Transfer Process With Uniform Heat Application And Element Therefor Patents (Class 430/254)
  • Patent number: 5541034
    Abstract: Heat-developable silver-based photosensitive imaging element comprising a heat-reducible organic silver salt, a photosensitive silver halide, a developing agent, and a releasing compound that upon reaction with either the reduced or the oxidized form of the developing agent is capable of releasing a hydrophobizing agent. The invention also relates to a method for producing a lithographic printing plate comprising image-wise exposing an imaging element, bringing the exposed element in face-to-face contact with an oleophobic surface of a printing plate precursor, heating the imaging element while in contact or before being brought in contact with the oleophobic surface to cause reduction of the organic silver salt and to cause the release of the hydrophobizing agent from the releasing compound, allowing the hydrophobizing agent to diffuse to the oleophobic surface to render the surface image-wise oleophilic, and separating the resulting lithographic printing plate from the imaging element.
    Type: Grant
    Filed: June 3, 1994
    Date of Patent: July 30, 1996
    Assignee: Agfa-Gevaert, N.V.
    Inventors: Luc Leenders, Rudy Van Cleuvenbergen, Rudi De Busser, Marcel Monbaliu
  • Patent number: 5533452
    Abstract: A printing method for an in situ plate production process in which a photosensitive plate blank having a polymerization layer between a support and a release film is fixed to a plate cylinder either before or after forming a polymerization-nonpolymerization pattern in the polymerization layer. The polymerization layer can be a thermal development-type photosensitive layer for forming the pattern. The release film is then peeled apart from the plate blank to leave a printing plate on the plate cylinder, which can be used for printing and for an inking step. The printing pattern of the plate can be formed by selective removal of the unpolymerized part or by selective transfer of the release film to the polymerized part of the polymerization layer.
    Type: Grant
    Filed: November 4, 1994
    Date of Patent: July 9, 1996
    Assignee: Canon Kabushiki Kaisha
    Inventors: Akihiro Mouri, Tsuyoshi Shibata, Yuji Kondo
  • Patent number: 5534384
    Abstract: A photosensitive material for the production of color proofing films for multicolor printing, having(A) a transparent, flexible film support of plastic,(B) a photopolymerizable layer which contains(B1) a polymeric binder,(B2) a free-radically polymerizable compound,(B3) a compound which is capable of initiating the polymerization of (B2) on exposure to actinic light, and(B4) a dye or a colored pigment in a primary color of multicolor printing, and(C) a thermoplastic adhesive layer having a layer weight of from about 2 to about 30 g/m.sup.2 on the photo-sensitive layer, wherein the thermoplastic adhesive layer contains from about 0.01 to about 0.5% by weight of a colorless pigment having a mean particle size which corresponds to from 1 to 100% of the layer thickness.
    Type: Grant
    Filed: February 19, 1993
    Date of Patent: July 9, 1996
    Assignee: Hoechst Aktiengesellschaft
    Inventors: Stephan J. W. Platzer, Siegfried Nuernberger, Karin Maerz
  • Patent number: 5534373
    Abstract: A photosensitive material comprising (A) a flexible transparent film support, (B) a colored photosensitive layer which contains an organic binder (B1) a dye or a colored pigment (B2), a compound (B3), which forms a strong acid on exposure to radiation, and a compound (B4) which has at least one group cleavable by the acid, and (C) an adhesion-promoting layer which contains a thermoplastic polymer which has a softening temperature in the range from 40.degree. to 200.degree. C., wherein the adhesion (a.sub.1) of the unexposed photosensitive layer (B) to the adhesion-promoting layer (C) is less than the adhesion (a.sub.3) of the unexposed photosensitive layer (B) to the film support (A) and than the cohesions of the layers (B) and (C), and the adhesion (a.sub.3 ') of the exposed photosensitive layer (B) to the film support (A) is less than the adhesion (a.sub.
    Type: Grant
    Filed: April 19, 1995
    Date of Patent: July 9, 1996
    Assignee: Agfa-Gevaert AG
    Inventors: Stephan J. W. Platzer, Andrea Buchmann, Gerhard Buhr
  • Patent number: 5527654
    Abstract: A process for the production of a color image is described, in which a photosensitive material that has a temporary support film, a colored photosensitive layer and an adhesion-promoting layer that can be activated by heat is laminated at high temperature and under pressure with an image-receiving material which carries, on a support, a pigment layer containing a white pigment. The photosensitive layer is exposed imagewise and developed to produce an image, the temporary support film is peeled off from the image-receiving material before or after exposure to light and, if required, these steps are repeated with at least one further photosensitive material whose colored layer has another color to produce a multi-colored image. The process gives color images having a smaller dot enlargement compared with a halftone original and is particularly suitable for the color testing of copy for multicolor printing.
    Type: Grant
    Filed: July 18, 1994
    Date of Patent: June 18, 1996
    Assignee: Hoechst Aktiengesellschaft
    Inventors: Martin Benzing, Dieter Mohr, Juergen Mertes, Peter Blum
  • Patent number: 5521035
    Abstract: Color filter elements are prepared by the laser induced thermal transfer of colorant from a color donor to a transparent, non-birefringent substrate such as glass or polymeric film. Transparent pigments which are less prone to migration, more thermally stable, and considerably more lightfast than dyes can be used to prepare the color filter elements of this invention. Color filter elements are useful for elements in color displays such as liquid crystal display devices.
    Type: Grant
    Filed: July 11, 1994
    Date of Patent: May 28, 1996
    Assignee: Minnesota Mining and Manufacturing Company
    Inventors: Martin B. Wolk, Thomas A. Isberg, Kenneth L. Hanzalik, Jeffrey C. Chang, Richard E. Bills, William V. Dower, Terrance P. Smith
  • Patent number: 5501940
    Abstract: A binary image comprising a plurality of first areas, at which a porous or particulate image-forming substance is adhered to a substrate, and a plurality of second areas, at which the substrate is free from the image-forming substance, is protected by laminating thereto a laminating sheet comprising a durable layer and a support layer with the durable layer facing the image, so that the durable layer adheres to both the first and second areas of the image. The support layer is then displaced away from the image such that the durable layer remains attached to the image. The durable layer is substantially transparent and comprises a polymeric organic material having incorporated therein a siloxane, the siloxane being incorporated into the polymeric material in such a manner that it is not removed therefrom by hexane, isopropanol or water.
    Type: Grant
    Filed: May 20, 1993
    Date of Patent: March 26, 1996
    Assignee: Polaroid Corporation
    Inventors: Iris B. K. Bloom, Agota F. Fehervari, Russell A. Gaudiana, Richard A. Minns, Howard G. Schild
  • Patent number: 5498504
    Abstract: A process is provided for forming an image involving a photosensitive element comprising a photopolymerisable monomer and a reducible metal salt, preferably silver behenate, and a donor element containing a reducing agent. After lamination to a cover sheet, photopolymerisation and delamination, the image density is built up by lamination to the donor element, transfer of reducing agent and peeling-apart, possibly followed by heating the photosensitive element.
    Type: Grant
    Filed: November 21, 1994
    Date of Patent: March 12, 1996
    Assignee: Agfa-Gevaert, N.V.
    Inventors: Luc Leenders, Eddie Daems
  • Patent number: 5478695
    Abstract: Heat-sensitive imaging element comprising a support carrying a binder layer, optionally an intermediate adhesive layer, and and a barrier layer that is ablatable by a laser beam or permeabilizable under the influence of a laser beam, wherein said binder layer contains at least one hydrophobizing agent capable of diffusing under the influence of heat through holes made in said barrier layer or through permeabilized parts of said barrier layer and capable of reacting with the oleophobic surface of a printing plate precursor brought in face-to-face contact with said barrier layer. The present invention also relates to a process for producing a lithographic printing plate, wherein use is made of such heat-sensitive imaging element.
    Type: Grant
    Filed: November 22, 1993
    Date of Patent: December 26, 1995
    Assignee: AGFA-Gevaert, N.V.
    Inventor: Luc Leenders
  • Patent number: 5478694
    Abstract: The invention relates to a photosensitive material for the production of color proofing films for multicolor printing comprising:A) a transparent, flexible film support,B) a photopolymerizable layer containing:B1) a polymeric binder,B2) a free radical-polymerizable compound,B3) a compound which is capable of initiating the polymerization of (B2) on exposure to actinic light, andB4) a dye or colored pigment in a primary color of multicolor printing, andC) a thermoplastic adhesive layer on the photosensitive layer,which contains at least about 1.5% by weight of a water-soluble, colorless, low-molecular-weight salt whose aqueous solution is not highly acidic.The material is processed by lamination onto an image-receiving material, exposure and peeling apart of the film support and the image-receiving material, the unexposed areas of the layer and the adhesive layer remaining on the image-receiving material.
    Type: Grant
    Filed: May 17, 1993
    Date of Patent: December 26, 1995
    Assignee: Hoechst Aktiengesellschaft
    Inventors: Karin Maerz, Ine Gramm, Manfred Hilger, Dieter Mohr, Stephan J. W. Platzer
  • Patent number: 5460918
    Abstract: A thermal transfer system for transferring material in an imagewise manner by means of thermal transfer printing from a donor element to an image receiving element is used to prepare printing plates. In one construction, a donor element, which is prepared by coating a photoinitiator (and optionally a sensitizer) in a binder on a backing material, is used with an image receiving element, which is prepared by coating a photopolymer (and optionally a sensitizer) on a substrate having a microporous hydrophilic crosslinked silicated surface. In an alternative construction, a donor element, which is prepared by coating a sensitizer in a binder on a backing material, is used with an image receiving element, which is prepared by coating a photopolymer and photoinitiator on a substrate having a microporous hydrophilic crosslinked silicated surface.
    Type: Grant
    Filed: October 11, 1994
    Date of Patent: October 24, 1995
    Assignee: Minnesota Mining and Manufacturing Company
    Inventors: M. Zaki Ali, Mahfuza Ali, David R. Boston, Jeffrey C. Chang
  • Patent number: 5455142
    Abstract: An image formation process uses two light-sensitive elements comprising first and second adhesive light-sensitive layers which become nonadhesive upon exposure to light, respectively, and first and second toner elements comprising toner layers (a') and (b') of hues (a) and (b), respectively.
    Type: Grant
    Filed: October 21, 1992
    Date of Patent: October 3, 1995
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Yohnosuke Takahashi, Hideyuki Nakamura, Fumiaki Shinozaki, Shinji Tsuno
  • Patent number: 5439775
    Abstract: An image formation process uses two light-sensitive elements comprising first and second adhesive light-sensitive layers which become nonadhesive upon exposure to light, respectively, and first and second toner elements comprising toner layers (a') and (b') of hues (a) and (b), respectively.
    Type: Grant
    Filed: December 14, 1994
    Date of Patent: August 8, 1995
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Yohnosuke Takahashi, Hideyuki Nakamura, Fumiaki Shinozaki, Shinji Tsuno
  • Patent number: 5436112
    Abstract: This invention provides novel ethylenically unsaturated urethane monomers and photoreactive compositions comprising such monomers as essential constituents. The monomers can be photopolymerized or photocrosslinked and are useful in coating systems and multilayer color proofing systems. Additionally, they offer superior advantages such as significantly reduced migration between layers in multilayer color proofing systems.
    Type: Grant
    Filed: April 1, 1994
    Date of Patent: July 25, 1995
    Assignee: Hoechst Celanese Corporation
    Inventors: Shane Hsieh, Wojciech A. Wilczak
  • Patent number: 5415974
    Abstract: A photosensitive material comprises a photosensitive silver halide, an organic silver salt, a reducing agent, a polymerizable polymer precursor, a photopolymerization initiator and a heat-diffusible coloring matter. As a preferred embodiment, the photosensitive material comprises a photosensitive layer containing the photosensitive silver halide, the organic silver salt and the reducing agent, a polymerizing layer containing the polymerizable polymer precursor and the photopolymerization initiator, and a coloring material layer containing the heat-diffusible coloring material. A image forming method employing the photosensitive material comprises the steps of a) subjecting the photosensitive material to imagewise exposure; b) heating the photosensitive material; c) subjecting to whole areas exposure at least the polymerizing layer; and d) heating at least the coloring material layer to transfer the heat-diffusible coloring matter to an image-receiving material, thus forming a color image.
    Type: Grant
    Filed: April 26, 1993
    Date of Patent: May 16, 1995
    Assignee: Canon Kabushiki Kaisha
    Inventors: Masato Kotayama, Tetsuro Fukui, Akihiro Mouri, Kazuo Isaka, Kyo Miura, Kenji Kagami, Masao Suzuki
  • Patent number: 5409799
    Abstract: According to the present invention a method is provided for obtaining an image comprising the steps of:information-wise exposing an imaging element comprising on a support a photosensitive layer containing a photopolymerizable composition and a base layer located between said support and said photosensitive layer and wherein said base layer is contiguous to said photosensitive layer and comprises a polymer containing polymerizable ethylenically unsaturated groups andtransferring upon heating the non-hardened or insufficiently hardened parts of said photosensitive layer to an image receiving material. When the image receiving material contains a hydrophilic surface a lithographic printing plate can be obtained.
    Type: Grant
    Filed: June 15, 1992
    Date of Patent: April 25, 1995
    Assignee: Agfa-Gevaert, N.V.
    Inventors: Herman J. Uytterhoeven, Rafael P. Samijn, Joan T. Vermeersch, Yves L. Verburgh
  • Patent number: 5409798
    Abstract: A printing plate blank is formed by disposing successively a base layer, a photosensitive layer susceptible of peeling development, and a peeling support layer (or a laminate of a photosensitive silver salt layer including a photosensitive silver halide, an organic silver salt and a reducing agent). A printing plate is prepared by forming a polymerized part in the photosensitive layer through imagewise exposure and peeling apart the peeling support layer (or the laminate) together with the yet-unpolymerized port of the photosensitive layer to leave the polymerized part of the photosensitive layer on the base layer. The resultant printing plate is provided with an improved printing durability primarily by inclusion of a polymerizable compound in the base layer effective for firmly fastening the polymerized part to the base layer and additionally by subjecting the thus-prepared printing plate to additional exposure, heating and/or pressure application.
    Type: Grant
    Filed: August 27, 1992
    Date of Patent: April 25, 1995
    Assignee: Canon Kabushiki Kaisha
    Inventors: Yuji Kondo, Tsuyoshi Shibata
  • Patent number: 5401606
    Abstract: A laser-induced melt transfer process is described in which a melt viscosity modifier is used to facilitate the melt transfer process.
    Type: Grant
    Filed: April 30, 1993
    Date of Patent: March 28, 1995
    Assignee: E. I. Du Pont de Nemours and Company
    Inventors: Joseph E. Reardon, Anthony J. Serino
  • Patent number: 5399458
    Abstract: A process for preparing images, particularly color proof prints, in which tacky and non-tacky areas are produced by imagewise exposure of a radiation-sensitive layer is described. The tacky areas are toned with a toner having a tackiness that can be increased by irradiation with actinic radiation.
    Type: Grant
    Filed: August 10, 1993
    Date of Patent: March 21, 1995
    Assignee: E. I. Du Pont de Nemours and Company
    Inventors: Mario Grossa, Dieter Tigler, Bernhard Metzger, Paola Gallo
  • Patent number: 5395729
    Abstract: A laser-induced melt transfer process is described which utilizes a melt viscosity modifier and in which a post-transfer treatment is used to substantially eliminate back-transfer.
    Type: Grant
    Filed: April 30, 1993
    Date of Patent: March 7, 1995
    Assignee: E. I. du Pont de Nemours and Company
    Inventors: Joseph E. Reardon, Anthony J. Serino
  • Patent number: 5395730
    Abstract: A method is disclosed for the formation of an image comprising the steps of(1) image-wise exposing, in the presence of a photopolymerizable compound, a photosensitive element comprising a support and at least one photosensitive layer containing a silver halide sensitive to actinic radiation, an organic silver salt and a reducing agent,(2) heating said photosensitive layer while in contact with a receiving element and allowing non-photopolymerized compound in the non-exposed areas to transfer and penetrate in said receiving element, and,(3) separating said receiving element from said photosensitive element.The obtained image can be a useful visible image produced on at least one of the separated elements, or it can be a hydrophobic polymer image on a hydrophilic background formed in the finally separated-receiving element which is usable as a printing plate. In the former embodiment the receiving element comprises a support and a layer containing a pigment, e.g. carbon black.
    Type: Grant
    Filed: August 31, 1993
    Date of Patent: March 7, 1995
    Assignee: Agfa-Gevaert, N.V.
    Inventors: Wolfgang Podszun, Herman J. Uytterhoeven, Roland F. Beels, Luc H. Leenders
  • Patent number: 5393639
    Abstract: A thermally imageable laminar composite comprising a pair of opposed sheets confining therebetween a frangible layer of image-forming substance partitionable to the respective sheets on separation of the sheets after thermal imaging is protected against premature stress-induced delamination by the heat bonding of the opposed sheets to one another through said image-forming substance at the periphery of said composite, said bonding being at a strength substantially greater than that required to separate said sheets in the expansive thermally imageable region confined by said periphery. A method for preparing individual units of an imageable composite, including the steps of establishing a band-like heated zone in a supply web of laminate, corresponding to the boundaries of a unit to be cut therefrom, and cutting a unit from within said band-like zone is described.
    Type: Grant
    Filed: November 25, 1992
    Date of Patent: February 28, 1995
    Assignee: Polaroid Corporation
    Inventor: Steven Kourepenis
  • Patent number: 5393638
    Abstract: An image is formed by subjecting to imagewise exposure an image forming medium containing at least a heat-diffusible coloring matter, a photosensitive silver halide, an organic silver salt, a reducing agent, a polymerizable polymer precursor and a photopolymerization initiator; heating the image forming medium thus treated; subjecting it to polymerization exposure to form a polymerized area and an unpolymerized area in the image forming medium; separating the polymerized area from the unpolymerized area; and superposing an image receiving medium onto the unpolymerized area to transfer the heat-diffusible coloring matter in the unpolymerized area to the image receiving medium.
    Type: Grant
    Filed: June 10, 1991
    Date of Patent: February 28, 1995
    Assignee: Canon Kabushiki Kaisha
    Inventors: Akihiro Mouri, Masato Katayama, Kazuo Isaka, Tetsuro Fukui
  • Patent number: 5374184
    Abstract: A photopolymerizable material having(A) a flexible, transparent film support;(B) a colored, polymerizable layer containing an organic binder, a free-radical-polymerizable compound, containing at least one terminal ethylenically unsaturated group, and a dye or colored pigment;(C) an adhesion layer containing a thermoplastic polymer and having a T.sub.g of from 25.degree. to 100.degree. C.; and(D) an uncolored photopolymerizable layer which contains a polymeric organic binder, a free-radical-polymerizable compound containing at least one terminal ethylenically unsaturated group and a photopolymerization initiator between the film support (A) and the colored polymerizable layer (B),where the cohesion of layers (B), (C) and (D) and the adhesion of these layers to one another and to the film support (A) provides the relationship wherein the adhesion (a.sub.2) of the photopolymerizable layer (D) to the colored layer (B) in the unexposed state is lower than: (i) the adhesion (a.sub.
    Type: Grant
    Filed: April 4, 1994
    Date of Patent: December 20, 1994
    Assignee: Hoeschst Aktiengesellschaft
    Inventors: Stephan J. W. Platzer, Gerhard Buhr, Manfred Michel, Andrea Buchmann
  • Patent number: 5374497
    Abstract: A print-out layer is incorporated in a donor element that is useful in a dry color proofing process in which a colored image is transferred from the donor element to a receiver. To achieve full color reproduction, images are transferred in succession and in register, to the receiver from donor elements, respectively containing yellow, magenta, cyan and black colorants. A visible image is formed in the print-out layer as a result of imagewise exposure of the donor element to activating radiation and is utilized to facilitate visual registration in forming the multicolor image on the receiver.
    Type: Grant
    Filed: August 31, 1993
    Date of Patent: December 20, 1994
    Assignee: Eastman Kodak Company
    Inventors: Richard J. Kapusniak, David A. Niemeyer
  • Patent number: 5360688
    Abstract: A composite film article which is a flexible, heat resistant, polymeric film material having a non-opaque, partially translucent white surface side, having a visible light opacity of from about 0.90 to about 0.99; and a non-opaque, black surface side having a visible light opacity of less than 1.0, a transmission density of less than about 2.0 and a thickness less than about 5.0 microns. The article may be used as a base for images such that the images have a reduced optical dot gain.
    Type: Grant
    Filed: November 23, 1993
    Date of Patent: November 1, 1994
    Assignee: Hoechst Celanese Corporation
    Inventors: Robert J. von Trebra, Dennis J. Bellville
  • Patent number: 5352562
    Abstract: Disclosed is an image forming process employing a light-sensitive image forming material. The image forming material comprises a support, a light-heat conversion layer and an image forming layer, superposed in order. The process comprises the steps of imagewise exposing the image forming material to light so as to increase a bonding strength between the light-heat conversion layer and the image forming layer in the exposed area, pressing a receiving sheet on the light-heat conversion layer, and removing the receiving sheet from the image forming material to form a negative image on the receiving sheet in the unexposed area and to leave a positive image on the light-heat conversion layer in the exposed area.
    Type: Grant
    Filed: March 26, 1992
    Date of Patent: October 4, 1994
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Yonosuke Takahashi, Hideyuki Nakamura, Fumiaki Shinozaki
  • Patent number: 5346801
    Abstract: An image forming process of an image forming material comprising a support and provided thereon, a photosensitive layer and a covering layer in that order comprises imagewise exposing the material by laser beam scanning, and peeling the covering film from the exposed material to form an image on the support or on the covering film, wherein said photosensitive layer contains a colorant, an addition-polymerizable or cross-linkable compound and a salt of a cationic dye with a borate anion represented by the following Formula (1):Formula (1) ##STR1##
    Type: Grant
    Filed: March 18, 1993
    Date of Patent: September 13, 1994
    Assignee: Konica Corporation
    Inventors: Hiroshi Watanabe, Tatsuichi Maehashi, Koichi Nakatani, Katsunori Kato, Tawara Komamura
  • Patent number: 5340693
    Abstract: The present invention provides a heat recording material comprising on a support in the order given a porous layer of an image forming substance, a substance capable of converting radiation into heat, a thermoplastic layer containing a photocurable composition and a stripping layer. The present invention further provides a method for obtaining an image with such an heat recording material. Images of high quality and good wear and scratch resistance are obtained.
    Type: Grant
    Filed: February 18, 1993
    Date of Patent: August 23, 1994
    Assignee: Agfa-Gevaert, N.V.
    Inventors: Herman Uytterhoeven, Luc Bastiaens, Rudolf Van den Bergh, Luc Leenders
  • Patent number: 5328727
    Abstract: An image formed by an arbitrary method, can be reproduced on an object (to which image transfer is performed) having a three-dimensional arcuated surface, e.g., a cylindrical object. An original plate sheet is prepared by forming an image on a transparent sheet by using an ink containing carbon. A transfer ink sheet having a hot-melt ink layer formed on its one surface and a reflecting layer formed on its other surface is placed on an object to which image transfer is performed. A cushion member having transparency is placed on the transfer ink sheet, and a transparent plate is stacked on the cushion member. When the transparent plate is urged against the object side, the cushion member is compressed. As a result, the original plate sheet is deformed along the outer surface shape of the object and is brought into tight contact therewith. A flash lamp is turned on in this state. An image portion absorbs infrared rays emitted from the flash to generate heat.
    Type: Grant
    Filed: August 10, 1992
    Date of Patent: July 12, 1994
    Assignee: Casio Computer Co., Ltd.
    Inventors: Yukio Kashio, Yasuo Genba
  • Patent number: 5328804
    Abstract: Transfer images with high resolution are obtained with an image producing element containing a layer of a photopolymerisable composition with a monomer of Formula I by imagewise exposure and transfer of the unhardened parts of the photopolymerisable composition to an acceptor material. ##STR1## In Formula I A denotes a double-bonded or triple-bonded condensed urea group;X denotes O or NR in which R=C.sub.1 -C.sub.12 -alkyl;R.sup.1 denotes a double-bonded hydrocarbon group having 2 to 25 carbon atoms;R.sup.2 denotes a double-bonded to six-bonded linear or branched hydrocarbon group with 2 to 18 carbon atoms optionally interrupted by up to 3 O atoms;R.sup.3 denotes H or methyl;n denotes an integer from 1 to 5 andm stands for 2 or 3.
    Type: Grant
    Filed: August 20, 1992
    Date of Patent: July 12, 1994
    Assignee: Agfa Gevaert Aktiengesellschaft
    Inventors: Wolfgang Podszun, Michael Muller, Herman Uytterhoeven
  • Patent number: 5328800
    Abstract: The present invention provides 4 embodiments of a new image forming method. The image forming method uses a light-sensitive material and an image receiving material. The light-sensitive material comprises a support and a light-sensitive polymerizable layer provided thereon. The light-sensitive polymerizable layer contains silver halide, a reducing agent, an ethylenically unsaturated polymerizable compound or/and a cross-linkable polymer and a colorant. The image forming method comprises an exposing step, a developing step, a removing step, a transferring step and a repeating step. Some embodiments of the method further contain a laminating step. The present invention is characterized in that a multicolor image is formed on an image receiving material by the repeating step.
    Type: Grant
    Filed: May 6, 1992
    Date of Patent: July 12, 1994
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Hiroaki Yokoya, Keiji Takeda, Osami Tanabe, Katsuji Kitatani
  • Patent number: 5326667
    Abstract: The present invention provides 6 embodiments of a new image forming method. The image forming method uses a light-sensitive material and an image receiving material. The light-sensitive material comprises a support and a light-sensitive polymerizable layer provided thereon. Some embodiments of the light-sensitive material further have an adhesive layer. The light-sensitive polymerizable layer contains silver halide, a reducing agent and an ethylenically unsaturated polymerizable compound or/and a cross-linkable polymer. Some embodiments of the light-sensitive polymerizable layer further contain a colorant. The image forming method comprises an exposing step, a developing step, a removing step and a transferring step or a laminating step. Some embodiments of the image forming method further contains a peeling step or a toning step. The present invention is characterized in the combination of the removing step with the transferring step or the laminating step.
    Type: Grant
    Filed: May 6, 1992
    Date of Patent: July 5, 1994
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Hiroaki Yokoya, Keiji Takeda, Osami Tanabe, Katsuji Kitatani
  • Patent number: 5314784
    Abstract: A process for transferring toned images to an image receptor at low temperatures with improved back transfer characteristics.
    Type: Grant
    Filed: March 4, 1993
    Date of Patent: May 24, 1994
    Assignee: E. I. Du Pont de Nemours and Company
    Inventor: Robert P. Held
  • Patent number: 5304454
    Abstract: The present invention provides 3 embodiments of a new image forming method. The image forming method uses a light-sensitive material and an removing sheet. The light-sensitive material comprises a support and a light-sensitive polymerizable layer provided thereon. Some embodiments of the light-sensitive material further have an adhesive layer. The light-sensitive polymerizable layer contains silver halide, a reducing agent and an ethylenically unsaturated polymerizable compound or/and a cross-linkable polymer. Some embodiments of the light-sensitive polymerizable layer further contain a colorant. The image forming method comprises an exposing step, a developing step and a removing step. Some embodiments of the image forming method further contains a toning step. The present invention is characterized in the removing step using a removing sheet.
    Type: Grant
    Filed: May 6, 1992
    Date of Patent: April 19, 1994
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Hiroaki Yokoya, Keiji Takeda, Osami Tanabe, Katsuji Kitatani
  • Patent number: 5300399
    Abstract: In the present invention, one produces a negative-acting color proofing element comprising, sequentially, a strippable cover sheet which is transparent to actinic radiation; a crosslinked layer containing a polymer having phenolic groups; a color layer, containing a colorant, a polymeric binder, a polymerizable monomer and, optionally, a photoinitiator; a photoadhering layer, containing a linear photosensitive polymer containing ethylenically unsaturated, free-radical polymerizable groups and having a molecular weight greater than 3,000, a polymerizable monomer, and, optionally, a free radical photoinitiator; a thermoplastic adhesive layer; and a receiver sheet, at least one of the color layer and the photoadhering layer containing the photoinitiator.
    Type: Grant
    Filed: January 21, 1993
    Date of Patent: April 5, 1994
    Assignee: Hoechst Celanese Corporation
    Inventor: Wojciech A. Wilczak
  • Patent number: 5296331
    Abstract: An image receiving material comprises an image receiving layer provided on a support. The image receiving layer contains particles of a thermoplastic compound. The image receiving layer has a porous surface formed by the particles. According to the present invention, the image receiving material is prepared by forming the image receiving layer on the support and heating the image receiving layer at a temperature of higher than a softening point of the thermoplastic compound to widen pores in the porous surface. The image receiving material is preferably used in combination with a light-sensitive material which comprises a support and a light-sensitive layer in which light-sensitive microcapsules are dispersed. The light-sensitive microcapsules contain silver halide, a reducing agent, an ethylenically unsaturated polymerizable compound and a color image forming substance.
    Type: Grant
    Filed: March 10, 1993
    Date of Patent: March 22, 1994
    Assignee: Fuji Photo Film Co., Ltd.
    Inventor: Keiichi Taguchi
  • Patent number: 5294515
    Abstract: This invention relates to negative working photopolymerizable sheet constructions which, upon exposure to an actinic radiation source through a screened image, can accurately reproduce said image. The construction is useful as a color proofing film which can be employed to accurately predict the image quality from a lithographic printing process. Image development is by peel apart processing.
    Type: Grant
    Filed: May 17, 1991
    Date of Patent: March 15, 1994
    Assignee: Hoechst Celanese Corporation
    Inventors: Wojciech A. Wilczak, Timothy Hannigan
  • Patent number: 5288570
    Abstract: A composite film article which is a flexible, heat resistant polymeric film material having a non-opaque, partially translucent white surface side, having a visible light opacity of from about 0.90 to about 0.99; and a non-opaque, black surface side having a visible light opacity of less than 1.0, a transmission density of less than about 2.0 and a thickness of less than about 5.0 microns. The article may be used as a base for images such that the images have a reduced optical dot gain.
    Type: Grant
    Filed: August 12, 1992
    Date of Patent: February 22, 1994
    Assignee: Hoechst Celanese Corporation
    Inventors: Robert J. von Trebra, Dennis J. Bellville
  • Patent number: 5262295
    Abstract: A heat-developable photosensitive material is disclosed which has a support and provided thereon a photosensitive layer. The photosensitive layer contains at least an organic silver salt, a silver halide and a reducing agent represented by the formula (I). Also, an image forming method using the heat-developable photosensitive material is disclosed.
    Type: Grant
    Filed: April 14, 1992
    Date of Patent: November 16, 1993
    Assignee: Canon Kabushiki Kaisha
    Inventors: Hiromi Tanaka, Tetsuro Fukui, Kenji Kagami, Masao Suzuki
  • Patent number: 5246811
    Abstract: An image forming method uses a light-sensitive material and an image receiving material. The light-sensitive material comprises a support and a light-sensitive layer provided thereon. The light-sensitive layer contains silver halide, a reducing agent, pigment particles, an ethylenically unsaturated polymerizable compound and a base precursor. The silver halide, the reducing agent, the pigment particles, the polymerizable compound and the base precursor are contained in microcapsules dispersed in the light-sensitive layer. The image forming method comprises imagewise exposing the light-sensitive material, developing the light-sensitive material to polymerize the polymerizable compound, and pressing the light-sensitive material on the image receiving material to transfer the pigment particles to the image receiving material. In the present invention, the light-sensitive material is pressed at a pressure in the range of 20 kg/cm.sup.2 to 500 kg/cm.sup.2 while heating the light-sensitive material at 30.degree. C.
    Type: Grant
    Filed: January 17, 1992
    Date of Patent: September 21, 1993
    Assignee: Fuji Photo Film Co., Ltd.
    Inventor: Manabu Higuchi
  • Patent number: 5246812
    Abstract: A white, partially translucent, metallized film article which having a flexible, heat resistant, polymeric film material with opposite sides. The film material has deposited on a first side a metal coating which is spectrally reflective and partially light transmissive in the visible region of the spectrum, is capable of transmitting from about 1% to about 70% of incident visible light cast thereon; the second side having a white outermost surface, and has a visible light opacity of from about 0.5 to about 0.98.
    Type: Grant
    Filed: March 22, 1990
    Date of Patent: September 21, 1993
    Assignee: Hoechst Celanese Corporation
    Inventors: Robert J. von Trebra, Gerald A. Smith, Roy E. Hensel, Oliver A. Barton, deceased
  • Patent number: 5236806
    Abstract: This invention relates to positive working photopolymerizable sheet constructions which, upon exposure to an actinic radiation source through a screened image, can accurately reproduce said image. The construction is useful as a color proofing film which can be employed to accurately predict the image quality from a lithographic printing process.
    Type: Grant
    Filed: June 13, 1991
    Date of Patent: August 17, 1993
    Assignee: Hoechst Celanese Corporation
    Inventor: Stephan J. W. Platzer
  • Patent number: 5236801
    Abstract: The present invention is directed to an imaging system wherein the developed image and non-image areas are transferred to a receptor element by a transfer coating layer. The transfer layer of the present invention is coated on the support of the imaging sheet and/or developer sheet and comprises a material capable of holding developed images and non-image areas that can be transferred to a receptor surface upon the application of heat to the rear surface of the support. The transfer coating layer is capable of liquefying when heated and resolidifying when heat is removed.
    Type: Grant
    Filed: April 7, 1992
    Date of Patent: August 17, 1993
    Assignee: Foto-Wear, Inc.
    Inventor: Donald Hare
  • Patent number: 5227277
    Abstract: An imaging medium comprises a layer, depolymerizable by exposure to actinic radiation and substantially non-tacky prior to depolymerization but becoming tacky upon at least partial depolymerization, disposed adjacent a layer of an imaging material, which has a cohesive strength greater than the adhesive strength between the imaging material and the depolymerizable layer prior to depolymerization. This medium is imagewise exposed to radiation, thereby causing at least partial depolymerization of the polymer in the exposed areas, so rendering these exposed areas tacky and firmly attaching exposed areas of the imaging material layer to the depolymerizable layer. The unexposed areas of the imaging material are then removed from the depolymerizable layer.
    Type: Grant
    Filed: April 17, 1991
    Date of Patent: July 13, 1993
    Assignee: Polaroid Corporation
    Inventor: Kenneth C. Waterman
  • Patent number: 5225314
    Abstract: An imaging medium comprises a layer, depolymerizable by exposure to actinic radiation and undergoing a reduction in cohesivity upon at least partial depolymerization, disposed adjacent a layer of an imaging material, which has a cohesive strength greater than the cohesive strength of the depolymerizable layer after depolymerization. This medium is imagewise exposed to radiation, thereby causing at least partial depolymerization of the polymer in the exposed areas, so rendering these exposed areas lower in cohesivity than the unexposed areas. The exposed areas of the imaging material are then removed from the depolymerizable layer.
    Type: Grant
    Filed: April 17, 1991
    Date of Patent: July 6, 1993
    Assignee: Polaroid Corporation
    Inventors: Kenneth C. Waterman, Michael A. Young, Edward P. Lindholm
  • Patent number: 5219702
    Abstract: A process for transferring toned images to an image receptor at low temperatures with improved back transfer characteristics.
    Type: Grant
    Filed: February 27, 1991
    Date of Patent: June 15, 1993
    Assignee: E. I. Du Pont de Nemours and Company
    Inventor: Robert P. Held
  • Patent number: 5215859
    Abstract: Negative-acting flexographic printing plates display enhanced performance when backside irradiated with ionizing radiation instead of longer wavelength ultraviolet radiation. A better defined floor and more readily controlled floor is produced on the final printing plate.
    Type: Grant
    Filed: July 26, 1990
    Date of Patent: June 1, 1993
    Assignee: Minnesota Mining and Manufacturing Company
    Inventor: John A. Martens
  • Patent number: 5213940
    Abstract: The present invention relates to an image recording method utilizing photosensitive microcapsules. These photosensitive microcapsules have characteristics of being rendered hardenable upon exposure. Further, only the hardenable photosensitive microcapsules can be hardened. In this image recording method, an optional image pattern is initially exposed to a photosensitive recording medium having thereon the photosensitive microcapsules for rendering only the exposed photosensitive microcapsules hardenable corresponding to the image pattern. Subsequently, the exposed photosensitive recording medium is heated to harden only the hardenable photosensitive microcapsules. Further, the photosensitive recording medium is entirely exposed again with light to render the unhardened photosensitive microcapsules hardenable.
    Type: Grant
    Filed: April 3, 1992
    Date of Patent: May 25, 1993
    Assignee: Brother Kogyo Kabushiki Kaisha
    Inventors: Kouji Inaishi, Naomichi Kobayashi
  • Patent number: 5196288
    Abstract: An image forming method of imagewise exposing and heating a light-sensitive material is disclosed. The light-sensitive material comprises a support and a light-sensitive layer provided thereon. The light-sensitive layer contains silver halide, a reducing agent, an ethylenically unsaturated polymerizable compound, a color image forming substance and a base precursor. The silver halide, the reducing agent, the polymerizable compound, the color image forming substance and the base precursor are contained in microcapsules which are dispersed in the light-sensitive layer. According to the present invention, the support is made of a thin polymer film having a thickness of not more than 75 .mu.m. The light-sensitive material is heated from the side of the support for 0.1 to 5 seconds.
    Type: Grant
    Filed: September 9, 1991
    Date of Patent: March 23, 1993
    Assignees: Fuji Photo Film Co., Ltd., Seiko Epson Corp., Seiko Instruments, Inc.
    Inventor: Taku Nakamura