refraction greater than 3.0, and a thickness near the first reflectivity minimum at the wavelength of interest; providing a metallic heat-absorbing layer over the anti-reflection layer for absorbing laser light which passes through the transparent support element and the anti-reflection layer; and selecting the transparent support element, the anti-reflection layer, and the metallic heat-absorbing layer to have an average reflectivity of less than 10%, and the micro reflectivity variation due to variations in the thickness of the transparent support element of less than 10% at the wavelength of interest; and providing one or more organic material layers in the absence of a binder material, over the metallic heat-absorbing layer.Type: GrantFiled: March 20, 2003Date of Patent: September 14, 2004Assignee: Eastman Kodak CompanyInventors: Donald R. Preuss, Fridrich Vazan
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Patent number: 6787298Abstract: Disclosed is a highly sensitive photothermographic material containing on a support a silver salt of an organic acid, a photosensitive silver halide, a reducing agent, a binder and, for example, a compound of which one-electron oxidized derivative produced by one electron oxidation of the compound is capable of releasing two or more electrons with a bond cleavage.Type: GrantFiled: October 3, 2002Date of Patent: September 7, 2004Assignee: Fuji Photo Film Co., Ltd.Inventors: Takahiro Goto, Kohzaburoh Yamada, Tomoyuki Ohzeki, Eiichi Okutsu, Shoji Yasuda
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Patent number: 6783915Abstract: A black matrix can be formed by thermal transfer on a receptor substrate for use, for example, in a display application. This black matrix can be used, for example, as a color filter black matrix or a TFT (thin film transistor) black matrix to provide contrast and/or to separate adjacent electrically-conducting components.Type: GrantFiled: July 7, 2003Date of Patent: August 31, 2004Assignee: 3M Innovative Properties CompanyInventors: Richard J. Pokorny, Raghunath Padiyath, Kazuki Noda
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Publication number: 20040161695Abstract: A method for forming an organic light-emitting device with improved performance including forming an anode over a substrate and providing a donor element including light-emitting materials and positioning such donor element in a material-transferring relationship with the substrate. The device also includes illuminating the donor element with radiation to cause the transfer of light-emitting material to deposit the light-emitting material and form a light-emitting layer over the anode and forming a performance-enhancing layer over the light-emitting layer including one or more chemical reducing materials selected to improve the performance of the organic light-emitting device. The device further includes forming an electron-transporting layer over the performance-enhancing layer and forming a cathode over the electron-transporting layer.Type: ApplicationFiled: February 14, 2003Publication date: August 19, 2004Applicant: Eastman Kodak CompanyInventors: Michael L. Boroson, Liang-Sheng Liao
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Publication number: 20040161696Abstract: In one method of making an organic electroluminescent device, a transfer layer is solution coated on a donor substrate. The transfer layer includes an amorphous, non-polymeric, organic matrix with a light emitting material disposed in the matrix. The transfer layer is then selectively patterned on a receptor. Examples of patterning methods include laser thermal transfer or thermal head transfer. The method and associated materials can be used to form, for example, organic electroluminescent devices.Type: ApplicationFiled: February 5, 2004Publication date: August 19, 2004Applicant: 3M Innovative Properties CompanyInventors: Yong Hsu, Martin B. Wolk
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Patent number: 6773860Abstract: An image receiving sheet, in which the received image is further transferable to a final recording medium is disclosed, comprising a support having thereon a heat-softening layer, an interlayer and an image receiving layer, wherein the interlayer has a surface roughness (Ra) of 0.05 to 5 &mgr;m and the image receiving layer has a surface roughness (Ra) of 0.01 to 0.4 &mgr;m, and the surface roughness (Ra) of the interlayer being greater than that of the image receiving layer. An imaging process by use of the image receiving sheet is also disclosed.Type: GrantFiled: August 22, 2002Date of Patent: August 10, 2004Assignee: Konica CorporationInventors: Takaaki Kuroki, Rieko Takahashi
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Process for making a flexographic printing plate and a photosensitive element for use in the process
Patent number: 6773859Abstract: The invention relates to a process for preparing a flexographic printing plate from a photosensitive element having a photopolymerizable layer and a thermally removable layer on the photopolymerizable layer. The process includes imagewise exposing the photosensitive element and thermally treating the exposed element to form a relief suitable for use in flexographic printing. The thermally removable layer can be transparent or opaque to actinic radiation. The invention also relates to a photosensitive element for use in this process. The photosensitive element includes a photopolymerizable layer and at least one thermally removable layer having a filler and a binder, wherein the binder is less than 49% by weight, based on the total weight of the binder and filler.Type: GrantFiled: February 27, 2002Date of Patent: August 10, 2004Assignee: E. I. du Pont de Nemours and CompanyInventors: Roxy Ni Fan, Mark A. Hackler, Anandkumar R. Kannurpatti, Adrian Lungu, Bradley K. Taylor -
Publication number: 20040142273Abstract: A transfer device in which a material which transmits a laser beam LB is employed as an upper mold, and a photothermal conversion layer is formed thereon. A transfer film, at which a transfer material layer is formed, and a workpiece are superposed and pressured between the upper mold and a lower mold. During this pressuring, the laser beam is irradiated in accordance with a pattern of an organic electroluminescent light-emitting layer that is to be formed on the workpiece. Thus, the photothermal conversion layer is heated and the transfer material layer is softened. As a result, the transfer material layer is cleaved and detached from a temporary support, and a component in the transfer material layer that is to form the organic electroluminescent light-emitting layer is transferred to the workpiece. Accordingly, efficient transfer processing is enabled when a transfer material is transferred to a transfer object by a thermal imaging process.Type: ApplicationFiled: November 7, 2003Publication date: July 22, 2004Inventors: Hiroyuki Nishida, Keisuke Endo
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Patent number: 6764803Abstract: Laser transfer film for durable inscription on components made from at least one backing layer, where on at least part of the underside of the backing layer there is an adhesion layer, wherein a pigment layer which comprises at least one laser-sensitive pigment has been applied to at least part of the adhesion layer and/or backing layer.Type: GrantFiled: November 20, 2001Date of Patent: July 20, 2004Assignee: tesa AGInventors: Arne Koops, Sven Reiter
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Patent number: 6762006Abstract: A donor element for use in laser thermal imaging has a layer which comprises an infrared-absorbing material, an image dye and a polymer matrix comprising a thermally degradable polymer and a non thermally degradable polymer there being an interaction between the infrared-absorbing material and the non degradable polymer to facilitate retention of the infrared-absorbing material in the donor element. The degradable and non degradable polymers are preferably copolymers both of which contain methacrylic acid as a monomer. The degradable polymer is preferably a copolymer of methoxyethyl cyanoacrylate and methacrylic acid preferably in molar proportions of from 1:1 to 12:1. The non degradable polymer is preferably a copolymer of methyl methacrylate and methacrylic acid, preferably in molar proportions of from 1:1 to 15:1. The element may be prepared from an aqueous solid particle dispersion which has been prepared by milling the components together in a ball mill.Type: GrantFiled: September 25, 2002Date of Patent: July 13, 2004Assignee: Eastman Kodak CompanyInventors: Malcolm D. Purbrick, Marie C. Bunce, Phillip J. Coldrick, Danuta Gibson, Ian M. Newington, Dawn J. Jenkins
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Publication number: 20040126677Abstract: This invention relates to laserable assemblages for use in laser-induced thermal transfer imaging which result in improvements in resolution and toughness in the transferred image when two binders differing in glass transition temperature are incorporated into the transfer layer.Type: ApplicationFiled: October 16, 2003Publication date: July 1, 2004Inventors: Gerald Donald Andrews, Graciela Beatriz Blanchet-Fincher
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Publication number: 20040115556Abstract: A heat transfer sheet comprising: a substrate; a light-heat conversion layer; and an image forming layer, wherein the light-heat conversion layer comprises polyamide-imide as a binder and a colorant having a water content of 3% by weight or more as measured under a condition of 23° C. and 60% RH.Type: ApplicationFiled: December 1, 2003Publication date: June 17, 2004Applicant: FUJI PHOTO FILM CO., LTD.Inventor: Hideyuki Nakamura
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Patent number: 6749981Abstract: A laser thermal transfer recording method is disclosed. The method employs an ink sheet having a light-heat conversion layer an a laser thermal transfer image receiving sheet having an image receiving layer in which Vicat softening point of the resin composing the thermoplastic layer of the image receiving layer is less than 80° C., and one of the image receiving layer and the ink layer contains a matting agent having a particle diameter larger than the thickness of the layer containing matting agent, the projection height of the matting agent is less than 3.5 &mgr;m and the frequency of the projections is from 400/mm2 to 4,000/mm2, and the peeling angle of the ink sheet and the image receiving sheet is controlled at an angle less than 30°.Type: GrantFiled: March 22, 2002Date of Patent: June 15, 2004Assignee: Konica CorporationInventors: Atsushi Nakajima, Katsumi Maejima
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Publication number: 20040110083Abstract: A thermal transfer donor element is provided which comprises a support, a light-to-heat conversion layer, an interlayer, and a thermal transfer layer. When the above donor element is brought into contact with a receptor and imagewise irradiated, an image is obtained which is free from contamination by the light-to-heat conversion layer. The construction and process of this invention is useful in making colored images including applications such as color proofs and color filter elements.Type: ApplicationFiled: December 1, 2003Publication date: June 10, 2004Applicant: 3M Innovative Properties CompanyInventors: Jeffrey C. Chang, John S. Staral, William A. Tolbert, Martin B. Wolk, Claire A. Jalbert, Hsin-Hsin Chou
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Patent number: 6743556Abstract: A method and apparatus for forming a partition layer on a substrate by imaging a thermal or laser transfer medium onto the substrate using a imagewise controlled radiation source. A matrix of partition cells are created on the substrate that can, in a further step, be selectively filled with fluid or ink using an inkjet printing technique. The partition layer, the substrate, and fluids to be deposited are selected so that the fluids wet the substrate but not the partitions, preventing bending between adjacent cells.Type: GrantFiled: August 9, 2001Date of Patent: June 1, 2004Assignee: Creo SRLInventors: Eran Elizur, Andrew Lau
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Publication number: 20040095457Abstract: A black matrix can be formed by thermal transfer on a receptor substrate for use, for example, in a display application. This black matrix can be used, for example, as a color filter black matrix or a TFT (thin film transistor) black matrix to provide contrast and/or to separate adjacent electrically-conducting components.Type: ApplicationFiled: July 7, 2003Publication date: May 20, 2004Applicant: 3M Innovative Properties CompanyInventors: Richard J. Pokorny, Raghunath Padiyath, Kazuki Noda
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Patent number: 6730446Abstract: A guest-host polarizer is disclosed that includes a host matrix, one or more first guest dyes disposed in the host matrix and oriented to absorb a first portion of visible light having a first polarization state, and one or more second guest dyes disposed in the host matrix and oriented to absorb a second portion of visible light having a second polarization state orthogonal to the first polarization state. Such guest-host polarizers can be used in various optical applications and display constructions.Type: GrantFiled: January 22, 2003Date of Patent: May 4, 2004Assignee: 3M Innovative Properties CompanyInventors: Hassan Sahouani, Kim Marie Vogel, Martin B. Wolk
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Patent number: 6720126Abstract: It is intended to provide a laser thermal transfer recording method which comprises the steps of feeding an image receptor sheet and a plural number of thermal transfer sheets from a recording medium cassette, superposing the image receptor layer of the image receptor sheet upon the image formation layer of the thermal transfer sheets and holding them on a recording medium support member, and then irradiating the thermal transfer sheets with laser beams appropriate for image data to transfer the laser-irradiated regions on the image formation layer onto the image receptor layer of the image receptor sheet thereby recording an image, characterized in that the image receptor sheet and the thermal transfer sheets are laminated in the order of feeding into the recording medium support member and contained in the recording medium cassette and the coefficient(s) of static friction of the back layer surface of the image receptor sheet and/or the above-described thermal transfer sheets are 0.7 or below.Type: GrantFiled: February 5, 2003Date of Patent: April 13, 2004Assignee: Fuji Photo Film Co., Ltd.Inventors: Akihiro Shimomura, Yoshiharu Sasaki
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Publication number: 20040062930Abstract: Electroactive polymeric arylenes and intermediates useful for making such polymers are disclosed. The present invention also provides electroactive compositions comprising the electroactive polymeric arylenes, organic electronic devices which comprise these polymers and compositions, and methods of fabricating these devices.Type: ApplicationFiled: September 25, 2002Publication date: April 1, 2004Applicant: 3M Innovative Properties CompanyInventors: Ralph R. Roberts, James G. Bentsen, Yingbo Li
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Publication number: 20040063010Abstract: A process for adjusting the energy of an imaging laser for element and thermally imageable elements suitable for this purpose are described.Type: ApplicationFiled: October 24, 2003Publication date: April 1, 2004Inventors: Richard Albert Coveleskie, Alan Lee Shobert, Gregory Charles Weed, Harry Richard Zwicker
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Publication number: 20040058814Abstract: The invention provides a multi-color image-forming material for recording an image by using an image-receiving sheet having an image-receiving layer and at least 4 kinds of heat transfer sheets different from each other in color and comprising a support having provided thereon at least a light-to-heat conversion layer and an image-forming layer, superposing the image-forming layer of each of the thermal transfer sheet on the image-receiving layer of the image-receiving sheet, in which the image-forming layer is opposed to the image-receiving layer, and irradiating a laser light thereto to transfer the laser-irradiated area of the image-forming layer to the image-receiving layer of the image-receiving sheet, wherein the material contains a heat transfer sheet (X) having an image-forming layer containing one selected from among Pigment Red 48:1, Pigment Red 48:3, Pigment Green 7, Pigment Blue 15:6, Pigment Blue 60, Pigment Violet 23 and Pigment Orange 43, and a method for forming a multi-color image comprises uType: ApplicationFiled: January 15, 2003Publication date: March 25, 2004Inventors: Shinichi Yoshinari, Shinji Fujimoto
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Publication number: 20040048175Abstract: A process for adjusting the energy of an imaging laser for imaging of a thermally imageable element including the steps of: (a) providing an imaging unit having a non-imaging laser and an imaging laser, the non-imaging laser having a light detector which is in communication with the imaging laser, (b) contacting a receiver element with the thermally imageable element in the imaging unit, wherein the receiver element comprises a light attenuating layer having a front surface and a back surface; (c) actuating the non-imaging laser to expose the thermally imageable element and the receiver element to an amount of light energy sufficient for the light detector to detect the amount of light reflected from the thermally imageable element and light attenuating layer of the receiver element; and (d) actuating the imaging laser to focus the imaging laser in order to expose the thermally imageable element to an amount of light energy sufficient for imaging the thermally imageable elementType: ApplicationFiled: June 13, 2003Publication date: March 11, 2004Inventors: John E. Bobeck, Richard Albert Coveleskie, Jeffrey Jude Patricia, Alan Lee Shobert, Harvey Walter Taylor, Jr, Harry Richard Zwicker
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Patent number: 6703180Abstract: A method of forming an organic light-emitting device with improved stability including forming an anode over a substrate, providing a cathode spaced from the anode, and providing a donor element including light-emitting material and positioning such donor element in a material-transferring relationship with the substrate. The method further includes illuminating the donor element with radiation to cause the transfer of light-emitting material to deposit the light-emitting material to form an emissive layer over the anode, and forming an organic layer including an organic compound doped with a low work function metal or metal compound capable of acting as a donor dopant between the emissive layer and the cathode to lower the electron-injecting barrier from the organic layer into the emissive layer thereby improving the stability of the organic light-emitting device.Type: GrantFiled: April 16, 2003Date of Patent: March 9, 2004Assignee: Eastman Kodak CompanyInventors: Michael L. Boroson, Liang-Sheng Liao
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Patent number: 6703179Abstract: Method and apparatus are disclosed for transferring organic material from a donor onto a substrate to form a layer of organic material on one or more OLED devices, by aligning first and second fixtures in a reduced pressure environment and positioning the substrate and donor in a chamber defined by the aligned first and second fixtures; increasing the pressure applied to the non-transfer surface of the donor so as to ensure the position of the donor relative to the substrate; moving a member provided on the first fixture from a closed to an open position which permits the transmission of radiation onto the non-transfer surface of the donor so that heat will be produced and organic material transferred from the donor to the substrate; and illuminating with radiation the donor through the open radiation-receiving position to cause the transfer of organic material to the substrate.Type: GrantFiled: March 13, 2002Date of Patent: March 9, 2004Assignee: Eastman Kodak CompanyInventor: Yuan-Sheng Tyan
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Patent number: 6703184Abstract: A low moisture donor element for use in transferring moisture sensitive organic material to an OLED device including a low moisture transparent support; an optional absorber antireflecting layer which increases the absorption efficiency of the element; a metallic heat absorbing layer provided over the low moisture transparent support; and an organic transfer layer consisting of one or more heat transferable organic layers provided over the support.Type: GrantFiled: May 22, 2003Date of Patent: March 9, 2004Assignee: Eastman Kodak CompanyInventors: Donald R. Preuss, Jehuda Greener
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Patent number: 6699629Abstract: The present invention relates to a method for placing process survivable indicia on a support for an imaging element comprising providing a support wherein the support comprises a closed cell foam core and adhered thereto at least one flange layer, wherein the closed cell foam core layer comprises a polymer that has been expanded through the use of a blowing agent, and placing process survivable ink on at least one flange layer, wherein the process survivable ink forms process survivable indicia. The invention also relates to a method for placing process survivable indicia on a support comprising a closed cell foam core and adhered thereto an upper flange layer and a lower flange layer. The invention also includes a method for placing process survivable indicia on a support by placing process survivable indicia on said closed cell foam core.Type: GrantFiled: December 23, 2002Date of Patent: March 2, 2004Assignee: Eastman Kodak CompanyInventors: Margaret J. Helber, Peter T. Aylward, Mridula Nair
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Patent number: 6699634Abstract: A multicolor image forming material comprising: an image-receiving sheet comprising an image-receiving layer; and at least four thermal transfer sheets differing in color each comprising a support, a light-to-heat conversion layer and an image-forming layer, wherein the image forming material is used for recording a multicolor image by superposing the image-forming layer of each thermal transfer sheet and the image-receiving layer to face each other, irradiating laser light and transferring a region irradiated with the laser light of the image-forming layer onto the image-receiving layer, and at least one layer selected from the image-receiving layer and the image-forming layers comprises, as a fluorine-containing surfactant, a copolymer (I) comprising following repeating units (A), (B) and (C) as defined herein.Type: GrantFiled: June 6, 2003Date of Patent: March 2, 2004Assignee: Fuji Photo Film Co., Ltd.Inventor: Mitsuru Yamamoto
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Patent number: 6695030Abstract: Apparatus for transferring organic material from a donor web onto a substrate to form a layer of organic material on one or more OLED devices including a web of donor material; first and second fixtures and a structure for applying fluid to a chamber to containing the fixtures to apply pressure to the non-transfer surface of the donor web so as to ensure the position of the donor web relative to the substrate; the first fixture including a transparent portion located in relationship to the non-transfer surface of the donor web to permit transmission of radiation through such transparent portion to the non-transfer surface of the donor web so that heat will be produced and the organic material will transfer from the donor web to the substrate.Type: GrantFiled: August 20, 2002Date of Patent: February 24, 2004Assignee: Eastman Kodak CompanyInventors: Bradley A. Phillips, David B. Kay