Making Printing Plate Patents (Class 430/204)
  • Patent number: 5508142
    Abstract: The present invention provides an imaging element comprising in the order given (i) a hydrophilic base, (ii) an image receiving layer containing physical development nuclei and (iii) a photosensitive layer containing a silver halide emulsion being in water permeable relationship with said image receiving layer, characterized in that said photosensitive layer or another optional layer being in water permeable relationship therewith contains at least one gelatin species whereof a 10% by weight aqueous solution at 36.degree. C. and pH 6 has a viscosity lower than 20 mPa.s at a shearing rate of 1000 s.sup.-1.
    Type: Grant
    Filed: June 29, 1994
    Date of Patent: April 16, 1996
    Assignee: AGFA-GEVAERT, N.V.
    Inventors: Paul Coppens, Eric Hoes, Ludovicus Vervloet
  • Patent number: 5501939
    Abstract: The present invention provides a photographic material with a pH at 25.degree. C. of at most 7, containing on a support at least one layer, comprising a prefogged direct-positive silver halide emulsion spectrally sensitized with one or more electron-accepting sensitizing dyes in a total amount of at least 0.15 mmole/mole silver halide, the silver halide crystals of said prefogged direct-positive silver halide emulsion containing silver chloride for at least 60 mole %, silver bromide in a range from 0.5 mole % to 39.98 mole % and silver iodide in a range from 0.02 mole % to 2 mole %, characterized in that said silver halide cristals contain silver iodide for at least 0.20 mmole/mole AgX in the outer 10% by weight of said cristals and said layer contains a gelatin species containing Ca.sup.2+ in an amount ranging from 0.2% to 1% by weight.
    Type: Grant
    Filed: June 13, 1995
    Date of Patent: March 26, 1996
    Assignee: AGFA-Gevaert, N.V.
    Inventors: Ludo Van Rompuy, Paul Coppens
  • Patent number: 5501150
    Abstract: Process for the manufacture of a lithographic printing plate comprising the steps of:(1) information-wise projecting droplets of liquid, onto a receiving material having a hydrophilic surface to form a silver image by bringing into working relationship on said hydrophilic surface a reducible silver compound (A), a reducing agent (B) for said silver compound and physical development nuclei (C) that catalyze the reduction of said silver compound to silver metal, and(2) hydrophobizing the silver image that has been obtained through said step (1) e.g. by overall contacting the printing surface with a hydrophobizing substance for said silver image or hydrophobizing said silver image by imagewise depositing said hydrophobizing substance thereon.
    Type: Grant
    Filed: May 18, 1995
    Date of Patent: March 26, 1996
    Assignee: Agfa-Gevaert, N.V.
    Inventors: Luc Leenders, Leo Oelbrandt, Jan Van den Bogaert, Guido Desie
  • Patent number: 5496679
    Abstract: The present invention provides an imaging element comprising on a flexible hydrophobic support (i) a hardened hydrophilic layer, containing a hydrophilic synthetic homocopolymer or copolymer and being hardened with a hydrolyzed tetraalkyl orthosilicate crosslinking agent, (ii) a receiving layer containing physical development nuclei contiguous to said hydrophilic layer, (iii) an intermediate layer comprising a non-proteinic hydrophilic film-forming polymer or hydrophobic polymer beads having an average diameter not lower than 0.2 .mu.m and having been prepared by polymerization of a ethylenically unsaturated monomer and (iv) a photosensitive layer containing a silver halide emulsion being in water permeable relationship with said receiving layer. The invention also relates to a method for making lithographic plates with said imaging element.
    Type: Grant
    Filed: March 22, 1995
    Date of Patent: March 5, 1996
    Assignee: AGFA-Gevaert, N.V.
    Inventors: Guido Hauquier, Willem Cortens, Paul Coppens, Ludovicus Vervloet
  • Patent number: 5494774
    Abstract: A thermal transfer system for transferring material in an imagewise manner by means of thermal transfer printing from a donor element to an image receiving element is used to prepare printing plates. In one construction, a donor element, which is prepared by coating a photoinitiator (and optionally a sensitizer) in a binder on a backing material, is used with an image receiving element, which is prepared by coating a photopolymer (and optionally a sensitizer) on a substrate having a microporous hydrophilic crosslinked silicated surface. In an alternative construction, a donor element, which is prepared by coating a sensitizer in a binder on a backing material, is used with an image receiving element, which is prepared by coating a photopolymer and photoinitiator on a substrate having a microporous hydrophilic crosslinked silicated surface.
    Type: Grant
    Filed: April 10, 1995
    Date of Patent: February 27, 1996
    Assignee: Minnesota Mining and Manufacturing Company
    Inventors: M. Zaki Ali, Mahfuza B. Ali, David R. Boston, Jeffrey C. Chang
  • Patent number: 5473413
    Abstract: A simplified process for making plates used in printing, including forming a chemically positive copy on a transparent or translucent sheet-like structure with the lines thereon being constituted of artificial powder without going through the steps of photographing and contact copying. The copy so formed may be directly used in retouching and then plate processing. This process does not require the use of photosensitive films and chemical photograhing so that the speed of making plates is increased and damage to the environment decreased.
    Type: Grant
    Filed: February 16, 1994
    Date of Patent: December 5, 1995
    Inventor: Chin-Shiung Fang
  • Patent number: 5472822
    Abstract: A lithographic printing plate is prepared from a silver halide photosensitive material in accordance with a silver complex diffusion transfer process. The photosensitive material is exposed and developed with a diffusion transfer processing solution containing a mesoionic compound as a silver halide complexing agent. The printing plate has good ink receptivity and minimized plate wear. The processing solution is free from the problems of corrosion and waste solution disposal.
    Type: Grant
    Filed: October 1, 1992
    Date of Patent: December 5, 1995
    Assignee: Fuji Photo Film Co., Ltd.
    Inventor: Katsumi Hayashi
  • Patent number: 5468588
    Abstract: A method of manufacturing a photosensitive element which can be exposed and enveloped by diffusion transfer processes to form a lithographic printing plate, said method comprising the steps of:(a) providing a support layer,(b) coating a negative acting silver halide emulsion layer onto said support layer, and(c) coating a physical development nucleation layer comprising particles onto said silver halide emulsion layer,wherein the coating of said physical development nucleation layer is performed with a coating composition which is at a temperature above 0.degree. C. and below 30.degree. C.
    Type: Grant
    Filed: October 18, 1994
    Date of Patent: November 21, 1995
    Assignee: Minnesota Mining and Manufacturing Company
    Inventors: Michael T. Macioch, Douglas M. Gates, Timothy M. Leary
  • Patent number: 5462833
    Abstract: The present invention provides a lithographic base comprising on a hydrophobic support a subbing layer and a hydrophilic layer containing a hydrophilic (co)polymer or (co)polymer mixture and being hardened with a hydrolyzed tetraalkyl orthosilicate crosslinking agent characterized in that said subbing layer contains a hydrophilic binder and silica, the surface area of the silica being at least 300 m.sup.2 per gram.
    Type: Grant
    Filed: March 9, 1994
    Date of Patent: October 31, 1995
    Assignee: Agfa-Gevaert, N.V.
    Inventors: Guido Hauquier, Willem Cortens, Paul Coppens, Joan Vermeersch, Erik Mostaert, Eric Verschueren
  • Patent number: 5460918
    Abstract: A thermal transfer system for transferring material in an imagewise manner by means of thermal transfer printing from a donor element to an image receiving element is used to prepare printing plates. In one construction, a donor element, which is prepared by coating a photoinitiator (and optionally a sensitizer) in a binder on a backing material, is used with an image receiving element, which is prepared by coating a photopolymer (and optionally a sensitizer) on a substrate having a microporous hydrophilic crosslinked silicated surface. In an alternative construction, a donor element, which is prepared by coating a sensitizer in a binder on a backing material, is used with an image receiving element, which is prepared by coating a photopolymer and photoinitiator on a substrate having a microporous hydrophilic crosslinked silicated surface.
    Type: Grant
    Filed: October 11, 1994
    Date of Patent: October 24, 1995
    Assignee: Minnesota Mining and Manufacturing Company
    Inventors: M. Zaki Ali, Mahfuza Ali, David R. Boston, Jeffrey C. Chang
  • Patent number: 5456999
    Abstract: The present invention provides a photographic material comprising a silver halide emulsion layer sensitized to light above 700 nm by means of an infrared sensitizing dye having a maximum absorption between 700 nm and 850 nm characterized in that said silver halide emulsion further comprises a red sensitizing dye of the cationic type having a maximum absorption between 600 nm and 700 nm. The thus obtained photographic material shows an increased sensitivity in the infrared region. The material can be used in as silver salt diffusion transfer process to prepare a lithographic printing plate.
    Type: Grant
    Filed: November 17, 1992
    Date of Patent: October 10, 1995
    Assignee: AGFA-Gevaert, N.V.
    Inventors: Jos Vaes, Luc Wabbes
  • Patent number: 5449585
    Abstract: The present invention provides a method for making an offset printing plate according to the silver salt diffusion transfer process having improved printing properties comprising the step of developing an imaging element comprising in the order given (i) a hydrophilic base, (ii) an image receiving layer containing physical development nuclei and (iii) a photosensitive layer containing a silver halide emulsion in the presence of a 1-phenyl-5-mercapto-tetrazole, being substituted by one or two substituents from the group consisting of:(i) a --COOM group with M representing hydrogen, a metal cation, or an ammonium group,(ii) a --SO.sub.3 M.sup.1 group, M.sup.1 representing hydrogen, a metal cation, or an ammonium group,(iii) an acylamido group,(iv) and a substituent containing at least one of the aforementioned substituents (i)-(iv).
    Type: Grant
    Filed: June 29, 1994
    Date of Patent: September 12, 1995
    Assignee: Agfa-Gevaert
    Inventors: Paul Coppens, Ludovicus Vervloet, Eric Hoes
  • Patent number: 5445914
    Abstract: The present invention provides a method for making an offset printing plate according to the silver salt diffusion transfer process using rinsing water, characterized in that alkali is added to said rinsing water before washing at most 20 m.sup.2 of said exposed and developed imaging element and/or before being in use for more than 24 hours in such an amount that a pH in said washing water between 10.5 and 13 is obtained.
    Type: Grant
    Filed: February 1, 1994
    Date of Patent: August 29, 1995
    Assignee: Agfa-Gevaert, N.V.
    Inventors: Paul Coppens, Augustin Meisters, Ludovicus Vervloet
  • Patent number: 5445912
    Abstract: The present invention provides a lithographic base comprising on a hydrophobic support a subbing layer contiguous to a hydrophilic layer containing a hydrophilic (co)polymer or (co)polymer mixture and being hardened with a hydrolyzed tetraalkyl orthosilicate crosslinking agent characterized in that said subbing layer contains a hydrophilic binder and silica and is applied at a solids content of more than 200 mg per m.sup.2 but less than 750 mg per m.sup.2.
    Type: Grant
    Filed: March 9, 1994
    Date of Patent: August 29, 1995
    Assignee: Agfa-Gevaert, N.V.
    Inventors: Guido Hauquier, Willem Cortens, Paul Coppens, Joan Vermeersch, Erik Mostaert, Eric Verschueren
  • Patent number: 5445915
    Abstract: The present invention provides an imaging element comprising on a support in the order given a base layer containing a matting agent having a number average diameter between 0.4 and 1 times the thickness of said base layer, a spectrally sensitized silver halide emulsion layer and a receiving layer containing physical development nuclei having an average diameter less than 6 nm and wherein the number of nuclei having a diameter larger than 4.5 nm is less than 15% of the total number of nuclei contained in said receiving layer and wherein substantially no matting agent is present in said receiving layer, silver halide emulsion layer or any other layer optionally being present between said receiving layer and silver halide emulsion layer.
    Type: Grant
    Filed: January 11, 1995
    Date of Patent: August 29, 1995
    Assignee: Agfa-Gevaert, N.V.
    Inventor: Jos Vaes
  • Patent number: 5437957
    Abstract: Disclosed is a lithographic printing plate material comprising a support and, provided thereon, at least a silver halide emulsion layer and a physical development nuclei layer wherein the physical development nuclei layer and/or a layer contiguous thereto contains at least one of water-soluble polymers represented by the following formula (I) or at least one of water-soluble polymers represented by the following formula (II): ##STR1## wherein R.sub.1 represents H or an alkyl group, R.sub.2 represents H or an alkali metal atom, n is 1-100 mol %, m is 0-50 mol % and l is 0-5 mol %, ##STR2## wherein R.sub.3 and R.sub.4 each represent a hydrogen atom or a lower alkyl group and A represents a residue of an ethylenically unsaturated monomer, l is 99.9-40 mol %, m is 0.1-10 mol % and n is 0-50 mol %. The polymer of the formula (I) may be used in combination with a water-soluble polysaccharide.
    Type: Grant
    Filed: February 4, 1994
    Date of Patent: August 1, 1995
    Assignee: Mitsubishi Paper Mills Limited
    Inventors: Motozo Yamano, Kozo Haino, Akio Yoshida, Hidetoshi Miura
  • Patent number: 5436119
    Abstract: The present invention provides a conversion liquid for converting silver areas of a silver based printing plate into ink repellant areas while rendering background areas of said silver based printing plate ink accepting, said conversion liquid comprising a hydrophobizing compound capable of adsorbing to said hydrophilic background areas and a hydrophilizing compound capable of adsorbing to said silver areas and/or a bleaching compound capable of oxidizing the silver in said silver based printing plate.
    Type: Grant
    Filed: May 5, 1994
    Date of Patent: July 25, 1995
    Assignee: Agfa-Gevaert, N.V.
    Inventors: Franciscus Heugebaert, Gilbert Voortmans, Jean-Marie Dewanckele, Johan Loccufier
  • Patent number: 5436110
    Abstract: The present invention provides an imaging element comprising in the order given (i) a hydrophilic grained and anodized aluminum support with an aluminum oxide barrier layer of at least 10 nm thickness, (ii) an image receiving layer containing physical development nuclei in an amount of at least 0.7 mg/m.sup.2 and (iii) a photosensitive layer containing a silver halide emulsion being in water permeable relationship with said image receiving layer. The invention also relates to a method for making lithographic plates with said imaging element.
    Type: Grant
    Filed: July 5, 1994
    Date of Patent: July 25, 1995
    Assignee: AGFA-Gevaert, N.V.
    Inventors: Paul Coppens, Guido Hauquier, Marcus Jonckheere, Willem Cortens, Augustin Meisters
  • Patent number: 5432042
    Abstract: The present invention provides a method for making a lithographic printing plate according to the silver salt diffusion transfer process using a photographic material comprising on a support a silver halide emulsion layer and a layer containing physical development nuclei comprising the steps of:image-wise exposing said photographic material anddeveloping a thus obtained image-wise exposed photographic material by guiding said image-wise exposed photographic material through an alkaline processing liquid in 15 s or less; characterized in that said alkaline processing liquid comprises a hydrophobizing compound having a mercapto group that has a pK.sub.a of 4.5 or less.
    Type: Grant
    Filed: May 25, 1994
    Date of Patent: July 11, 1995
    Assignee: Agfa-Gevaert, N.V.
    Inventors: Lode Deprez, Jos Vaes, Paul Gestels
  • Patent number: 5427889
    Abstract: The present invention provides a lithographic printing plate material which comprises a grained and anodized aluminum support and a silver halide emulsion layer between which physical development nuclei are provided wherein said aluminum support have 500 or more pits having a diameter of 0.03-0.30 .mu.m and an average diameter of 0.05-0.20 .mu.m per 100 .mu.m.sup.2.
    Type: Grant
    Filed: August 12, 1994
    Date of Patent: June 27, 1995
    Assignee: Mitsubishi Paper Mills Ltd.
    Inventors: Masahiko Saikawa, Akira Kaneko, Keisuke Iguchi, Akio Yoshida, Yutaka Araki, Takenobu Yoshiki
  • Patent number: 5413897
    Abstract: The present invention provides a photographic material comprising on a support (i) photosensitive silver halide particles, (ii) substantially light insensitive silver salt particles having a speed at least a factor 10 less than said photosensitive silver halide particles under the same conditions of exposure and development of said photosensitive silver halide particles and (iii) a releasing compound capable of image-wise releasing under the conditions for image-wise development of said photosensitive silver halide to silver a chemical sensitizer, said chemical sensitizer rendering said substantially light insensitive silver salt particles developable. The present invention also provides a method for making an image therewith and a method for making a lithographic printing plate.
    Type: Grant
    Filed: May 4, 1994
    Date of Patent: May 9, 1995
    Assignee: Agfa-Gevaert, N.V.
    Inventors: Ludo L. Van Rompuy, Jean-Marie O. Dewanckele, Jos A. Vaes, Marcel J. Monbaliu
  • Patent number: 5405729
    Abstract: The present invention provides a method for making an offset printing plate according to the silver salt diffusion transfer process using rinsing water, characterized in that said rinsing water before washing at most 20 m.sup.2 of said exposed and developed imaging element and/or before being in use for more than 24 hours is brought in contact with (i) a metal of the group IB or IIB or VIII of the periodic table or (ii) with an alloy containing at least one of said metals or (iii) with a salt containing an ion of at least one of said metals.
    Type: Grant
    Filed: February 1, 1994
    Date of Patent: April 11, 1995
    Assignee: AGFA-Gevaert, N.V.
    Inventors: Paul Coppens, Ludovicus Vervloet, Augustin Meisters, Jean-Pierre Tahon
  • Patent number: 5405730
    Abstract: The present invention provides an imaging element comprising in the order given (i) a hydrophilic grained and anodized aluminum support, (ii) an image receiving layer containing physical development nuclei and (iii) a photosensitive layer containing a silver halide emulsion being in water permeable relationship with said image receiving layer characterized in that the sum of the surface areas of subsidences amounts to at least 50% of the total surface area area of the grained and anodized side of said support.
    Type: Grant
    Filed: July 5, 1994
    Date of Patent: April 11, 1995
    Assignee: AGFA-Gevaert, N.V.
    Inventors: Paul Coppens, Marcus Jonckheere
  • Patent number: 5399457
    Abstract: A method of making a lithographic printing plate that comprises the steps of:(a) imagewise exposing a unitary, light sensitive material which consists of a support, at least one negative working light sensitive silver halide layer and a surface physical development nucleating layer, said construction containing a developing agent and electron transfer agent in one or more layers;(b) processing said printing plate in a diffusion transfer alkaline activator solution containing at least one aminocarboxylic acid complexing agent.
    Type: Grant
    Filed: October 15, 1993
    Date of Patent: March 21, 1995
    Assignee: Minnesota Mining and Manufacturing Company
    Inventors: Paul Davies, Elsie A. Fohrenkamm
  • Patent number: 5395730
    Abstract: A method is disclosed for the formation of an image comprising the steps of(1) image-wise exposing, in the presence of a photopolymerizable compound, a photosensitive element comprising a support and at least one photosensitive layer containing a silver halide sensitive to actinic radiation, an organic silver salt and a reducing agent,(2) heating said photosensitive layer while in contact with a receiving element and allowing non-photopolymerized compound in the non-exposed areas to transfer and penetrate in said receiving element, and,(3) separating said receiving element from said photosensitive element.The obtained image can be a useful visible image produced on at least one of the separated elements, or it can be a hydrophobic polymer image on a hydrophilic background formed in the finally separated-receiving element which is usable as a printing plate. In the former embodiment the receiving element comprises a support and a layer containing a pigment, e.g. carbon black.
    Type: Grant
    Filed: August 31, 1993
    Date of Patent: March 7, 1995
    Assignee: Agfa-Gevaert, N.V.
    Inventors: Wolfgang Podszun, Herman J. Uytterhoeven, Roland F. Beels, Luc H. Leenders
  • Patent number: 5391457
    Abstract: A lithographic printing plate is prepared from a photosensitive material comprising a silver halide emulsion layer and a physical development nucleus layer on a support in accordance with a silver complex diffusion transfer process. The photosensitive material is diffusion transfer processed in the presence of both a triazole, oxadiazole or similar compound and an organic thioether compound. The printing plate has good ink receptivity and minimized plate wear. The processing solution is free from the problems of corrosion and waste solution disposal.
    Type: Grant
    Filed: November 3, 1992
    Date of Patent: February 21, 1995
    Assignee: Fuji Photo Film Co., Ltd
    Inventor: Katsumi Hayashi
  • Patent number: 5387483
    Abstract: Lithographic printing material is processed with a developer at pH 10.0 to 11.8 containing 30 to 80 gram/liter of hydroquinone in accordance with a diffusion transfer process. The developer is capable and stable. The resulting transfer silver image has improved printing endurance and ink receptivity.
    Type: Grant
    Filed: December 3, 1993
    Date of Patent: February 7, 1995
    Assignee: Fuji Photo Film Co., Ltd.
    Inventor: Yoshihiro Takagi
  • Patent number: 5368980
    Abstract: A method of making a lithographic printing plate that comprises of:(a) imagewise exposing a light sensitive material comprising of a support, at least a negative working light sensitive silver halide layer and a surface physical development nucleating layer, said material containing a silver halide black-and-white photographic developing agent and an electron transfer agent in one or more layers;(b) processing said printing plate in a diffusion-transfer alkaline activator solution to provide a transferred oleophilic silver complex and a non-transferred black image in the nucleating layer;(c) said diffusion-transfer alkaline activator comprising at least one compound of the following structure: ##STR1## where R is a hydrogen, hydroxy or amine group,R.sub.1, may be a methine group,n is zero or one,R.sub.2 is hydrogen, a lower alkyl, alkoxy, carboxyl, or forms a pyrazolidone group with the nitrogen atom,X may be one or more amine, hydroxy, lower alkyl, alkoxy or carboxyl substituent groups.
    Type: Grant
    Filed: October 25, 1993
    Date of Patent: November 29, 1994
    Assignee: Minnesota Mining and Manufacturing Company
    Inventor: Paul Davies
  • Patent number: 5366837
    Abstract: An image receiving sheet of the present invention for receiving a desired image thereon includes a support layer and an absorbing layer containing heat-meltable or thermoplastic particles. A desired image can be formed in the absorbing layer of the image receiving sheet. Through heating the image receiving sheet formed with the desired image, the heat-meltable or thermoplastic particles are thermally melted or softened to attain a glossy and transparent surface formed with the desired image. As a result, an image bearing product coated with a glossy and transparent surface formed with the desired image is obtained. Through thermally pressing the image receiving sheet formed with the visible image toward an article of arbitrary type, on the other hand, the heat-meltable or thermoplastic particles are thermally melted or softened to be adhered to a surface of the article, so that the desired image is transferred onto the surface of the article.
    Type: Grant
    Filed: July 10, 1992
    Date of Patent: November 22, 1994
    Assignee: Brother Kogyo Kabushiki Kaisha
    Inventor: Jun Sakai
  • Patent number: 5348836
    Abstract: The present invention provides a photographic material comprising on a support photosensitive silver halide particles, and substantially light insensitive silver salt particles having a speed at least a factor 10 less under the same conditions of exposure and development of said photosensitive silver halide particles than said photosensitive silver halide particles and a releasing compound of formula (I) or (II) as specified in the claims capable of image-wise releasing sulphide or a sulphide under conditions for image-wise development of said photosensitive silver halide particles to silver. The present invention further provides a method for obtaining an image and a lithographic printing plate with said photographic material.
    Type: Grant
    Filed: April 22, 1993
    Date of Patent: September 20, 1994
    Assignee: AGFA-Gevaert, N.V.
    Inventors: Ludo Van Rompuy, Jean-Marie Dewanckele
  • Patent number: 5342784
    Abstract: Provided is an electrophotographic photoreceptor which comprises an electrically conductive support and a photoconductive layer comprising at least an organic photoconductive compound and an alkali and/or alcohol soluble binder resin provided on said support and which is used for making a lithographic printing plate therefrom by electrophotographically forming a toner image and decoating the photoconductive layer of non-image portion other than the toner image portion by contacting with an alkaline decoating solution, wherein an arithmetical mean deviation of profile (Ra.sub.1) of the surface of said electrically conductive support having said photoconductive layer thereon is 0.3-1.0 .mu.m and a ratio of Ra.sub.2 /Ra.sub.1 of an arithmetical mean deviation of profile (Ra.sub.2) of the surface of said photoconductive layer and the (Ra.sub.1) is 0.5-1.0. The image formed on the printing plate is free from indentation at the edge of the image. Resolution and sharpness of the image are improved.
    Type: Grant
    Filed: April 7, 1992
    Date of Patent: August 30, 1994
    Assignee: Mitsubishi Paper Mills Limited
    Inventors: Jun Yamada, Seiji Shinohara
  • Patent number: 5340691
    Abstract: The present invention provides a method for making a lithographic printing plate accordig to the silver salt diffusion transfer process comprising the steps of:image-wise exposing an imaging element comprising on a support a photosensitive layer comprising a silver halide emulsion and an image receiving layer containing physical development nuclei,developing said imaging element in the presence of developing agent(s) and silver halide solvent(s) using an alkaline processing liquid andneutralizing the thus obtained developed imaging element using a neutralization liquid characterized in that said neutralization liquid contains a meso-ionic compound.
    Type: Grant
    Filed: September 29, 1993
    Date of Patent: August 23, 1994
    Assignee: AGFA-Gevaert, N.V.
    Inventors: Jos Vaes, Jean-Marie Dewanckele, Marcel Monbaliu
  • Patent number: 5340690
    Abstract: According to the present invention there is provided a method for making a lithographic printing plate according to the DTR-process comprising the steps of:information-wise exposing an imaging element comprising on a support a silver halide emulsion layer and an image-receiving layer containing physical development nuclei anddeveloping said information-wise exposed imaging element with an alkaline processing liquid in the presence of developing agent(s) and silver halide solvent(s) characterized in that said silver halide solvents comprise a combination of (an) alkanolamine(s) and a thiosulfate wherein said thiosulfate is used in a total amount between 0.01% and 1% by weight in said alkaline processing liquid.
    Type: Grant
    Filed: March 15, 1993
    Date of Patent: August 23, 1994
    Assignee: Agfa-Gavaert, N.V.
    Inventors: Rene M. De Keyzer, Jean-Marie O. Dewanckele, Ludo L. Van Rompuy, Jos A. Vaes
  • Patent number: 5324622
    Abstract: The present invention provides a photographic material comprising on a support (i) photosensitive silver halide particles, (ii) substantially light insensitive silver salt particles having a speed at least a factor 10 less than said photosensitive silver halide particles under the same conditions of exposure and development of said photosensitive silver halide particles and (iii) a releasing compound capable of image-wise releasing under the conditions for image-wise development of said photosensitive silver halide to silver a chemical sensitizer, said chemical sensitizer rendering said substantially light insensitive silver salt particles developable. The present invention also provides a method for making an image therewith and a method for making a lithographic printing plate.
    Type: Grant
    Filed: July 29, 1992
    Date of Patent: June 28, 1994
    Assignee: AGFA-Gevaert, N.V.
    Inventors: Ludo L. Van Rompuy, Jean-Marie O. Dewanckele, Jos A. Vaes, Marcel J. Monbaliu
  • Patent number: 5322763
    Abstract: A process for making a metal ledge on one side of a metal screen involves exposing through the stencil screen a photoresist layer, removing unexposed photoresist areas, plating the metal stencil screen where the unexposed photoresist has been removed and removing the exposed photoresist.
    Type: Grant
    Filed: May 6, 1992
    Date of Patent: June 21, 1994
    Assignee: E. I. Du Pont de Nemours and Company
    Inventors: Allan Cairncross, Chester A. Thayer, II
  • Patent number: 5283156
    Abstract: The present invention provides a method for making a lithographic printing plate according to the silver salt diffusion transfer process comprising the steps of image-wise exposing an imaging element comprising on a support a photosensitive layer comprising a silver halide emulsion and an image receiving layer containing physical development nuclei and developing said imaging element in the presence of developing agent(s) and silver halide solvent(s) using an alkaline processing liquid characterized in that said development is carried out in the presence of a regulator according to one of the formulas as specified in the claims. The present invention further provides an imaging element and alkaline processing liquid for use in said method.
    Type: Grant
    Filed: December 4, 1992
    Date of Patent: February 1, 1994
    Assignee: Agfa-Gevaert, N.V.
    Inventors: Marcel Monbaliu, Rene De Keyzer, Jean-Marie Dewanckele, Jos Vaes, Ludo Van Rompuy
  • Patent number: 5283157
    Abstract: A method for making a lithographic printing plate which comprises the steps of A) imagewise exposing a light sensitive material which comprises a support, a negative working silver halide emulsion layer and a surface physical development nucleating layer on said support, and B) processing the exposed material in a silver complex diffusion transfer developer containing a water soluble iodide to produce a non-black oleophilic silver image on the surface of said printing plate.
    Type: Grant
    Filed: March 22, 1993
    Date of Patent: February 1, 1994
    Assignee: Minnesota Mining and Manufacturing Company
    Inventor: Paul Davies
  • Patent number: 5281509
    Abstract: Disclosed is a light-sensitive element for lithographic printing plates excellent in stain resistance and water-carrying capacity which comprises a support and, coated thereon in succession, at least one undercoat layer, a silver halide emulsion layer and a physical development nuclei layer wherein at least one of the layers on the silver halide emulsion layer-provided side of the support contains 0.1-2.0 g/m.sup.2 of a matting agent of 5.mu. in average particle size and the light-sensitive element has an arithmetical mean deviation of profile Ra of 1.2 or less.
    Type: Grant
    Filed: September 9, 1992
    Date of Patent: January 25, 1994
    Assignee: Mitsubishi Paper Mills Limited
    Inventors: Tetsunobu Murakata, Hideaki Baba, Akio Yoshida, Kazuhisa Nakao, Motozo Yamano, Yasuo Tsubai
  • Patent number: 5278023
    Abstract: Laser-addressable thermal transfer materials for producing color proofs, printing plates, films, printed circuit boards, and other media are disclosed. The materials contain a substrate coated thereon with a propellant layer wherein the propellant layer contains a material capable of producing nitrogen (N.sub.2) gas at a temperature of preferably less than about 300.degree. C.; a radiation absorber; and a thermal mass transfer material. The thermal mass transfer material may be incorporated into the propellant layer or in an additional layer coated onto the propellant layer. The radiation absorber may be employed in one of the above-disclosed layers or in a separate layer in order to achieve localized heating with an electromagnetic energy source, such as a laser. Upon laser induced heating, the transfer material is propelled to the receptor by the rapid expansion of gas.
    Type: Grant
    Filed: November 16, 1992
    Date of Patent: January 11, 1994
    Assignee: Minnesota Mining and Manufacturing Company
    Inventors: Richard E. Bills, William V. Dower, Thomas A. Isberg, Stanley C. Busman, Jeffrey C. Chang, Minyu Li, Hsin-hsin Chou
  • Patent number: 5273858
    Abstract: Method for making lithographic aluminum offset printing plates according to the DTR-process by photo-exposing a photosensitive monosheet layer assemblage comprising a hydrophilic aluminum foil, an intermediate layer comprising hydrophobic polymer beads prepared by polymerization of ethylenically unsaturated monomer(s) and having an average diameter not lower than 0.2 .mu.m, and a silver halide emulsion layer, applying an aqueous alkaline solution to the photo-exposed silver halide emulsion layer in the presence of a developing agent and a silver halide solvent to form a silver image and to allow unreduced silver halide or complexes formed thereof to diffuse imagewise from the developed silver halide emulsion layer to said aluminum foil to produce thereon a silver image, and separating said emulsion layer and said intermediate layer from the imaged aluminum foil. The invention also relates to the photosensitive monosheet layer assemblage used for making such printing plates.
    Type: Grant
    Filed: October 28, 1991
    Date of Patent: December 28, 1993
    Assignee: Agfa-Gevaert, N.V.
    Inventors: Paul J. Coppens, Joan T. Vermeersch, Luc H. Leenders, Ludovicus H. Vervloet, Eric M. Hoes, Eddie R. Daems
  • Patent number: 5272041
    Abstract: The present invention provides a method for obtaining a negative type lithographic printing plate comprising the steps of (i) image-wise exposing a diffusion transfer reversal imaging element comprising a direct positive silver halide emulsion that mainly forms an internal latent image and a layer containing physical development nuclei, (ii) fogging said image-wise exposed imaging element, (iii) developing said imaging element using a surface developer, (iv) transfering the undeveloped silver salts in the non-exposed areas to said layer containing physical development nuclei and (v) image-wise depositing said silver salts on said physical development nuclei in the presence of physical development restraining compound(s).
    Type: Grant
    Filed: October 10, 1991
    Date of Patent: December 21, 1993
    Assignee: Agfa-Gevaert, N.V.
    Inventor: Ludo L. Van Rompuy
  • Patent number: 5268253
    Abstract: The present invention provides a method for making a lithographic printing plate according to the DTR-process comprising the steps of:information-wise exposing an imaging element comprising on a support in the order given a photosensitive layer containing a silver halide emulsion and a layer containing physical development nuclei;developing said information-wise exposed imaging element in the presence of developing agent(s) and silver halide solvent(s)characterized in that said silver halide emulsion comprises said silver halide in an amount of at least 2 g/m.sup.2 (expressed as AgNO.sub.3), said development is carried out in the presence of a physical development restraining compound and wherein imaging elements comprising a positive working silver halide emulsion of the internal latent image type are excluded. Lithographic printing plates with substantially improved printing endurance are obtained.
    Type: Grant
    Filed: January 27, 1993
    Date of Patent: December 7, 1993
    Assignee: Agfa-Gevaert, N.V.
    Inventor: Ludo Van Rompuy
  • Patent number: 5258258
    Abstract: Disclosed is a processing solution used for making lithographic printing plates by silver complex diffusion transfer process which contains at least one thioether derivative represented by the following formulas (I), (II) and (III): ##STR1## wherein n.sub.1 and n.sub.2 each represents 0, 1 or 2 and R.sub.1 and R.sub.2 each represents an alkylene group of 1-5 carbon atoms, ##STR2## wherein R.sub.1 represents an alkylene group of 1-5 carbon atoms, X represents a hydrogen atom, a carboxy group, an alkoxycarbonyl group, a carbamoyl group, a hydroxy group, or --OR.sup.2 in which R.sup.2 has the same meaning as --R.sub.1 --S).sub.n CH.sub.2 CH.sub.2 OH above, and n represents 0, 1 or 2, ##STR3## wherein X' represents an aromatic or heterocyclic group which has a carboxy group, R.sub.1 and R.sub.2 each represents an alkylene group of 1-5 carbon atoms and n represents 0, 1, 2 or 3.
    Type: Grant
    Filed: October 10, 1991
    Date of Patent: November 2, 1993
    Assignee: Mitsubishi Paper Mills Limited
    Inventors: Eiji Matsubara, Hidetoshi Miura, Takimi Hashimoto
  • Patent number: 5236802
    Abstract: The present invention provides a lithographic printing plate material utilizing silver complex diffusion transfer process which can provide a lithographic printing plate markedly improved in water retentivity and prevented from deterioration of printability after storage. The lithographic printing plate material comprises a support and at least a silver halide emulsion layer and a physical development nuclei layer, wherein at least one of the physical development nuclei layer and a layer contiguous to the nuclei layer contains at least one water-soluble synthetic polymer selected from those which are represented by the following formulas: ##STR1## wherein R.sub.1 represents H or an alkyl group and n represents 100-3500 and ##STR2## wherein R.sub.2 represents H or an alkyl group, R.sub.3 represents H or an alkali metal, the ratio of n:m is 10:0-1:9, and polymerization degree is 100-3500.
    Type: Grant
    Filed: March 2, 1992
    Date of Patent: August 17, 1993
    Assignee: Mitsubishi Paper Mills Limited
    Inventors: Motozo Yamano, Akio Yoshida
  • Patent number: 5227275
    Abstract: Disclosed is a lithographic printing plate material which provides a printing plate which causes no peeling of film even after printing of a large number of prints and even with use of special printing ink such as ultraviolet-curing ink. This printing plate material comprises a polyester film subjected to hydrophilization treatment by coating with an organic copolymer as a support and at least one undercoat layer, at least one emulsion layer containing a silver halide, and an image receiving layer containing physical development nuclei provided on the support in this order, characterized in that the lowermost undercoat layer contiguous to the support contains a bisphenol type epoxy resin latex.
    Type: Grant
    Filed: September 28, 1992
    Date of Patent: July 13, 1993
    Assignee: Mitsubishi Paper Mills Limited
    Inventors: Hiroshi Miyazu, Yoshikazu Takaya
  • Patent number: 5202218
    Abstract: The present invention provides a lithographic printing plate material for silver complex diffusion transfer process by scanning type exposure which comprises a film support and, provided thereon, at least a silver halide emulsion layer and a surface physical development nuclei layer, wherein water content in the whole lithographic printing plate material including the support is 1.5% or less. Preferably, the silver halide emulsion comprises about 95 mol % or more of silver chloride, 90% by weight or more of the silver halide grains have a size within .+-.40% of average grain size, the silver halide grains have an average grain size of about 0.3.mu.-about 1.0.mu., and the surface of the grains is replaced with about 0.1 mol %-about 3.0 mol % of an iodide per 1 mol of the silver halide.
    Type: Grant
    Filed: March 19, 1991
    Date of Patent: April 13, 1993
    Assignee: Mitsubishi Paper Mills Limited
    Inventors: Akio Yoshida, Keisuke Iguchi, Hiroyuki Ishikura, Hiroshi Nishinoiri
  • Patent number: 5200294
    Abstract: According to the present invention there is provided a method for making a lithographic printing plate according to the DTR-process comprising the steps of:information-wise exposing an imaging element comprising on a support a silver halide emulsion layer and an image-receiving layer containing physical development nuclei anddeveloping said information-wise exposed imaging element with an alkaline processing liquid in the presence of developing agent(s), silver halide solvent(s) and hydrophobizing agent(s) characterized in that said hydrophobizing agent(s) are present in said alkaline processing liquid in a total amount of at least 0.1 g/l and wherein at least one of said silver halide solvents is a compound corresponding to the following formula:Z--(R.sup.1 --S).sub.t --R.sup.2 --S--R.sup.3 --Y (I)wherein Z and Y each independently represents hydrogen, an alkyl group, an amino group, and ammonium group, a hydroxyl, a sulfo group, a carboxyl, an amino carbonyl or an aminosulfonyl, R.sup.1, R.sup.2 and R.sup.
    Type: Grant
    Filed: December 19, 1991
    Date of Patent: April 6, 1993
    Assignee: Agfa-Gevaert, N.V.
    Inventors: Rene M. De Keyzer, Jean-Marie O. Dewanckele, Ludo L. Van Rompuy, Jos A. Vaes
  • Patent number: 5196290
    Abstract: The present invention provides a method for making a lithographic aluminium offset printing plate comprising the steps of:information-wise exposing an imaging element comprising on an aluminium support a layer of physical development nuclei and a silver halide emulsion layerdeveloping said information-wise exposed imaging element in the presence of a silver halide solvent to obtain a silver image in said layer of physical development nuclei andremoving all layers on top of said silver image to expose said silver image by means of washing with rinsing water characterized in that said rinsing water has a pH of 4 to 8 and is bufferred.
    Type: Grant
    Filed: May 27, 1992
    Date of Patent: March 23, 1993
    Assignee: AGFA-Gevaert, N.V.
    Inventors: Paul J. Coppens, Ludovicus H. Vefvloet, Eric M. Hoes
  • Patent number: 5164277
    Abstract: A light-sensitive material comprises a support and a light-sensitive layer provided thereon. The light-sensitive layer contains silver halide, a reducing agent and a polymerizable compound. In the light-sensitive material of the present invention, the polymerizable compound is a (meth)acrylic ester of an adduct of ditrimethylolpropane with an alkylene oxide. The amount of the alkylene oxide in the adduct is 1 to 10 mole based on one mole of ditrimethylolpropane.
    Type: Grant
    Filed: April 21, 1992
    Date of Patent: November 17, 1992
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Hiroyuki Hirai, Makoto Yamada
  • Patent number: 5156940
    Abstract: A new class of photographic stabilizers is prepared and their use in photographic materials is disclosed. These compounds are 1-phenyl-3-pyrazolidinone derivatives corresponding to following general formula: ##STR1## wherein: A represents a group capable of adsorbing at the surface of silver halides;L is a divalent linking group and r is 0 or 1;R1 and R2 each represent hydrogen, lower alkyl or substituted lower alkyl.The photographic materials containing the substances of the invention are preferably DTR mono-sheet elements which after processing can serve as planographic printing plates.
    Type: Grant
    Filed: February 13, 1991
    Date of Patent: October 20, 1992
    Assignee: AGFA-Gevaert, N.V.
    Inventors: Piet Kok, Jos A. Vaes, Jean-Marie O. Dewanckele, Luc J. Wabbes