Permanent Laminate Patents (Class 430/229)
  • Patent number: 7498071
    Abstract: It is an object of the present invention to provide a laminated member with an recorded information code, having a high reading accuracy, which do not detract from product design and which do not require a special reading apparatus. A laminated member 10 of the present invention comprises a transparent material layer 12 on which an information code is recorded, and a reflection-reduction layer 14 provided at the opposite side from a side where the information code is observed. The transparent layer 12 comprises low-reflectance portions 18 and high-reflectance portions 16 having a higher reflectance than the low-reflectance portions 18. The information code is recorded as a distributed pattern of the high-reflectance portions 16. The reflection-reduction layer 14 reduces reflected light advancing to the transparent material layer 12.
    Type: Grant
    Filed: January 16, 2004
    Date of Patent: March 3, 2009
    Assignee: Shiseido Co., Ltd.
    Inventors: Kenichi Sakuma, Masayoshi Wada, Asa Kimura
  • Patent number: 7078146
    Abstract: Disclosed are a planographic printing plate material comprising a plastic sheet support, and provided thereon, a hydrophilic layer, a silver halide emulsion layer, a physical developing nucleus-containing layer, and a backing layer, wherein the hydrophilic layer, the silver halide emulsion layer, and the physical developing nucleus-containing layer are provided on one side of the support, and the backing layer is provided on the other side of the sheet opposite the silver halide emulsion layer, and wherein a surface on the backing layer side has a specific resistance of from 1×1011 to 1×1013 ?, and a coefficient of dynamic friction of from 0.15 to 0.6, the coefficient of dynamic friction being one of the surface on the backing layer side to a stainless steel surface.
    Type: Grant
    Filed: May 25, 2004
    Date of Patent: July 18, 2006
    Assignee: Konica Minolta Medical & Graphic, Inc.
    Inventor: Takeshi Sampei
  • Publication number: 20030096188
    Abstract: A planographic printing plate material and a method of preparing a planographic printing plate are disclosed, the planographic printing plate material comprising a support and provided thereon, one or more structural layers containing light sensitive silver halide grains, organic silver salt grains, a reducing agent, a contrast-increasing agent and a physical developing nucleus.
    Type: Application
    Filed: March 12, 2002
    Publication date: May 22, 2003
    Inventor: Takeshi Sampei
  • Patent number: 6017673
    Abstract: A lithographic printing plate that works according to the silver salt diffusion transfer reversal process is disclosed. The lithographic properties of said plate can be improved by incorporating a hydrophilic amphoteric block copolymer, comprising a non-ionic block of acrylic units with pendant nitrile groups and an acrylamid(in)e block which comprises units with pendant basic and acidic groups. The hydrophilic amphoteric block copolymer is preferentially present in the image receiving layer of the lithographic printing plate. In an alternative embodiment, said block copolymer may be present in a treating solution used for processing said plate or applied onto said plate while printing. The hydrophilicity of the printing plate's surface is improved without deteriorating the ink-acceptance in the printing areas.
    Type: Grant
    Filed: April 1, 1998
    Date of Patent: January 25, 2000
    Assignee: Agfa-Gevaert, N.V.
    Inventors: Luc Vanmaele, Lode Deprez, Frank Louwet
  • Patent number: 5800961
    Abstract: The present invention provides an imaging element comprising on a support in the order given (i) a base layer comprising a binder in an amount between 1 and 4 g/m.sup.2, (ii) a photosensitive layer comprising a spectrally sensitised silver halide emulsion, and (iii) a receiving layer containing physical development nuclei in water permeable relationship with said photosensitive layer, characterized in that the base layer contains a latex polymer or copolymer with a glass transition temperature Tg not higher than 40.degree. C.
    Type: Grant
    Filed: June 30, 1997
    Date of Patent: September 1, 1998
    Assignee: Agfa-Gevaert, N.V.
    Inventor: Lode Deprez
  • Patent number: 5733703
    Abstract: The present invention provides an imaging element comprising on a support in the order given a photosensitive layer comprising a silver halide emulsion and an image receiving layer containing physical development nuclei in water permeable relationship with said emulsion layer, characterized in that said imaging element comprises at least 50 mg/m.sup.2 of tetramethyl reductic acid and at least 100 mg/m.sup.2 of ascorbic acid.According to the present invention there is further provided a method for making a lithographic printing plate comprising the steps of image-wise exposing an imaging element as defined above and subsequently developing a thus obtained imaging element by an alkaline processing liquid in the presence of developing agent(s) and silver halide solvent(s).
    Type: Grant
    Filed: December 8, 1995
    Date of Patent: March 31, 1998
    Assignee: Agfa-Gevaert, N.V.
    Inventors: Jos Vaes, Luc Wabbes
  • Patent number: 5731124
    Abstract: The present invention provides a method for preparing an aluminium foil comprising the steps of roughening an aluminium foil and subsequently anodizing said aluminium foil characterized in that after said anodization said aluminium foil is cleaned using an aqueous bicarbonate containing solution. The present invention further provides a mono-sheet silver salt diffusion transfer material having as a support the alumium foil obtainable from the above defined method. The step of cleaning in the bicarbonate containing solution improves the adhesion of an image receiving layer containing physical development nuclei to the aluminum foil as revealed from the increased amount of silver precipitated in the image receiving layer when the aluminum foil provided with an image receiving layer is used in a diffusion transfer reversal (DTR) process.
    Type: Grant
    Filed: June 26, 1996
    Date of Patent: March 24, 1998
    Assignee: AGFA-Gevaert, N.V.
    Inventors: Marcus Jonckheere, Paul Coppens
  • Patent number: 5641605
    Abstract: Disclosed is a lithographic printing plate excellent in scratch resistance, stain resistance, print image quality and ink-removability. The lithographic printing plate comprises a support and, coated thereon in succession, at least one undercoat layer, a silver halide emulsion layer and a physical development nuclei layer, characterized in that the lithographic printing plate has an arithmetical mean deviation of the profile Ra of 0.6 or less and the layers on the silver halide emulsion layer-provided side of the support contain 2.0 g/m.sup.2 or more of a matting agent.
    Type: Grant
    Filed: November 6, 1995
    Date of Patent: June 24, 1997
    Assignee: Mitsubishi Paper Mills Limited
    Inventors: Akio Yoshida, Hideaki Baba, Motozo Yamano
  • Patent number: 5637437
    Abstract: The present invention provides an imaging element comprising on a support in the order given (i) a base layer comprising a binder in an amount between 1 and 3 g/m.sup.2, (it) a photosensitive layer comprising a spectrally sensitised silver halide emulsion, said emulsion consisting principally of silver chloride but containing bromide ranging from 0.1 mole % to 40 mole % and iodide ranging from 0 to 2 mole % and (iii) a receiving layer containing physical development nuclei in water permeable relationship with said photosensitive layer, characterized in that the ratio by weight of gelatin to silver halide (expressed as an equivalent amount of AgNO.sub.3) in said photosensitive layer is at least 1.35.
    Type: Grant
    Filed: May 3, 1996
    Date of Patent: June 10, 1997
    Assignee: AGFA-Gevaert, N.V.
    Inventors: Jos Vaes, Luc Wabbes
  • Patent number: 5624783
    Abstract: The present invention provides an imaging element comprising on one side of a support a photosensitive layer comprising a silver halide emulsion and an image receiving layer containing physical development nuclei in water permeable relationship with said emulsion layer and on the other side of the support at least one backing layer comprising gelatin and a dye and/or a dye precursor characterized in that said dye or dye precursor is such that after treatment of said imaging element in an alkaline solution with a pH of 10.9 for 20 s at a temperature of 30.degree. C. the backing layer has a reflection spectrum when treated for 20 s at 20.degree. C. in a neutralizing solution with a pH of 7.5 that is visually different from the reflection spectrum when treated for 20 s at 20.degree. C. in a neutralizing solution with a pH of 8.5.
    Type: Grant
    Filed: April 8, 1996
    Date of Patent: April 29, 1997
    Assignee: Agfa-Gevaert, N.V.
    Inventors: Lode Deprez, Eric Kiekens
  • Patent number: 5618651
    Abstract: There is provided an imaging element having a flexible support and comprising on said support a photosensitive layer comprising a silver halide emulsion and an image-receiving layer comprising physical development nuclei, said layers being in water permeable contact with each other, characterized in that said flexible support is a polyester film having a thickness between 0.15 and 0.35 mm and consisting of polyethylene 2,6-naphthalenedicarboxylate. There is also provided a method for making a lithographic printing plate comprising the steps of image-wise exposing an imaging element as defined above and subsequently developing a thus obtained imaging element by an alkaline processing liquid in the presence of developing agent(s) and silver halide solvent(s).
    Type: Grant
    Filed: January 29, 1996
    Date of Patent: April 8, 1997
    Assignee: AGFA-Gevaert, N.V.
    Inventors: Marc Stevens, Johan Van Hunsel, Jos Vaes
  • Patent number: 5618650
    Abstract: The present invention provides an imaging element comprising on a support a silver halide emulsion layer and an image receiving layer comprising physical development nuclei being in water permeable contact with said silver halide emulsion layer, characterized in that said image receiving layer comprises a colloidal clay.According to the invention there is further provided a method for making a lithographic printing plate comprising the steps of image-wise exposing an imaging element as defined above and subsequently developing a thus obtained image-wise exposed imaging element by means of an alkaline processing solution in the presence of a developing agent and a silver halide solvent.
    Type: Grant
    Filed: November 8, 1995
    Date of Patent: April 8, 1997
    Assignee: AGFA-Gevaert, N.V.
    Inventors: Ren e De Keyzer, Jos Vaes
  • Patent number: 5552258
    Abstract: A process is described for producing a lithographic printing plate. The process comprises the steps of imagewise exposing a single sheet lithographic plate material consisting of a flexible support, having thereon a) at least an underlayer containing an acid ossein gelatin, b) a light sensitive silver halide layer, and c) a physical development nucleating surface layer, and, after said exposing, processing said plate material in a diffusion transfer developer or alkaline activator solution to develop imaged portions as hydrophilic areas and retain non-exposed areas as oleophilic areas on said plate.
    Type: Grant
    Filed: April 13, 1995
    Date of Patent: September 3, 1996
    Assignee: Minnesota Mining and Manufacturing Company
    Inventor: Michael T. Macioch
  • Patent number: 5512413
    Abstract: The present invention provides an imaging element comprising on the same side of a support in the order given a base layer, a light sensitive layer containing a silver halide emulsion and a surface layer comprising physical development nuclei characterized in that said base layer and/or said light-sensitive layer comprises gelatin being hardened with a divinylsulfonyl hardener such that the time needed to completely brake down said base layer, light sensitive layer and surface layer using an aqueous solution of 0.14% by weight of NaOCl at 25.degree. C. is between 1000s and 1600s. A lithographic printing plate can be obtained with such imaging element according to the silver salt diffusion transfer process and exhibits an improved printing endurance.
    Type: Grant
    Filed: June 6, 1995
    Date of Patent: April 30, 1996
    Assignee: AGFA-Gevaert N.V.
    Inventors: Lode Deprez, Eddy Michiels
  • Patent number: 5468588
    Abstract: A method of manufacturing a photosensitive element which can be exposed and enveloped by diffusion transfer processes to form a lithographic printing plate, said method comprising the steps of:(a) providing a support layer,(b) coating a negative acting silver halide emulsion layer onto said support layer, and(c) coating a physical development nucleation layer comprising particles onto said silver halide emulsion layer,wherein the coating of said physical development nucleation layer is performed with a coating composition which is at a temperature above 0.degree. C. and below 30.degree. C.
    Type: Grant
    Filed: October 18, 1994
    Date of Patent: November 21, 1995
    Assignee: Minnesota Mining and Manufacturing Company
    Inventors: Michael T. Macioch, Douglas M. Gates, Timothy M. Leary
  • Patent number: 5456999
    Abstract: The present invention provides a photographic material comprising a silver halide emulsion layer sensitized to light above 700 nm by means of an infrared sensitizing dye having a maximum absorption between 700 nm and 850 nm characterized in that said silver halide emulsion further comprises a red sensitizing dye of the cationic type having a maximum absorption between 600 nm and 700 nm. The thus obtained photographic material shows an increased sensitivity in the infrared region. The material can be used in as silver salt diffusion transfer process to prepare a lithographic printing plate.
    Type: Grant
    Filed: November 17, 1992
    Date of Patent: October 10, 1995
    Assignee: AGFA-Gevaert, N.V.
    Inventors: Jos Vaes, Luc Wabbes
  • Patent number: 5445915
    Abstract: The present invention provides an imaging element comprising on a support in the order given a base layer containing a matting agent having a number average diameter between 0.4 and 1 times the thickness of said base layer, a spectrally sensitized silver halide emulsion layer and a receiving layer containing physical development nuclei having an average diameter less than 6 nm and wherein the number of nuclei having a diameter larger than 4.5 nm is less than 15% of the total number of nuclei contained in said receiving layer and wherein substantially no matting agent is present in said receiving layer, silver halide emulsion layer or any other layer optionally being present between said receiving layer and silver halide emulsion layer.
    Type: Grant
    Filed: January 11, 1995
    Date of Patent: August 29, 1995
    Assignee: Agfa-Gevaert, N.V.
    Inventor: Jos Vaes
  • Patent number: 5281509
    Abstract: Disclosed is a light-sensitive element for lithographic printing plates excellent in stain resistance and water-carrying capacity which comprises a support and, coated thereon in succession, at least one undercoat layer, a silver halide emulsion layer and a physical development nuclei layer wherein at least one of the layers on the silver halide emulsion layer-provided side of the support contains 0.1-2.0 g/m.sup.2 of a matting agent of 5.mu. in average particle size and the light-sensitive element has an arithmetical mean deviation of profile Ra of 1.2 or less.
    Type: Grant
    Filed: September 9, 1992
    Date of Patent: January 25, 1994
    Assignee: Mitsubishi Paper Mills Limited
    Inventors: Tetsunobu Murakata, Hideaki Baba, Akio Yoshida, Kazuhisa Nakao, Motozo Yamano, Yasuo Tsubai
  • Patent number: 5236802
    Abstract: The present invention provides a lithographic printing plate material utilizing silver complex diffusion transfer process which can provide a lithographic printing plate markedly improved in water retentivity and prevented from deterioration of printability after storage. The lithographic printing plate material comprises a support and at least a silver halide emulsion layer and a physical development nuclei layer, wherein at least one of the physical development nuclei layer and a layer contiguous to the nuclei layer contains at least one water-soluble synthetic polymer selected from those which are represented by the following formulas: ##STR1## wherein R.sub.1 represents H or an alkyl group and n represents 100-3500 and ##STR2## wherein R.sub.2 represents H or an alkyl group, R.sub.3 represents H or an alkali metal, the ratio of n:m is 10:0-1:9, and polymerization degree is 100-3500.
    Type: Grant
    Filed: March 2, 1992
    Date of Patent: August 17, 1993
    Assignee: Mitsubishi Paper Mills Limited
    Inventors: Motozo Yamano, Akio Yoshida
  • Patent number: 5202218
    Abstract: The present invention provides a lithographic printing plate material for silver complex diffusion transfer process by scanning type exposure which comprises a film support and, provided thereon, at least a silver halide emulsion layer and a surface physical development nuclei layer, wherein water content in the whole lithographic printing plate material including the support is 1.5% or less. Preferably, the silver halide emulsion comprises about 95 mol % or more of silver chloride, 90% by weight or more of the silver halide grains have a size within .+-.40% of average grain size, the silver halide grains have an average grain size of about 0.3.mu.-about 1.0.mu., and the surface of the grains is replaced with about 0.1 mol %-about 3.0 mol % of an iodide per 1 mol of the silver halide.
    Type: Grant
    Filed: March 19, 1991
    Date of Patent: April 13, 1993
    Assignee: Mitsubishi Paper Mills Limited
    Inventors: Akio Yoshida, Keisuke Iguchi, Hiroyuki Ishikura, Hiroshi Nishinoiri
  • Patent number: 5153097
    Abstract: The invention provides a light-sensitive material for making lithographic printing plate through high-intensity short-time exposure which comprises a support and, provided thereon, at least a silver halide emulsion layer and a physical development nuclei layer wherein an intermediate layer comprising a water-permeable film forming polymer is provided between the emulsion layer and the nuclei layer. Furthermore, a process for making a lithographic printing plate from said light-sensitive material is provided which comprises subjecting the light-sensitive material to imagewise exposure of high intensity short time, silver complex diffusion transfer development and subsequently treatment with an oxidizing agent for silver and an oleophilic organic compound.
    Type: Grant
    Filed: August 19, 1991
    Date of Patent: October 6, 1992
    Assignee: Mitsubishi Paper Mills Limited
    Inventors: Hiroshi Nishinoiri, Yoshikazu Takaya, Yasuo Tsubai, Toshiro Kondo
  • Patent number: 4948699
    Abstract: This invention provides a silver halide photographic light sensitive material and a light sensitive lithographic printing plate material which are enhanced in sensitivity to semiconductor laser beam and improved in storage stability and printing endurance. The former comprises a support and a silver halide emulsion layer containing a sensitizing dye having a spectral sensitivity maximum in a wavelength region longer than 700 nm wherein said emulsion layer contains a water-soluble polymer containing a carboxyl group and having a number-average molecular weight of 20,000 or less and the latter comprises a support and, provided thereon, a silver halide emulsion layer containing a sensitizing dye having a spectral sensitivity maximum in a wavelength region longer than 700 nm and a physical development nuclei layer and said emulsion layer contains the above mentioned water-soluble polymer.
    Type: Grant
    Filed: August 1, 1988
    Date of Patent: August 14, 1990
    Assignee: Mitsubishi Paper Mills Limited
    Inventors: Hiroshi Nishinoiri, Toshiro Kondo, Yoshikazu Takaya
  • Patent number: 4879193
    Abstract: Disclosed are a light sensitive material and a lithographic printing plate made therefrom by silver complex diffusion transfer process ree from peeling of layer during printing which comprises a polyester film support made hydrophilic by coating with an organic copolymer as a support and at least one undercoat layer, a silver halide emulsion layer and an image receiving layer containing physical development nuclei layer provided on said support in succession, said undercoat layer contiguous to the support containing a polyfunctional epoxy compound having at least three epoxy groups in molecule.
    Type: Grant
    Filed: March 16, 1988
    Date of Patent: November 7, 1989
    Assignee: Mitsubishi Paper Mills, Ltd.
    Inventors: Yoshikazu Takaya, Kazuo Yokoyama
  • Patent number: 4824760
    Abstract: A lithographic printing plate made by silver complex diffusion transfer process from a lithographic printing plate material which contains a compound represented by the general formula [I] in photographic constituting layer is markedly improved in its printing endurance: ##STR1## wherein M represents hydrogen, an alkali metal or ammonium ion and R.sup.1 -R.sup.4 each represents hydrogen atom, alkyl group, alkenyl group, aralkyl group, aryl group, halogen atom, alkoxy group, hydroxyl group, amino group, carboxyl group, sulfone group, alkoxycarbonyl group, acylamide group or sulfonamide group and two of R.sup.1 -R.sup.4 may jointly form a ring.
    Type: Grant
    Filed: April 7, 1987
    Date of Patent: April 25, 1989
    Assignee: Mitsubishi Paper Mills, Ltd.
    Inventors: Kazuyoshi Yamamoto, Masahiko Saikawa, Eiji Kanada
  • Patent number: 4772535
    Abstract: Printing characteristics of a lithographic printing plate material using the silver complex diffusion transfer process and comprising a support and a silver halide emulsion layer and a surface physical development nuclei layer are markedly improved when the emulsion layer comprises two emulsion layers, the lower layer of which has substantially no light-sensitivity.
    Type: Grant
    Filed: April 7, 1987
    Date of Patent: September 20, 1988
    Assignee: Mitsubishi Paper Mills, Ltd.
    Inventors: Motozo Yamano, Kazunaka Endo, Eiji Kanada
  • Patent number: 4743525
    Abstract: Disclosed is a lithographic printing plate material which comprises a support and at least an undercoat layer, a silver halide emulsion layer and a catalytic layer containing physical development nuclei provided in this order on said support and which utilizes silver complex diffusion transfer process, wherein content of calcium ion in at least one of lime treated gelatin-containing layers is 1000 ppm or less.
    Type: Grant
    Filed: October 24, 1986
    Date of Patent: May 10, 1988
    Assignee: Mitsubishi Paper Mills, Ltd.
    Inventors: Kazuyoshi Yamamoto, Eiji Kanada, Kyonosuke Yamamoto, Satoshi Katano
  • Patent number: 4510228
    Abstract: Disclosed is a photosensitive element for the production of lithographic printing plates improved in printing endurance comprising a support, a physical development nuclei layer, and at least one gelatin-containing layer including a silver halide emulsion layer disposed under said nuclei layer, which is adapted to the silver complex diffusion transfer process to utilize the transferred silver image on said nuclei layer as ink-receptive areas, all of the gelatin-containing layers having a pH value below the isoelectric point of the gelatin used in each layer. Further improvement can be attained by using a photographic gelatin and a low molecular weight gelatin in at least one of said gelatin-containing layers.
    Type: Grant
    Filed: April 20, 1983
    Date of Patent: April 9, 1985
    Assignee: Mitsubishi Paper Mills, Ltd.
    Inventors: Yasuo Tsubai, Yoshikazu Takaya, Eiji Kanada
  • Patent number: 4500636
    Abstract: A silver halide photographic light-sensitive material which comprises a light-sensitive silver halide emulsion layer having associated therewith a blocked photographic agent, said blocked photographic agent being represented by the following general formula (I): ##STR1## wherein A represents a photographic agent moiety which is attached to a blocking moiety through a hetero atom; Z represents a divalent linkage group; p represents 0 or 1; X and Y each represents a substituent: m represents an integer of 0 to 4: and n represents an integer of 0 to 5.
    Type: Grant
    Filed: January 27, 1984
    Date of Patent: February 19, 1985
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Mitsunori Ono, Isamu Itoh, Keiji Mihayashi, Yukio Karino
  • Patent number: 4499164
    Abstract: An optical barrier layer for use in reflection type image carrying media of the type wherein a thin transparent image receiving layer includes an image which is viewed through one side of the image receiving layer with ambient light that is reflected from a light scattering layer located on the other side of the image-receiving layer. The optical barrier layer is a thin, transparent layer located between the image receiving layer and the light scattering layer and operates to minimize nonlinear density effects of multiple internal reflections.
    Type: Grant
    Filed: May 3, 1984
    Date of Patent: February 12, 1985
    Assignee: Polaroid Corporation
    Inventor: William T. Plummer
  • Patent number: 4489152
    Abstract: Diffusion transfer film units and processes are disclosed wherein a silver transfer image is formed in an image layer separated from the silver halide emulsion by a layer containing carbon black. Inclusion of polyvinylpyrrolidone in the carbon black layer provides increased silver transfer density.
    Type: Grant
    Filed: February 29, 1984
    Date of Patent: December 18, 1984
    Assignee: Polaroid Corporation
    Inventors: David F. Oberhauser, Peter H. Roth
  • Patent number: 4476213
    Abstract: A self-contained silver halide diffusion transfer imaging sheet is provided which contains three layers on a substrate. The first layer is a silver halide emulsion formed in a non-ionic material. The intermediate layer is a water barrier. The third layer is a nucleating region which contains colloidal silver. A developer, base and silver transport agent can also be located in these layers. For example, the base and silver transport agent can be located in the nucleating layer, with the developer located in the emulsion layer. After the emulsion is exposed to actinic radiation, a non-aqueous activating medium is supplied which initiates the development and diffusion transfer processes. The final result is a positive image in the nucleating layer.
    Type: Grant
    Filed: December 10, 1982
    Date of Patent: October 9, 1984
    Assignee: The Mead Corporation
    Inventors: Paul C. Adair, Amy L. Burkholder, Homer G. Duda, Richard F. Wright, Mary M. Stanley
  • Patent number: 4415648
    Abstract: Photographic transparency assemblies comprising a photographic image supported on a transparent sheet material associated with a light polarizer element. The transparency assembly, including the light polarizer element, can be viewed in conjunction with a second partially crossed light polarizer element in order to modify the transmission density of the transparency image.
    Type: Grant
    Filed: February 17, 1981
    Date of Patent: November 15, 1983
    Assignee: Polaroid Corporation
    Inventors: Ruth C. Bilofsky, Ronald A. Sahatjian
  • Patent number: 4400462
    Abstract: Photographic materials and photographic processes employing light sensitive silver halide particles, silver halide particles which are substantially non-light sensitive having been modified with a silver halide solubility reducing agent and internally fogged silver halide particles which are substantially non-light sensitive provide negative silver images of high contrast and high maximum density.
    Type: Grant
    Filed: June 1, 1981
    Date of Patent: August 23, 1983
    Assignee: Konishiroku Photo Industry Co., Ltd.
    Inventors: Kouzi Ono, Mikio Kawasaki, Mariko Natori, Eiichi Sakamoto
  • Patent number: 4376157
    Abstract: Transfer images of high contrast, high density and high sharpness can be obtained by DTR process wherein all of the physical development nucleus particles are covered with a water permeable colloid having a thickness of at least 10 times the average diameter of the nucleus particles and all of the physical development nucleus particles are substantially two-dimensionally distributed at such intervals as capable of forming a continuous transfer developed silver.
    Type: Grant
    Filed: March 19, 1981
    Date of Patent: March 8, 1983
    Assignee: Mitsubishi Paper Mills, Ltd.
    Inventors: Yasuo Tsubai, Yoshikazu Takaya, Takao Senga
  • Patent number: 4312938
    Abstract: A broadband laser recording and data storage medium for direct read after writing, formed from a photosensitive silver-halide emulsion in four steps. First, a non-saturating actinic radiation exposure is used to create latent images. A normal photographic development is used to produce a medium of gray neutral density. The surface of the remaining silver halide is fogged in a water or alcohol based solution to create a very thin layer of silver precipitating nuclei on the surface. Finally, a single-step, negative silver diffusion transfer process is used to dissolve the unexposed and undeveloped silver halide, forming silver ion complexes.
    Type: Grant
    Filed: October 17, 1980
    Date of Patent: January 26, 1982
    Assignee: Drexler Technology Corporation
    Inventors: Jerome Drexler, Eric W. Bouldin
  • Patent number: 4304848
    Abstract: A method of replicating data from a master transmissive optical data storage medium whereby the resulting product displays areas of low reflectivity and high reflectivity. Actinic radiation is shone through transmissive areas onto a silver-halide emulsion photosensitive medium. The photosensitive medium is then chemically developed black. Next, the developed medium is fogged to create a latent image layer of silver precipitating nuclei. Finally, the fogged medium is placed in a monobath comprising a weak silver-halide reducing agent and a rapid-acting silver-halide solvent for partial chemical development and substantial physical development. The resulting product displays areas of low reflectivity, which correspond to the transmissive areas of the master, in a reflective field.
    Type: Grant
    Filed: June 4, 1980
    Date of Patent: December 8, 1981
    Assignee: Drexler Technology Corporation
    Inventors: Eric W. Bouldin, Jerome Drexler
  • Patent number: 4297430
    Abstract: In production of lithographic printing plates by developing a photographic material comprising a support having thereon at least both silver halide emulsion layer and physical development nuclei layer by silver complex diffusion transfer process to form transfer silver to be used as ink-receptive portions of the lithographic printing plates, when the development is carried out in the presence of a cyclic imide compound (alone or in combination with sulfites, thiosulfates, thiocyanates or alkanolamines) as defined hereinafter, ink-receptivity of the transfer silver image portions and printing endurance of thus obtained printing plates are improved. Moreover, the non-image portions have no or substantially no stains.
    Type: Grant
    Filed: August 1, 1980
    Date of Patent: October 27, 1981
    Assignee: Mitsubishi Paper Mills, Ltd.
    Inventors: Eiji Kanada, Shoji Yamada, Yasuo Tsubai
  • Patent number: 4297429
    Abstract: Lithographic printing plates having high ink receptivity, suffuring no ink stains and having much improved printing endurance can be produced by silver complex diffusion transfer process from lithographic printing plate materials comprising a support having thereon at least both silver halide emulsion layer and physical development nuclei layer wherein the diffusion transfer processing is carried out in the presence of 2-mercaptobenzoic acid derivatives or, besides this 2-mercaptobenzoic acid derivatives, at least one compound selected from the group consisting of alkanolamines and cyclic imide compounds which may be contained in at least one layers of the lithographic printing plate materials and/or the diffusion transfer developing solutions.
    Type: Grant
    Filed: June 11, 1980
    Date of Patent: October 27, 1981
    Assignee: Mitsubishi Paper Mills, Ltd.
    Inventors: Eiji Kanada, Shoji Yamada, Yasuo Tsubai
  • Patent number: 4278756
    Abstract: A reflective laser recording and data storage medium, for direct reading after writing, formed from a photosensitive silver-halide emulsion wherein a surface latent image exposure on the recording area forms a depthwise gradient of silver nuclei. A single step negative silver diffusion transfer process is used to develop silver nuclei of the latent image and dissolve unexposed silver halide elsewhere, forming silver ion complexes. These complexes are transported by diffusion transfer to the developing silver nuclei sites where silver is precipitated and adsorbed to form a high concentration of non-filamentary particles at a surface of a low melting temperature dielectric matrix which is highly reflective of light and electrically non-conducting.
    Type: Grant
    Filed: July 6, 1979
    Date of Patent: July 14, 1981
    Assignee: Drexler Technology Corporation
    Inventors: Eric W. Bouldin, Jerome Drexler
  • Patent number: 4269917
    Abstract: A reflective laser recording and data storage medium, for direct reading after writing, formed from a photosensitive silver-halide emulsion wherein a surface latent image exposure on the recording area forms a depthwise gradient of silver nuclei. A single step negative silver diffusion transfer process is used to develop silver nuclei of the latent image and dissolve unexposed silver halide elsewhere, forming silver ion complexes. These complexes are transported by diffusion transfer to the developing silver nuclei sites where silver is precipitated and adsorbed to form a high concentration of non-filamentary particles at a surface of a low melting temperature dielectric colloid matrix which is highly reflective of light and electrically non-conducting.
    Type: Grant
    Filed: July 14, 1980
    Date of Patent: May 26, 1981
    Assignee: Drexler Technology Corporation
    Inventors: Jerome Drexler, Eric W. Bouldin
  • Patent number: 4216286
    Abstract: Cloth, such as cotton, burlap, or canvas, has a photographic emulsion laminated thereto, along with an outer protective film. The composite laminate formed is permanent, and sufficiently firmly affixed to the cloth that the cloth is machine washable without substantial damage or alteration of the laminated image. The method of making the cloth laminated with photographic emulsion comprises applying the photographic emulsion facedown on a protective film, coating with adhesive and applying the cloth, drying the emulsion and cloth and pressing between plates, at least one of which is heated. By dipping the emulsion in a stripping solution prior to applying to the protective film, adherence and permanence of the laminate formed is substantially increased.
    Type: Grant
    Filed: September 7, 1978
    Date of Patent: August 5, 1980
    Inventors: J. Jerrold Greene, Avrom Keller
  • Patent number: 4186001
    Abstract: The present invention is concerned with photographic products and processes, particularly diffusion transfer products and processes employing as a colored light-screening dye(s), a 3,3-disubstituted sulfam(na)phthalein wherein one of the 3-substituents is a 4'-hydroxy-1'-naphthyl moiety substituted in the 3'-position with a perhalomethylcarbinol group and the other of the 3-substituents is a phenyl moiety substituted with an electron-donating group and wherein the N atom of the sulfam(na)phthalein ring is substituted with a carbonyl moiety possessing a ##STR1## group bonded to the N atom of said sulfam(na)phthalein ring, which carbonyl moiety undergoes an irreversible cleavage reaction in alkaline solution above a predetermined alkaline pH to form a new compound which is colorless and non-reversible to said light-screening dye.
    Type: Grant
    Filed: November 2, 1978
    Date of Patent: January 29, 1980
    Assignee: Polaroid Corporation
    Inventor: James W. Foley